CN1445277A - 一种低表面能的尼龙(pa66)复合物及其制备方法 - Google Patents
一种低表面能的尼龙(pa66)复合物及其制备方法 Download PDFInfo
- Publication number
- CN1445277A CN1445277A CN 03114188 CN03114188A CN1445277A CN 1445277 A CN1445277 A CN 1445277A CN 03114188 CN03114188 CN 03114188 CN 03114188 A CN03114188 A CN 03114188A CN 1445277 A CN1445277 A CN 1445277A
- Authority
- CN
- China
- Prior art keywords
- mixture
- nylon
- surface energy
- low surface
- brominated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 5
- 239000004677 Nylon Substances 0.000 title abstract description 7
- 229920001778 nylon Polymers 0.000 title abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 239000002131 composite material Substances 0.000 claims abstract description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 9
- 239000012757 flame retardant agent Substances 0.000 claims description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical group N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 6
- 239000012745 toughening agent Substances 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 230000004927 fusion Effects 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- DGZQEAKNZXNTNL-UHFFFAOYSA-N 1-bromo-4-butan-2-ylbenzene Chemical class CCC(C)C1=CC=C(Br)C=C1 DGZQEAKNZXNTNL-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000006224 matting agent Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 6
- 229920006351 engineering plastic Polymers 0.000 abstract description 5
- 230000003213 activating effect Effects 0.000 abstract 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003340 retarding agent Substances 0.000 abstract 1
- 238000003466 welding Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 6
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004568 cement Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000075 oxide glass Substances 0.000 description 2
- -1 perfluoro Chemical group 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1组分名称 | 尼龙66 | 全氟壬氧基苯磺酸钠 | 十溴联苯醚 | 三氧化二锑 | 玻璃纤维 |
重量份数 | 47.5 | 0.5 | 15.5 | 6.5 | 30 |
实施例2组分名称 | 尼龙66 | 全氟十六烷基苯甲酸钾 | 溴化环氧树脂 | 三氧化二锑 | 玻璃纤维 |
重量份数 | 45.5 | 0.5 | 17 | 7 | 30 |
项目 | 测试方法 | 单位 | 指标 | |
实施例1 | 实施例2 | |||
拉伸强度 | GB1040 | MPa | 155 | 145 |
弯曲强度 | GB9341 | MPa | 225 | 210 |
弯曲模量 | GB9341 | MPa | 9500 | 9200 |
缺口冲击强度 | GB1843 | KJ/m2 | 10.5 | 8.8 |
热变形温度 | GB1634 | ℃ | 250 | 252 |
阻燃性能 | UL94 | 0.8mm | V-0 | V-0 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03114188 CN1215120C (zh) | 2003-04-10 | 2003-04-10 | 一种低表面能的尼龙(pa66)复合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03114188 CN1215120C (zh) | 2003-04-10 | 2003-04-10 | 一种低表面能的尼龙(pa66)复合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1445277A true CN1445277A (zh) | 2003-10-01 |
CN1215120C CN1215120C (zh) | 2005-08-17 |
Family
ID=27814780
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03114188 Expired - Lifetime CN1215120C (zh) | 2003-04-10 | 2003-04-10 | 一种低表面能的尼龙(pa66)复合物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1215120C (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103665858A (zh) * | 2013-11-18 | 2014-03-26 | 安徽宜万丰电器有限公司 | 一种汽车塑料件用珍珠岩粉改性尼龙66材料 |
CN103911003A (zh) * | 2014-04-02 | 2014-07-09 | 合肥杰事杰新材料股份有限公司 | 一种低表面能聚酰胺66工程塑料及其制备方法 |
CN104629355A (zh) * | 2013-11-08 | 2015-05-20 | 上海杰事杰新材料(集团)股份有限公司 | 一种阻燃增强半芳香族尼龙/液晶聚合物复合材料及其制备方法 |
CN106589931A (zh) * | 2016-11-16 | 2017-04-26 | 马鞍山市华能电力线路器材有限责任公司 | 一种高韧性电力金具用阻燃尼龙复合材料及其制作方法 |
WO2022057210A1 (zh) * | 2020-09-21 | 2022-03-24 | 金发科技股份有限公司 | 一种具有ntc效应的聚酰胺组合物及其制备方法 |
-
2003
- 2003-04-10 CN CN 03114188 patent/CN1215120C/zh not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104629355A (zh) * | 2013-11-08 | 2015-05-20 | 上海杰事杰新材料(集团)股份有限公司 | 一种阻燃增强半芳香族尼龙/液晶聚合物复合材料及其制备方法 |
CN103665858A (zh) * | 2013-11-18 | 2014-03-26 | 安徽宜万丰电器有限公司 | 一种汽车塑料件用珍珠岩粉改性尼龙66材料 |
CN103911003A (zh) * | 2014-04-02 | 2014-07-09 | 合肥杰事杰新材料股份有限公司 | 一种低表面能聚酰胺66工程塑料及其制备方法 |
CN106589931A (zh) * | 2016-11-16 | 2017-04-26 | 马鞍山市华能电力线路器材有限责任公司 | 一种高韧性电力金具用阻燃尼龙复合材料及其制作方法 |
WO2022057210A1 (zh) * | 2020-09-21 | 2022-03-24 | 金发科技股份有限公司 | 一种具有ntc效应的聚酰胺组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1215120C (zh) | 2005-08-17 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI JINFA TECHNOLOGY DEVELOPMENT CO., LTD. Effective date: 20050826 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20050826 Address after: 510520 Guangdong city of Guangzhou province Tianhe District Ke Mu Lang Gaotang Industrial Zone Co-patentee after: SHANGHAI KINGFA SCI.,&TECH. Co.,Ltd. Patentee after: Guangzhou Kingfa Science and Technology Co.,Ltd. Address before: 510520 Guangdong city of Guangzhou province Tianhe District Ke Mu Lang Gaotang Industrial Zone Patentee before: Guangzhou Kingfa Science and Technology Co.,Ltd. |
|
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: Ke Feng Lu Science City high tech Industrial Development Zone of Guangzhou City, Guangdong Province, No. 33 zip code: 510663 Co-patentee after: SHANGHAI KINGFA SCI.,&TECH. Co.,Ltd. Patentee after: KINGFA SCI. & TECH. Co.,Ltd. Address before: Guangdong city of Guangzhou province Tianhe District postcode: 510520 Ke Mu Lang Gaotang Industrial Zone Co-patentee before: SHANGHAI KINGFA SCI.,&TECH. Co.,Ltd. Patentee before: Guangzhou Kingfa Science and Technology Co.,Ltd. |
|
C56 | Change in the name or address of the patentee |
Owner name: JINFA SCIENCE CO., LTD. Free format text: FORMER NAME: GUANGZHOU JINFA SCIENCE + TECHNOLOGY CO. LTD. |
|
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: ZHUHAI WANGO CHEMICAL Co.,Ltd. Assignor: KINGFA SCI. & TECH. Co.,Ltd.|SHANGHAI KINGFA SCI.,&TECH. Co.,Ltd. Contract record no.: 2011440000002 Denomination of invention: Nylon(PA66) complex with low surface energy and its preparing method Granted publication date: 20050817 License type: Exclusive License Open date: 20031001 Record date: 20110104 |
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CX01 | Expiry of patent term |
Granted publication date: 20050817 |
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CX01 | Expiry of patent term |