CN1425798A - Activation solution for aluminium alloy before chemical nickel plating - Google Patents
Activation solution for aluminium alloy before chemical nickel plating Download PDFInfo
- Publication number
- CN1425798A CN1425798A CN 02145571 CN02145571A CN1425798A CN 1425798 A CN1425798 A CN 1425798A CN 02145571 CN02145571 CN 02145571 CN 02145571 A CN02145571 A CN 02145571A CN 1425798 A CN1425798 A CN 1425798A
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- CN
- China
- Prior art keywords
- solution
- activated
- tartaric acid
- nickel plating
- acid potassium
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Abstract
Of the aluminum alloy activating solution, each liter contains zinc oxide 10-50 g, sodium hydroxide 100-300g, nickel sulfate 20-50 g, ferric trichloride 2-5 g and potassium-sodium tartrate 20-50 g. It is used int reating aluminium alloy before nickel plating at 30-50 deg.c for 20-200 sec. The treatment can lower the potential difference between the activated layer and the plated layer, raise the activity of the aluminum alloy surface, reduce the pollution to plating liquid, raise the binding force and protecting function of the plated layer, increase the service life of chemical nickel plating solution and reduce chemical nickel plating cost.
Description
Technical field
The present invention relates to the activated solution of the preceding aluminium alloy of chemical nickel plating.
Background technology
Processing before traditional aluminium alloy plating is to carry out double zincate process, because the potential difference between zinc and the nickel-phosphorus alloy coating is bigger, influences the bonding force and the protective of coating.
Summary of the invention
It is little to the purpose of this invention is to provide a kind of pollution, the activated solution that life cycle is long.
The technical scheme that realizes the object of the invention for the weight that each rises contained material in the activated solution is:
Zinc oxide 10-50g
Sodium hydroxide 100-300g
Single nickel salt 20-50g
Iron trichloride 2-5g
When Tartaric acid potassium sodium 20-50g used activated solution, temperature was controlled at 30-50 ℃, and soak time is 20-200s
The configuration of solution
The sodium hydroxide that scale is good dissolves with pure water earlier, then zinc oxide is added wherein, and the limit edged stirs; Dissolve iron trichloride, single nickel salt, Tartaric acid potassium sodium respectively with pure water again, iron trichloride, nickel sulfate solution are added respectively in the Tartaric acid potassium sodium solution; At last mixed Tartaric acid potassium sodium solution is added in sodium hydroxide and the zinc oxide mixing solutions, after careful the filtration, can use.
Adopt this solution that aluminium alloy is handled, reduced the potential difference of active layer and coating, improved the activity of aluminum alloy surface, and reduced pollution to plating bath, and improved the bonding force and the protective of coating, prolonged 0.5-1 cycle of chemical nickel-plating solution working life, in one liter of plating bath, cost-saved 4 yuan, 2 yuan of create beneficial results, 30,000 yuan of year create beneficial results (calculating) to consume 5000 liters of plating baths year.
Embodiment
Embodiment 1
Prepare 1 liter of activation solution: earlier the 220g sodium hydroxide that takes by weighing is dissolved with an amount of pure water, then the 30g zinc oxide that takes by weighing is added wherein, the limit edged stirs, and makes the zinc oxide dissolving fully; Dissolve iron trichloride 3g, single nickel salt 30g, Tartaric acid potassium sodium 50g respectively with an amount of 50~60 ℃ of pure water again, iron trichloride, nickel sulfate solution are added respectively in the Tartaric acid potassium sodium solution; At last mixed Tartaric acid potassium sodium solution is added in sodium hydroxide and the zinc oxide mixing solutions, can use after careful the filtration, during use, temperature is controlled at 38 ℃, and soak time is 80s
Embodiment 2
Prepare 200 liters of activation solutions: earlier the 44kg sodium hydroxide that takes by weighing is dissolved with an amount of pure water, then the 6kg zinc oxide that takes by weighing is added wherein, the limit edged stirs, and makes the zinc oxide dissolving fully; Dissolve iron trichloride 0.6kg, single nickel salt 6kg, Tartaric acid potassium sodium 10kg respectively with an amount of 50~60 ℃ of pure water again, iron trichloride, nickel sulfate solution are added respectively in the Tartaric acid potassium sodium solution; At last mixed Tartaric acid potassium sodium solution is added in sodium hydroxide and the zinc oxide mixing solutions, can use after careful the filtration, during use, temperature is controlled at 45 ℃, and soak time is 120s
Claims (4)
- The activated solution of aluminium alloy before 1 chemical nickel plating is characterized in that each weight that rises contained material in the activated solution is:Zinc oxide 10-50gSodium hydroxide 100-300gSingle nickel salt 20-50gIron trichloride 2-5gTartaric acid potassium sodium 20-50g
- 2 activated solutions as claimed in claim 1, when it is characterized in that using activated solution, temperature is controlled at 30-50 ℃
- 3 activated solutions as claimed in claim 1 is characterized in that soak time is 20-200s
- 4 activated solutions as claimed in claim 1, when it is characterized in that disposing solution, the sodium hydroxide that scale is good dissolves with pure water earlier, then zinc oxide is added wherein, and the limit edged stirs; Dissolve iron trichloride, single nickel salt, Tartaric acid potassium sodium respectively with pure water again, iron trichloride, nickel sulfate solution are added respectively in the Tartaric acid potassium sodium solution; At last mixed Tartaric acid potassium sodium solution is added in sodium hydroxide and the zinc oxide mixing solutions, after careful the filtration, can use.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02145571 CN1425798A (en) | 2002-12-31 | 2002-12-31 | Activation solution for aluminium alloy before chemical nickel plating |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02145571 CN1425798A (en) | 2002-12-31 | 2002-12-31 | Activation solution for aluminium alloy before chemical nickel plating |
Publications (1)
Publication Number | Publication Date |
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CN1425798A true CN1425798A (en) | 2003-06-25 |
Family
ID=4750939
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 02145571 Pending CN1425798A (en) | 2002-12-31 | 2002-12-31 | Activation solution for aluminium alloy before chemical nickel plating |
Country Status (1)
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CN (1) | CN1425798A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102199763A (en) * | 2011-04-01 | 2011-09-28 | 广东工业大学 | Preparation method for electroless plating activator capable of screen printing, and activating treatment process using same |
CN102234795A (en) * | 2011-06-02 | 2011-11-09 | 杭州震达五金机械有限公司 | Zinc-based polynary alloy sedimentation liquid for processing bimetallic composite wire rod |
CN103668198A (en) * | 2012-09-01 | 2014-03-26 | 无锡新大中薄板有限公司 | Three-element zinc-nickel iron soaking technique of aluminum alloy plate |
CN103668192A (en) * | 2012-09-01 | 2014-03-26 | 无锡新大中薄板有限公司 | Four-element zinc-tin-nickel-iron soaking technique of aluminum alloy plate |
CN104032343A (en) * | 2014-05-14 | 2014-09-10 | 蚌埠富源电子科技有限责任公司 | Novel electroplating pre-treatment technology for titanium and titanium alloy |
CN115555232A (en) * | 2022-10-11 | 2023-01-03 | 浙江旗创新材料科技有限公司 | Preparation method of leakage-free high-resistance anticorrosive coating |
-
2002
- 2002-12-31 CN CN 02145571 patent/CN1425798A/en active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102199763A (en) * | 2011-04-01 | 2011-09-28 | 广东工业大学 | Preparation method for electroless plating activator capable of screen printing, and activating treatment process using same |
CN102199763B (en) * | 2011-04-01 | 2012-09-05 | 广东工业大学 | Preparation method for electroless plating activator capable of screen printing, and activating treatment process using same |
CN102234795A (en) * | 2011-06-02 | 2011-11-09 | 杭州震达五金机械有限公司 | Zinc-based polynary alloy sedimentation liquid for processing bimetallic composite wire rod |
CN102234795B (en) * | 2011-06-02 | 2016-09-07 | 杭州震达五金机械有限公司 | Zinc-based multi-element alloy deposition liquid for bimetallic composite wire rod processing |
CN103668198A (en) * | 2012-09-01 | 2014-03-26 | 无锡新大中薄板有限公司 | Three-element zinc-nickel iron soaking technique of aluminum alloy plate |
CN103668192A (en) * | 2012-09-01 | 2014-03-26 | 无锡新大中薄板有限公司 | Four-element zinc-tin-nickel-iron soaking technique of aluminum alloy plate |
CN104032343A (en) * | 2014-05-14 | 2014-09-10 | 蚌埠富源电子科技有限责任公司 | Novel electroplating pre-treatment technology for titanium and titanium alloy |
CN115555232A (en) * | 2022-10-11 | 2023-01-03 | 浙江旗创新材料科技有限公司 | Preparation method of leakage-free high-resistance anticorrosive coating |
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