CN1439683A - Novel high-molecular waterproof coating for roof - Google Patents
Novel high-molecular waterproof coating for roof Download PDFInfo
- Publication number
- CN1439683A CN1439683A CN 03106524 CN03106524A CN1439683A CN 1439683 A CN1439683 A CN 1439683A CN 03106524 CN03106524 CN 03106524 CN 03106524 A CN03106524 A CN 03106524A CN 1439683 A CN1439683 A CN 1439683A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- water
- waterproof
- resistance
- organic silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title abstract description 8
- 239000011248 coating agent Substances 0.000 title abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003973 paint Substances 0.000 claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 9
- 239000004814 polyurethane Substances 0.000 claims description 9
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 8
- 239000011118 polyvinyl acetate Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 239000010456 wollastonite Substances 0.000 claims description 7
- 229910052882 wollastonite Inorganic materials 0.000 claims description 7
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 3
- 238000004581 coalescence Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 7
- 229920002521 macromolecule Polymers 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 240000002853 Nelumbo nucifera Species 0.000 abstract description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 abstract description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract 3
- 230000007547 defect Effects 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000003487 anti-permeability effect Effects 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 230000007812 deficiency Effects 0.000 abstract 1
- 230000009965 odorless effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention is prepared by taking acrylic emulsion, organic silicon emulsion and the like as main film forming substances, taking water as a solvent and adding other auxiliary agents. Because of using several kinds of macromolecule latex emulsion, overcome the limitation that a kind of macromolecule latex emulsion exists, they can make up for the deficiency each other, bring out the best in each other. It uses water as solvent, and is non-toxic, odorless and free from environmental pollution; because the organic silicon emulsion is used, the coating has very good hydrophobicity after being dried, and water drops on the surface of the coating are just like water drops on lotus leaves; it has unique waterproof performance, ultraviolet irradiation resistance and ageing resistance; the waterproof paint avoids the defects of poor waterproof effect, poor aging resistance and the like of a single high-molecular emulsion waterproof paint; it can be made into various colors according to the needs, and overcomes the defect of single color of other waterproof coatings; the adhesive has high bonding strength, good waterproof and anti-permeability effects, heat resistance, frost resistance and good extensibility; it is cold constructed, directly coated and simply operated. It is suitable for various buildings, such as new and old roofs, basements, toilets and other buildings, and has the functions of water prevention, seepage prevention and moisture prevention.
Description
Technical field
The invention belongs to the coating class in the chemical industry.Just be to use the waterproof paint on building roofing specifically.
Background technology
At present, the roofing waterproof paint kind of China is more single.Wherein main products has, and a class is a urethane, and its quality is better, but price is higher.Just present, most urethane still use dimethylbenzene to make solvent, and it is poisonous, influences operator's health, serious environment pollution.Although it is no-solvent polyurethane finds out in China, few in application on the market; Another kind of is Crumber rubber modified asphalt.Its cost is lower, and is second-rate.Be easy to catch fire when producing this product, potential safety hazard is very big; Also having a class is ACRYLIC EMULSION.It is solvent with water, and nontoxic, quality is better, and moderate cost is rising.But, the present water-proof acrylic acid paint of selling on the market, tensile strength is less, and resistance to low temperature is bad, and weathering resistance is poor.Special for this reason the present invention---the novel high polymer roofing waterproof paint that proposes.
Summary of the invention
The novel high polymer roofing waterproof paint belongs to the modification acrylate class.It is a main film forming substance with pure acrylic acid ester emulsion, organic silicon emulsion, aqueous polyurethane emulsion and ethene-aqueous polyvinyl acetate emulsion, is solvent with water, is filler with sericite in powder etc., adds other auxiliary agent and is prepared from.The present invention has overcome the existing limitation of simple a kind of macromolecule emulsion owing to used several macromolecule emulsions, and they can cover the shortage mutually, bring out the best in each other.It is solvent with water, nonpoisonous and tasteless non-environmental-pollution; Owing to used organic silicon emulsion, have extraordinary hydrophobic nature behind the dried coating film, the globule is the globule on lotus leaf in its surface; It has unique water resistance, and the UV resistant irradiation is anti-aging; It has avoided simple a kind of macromolecule emulsion waterproofing paint waterproof effect bad, shortcomings such as loss of properties on aging; It can make shades of colour as required, has overcome the single shortcoming of other waterproof paint color; Its bonding strength is big, and water proof anti-seepage is effective, and is heat-resisting freeze proof, good extending performance; Its cold construction, directly brushing is easy and simple to handle.It is applicable to the new old roof of various buildingss, waterproof, antiseepage, the protection against the tide of all kinds of buildings such as vault, toilet, grain depot, water conservancy dykes and dams, oil depot, pipeline, swimming pool, tunnel, construction joint, expansion joint, road and bridge.
The prescription of novel high polymer roofing waterproof paint is as follows:
The material name massfraction
Pure acrylic acid ester emulsion 0.1-0.3
Aqueous polyurethane emulsion 0.1-0.2
Organic silicon emulsion 0.2-0.3
Ethene-aqueous polyvinyl acetate emulsion 0.1-0.3
Sericite in powder 0.2-0.3
Wollastonite powder 0.1-0.3
Titanium dioxide (rutile-type) 0.1-0.2
Sodium hexametaphosphate 99 (dispersion agent) 0.01-0.05
Ethylene glycol (film coalescence aid) 0.01-0.03
Dibutyl phthalate (softening agent) 0.01-0.03
Sodium pentachlorophenate (sanitas) 0.001-0.005
Silicone antifoam agent 0.01-0.02
Water 0.6-0.01
Above-mentioned all components sum equals 100%.
Technological process:
Water intaking adds dispersion agent, stirs.Add sericite in powder, wollastonite powder, titanium dioxide stirs, and grinds three times with three roller shredders.Add pure acrylic acid ester emulsion, aqueous polyurethane emulsion, organic silicon emulsion, ethene-aqueous polyvinyl acetate emulsion, film coalescence aid, softening agent, sanitas stirs, and adds defoamer, stirs, and promptly gets product of the present invention.
Embodiment
Embodiment one
Prescription:
The material name massfraction
Pure acrylic acid ester emulsion 0.1
Aqueous polyurethane emulsion
Organic silicon emulsion 0.2
Ethene-aqueous polyvinyl acetate emulsion 0.1
Sericite in powder 0.2
Wollastonite powder 0.1
Titanium dioxide (rutile-type) 0.1
Sodium hexametaphosphate 99 0.01
Ethylene glycol 0.01
Dibutyl phthalate 0.01
Sodium pentachlorophenate 0.001
Silicone antifoam agent 0.01
Water surplus
Technological process:
Water intaking adds Sodium hexametaphosphate 99, stirs, and adds sericite in powder, wollastonite powder, titanium dioxide stirs, mill is three times on three roller shredders, adds pure acrylic acid ester emulsion, aqueous polyurethane emulsion, organic silicon emulsion, ethene-aqueous polyvinyl acetate emulsion, ethylene glycol, dibutyl phthalate, sodium pentachlorophenate stirs, add silicone antifoam agent, stir, promptly get product of the present invention.
Embodiment two
Prescription:
The material name massfraction
Pure acrylic acid ester emulsion 0.2
Aqueous polyurethane emulsion 0.1
Organic silicon emulsion 0.2
Ethene-aqueous polyvinyl acetate emulsion 0.1
Sericite in powder 0.2
Wollastonite powder 0.1
Titanium dioxide (rutile-type) 0.1
Sodium hexametaphosphate 99 0.01
Ethylene glycol 0.01
Dibutyl phthalate 0.01
Sodium pentachlorophenate 0.001
Silicone antifoam agent 0.01
Water surplus
Technological process:
Water intaking adds Sodium hexametaphosphate 99, stirs, and adds sericite in powder, wollastonite powder, titanium dioxide stirs, mill is three times on three roller shredders, adds pure acrylic acid ester emulsion, aqueous polyurethane emulsion, organic silicon emulsion, ethene-aqueous polyvinyl acetate emulsion, ethylene glycol, dibutyl phthalate, sodium pentachlorophenate stirs, add silicone antifoam agent, stir and promptly get product of the present invention.
Reference:
CN 93119512 castor oil water-proof paint for roof and manufacture method thereof
CN 92107129 waterproof coating of high molecular polymer
The manufacture method of CN 86106496 modified water-proof coating of polystyrene
Claims (1)
1. novel high polymer roofing waterproof paint is characterized in that the massfraction that raw material is formed is:
The material name massfraction
Pure acrylic acid ester emulsion 0.1-0.3
Aqueous polyurethane emulsion 0.1-0.2
Organic silicon emulsion 0.2-0.3
Ethene-aqueous polyvinyl acetate emulsion 0.1-0.3
Sericite in powder 0.2-0.3
Wollastonite powder 0.1-0.3
Titanium dioxide (rutile-type) 0.1-0.2
Sodium hexametaphosphate 99 (dispersion agent) 0.01-0.05
Ethylene glycol (film coalescence aid) 0.01-0.03
Dibutyl phthalate (softening agent) 0.01-0.03
Sodium pentachlorophenate (sanitas) 0.001-0.005
Silicone antifoam agent 0.01-0.02
Water 0.6-0.01
Above-mentioned all components sum equals 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03106524 CN1439683A (en) | 2003-02-26 | 2003-02-26 | Novel high-molecular waterproof coating for roof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03106524 CN1439683A (en) | 2003-02-26 | 2003-02-26 | Novel high-molecular waterproof coating for roof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1439683A true CN1439683A (en) | 2003-09-03 |
Family
ID=27796639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03106524 Pending CN1439683A (en) | 2003-02-26 | 2003-02-26 | Novel high-molecular waterproof coating for roof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1439683A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100363447C (en) * | 2005-03-24 | 2008-01-23 | 郑州大学 | Modified water-proof acrylic acid paint |
| CN100384954C (en) * | 2004-06-18 | 2008-04-30 | 周仁杰 | Water-proof acrylic acid latex |
| CN103468118A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | White environment-friendly waterproof coating |
| CN104004425A (en) * | 2014-06-05 | 2014-08-27 | 隋庆宇 | Acrylic acid waterborne polyurethane waterproofing coatings and manufacturing technology thereof |
| CN104250494A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Water-based seal primer for penetrative building wall surface |
| CN104479467A (en) * | 2014-12-25 | 2015-04-01 | 上海奇想青晨新材料科技股份有限公司 | Water-based non-breathable water-resistant paint and preparation method thereof |
| CN104946041A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | Ageing-resistant coating for exterior walls |
| CN104946054A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | High-strength water-resistance coating for exterior walls |
| CN106085186A (en) * | 2016-08-22 | 2016-11-09 | 安徽宇瑞环保建设有限公司 | A kind of environment-friendly waterproof paint |
| CN108300016A (en) * | 2017-09-30 | 2018-07-20 | 江苏亿可得电子科技有限公司 | A kind of television set method of producing waterproof coating material |
| CN109930705A (en) * | 2019-03-23 | 2019-06-25 | 朱卫兵 | A kind of fabricated construction improving intensity and waterproofness at node |
| US10865567B2 (en) | 2018-07-11 | 2020-12-15 | Owens Coming Intellectual Capital, LLC | Shingles with increased hydrophobicity |
| US11933048B2 (en) | 2014-02-21 | 2024-03-19 | Owens Corning Intellectual Capital, Llc | Shingles with increased hydrophobicity |
| US12065835B2 (en) | 2019-12-03 | 2024-08-20 | Owens Corning Intellectual Capital, Llc | Roofing materials including a layer of a parting agent |
-
2003
- 2003-02-26 CN CN 03106524 patent/CN1439683A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100384954C (en) * | 2004-06-18 | 2008-04-30 | 周仁杰 | Water-proof acrylic acid latex |
| CN100363447C (en) * | 2005-03-24 | 2008-01-23 | 郑州大学 | Modified water-proof acrylic acid paint |
| CN103468118A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | White environment-friendly waterproof coating |
| CN103468118B (en) * | 2013-08-16 | 2016-06-01 | 安徽快来防水防腐有限公司 | A kind of White environment-friendlywaterproof waterproof paint |
| US11933048B2 (en) | 2014-02-21 | 2024-03-19 | Owens Corning Intellectual Capital, Llc | Shingles with increased hydrophobicity |
| CN104004425A (en) * | 2014-06-05 | 2014-08-27 | 隋庆宇 | Acrylic acid waterborne polyurethane waterproofing coatings and manufacturing technology thereof |
| CN104250494A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Water-based seal primer for penetrative building wall surface |
| CN104479467A (en) * | 2014-12-25 | 2015-04-01 | 上海奇想青晨新材料科技股份有限公司 | Water-based non-breathable water-resistant paint and preparation method thereof |
| CN104946041A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | Ageing-resistant coating for exterior walls |
| CN104946054A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | High-strength water-resistance coating for exterior walls |
| CN106085186A (en) * | 2016-08-22 | 2016-11-09 | 安徽宇瑞环保建设有限公司 | A kind of environment-friendly waterproof paint |
| CN108300016A (en) * | 2017-09-30 | 2018-07-20 | 江苏亿可得电子科技有限公司 | A kind of television set method of producing waterproof coating material |
| US10865567B2 (en) | 2018-07-11 | 2020-12-15 | Owens Coming Intellectual Capital, LLC | Shingles with increased hydrophobicity |
| US10865565B2 (en) | 2018-07-11 | 2020-12-15 | Owens Coming Intellectual Capital, LLC | Shingles with increased hydrophobicity |
| US10865566B2 (en) | 2018-07-11 | 2020-12-15 | Owens Coming Intellectual Capital, LLC | Shingles with increased hydrophobicity |
| US11359377B2 (en) | 2018-07-11 | 2022-06-14 | Owens Corning Intellectual Capital, Llc | Shingles with increased hydrophobicity |
| US11629496B2 (en) | 2018-07-11 | 2023-04-18 | Owens Corning Intellectual Capital, Llc | Shingles with increased hydrophobicity |
| CN109930705B (en) * | 2019-03-23 | 2021-03-19 | 朱卫兵 | Assembly type structure for improving node strength and waterproofness |
| CN109930705A (en) * | 2019-03-23 | 2019-06-25 | 朱卫兵 | A kind of fabricated construction improving intensity and waterproofness at node |
| US12065835B2 (en) | 2019-12-03 | 2024-08-20 | Owens Corning Intellectual Capital, Llc | Roofing materials including a layer of a parting agent |
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