CN1436830A - Waterproof and antiseepage organosilicon fluid - Google Patents
Waterproof and antiseepage organosilicon fluid Download PDFInfo
- Publication number
- CN1436830A CN1436830A CN 02113337 CN02113337A CN1436830A CN 1436830 A CN1436830 A CN 1436830A CN 02113337 CN02113337 CN 02113337 CN 02113337 A CN02113337 A CN 02113337A CN 1436830 A CN1436830 A CN 1436830A
- Authority
- CN
- China
- Prior art keywords
- waterproof
- antiseepage
- liquid
- raw material
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 8
- 229920000053 polysorbate 80 Polymers 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 6
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 3
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The waterproof and antiseepage organosilicon fluid is prepared by mixing the following materials: basic matter polymer D4 or DMC fluid 30-80 weight portions, liquid crosslinking agent 10-50 weight portions, liquid cure agent 1-10 weight portions and liquid stabilizer 0-3 weight portions. It may permeate into painted matter to seal capillary holes and has long waterproof life.
Description
Technical field:
The present invention is relevant with construction waterproof coating.
Technical background:
Existing water-proof impervious organosilicon paint (Chinese patent publication number: CN1245191A) form by organosilicon, emulsifying agent, linking agent, membrane-forming agent, additive, auxiliary agent.Its preparation method is that organosilicon 25%-40% is added auxiliary agent ethylene glycol 1-3%, under the normal temperature crosslinked 50-60 minute, after modification finishes, add benzene-acrylic emulsion 6-10% and film coalescence aid phenylcarbinol 2-4%, mix and stirred 10-20 minute, add building glue 107 glue then, asbestos powder, talcum powder, perlite powder are mixed and form, and add light calcium carbonate successively, and Sodium Silicofluoride, terra alba, white cement are mixed, stir, filter and promptly get waterproof paint.During use it is coated in body surface, solidifies the back and form waterproof membrane on the surface.Because the intermolecular of this film has cross-link bond to have its water extension rate and impervious pressure height.But after being positioned at the film destroy on surface, still can produce seepage.
The content of invention:
The purpose of this invention is to provide a kind of coated article body inside of infiltrating, the waterproof and antiseepage organosilicon fluid of after the curing waterproof life-span pore waterproof sealing, that do not influence the base material ventilation property being grown.
The present invention is achieved in that
Waterproof and antiseepage organosilicon fluid of the present invention is mixed and made into by following proportion raw material: weight part
A. basic thing: D
4Or DMC liquid, 30-80
B. linking agent liquid 10-50
C. solidifying agent liquid 1-10
D. stablizer liquid 0-3.
The said A component of the present invention basis thing is made by following proportion raw material: weight part
1, D
4Octamethylcyclotetrasiloxane 10-40
2, emulsifying agent:
Cetyl trimethylammonium bromide 0.5-15
Dodecyl dimethyl benzyl ammonium bromide 0.5-15
Peregal 0 0.01-15
Tween-80 0.01-15
Catalyzer 0.1-15
Water 60-88
The raw material of said ratio is mixed except that catalyzer, and stirring heating heats up 60 °-90 ℃ the time, adds catalyzer, and clock reaction 6-12 hour, reduce to room temperature, add the acetic acid neutrality that neutralizes, promptly get the basic thing of liquid A component,
B component of the present invention is made by following proportion raw material: weight part
Methylhydrogenpolysi,oxane
Or Union carbide A-162
Or tetraethoxy or metatitanic acid
Butyl ester or methylhydrogenpolysi,oxane
Or some kinds of cooperations 150 in the above-mentioned raw materials
Tween-80 3.75
OP-10 3.75
Deionized water 343
Above-mentioned substance is made stable emulsion, and pH4-6 forms through acidifying,
C component of the present invention is made by following proportion raw material: weight part
Dibutyltin diacetate 25/6
Dibutyl tin laurate 25/6 * 5
Tween-80 3.75
Peregal 0 0.375
Deionized water 74.5
Above-mentioned raw materials is made stable emulsion
D component of the present invention is for to be dissolved in the solution of making in 98 parts of water by 2 parts of stablizers.
Advantage of the present invention is as follows:
1, permeate in the invisible molecular film of the inner formation of base material, be difficult for destroyed.
2, the weather resisteant with organosilyl excellence, long service life.
3, the siloxane molecule film of generation has low surface tension, waterproof infiltration but can not damage the ventilation property of base material.
4, colourless, nontoxic, tasteless, easy to use safe and reliable, can keep the true qualities of original building material.
Embodiment:
Embodiment 1:
1, produce A component basis thing:
Use D
4Octamethylcyclotetrasiloxane 125 weight parts, add each 5.75 parts of emulsifying agent cetyl trimethylammonium bromide, dodecyl dimethyl benzyl ammonium bromides, each 0.75 part of peregal 0, tween-80,361 parts of deionized waters stir and heat up, be controlled at 75 ℃, add 0.9 part of catalyst n aOH, clock reaction 9 hours is reduced to room temperature, with arriving neutral, standby with gained A component basis thing (liquid) in the acetic acid.
3, produce B component linking agent:
Methylhydrogenpolysi,oxane 150 weight parts, tween-80, each 3.75 weight part of OP-10, deionized water 343 weight parts are made stable emulsion through colloidal mill or refiner shearing, through acidifying pH4-6.
3, produce the C component:
Dibutyltin diacetate: dibutyl tin laurate=1: 5, totally 25 parts, tween-80, respectively 0.375 part of peregal 0,74.5 parts of deionized waters are made stable emulsion through colloidal mill or homogenate machine.
4, the preparation of D component
Select carboxymethyl to tie up 2 parts of plain sodium salt or sodium hydroxyethyl cellulose salt or polyvinyl alcohol, 98 parts in water is made solution promptly.
A, B, C, D component fluids are promptly got the present invention according to following proportioning mixing: weight part
A, basic thing liquid 70
B, linking agent liquid 22
C, solidifying agent liquid 6
D, stablizer liquid 2.
Claims (5)
1, waterproof and antiseepage organosilicon fluid is mixed and made into by following proportion raw material: weight part
A. basic thing is D
4Or the polymkeric substance 30-80 of DMC
B. linking agent liquid 10-50
C. solidifying agent liquid 1-10
D. stablizer liquid 0-3.
A, B, C, D liquid mixed
2, waterproof and antiseepage organosilicon fluid according to claim 1 is characterized in that said A component basis thing made by following proportion raw material: weight part
1, D
4Octamethylcyclotetrasiloxane or DMC 10-40
2, emulsifying agent:
Cetyl trimethylammonium bromide 0.5-15
Dodecyl dimethyl benzyl ammonium bromide 0.5-15
Peregal 0 0.01-15
Tween-80 0.01-15
Catalyzer 0.1-15
Water 60-88
The raw material of said ratio is mixed except that catalyzer, and stirring heating when being warmed up to 60-90 ℃, adds catalyzer, and clock reaction 6-12 hour, reduce to room temperature, add the acetic acid neutrality that neutralizes, promptly get the basic thing of liquid A component,
3, waterproof and antiseepage organosilicon fluid according to claim 1 is characterized in that said B component made by following proportion raw material: weight part
Methylhydrogenpolysi,oxane
Or Union carbide A-162
Or tetraethoxy or metatitanic acid
Butyl ester or methylhydrogenpolysi,oxane
Or some kinds of cooperations 150 in the above-mentioned raw materials
Tween-80 3.75
OP-10 3.75
Deionized water 343
Above-mentioned substance is made stable emulsion, and pH4-6 forms through acidifying,
4, waterproof and antiseepage organosilicon fluid according to claim 1 is characterized in that said C component made by following proportion raw material: weight part
Dibutyltin diacetate 25/6
Dibutyl tin laurate 25/6 * 5
Tween-80 0.375
Peregal 0 0.375
Deionized water 74.5
Above-mentioned raw materials is made stable emulsion
5, waterproof and antiseepage organosilicon fluid according to claim 1 is characterized in that said D component is for to be dissolved in the solution of making in 98 parts of water by 2 parts of stablizers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02113337 CN1239668C (en) | 2002-02-07 | 2002-02-07 | Waterproof and antiseepage organosilicon fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02113337 CN1239668C (en) | 2002-02-07 | 2002-02-07 | Waterproof and antiseepage organosilicon fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1436830A true CN1436830A (en) | 2003-08-20 |
| CN1239668C CN1239668C (en) | 2006-02-01 |
Family
ID=27628410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02113337 Expired - Fee Related CN1239668C (en) | 2002-02-07 | 2002-02-07 | Waterproof and antiseepage organosilicon fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1239668C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104891943A (en) * | 2015-05-21 | 2015-09-09 | 安徽鑫润新型材料有限公司 | Composite magnesium oxide board with excellent water-resistant and moisture-resistant effects and preparation method thereof |
-
2002
- 2002-02-07 CN CN 02113337 patent/CN1239668C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104891943A (en) * | 2015-05-21 | 2015-09-09 | 安徽鑫润新型材料有限公司 | Composite magnesium oxide board with excellent water-resistant and moisture-resistant effects and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1239668C (en) | 2006-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| ASS | Succession or assignment of patent right |
Owner name: SICHUAN XINGCHEN TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SICHUAN XINGCHEN ENTERPRISE CO. Effective date: 20030813 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20030813 Applicant after: Sichuan Xingchen Enterprise Co. Applicant before: Sichuan Xingchen Enterprise Co. |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060201 Termination date: 20170207 |