CN1450178A - Composite manganese base deoxidized alloy - Google Patents

Composite manganese base deoxidized alloy Download PDF

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Publication number
CN1450178A
CN1450178A CN 03123039 CN03123039A CN1450178A CN 1450178 A CN1450178 A CN 1450178A CN 03123039 CN03123039 CN 03123039 CN 03123039 A CN03123039 A CN 03123039A CN 1450178 A CN1450178 A CN 1450178A
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China
Prior art keywords
raw material
alloy
manganese base
content
surplus
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Pending
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CN 03123039
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Chinese (zh)
Inventor
李永毅
刘庆丰
杨志英
吴立恩
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Individual
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Individual
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Priority to CN 03123039 priority Critical patent/CN1450178A/en
Publication of CN1450178A publication Critical patent/CN1450178A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses a composite manganese base deoxidized alloy. It is made up by using metal aluminium, magnesium, ferromanganese, silicon-calcium-barium and adhesive as raw material through the processes of pulverizing raw material, stirring, press-forming and drying, etc. Said invention overcomes the defects of smelting method which can produce non-uniform molten alloy and lots of slag spot, and can make its product have higher cleaness, and can ensure alloy density, and can raise steel material quality and reduce steel-smelting cost.

Description

Compound manganese base deoxygenated alloy
Technical field
The present invention relates to a kind of alloy material, relate to a kind of compound manganese base deoxygenated alloy specifically.
Background technology
At present, relate to for smelting industry that to make steel the deoxygenated alloy of usefulness of a great variety, but these alloys are to be main deoxidation and so on aluminium mostly.This class deoxygenated alloy proportion is less, thereby has influenced the direct reaction with molten steel, deoxidation effect instability.Because its deoxidation products in participating in deoxidation process is to be present in the molten steel with floss, ascent rate is very slow, has influenced the cleanliness factor of steel on the one hand; On the other hand,, cause the tundish dross easily, cause and stop in the continuous casting to water, influence extraordinary production if add-on is excessive.Therefore, need this technology is further improved.
Summary of the invention
The purpose of this invention is to provide a kind of compound manganese base deoxygenated alloy, be with the bigger ferromanganese of density as matrix, make it have that density is big, lumpiness is even, molten speed is fast, cleaning molten steel, raising steel product quality, reduce the result of use of steel-making cost.
For achieving the above object, alloy raw material that technical scheme of the present invention adopted and content (is unit with the weight percent):
C:1-7%, Mn:20-55%, Si:3-12%, Al:5-20%, Ca+Ba+Mg: P 〉=5%: S≤0.20%: moisture content≤0.08% :≤0.50%, surplus is Fe.
Preferred feedstock ratio range of the present invention:
C:3-6%, Mn:35-45%, Si:5-10%, Al:12-16%, Ca+Ba+Mg: P 〉=5%: S≤0.20%: moisture content≤0.08% :≤0.50%, surplus is Fe.
Optimum material proportion scope of the present invention:
C:4.72%, Mn:41.3%, Si:7.49%, Al:14.71%, Ca+Ba+Mg:5.94%, P:0.153%, S: moisture content≤0.059% :≤0.41%, surplus is Fe.
Its processing step:
1, choosing high-quality ferromanganese, metallic aluminium, magnesium, silico-calcium barium in proportion is raw material for standby;
2, add binding agent after above-mentioned raw materials is crushed to the 10-50 order, it is standby fully to be mixed;
3, the material after above-mentioned being mixed is poured into compression moulding in the mould of pressing machine, drying to 180 ℃ is finished product again.
Characteristics of the present invention are: compound manganese base deoxygenated alloy is to adopt physics synthetic mode, has overcome shortcomings such as smelting process alloy melting inequality, slag inclusion are many, and the cleanliness factor that makes its product more.Its effect be with ferromanganese as matrix, guaranteed the density of alloy, alloy is directly contacted with molten steel, satisfied the requirement of molten steel degree of depth deoxidation greatly; Alkaline-earth metal Ca, Ba in this alloy, Mg are reductors, after these elements are added by a certain percentage, can improve inclusion morphology in the molten steel, help the floating upward quickly of inclusion, thereby have played the effect of strong deoxidation and cleaning molten steel; This alloy product substitutes aluminium base deoxygenated alloy in addition, can reduce steel-making cost.
Embodiment
One, chooses the raw material composition
1. metallic aluminium powder: composition Al:99.9%;
2. metal magnesium powder: composition Mg:99.95;
3. ferromanganese powder: composition Mn:65.32%, C:6.51%, Si:1.54%, P:0.184%, S:0.042%;
4. silico-calcium barium powder: composition Si:45.41%, Ca:15.25%, Ba:10.78%, C:0.35%, P:0.026%, S:0.024%;
5. binding agent (water glass): 52 ° of degree Beaume.
Two, composition of raw materials:
Metallic aluminium Al:15%, MAGNESIUM METAL Mg:2%, ferromanganese powder Mn:64%, silico-calcium barium Si:17%, binding agent: 2%.
Three, production craft step:
1, all raw materials are taken by weighing in proportion, gross weight is 100Kg, makes raw material pulverizing add binding agent to the 10-50 order, fully stirs 10 minutes in sand mill.
2, the above-mentioned raw material that is mixed is put into pressing machine mould (Φ 50mm * 50mm), compression moulding.
3, the material of compression moulding is put into drying kiln, oven dry is to 180 ℃, and kiln discharge naturally cooling packing is finished product.

Claims (4)

1, a kind of compound manganese base deoxygenated alloy, it comprises following raw material and content; Weight is %:
C:1-7%, Mn:20-55%, Si:3-12%, Al:5-20%, Ca+Ba+Mg: P 〉=5%: S≤0.20%: moisture content≤0.08% :≤0.50%, surplus is Fe.
2,, it is characterized in that the preferable range of described raw material and content by the described compound manganese base deoxygenated alloy of claim 1:
C:3-6%, Mn:35-45%, Si:5-10%, Al:12-16%, Ca+Ba+Mg: P 〉=5%: S≤0.20%: moisture content≤0.08% :≤0.50%, surplus is Fe.
3,, it is characterized in that the optimum range of described raw material and content by the described compound manganese base deoxygenated alloy of claim 1:
C:4.72%, Mn:41.3%, Si:7.49%, Al:14.71%, Ca+Ba+Mg:5.94%, P:0.153%, S: moisture content≤0.059% :≤0.41%, surplus is Fe.
4, a kind of technology that is used for the compound manganese base deoxygenated alloy of aforesaid right requirement is:
1. choosing high-quality ferromanganese, metallic aluminium, magnesium, silico-calcium barium in proportion is raw material for standby;
2. add binding agent after above-mentioned raw materials being crushed to the 10-50 order, it is standby fully to be mixed;
3. pour the above-mentioned material that is mixed in pressing machine mould compression moulding, drying to 180 ℃ is finished product again.
CN 03123039 2003-04-28 2003-04-28 Composite manganese base deoxidized alloy Pending CN1450178A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 03123039 CN1450178A (en) 2003-04-28 2003-04-28 Composite manganese base deoxidized alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 03123039 CN1450178A (en) 2003-04-28 2003-04-28 Composite manganese base deoxidized alloy

Publications (1)

Publication Number Publication Date
CN1450178A true CN1450178A (en) 2003-10-22

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Family Applications (1)

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CN 03123039 Pending CN1450178A (en) 2003-04-28 2003-04-28 Composite manganese base deoxidized alloy

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CN (1) CN1450178A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101906560A (en) * 2010-07-15 2010-12-08 首钢总公司 Magnesium-aluminum-ferromanganese alloy for steelmaking deoxidization and desulphurization and preparation method thereof
CN102643953A (en) * 2012-04-28 2012-08-22 常州市茂盛特合金制品有限公司 Compressing double deoxidizer for steelmaking and preparation method thereof
CN103556028A (en) * 2013-11-06 2014-02-05 攀钢集团研究院有限公司 Magnesium-and-manganese-containing deoxidizing alloy for steel making and deoxidizing method for steel making

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101906560A (en) * 2010-07-15 2010-12-08 首钢总公司 Magnesium-aluminum-ferromanganese alloy for steelmaking deoxidization and desulphurization and preparation method thereof
CN101906560B (en) * 2010-07-15 2012-07-04 首钢总公司 Magnesium-aluminum-ferromanganese alloy for steelmaking deoxidization and desulphurization and preparation method thereof
CN102643953A (en) * 2012-04-28 2012-08-22 常州市茂盛特合金制品有限公司 Compressing double deoxidizer for steelmaking and preparation method thereof
CN103556028A (en) * 2013-11-06 2014-02-05 攀钢集团研究院有限公司 Magnesium-and-manganese-containing deoxidizing alloy for steel making and deoxidizing method for steel making
CN103556028B (en) * 2013-11-06 2015-09-16 攀钢集团研究院有限公司 Containing steel-making deoxygenated alloy and the deoxidation in steel making method of magnesium, manganese

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