CN1448448A - Hydrolytic blackboard-writing ink composition - Google Patents
Hydrolytic blackboard-writing ink composition Download PDFInfo
- Publication number
- CN1448448A CN1448448A CN 03114634 CN03114634A CN1448448A CN 1448448 A CN1448448 A CN 1448448A CN 03114634 CN03114634 CN 03114634 CN 03114634 A CN03114634 A CN 03114634A CN 1448448 A CN1448448 A CN 1448448A
- Authority
- CN
- China
- Prior art keywords
- writing
- blackboard
- ink
- hydrolysis
- pyridine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003301 hydrolyzing effect Effects 0.000 title 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 229960004063 propylene glycol Drugs 0.000 claims abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- 230000007062 hydrolysis Effects 0.000 claims description 21
- 238000006460 hydrolysis reaction Methods 0.000 claims description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 18
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 18
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 235000017550 sodium carbonate Nutrition 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 8
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 8
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 6
- 150000007857 hydrazones Chemical class 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
- LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 claims description 4
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 235000019439 ethyl acetate Nutrition 0.000 claims description 4
- OBRGVMYQZVQHGO-UHFFFAOYSA-N 3,3-bis(3,5-dibromo-4-hydroxyphenyl)-2-benzofuran-1-one Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2C(=O)O1 OBRGVMYQZVQHGO-UHFFFAOYSA-N 0.000 claims description 3
- CPBJMKMKNCRKQB-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-2-benzofuran-1-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 CPBJMKMKNCRKQB-UHFFFAOYSA-N 0.000 claims description 3
- 239000002696 acid base indicator Substances 0.000 claims description 3
- HQHBAGKIEAOSNM-UHFFFAOYSA-N naphtholphthalein Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=CC=C(C4=CC=CC=C43)O)=CC=C(O)C2=C1 HQHBAGKIEAOSNM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004782 1-naphthols Chemical class 0.000 claims description 2
- KAQBNBSMMVTKRN-UHFFFAOYSA-N 2,4,6-trinitrobenzoic acid Chemical compound OC(=O)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O KAQBNBSMMVTKRN-UHFFFAOYSA-N 0.000 claims description 2
- HGPSVOAVAYJEIJ-XDHOZWIPSA-N 2-[(e)-(3,4-dihydroxyphenyl)-(3-hydroxy-4-oxoniumylidenecyclohexa-2,5-dien-1-ylidene)methyl]benzenesulfonate Chemical compound C1=CC(=O)C(O)=C\C1=C(C=1C(=CC=CC=1)S(O)(=O)=O)/C1=CC=C(O)C(O)=C1 HGPSVOAVAYJEIJ-XDHOZWIPSA-N 0.000 claims description 2
- RTZZCYNQPHTPPL-UHFFFAOYSA-N 3-nitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1 RTZZCYNQPHTPPL-UHFFFAOYSA-N 0.000 claims description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- WCANPUKMWPPUNS-UHFFFAOYSA-N [N+](=O)([O-])C1=C(N(C)C)C(=CC(C1)([N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-] Chemical compound [N+](=O)([O-])C1=C(N(C)C)C(=CC(C1)([N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-] WCANPUKMWPPUNS-UHFFFAOYSA-N 0.000 claims description 2
- 229960004217 benzyl alcohol Drugs 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- UWHUTZOCTZJUKC-JKSUJKDBSA-N brazilin Chemical compound C12=CC(O)=C(O)C=C2C[C@]2(O)[C@H]1C1=CC=C(O)C=C1OC2 UWHUTZOCTZJUKC-JKSUJKDBSA-N 0.000 claims description 2
- UWHUTZOCTZJUKC-CVEARBPZSA-N brazilin Natural products C12=CC(O)=C(O)C=C2C[C@@]2(O)[C@@H]1C1=CC=C(O)C=C1OC2 UWHUTZOCTZJUKC-CVEARBPZSA-N 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 claims description 2
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- -1 nitro phenolphthalein Chemical compound 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 150000005189 1,3,5-trinitrobenzenes Chemical class 0.000 claims 1
- 241000233855 Orchidaceae Species 0.000 claims 1
- 235000015424 sodium Nutrition 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 239000007793 ph indicator Substances 0.000 abstract 1
- 239000002893 slag Substances 0.000 description 8
- 238000009736 wetting Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 241000283070 Equus zebra Species 0.000 description 1
- UATJOMSPNYCXIX-UHFFFAOYSA-N Trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UATJOMSPNYCXIX-UHFFFAOYSA-N 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- HAWFSFZXNWBZRU-UHFFFAOYSA-L disodium;2-[(4-oxidophenyl)-(4-oxocyclohexa-2,5-dien-1-ylidene)methyl]benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C(C=1C=CC([O-])=CC=1)=C1C=CC(=O)C=C1 HAWFSFZXNWBZRU-UHFFFAOYSA-L 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pens And Brushes (AREA)
Abstract
The ink for writing in board and capable of being hydrolyzed includes the following components: pH indicator, alkali, 1, 2-propylene glycol, glycerine, ethanol and deionized water and is prepared through dissolving and polymerization. It may be filled into thick board-writing pen for writing in teacher's board, office board, etc. and filled into thin pen for writing draught and writing projecting sheets. It has the features of high stability, fluent writing, no adhesion to pen tip, easy erasing with wet cloth and no dust pollution.
Description
The present invention relates to the writing on the blackboard material, the present invention relates to the free of contamination ink for writing on blackboard of hydrolyzable specifically.
For a long time, teaching board uses chalk, writing on the blackboard and dust from flying when erasing the board, pollution classroom.Japanese Patent (flat 1-19708), (clear 64-4552) disclose notes plate ink composition, (clear 62-9149) discloses notes plate marking ink, and all kinds of blank pen of domestic and international current trend, people have been familiar with such ink can write on plate face smooth, that do not absorb water, can wipe with blackboard eraser and do not have dust from flying, but such ink blank pen exists serious disadvantage: after wiping, can cause dirty plate by residual look slag on plate face and blackboard eraser; Open the cap for brush, nib is exposed in the air dry and hard easily; It depends on the smooth plate face that does not absorb water can wiping, and smooth plate is used for the school instruction plate then can be reflective, and the student does not see the font at reflective position.
The objective of the invention is to overcome the deficiency in the prior art products, avoid the limitation of chalk and blank pen, provide a kind of energy wet rubbing pollution-free non-dusting writing on the blackboard material for teaching board, office account, exercise plate.With wetting rag wiping, person's handwriting wink is that hydrolysis disappears the not residual look slag of plate face and rag after the writing on the blackboard; Nib is exposed to and is difficult for dry and hardly in the air, writes in optic panel and dull surface writing on the blackboard and all can wipe not dirty plate.
The present invention is achieved by following technical proposals.
The present invention has redness, orange, red-purple, purple, blue look, yellow, green and secondary color and secondary color, is with the hydrolysis ink for writing on blackboard writing on the blackboard pen of packing into during use, writes on clipboard.
The present invention includes following component (by weight percentage):
Make red hydrolysis ink for writing on blackboard:
Phenolphthalein or allusion quotation eosin or 2,4,6-trinitro--N-methyl N-methyl-p-nitroaniline 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
Make orange hydrolysis ink for writing on blackboard:
2 or 1,3,5 trinitrobenzene 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
System red-purple hydrolysis ink for writing on blackboard:
O-cresolphthalein or brazilin or four allusion quotation Phenolphthalein Sodium 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, glycerol 0.2%-8%, 1,2 propylene glycol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
System purple hydrolysis ink for writing on blackboard:
Phenolphthalein 0.5%-4% adds thymolphthalein 0.5%-4%, or tetrabromophenolphthalein or the blue 1%-8% of quinoline, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
Make blue look hydrolysis ink for writing on blackboard:
Thymolphthalein or p-Xylol phenolphthalein or two (1-naphthols) benzylalcohol or ethyl two (2, the 4-dimethyl benzene) acetic ester or two (2, the 4-dinitrophenyl) ethyl acetate 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
Make green hydrolysis ink for writing on blackboard:
The blue SA of alizarin or alphanaphthol phthalein or Pyrocatechol violet or 2,2 '-dihydroxy-benzene ketene 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
Manufacture-yellow look hydrolysis ink for writing on blackboard:
M-nitrophenol or nitro phenolphthalein or trinitrobenzoic acid or pyridine-2-aldehyde-2 '-pyridine hydrazone zinc or pyridine-2-aldehyde-2 '-pyridine hydrazone nickel or pyridine-2-aldehyde-2 '-pyridine hydrazone cadmium 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%.
With above-mentioned acid base indicator raw material more than two or three or can prepare the secondary color and the secondary color of above-mentioned look with the above-mentioned two or three above ink for preparing.
More than selected acid base indicator see structural formula respectively for details:
Provide embodiments of the invention, blending process below and its effect performance is made an appraisal.
Embodiment and performance evaluation thereof
| Consumption (gram) | |||||||||||||
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | ||
| Raw material | Phenolphthalein | 3.5 | 5 | 1.5 | 1.8 | 1.5 | |||||||
| O-cresolphthalein | 3.3 | 5 | 1 | ||||||||||
| 1,3, the 5-trinitrobenzene | 4 | ||||||||||||
| Tetrabromophenolphthalein | 3.5 | ||||||||||||
| Thymolphthalein | 1 | 1.8 | 2.5 | 3.6 | |||||||||
| Nitro phenolphthalein | 3 | ||||||||||||
| Alphanaphthol phthalein | 2.8 | ||||||||||||
| Sodium hydroxide | 1.4 | 2 | 1.4 | 3 | 1.5 | 1.6 | 2 | 1.5 | |||||
| Yellow soda ash | 1.5 | 1.4 | 1.5 | 1.4 | |||||||||
| 1,2 propylene glycol | 0.2 | 0.2 | 0.5 | 0.2 | 0.5 | 1 | 0.4 | 0.3 | 0.5 | 0.2 | 0.5 | 0.5 | |
| Glycerol | 0.2 | 0.3 | 1 | 0.2 | 1.5 | 2 | 1.2 | 0.5 | 1 | 0.5 | 0.5 | 1 | |
| Ethanol (content 95%) | 60 | 60 | 80 | 60 | 50 | 60 | 30 | 66 | 70 | 70 | 54.5 | 60 | |
| Deionized water | 34.7 | 32.5 | 13 | 34.9 | 40 | 32 | 63.5 | 28 | 22.5 | 24.2 | 40 | 34.3 | |
| Effect performance evaluation | Color | Red | Red | Orange | Purplish red | Purplish red | Purplish red | Purple | Purple | Purple | Yellow | Green | |
| Fluent writing | Excellent | Excellent | Very | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Very | Excellent | |
| Erasability | Excellent | Very | Very | Excellent | Very | Excellent | Very | Excellent | Very | Excellent | Excellent | Very | |
| Stability | Excellent | Excellent | Very | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | |
| The look slag is residual | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | |
| Nib is anti-to be done the time (h) | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | ＞24 | |
Blending process: at normal temperatures each component is dropped into the container polymerization successively, stirred 30 minutes, it is fully dissolved, leave standstill after 3 hours standby.
After ink made, in its writing on the blackboard pen of packing into, its color, fluent writing and erasability were observed in writing on the blackboard on light face and dull surface clipboard; With wetting rag wiping, observe its wiping effect, look slag residual condition; The writing on the blackboard pen is opened the cap for brush expose nib, under normal temperature laboratory, placed 24 hours, observe anti-time and the stability of ink done of nib.
Compare experiment with the blank pen
One. experiment purpose:
1. comparison colours slag residual condition
2. relatively open cap for brush nib and reveal the anti-dried time in the air of putting
3. relatively wipe away situation at optic panel, dull surface blackboard eraser
Two. material is prepared:
1. one in hydrolysis writing on the blackboard red ink writing on the blackboard pen (getting embodiment 1 ink)
2. one in Japanese zebra board redness (middle word) blank pen
3.600 * 800mm light face is write blank, dull surface is write each two of blanks
4. whiteboard eraser is one
5. one of wetting towel
Three. room temp: 20 ℃
Four. operation steps:
1. be 10 of 80 * 80mm Chinese characters with blank pen and hydrolysis ink writing on the blackboard pen writing on the blackboard specification on two light face clipboards and two dull surface clipboards respectively.
2. the word of writing with whiteboard eraser wiping blank pen; The word of writing with wetting towel wiping hydrolysis ink writing on the blackboard pen.Comparing result is as follows:
A. the light colourless plate that writes of blank pen and whiteboard eraser are all residual an ink look slag; Water
The wetting towel of separating light colourless plate that ink writing on the blackboard pen writes and Wiper plate face is equal
Do not find the look slag.
B. the dirty plate of the dull surface blank that writes of blank pen is serious, and hydrolysis ink writing on the blackboard pen is write
The dull surface blank of word does not have dirty plate phenomenon.
3. blank pen and hydrolysis ink writing on the blackboard pen are opened the cap for brush simultaneously, allow nib be placed in the air after 6 hours, use blank pen and the writing on the blackboard on clipboard of hydrolysis ink writing on the blackboard pen respectively.Comparing result is as follows: the dry and hard word of can not writing of blank pen nib; Hydrolysis ink writing on the blackboard pen still can normally be write.
Through the use of embodiment being observed and being shown with contrast experiment's report that the blank pen carries out: the present invention writes smoothness, steady quality; No matter on optic panel or dull surface plate, write, all can not stay stains with wetting rag wiped clean, not residual look slag; Open nib, the anti-dried time is longer, is fit to do school instruction writing on the blackboard apparatus.
Claims (3)
1. hydrolysis ink for writing on blackboard constituent, it is characterized in that: include following component (by weight percentage): phenolphthalein or allusion quotation eosin or 2,4,6-trinitro--N-methyl N-methyl-p-nitroaniline or 2,4,6-trotyl or 1,3,5 trinitrobenzenes or o-cresolphthalein or brazilin or four allusion quotation Phenolphthalein Sodiums or thymolphthalein or tetrabromophenolphthalein or quinoline orchid or p-Xylol phenolphthalein or two (1-naphthols) benzylalcohol or ethyl two (2, the 4-dimethyl benzene) acetic ester or two (2, the 4-dinitrophenyl) the blue SA of ethyl acetate or alizarin or alphanaphthol phthalein or Pyrocatechol violet or 2,2 '-dihydroxy-benzene ketene or m-nitrophenol or nitro phenolphthalein or trinitrobenzoic acid or pyridine-2-aldehyde-2 '-pyridine hydrazone zinc or pyridine-2-aldehyde-2 '-pyridine hydrazone nickel or pyridine-2-aldehyde-2 '-pyridine hydrazone cadmium 1%-8%, sodium hydroxide or potassium hydroxide or yellow soda ash or sodium bicarbonate or ammoniacal liquor (content 35%) 1%-8%, 1,2 propylene glycol 0.2%-8%, glycerol 0.2%-8%, ethanol (content 95%) 5%-95%, deionized water 5%-95%;
2. according to hydrolysis ink for writing on blackboard constituent according to claim 1, it is characterized in that: adopt above-mentioned two or three above acid base indicator to be made into their secondary color or secondary color in proportion;
3. hydrolysis ink for writing on blackboard constituent according to claim 1 is characterized in that: prepare their secondary color and secondary color in proportion with the two or three above hydrolysis ink for writing on blackboard for preparing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03114634 CN1186410C (en) | 2003-05-08 | 2003-05-08 | Hydrolytic blackboard-writing ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03114634 CN1186410C (en) | 2003-05-08 | 2003-05-08 | Hydrolytic blackboard-writing ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1448448A true CN1448448A (en) | 2003-10-15 |
| CN1186410C CN1186410C (en) | 2005-01-26 |
Family
ID=28684131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03114634 Expired - Fee Related CN1186410C (en) | 2003-05-08 | 2003-05-08 | Hydrolytic blackboard-writing ink composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1186410C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2938266A1 (en) * | 2008-11-12 | 2010-05-14 | Ermanno Bo | SELF-DEACTING INK BY AUTO EVAPORATION, USEABLE ON PAPER SUPPORT, BY MEANS OF A SPECIFIC PEN, BUT NOT EXCLUSIVELY. |
| CN101386725B (en) * | 2008-10-24 | 2010-06-02 | 山西大学 | Solid colorful writing pen |
| CN101503589B (en) * | 2009-03-03 | 2012-05-23 | 山西大学 | Erasable atroceruleous writing solution |
| CN102514424A (en) * | 2011-12-23 | 2012-06-27 | 江门市盈江科技有限公司 | Whiteboard eraser structure with integrated functions of chemical erasure and physical erasure |
| CN102837532A (en) * | 2012-09-17 | 2012-12-26 | 山西大学 | Writing board coated with surface-modified paint and writing liquid matched with writing board |
| CN103044174A (en) * | 2012-12-25 | 2013-04-17 | 山西大学 | Red smoke agent |
| CN103073955A (en) * | 2013-01-14 | 2013-05-01 | 山西大学 | Colored dust-free chalk capable of fading automatically and preparation method thereof |
| CN105295539A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Erasable ink for writing on whiteboard |
| CN105295529A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink for fiber-tip pen |
| CN105295526A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed and used for fiber pen |
| CN105295525A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Erasable ink for fiber-tip pen |
| CN105295520A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink for writing on whiteboard through fiber-tip pen |
| CN105295540A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed |
| CN105504985A (en) * | 2016-01-06 | 2016-04-20 | 山西大学 | Fadable calligraphy training ink and preparation method thereof |
| CN106433309A (en) * | 2016-12-14 | 2017-02-22 | 陈庭 | Erasable colorful hydrolysable ink capable of fading and disappearing and preparation method of erasable colorful hydrolysable ink |
| CN108047816A (en) * | 2018-02-02 | 2018-05-18 | 蔡云杰 | A kind of white board pen ink for meeting water bleeding |
-
2003
- 2003-05-08 CN CN 03114634 patent/CN1186410C/en not_active Expired - Fee Related
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386725B (en) * | 2008-10-24 | 2010-06-02 | 山西大学 | Solid colorful writing pen |
| WO2010055226A1 (en) * | 2008-11-12 | 2010-05-20 | Ermanno Bo | Ink that erases itself by self-evaporation and can be used on a paper medium by means of a specific writing implement |
| FR2938266A1 (en) * | 2008-11-12 | 2010-05-14 | Ermanno Bo | SELF-DEACTING INK BY AUTO EVAPORATION, USEABLE ON PAPER SUPPORT, BY MEANS OF A SPECIFIC PEN, BUT NOT EXCLUSIVELY. |
| CN101503589B (en) * | 2009-03-03 | 2012-05-23 | 山西大学 | Erasable atroceruleous writing solution |
| CN102514424A (en) * | 2011-12-23 | 2012-06-27 | 江门市盈江科技有限公司 | Whiteboard eraser structure with integrated functions of chemical erasure and physical erasure |
| CN102837532A (en) * | 2012-09-17 | 2012-12-26 | 山西大学 | Writing board coated with surface-modified paint and writing liquid matched with writing board |
| CN102837532B (en) * | 2012-09-17 | 2015-03-04 | 山西大学 | Writing board coated with surface-modified paint and writing liquid matched with writing board |
| CN103044174B (en) * | 2012-12-25 | 2018-09-14 | 山西大学 | A kind of red smoke agent |
| CN103044174A (en) * | 2012-12-25 | 2013-04-17 | 山西大学 | Red smoke agent |
| CN103073955A (en) * | 2013-01-14 | 2013-05-01 | 山西大学 | Colored dust-free chalk capable of fading automatically and preparation method thereof |
| CN103073955B (en) * | 2013-01-14 | 2014-10-22 | 山西大学 | Colored dust-free chalk capable of fading automatically and preparation method thereof |
| CN105295539A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Erasable ink for writing on whiteboard |
| CN105295526A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed and used for fiber pen |
| CN105295525A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Erasable ink for fiber-tip pen |
| CN105295520A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink for writing on whiteboard through fiber-tip pen |
| CN105295540A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed |
| CN105295529A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink for fiber-tip pen |
| CN105504985A (en) * | 2016-01-06 | 2016-04-20 | 山西大学 | Fadable calligraphy training ink and preparation method thereof |
| CN106433309A (en) * | 2016-12-14 | 2017-02-22 | 陈庭 | Erasable colorful hydrolysable ink capable of fading and disappearing and preparation method of erasable colorful hydrolysable ink |
| CN108047816A (en) * | 2018-02-02 | 2018-05-18 | 蔡云杰 | A kind of white board pen ink for meeting water bleeding |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1186410C (en) | 2005-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1186410C (en) | Hydrolytic blackboard-writing ink composition | |
| CN101386725B (en) | Solid colorful writing pen | |
| CN101845251B (en) | Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof | |
| CN102925006B (en) | Ink and preparation method thereof | |
| CN107573760A (en) | One kind is raised one's hat humidity-preserving type white board pen ink | |
| CN102417763B (en) | Preparation method of easily-erasable liquid teaching writing ink and color paste used therein | |
| CN101412866A (en) | Neutral fading ink refill | |
| CN100580039C (en) | Dry-wiping white board marker ink | |
| CN102816475B (en) | Alcohol soluble white board marker ink easy to dry-erase and preparation method thereof | |
| CN113773702B (en) | Writing chalk and preparation method thereof | |
| CN110643256A (en) | Water-based environment-friendly wall paint capable of being repeatedly written with water and preparation method thereof | |
| CN108047816A (en) | A kind of white board pen ink for meeting water bleeding | |
| CN1129722A (en) | Writing liquid for teaching board | |
| DE3873372T2 (en) | INK COMPOSITION AND PRINT-SENSITIVE COPY MATERIAL. | |
| CN102558967A (en) | White board writing ink | |
| CN110819162A (en) | Easily-cleaned white board pen ink and preparation method thereof | |
| KR100875265B1 (en) | Nontoxic ink compositions and process for producing same | |
| EP0148615B1 (en) | Inks for transparency films | |
| CN115710443B (en) | Degradable liquid chalk and preparation method thereof | |
| CN1594463A (en) | Light catalyzed oxidation reduction degradation decolorization writing ink used for blackboard and degradation promoter thereof | |
| CN1138647C (en) | Blackboard writing pen and its making process | |
| CN1594464A (en) | Light degradable children's painting writing ink | |
| JP7359678B2 (en) | Marking ink composition for writing boards | |
| KR20010068200A (en) | Method of making ink for blue blackboard | |
| CN1456609A (en) | Graphite ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Fan Yuanhua Document name: Patent specification |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Fan Yuanhua Document name: payment instructions |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Fan Yuanhua Document name: payment instructions |
|
| DD01 | Delivery of document by public notice |
Addressee: Fan Yuanhua Document name: Notification that Application Deemed not to be Proposed |
|
| ASS | Succession or assignment of patent right |
Owner name: JIANGMEN YINGJIANG TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: FAN YUANHUA Effective date: 20111221 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 541001 GUILIN, GUANGXI ZHUANG AUTONOMOUS REGION TO: 529000 JIANGMEN, GUANGDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20111221 Address after: 529000, No. 12, Bei Bei Road, Pengjiang District, Guangdong, Jiangmen Patentee after: Jiangmen Yingjiang Technology Co., Ltd. Address before: 541001 No. 922, the Guangxi Zhuang Autonomous Region, Guilin, Zhongshan North Road Patentee before: Fan Yuanhua |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050126 Termination date: 20210508 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |