CN1451730A - Detergent composition - Google Patents
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- CN1451730A CN1451730A CN 03119380 CN03119380A CN1451730A CN 1451730 A CN1451730 A CN 1451730A CN 03119380 CN03119380 CN 03119380 CN 03119380 A CN03119380 A CN 03119380A CN 1451730 A CN1451730 A CN 1451730A
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Abstract
A detergent composition contains ingredients (A), (B), and (C): (A) phosphoric acid ester-based surfactant, comprising (a1) a phosphoric acid monoester represented by general formula (1) or (2) and (a2) a phosphoric acid diester represented by general formula (3) in the content ratio of (a1)/(a2) of 100/0-50/50 by weight, (B) a sulfobetaine represented by general formula (3); and (C) an alkyl saccharide-based surfactant represented by general formula (4). The detergent composition has reduced irritation to the skin, etc., excellent stability at low temperature and foaming power and improved sense of use.
Description
Technical field
The present invention relates to cleansing composition, relate to that pungency to skin etc. is little, low-temperature stability and whipability is all excellent and cleansing composition that usability is good.
Background technology
Phosphoric acid ester is that tensio-active agent is widely used in the composition as skin cleaning agent, compares with soap, alkyl ether sulphate and alkyl sulfuric ester, and its pungency to skin or hair is lower.Therefore, it is characterized in that to be applied in the middle of other anion surfactants of wide range or the mixed stocker of nonionogenic tenside etc.
, phosphoric acid ester is that tensio-active agent generally obtains as the mixture of monoesters or diester, and alkyl phosphate is to mix with water-soluble dialkyl group phosphoric acid not good and that latherability is also poor to exist.And, with phosphoric acid ester being tensio-active agent when using separately,, therefore the method for other cooperation as the tensio-active agent of auxiliary agent just proposed generally in aspects such as latherability and low-temperature stability existing problems as the main component of detergent.
Open in the clear 62-138594 communique the spy, disclosing and having used phosphoric acid ester is tensio-active agent and as the method for the hydroxyl sulfo betaine with ad hoc structure of auxiliary agent, this method is strong and to improve aspect the low-temperature stability be than more excellent method in latherability, but the cleansing composition that obtains can not satisfy latherability and usability two aspects simultaneously.
Open among the flat 1-287198 the spy, disclose and used phosphoric acid ester and be tensio-active agent and be the method for tensio-active agent as the alkyl sugar of auxiliary agent, the cleansing composition that obtains is being excellent aspect clearing power, the latherability, pungency is also low, but can not satisfy low-temperature stability and two aspects of usability simultaneously.
Therefore, it is all excellent and the cleansing composition of good usability arranged to the purpose of this invention is to provide a kind of, low-temperature stability little to pungencys such as skins and latherability.
Summary of the invention
The inventor finds, for using phosphoric acid ester is the cleansing composition of tensio-active agent, by with specific sultaine and alkyl sugar being tensio-active agent and with cooperating, it is all excellent and have a cleansing composition of good usability to access, low-temperature stability little to pungencys such as skins and whipability.
That is, the invention provides a kind of following compositions (A), (B) and cleansing composition (C) of containing.
(A) phosphoric acid ester is a tensio-active agent, and it is
(a
1) with general formula (1) expression phosphate monoester; With
(a
2) with general formula (2) expression phosphodiester;
Mixture, it contains ratio is weight ratio (a
1)/(a
2)=100/0～50/50
(in the formula, R
1, R
2And R
3The alkyl or alkenyl of representing the straight or branched of carbonatoms 8～18 respectively, X
1, X
2Represent hydrogen atom, alkali metal atom, alkaline earth metal atom, alkanolamine or ammonium respectively with Y, on average additional mole number k, m and n represent 0～10 numeral respectively).
(B) sultaine of representing with general formula (3)
(in the formula, R
4Saturated or the undersaturated alkyl of expression carbonatoms 8～18, R
5The alkyl of expression hydrogen atom or carbonatoms 1～4, R
6And R
7The alkyl of representing carbonatoms 1～4 respectively, p are represented 0～1 numeral, and q represents 0～6 numeral, and Z represents hydrogen atom or hydroxyl).
(C) the alkyl sugar with general formula (4) expression is tensio-active agent
(in the formula, R
8The straight chain of expression carbonatoms 8～18 or alkyl, thiazolinyl or the alkyl phenyl of side chain, R
9The alkylidene group of expression carbonatoms 2～4, G represents the reducing sugar of carbonatoms 5～6, on average additional mole number s represents 0～10 numeral, average sugared polymerization degree t represents 1～10 numeral).
Embodiment
In as the present invention in the phosphoric acid ester by general formula (1) and (2) expression of the composition of employed low irritant base (A), as R
1, R
2And R
3, be preferably carbonatoms 10～16, be preferably the alkyl of carbonatoms 12～14, X especially
1, X
2With Y preferably alkali metal atom such as potassium or sodium or trolamine,, be preferably potassium especially from this puts to the solvability of water.Average additional mole number k, m and the n of oxyethane from the viewpoint of foaming power, are respectively 0～4 mole, preferred especially 0～2 mole.
Alkyl phosphate monoester (a in the composition (A)
1) and alkylphosphonic acid carboxylic acid diester (a
2) contain proportional, the viewpoint that viscosity does not raise, cooperates easily when making, preferred weight ratio (a
1)/(a
2)=90/10～50/50, more preferably 90/10～60/40, be preferably 85/15～65/35 especially.Alkyl phosphate monoester (a
1) containing ratio when low, whipability is poor.
The phosphoric acid ester of composition (A) is the use level of tensio-active agent, from foaming, clearing power and the easy viewpoint that cooperates, is preferably 5～40 weight % of cleansing composition of the present invention, and more preferably 8～30 weight % are preferably 10～30 weight % especially.
In the sultaine by general formula (3) expression of composition (B), R
4The alkyl of carbonatoms 8～18 preferably, R
5Preferably hydrogen atom or ethyl, R
6And R
7Preferably methyl or ethyl, p is 0～1 numeral preferably, and q is 0～4 numeral preferably, and Z is hydroxyl preferably.
Sultaine as preferred composition (B), can enumerate alkylamino propyl group sultaine, alkyl hydroxy sultaine, amidosulfobetaines, can enumerate lauryl dimethyl hydroxyl sulfo betaine, myristyl dimethyl hydroxyl sultaine, N especially, N-dimethyl lauric acid amido-2-hydroxyl sulfo betaine, N, N-dimethyl coco-nut oil fatty acid amido propyl-2-hydroxyl sulfo betaine, wherein R
6And R
7Be methyl, R
4Be the compound of lauryl or myristyl, promptly lauryl dimethyl hydroxyl sultaine and myristyl dimethyl hydroxyl sultaine are most preferred.
Composition (B) has the maintenance low-temperature stability, improves the effect of foaming power.
From the viewpoint of whipability and low-temperature stability, the content of composition (B) is preferably 0.1～20 weight % of cleansing composition of the present invention, and more preferably 1～15 weight % is preferably 2～10 weight % especially.
The alkyl sugar by general formula (4) expression at composition (C) is in the tensio-active agent, R
8The alkyl or alkenyl of the straight or branched of carbonatoms 10～14 preferably, G be as reducing sugar, preferably glucose, lactose, fructose, especially preferably glucose.
The average sugared polymerization degree is preferably 1～4.So average sugared polymerization degree t wishes by R
8The physicals that alkyl or alkenyl brought on consideration select, such as, at R
8Be that carbonatoms is that t is preferably 1～1.4 under 8～11 the alkyl situation.At R
8Be that carbonatoms is that t is preferably 1.2～2.0 under 12～14 the alkyl situation.And at R
8Be that t is preferably 1.2～1.4 under the situation of alkyl of carbonatoms 8～14.
Composition (C) has the effect of the whipability of raising in the hard water of high rigidity.
The content of composition (C) is preferably 0.1～20 weight % of cleansing composition of the present invention, is preferably 2～15 weight % especially.
From low-temperature stability with improve the viewpoint of foaming power, with respect to the content of composition (A), weight ratio (A)/[(B)+(C)]=99/1～40/60 of composition (B) and total content (C), especially preferably 95/5～70/30.From improving the viewpoint of low-temperature stability and usability, (B) and the weight ratio (B)/(C)=99/1～40/60 of use level (C), especially preferably 95/5～50/50.
Because used composition (A), (B) and (C) simultaneously, when the maintenance phosphoric acid ester was tensio-active agent inherent low irritant, having improved as phosphoric acid ester was the whipability of tensio-active agent shortcoming.And see that low-temperature stability also improves more, usability also is good.
In cleansing composition of the present invention, according to application target, can also in the scope of harmless effect of the present invention, add pigment, spices, sterilant, antiphlogistic, sequestrant, suds booster, tackifier, viscosity modifier, granularity and adjust agent, sanitas, wetting agent, pH value conditioning agent, other tensio-active agent etc.
Formulation to cleansing composition of the present invention has no particular limits, and can be existing known various formulations, such as liquid shampoo, creaminess Cleansing Foam, bathing agents etc.
The manufacture method of cleansing composition of the present invention comprises following operation.
1) modulation contains composition (A), (B) and mixture (C);
2) then this mixture container of packing into.
In the time of in mixing element (A), (B) and (C), their addition sequence has nothing to do, and also can add simultaneously.Owing to see that viscosity can increase when gradation composition (A), preferably under 40～80 ℃, carry out heated and stirred.
Alkyl phosphate monoester (a in composition (A)
1) and alkylphosphonic acid carboxylic acid diester (a
2) weight ratio (a
1)/(a
2)=90/10～50/50, particularly 90/10～60/40 o'clock, viscosity can sharply not increase when mixing, can below 10000mPas, make, and it is 85/15～65/35 o'clock, because the dissolution time when cooperating is short, can suppress the raw material smell that causes by heat and the deterioration of color, so be preferred.
Embodiment
Embodiment 1～15 and comparative example 1～7
According to usual method, the cleansing composition of the composition shown in the modulometer 1～3, the evaluation of carrying out whipability, usability and low-temperature stability as described below.Its result is illustrated in table 1～3.In addition, when the composition of preparation table 1 and table 2, viscosity does not increase, and cooperates easily.
(1) foaming power test
The artificial dirt lanolin of adding 0.5% in cleansing composition 1% (the 4 ° of hard water) aqueous solution, with the flat pattern blade under 40 ℃ of conditions with the rotating speed of 1000rpm, in rotary drum, stirred 5 minutes in the mode that turning direction was reversed in per 10 seconds, stir and finish then to estimate according to blistered amount.
(2) whipability and usability
1g is coated on the palm according to the cleansing composition of usual method adjustment, whipability and usability when observe cleaning hand, wrist, the special evaluation group that is made up of 10 people estimates according to following judgement criteria.
(whipability)
A: the bubble amount is very many
B: the bubble amount is many
C: the bubble amount is few slightly
D: the bubble amount is few
(usability)
A: usability is good
B: usability is good slightly
C: usability is poor
(3) low-temperature stability test
Cleansing composition is put into vial, and preservation is after 15 days down at 5 ℃, and by 5 ℃ of taking-ups, placement is 1 hour under room temperature (25 ℃), is estimated by naked eyes according to following standard.
◎: transparent
Zero: muddy a little
△: slight haze
*: produce precipitation and separation
Table 1
| Embodiment | |||||||||
| ?1 | ?2 | ?3 | ?4 | ?5 | ?6 | ?7 | ?8 | ||
| (A) | / ( / ＝75/25 ) / ( / ＝90/10 ) / ( / ＝70/30 ) / ( / ＝85/15 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 2 ) / ( 2 ) ( /＝75/25 ) ( 1 ) / ( 1 ) ( / ＝75/25 ) ( 3 ) / ( 3 ) ( / ＝80/20 ) | ?14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ??- ??- ??- ?15 ??- ??- ??- ??- | ?- ?15 ??- ??- ??- ??- ??- ??- | ??- ??- ?28 ??- ??- ??- ??- ??- |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay matrix/dilauryl body=35/65) | ??- | ??- | ??- | ??- | ??- | ??- | ??- | ??- | |
| (B) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine N, N-dimethyl dodecanamide propyl-2-hydroxyl sulfo betaine | ?2.5 ??- ??- | ?3.0 ??- ??- | ?2.5 ??- ??- | ?2.5 ??- ??- | ?7.0 ??- ??- | ?2.5 ??- ??- | ?5.0 ??- ??- | ?7.0 ??- ??- |
| (C) | Alkyl sugar [C 12-O-(G) 1.3] *1Dodecyl maltoside octyl glucoside | ?2.5 ??- ??- | ?2.0 ??- ??- | ??- ?2.5 ??- | ??- ??- ?2.5 | ?3.0 ??- ??- | ?2.5 ??- ??- | ?5.0 ??- ??- | ?3.0 ??- |
| Purified Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| Foaming power (mL) | ?190 | ?200 | ?210 | ?191 | ?231 | ?210 | ?225 | ?230 | |
| Whipability usability low-temperature stability | ??A ??A ??◎ | ??A ??A ??◎ | ??A ??A ??○ | ??A ??A ??○ | ??A ??A ??◎ | ??A ??A ??◎ | ??A ??A ??◎ | ??A ??A ??○ | |
* 1: C
12The expression lauryl.G represents glucose
Table 2
| Embodiment | ||||||||
| ??9 | ?10 | ?11 | ?12 | ?13 | ?14 | ??15 | ||
| ??(A) | / ( / ＝75/25 ) / ( / ＝90/10 ) / ( /＝70/30 ) / ( / ＝85/15 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 1 ) / ( 1 ) ( / ＝75/25 ) ( 3 ) / ( 3 ) ( / ＝80/20 ) | ?20 ??- ??- ??- ??- ??- ??- ??- | ?28 ??- ??- ??- ??- ??- ??- ??- | ?14 ???- ???- ???- ???- ???- ???- ???- | ??- ??- ??- ??- ?14 ???- ???- ??- | ??- ??- ??- ??- ?10.5 ?3.5 ???- ??- | ??- ??- ??- ??- ???- ???- ?14 ???- | ???- ???- ???- ???- ???- ???- ???- ??14 |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay matrix/dilauryl body=35/65) | ??- | ??- | ???- | ??- | ??- | ???- | ???- | |
| ??(B) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine N, N-dimethyl dodecanamide propyl-2-hydroxyl sulfo betaine | ??- ??5 ??- | ??2.0 ??- ??- | ???- ???- ??2.5 | ??2.5 ??- ??- | ??2.5 ??- ??- | ??2.5 ??- ??- | ??2.5 ???- ???- |
| ??(C) | Alkyl sugar [C 12-O-(G) 13] *1Dodecyl maltoside octyl glucoside | ?3.0 ??- ??- | ?1.0 ??- ??- | ??2.5 ???- ???- | ??2.5 ???- ???- | ??3.5 ??- | ??4.5 ???- ???- | ??5.5 ???- ???- |
| Purified Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| Foaming power (mL) | ??251 | ??245 | ??200 | ??191 | ??200 | ??192 | ??180 | |
| Whipability usability low-temperature stability | ??A ??A ??○ | ??A ??A ??○ | ??A ??A ??○ | ???A ???A ???◎ | ???A ???A ???◎ | ??A ??A ??◎ | ???B ???A ???◎ | |
* 1: C
12The expression lauryl.G represents glucose
Table 3
| Comparative example | ||||||||
| ??1 | ??2 | ??3 | ??4 | ??5 | ??6 | ??7 | ||
| (A) | / ( / ＝75/25 ) / ( / ＝90/10 ) / ( /＝70/30 ) / ( / ＝85/15 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 1 ) / ( 1 ) ( / ＝75/25 ) ( 3 ) / ( 3 ) ( / ＝80/20 ) | ??14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ?14 ??- ??- ???- ????- ????- ???- ???- | ??- ??- ??- ??- ???- ???- ??- ??- | ?14 ??- ??- ??- ??- ??- ??- ??- | ??- ??- ??- ??- ?14 ??- ??- ??- | ??- ??- ??- ??- ?14 ??- ??- ??- |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay matrix/dilauryl body=35/65) | ??- | ??- | ???- | ?15.0 | ??- | ??- | ??- | |
| (B) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine N, N-dimethyl dodecanamide propyl-2-hydroxyl sulfo betaine | ?2.5 ??- ??- | ??- ??- ??- | ???- ???- ???- | ??5.0 ??- ??- | ??- ??- ?2.5 | ?2.5 ??- ??- | ???- ???- ???- |
| (C) | Alkyl sugar [C 12-O-(G) 13] *1Dodecyl maltoside octyl glucoside | ??- ??- | ?2.5 ??- | ???- ???- | ?5.0 ??- | ??- ??- | ??- ??- | ??2.5 ??- |
| Purified Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| Foaming power (mL) | ?125 | ?135 | ?50 | ?100 | ?136 | ?120 | ?129 | |
| Whipability usability low-temperature stability | ??C ??B ??△ | ??C ??C ??△ | ??D ??B ??× | ??D ??B ??△ | ??C ??A ??△ | ??C ??B ??△ | ??C ??C ??△ | |
* 1: C
12The expression lauryl, G represents glucose
Embodiment 16 (bathing agents)
Make bathing agents according to following prescription:
(weight part)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 20
(single bay matrix/dilauryl body=75/25)
Lauryl hydroxyl sulfo betaine 3
Alkyl sugar [C
12-O-(G)
1.3]
A)3
Propylene glycol 5
Vinylformic acid-alkyl methacrylate multipolymer
B)0.5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT???????????????????????????????????????????????????????????0.2
Spices 0.05
The Purified Water surplus
Add up to 100.00
A): C
12The expression lauryl, G represents glucose
B): power one ボ Port one Le ETD2020; BFGoodrich society system
Embodiment 17 (bathing agents)
Make bathing agents according to following prescription:
(weight part)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 15
(single bay matrix/dilauryl body=75/25)
Lauryl hydroxyl sulfo betaine 5
Alkyl sugar [C
10-O-(G)
1.3]
C)3
Propylene glycol 2
Polyethylene oxide alkyl ethers potassium salt 2
Glycerine 3
Cationic cellulose [Port イ ズ C-150L; Flower king (strain) system] 0.3
Diglycol stearate 2
Whitfield's ointment 0.2
BHT???????????????????????????????????????????????????????????0.2
Spices 0.05
The Purified Water surplus
Add up to 100.00
C): C
10The expression decyl, G represents glucose
The bathing agents of embodiment 16 and embodiment 17, the whipability excellence, and in use, the sense of touch after using is good.
The embodiment 18:(agent of washing one's face)
According to the following prescription manufacturing agent of washing one's face.
(weight part)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 19
(single bay matrix/dilauryl body=75/25)
Lauryl hydroxyl sulfo betaine 5
Alkyl sugar [C
12-O-(G)
1.3]
D)3
Dipropylene glycol 1.5
Propylene glycol 5
Sorbyl alcohol 5
Polyethylene oxide alkyl ethers potassium salt 1.8
(alkyl: C
12/ C
14=75/25, EO:10)
Three Unimac 5680 polyoxyethylene shrink sorbitol esters (EO=160) 2
Cationic cellulose [Port イ ズ C-150L; Flower king (strain) system] 0.3
Vinylformic acid-methacrylic dialkylaminobenzoic acid resin copolymer
E)0.5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.3
BHT????????????????????????????????????????????????????????0.2
Spices 0.05
The Purified Water surplus
Add up to 100.00
D): C
12The expression lauryl, G represents glucose
E): power one ボ Port one Le ETD2020; BFGoodrich society system
Embodiment 19 (agent of washing one's face)
According to the agent of washing one's face of following formulation.
(weight part)
Lauryl nitranol salt/dilauryl nitranol 19
Salt (single bay matrix/dilauryl body=73/27)
Alkyl sugar [C
10-O-(G)
1.3]
F)3
Glycerine 16
Three Unimac 5680 polyoxyethylene shrink sorbitol esters (EO=160) 2
Cationic cellulose [Port イ ズ C-150L; Flower king (strain) system] 0.5
Hydroxylated cellulose
G)1
Lauryl hydroxyl sulfo betaine 5
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT???????????????????????????????????????????????????????0.2
The Purified Water surplus
Add up to 100.00
D): C
10The expression lauryl, G represents glucose
E): HEC850K; ダ イ セ Le chemical industry (strain) system
The agent of washing one's face of embodiment 18 and embodiment 19, the whipability excellence, and in use with use after sense of touch good.
Embodiment 20 (bathing agents)
According to following formulation bathing agents.
(weight part)
Polyoxyethylene (2) lauryl potassium phosphate salt/polyoxyethylene (2) February 15
Osmanthus base potassium phosphate salt (single bay matrix/dilauryl body=75/25)
Lauryl hydroxyl sulfo betaine 5
Alkyl sugar [C
12-O-(G)
1.3]
H)3
Dipropylene glycol 2
Polyethylene oxide alkyl ethers potassium salt 2
Glycerine 3
Cationic cellulose [Port イ ズ C-150L; Flower king (strain) system] 0.3
Diglycol stearate 2
Whitfield's ointment 0.2
BHT???????????????????????????????????????????????????????0.2
Spices 0.05
The Purified Water surplus
Add up to 100.00
H): C
12The expression lauryl, G represents glucose
The whipability excellence of the bathing agents of embodiment 20, and in use with use after sense of touch good.
Embodiment 21 (agent of washing one's face)
According to the agent of washing one's face of following formulation.
(weight part)
Polyoxyethylene (2) lauryl potassium phosphate salt/polyoxyethylene (2) February 19
Osmanthus base potassium phosphate salt (single bay matrix/dilauryl body=75/25)
Polyoxyethylene (2) myristyl potassium phosphate salt/polyoxyethylene (2) 26
Myristyl potassium phosphate salt (single Semen Myristicae matrix/myristyl body
＝75/25)
Alkyl sugar [C
12-O-(G)
1.3]
I)3
Glycerine 16
Three Unimac 5680 polyoxyethylene shrink sorbitol esters (EO:160) 2
Poise C-80M [Port イ ズ C-150L; Flower king (strain) system] 0.5
Vinylformic acid-methacrylic dialkylaminobenzoic acid resin copolymer
J)1
Lauryl hydroxyl sulfo betaine 5
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT???????????????????????????????????????????????????????0.2
The Purified Water surplus
Add up to 100.00
I): C
12The expression lauryl, G represents glucose
J): power one ボ Port one Le ETD2020; BFGoodrich society system
The agent of washing one's face of embodiment 21, the whipability excellence, and in use with use after sense of touch good.
Utilizability on the industry
Cleansing composition of the present invention is little to the excitant of skin etc., the foaming characteristic excellence, make with a good sense, the low-temperature stability excellence.
Claims (9)
1. cleansing composition is characterized in that: contain following composition (A), (B) and (C), (A) phosphoric acid ester is a tensio-active agent, and it is
(a
1) with general formula (1) expression phosphate monoester; With
(a
2) with general formula (2) expression phosphodiester; Mixture, it contains ratio is weight ratio (a
1)/(a
2)=100/0～50/50
(in the formula, R
1, R
2And R
3The alkyl or alkenyl of representing the straight or branched of carbonatoms 8～18 respectively, X
1, X
2Represent hydrogen atom, alkali metal atom, alkaline earth metal atom, alkanolamine or ammonium respectively with Y, on average additional mole number k, m and n represent 0～10 numeral respectively).
(B) sultaine of representing with general formula (3)
(in the formula, R
4Saturated or the undersaturated alkyl of expression carbonatoms 8～18, R
5The alkyl of expression hydrogen atom or carbonatoms 1～4, R
6And R
7The alkyl of representing carbonatoms 1～4 respectively, p are represented 0～1 numeral, and q represents 0～6 numeral, and Z represents hydrogen atom or hydroxyl).
(C) the alkyl sugar with general formula (4) expression is tensio-active agent
(in the formula, R
8The straight chain of expression carbonatoms 8～18 or alkyl, thiazolinyl or the alkyl phenyl of side chain, R
9The alkylidene group of expression carbonatoms 2～4, G represents the reducing sugar of carbonatoms 5～6, on average additional mole number s represents 0～10 numeral, average sugared polymerization degree t represents 1～10 numeral).
2. cleansing composition as claimed in claim 1 is characterized in that: in cleansing composition, composition (A) is 5～40 weight %.
3. cleansing composition as claimed in claim 1 is characterized in that: in cleansing composition, composition (B) is 0.5～20 weight %.
4. cleansing composition as claimed in claim 1 is characterized in that: in cleansing composition, composition (C) is 0.5～20 weight %.
5. cleansing composition as claimed in claim 1 is characterized in that; In cleansing composition, composition (A) is 5～40 weight %, and composition (B) is 0.5～20 weight %, and composition (C) is 0.5～20 weight %.
6. cleansing composition as claimed in claim 1 is characterized in that: weight ratio (A)/[(B)+(C)]=99/1～40/60 of the total of composition (A) and composition (B) and composition (C).
7. cleansing composition as claimed in claim 1 is characterized in that: weight ratio (B)/(C)=99/1～40/60.
8. cleansing composition as claimed in claim 1 is characterized in that: (a in the composition (A)
1) and (a
2) content weight ratio (a
1)/(a
2)=90/10～60/40.
9. the manufacture method of each described cleansing composition in the claim 1～8 is characterized in that: have with composition (A), (B) with (C) mix, the operation of heated and stirred under 40～80 ℃ of conditions then.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002110976 | 2002-04-12 | ||
| JP2002110976 | 2002-04-12 | ||
| JP2002292355 | 2002-10-04 | ||
| JP2002292355A JP3977718B2 (en) | 2002-04-12 | 2002-10-04 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1451730A true CN1451730A (en) | 2003-10-29 |
| CN1329496C CN1329496C (en) | 2007-08-01 |
Family
ID=29253544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031193803A Expired - Lifetime CN1329496C (en) | 2002-04-12 | 2003-03-14 | Detergent composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3977718B2 (en) |
| CN (1) | CN1329496C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100465258C (en) * | 2003-12-26 | 2009-03-04 | 花王株式会社 | Detergent compositions |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0246639B2 (en) * | 1985-12-12 | 1990-10-16 | Kao Corp | SENJOZAISOSEIBUTSU |
| JP2623333B2 (en) * | 1988-01-12 | 1997-06-25 | 花王株式会社 | Detergent composition |
| JP3327889B2 (en) * | 1999-12-24 | 2002-09-24 | 花王株式会社 | Detergent composition |
| JP4591222B2 (en) * | 2005-06-09 | 2010-12-01 | セイコーエプソン株式会社 | Electro-optical device and image forming apparatus |
-
2002
- 2002-10-04 JP JP2002292355A patent/JP3977718B2/en not_active Expired - Fee Related
-
2003
- 2003-03-14 CN CNB031193803A patent/CN1329496C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100465258C (en) * | 2003-12-26 | 2009-03-04 | 花王株式会社 | Detergent compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004002273A (en) | 2004-01-08 |
| CN1329496C (en) | 2007-08-01 |
| JP3977718B2 (en) | 2007-09-19 |
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