CN1425728A - Environment protection transfer coating and its use - Google Patents
Environment protection transfer coating and its use Download PDFInfo
- Publication number
- CN1425728A CN1425728A CN 01131625 CN01131625A CN1425728A CN 1425728 A CN1425728 A CN 1425728A CN 01131625 CN01131625 CN 01131625 CN 01131625 A CN01131625 A CN 01131625A CN 1425728 A CN1425728 A CN 1425728A
- Authority
- CN
- China
- Prior art keywords
- water
- resin
- water soluble
- environment protection
- transfer coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000004744 fabric Substances 0.000 claims abstract description 9
- 239000010985 leather Substances 0.000 claims abstract description 9
- -1 amino acid ester Chemical class 0.000 claims abstract description 7
- 229920003180 amino resin Polymers 0.000 claims abstract description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 7
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 3
- 239000000123 paper Substances 0.000 claims description 16
- 239000010408 film Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000003086 colorant Substances 0.000 claims description 9
- 239000005030 aluminium foil Substances 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000011087 paperboard Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000008399 tap water Substances 0.000 claims description 4
- 235000020679 tap water Nutrition 0.000 claims description 4
- 239000012770 industrial material Substances 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- QMYDVDBERNLWKB-UHFFFAOYSA-N propane-1,2-diol;hydrate Chemical compound O.CC(O)CO QMYDVDBERNLWKB-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000004411 aluminium Substances 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000012461 cellulose resin Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920006233 biaxially oriented polyamide Polymers 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The transfer coating consists of water soluble amino resin, water soluble amino acid ester resin, water soluble vinyl resin, water soluble acrylic resin or cellulose resin 1-20 portions, pigment 1-10 portions, cosolvent 1-30 portions and water 30-80 portions, and is prepared through synthesis, moistening and dispersion. It is suitable for painting to carrier film; and the carrier film may be aluminium plated before being combined with paper, paper card, fabric, leather and other material. The present invention has the features of raised environment protecting performance, simplified production process, low production cost and stable product quality.
Description
Technical field: the present invention relates to a kind of transfer coatings and uses thereof, particularly a kind of environmental protection water-soluble transfer coating material and uses thereof.
Background technology: the transfer composite aluminium foil paper environmentally friendly packing material of external invention of early 1980s is because it has environmental protection; energy-conservation; the economic dispatch high-performance; day by day replaced the fine aluminium foil paper; plastics aluminium plating film composite aluminium foil paper; domestic also obtaining in recent years promoted; though existing transfer composite aluminium foil paper has above-mentioned advantage; but it is solvent type that the transfer coatings that uses in its production technique is still; go back the residual harmful thing in its coating; its production process drying and volatilizing thing also pollutes environment; its transfer coatings system is combined into by release material and protective layer (colorant) coating secondary coating process, and technology is more relatively.
Summary of the invention: the object of the present invention is to provide that a kind of to adopt water be solvent, that be used for transfer composite aluminium foil paper coating and only need once coating can finish environment-friendly type transfer coatings of coating process and uses thereof.The objective of the invention is to be achieved through the following technical solutions: it is made by the following weight proportion raw material, water soluble amino resin 1-20 part, or water-soluble amino-acid ester resin 1-20 part, or water soluble vinyl resin 1-20 part, or water-soluble acrylic fat resin 1-30 part, or celluosic resin 1-20 part, or its arbitrary combination, auxiliary agent 1-10 part, solubility promoter 1-30 part, water 30-80 part is made aqueous transfer coating through synthetic, wetting dispersion, allotment.Its optimum weight proportioning is: water soluble amino resin 1-10 part, or water-soluble amino-acid ester resin 1-10 part, or water soluble vinyl resin 1-5 part, or water-soluble acrylic fat resin 1-30 part, or celluosic resin 1-10 part, or its arbitrary combination, auxiliary agent 5-10 part, colorant 1-10 part, solubility promoter 1-30 part, deionized water or tap water 30-70 part.Auxiliary agent can adopt linking agent or salt forming agent, wetting dispersing agent, coupling agent etc., and colorant can adopt dyestuff or pigment, and solubility promoter can adopt alcoholic solvent to comprise that Virahol, propylene glycol monomethyl ether etc., water are deionized water or cleaning tap water.The purposes of described environment protection transfer coating is applicable to once coats carrier thin film, in vacuum aluminum-coated machine, aluminize behind the dry crosslinking curing, thereafter with all kinds of paper, paperboard, fabric, base materials such as leather carry out compound, after the complex body drying, carrier thin film is stripped down from complex body, carrier film can turn back to front first procedure and continue repeated multiple times as carrier film, last complex body is transfer composite aluminium foil paper after the carrier film strip off, be compound in paper or paperboard and promptly can be used as environmentally friendly packing material, be compound in fabric or leather and then can be used as other industrial material.It is solvent that transfer coatings of the present invention has adopted with water; compliance with environmental protection requirements more; in coating process, taked to comprise release coating and protective layer (colorant) coating is the integrated technique method; making original transfer coated process modification that needs secondary to be coated with is the technology that release material and protection layer for paint are once finished coating simultaneously, and further improves the printability of finished product.
Embodiment:
Embodiment 1, press column weight amount proportioning and extract raw material: water soluble amino resin 1-20 part, water-soluble amino-acid ester resin 8-12 part, water soluble vinyl resin 8-12 part, water-soluble acrylic fat resin 26-30 part, celluosic resin 8-12 part, auxiliary agent 8-10 part, colorant 8-10 part, solubility promoter 26-30 part, water 30-80 part is made aqueous transfer coating through synthetic, wetting dispersion, allotment, and it is applicable to that the transfer of base materials such as paper, paperboard, fabric, leather is compound.
Embodiment 2, press column weight amount proportioning and extract raw material: 10 parts of water soluble amino resins, 10 parts of water-soluble amino-acid ester resins, 5 parts of water soluble vinyl resins, 30 parts of water-soluble acrylic fat resins, 10 parts of celluosic resins, 10 parts of auxiliary agents, 10 parts in colorant, 30 parts of solubility promoters, water 30-80 part is made aqueous transfer coating through synthetic, wetting dispersion, allotment, and it is applicable to that the transfer of base materials such as paper, paperboard, fabric, leather is compound.
Embodiment 3, the transfer coatings that embodiment 1 and embodiment 2 are made is used for once coating carrier thin film, as PET, the surface of BOPP and BOPA etc., through (80-120 ℃) drying of heating, after the crosslinking curing film forming, in vacuum aluminum-coated machine, aluminize, thereafter with all kinds of paper, paperboard, fabric, base materials such as leather carry out compound, after the complex body drying, carrier thin film is stripped down from complex body, carrier film can turn back to front first procedure and continue repeated multiple times as carrier film, last complex body is transfer composite aluminium foil paper after the carrier film strip off, it is strong that it has the metal sense, the glossiness height, with the aluminium coated strong adhesion, surface abrasion resistance and to republish performance good is with printing ink bonding force height, the ink setting of printing is fast, is applicable to offset printing, gravure, flexo, all kinds of typographies such as wire mark and protruding seal.It is compound in paper or paperboard promptly can be used as environmentally friendly packing material, is compound in fabric or leather and then can be used as other industrial material.
In sum; it is solvent that transfer coatings of the present invention has adopted with water; compliance with environmental protection requirements more; in coating process, taked to comprise release coating and protective layer (colorant) coating is the integrated technique method, made that original transfer coated to need the process modification of secondary coating be the technology that release material and protection layer for paint are once finished coating simultaneously.It is except that the suitability with solvent based coating, and its drying process is that the vaporization of aqueous solvent can not cause the infringement to environment with the crosslinking curing film forming.After the coating drying, can not retain nuisance in the coating, dried coating conforms with the food sanitation requirement, is the novel environment-friendly type transfer coatings of a class.It has more environmental-protecting performance, lower cost, simpler technology, more stable performance and quality, has improved functions such as wear resistance, solvent resistance and printability.
Claims (4)
1, a kind of environment protection transfer coating, it is characterized in that: it is made by the following weight proportion raw material, water soluble amino resin 1-20 part, or water-soluble amino-acid ester resin 1-20 part, or water soluble vinyl resin 1-20 part, or water-soluble acrylic fat resin 1-30 part, or celluosic resin 1-20 part, or its arbitrary combination, auxiliary agent 1-10 part, solubility promoter 1-30 part, water 30-80 part is modulated into aqueous transfer coating through synthetic, wetting dispersion.
2, according to the described environment protection transfer coating of claim 1, it is characterized in that: it is made by the following weight proportion raw material, water soluble amino resin 1-10 part, or water-soluble amino-acid ester resin 1-10 part, or water soluble vinyl resin 1-5 part, or water-soluble acrylic fat resin 1-30 part, or celluosic resin 1-10 part, or its arbitrary combination, auxiliary agent 5-10 part, colorant 1-10 part, solubility promoter 1-30 part, deionized water or tap water 30-70 part.
3, according to the described environment protection transfer coating of claim 1, it is characterized in that: auxiliary agent can adopt linking agent or salt forming agent, wetting dispersing agent, coupling agent, colorant can adopt dyestuff or pigment, solubility promoter can adopt alcoholic solvent to comprise Virahol, propylene glycol monomethyl ether, and water is deionized water or cleaning tap water.
4, according to claim 1, or 2, or the purposes of 3 described environment protection transfer coatings, it is characterized in that: be applicable to and once coat carrier thin film, in vacuum aluminum-coated machine, aluminize behind the dry crosslinking curing, thereafter with all kinds of paper, paperboard, fabric, base materials such as leather carry out compound, after the complex body drying, carrier thin film is stripped down from complex body, carrier film can turn back to front first procedure and continue repeated multiple times as carrier film, last complex body is transfer composite aluminium foil paper after the carrier film strip off, be compound in paper or paperboard and promptly can be used as environmentally friendly packing material, be compound in fabric or leather and then can be used as other industrial material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01131625XA CN1293157C (en) | 2001-12-17 | 2001-12-17 | Environment protection transfer coating and its use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01131625XA CN1293157C (en) | 2001-12-17 | 2001-12-17 | Environment protection transfer coating and its use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1425728A true CN1425728A (en) | 2003-06-25 |
| CN1293157C CN1293157C (en) | 2007-01-03 |
Family
ID=4670741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB01131625XA Expired - Fee Related CN1293157C (en) | 2001-12-17 | 2001-12-17 | Environment protection transfer coating and its use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1293157C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999640B (en) * | 2006-12-19 | 2010-06-23 | 乳源瑶族自治县阳之光亲水箔有限公司 | Non-solvent type aluminum foil coating for air conditioner |
| CN101260274B (en) * | 2007-12-21 | 2010-10-20 | 华东理工大学华昌聚合物有限公司 | Technique for preparing two-component epoxy vinyl ester resin paint |
| CN101408015B (en) * | 2008-11-14 | 2010-10-27 | 上海维凯化学品有限公司 | Combination type full dummy brightness transferring aluminum-plating paper coating and preparing method thereof |
| CN101519556B (en) * | 2009-03-24 | 2011-04-06 | 汕头市龙湖昌丰化工有限公司 | Water-washable ink used in a packaging film local aluminum plating process and preparation method thereof |
| CN101619186B (en) * | 2009-08-07 | 2011-07-27 | 西安大天科技股份有限公司 | Solvent matte transfer aluminium-plating coating and preparation method thereof |
| CN101407656B (en) * | 2008-11-14 | 2011-08-17 | 上海维凯化学品有限公司 | Environment-friendly type moldable aqueous transfer coating, preparation and use thereof |
| CN102260443A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Water-diluted acrylate resin coating and preparation method thereof |
| CN101451040B (en) * | 2008-12-26 | 2012-12-12 | 广州擎天实业有限公司 | Reworking agent of ultraviolet cured paint |
| CN101905622B (en) * | 2009-06-02 | 2013-02-06 | 陈武 | Decorative coating transfer film |
| CN102993895A (en) * | 2012-10-16 | 2013-03-27 | 益阳祥瑞科技有限公司 | Water-soluble amino paint |
| CN104497749A (en) * | 2015-01-11 | 2015-04-08 | 湖北绿新环保包装科技有限公司 | Transfer paint producing no regenerated benzene after UV (ultraviolet) printing and preparation method thereof |
| CN112920698A (en) * | 2021-04-08 | 2021-06-08 | 广东邦固化学科技有限公司 | Printable water-based transfer coating and preparation method thereof |
| CN115505285A (en) * | 2022-05-19 | 2022-12-23 | 东莞市科迪实业有限公司 | Easy-to-clean wear-resistant synthetic leather and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049391A (en) * | 1989-08-07 | 1991-02-20 | 朱柏海 | A kind of method of making metal film-plating paper |
| CN1032865C (en) * | 1991-05-16 | 1996-09-25 | 苏州造漆厂 | Process for preparing water-soluble amino acrylic baking paint |
| CN1083504A (en) * | 1993-09-10 | 1994-03-09 | 王衡新 | Mutually intersecting network polymer multi-colour water-coluble figure paint |
| CN1109488A (en) * | 1994-11-29 | 1995-10-04 | 蔡晋才 | Water cement lacquer and its preparing method |
| CN1061670C (en) * | 1997-05-21 | 2001-02-07 | 褚炎明 | Namometre automotive metal finish |
-
2001
- 2001-12-17 CN CNB01131625XA patent/CN1293157C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999640B (en) * | 2006-12-19 | 2010-06-23 | 乳源瑶族自治县阳之光亲水箔有限公司 | Non-solvent type aluminum foil coating for air conditioner |
| CN101260274B (en) * | 2007-12-21 | 2010-10-20 | 华东理工大学华昌聚合物有限公司 | Technique for preparing two-component epoxy vinyl ester resin paint |
| CN101408015B (en) * | 2008-11-14 | 2010-10-27 | 上海维凯化学品有限公司 | Combination type full dummy brightness transferring aluminum-plating paper coating and preparing method thereof |
| CN101407656B (en) * | 2008-11-14 | 2011-08-17 | 上海维凯化学品有限公司 | Environment-friendly type moldable aqueous transfer coating, preparation and use thereof |
| CN101451040B (en) * | 2008-12-26 | 2012-12-12 | 广州擎天实业有限公司 | Reworking agent of ultraviolet cured paint |
| CN101519556B (en) * | 2009-03-24 | 2011-04-06 | 汕头市龙湖昌丰化工有限公司 | Water-washable ink used in a packaging film local aluminum plating process and preparation method thereof |
| CN101905622B (en) * | 2009-06-02 | 2013-02-06 | 陈武 | Decorative coating transfer film |
| CN101619186B (en) * | 2009-08-07 | 2011-07-27 | 西安大天科技股份有限公司 | Solvent matte transfer aluminium-plating coating and preparation method thereof |
| CN102260443A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Water-diluted acrylate resin coating and preparation method thereof |
| CN102260443B (en) * | 2011-02-17 | 2014-06-04 | 湖南晟通科技集团有限公司 | Water-diluted acrylate resin coating and preparation method thereof |
| CN102993895A (en) * | 2012-10-16 | 2013-03-27 | 益阳祥瑞科技有限公司 | Water-soluble amino paint |
| CN104497749A (en) * | 2015-01-11 | 2015-04-08 | 湖北绿新环保包装科技有限公司 | Transfer paint producing no regenerated benzene after UV (ultraviolet) printing and preparation method thereof |
| CN112920698A (en) * | 2021-04-08 | 2021-06-08 | 广东邦固化学科技有限公司 | Printable water-based transfer coating and preparation method thereof |
| CN115505285A (en) * | 2022-05-19 | 2022-12-23 | 东莞市科迪实业有限公司 | Easy-to-clean wear-resistant synthetic leather and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1293157C (en) | 2007-01-03 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
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| C14 | Grant of patent or utility model | ||
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| ASS | Succession or assignment of patent right |
Owner name: ZHEJIANG PROV HENGFENG PACKING CO., LTD. Free format text: FORMER OWNER: ZHANG XUEYI Effective date: 20090515 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090515 Address after: No. 1688, Jiashan Avenue, Jiashan County, Zhejiang Province Patentee after: ZHEJIANG HENGFENG PACKING CO., LTD. Address before: Hunan Xiangtan Yuhu Shaoshan West Road Xiangtan plastic first factory Patentee before: Zhang Xueyi |
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Granted publication date: 20070103 Termination date: 20121217 |