CN1423549A - Personal care articles comprising a hydrophilic conditioning agent exhibiting a defined leaching value - Google Patents

Abstract

The present invention relates to a substantially dry, disposable personal care article comprising: a) a water insoluble substrate comprising a nonwoven layer; and a therapeutic benefit component, disposed adjacent to said water insoluble substrate, wherein said component comprises from about 10 % to about 1000 %, by weight of the water insoluble substrate, of a therapeutic benefit composition comprising a hydrophilic conditioning agent wherein the agent exhibits a Leaching Value of less than about 25 % at 1 minute and less than about 50 % at 5 minutes when the article is exposed to water. These articles have been found to be particularly useful for personal cleansing applications, namely for the skin and hair. Thus, the present invention further relates to methods of cleansing and/or therapeutically treating (e.g., conditioning) skin and hair utilizing the articles of the present invention.

Description

The personal-care supplies that comprise hydrophilic conditioning agent with definite leaching value

Technical field

The disposable personal care articles for use that the present invention relates to be applicable to cleaning and/or therapeutic treatment skin, hair and need any other position of this processing.These articles for use contain the water-insoluble substrate that comprises nonwoven layers and with the useful component of treatment (therapeuticbenefit component) of the adjacent setting of described water-insoluble substrate (disposed), wherein said component comprises the treatment advantageous compositions that accounts for the about 10%-of water-insoluble substrate weight about 1000%, said composition comprises hydrophilic conditioning agent, wherein when these articles for use contact with water, this conditioner showed the leaching value (LeachingValue) less than about 25% in the time of 1 minute, showed the leaching value less than about 50% in the time of 5 minutes.

Consumer uses articles for use of the present invention by following manner: water is this articles for use moistening, and with the zone of this articles for use wiping desire cleaning and/or therapeutic treatment (for example conditioning).

The invention still further relates to and use product of the present invention to clean and/or the method for conditioning skin and hair.

Background of invention

The personal care product, particularly cleaning and conditioning products with the form of multiple multi-form for example soap slab, cream, emulsion and gel, are sold on market.These products generally attempt to satisfy a plurality of standards for consumer accepted.These standards comprise cleaning effectiveness, skin use feeling, to skin, hair and eye mucosa gentleness and foam volume.Ideal personal cleanser is cleaning skin or hair leniently, causes very little or does not cause any stimulation, and when frequent the use, is not taken on skin or the hair excessive accumulation or makes skin or the hair overdrying.

Also wish very much to obtain from cleaning and conditioning beneficial effect that the disposable products acquisition is such.Disposable products are very convenient, because they do not need to carry or store the packing cleaning product or other can provide treatment or bottle, bar, jar, pipe and other mixed and disorderly packaged form of the heaviness of the product of the beneficial effect of improving looks.Carrying out a large amount of reusable sponges, towel or other cleaning appliance with plan compares, disposable products are also much cleaner, because foreign odor and other negative characteristics be grown, be brought to these sponges, towel or other cleaning appliance can breed bacteria owing to be repeatedly used.

Articles for use of the present invention provide effective cleaning and/or treatment beneficial effect for skin and hair in the mode of convenient, cheap and health astoundingly.Convenience provided by the invention is, for cleaning agent and/or treat useful articles for use, need not to carry, store or use independent apparatus (for example towel or sponge).These articles for use are easy to use, because they are unitary type disposable personal care articles for use or the compound disposable products that are used for cleaning and administering therapeutic or beauty treatment beneficial agent (aesthetic benefit agent).In addition, these articles for use are suitable for using in being designed for more widely used other appliance for personal care or uniting use with such apparatus.In this case, articles for use of the present invention are to place the independent appliance for personal care that is not easy to handle for example in bath towel or the towel or attached on such apparatus.In addition, disposable product of the present invention can be in removable mode attached on handle or the handle, and such handle or handle are suitable for articles for use are moved on the surface of desire cleaning and/or therapeutic treatment (for example conditioning).

Though in preferred embodiments; articles for use of the present invention are suitable for personal care applications; but they also can be used for multiple other industry; for example automobile maintenance, boats and ships maintenance, maintenance at home, animal maintenances etc., these surfaces or zone need cleaning and/or use benefit materials for example wax, conditioner, uv-protector etc.

In the preferred embodiment of the invention, articles for use are suitable for personal care applications, and can be used for cleaning and/or the similar keratinous surfaces of conditioning skin, hair and this processing of needs.Consumer uses these articles for use by water with its moistening and with their wipings desire treatment surface.Articles for use of the present invention are made of water-insoluble substrate and the useful component of treatment.Be not bound by theory, the nonwoven layers that it is believed that substrate has improved cleaning especially and has stripped off effect, and optimization be included in sending and deposition of treatment in the articles for use or beauty treatment benefit materials.

Summary of the invention

The present invention relates to dried basically disposable personal care articles for use, these articles for use comprise:

A) comprise nonwoven layers water-insoluble substrate and

B) with the useful component of treatment of the adjacent setting of described water-insoluble substrate, wherein said component comprises the treatment advantageous compositions that accounts for the about 10%-of water-insoluble substrate weight about 1000%, said composition comprises hydrophilic conditioning agent, wherein when described articles for use contact with water, this conditioner showed the leaching value less than about 25% in the time of 1 minute, showed the leaching value less than about 50% in the time of 5 minutes.

The invention still further relates to the method for a kind of cleaning and/or conditioning skin and hair, this method may further comprise the steps: a) with these articles for use of water-wet, with b) articles for use of this moistening are contacted with hair with skin.

Except as otherwise noted, otherwise all percentage ratios and ratio all be by weight, and all are measured all 25 ℃ of mensuration.The present invention can comprise basic and optional ingredients and component described herein, is perhaps formed or is made up of them basically by them.

Multiple different embodiment and/or independent feature are disclosed in description of the present invention.Be clear that very that for those skilled in the art all these embodiments and combination of features all are possible, and can constitute the preferred embodiments of the invention.

The All Files that this paper quoted comprises that patent, patent application and printing promulgation thing all introduces the present invention with for referencial use in full.

Detailed Description Of The Invention

" disposable " used herein uses with its conventional sense, and is meant the use through limited number of times, preferably is lower than 25 times, more preferably less than about 10 times, most preferably is lower than the articles for use of disposing or abandoning after about 2 complete uses.

" doing basically " used herein is meant that the moisture-holding capacity of articles for use of the present invention is lower than about 0.95gms, preferably be lower than about 0.75gms, more preferably less than about 0.5gms, even more preferably less than about 0.25gms, also, most preferably be lower than about 0.1gms more preferably less than about 0.15gms.The mensuration of moisture-holding capacity will be described below.

Personal-care supplies of the present invention comprise following solvent.

Water-insoluble substrate

Articles for use of the present invention comprise water-insoluble substrate, and described substrate comprises at least a nonwoven layers or laminate.Nonwoven layers preferably is non-scrubbing character.The attrition value that " (non-scouring) of non-scrubbing character " used herein is meant the nonwoven layers of measuring according to following attrition value algoscopy is greater than about 15, be preferably greater than about 30, more preferably greater than about 50, even more preferably greater than about 70, most preferably greater than about 80.Hypothallus is preferably soft, and in use, and the skin of consumer is had health-care effect.

Be not bound by theory, water-insoluble substrate can promote cleaning and/or therapeutic treatment.The every side of substrate has identical or different matter structure, and the matter structure of the extracting side of articles for use and skin/position contact side is identical or different like this.Substrate can play effective foaming and strip off apparatus.By contact auxiliary significantly skin and other spall that cleans and remove dirt, cosmetics, death of substrate with skin or hair physics.Yet in preferred embodiments, substrate is non-scrubbing character or non-abrasiveness for skin.

The material that is applicable to nonwoven layers is selected from cellulose non-woven fleece, sponge (being natural and synthetic sponge), formed film (formed film), bat (batting) and their combination.This layer preferably comprises and is selected from following material: the laminated material that cellulose non-woven fleece, formed film, fluffy bat, foamed materials, sponge, reticulated foam, vacuum form, lax fabric (scrim), polymerization net and their combination.Preferred situation is, nonwoven layers comprises and is selected from following material: cellulose non-woven fleece, non-fluffy non-woven fleece, formed film, fluffy bat and their combination." nonwoven " used herein is meant that this layer do not comprise the fiber that is made into fabric, but this layer also need not to comprise fiber, as formed film, sponge, foam, lax fabric etc., when nonwoven layers comprises fiber, this fiber can be at random (be random alignment) or can be by (being a basic direction promptly) of combing by combing.In addition, nonwoven layers can be by other layer, at random the composite that combines with combing fiber type layer, i.e. multilamellar.

In one embodiment, the nonwoven layers of substrate comprises bat.Nonwoven layers is preferably fluffy, non-scrubbing character, and has a low-density." fluffy " used herein is meant that the density of this layer is about 0.00005g/cm ³-Yue 0.1g/cm ³, be preferably about 0.001g/cm ³-Yue 0.09g/cm ³, and at 5gms/in ²The time thickness be about 0.04 inch-Yue 2 inches.The nonwoven layers that comprises bat preferably comprises synthetic material." synthesizing " used herein is meant that material mainly is to be obtained by various artificial materials or the natural material that further changed.Appropriate synthetic materials includes but not limited to acetate fiber, acrylic fiber, cellulose ester fiber, modacrylic fibers, Fypro, polyester fiber, polyolefine fiber, vinal, staple fibre, polyethylene foam material, polyurethane foamed material and their combination.Preferred synthetic material, particularly fiber can be selected from nylon fiber, staple fibre, polyolefine fiber, polyester fiber and their combination.Preferred polyolefine fiber is to be selected from following fiber: polyethylene, polypropylene, polybutene, polypenthylene and their combination and copolymer.Preferred polyolefine fiber is to be selected from following fiber: polyethylene, polypropylene and their combination and copolymer.The preferred polyester fiber is to be selected from following fiber: polyethylene terephthalate, polybutylene terephthalate (PBT), poly terephthalic acid cyclohexanedimethanol ester and their combination and copolymer.Preferred polyester fiber is to be selected from following fiber: polyethylene terephthalate, polybutylene terephthalate (PBT) and their combination and copolymer.Most preferred synthetic fibers comprise the solid short polyester fiber that contains polyethylene terephthalate homopolymer.Appropriate synthetic materials can comprise that solid one-component (being chemical homogeneity) fiber, multi-constituent fibre (multiconstituent fibers) (material that is more than one constitutes every kind of fiber) and multicomponent fibre (multicomponent fibers) (are synthetic fibers, comprise two or more different filament types, these long filaments mat in some way form big fiber) and their combination.Preferred fiber comprises bi-component, multi-constituent fibre and combination thereof.Two component fibres like this can have core/sheath geometry or configuration side by side.In either case, nonwoven layers can comprise the fiber that contains above-mentioned material or itself contain the combination of the fiber of above-mentioned material combination.

For sheath core fiber, the nuclear core comprises and is selected from following material: its T _gThan of polyolefin, polyester and their combination of leather material height at least about 10 ℃.On the contrary, the skin of two component fibres preferably comprises and is selected from following material: its T _gRatio nuclear core material is hanged down polyolefin, its T at least about 10 ℃ _gLower than the nuclear core material at least about 10 ℃ polyester polyolefin and their combination.Preferred situation is examine core and comprise polyester material, and suitcase to contain polythene material.

For any situation of configuration or core/sheath geometry side by side, the fiber of nonwoven layers can show spiral or helical or curled configuration, and is all the more so for two component fibres.

The bat nonwoven layers also can comprise natural fiber.

In addition, the average thickness of the fiber of bat nonwoven layers is preferably about 0.5 micron-Yue 150 microns.More preferably about 5 microns-Yue 75 microns of the average thicknesss of fiber.In addition preferred embodiment in, the average thickness of fiber is about 8 microns-Yue 40 microns.In addition, the fiber of nonwoven layers can have the size of variation, and promptly the fiber of nonwoven layers can comprise the fiber with different average thicknesss.And the cross section of fiber can be circle, plane, avette, oval or other shape.

In another embodiment, nonwoven layers of the present invention can comprise composite, the material that promptly has one or more layers identical or different suitable material, the only physics stack of these materials, be bonded together continuously (for example lamination etc.) or with discontinuous graphic being bonded together, or the outward flange (or periphery) of layer in conjunction with and/or combine in discrete locations.For example, nonwoven layers can also comprise and is selected from following composite: fiber non-woven thing, sponge, foamed materials, reticulated foam, polymerization net, lax bafta, laminated material, formed film and the formed film composite that vacuum forms.Nonwoven layers preferably comprises the formed film composite, and this composite comprises at least a formed film and at least a non-woven fleece, and wherein this layer is that vacuum forms.Suitable formed film composite includes but not limited to by with basis weights being the carded polypropylene non-woven fleece of 30gsm and the vacuum lamination combined shaping membrane material that the formed film combination forms.

In another embodiment, nonwoven layers is foraminous.The average diameter in the hole in the nonwoven layers of water-insoluble substrate is generally about 0.5mm-5mm.The more preferably about 1mm-4mm of the average diameter in hole.Preferred situation is, in the nonwoven layers of substrate, has to be no more than its diameter of hole of about 10% outside these scopes.Preferred situation is, in the nonwoven layers of substrate, has to be no more than its diameter of hole of about 5% outside these scopes.For shape is not circular hole, and " diameter " in hole is meant the diameter that has the circular orifice of identical table area with the aperture of non-circular hole.

In nonwoven layers, the hole exists with about 0.5-12 hole/centimetre collinear frequency usually.Preferred situation is that the hole exists with about 1.5-6 hole/centimetre collinear frequency in the nonwoven layers surface.

The hole must be at least in nonwoven layers.Such hole need not fully to be penetrated into another surface from a surface of nonwoven layers.Yet they also can be like this.In addition, the hole can be in or be not in the nonwoven layers of substrate, and the hole that whole like this articles for use on whole volume all are penetrates.

The hole can form in the nonwoven layers in this substrate when water-insoluble substrate or formation of its nonwoven layers or preparation.Perhaps also can be completed into the back and in nonwoven layers, form the hole in the substrate that comprises nonwoven layers.

Nonwoven layers can comprise multiple different natural and synthetic fibers or material." natural " used herein is meant that material is that secondary articles for use by plant, animal, insecticide or plant, animal and insecticide obtain.Basic material commonly used normally comprises the fleece of any conventional synthetic or natural fabric length fiber or their combination.

The limiting examples that can be used for natural material of the present invention includes but not limited to silk fiber, keratin fiber and cellulose fibre.The limiting examples of keratin fiber comprises and is selected from following those: wool fiber, Pilus Cameli fiber etc.The limiting examples of cellulose fibre comprises and is selected from following those: wood pulp cellulose, cotton fiber, hemp, tossa, flax fiber and their combination.In the present invention, cellulosic fibre material is preferred.

The limiting examples that can be used for synthetic material of the present invention comprises and is selected from following those: acetate fiber, acrylic fiber, cellulose ester fiber, modacrylic fibers, Fypro, polyester fiber, polyolefine fiber, vinal, staple fibre, polyethylene foam material, polyurethane foamed material and their combination.The example of appropriate synthetic materials comprises acrylic acid for example Acrilan (acrilan), Creslan (creslan) and based on fiber, the Orlon of acrylonitrile; Cellulose ester fiber is cellulose acetate, arnel and acele for example; Polyamide is nylon (for example nylon 6, nylon 66, NYLON610 etc.) for example; Polyester is fortrel, Ke Daier (kodel) and dacron fibre, polybutylene terephthalate (PBT) fiber, terylene (dacron) for example; Polyolefin is polypropylene, polyethylene for example; The polyvinyl acetate ester fiber; Polyurethane foamed material and their combination.Fiber that these and other is suitable and non-woven fleece prepared therefrom are described in the following document: Riedel, " Nonwoven BondingMethods and Materials ", Nonwoven World(1987); The Encyclopedia Americana, vol.11, pp.147-153 and vol.26, pp.566-581 (1984); Authorize people's such as Thaman United States Patent (USP) 4,891,227 and United States Patent (USP) 4,891,228 January 2 nineteen ninety, these documents are all introduced the present invention with for referencial use in full.

The non-woven fleece of being made by natural material is made of net or thin slice, and these nets or thin slice are the most normally formed by the liquid suspension of fiber on the filament screen cloth.Referring to people such as C.A.Hampel, The Encyclopedia of Chemistry, the third edition, 1973, pp.793-795 (1973); The Encyclopedia Americana, vol.21, pp.376-383 (1984); And G.A.Smook, Handbook of Pulp and Paper Technologies, Technical Association for the Pulpand Paper Industry (1986), these documents are incorporated herein by reference.

Can be used for natural material non-woven fleece of the present invention can be obtained by a plurality of commercial source.The limiting examples that can be used for suitable commercially available ply of paper of the present invention comprises Airte , and a kind of basis weights is spread the method cellulose layer for the embossing gas of about 71gsy, can be available from James River, and Green Bay, WI; Walkisoft , a kind of basis weights is the embossing gas shop method cellulose layer of about 75gsy, can be available from Walkisoft U.S.A., Mount Holly, NC.

Those that other suitable non-woven fleece material includes but not limited to describe in following United States Patent (USP): 4,447,294 of the Osborn of promulgation on May 8th, 1984; 4,603,176 of the Bjorkquist of promulgation on July 29th, 1986; 4,981,557 of the Bjorkquist of promulgation on January 1st, 1991; 5,085,736 of the Bjorkquist of promulgation on February 4th, 1992; 5,138,002 of the Bjorkquist of promulgation on August 8th, 1992; The people's such as Phan of promulgation on November 16th, 1993 5,264,007; The people's such as Phan of promulgation on November 23rd, 1993 5,264,082; 4,637,859 of the Trokhan of promulgation on January 20th, 1987; 4,529,480 of the Trokhan of promulgation on July 16th, 1985; 4,687,153 of the McNeil of promulgation on August 18th, 1987; The people's such as Phan of promulgation on June 29th, 1993 5,223,096; The people's such as Rasch of promulgation on October 21st, 1997 5,679,222, these patents are all introduced the present invention with for referencial use in full.

The method for preparing non-woven fleece is well-known in the art.These non-woven fleeces generally can be spread method (air-laying), water shop method (water-laying), meltblown, conformal established law (coforming), spun-bond process (spunbonding) or combing method by gas and make, wherein be at first fiber or long filament to be cut into Len req from the long filament bar, place current or air-flow, will carry then the gas of fiber or water flow through screen cloth with fiber laydown on screen cloth.No matter its preparation method or composition carry out the binding operation of at least a type in the several types with formed layer, so that independent fiber is combined together to form the self-supporting net.In the present invention, nonwoven layers can make by multiple distinct methods.These methods include but not limited to gas entanglement method (airentanglement), water entanglement method (hydroentanglement), accumulation of heat is legal and the combination of these methods.

Can be used for the non-woven fleece that is made by synthetic material of the present invention can be obtained by a plurality of commercial source.The limiting examples that can be used for suitable nonwoven layers material of the present invention comprises HEF 40-047, and a kind of foraminous water entanglement material contains have an appointment 50% staple fibre and 50% polyester, and basis weights is about 61 gram/square metre (gsm), can be available from Veratec, and Inc., Walpole, MA; HEF 140-102, a kind of foraminous water entanglement material contains have an appointment 50% staple fibre and 50% polyester, and basis weights is about 67gsm, can be available from Veratec, Inc., Walpole, MA; Novonet  149-616, a kind of material of grizzly bar style of thermal contains 100% polypropylene of having an appointment, and basis weights is about 60gsm, can be available from Veratec, Inc., Walpole, MA; Novonet  149-801, a kind of material of grizzly bar style of thermal contains 69% staple fibre of having an appointment, about 25% polypropylene and about 6% cotton, and basis weights is about 90gsm, can be available from Veratec, and Inc.Walpole, MA; Novonet149-191, a kind of material of grizzly bar style of thermal contains 69% staple fibre of having an appointment, about 25% polypropylene and about 6% cotton, and basis weights is about 120gsm, can be available from Veratec, Inc.Walpole, MA; HEF Nubtex  149-801, a kind of caked foraminous water entanglement material contains 100% polyester of having an appointment, and basis weights is about 84gsm, can be available from Veratec, Inc.Walpole, MA; Keybak 951V , a kind of dry foraminous material that forms contains 75% staple fibre of having an appointment, about 25% acrylic fiber, and basis weights is about 51gsm, can be available from Chicopee, and New Brunswick, NJ; Keybak  1368, a kind of porose material contains 75% staple fibre of having an appointment, about 25% polyester, and basis weights is about 47gsm, can be available from Chicopee, and New Brunswick, NJ; Duralace  1236, a kind of foraminous water entanglement material contains 100% staple fibre of having an appointment, and basis weights is the about 138gsm of about 48gsm-, can be available from Chicopee, New Brunswick, NJ; Duralace  5904, a kind of foraminous water entanglement material contains 100% polyester of having an appointment, and basis weights is the about 138gsm of about 48gsm-, can be available from Chicopee, New Brunswick, NJ; Chicopee  5763, a kind of water pore-forming material of combing (8 * 6 hole/inches, 3 * 2 holes/cm), contain 70% staple fibre of having an appointment, about 30% polyester, and the optional latex adhesive (based on acrylate or EVA) that is up to about 5%w/w that contains, and basis weights is the about 90gsm of about 60gsm-, can be available from Chicopee, New Brunswick, NJ; (for example Chicopee 9931 for Chicopee  9900 series, 62gsm, 50/50 staple fibre/polyester and Chicopee 9950 50gsm, 50/50 staple fibre/polyester), the water entanglement material of combing, contain the fiber that consists of about 50% staple fibre/50% polyester-0% staple fibre/100% polyester or 100% staple fibre/0% polyester, and basis weights is the about 84gsm of about 36gsm-, can be available from Chicopee, New Brunswick, NJ; Sontara 8868, and water entanglement material contains have an appointment 50% cellulose and about 50% polyester, and basis weights is about 72gsm, can be available from Dupont Chemical Corp.The basis weights of preferred nonwoven host material is the about 96gsm of about 24gsm-, and the about 84gsm of more preferably about 36gsm-most preferably is the about 78gsm of about 42gsm-.

Nonwoven layers can also be as the polymerization mesh sponge of describing in European patent application EP 702550A1, and this patent application is announced on March 27th, 1996, it is introduced the present invention in full with for referencial use.The netted sponge-rubber pad of such polymerization contains a plurality of overlapping layers of extruding tubular mesh, and described net is by the high flexibility polymer, for example the polyamide of the addition polymer of olefinic monomer and polycarboxylic acids and making.

Nonwoven layers can also comprise formed film and composite, promptly contains the multilayer material of formed film.Such formed film is tending towards remollescent plastics when preferably being contained in contact skin.Suitable flexible plastic formed film includes but not limited to for example low density polyethylene (LDPE) (LDPE) of polyolefin.When nonwoven layers comprised the plastics forming film, nonwoven layers preferably had the hole, for example macropore or micropore, and nonwoven layers has liquid permeable like this.In one embodiment, nonwoven layers comprises the plastics forming film that only has micropore.Depart from the surface of micropore, and promptly outer (male) side is preferably placed at the inner surface of the second layer, and preferably towards the inside of substrate, promptly towards cleaning component.Comprise in the embodiment with hole that the petal-shaped edge surface departs from some, be not bound by theory, it is believed that when the surface in hole is departed from towards the cleaning component that contains surfactant and/or treated useful component, exert pressure to articles for use with hands and can make that the petal-shaped edge that the surface departs from is inwardly folding, inner surface at layer produces a large amount of valves thus, these valves will be included in the described cleaning in the articles for use and/or treat useful component metering and discharge, and prolong the service life of articles for use thus.

In another embodiment, nonwoven layers comprises and both has the plastics forming film that macropore also has micropore.In such embodiments, nonwoven layers is very suitable for contacting with the zone of processing to be cleaned, thereby gives sensation as cloth for such microporous membrane.In such scheme, micropore surface depart from towards preferably with the big hole surface of nonwoven layers depart from towards opposite.In this case, macropore makes the whole moistening/foaming characteristic of articles for use reach maximum by following manner: during using articles for use, under normal pressure and decompression, departed to form three-dimensional thickness by the surface, produce foam passage (bellow) thus.

Under any circumstance, the nonwoven layers that comprises formed film preferably has at least about 100 hole/cm ², more preferably at least 500 hole/cm ², even more preferably at least about 1000 holes/cm ², most preferably at least about 1500 hole/cm ²Substrate.Preferred embodiment of the present invention comprises the following nonwoven layers of water flow velocity: about 5cm ³/ cm ²The about 70cm of-s- ³/ cm ²-s, more preferably from about 10cm ³/ cm ²The about 50cm of-s- ³/ cm ²-s most preferably is 15cm ³/ cm ²The about 40cm of-s- ³/ cm ²-s.

The composite that can be used for the suitable formed film of nonwoven layers of the present invention and contain formed film includes but not limited to those disclosed in following patent: at the people's such as Radel of promulgation on August 3 nineteen eighty-two United States Patent (USP) 4,342,314, commonly assigned unsettled U. S. application 08/326,571 and submit to and at disclosed PCT application on January 11st, 1996 US95/07435 in June 12 nineteen ninety-five, United States Patent (USP) 4 the people such as Curro of December in 1986 promulgation on the 16th, 629,643, these documents are all introduced the present invention with for referencial use in full.In addition, nonwoven layers can be the formed film composite, wherein comprises at least a formed film and at least a non-woven fleece, and wherein this layer is that vacuum forms.Suitable formed film composite includes but not limited to by with basis weights being the carded polypropylene non-woven fleece of 30gsm and the vacuum lamination combined shaping membrane material that the formed film combination forms.

In addition, nonwoven layers and any other layer preferably are bonded to each other to keep the integrity of articles for use.This combination can be a combination (for example focus in conjunction with), with the mode of being interrupted engage continuously (for example lamination etc.), the outward flange (or periphery) of layer in conjunction with and/or discrete locations in conjunction with or their combination.When in articles for use of the present invention, use point in conjunction with the time, put bonded interval and preferably be not less than about 1cm.Yet, under any circumstance, in conjunction with arranging like this, on the outer surface of layer and gained articles for use, to produce geometry and graphic, for example rhombus, circle, square etc.

In articles for use of the present invention, nonwoven layers and any other layer can be carried out finishing, have 2 lateral single composite beds that the matter structure is different with formation.Therefore, water-insoluble substrate can comprise the single composite bed with dual matter structure side or surface.

Under any circumstance, the bonded area between nonwoven layers and any other layer preferably is no more than the about 50% of each layer total surface area, preferably is no more than approximately 15%, more preferably no more than about 10%, is most preferably not exceeding about 8%.

Each of Tao Luning layer comprises at least two surfaces, i.e. inner surface and outer surface in this article.Each surface can have identical or different matter structure and abrasiveness.Articles for use of the present invention preferably comprise substrate and to the softish layer of skin.Yet,, can obtain to have the not substrate of homogeneity structure by using different combinations of materials or using different preparation methoies or their combination.For example, can prepare water-insoluble substrate, so that the personal-care supplies with following advantage to be provided: have the stronger side of abrasiveness that is used to strip off, be used for the gentle cleaning and the softer absorption side of therapeutic treatment with dual matter structure.In addition, can prepare the substrate that each layer has different colours, further distinguish these surfaces to help user thus.

In addition, each layer and the articles for use self of articles for use multiple different shape and form be can be made, plain cushion, hassock, thin slice, spherical apparatus and apparatus in irregular shape comprised.The accurate dimension of each layer depends on the feature of desired application and articles for use, and surface area can be about 1 square inch to hundreds and thousands of approximately square inches.Convenient especially layer and the articles for use shape of using includes but not limited to square, circle, rectangle, taper, glove type or ellipse, and its surface area is about 5in ²-Yue 200in ², preferably about 6in ²-Yue 120in ², 15in more preferably from about ²-Yue 100in ², and thickness is the about 50mm of about 0.5mm-, the about 25mm of preferably about 1mm-, the more preferably from about about 20mm of 2mm-.

The attrition value algoscopy

Abrasiveness is meant " non-scouring " property of the nonwoven layers of articles for use of the present invention.Nonwoven layers of the present invention has stripping off property of appropriateness, but not coarse to skin.Therefore, attrition value is measured and to be comprised and use machinery along the test surfaces substrate that rubs, the scratch labelling that uses different analytical technologies to be determined at then to produce on the test surfaces.

This method needs following apparatus.

1.Martindale toothbrush consume and examine for wear device: Model 103 are more than the series number 103-1386/2.The Martindale 07-01-88 that James H.Heal and Co.Ltd makes.Yarn fabric test and QC device.Instep is long-pending: 43 * 44mm.Weight 1Kg.

2. end capped polystyrene bar 11 * 8cm.General Clean-polystyrene layer on white high impact polystyrene, for example EMA Model Supplies SS-20201L.

3. the substrate of desire test.

4. gloss meter, for example Sheen Tri-Microgloss 20-60-85

By removing plastic protective film for plastics and prepare polystyrene bar (not using fabric) with washing with alcohol from the side of desire scraping.The polystyrene bar is placed on the non-wear surface, and allows this at air drying.Then the polystyrene bar is fixed in the substrate of Martindale examine for wear device with adhesive tape along the edge.With polystyrene bar center-aligned below the scratch device path, the length direction of bar is consistent with the direction of motion.Downcut the substrate sample of 2.5 " * 2.5 ".The substrate sample is fixed on scraping of Martindale wipe one's feet with two-sided tape, allows the instrument direction and the moving direction of substrate be in line.To scrape the assembly that wipes one's feet with the screw of supplying with is fixed in the device.Apply 1Kg weight above wiping one's feet scraping, and guarantee to scrape and only wipe one's feet in a direction motion (forward and backward).With sealer whole M artindale is covered.The speed of instrument be set to 50 circles/minute, and allow its running.(frequency=0.833Hz).In case instrument shuts down, promptly take off and scrape the assembly that wipes one's feet, and the polystyrene bar is taken off from the substrate of instrument.The labelling polystyrene to be showing used substrate, and stores in plastic bag.

Next p-poly-phenyl ethylene bar is analyzed.The polystyrene bar is placed on the black structure paper back of the body at the end, and analyzes at least 5 same matrix samples to obtain reproducible meansigma methods.Place gloss meter (light beam and scratch meet at right angles like this) with orthogonal manner, and allow gloss meter at polystyrene bar scraping side upper central place.Select 20 degree angles, and measure sample to obtain attrition value.Along with the reduction of attrition value, the scraping of substrate or scrubbing character improve.

Treat useful component

Articles for use of the present invention also contain the useful component of treatment of safe and effective amount.Treat the adjacent setting with water-insoluble substrate of useful component, and comprise that to account for the about 10%-of water-insoluble substrate weight about 1000%, more preferably from about 10%-is about 500%, most preferably from about the treatment advantageous compositions of 10%-about 250%.Said composition comprises hydrophilic conditioning agent, and wherein when these articles for use contacted with water, this conditioner showed the leaching value (Leaching Value) less than about 25% in the time of 1 minute, showed the leaching value less than about 50% in the time of 5 minutes.Preferred situation is, hydrophilic conditioning agent showed the leaching value less than about 15% in the time of 1 minute, in the time of 5 minutes, show leaching value less than about 30%, even be more preferably the leaching value that in the time of 1 minute, shows less than about 10%, in the time of 5 minutes, show leaching value less than about 20%, also be more preferably the leaching value that in the time of 1 minute, shows less than about %, in the time of 5 minutes, show leaching value less than about 10%, most preferably in the time of 1 minute, show leaching value, in the time of 5 minutes, show leaching value less than about 8% less than 2.5%.

The leaching value of hydrophilic conditioner (for example glycerol) uses following instrument and material to measure:

1. gas chromatograph (for example being equipped with the HP5890 of capillary feed system, flame ionization detector and data handling system)

2. the 150mL beaker that has stirring rod

3.100mL graduated graduated cylinder

4.5mL pipet

5.98-104 tap water

6. be used to collect the 20mL bottle (vial) of 5mL aliquot

7. timer

8. water-bath (for example dark ware on electric hot plate)

9. be cut into the personal-care supplies that contain hydrophilic conditioning agent (for example glycerol) of 6 * 6cm

10.10-100 the pipet of μ L variable-volume

11.100-1000 the pipet of μ L variable-volume

12. have Pyrex 13 * 100mm glass culture tube of the screw lid of the teflon lined of being added with

13. analytical balance

14. centrifuge (for example Savant Speed Vac)

15. glass GC bottle and the lid that is added with teflon lined

Reference material and special material

	Suggestion source or preparation (or coordinate)
		Methanol	ACS level reagent, J.T.Baker cat.no.9070-33
Sylon BFT (two (trimethyl silyl) trifluoroacetamide: trim,ethylchlorosilane 99: 1)	Supelco?Cat.#3-3149

Tridecyl alcohol	98% lowest purity, ICN Biomedicals Cat. #156998
		Hydrophilic conditioner (glycerol)	USP，J.T.Baker?Cat.#2140-01

Reference material

Inner mark solution (ISTD)	Weigh 500mg ± 20mg tridecyl alcohol of being accurate to 0.1mg and place the 10mL volumetric flask writes down this weight.Be diluted to the scale volume with methanol, clog, and fully mix with stopper.
		Calibration standard	Weigh 50 ± 5mg glycerol of being accurate to 0.1mg and place the 10mL volumetric flask writes down this weight.Be diluted to the scale volume with methanol, clog, and fully mix with stopper.The other standard solution that in the 10mL volumetric flask, prepares following concentration by serial dilution: 2500,1000 and 500 μ g/mL

Prepare aforesaid reference material.For each reference material, Pyrex 13 * 100mm screw lid culture tube is marked.Suction moves 100 μ L glycerol reference materials (5000,2500,1000 and 500 μ g/mL) and places suitable pipe respectively.Suction moves mark, the solution of 5mg/mL tridecyl alcohol in methanol in the 50 μ L, places each pipe.Use Speed Vac, with the reference material traditional vacuum until drying.Add 500 μ L SylonBFT, stopper beyond the Great Wall, and 85 ℃ of heating 30 minutes.Transfer in the GC bottle, and be expelled in the GC.

Water-bath is set to 98 °F-104 °F.Using graduated graduated cylinder to measure the 100ml tap water is added in the beaker.Add stirring rod, and beaker is placed in the water-bath.Stirring is set at scale 4.Articles for use are placed the water of stirring, and pick up counting.After 1 minute, use pipet to take out 5ml water, and sample is placed the 20ml bottle.After having spent 4 minutes again (after picking up counting 5 minutes), take out the 5ml sample with pipet and place the 20ml bottle.

Sample is transferred in 13 * 100mm glass culture tube of screw lid of labelling with the teflon lined of being added with.With each scintillation vial of 1mL methanol wash.Methanol wash liquid is added in suitable 13 * 100mm culture tube.Mark in the 50 μ L is shifted out in suction, and the solution of 5mg/mL tridecyl alcohol in methanol is added in each pipe.Use speed vac, with the reference material traditional vacuum until drying.Add 500 μ LSylon BFT, stopper beyond the Great Wall, and 85 ℃ of heating 30 minutes.Transfer in the GC bottle, and be expelled in the GC.

The gas chromatogram of carrying out as described below is operated:

Chromatographic condition
		Carrier gas	Helium via gas purifier and scrubber purification.
Carrier pressure	15psi, the constant pressure state
		Shunting	20: 1
Injector temperature	310 ℃
		Volume injected	1 μ L
Program oven temperature	325 ℃ of speed: 80 ℃--＞325 ℃ @15 ℃/minute end temperatures 5 minutes
		Detector temperature	350 ℃
Detector flow velocity: air column+composition hydrogen	380-420mL/ minute 29-31mL/ minute 29-31mL/ minute

In case setting completed for this device, promptly this device of running under condition shown in the last table is set integrator or data handling system, with weight according to hydrophilic conditioning agent (for example glycerol) in the following Equation for Calculating sample:

Wherein:

Target area in the A=calibration solution

The weight (gram) of hydrophilic conditioning agent (glycerol) in the B=calibration solution

Target weight (gram) in the C=calibration solution

The area of hydrophilic conditioning agent (glycerol) in the D=calibration solution

Wherein:

RF=is by the response factor of above-mentioned Equation for Calculating

Target weight (gram) in the E=sample solution

The area of hydrophilic conditioning agent in the F=sample solution (glycerol)

Target area in the G=sample solution

By the amount of hydrophilic conditioning agent in the sample is determined leaching value (%) divided by the total amount of hydrophilic conditioning agent in the articles for use before immersing.

The present invention treats advantageous compositions and preferably also comprises the treatment benefit materials that is selected from hydrophobicity conditioner, structure conditioner and combination thereof.

Hydrophilic conditioning agent

Articles for use of the present invention comprise one or more hydrophilic conditioning agents.The limiting examples of hydrophilic conditioning agent comprises and is selected from following those: polyhydric alcohol, polypropylene glycol, Polyethylene Glycol, ureas, 2-pyrrolidone-5-carboxylic acid, ethoxylation and/or propenoxylated C ₃-C ₆Two pure and mild triols, Alpha-hydroxy C ₂-C ₆Sugar carboxylic acid, ethoxylation and/or propenoxylated, acrylic copolymer, sugar, sugar alcohol and their mixture with about at the most 12 carbon atoms with about at the most 12 carbon atoms.The instantiation of useful hydrophilic conditioning agent comprises following material, for example carbamide; Guanidine; Glycolic acid and glycol hydrochlorate (for example ammonium salt and alkyl quaternary ammonium salts); Lactic acid and lactate (for example ammonium salt and alkyl quaternary ammonium salts); Sucrose, fructose, glucose, erythrose, erithritol, sorbitol, mannitol, glycerol, hexanetriol, propylene glycol, butanediol, hexanediol etc.; Polyethylene Glycol, for example PEG-2, PEG-3, PEG-30, PEG-50; Polypropylene glycol, for example PPG-9, PPG-12, PPG-15, PPG-17, PPG-20, PPG-26, PPG-30, PPG-34; The alkoxylate glucose; Hyaluronic acid; Cation skin condition polymer (for example quaternary ammonium polymer, as the polyquaternary amine polymer); And composition thereof.In articles for use of the present invention, glycerol is particularly preferred hydrophilic conditioning agent.Other useful material is that for example various forms of Aloes (for example Aloe gel), chitosan and chitosan derivative are as Kytamer L, lactamide monoethanolamine; The acetamide monoethanolamine; And composition thereof.Other usefully propenoxylated glycerol, as be recorded in propenoxylated glycerol in people's such as Orr the United States Patent (USP) 4,976,953 of nineteen ninety December 11 days promulgation, the document is incorporated herein by reference.

The hydrophobicity conditioner

Articles for use of the present invention can comprise one or more hydrophobicity conditioners, and they are in order to provide useful opsonic action to skin or hair at articles for use between the operating period.It is about 1,000% that articles for use of the present invention preferably are included as the about 0.5%-of water-insoluble substrate weight, and more preferably from about 1%-is about 200%, most preferably from about the hydrophobicity conditioner of about 100% weight of 10%-.

The hydrophobicity conditioner can be selected from one or more weighted arithmetic mean solubility parameters and be less than or equal to 10.5 hydrophobicity conditioner.It is reported, mathematical definition based on solubility parameter, if the solubility parameter of self that a kind of in the chemical compound has is greater than 10.5, then for the hydrophobicity conditioner that contains two or more chemical compounds, might obtain required weighted arithmetic mean solubility parameter, promptly this parameter is less than or equal to 10.5.

Solubility parameter is executed known for preparation chemist common in this area, and is commonly used for definite material compatibility and deliquescent indication in compound method.

The solubility parameter δ of chemical compound is defined as the square root of the cohesion energy density of this chemical compound.Usually, to the list value of the contribution of heat of evaporation and the molal volume of this compound component, use the solubility parameter of following formula computerized compound by additional group: $\mathrm{\δ}=[\frac{\underset{i}{\mathrm{\Σ}}{E}_i}{\underset{i}{\mathrm{\Σ}}{m}_i}{]}^{1/2}$

∑ wherein _iE _iThe heat of evaporation sum of=additional group contribution, and

∑ _im _iThe molal volume sum of=additional group contribution

Additional group comes together in Barton, A.F.M. to various atoms and the heat of evaporation of atomic radical contribution and the standard list value of molal volume Handbook of Solubility Parameters, CRC Press, Chapter 6, table 3, pp.64-66 (1985).The document is incorporated herein by reference.Above-mentioned solubility parameter is at Fedors, R.F., " A Method for Estimating Both the SolubilityParameters and Molar Volumes of Liquids ", Polymer Engineering and Science, vol.14 describes among the no.2, pp.147-154 (in February, 1974).The document is introduced the present invention in full with for referencial use.

Solubility parameter is followed mixing rule, so the weighted arithmetic average (be weighted average) of the solubility parameter of mixture by the solubility parameter of each component in this mixture draws.Referring to, Handbook Of Chemistry and Physics, 57th edition, CRC Press, p.C-726 (1976-1977).The document is incorporated herein by reference.

The preparation chemist is usually with (cal/cm ³) ^1/2Be unit record and use solubility parameter. Handbook of Solubility ParametersIn, additional group is that unit provides with kJ/mol to the list value of heat of evaporation contribution.But, be easy to the list value of these heat of evaporations is converted into cal/mol unit with following known relationships:

1J/mol=0.239006cal/mol and 1000J=1kJ.

Referring to Gordon, people such as A.J., The Chemist ' s Companion, John Wiley﹠amp; Sons, pp.456-463, (1972).The document is introduced the present invention in full with for referencial use.

Also free list is listed the solubility parameter of various chemical substances.The list value of solubility parameter can be referring to above-mentioned Handbook of Solubility ParametersAlso referring to " Solubility Effects InProduct, Package, Penetration, And Preservation ", C.D.Vaughan, Cosmetics And Toiletries, vol.103, in October, 1988, pp.47-69.The document is introduced the present invention in full with for referencial use.

The limiting examples of hydrophobicity conditioner comprises and is selected from following those: mineral oil, vaseline, lecithin, hydrolecithin, lanoline, lanolin derivative, C ₇-C ₄₀Branched-chain hydrocarbons, C ₁-C ₃₀The C of carboxylic acid ₁-C ₃₀Alcohol ester, C ₂-C ₃₀The C of dicarboxylic acids ₁-C ₃₀Alcohol ester, C ₁-C ₃₀The monoglyceride of carboxylic acid, C ₁-C ₃₀The diglyceride of carboxylic acid, C ₁-C ₃₀The triglyceride of carboxylic acid, C ₁-C ₃₀The ethylene glycol ester of carboxylic acid, C ₁-C ₃₀The ethylene glycol diester of carboxylic acid, C ₁-C ₃₀The propylene glycol monoester of carboxylic acid, C ₁-C ₃₀The C of the propylene glycol diesters of carboxylic acid, sugar ₁-C ₃₀Dicarboxylic acid monoester and polyester, polydialkysiloxane, poly-diaromatic siloxane, poly-alkaryl siloxanes, have cyclopolymethyl siloxane (cyclomethicone), vegetable oil, hydrogenated vegetable oil, the polypropylene glycol C of 3-9 silicon atom ₄-C ₂₀Alkyl ether, two C ₈-C ₃₀Alkyl ether and combination thereof.

The mineral oil that also is called vaseline liquid is can be from the mixture of the liquid hydrocarbon of oil.Referring to The Merck Index, Tenth Edition, Entry 7048, p.1033 (1983) and InternationalCosmetic Ingredient Dictionary, Fifth Edition, vol.1, p.415-417 (1993).The two introduces the present invention in full with for referencial use.

The vaseline that also is called vaseline is the colloidal state system of non-straight chain hydrocarbon solid and high boiling liquid hydrocarbon, and wherein the most liquid hydrocarbon is retained in the inside of micelle.Referring to The Merck Index, Tenth Edition, Entry 7047, p.1033 (1983); Schindler, Drug.Cosmet.Ind., 89,36-37,76,78-80,82 (1961); International Cosmetic Ingredient Dictionary, Fifth Edition, vol.1, p.537 (1993).These documents are introduced the present invention in full with for referencial use.

Lecithin also can be used as the hydrophobicity conditioner.Lecithin is the mixture of the diglyceride of naturally occurring some fatty acid that links to each other with the cholinester of phosphoric acid.

The present invention uses straight chain and the branched-chain hydrocarbons with about 40 carbon atoms of about 7-.The limiting examples of these hydrocarbon comprises dodecane, Fancol ID, squalane, cholesterol, Parleam, docosane (that is C, ₂₂Hydrocarbon), hexadecane, 2-Methylpentadecane (a kind of with Permethyl  101A available from Presperse, South Plainfield, the commercially available hydrocarbon of NJ).Other is C usefully ₇-C ₄₀Isoparaffin, they are C ₇-C ₄₀Branched-chain hydrocarbons.A kind of liquid hydrocarbon-poly decene of side chain also can be used for the present invention, it with trade name Puresyn 100 μ and Puresyn 3000  available from Mobile Chemical (Edison, NJ).

Other is C usefully ₁-C ₃₀Carboxylic acid and C ₂-C ₃₀The C of dicarboxylic acids ₁-C ₃₀Alcohol ester comprises the material and the aromatic derivative of straight chain and side chain.Other is ester usefully, for example C ₁-C ₃₀The monoglyceride of carboxylic acid, C ₁-C ₃₀The diglyceride of carboxylic acid, C ₁-C ₃₀The triglyceride of carboxylic acid, C ₁-C ₃₀The ethylene glycol ester of carboxylic acid, C ₁-C ₃₀The ethylene glycol diester of carboxylic acid, C ₁-C ₃₀The propylene glycol monoester of carboxylic acid and C ₁-C ₃₀The propylene glycol diesters of carboxylic acid.The present invention includes straight chain, side chain and aryl carboxylic acid.Also can use the propoxylation of these materials and the derivant of ethoxylation.Limiting examples comprises the decanedioic acid diisopropyl ester, the adipic acid diisopropyl ester, the myristic acid isopropyl esters, the Palmic acid isopropyl esters, propanoic acid myristyl ester, diglycol stearate, 2-ethylhexyl cetylate, neopentanoic acid isodecyl Arrcostab, two-2-ethylhexyl maleate, Palmic acid cetyl ester, myristic acid myristyl ester, the stearic acid stearyl, stearic acid cetyl ester, mountain Yu acid mountain Yu base ester, maleic acid dioctyl ester, decanedioic acid dioctyl ester, the adipic acid diisopropyl ester, cetyl octanoate, the dilinoleic acid diisopropyl ester, sad/the caproic acid triglyceride, PEG-6 is sad/the caproic acid triglyceride, PEG-8 is sad/caproic acid triglyceride and combination thereof.

Other is the C of various sugar usefully ₁-C ₃₀Monoesters and polyester and relevant material.These esters are derived by sugar or polyol moiety and a kind of or polyester carboxylic moiety and are obtained.According to the acid of forming and sugared, these esters at room temperature can be the liquid or solid forms.The example of liquid ester comprises: glucose four oleates, the glucose tetra-ester of soy(a)-bean oil fatty acid (undersaturated), mannose four esters of blended soy(a)-bean oil fatty acid, oleic galactose four esters, linoleic arabinose four esters, xylose four linoleates, galactose five oleates, sorbitol four oleates, sorbitol six esters of unsaturated soy(a)-bean oil fatty acid, xylitol five oleates, sucrose four oleates, sucrose five oleates, sucrose six oleates, sucrose seven oleates, sucrose eight oleates and composition thereof.The example of solid ester comprises: sorbitol six esters, carboxylate moiety wherein are that mol ratio is 1: 2 palm acid ester and an Arachidate; The octaester of Raffinose, carboxylate moiety wherein are that mol ratio is 1: 3 linoleate and a behenate; Seven esters of maltose, esterification carboxylic moiety wherein are that mol ratio is 3: 4 Oleum Helianthi fatty acid and a lignoceric acid; The octaester of sucrose, wherein the carboxylic moiety of esterification is that mol ratio is 2: 6 oleate and a behenate; The octaester of sucrose, wherein the carboxylic moiety of esterification is that mol ratio is 1: 3: 4 laurate, linoleate and a behenate.Preferred solid material is a sucrose polyfatty acid esters, and esterification degree wherein is 7-8, and fatty acid part wherein is C ₁8 one-and/or two-unsaturated fatty acid and mountain Yu acid, the mol ratio of unsaturated fatty acid and mountain Yu acid is 1: 7～3: 5.Particularly preferred sugar cube polyester is the octaester of sucrose, has about 7 22 carbon fatty acids and about 1 oleic acid in its molecule.Other material comprises the Oleum Gossypii semen or the soybean oil fatty acid esters of sucrose.These ester materials also are recorded in United States Patent (USP) 2,831, the United States Patent (USP) 4,005,196 of the Jandacek of promulgation on January 25th, 854,1977; The people's such as Letton of the United States Patent (USP) promulgation on April 26th, 4,005,195,1994 of the Jandacek of promulgation on January 25th, 1977 United States Patent (USP) 5,306,516; The people's such as Letton of promulgation on April 26th, 1994 United States Patent (USP) 5,306,515; The people's such as Letton of promulgation on April 26th, 1994 United States Patent (USP) 5,305,514; The people's such as Jandacek of promulgation on January 10th, 1989 United States Patent (USP) 4,797,300; The people's such as Rizzi of promulgation on June 15th, 1976 United States Patent (USP) 3,963,699; The United States Patent (USP) 4,518,772 of the Volpenhein of promulgation on May 21st, 1985; United States Patent (USP) 4,517,360 with the Volpenhein that issued on May 21st, 1985.These documents are incorporated herein by reference.

Nonvolatile polysiloxanes also is useful oil as polydialkysiloxane, poly-diaromatic siloxane and poly-alkaryl siloxanes.These polysiloxanes are recorded in the United States Patent (USP) 5,069,897 of Orr of December in 1991 promulgation on the 3rd, and the document is incorporated herein by reference.Poly-alkylsiloxane and chemical general formula R ₃SiO[R ₂SiO] _xSiR ₃Corresponding, wherein R is that alkyl (R is methyl or ethyl preferably, is more preferably methyl) and x are up to about 500 integer, selects these parameters to obtain required molecular weight.Commercially available poly-alkylsiloxane comprises polydimethylsiloxane, this chemical compound is also referred to as dimethicone, and its limiting examples comprises Vicasil  series of being sold by General Electric Company and Dow Corning  200 series of being sold by Dow Corning Corporation.The instantiation that is used for polydimethylsiloxane of the present invention comprises Dow Corning  225 fluids, and it is that viscosity is 10 centistokes and boiling point greater than 200 ℃ liquid; Dow Corning  200 fluids, it is that viscosity is respectively 50,350 12,500 centistokes and boiling point greater than 200 ℃ liquid.Other useful material is that for example trimethylsiloxy esters of silicon acis, this chemical compound are a kind of corresponding to chemical general formula [(CH ₂) ₃SiO _1/2] _x[SiO ₂] polymer of y, wherein x is that integer and the y of about 1-about 500 are the integers of about 1-about 500.A kind of commercially available trimethylsiloxy esters of silicon acis is as selling with Dow Corning  593 fluids with the mixture of polydimethylsiloxane.The present invention also can use dimethiconol, and it is hydroxy-end capped dimethyl polysiloxane.These materials can chemical general formula R ₃SiO[R ₂SiO] _xSiR ₂OH and HOR ₂SiO[R ₂SiO] _xSiR ₂OH represents that wherein R is that alkyl (R is methyl or ethyl preferably, is more preferably methyl) and x are up to about 500 integer, selects these parameters to obtain required molecular weight.Commercially available dimethiconol is sold (as Dow Corning  1401,1402 and 1403 liquid) with the form of mixtures of itself and polydimethylsiloxane or SILIBIONE OIL 70047 V20 DC-21330 DC21330 typically.The present invention also can use poly-alkaryl siloxanes, is preferred 25 ℃ of following viscosity for the PSI of about 65 centistokes of about 15-.These materials have commercially available, for example sell with the title of SF1075 aminomethyl phenyl fluid (being sold by General Electric Company) and the poly-trimethicone fluid of 556 cosmetics-stage phenyl (being sold by Dow Corning Corporation).Alkylating polysiloxanes can be used for the present invention as methyl decyl polysiloxanes and Methyl Octyl polysiloxanes, and they can be available from General Electric Company.Being used for other material of the present invention is alkyl-modified siloxanes, and as alkyl polymethyl siloxane and alkyl polydimethylsiloxane, wherein alkyl chain comprises 10-50 carbon atom.This class siloxanes is by commercially available, and its commodity are called ABIL WAX 9810 (C ₂₄-C ₂₈The alkyl polymethyl siloxane) (by the Goldschmidt sale) and SF1632 (spermaceti/stearyl polymethyl siloxane) (selling) by General Electric Company.

Vegetable oil and hydrogenated vegetable oil also can be used for the present invention.The example of vegetable oil and hydrogenated vegetable oil comprises safflower oil, Oleum Ricini, Oleum Cocois, Oleum Gossypii semen, pilchardine, palm-kernel oil, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, Oleum Glycines, Oleum Brassicae campestris, Semen Lini oil, Testa oryzae oil, Oleum Pini, Oleum sesami, Oleum Helianthi, the hydrogenation safflower oil, castor oil hydrogenated, hydrogenated coconut oil, hydrogenated cottonseed oil, the hydrogenation pilchardine, hydrogenated palm kernel oil, hydrogenated palm oil, hydrogenated groundnut, hydrogenated soybean oil, hydrogenated rapeseed oil, the hydrogenation Semen Lini oil, the hydrogenation Testa oryzae oil, the hydrogenation Oleum sesami, hydrogenation Oleum Helianthi and their mixture.

Also can use the C of polypropylene glycol ₄-C ₂₀The C of alkyl ether, polypropylene glycol ₁-C ₂₀Carboxylate and two-C ₈-C ₃₀Alkyl ether.The limiting examples of these materials comprises PPG-14 butyl ether, PPG-15 stearyl ether, dicaprylyl ether, lauryl Octyl Ether and its mixture.

The hydrophobicity chelating agen also can be used as the hydrophobicity conditioner and is used for the present invention.Suitable hydrophobic chelating agen is described in the following document: in the people's such as Scanlon of June 7 nineteen eighty-three promulgation United States Patent (USP) 4,387,244 and with people's such as Schwartz name in the unsettled U.S. Patent application of submitting on February 26th, 1,999 09/258,747 and 09/259,485.

Treating useful component can be made into multiple multi-form.In one embodiment of the invention, treating useful component is emulsion form.For example, oil-in-water, Water-In-Oil, W/O/W and polysiloxane emulsion bag oil-in-water all can be used for the present invention." water " that uses in the context of emulsion not only refers to water, also refers to water miscible or miscible with water material, as glycerol.

The useful component of preferred treatment comprises a kind of emulsion, and this emulsion comprises water and oil phase.It will be understood by those skilled in the art that given component will mainly be distributed in water or the oil phase according to the water solublity/water dispersible of treatment benefit materials in the component.In one embodiment, oil phase contains one or more hydrophobicity conditioners.In another embodiment, water contains one or more hydrophilic conditioning agents.

The present invention of emulsion form treats useful component and comprises water and oil phase or lipid usually mutually.Suitable oil or lipid can be from animal, plant or oil, they can be natural or synthetic (promptly synthetical).Superincumbent hydrophobicity conditioner has partly been discussed this class oil.Suitable water component comprises hydrophobic conditioner discussed above.Preferred emulsion form comprises the emulsion of water-in-oil emulsion, water-in-silicone emulsion and other reverse.In addition, preferred emulsions also contains hydrophilic conditioning agent, as glycerol, obtains oil bag glycerol emulsion thus.

It is about 10% that the useful component of the treatment of emulsion form also preferably comprises about 1%-, and the emulsifying agent of 2%-about 5% more preferably from about is to treat the weight of useful component.Emulsifying agent can be nonionic, anionic property or cationic.Examples of suitable emulsifiers is disclosed in, for example the people's such as Dickert of promulgation on August 28th, 1973 United States Patent (USP) 3,755,560; The people's such as Dixon of nineteen eighty-three December promulgation on the 20th United States Patent (USP) 4,421,769; With McCutcheon ' s Detergents and Emulsifiers, NorthAmerican Edition, p.317-324 (1986).The useful component of the treatment of emulsion form also can contain defoamer, minimizes to make foam when being applied to skin.Defoamer comprises other material of high-molecular weight polysiloxanes and such use known in this field.

Treating useful component can also be microemulsion (microemulsion) form." microemulsion " used herein is meant by amphiphile, amphiphilic molecule, surfactant, the thermodynamically stable mixture of two kinds of stable immiscible solvents (a kind of is nonpolar, and another kind is polar).Preferred microemulsion comprises water-in-oil microemulsion.

The structure conditioner

Treat useful component and can comprise structure conditioner (structured conditioning agent).Suitable structure conditioner includes but not limited to vesicle structure (vesicular structure) for example ceramide, liposome etc.

In another embodiment, the treatment benefit materials of treatment beneficiating ingredient is included in the coacervate formation compositions.Coacervate formation compositions can preferably comprise the skin of cationic polymer, anion surfactant and described polymer and surfactant can accept carrier.Cationic polymer can be selected from natural main chain quaternary ammonium polymer, synthetic main chain quaternary ammonium polymer, natural main chain amphoteric polymer, synthetic main chain amphoteric polymer and their combination.

Cationic polymer more preferably is selected from following polymers: be selected from following natural main chain quaternary ammonium polymer: polyquaternary amine (polyquaternium)-4, Onamer M 0, polyquaternary amine-24, PG-hydroxyethyl-cellulose alkyl-dimethyl ammonium chloride, Rhaball Gum CG-M 8M, hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chloride and their combination; Be selected from following synthetic main chain quaternary ammonium polymer: polyquaternary amine-2, polyquaternary amine-6, polyquaternary amine-7, Onamer M 1, Onamer M 6, Onamer M 7, Onamer M 8, polyquaternary amine-28, polyquaternary amine-32, polyquaternary amine-37, polyquaternary amine-43, polyquaternary amine-44, polyquaternary amine-46, polyisobutylene acylamino-oxypropyl trimethyl ammonium chloride, acrylamido oxypropyl trimethyl ammonium chloride/acrylamide copolymer and their compositions; Be selected from following natural main chain amphoteric polymer: chitosan, quaternized albumen, hydrolyzed protein and their combination; Be selected from following synthetic main chain amphoteric polymer: polyquaternary amine-22, polyquaternary amine-39, polyquaternary amine-47, adipic acid/dimethylamino hydroxypropyl diethylenetriamines copolymer, polyvinylpyrrolidone/dimethyl aminoethyl methacrylate ester copolymer, caprolactam/polyvinylpyrrolidone/dimethyl aminoethyl methacrylate ester copolymer, caprolactam/polyvinylpyrrolidone/dimethylaminopropyl MAAm terpolymer, polyvinylpyrrolidone/dimethylaminopropyl MAAm copolymer, polyamine and their combination; And above-mentioned combination.Even preferred situation is that cationic polymer is synthetic main chain amphoteric polymer.Also more preferably, cationic polymer is a polyamine.

When cationic polymer was polyamine, the cationic polyamine polymer was preferably selected from polymine, polyvinylamine, polypropylene imines, polylysine (polylysine) and their combination.Cationic polyamine polymer even polymine more preferably.

Cationic polymer is in some embodiments of polyamine therein, and polyamine can be the polyamine of hydrophobic or hydrophilic modifying.In this case, the cationic polyamine polymer is selected from benzyl polyamine, ethoxylation polyamine, propoxylation polyamine, alkyl polyamine, amidatioon polyamine, esterification polyamine and their combination.Coacervate forms compositions and comprises and account for coacervate to form the about 0.01%-of composition weight about 20%, and more preferably from about 0.05%-is about 10%, most preferably from about the cationic polymer of 0.1%-about 5%.

There is multiple anion surfactant to be applicable to the present composition.The limiting examples of authorizing people's such as Laughlin United States Patent (USP) 2,929,678 anion surfactants on the 30th referring to for example December in 1975 comprises acyl-hydroxyethyl sulfonate (C for example ₁₂-C ₃₀), alkyl and alkyl ether sulfate and salt thereof, alkyl and alkyl ether phosphate and salt thereof, alkyl methyl taurine salt (C for example ₁₂-C ₃₀), the soap of alkanolamine phosphate and fatty acid (for example alkali metal salt such as sodium salt or potassium salt).Form compositions for coacervate, anion surfactant is preferably selected from sarcosinate, glutamate, Glu, alkyl sodium sulfate, alkylsurfuric acid ammonium, alkyl ether (alkyleth) sodium sulfate, alkyl ether ammonium sulfate, lauryl polyethenoxy ether sodium sulfate (laureth-n-sulfate), sodium laureth sulfate, isethionate, glycerol ether sulfonate, sulfosuccinate, an alkanolamine phosphate and their combination.Anion surfactant more preferably is selected from sodium N-lauroyl sarcosinate, lauroyl glutamate one sodium, alkyl sodium sulfate, alkylsurfuric acid ammonium, sodium alkylether sulphate, alkyl ether ammonium sulfate, an alkanolamine phosphate and their combination.

Suitable coacervate forms compositions and also describes in the following pending application: under names such as Schwartz, submit to U.S. Patent application 09/397,747, under names such as Heinrich, submit to 09/397,746; Under names such as Schwartz, submit to 09/397,712; Under names such as Heinrich, submit to 09/397,723; 09/397,722 of the following submission of names such as Venkitaraman; Described application was all submitted to JIUYUE in 1999 on the 16th.

In addition, coacervate forms the skin that compositions can comprise anionic polymer, cationic surfactant and described polymer and surfactant and can accept carrier.Described anionic polymer can be selected from: the natural or synthetic polymer (for example polystyrene, polybutene, polyurethane etc.) of the copolymer of acrylic acid polymer, polyacrylamide polymers, acrylic acid and acrylamide and other, natural derive natural gum and their combination.Suitable natural gum comprises alginate esters (for example propylene glycol alginate), pectin, chitosan (for example lactic acid chitosan) and modification natural gum (for example starch octenyl succinate) and their combination.Preferred situation is that anionic polymer is selected from acrylic acid polymer, polyacrylamide polymers, pectin, chitosan and their combination.Preferred articles for use of the present invention comprise and account for coacervate to form the about 0.01%-of composition weight about 20%, and more preferably from about 0.05%-is about 10%, most preferably from about the anionic polymer of 0.1%-about 5%.Those that suitable cationic surfactants includes but not limited to describe in this article.

The useful component of the treatment of articles for use of the present invention is suitable for treating on the surface or beauty treatment skin or hair by not only being deposited on conditioner but also with various active substances, and described active substance includes but not limited to anti-acne active substance, anti-wrinkle active substance, anti-microbial active matter, antifungus active substance, anti-inflammatory activity material, local anesthesia active substance, artificial tanned activating agent and promoter, antiviral agent, enzyme, sunscreen actives, antioxidant, decorticating agent and their combination.

Should be appreciated that the useful component of treatment can be included in the cleaning component of the present invention, perhaps vice versa, and they form the one-component with indistinguishable composition like this.

The saturated ratio assay method in surface

Articles for use of the present invention comprise the useful component of the treatment that is present in basically on the stromal surface." being present on the stromal surface basically " used herein is meant surperficial saturated ratio (surface to saturation ratio) greater than about 1.25, be preferably greater than about 1.5, more preferably greater than about 2.0, even more preferably greater than about 2.25, most preferably greater than 2.5.The saturated ratio in surface is the ratio of measuring of the benefit materials on stromal surface.These are measured and use the decay infrared Fourier spectrogrph acquisition of reflection (ATR) altogether, and its application is that the analytical chemistry those skilled in the art are well-known.

Conditioner is applied to many conventional methods on the substrate has all used the object of the invention method that is unsuitable for/or articles for use rheology.For example, a kind of method is that the substrate net is immersed in the liquid bath of conditioner, via the metering roll substrate net is pushed then, promptly so-called " soak and press from both sides " method, conditioner is applied on the whole substrate, and therefore can not effectively compositions be directly come on another surface under the transmission on substrate in use.In addition, many articles for use of the present invention are that the capacity conditioner is applied on the substrate, so that effective whole beneficial effect to be provided, by the weight of dry matrices, need the load ratio of about 100%-200% usually.Use the known appliance for personal care of these high capacity levels to avoid basically handling possibility owing to the cosmetic problem that these high capacities brought, this is to realize by loaded article being evenly distributed in the whole substrate that comprises substrate inside.The applicant is surprised to find, and the conditioner of high capacity can be remained on the surface of articles for use, has advantageously realized thus during use benefit materials directly being transferred to from substrate desiring to have improved attractive in appearance simultaneously by the present composition on the treatment surface.

Measuring process is as described below:

Instrument is provided with:Use BioRad FTS-7 spectrometer to collect infrared spectrum, this instrument is by being positioned at Cambridge, the Bio Rad Labs of MA, Digital Laboratory Division production.This mensuration generally comprises at 4cm ^-1Do 100 scannings under the resolution.Collect optical instrument and constitute, by being positioned at Fairfield, the Graseby Specac of CT, Inc. manufacturing by flat 60deg ZnSe atr crystal.Data use Grams 386 softwares to analyze 25 ℃ of collections, and this software is to be distributed by the Galactic Industries Corp. that is positioned at NH state Salem.Before mensuration, with suitable solvent cleaned crystal.Sample is placed on the atr crystal, and remain on constant 4 kilograms below the weight.

Experimental procedure:

(1) reference (background) spectrum of mensuration cleaning, air-dry cell.

(2) at first, select not apply the substrate of any benefit materials, selected substrate has constituted the outer surface of articles for use.With substrate place atr crystal above, outer surface is facing to crystal.At first substrate plane is placed on and measures on the platform.On substrate, place 4kg weight then.Measure spectrum (generally at 4cm ^-1Resolution is done 100 scannings).Substrate plays interior target effect, because the trap of substrate is identical separately.Determine main substrate peak and wave number.

(3) substrate with the articles for use that apply benefit materials repeats said determination.Determine the peak height of main benefit materials, promptly viewed summit, this summit is not corresponding with the substrate peak of above-mentioned observation, and perhaps corresponding to the substrate peak, but because the existence of conditioner shows maximum increase percentage ratio.Write down the wave number and the absorbance at several benefit materials peak.

(4) select the substrate peak from the spectrum of measuring in step 3, this peak appears under the wave number of step 2 mensuration, but does not correspond to one of main benefit materials peak of selecting in the step.Write down the absorbance of the absorption spectrum of selected wave number nuclear in step 3.

(5) calculate the ratio of the peak height of each benefit materials of in step 3, measuring and the substrate peak height of in step 4, measuring.The highest number of group is represented the surperficial saturated ratio of articles for use.

Be some examples below:

Substrate *	Substrate peak and peak High	? Conditioner	? The conditioner peak height	? Ratio
					Bat (the thermal mixture of polyester and 70% PET/PE, two component fibres)	0.0865 (the C=O peak is at 1710cm -1)	(the C-O peak is at 1030cm for glycerol -1)	??0.181	??2.09
Bat (the thermal mixture of polyester and 70% PET/PE, two component fibres)	0.0865 (the C=O peak is at 1710cm -1)	(the C-H peak is at 2923cm for hydrocarbon -1)	??0.160	??1.85
					70% staple fibre/30% polyester that water tangles	0.0333 (the C=O peak is at 1710cm -1)	(the C-O peak is at 1030cm for glycerol -1)	??0.0684	??2.05

^*The substrate of these types is easy to obtain, for example can be available from PGI Nonwovens, Benson, NC.

The moisture-holding capacity assay method

As mentioned above, articles for use of the present invention are " doing basically "." doing basically " used herein is meant that the moisture-holding capacity of articles for use of the present invention is lower than about 0.95gms, preferably be lower than about 0.75gms, more preferably less than about 0.5gms, even more preferably less than about 0.25gms, also, most preferably be lower than about 0.1gms more preferably less than about 0.15gms.The index of dry sensation that felt, opposite with the sensation of " humidity " cleaning piece when the moisture-holding capacity person of being to use contacts articles for use of the present invention.

In order to measure the moisture-holding capacity of the disposable articles for use based on substrate of articles for use of the present invention and other, need following apparatus and material.

The Bounty white paper towels	Procter﹠Gamble SKU 37,000 63037 basis weights=42.14gsm
		Balance	Be accurate to 0.0g
Lexan	0.5 " thickness covers sample fully to being enough to greatly, and heavy 1000g
		Weight	2000g counterweight or equal the counterweight combination of 2000g

2 napkins of weighing separately, and write down each weight.A slice napkin is placed on smooth surface (wasteful as on the laboratory table).With the articles for use sample be placed on napkin above.With other napkin be placed on the articles for use sample above.Place the 2000g counterweight above the sandwich style articles for use sample at this after placing Lexan then.Wait for 1 minute.After 1 minute, remove counterweight and Lexan.Weigh above and following napkin, and the record weight.

Deduct initial napkin weight by initial weight and calculate moisture-holding capacity top and following napkin (after 1 minute).Will be by weight difference addition top and that following napkin is obtained.What suppose test is a plurality of articles for use, with total weight difference on average to obtain moisture-holding capacity.

Compound articles for use embodiment (Multiple Article Embodiment)

Articles for use of the present invention are packing separately, perhaps with the beneficial effect that is suitable for providing independently, main articles for use do not provide for example improve looks, the additional articles for use of treatment, function etc. pack, to form the personal nursing kit utility.The additional articles for use that the present invention nurses kit utility preferably comprise water-insoluble substrate, and this substrate comprises at least one layer and contains the cleaning component of lathering surfactant or be deposited on or the useful component of treatment in additional articles for use hypothallus of infiltrating.

Except treatment or beauty treatment beneficial effect, the additional articles for use of the present invention can also have the function beneficial effect, perhaps have the function beneficial effect and come replacement therapy or beauty treatment beneficial effect.For example, additional articles for use can be used as and are suitable for helping dry apparatus that water is removed from the skin of finishing shower or bathing or hair.

Multicell embodiment (Multiple Chambered Embodiment)

Articles for use of the present invention can also comprise one or more chambers.Such chamber or compartment are realized to limit the closed area by hypothallus is connected to each other at different parts (for example combination).These chambers can be used for for example that different articles for use components is separate, and the cleaning component and the conditioner that for example will contain surfactant are separated.The articles for use component of the separation of treatment or beauty treatment or cleaning beneficial effect is provided, can from the chamber, discharges by different approaches.Delivery pathways includes but not limited to solubilising, emulsifying, mechanical transfer, pierces through, explosion, outburst, pressing cavity or peel off from the hypothallus of forming a part of chamber equably.

Optional components

Articles for use of the present invention can contain multiple other component, for example are usually used in given type articles for use, and do not change the component of beneficial effect of the present invention.These optional components should be suitable for being administered to application on human skin and hair, that is to say that in the time of in being included in articles for use of the present invention, they are suitable for contacting with application on human skin, in rational doctor and preparation teacher determination range, can not cause unsuitable toxicity, incompatibility, unstability, allergy etc.CTFA Cosmetic Ingredient Handbook, Second Edition (1992) have described multiple nonlimiting cosmetic and the drug component that is usually used in skin nursing industry, and they are applicable in the articles for use of the present invention.Other example of these group categories comprises: enzyme, abrasive, decorticating agent, absorbent, the beauty treatment component is spice for example, pigment, coloring agent/colorant, quintessence oil, the skin feel agent, (Oleum Caryophylli for example such as astringent, menthol, Camphora, Eucalyptus oil, acetaminol, menthyl lactate, the Hamamelis virginiana distillation), anti-acne agents (resorcinol for example, sulfur, salicylic acid, erythromycin, zinc etc.), anti-caking agent, defoamer, other antimicrobial (for example butyl carbamic acid iodine propyl ester), antioxidant, binding agent, bio-additive, buffer agent, filler, chelating agen, chemical addition agent, coloring agent, the cosmetic astringent, the cosmetic Biocide, denaturant, the medicine astringent, the external application analgesic agent, film former or material for example improve the polymer (for example eicosylene and vinylpyrrolidone copolymers) of compositions film property and solidity (substantivity), wetting agent, opacifying agent, the pH regulator agent, propellant, Reducing agent, chelating agen, Porcelana Skin Bleaching Agent Porcelana (or brightener) (hydroquinone for example, kojic acid, ascorbic acid, anti-bad blood acyl magnesium phosphate, anti-bad blood acyl glycosamine), skin is consoled agent and/or consolidant (for example pantothenylol and derivant (for example ethyl pantothenylol), Aloe vulgaris (aloe vera), pantothenic acid and derivant thereof, allantoin, bisabolol and glycyrrhizic acid dipotassium), skin treatment agents, comprise prevention, postpone, suppress and/or reverse the material (for example 'alpha '-hydroxy acids for example lactic acid and glycolic acid and beta-hydroxy acid salicylic acid for example) of wrinkle of skin, thickening agent, hydrocolloid, particularly zeolite, and vitamin and derivant thereof (tocopherol for example, tocopherol acetate, beta-carotene, tretinoin, retinol, retinoid, retinyl palmitate, nicotinic acid, nicotiamide etc.).Articles for use of the present invention can comprise carrier component, for example known in the art those.Such carrier can comprise one or more compatible liquid or solid filling diluent or excipient that are suitable for being administered to skin or hair.

Articles for use of the present invention can be chosen wantonly and comprise one or more these optional component.Preferably articles for use are chosen the useful component of treatment that contains safe and effective amount wantonly, and this component comprises the treatment benefit materials that is selected from: element-vitamine compound, skin-care agent (skin treating agent), anti-acne active substance, anti-wrinkle active substance, anti-skin atrophy actives matter, anti-inflammatory activity material, local anesthetic, artificial tanned activating agent and promoter, anti-microbial active matter, antifungus active substance, antiviral agent, enzyme, sunscreen actives, antioxidant, decorticating agent and their combination.The amount of " safe and effective amount " used herein expression chemical compound or component is enough to produce significantly positivity effect or benefit, this amount is enough low again and prevent to produce serious adverse (for example unsuitable toxicity or allergy) simultaneously, promptly in rational medical determination range, this amount can provide suitable benefited dangerous ratio.

Can be used for optional components of the present invention can sort out by their treatment or its model of action of beauty treatment beneficial effect or deduction.Yet should be appreciated that can be used for optional components of the present invention can provide more than one treatment or beauty treatment beneficial effect in some cases or work via more than one model of action.Therefore, the classification of this paper is not for component is restricted on the listed application-specific just for convenience.And work as where applicable, the officinal salt of component also can be used for the present invention.

Anionic polymer

Articles for use of the present invention can be chosen wantonly and comprise anionic polymer.Suitable anionic polymer can be selected from: the copolymer of acrylic acid polymer, polyacrylamide polymers, acrylic acid and acrylamide and other natural or synthetic polymer (for example polystyrene, polybutene, polyurethane etc.), natural deutero-natural gum and their combination.Suitable natural gum comprises alginate esters (for example propylene glycol alginate), pectin, chitosan (for example lactic acid chitosan) and modification natural gum (for example starch octenyl succinate) and their combination.

Element-vitamine compound

Articles for use of the present invention can comprise element-vitamine compound, precursor and derivant thereof.These element-vitamine compounds can be natural or synthesized forms.The suitable vitamins chemical compound includes but not limited to vitamin A (beta-carotene for example, tretinoin, retinol, retinoid, retinyl palmitate, Vitamin A propionate etc.), vitamin B (nicotinic acid for example, nicotiamide, riboflavin, pantothenic acid etc.), vitamin C (for example ascorbic acid etc.), vitamin D (ergosterol for example, vitamin D2, cholecalciferol etc.), vitamin E (for example tocopherol acetate etc.) and vitamin K (phytonadione for example, menadione, phthiocol etc.) chemical compound.

Particularly, articles for use of the present invention can comprise the vitamin B of safe and effective amount ₃Chemical compound.Of the unsettled U. S. application 08/834,010 (corresponding to international publication WO97/39733A1) (this patent application is introduced the present invention in full with for referencial use) submitting on April 11st, 1997 in promulgation on October 30th, 1997, vitamin B ₃Chemical compound is specially adapted to regulate skin.。The present invention treats component, and preferably to comprise about 0.01%-about 50%, and more preferably from about 0.1%-is about 10%, even more preferably from about 0.5%-is about 10%, and also more preferably from about 1%-is about 5%, most preferably from about the vitamin B of 2%-about 5% ₃Chemical compound.

" vitamin B used herein ₃Chemical compound " be meant chemical compound with following formula:

Wherein R is-CONH ₂(being nicotiamide) ,-COOH (being nicotinic acid) or-CH ₂OH (being nicotinyl alcohol); And derivant; Salt with any aforesaid compound.

Aforementioned vitamin B ₃The example of the derivant of chemical compound comprises nicotinate, comprises nicotinyl alcohol esters, nicotinic acid N-oxide and the nicotinoyl amine n-oxide of non-vasodilation nicotinate, cigarette base aminoacid, carboxylic acid.

Suitable vitamins B ₃Examples for compounds is well-known in the art, and can be obtained by a plurality of commercial source, for example from the Sigma Chemical Company (St.Louis, MO); ICNBiomedicals, (Irvin, CA) (Milwaukee WI) buys Inc. with Aldrich Chemical Company.

Element-vitamine compound can be used as pure basically material and uses, perhaps as using from the extract that natural (for example plant) source obtains by suitable physics and/or Chemical Decomposition means.

Skin-care agent

Articles for use of the present invention can comprise one or more skin-care agents.The suitable skin nursing agent comprises the material that can effectively prevent, postpone, suppress and/or reverse wrinkle of skin.The example of suitable skin nursing agent includes but not limited to 'alpha '-hydroxy acids for example lactic acid and glycolic acid, and beta-hydroxy acid salicylic acid for example.

The anti-acne active substance

The example that can be used for the anti-acne active substance of articles for use of the present invention includes but not limited to for example for example 5-MEXORYL SAM and resorcinol of salicylic acid (oxybenzoic acid), salicyclic acid derivatives of keratolytic; Retinoid is tretinoin and derivant (for example cis and trans) thereof for example; The D of sulfur-bearing and L aminoacid and derivant and salt, particularly its N-acetyl derivative, preferred examples are N-acetyl group-L-cysteine; Thioctic acid; Antibiotic and antimicrobial be benzoyl peroxide, Octopirox, tetracycline, 2 for example, 4,4 '-three chloro-2 '-hydroxy diphenyl ether, 3,4,4 '-neko, Azelaic Acid and derivant, phenyl phenol, phenoxypropanol, phenoxy group isopropyl alcohol, ethyl acetate, clindamycin (clindamycin) and meclocycline (meclocycline); Sebostats is flavonoid for example; And bile salts for example sulphuric acid scymnol ester and derivant, dexycholate and cholate.

Anti-wrinkle and anti-skin atrophy actives matter

Can be used for the anti-wrinkle of articles for use of the present invention and the example of anti-skin atrophy actives matter and include but not limited to tretinoin and derivant (for example cis and trans) thereof; Retinol, retinyl ester, nicotiamide, salicylic acid and derivant thereof; The D of sulfur-bearing and L aminoacid and derivant and salt, particularly its N-acetyl derivative, preferred examples are N-acetyl group-L-cysteine; Mercaptan, for example ethyl mercaptan; Hydroxy acid, phytic acid, thioctic acid; Lysophosphatidic acid and decorticating agent (for example phenol etc.).

Non-steroid class anti-inflammatory activity material (NSAIDS)

The example that can be used for the NSAIDS of articles for use of the present invention includes but not limited to the activating agent of following kind: propanoic derivatives, acetogenin, fenamic acid derivatives, biphenylcarboxylic acid derivatives and oxicams.All these NSAIDS describe in the people's such as Sunshine that are promulgation on January 15th, 1991 the United States Patent (USP) 4,985,459 fully.This full patent texts is introduced the present invention with for referencial use.The example of spendable NSAIDS comprises aspirin, ibuprofen, naproxen, Benoxaprofen, flurbiprofen, fenoprofen, fenbufen, ketoprofen, Indoprofen, pirprofen, Carprofen, oxaprozine, pranoprofen, miroprofen, benzene evil sulfur propanoic acid, suprofen (suprofen), alminoprofen, tiaprofenic acid (tiaprofenicacid), flurbiprofen and bucloxic acid (bucloxic acid).Also can use steroidal antiinflammatory drugs, comprise hydrocortisone etc.

Local anesthetic

The example that can be used for the local anaesthesia medicine of articles for use of the present invention includes but not limited to benzocaine, lignocaine, bupivacaine, chloroprocaine, cinchocaine (dibucaine), etidocaine (etidocaine), mepivacaine, tetracaine, dyclonine, hexylcaine hydrochloride, procaine, cocaine, ketamine, pramocaine (pramoxine), phenol and their officinal salt.

Artificial tanned activating agent and promoter

Can be used for the artificial tanned activating agent (artificial tanning active) of articles for use of the present invention and the example of promoter and include but not limited to dihydroxy acetone, tyrosine, tyrosine ester for example tyrosine ethyl ester and phosphoric acid DOPA.

Antimicrobial and antifungus active substance

Can be used for the antimicrobial of articles for use of the present invention and the example of antifungus active substance includes but not limited to: the beta-lactam medicine, quinolinones (quinolone) medicine, ciprofloxacin, norfloxacin, tetracycline, erythromycin, amikacin (amikacin), 2,4,4 '-three chloro-2 '-hydroxy diphenyl ether, 3,4,4 '-neko, phenyl phenol, phenoxypropanol, the phenoxy group isopropyl alcohol, doxycycline, capreomycin, chlorhexidine, duomycin, oxytetracycline, clindamycin, ethambutol, esomedina (hexamidine isethionate), metronidazole, penta oxygen benzene carbon amidine (pentamidine), gentamycin, kanamycin, lineomycin, metacycline (methacycline), hexamethylenamine, minocycline (minocycline), neomycin, netilmicin, paromomycin, streptomycin, tobramycin, miconazole, quadracycline, erythromycin, erythromycin zinc, erythromycin propionate lauryl sulfate, erythromycin octadecanoate, amikacin sulfate, doxycycline hydrochloride, capreomycin sulfate Capastat sulfate, chlorhexidine gluconate, Chlorhexidine hydrochloride, chlortetracycline hydrochloride, tetramycin hydrochloride, Clindamycin Hydrochloride, ebutol, the hydrochloric acid metronidazole, hydrochloric acid penta oxygen benzene carbon amidine, gentamycin sulfate, kanamycin sulfate, hydrochloric acid lineomycin, metacyclini chloridum, methenamine hippu, hexamine mandelate, minocycline hydrochloride, polygynax, netilmicin sulfate, paromomycin sulfate, streptomycin sulfate, tobramycin sulfate, the hydrochloric acid miconazole, amantadine hydrochloride (amanfadine), PK-Merz (Merz), Octopirox, parachlorometaxylenol, nystatin, tolnaftate (tolnaftate), sulfur oxy picolinate (zinc pyrithione) and clotrimazole.

Antiviral agent

Articles for use of the present invention can also comprise one or more antiviral agent.Suitable antiviral agent includes but not limited to slaine (for example silver nitrate, copper sulfate, iron chloride etc.) and organic acid (for example malic acid, salicylic acid, succinic acid, benzoic acid etc.).The compositions that contains in addition suitable antiviral agent particularly is included in those that describe in the following unsettled patent application: U.S. Patent application 09/421,084 people such as () Beerse; 09/421,131 (people such as Biedermann); 09/420,646 (people such as Morgan); 09/421,179 (people such as Page), these applications are all submitted on October 19th, 1999.

Enzyme

Articles for use of the present invention can be chosen wantonly and comprise one or more enzymes.Such enzyme preferably skin is acceptable.Suitable enzyme includes but not limited to keratinase, protease, amylase, subtilisin etc.

Sunscreen actives

The present invention also can use sunscreen actives.Multiple sunscreen has been described: in the people's such as Haffey of on February 11st, 1992 promulgation United States Patent (USP) 5,087,445 in the following document; United States Patent (USP) 5,073,372 the people such as Turner of December in 1991 promulgation on the 17th; United States Patent (USP) 5,073,371 the people such as Turner of December in 1991 promulgation on the 17th; And people such as Segarin Cosmetics Science and Technology, VIII chapter, the 189th page of later part.All these documents are all introduced the present invention with for referencial use in full.The limiting examples that can be used for the sunscreen in the present composition is selected from p-methoxycinnamic acid 2-ethyl hexyl ester, N, N-dimethyl para-amino benzoic acid 2-ethyl hexyl ester, para-amino benzoic acid, 2-Phenylbenzimidazole-5-sulfonic acid, octocrylene, oxybenzone, high menthol salicylate, ethylhexyl salicylate, 4,4 '-methoxyl group- Uncle-butyl dibenzoyl methane, 4-isopropyl diphenyl formoxyl methane, 3-benzylidene camphor, 3-(4-methyl benzal) Camphora, titanium dioxide, zinc oxide, silicon dioxide (silica), ferrum oxide and their mixture.Other spendable sunscreen is the United States Patent (USP) 4,937,370 in promulgation on June 26 nineteen ninety of those disclosed in following patent: Sabatelli; People's such as Sabatelli United States Patent (USP) 4,999,186 in promulgation on March 12nd, 1991.These two pieces of patents are all introduced the present invention with for referencial use in full.The example of especially preferred these sunscreen is selected from: 2; the 4-N of 4-dihydroxy benaophenonel; the 4-N of N-(2-ethylhexyl) methylamino benzoate, 4-hydroxy benzophenone acyl group methane; the 4-N of N-(2-ethylhexyl) methylamino benzoate, 2-hydroxyl-4-(2-hydroxyl-oxethyl) benzophenone; the 4-N of N-(2-ethylhexyl) methylamino benzoate, 4-(2-hydroxyl-oxethyl) dibenzoyl methane, N-(2-ethylhexyl) methylamino benzoate and their mixture.The accurate consumption of spendable sunscreen will depend on selected sunscreen and required sun protection factor (SPF) and determine.SPF is that the commonly used of photoprotection of the anti-erythema of sunscreen measured.Referring to Federal Register, Vol.43, No.166, pp.38206-38269, on August 25th, 1978.The document is introduced the present invention in full with for referencial use.

Hydrocolloid

Articles for use of the present invention also can be chosen wantonly and comprise hydrocolloid (hydrocolloid).Hydrocolloid is well-known in the art, and helps to prolong the service life that is included in the surfactant in the cleaning component of the present invention.These articles for use can be kept at least one complete drenching or the shower process like this.Suitable hydrocolloid includes but not limited to xanthan gum, carboxymethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, methylcellulose and ethyl cellulose, natural gum, gudras guar gum, locust beam gum, native starch, deionization starch (for example starch octenyl succinate) etc.

The heat release zeolite

Articles for use of the present invention also can be chosen other chemical compound that comprises zeolite and play exothermic reaction when mixing with water wantonly.

The structure conditioner

Articles for use of the present invention can be chosen wantonly and comprise the structure conditioner.Suitable structure conditioner includes but not limited to vesicle structure for example ceramide, liposome etc.

Hydrogel forms the polymerization gellant

In some embodiment of the present invention, articles for use can be chosen wantonly and comprise by polymerization gellant that forms hydrogel and aqueous gel that water forms, i.e. " hydrogel ".More particularly, hydrogel is included in the cleaning component of articles for use or treats in the useful component.When containing hydrogel, articles for use of the present invention preferably comprise and account for the about 0.1%-of water-insoluble substrate weight about 100%, more preferably from about 3%-is about 50%, the polymerization gellant of the formation hydrogel of 5%-about 35% most preferably from about, and wherein said weight is meant the dry weight of the polymerization gellant that forms hydrogel.

The polymerization gellant of formation hydrogel of the present invention generally is by water solublity or by the hydrolysis partial cross-linked at least polymer that water miscible polymerisable unsaturated acidiferous monomer makes that becomes.These gels comprise the monoene unsaturated compound with a hydrophilic group, include but not limited to contain the alkene unsaturated acids and the anhydride of the two keys of at least one carbon-to-carbon alkene.For these monomers, water solublity is meant that at 25 ℃ of following monomers preferred at least 1.0% level is dissolved in the deionized water so that few 0.2%.

During polyreaction, aforesaid monomeric unit accounts for about 25 molar percentages-99.99 molar percentage of the polymerization gellant material (based on the weight of dry polymeric) of acidiferous monomer usually, 50 molar percentages-99.99 molar percentage more preferably from about is most preferably at least about 75 molar percentages.

The polymerization gellant of formation hydrogel of the present invention is partly crosslinked preferably to reach sufficiently high degree, so that resulting polymers shows the glass transition temperature (Tg) that is not less than 140 ℃.Therefore, term used herein " forms the polymerization gellant of hydrogel " and is meant the polymer that satisfies this parameter.The polymerization gellant that forms hydrogel preferably has and is not less than about 180 ℃, and does not more preferably have Tg before decomposing copolymer, about 300 ℃ or higher temperature.Tg can pass through differential scanning calorimetry (DSC), under 20.0 ℃/minute the rate of heat addition, measures with the sample of 5mg or less amount.On DSC heat heating curves, the starting point and the mid-point computation between terminal point that change with the hot-fluid corresponding to gamma transition are Tg.It is well-known in the art using DSC to measure Tg, and B.Cassel and M.P.DiVito are at " Use of DSC To Obtain Accurate Thermodynamic and Kinetic Data ", American Laboratory January 1994, among the pp 14-19 and B.Wunderlich exist Thermal Analysis,Academic Press, Inc. has put down in writing this method in 1990.

Form hydrogel polymeric material be characterized as high-absorbable, and can under its absorption or " gel " state, keep moisture.The polymerization gellant of preferred formation hydrogel of the present invention can absorb at least about 40g water (deionized)/g, preferably at least about 60g/g, more preferably at least about the 80g/g gellant.These numerical value that are called " absorbability " herein can be measured according to the method in above-mentioned absorbability " tea-bag " test.

The polymerization gellant of formation hydrogel of the present invention is normally partial cross-linked at least.Suitable cross-linking agent is well-known in the art, comprises that for example (1) has the chemical compound of at least two polymerizable double bonds; (2) have at least one polymerizable double bond and at least one can with the chemical compound of the functional group of acidiferous monomeric substance reaction; (3) have at least two can with the chemical compound of the functional group of acidiferous monomer substance reaction; (4) can form the polyvalent metal compounds of ionic cross-linked bond.

Cross-linking agent with at least two polymerizable double bonds comprises (i) two-or many-vinyl compound, for example divinylbenzene and divinyl toluene; (ii) undersaturated one-or two-or many-ester of many-carboxylic acid and polyhydric alcohol, as two of the polyhydric alcohol of ethylene glycol, trimethylolpropane, glycerol or polyoxygenated ethylidene glycol-or three-acrylate; (iii) two acryloyl group amide, as N, N-methylene two acryloyl group amide; The carbamate that (iv) can the monomer reaction by polyisocyanate and hydroxyl obtains; (v) two of polyhydric alcohol-or many-allyl ether; (vi) polycarboxylic two-or many-allyl ester, for example diallyl ester of the diallyl ester of phthalic acid, adipic acid etc.; (vii) unsaturated one-or the ester of one-allyl ester of many-carboxylic acid and polyhydric alcohol, for example acrylate of Polyethylene Glycol one allyl ether; (viii) two-or three-allyl amine.

Have at least one polymerizable double bond and at least one and can comprise N hydroxymethyl acrylamide, glycidyl acrylate etc. with the cross-linking agent of the functional group of acidiferous monomer substance reaction.Having at least two can comprise Biformyl, polyhydric alcohol with the cross-linking agent of the functional group of acidiferous monomer substance reaction, as ethylene glycol and glycerol; Polyamine is as Alkylenediamine (for example ethylenediamine), polyalkylene polyamine, polyepoxide, two-or polyglycidyl ether etc.The suitable polyvalent metal cross-linking agent that can form ionic cross-linked bond comprises and comprises oxide, hydroxide and the salt of weak acid (for example carbonate, acetate etc.) of alkaline-earth metal (for example calcium, magnesium) and zinc, for example calcium oxide and zinc diacetate.

Aforementioned polytype cross-linking agent write up is in the people's such as Masuda of promulgation on February 28th, 1978 United States Patent (USP) 4, the people's such as Allen of promulgation on August 29th, 076,663 and 1989 United States Patent (USP) 4,861, in 539, these two pieces of patents are all introduced the present invention with for referencial use in full.Preferred cross-linking agents comprises the unsaturated monobasic of polyhydric alcohol or two or polyester of polybasic carboxylic acid one allyl ester, bisacrylamide and two or triallylamine.The instantiation of especially preferred cross-linking agent comprises N, N '-methylene-bisacrylamide and trimethylolpropane triacrylate.

Cross-linking agent accounts for about 0.001 molar percentage-5 molar percentage that the gained hydrogel forms polymeric material usually.Cross-linking agent more generally accounts for about 0.01 molar percentage-3 molar percentage of the polymerization gellant of the used formation hydrogel of the present invention.

The polymerization gellant that forms hydrogel can the neutral form of its part use.For the object of the invention, when at least 25 molar percentages, the monomer that is used to form polymer of preferred at least 50 molar percentages is during by the neutral acidiferous monomer of alkali, can think that such material is that part is neutral.Suitable neutralization bases cation comprises for example amino alcohol (2-amino-2-methyl-1 for example, ammediol, diethanolamine and 2-amino-2-methyl-1-propanol of the ammonium of hydroxide (for example KOH, NaOH), ammonium, replacement of alkali metal and alkaline-earth metal and amine.All monomeric percentage ratios that contain the acid groups that is neutralized are referred to herein as " degree of neutralization ".Degree of neutralization preferably is no more than 98%.

The polymerization gellant that is applicable to formation hydrogel of the present invention is well-known in the art, and is described in for example following document: at the people's such as Masuda of on February 28th, 1978 promulgation United States Patent (USP) 4,076,663; United States Patent (USP) 4,062,817 at the Westerman of December in 1977 promulgation on the 13rd; United States Patent (USP) 4,286,082 the people such as Tsubakimoto of on August 25th, 1981 promulgation; At the people's such as Goldman of on October 29th, 1991 promulgation United States Patent (USP) 5,061,259, at the people's such as Brandt of promulgation on March 31st, 1987 United States Patent (USP) 4,654,039.These patents are all introduced the present invention with for referencial use in full.

The polymerization gellant that is applicable to formation hydrogel of the present invention also is described in the following patent: at the United States Patent (USP) 4,731,067 of the Le-Khac of on March 15th, 1988 promulgation, United States Patent (USP) 4,743,244 at the Le-Khac of on May 10th, 1988 promulgation, United States Patent (USP) 4,813,945 at the Le-Khac of on March 21st, 1989 promulgation, United States Patent (USP) 4,880,868 at the Le-Khac of on November 14th, 1989 promulgation, United States Patent (USP) 4 at the Le-Khac of January 9 nineteen ninety promulgation, 892,533, at the United States Patent (USP) 5 of the Le-Khac of on June 25th, 1991 promulgation, 026,784, at the United States Patent (USP) 5,079 of the Le-Khac of on January 7th, 1992 promulgation, 306, United States Patent (USP) 5,151,465 at the Le-Khac of JIUYUE in 1992 promulgation on the 29th, Allen in promulgation on August 29th, 1989, the United States Patent (USP) 4,861,539 of Farrer and Flesher, Allen in promulgation on October 9 nineteen ninety, the United States Patent (USP) 4,962,172 of Farrer and Flesher.These patents are all introduced the present invention with for referencial use in full.

The polymerization gellant of the formation hydrogel of suitable particle form is available from Hoechst CelaneseCorporation, Portsmouth, VA, USA (Sanwet ^TMSuperabsorbent Polymers) Nippon Shokubai, Japan (Aqualic ^TM, L-75 for example, L-76) and Dow Chemical Company, Midland, MI, USA (Dry Tech ^TM).

The polymerization gellant of the formation hydrogel of fibers form is available from Camelot Technologies Inc., Leominster, MA, USA (Fibersorb ^TM, for example SA 7200H, SA 7200M, SA 7000L, SA 7000 and SA 7300).

Articles for use of the present invention also comprise other hydrophilic gelling agent.These comprise the above-mentioned other polymer that contains carboxylic acid, different is that they have the relatively low degree of cross linking, show thus and be lower than 140 ℃ Tg, also comprise various other water solublity or colloidal state water-soluble polymers, for example cellulose ether (as hydroxyethyl-cellulose, methylcellulose, hydroxypropyl methylcellulose), polyvinylpyrrolidone, polyvinyl alcohol, guar gum, hydroxypropyl cellulose guar gum and xanthan gum.In these hydrophilic gelling agent, preferably contain acid polymer, especially contain the polymer of carboxylic acid.Especially preferred is to comprise and those of the crosslinked acrylic acid water-soluble polymer of the poly alkenyl ether of polyhydric alcohol, and optional acrylate or the polyfunctional vinylidene monomer of comprising.

Be used for preferred copolymer of the present invention and be containing the polymer of monomer mixture of the alkene unsaturated carboxylic acid monomer of 95-99% weight, described alkene unsaturated carboxylic acid monomer is selected from acrylic acid, methacrylic acid and ethylacrylic acid; The acrylate of the following formula of about 3.5% weight of about 1-:

Wherein R is alkyl and the R that contains 10-30 carbon atom ₁Be hydrogen, methyl or ethyl; With the polymerisable crosslinked polyalkenyl polyethers that comprises the polyhydric alcohol of more than one alkenyl ether in each molecule of 0.1-0.6% weight, wherein the parent polyhydric alcohol comprises at least 3 carbon atoms and at least 3 hydroxyls.

These polymer preferably comprise the acrylic acid of about 97.9% weight of about 96-and the acrylate of about 3.5% weight of about 2.5-, and alkyl wherein comprises 12-22 carbon atom, R ₁Be methyl, acrylate most preferably is the methacrylic acid stearate.The amount of crosslinked polyalkenyl polyether monomer is preferably about 0.2-0.4% weight.Preferred crosslinked polyalkenyl polyether monomer is pi-allyl tetramethylolmethane, trimethylolpropane allyl ether or allyl sucrose.The people's such as Huang of promulgation on April 5th, 1985 United States Patent (USP) 4,509,949 has been described these polymer comprehensively.This patent is incorporated herein with for referencial use.

Being used for other preferred copolymer of the present invention is the polymer that comprises at least two kinds of monomer components.A kind of is the alkene unsaturated carboxylic acid monomer, and another kind is the polyalkenyl polyethers of polyhydric alcohol.If desired, also can there be other monomeric substance in the monomer mixture, even exists with the advantage ratio.

The first kind of monomer component that uses in the production of these carboxylic acid polyalcohols is the alkene unsaturated carboxylic acid that contains the two keys of at least one activatory carbon-to-carbon alkene and at least one carboxyl.Preferred carboxylic acid monomer is the acrylic acid with following general formula:

R wherein ²Be to be selected from following substituent group: hydrogen, halogen and cyano group (C=N), univalent alkyl, monovalence alkaryl and monovalence cyclic aliphatic alkyl.At this apoplexy due to endogenous wind, preferred acrylic acid, methacrylic acid and ethylacrylic acid.Another kind of useful carboxylic acid monomer is maleic anhydride or maleic acid.The consumption of acid is about 98.9% weight of about 95.5-.

The second kind of monomer composition that uses in the production of these carboxylic acid polyalcohols is the polyalkenyl polyethers that per molecule has an above alkenyl ether, and for example the two keys of the alkene of Cun Zaiing are the alkenyls that link to each other with terminal methylene, CH ₂=C＜.

Can be present in other monomer in the polymer comprises and contains at least two terminal CH ₂＜multifunctional vinylidene monomer, comprise for example butadiene, isoprene, divinylbenzene, divinyl naphthalene, acrylic acid allyl ester etc.In the people's such as Brown of promulgation on July 2 nineteen fifty-seven the United States Patent (USP) 2,798,053 these polymer have been described comprehensively.The document is incorporated herein by reference.

The example that is used for polymers of carboxylic acid of the present invention comprises Carbomer 934, Carbomer 941, Carbomer 950, Carbomer 951, Carbomer 954, Carbomer 980, Carbomer 981, Carbomer 1342, acrylate/C ₁The 0-30 alkyl acrylate crosspolymer (can buy with Carbopol934, Carbopol 941, Carbopol 950, Carbopol 951, Carbopol 954, Carbopol 980, Carbopol 981, Carbopol 1342, and available from the Pemulen series of B.F.Goodrich).

Can be used for other polymers of carboxylic acid of the present invention and comprise acrylic acid sodium salt/acrylamide copolymer, sell by Hoechst Celanese Corporation with trade name Hostaceren PN73.What also comprise is the aquogel polymer of being sold by Lipo Chemicals Inc with trade name HYPAN hydrogel.These hydrogels comprise having various other vertical group, for example crystallization plicks of the nitrate of carboxyl, amide and amidino groups of connecing on the C-C main chain.Example comprises HYPAN SA 100 H, a kind of polymer powder available from Lipo Chemical.

The acidic group nertralizer of these polymer of being used to neutralize comprise previously described those.

Cleaning component

Articles for use of the present invention can randomly comprise cleaning component, and this component contains one or more surfactants in addition.The adjacent setting of the nonwoven layers of cleaning component and water-insoluble substrate.It is about 1,000% that articles for use of the present invention comprise about 10%-, and preferably about 50%-is about 600%, and the surfactant of 100%-about 250% more preferably from about is in the weight of water-insoluble substrate.In addition, articles for use of the present invention preferably comprise the surfactant at least about 1 gram, in the weight of water-insoluble substrate.Therefore, drying-free process, cleaning component just can be added in this substrate.

The surfactant of cleaning component is lathering surfactant preferably." lathering surfactant " used herein be meant when mix with water and mechanical agitation under generation foam or blistered surfactant.This class surfactant is preferred, because as the sign that cleans effectiveness, the foam that increases is important for consumer.In certain embodiments, the combination of surfactant or surfactant is gentle." gentleness " used herein is meant that surfactant and articles for use of the present invention demonstrate at least the skin mildness than common soap slab substrate milder, and common soap slab comprises natural soap and synthetic surfactant (for example Lever 2000  and Zes  t usually simultaneously.Mensuration contains the mildness of the articles for use of surfactant, and perhaps on the contrary, irritating method is that carry out on the basis with the skin barrier failure test.In this test, surfactant is gentle more, and ruined skin barrier is just few more.By radiolabeled (tritium-labeled) water (3H-H ₂O) enter the destruction that relative quantity in the physiological buffer that holds in the diffuser casing is measured skin barrier by epiderm skin by testing liquid.This test is recorded in by T.J.Franz J.Invest. Dermatol., 1975,64, pp.190-195; And on June 16th, 1987 authorize in people's such as Small the United States Patent (USP) 4,673,525.These two pieces of documents are incorporated herein by reference.Also can use other test method of mensuration surfactant mildness known to a person of ordinary skill in the art.

Various lathering surfactant all can be used for the present invention, and they comprise and are selected from following those: anionic property lathering surfactant, nonionic lathering surfactant, cationic lathering surfactant, both sexes lathering surfactant and their mixture.

The anionic property lathering surfactant

The limiting examples that is used for the anionic property lathering surfactant of the present composition is disclosed in McCutcheon ' s that Allured Publishing Corporation publishes, Detergents and Emulsifiers, North American edition (1986); McCutcheon ' s, Functional Materials, NorthAmerican Edition (1992); And in the people's such as Laughlin of December in 1975 promulgation on the 30th the United States Patent (USP) 3,929,678.These documents are incorporated herein by reference.

Various anion surfactants all can be used for the present invention.The example of anionic property lathering surfactant comprises and is selected from following those: alkyl and alkyl ether sulfate; the sulphation monoglyceride; sulfonation alkene; alkylaryl sulfonates; uncle or secondary paraffin sulfonate; alkyl sulfo succinate; acyl taurine salt; acyl-hydroxyethyl sulfonate; alkyl glycerol ether sulfonate; the sulfonation methyl ester; alpha-sulfonated fatty acid; alkylphosphonic; acyl glutamate; acyl sarcosinates; one alkanolamine phosphate; alkyl sulfoacetate; acylated peptide; the alkyl ether carboxy acid salt; acyl-lactate; anionic fluorosurfactants and their mixture.The compositions of anion surfactant also can be used for the present invention effectively.

The anion surfactant that is used for cleaning component comprises alkyl and alkyl ether sulfate.These materials have formula R respectively ₁O-SO ₃M and R ₁(CH ₂H ₄O) x-O-SO ₃The structure of M, wherein R ₁Be the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, x is 1-10, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.Alkyl sulfate prepares by sulphation monohydric alcohol (having about 24 carbon atoms of about 8-) or other known sulphation technology with sulfur trioxide usually.Alkyl ether sulfate obtains the condensation product of oxirane and monohydric alcohol (having about 24 carbon atoms of about 8-) usually earlier, and then sulphation makes.These alcohol can be from fat, and for example Oleum Cocois or Adeps Bovis seu Bubali perhaps can be synthetic.The instantiation that can be used for the alkyl sulfate in the cleaning component is the vitriolic sodium of lauryl or myristyl, ammonium, potassium, magnesium or TEA salt.The example of spendable alkyl ether sulfate comprises the vitriolic ammonium of laureth-3, sodium, magnesium or TEA salt.

The another kind of anion surfactant that is fit to type is formula R ₁CO-O-CH ₂-C (OH) H-CH ₂-O-SO ₃The sulphation monoglyceride of M, wherein R ₁Be the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These materials form monoglyceride by glycerol and fatty acid (having about 24 carbon atoms of about 8-) reaction usually, make with this monoglyceride of sulfur trioxide sulphation subsequently.The example of sulphation monoglyceride is a Cortex cocois radicis monoglyceride sodium sulfate.

Other suitable anion surfactant comprises formula R ₁SO ₃The alkene sulfonate of M, wherein R ₁Be one-alkene, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine with about 24 carbon atoms of about 12-.These chemical compounds can be prepared as follows: with not compound SO 3 sulfonated alhpa olefin, the sultones hydrolysis that forms in making reaction then obtains neutralizing acid reactant mixture under the condition of corresponding hydroxyl paraffin sulfonate.The example of sulfonation alkene is C ₁₄/ C ₁₆The alpha-olefin sodium sulfonate.

Other suitable anion surfactant is formula R ₁-C ₆H ₄-SO ₃The linear alkyl benzene sulfonate of M, wherein R ₁Be the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These materials form by the alkylbenzene with SO 3 sulfonated linearity.The example of this analog anion surfactants is a dodecylbenzene sodium sulfonate.

Other anion surfactant that is applicable to this cleaning group phenol comprises formula R ₁SO ₃The uncle of M or secondary paraffin sulfonate, wherein R ₁Be the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These materials usually chlorine and ultraviolet in the presence of, form with the sulfur dioxide sulfonated alkane; Perhaps form by other known method of sulfonating.Sulfonation can occur in the secondary position or the uncle position of alkyl chain.The example that is used for paraffin sulfonate of the present invention is C ₁3-C ₁The alkali metal of 7 alkane sulfonic acid or ammonium salt.

Other suitable anion surfactant is an alkyl sulfo succinate, they comprise N-disodium octadecyl sulfosuccinate, lauryl disodium sulfosuccinate, N-(1,2-two carboxyethyls)-N-octadecyl 2-Sulfosuccinic acid four sodium, the diamyl ester of sodium sulfosuccinate, the dihexyl ester of sodium sulfosuccinate and the dioctyl ester of sodium sulfosuccinate.

Also can use taurate, be also referred to as 2-aminoethyl sulfonic acid based on taurine.The example of taurate comprises the N-alkyl taurine, as the product that makes by lauryl amine and sodium isethionate reaction.This product write up is in United States Patent (USP) 2,658, in 072.The document is incorporated herein by reference.Other example based on taurine comprises the acyl group taurine that forms by n-N-methyltaurine and fatty acid (having about 24 carbon atoms of about 8-) reaction.

Be applicable to that the another kind of anion surfactant in the cleaning component is an acyl-hydroxyethyl sulfonate.Acyl-hydroxyethyl sulfonate has formula R usually ₁CO-O-CH ₂CH ₂SO ₃The structure of M, wherein R ₁Be the alkyl with about 30 carbon atoms of about 10-of saturated or unsaturated, side chain or straight chain, and M is a cation.These materials form by the alkali metal salt reaction of fatty acid (having about 30 carbon atoms of about 8-) with hydroxyethylsulfonic acid. usually.The limiting examples of these acyl-hydroxyethyl sulfonates comprises Ammonium cocoyl isethionate, cocoyl hydroxyethyl sulfonate, lauroyl hydroxyethyl sulfonate and their mixture.

Other suitable anion surfactant is formula R ₁-OCH ₂-C (OH) H-CH ₂-SO ₃The alkyl glycerol ether sulfonate of M, wherein R ₁Be the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, and M is water-soluble cationic, as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These materials can or pass through other known method by chloropropylene oxide and sodium acid sulfite and aliphatic alcohol (having about 24 carbon atoms of about 8-) reaction and form.A kind of example is a cocos nucifera oil glyceryl ether sulfonic acid sodium.

Other suitable anion surfactant comprises formula R ₁-CH (SO ₄The alpha-sulfonated fatty acid of)-COOH and formula R1-CH (SO ₄)-CO-O-CH ₃Sulfonated formate, R wherein ₁It is the alkyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain.These materials can be by forming with SO 3 sulfonated fatty acid or alkyl methyl ester (having about 24 carbon atoms of about 8-) or other sulfonation technology.Example comprises sulfonated coco-nut oil fatty acid of α and lauryl methyl ester.

Other anionic species comprises phosphonate, for example an alkyl, dialkyl group and trialkyl phosphine hydrochlorate, and these phosphate form by the monohydric alcohol reaction with about 24 carbon atoms of about 8-of five phosphorous oxide and side chain or straight chain.These phosphate also can form by other known phosphorylation method.The example of such surfactant is one or the dilauryl Alendronate.

Other anionic species comprises corresponding to formula R ₁CO-N (COOH)-CH ₂CH ₂-CO ₂The acyl glutamate of M, wherein R ₁Be the alkyl or the alkenyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, and M is a water-soluble cationic.Its limiting examples comprises sodium lauroyl glutamate and cocoyl sodium glutamate.

Other anionic species comprises corresponding to formula R ₁CON (CH ₃)-CH ₂CH ₂-CO ₂The alkanoyl sarcosinate of M, wherein R ₁Be the alkyl or the alkenyl of about 20 carbon atoms of about 10-of saturated or unsaturated, side chain or straight chain, and M is a water-soluble cationic.Its limiting examples comprises sodium N-lauroyl sarcosinate, cocoyl sodium sarcosinate and lauroyl sarcosine ammonium.

Other anionic species comprises corresponding to formula R ₁-(OCH ₂CH ₂) x-OCH ₂-CO ₂The alkyl ether carboxy acid salt of M, wherein R ₁Be the alkyl or the alkenyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain, x is 1-10, and M is a water-soluble cationic.Its limiting examples comprises the laureth carboxylic acid sodium.

Other anionic species comprises corresponding to formula R1CO-[O-CH (CH3)-CO] acyl-lactate (lactylate) of x-CO2M; wherein R1 is the alkyl or the alkenyl of about 24 carbon atoms of about 8-of saturated or unsaturated, side chain or straight chain; x is 3, and M is a water-soluble cationic.Its limiting examples comprises the cocoyl sodium lactate.

Other anionic species comprises carboxylate, and its limiting examples comprises lauroyl carboxylic acid sodium, cocoyl carboxylic acid sodium and lauroyl carboxylic acid ammonium.Also can use anionic fluorosurfactants.

Other anionic species comprises the natural soap that is obtained by vegetable oil and/or Animal fat and oily saponification, and the example comprises sodium laurate, Sodium myristate, sodium palmitate, stearate, tallow acid salt, cocos nucifera oil hydrochlorate.

Any counter cation M all can be used for anion surfactant.Counter cation is preferably selected from sodium, potassium, ammonium, monoethanolamine, diethanolamine and triethanolamine.Counter cation is more preferably ammonium.

The nonionic lathering surfactant

The limiting examples that is used for the nonionic lathering surfactant of the present composition is disclosed in the McCutcheon ' s that is published by influential Publishing Corporation, Detergents and Emulsifiers, North American edition (1986); And McCutcheon ' s, Functional Materials, among the North American Edition (1992).These two pieces of documents are incorporated herein by reference.

Being used for nonionic lathering surfactant of the present invention comprises and is selected from following those: alkyl (Portugal) glucosides class, alkyl many (Portugal) glucosides class, polyhydroxy fatty acid amide, alkoxy fatty acid ester, sucrose ester, amine oxide and their mixture.

Alkyl (Portugal) glucosides and alkyl many (Portugal) glucosides class can be used for the present invention, and they are defined as long-chain alcohol, for example C at large _8-30The condensation product of alcohol and sugar, starch or sugar or starch polymer, i.e. glucosides or polysaccharide glycoside.These chemical compounds can be used formula (S) _n-O-R represents that wherein S is a sugar moieties, as glucose, fructose, mannose and galactose; N is the integer of about 1-about 1000, and R is C _8-30Alkyl.Can comprise decanol, spermol, stearyl alcohol, lauryl alcohol, myristyl alcohol, oleyl alcohol etc. by the example of the long-chain alcohol of its alkyl of deriving.The preferred embodiment of these surfactants comprises that wherein S is a glucose moiety, and R is C _8-20Alkyl, and n is those of integer of about 1-about 9.The ready-made commercial examples of this class surfactant comprises decyl many (Portugal) glucosides (available from APG 325 CS of Henkel) and lauryl many (Portugal) glucosides (available from APG 600CS and 625 CS of Henkel).Other is the sucrose ester surfactant usefully, as sucrose cocos nucifera oil acid esters and Surfhope SE Cosme C 1216.

Other useful ionic surfactant pack is drawn together polyhydroxy fatty acid amide, its more specifically example comprise glucamide corresponding to following formula:

R wherein ¹Be H, C ₁-C ₄Alkyl, 2-ethoxy, 2-hydroxyl-propyl group, preferred C ₁-C ₄Alkyl, more preferably methyl or ethyl, most preferable; R ²Be C ₅-C ₃₁Alkyl or alkenyl, preferred C ₇-C ₁₉Alkyl or alkenyl, more preferably C ₉-C ₁₇Alkyl or alkenyl, most preferably C ₁₁-C ₁₅Alkyl or alkenyl; And Z is the polyhydroxy alkyl part with the straight-chain hydrocarbons that contains at least 3 hydroxyls that directly link to each other with chain, or its alkoxy derivative (preferred ethoxylation or propenoxylated).Z preferably is selected from the part of following sugar: glucose, fructose, maltose, lactose, galactose, mannose, xylose and their mixture.Corresponding to the particularly preferred surfactant of following formula structure is cocos nucifera oil alkyl N-methyl glucosamine amide (i.e. R wherein ²The CO-part is derived by coco-nut oil fatty acid).The method for compositions that preparation contains polyhydroxy fatty acid amide is disclosed: the Thomas Hedley﹠amp that publishes February 18 nineteen fifty-nine for example; Co., the G.B. patent specification 809,060 of Ltd.; The United States Patent (USP) 2,965,576 of the Wilson of nineteen sixty December promulgation on the 20th; The United States Patent (USP) 2,703,798 of the A.M.Schwartz of promulgation on March 8 nineteen fifty-five; United States Patent (USP) 1,985,424 with the Piggott of December in 1934 promulgation on the 25th.These documents are incorporated herein by reference.

The example of other non-ionic surface active agent comprises amine oxide.Amine oxide is corresponding to general formula R ₁R ₂R ₃N → O, wherein R ₁The alkyl, alkenyl or the monohydroxy alkyl that comprise about 18 carbon atoms of about 8-, about 10 ethylene oxides part of about 0-and about 1 the glyceryl part of about 0-; R ₂And R ₃Comprise about 3 carbon atoms of about 1-and about 1 hydroxyl of about 0-, for example methyl, ethyl, propyl group, ethoxy or hydroxypropyl.The semi-polar key of arrow ordinary representation in the formula.Be applicable to that amine oxide example of the present invention comprises dimethyl lauryl amine oxide, oil base two (2-ethoxy) amine oxide, dimethyloctylamine oxide, dimethyl-decyl amine oxide, dimethyl-myristyl amine oxide, 3,6,9-trioxa heptadecyl diethyl amine oxide, two (2-ethoxy)-myristyl amine oxides, 2-dodecyloxy ethyl dimethyl oxidation amine, 3-dodecyloxy-2-hydroxypropyl two (3-hydroxypropyl) amine oxide, dimethyl cetyl amine oxide.

The limiting examples of preferred nonionic is selected from C ₈-C ₁₄Glucamide, C ₈-C ₁₄Alkyl polyglucoside, sucrose cocos nucifera oil acid esters, Surfhope SE Cosme C 1216, lauryl amine oxide, coco group amine oxide and their mixture.

The cation lathering surfactant

The cation lathering surfactant also can be used in the articles for use of the present invention.Suitable cation lathering surfactant includes, but not limited to fatty amine, two fatty quaternary ammoniums, three fatty quaternary ammoniums, imidazoline father-in-law ammonium salt and their mixture.Suitable fatty amine comprises a quaternary ammonium alkyl, as the cetyl trimethylammonium bromide.Suitable quaternary ammonium is a dialkyl group acylamino-ethyl-hydroxyethyl methyl formate ammonium sulfate.But fatty amine is preferred.When the cation lathering surfactant is main lathering surfactant in the cleaning component, preferably use suds booster.Find that in addition non-ionic surface active agent especially can be united use with this cationoid lathering surfactant.

The both sexes lathering surfactant

Term used herein " both sexes lathering surfactant " also should comprise zwitterionic surfactant, and they are class materials that the professional preparation teacher of this area is known as amphoteric surfactant.

Various both sexes lathering surfactant can be used for the present composition.Especially can use those of those derivants that generally are defined as the secondary and tertiary amine of aliphatic series, preferred wherein nitrogen-atoms is a cation state, wherein aliphatic group can be straight or branched and one of them group comprise ionizable water soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.

The limiting examples that is used for the amphoteric surfactant of the present composition is disclosed in McCutcheon ' s that influential Publishing Corporation publishes, Detergents and Emulsifiers, North American edition (1986); And McCutcheon ' s, Functional Materials, among the NorthAmerican Edition (1992).These two pieces of documents are incorporated herein by reference.

The limiting examples of both sexes or zwitterionic surfactant is to be selected from following those: betanin, sulfobetaines, hydroxyl sulfo betaine, alkyl imino acetate, iminodiacetic alkanoate, amino-alkane hydrochlorate and its mixture.

The example of betanin comprises the senior alkyl betaines, as the coco dimethyl carboxymethyl betaine, the lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine (can Lonzaine 16SP title available from LonzaCorp.), lauryl two-(2-ethoxy) carboxymethyl betaine, oil base dimethyl γ-carboxylic CAB, lauryl two-(2-hydroxypropyl) α-carboxyethyl betanin, the coco dimethyl sulfopropyl betaine, lauryl dimethyl sulfo group ethyl betanin, lauryl two-(2-ethoxy) sulfopropyl betaine, amido betaines and acylamino-sulfobetaines (RCONH (CH wherein ₂) ₃Group links to each other with the nitrogen-atoms of lactams), oil-based betaine (can with both sexes Velvetex OLB-50 title available from Henkel) and cocoamidopropyl (can with Velvetex BK-35 and BA-35 available from Henkel).

The example of sulfobetaines and hydroxyl sulfo betaine comprises, for example cocos nucifera oil acylamino-propyl hydroxy sulfobetaines (can with Mirataine CBS available from Rhone-Poulenc).

Being preferred for of the present invention is the amphoteric surfactant of following formula:

R wherein ¹It is the alkyl with about 22 carbon atoms of about 9-unsubstituted, saturated or unsaturated, straight or branched.Preferred R ¹Have about 18 carbon atoms of about 11-; About 18 carbon atoms of 12-more preferably from about; Especially more preferably from about about 18 carbon atoms of 14-; M is the integer of 1-about 3, and more preferably from about 2-about 3, more preferably about 3; N is 0 or 1, preferably 1; R ²And R ³Be independently from each other unsubstituted or by the alkyl of about 3 carbon atoms of the monobasic 1-of having of hydroxyl, preferred R ²And R ³It is methyl; X is selected from CO ₂, SO ₃And SO ₄R ⁴Be selected from the alkyl with about 5 carbon atoms of 1-unsubstituted or monobasic, saturated or unsaturated, straight or branched by hydroxyl.When X is CO ₂The time, R ⁴Preferably has 1 or 3 carbon atom, more preferably 1 carbon atom.When X is SO ₃Or SO ₄The time, R ⁴Preferably have about 4 carbon atoms of about 2-, more preferably 3 carbon atoms.

Examples of amphoteric surfactants of the present invention comprises following compounds:

Cetyl dimethyl betaine (the CTFA name of this material is also referred to as cetyl betaine)

Cocoamidopropyl

Wherein R has about 13 carbon atoms of about 9-.

Cocos nucifera oil acylamino-propyl hydroxy sulfobetaines

Wherein R has about 13 carbon atoms of about 9-.

Other useful examples of amphoteric surfactants is the alkyl imino acetate, and the iminodiacetic alkanoate of following formula and amino-alkane hydrochlorate: RN[(CH ₂) _mCO ₂M] ₂And RNH (CH2) mCO ₂M, wherein m is 1-4, R is C ₈-C ₂₂Alkyl or alkenyl, and M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium.Also comprise imidazolium and ammonium derivative.The instantiation of suitable amphoteric surfactant comprises 3-lauryl-alanine sodium, 3-lauryl amino propane sulfonic acid sodium, N-senior alkyl aspartic acid, and for example United States Patent (USP) 2,438, those of instruction in 091.This full patent texts is incorporated herein by reference; And sell with " Miranol " trade name and be recorded in United States Patent (USP) 2,528, those articles for use in 378.This full patent texts is incorporated herein by reference.Other example of spendable amphoteric surfactant comprises two acid phosphates, as cocos nucifera oil acylamino-propyl group pg dimonium chloride phosphate (can with Monaquat PTC available from Mona Corp.).Other is the both sexes acetate usefully, for example lauric acid both sexes acetic acid disodium, lauric acid both sexes sodium acetate and their mixture.

Preferred lathering surfactant is selected from the anion lathering surfactant, and they are selected from lauroyl sarcosine ammonium, tridecyl ether sodium sulfate, sodium N-lauroyl sarcosinate, lauryl polyethenoxy ether sodium sulfate, sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, cocoyl hydroxyethylsulfonic acid. ammonium, cocoyl sodium isethionate, lauroyl sodium isethionate, cetyl sodium sulfate, a lauryl sodium phosphate, cocos nucifera oil glyceryl ether sulfonic acid sodium, C ₉-C ₂₂Soda soap and their combination; The nonionic lathering surfactant, they are selected from lauryl amine oxide, cocos nucifera oil amine oxide, decyl polydextrose, lauryl polydextrose, sucrose cocos nucifera oil acid esters, C _12-14Glucamide, their combination of Surfhope SE Cosme C 1216; The cation lathering surfactant, they are selected from fatty amine, two-fatty quaternary ammonium, three-fatty quaternary ammonium, imidazoles quaternary ammonium salt and their combination; The both sexes lathering surfactant, they are selected from: lauric acid both sexes oxalic acid disodium, lauric acid both sexes sodium acetate, cetyl dimethyl betaine, cocoamidopropyl, cocos nucifera oil acylamino-propyl hydroxy sulfobetaines and their combination.

Cationic surfactant

Cationic surfactant is divided into non-expansion type surfactant usually.But, just can be applicable in the articles for use of the present invention as long as they do not have a negative impact to the beneficial effect of articles for use of the present invention.

The limiting examples that is used for cationic surfactant of the present invention is disclosed in McCutcheon ' s that influential Publishing Corporation publishes, Detergents and Emulsifiers, NorthAmerican edition (1986); And McCutcheon ' s, Functional Materials, among the NorthAmerican Edition (1992).These two parts of documents are incorporated herein by reference.

The limiting examples that is used for cationic surfactant of the present invention comprises the kation alkyl ammonium salt of following formula:

R ₁R ₂R ₃R ₄N ⁺X ^-

R wherein ₁Be selected from alkyl, perhaps have the aromatics aryl or the alkaryl of about 18 carbon atoms of about 12-with about 18 carbon atoms of about 12-; R ₂, R ₃And R ₄Be independently from each other hydrogen, have the alkyl of about 18 carbon atoms of about 1-or have the aromatics aryl or the alkaryl of about 18 carbon atoms of about 12-; And X is selected from following anion: chloride ion, bromide ion, iodide ion, acetate, phosphate radical, nitrate anion, sulfate radical, methyl ester sulfonate radical, ethyl ester sulfonate radical, tosylate, lactate, citrate, glycol acid radical and their mixture.In addition, alkyl also can comprise ehter bond or hydroxyl or amino substituent group (for example alkyl can comprise Polyethylene Glycol and polypropylene glycol part).

More preferably, R ₁It is alkyl with about 18 carbon atoms of about 12-; R ₂Be selected from hydrogen or have the alkyl of about 18 carbon atoms of about 1-; R ₃And R ₄Be independently from each other H or have the alkyl of about 3 carbon atoms of about 1-; And described in X such as the epimere.

More preferably, R ₁It is alkyl with about 18 carbon atoms of about 12-; R ₂, R ₃And R ₄Be selected from H or have the alkyl of about 3 carbon atoms of about 1-; And X as mentioned above.

In addition, other useful cationic surfactant comprises amino-amide-type, R in the said structure formula ₁Can also be R ₅CO-(CH ₂) _n-, R wherein ₅Be the alkyl with about 22 carbon atoms of about 12-, and n is the integer of about 2-about 6, more preferably from about 2-is about 4, most preferably is the integer of about 2-about 3.The limiting examples of these cationic emulsifiers comprises the amino propyl group pg dimonium chloride of stearoyl phosphate, the amino propyl group ethyl of stearoyl dimethyl ethyl ester ichthyodin, amino propyl-dimethyl (myristyl acetas) ammonium chloride of stearoyl, the amino propyl-dimethyl spermaceti of stearoyl/stearyl ammonium tosylate, the amino propyl-dimethyl ammonium chloride of stearoyl, the amino propyl-dimethyl DL-Lactic acid ammonium salt. of stearoyl and composition thereof.

The limiting examples of quaternary cationics comprises and is selected from following those: cetyl ammonium chloride, cetyl bromination ammonium, lauryl chlorination ammonium, lauryl bromination ammonium, stearyl chlorination ammonium, the stearyl ammonium bromide, the cetyl alkyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl dimethyl ammonium chloride, the lauryl dimethyl ammonium bromide, the stearyl alkyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, the cetyl trimethyl ammonium chloride, the cetyl trimethylammonium bromide, lauryl trimethyl ammonium chloride, the lauryl trimethylammonium bromide, the stearyl trimethyl ammonium chloride, the stearyl trimethylammonium bromide, lauryl dimethyl ammonium chloride, stearyl dimethyl cetyl two Adeps Bovis seu Bubali alkyl dimethyl ammonium chlorides, two cetyl ammonium chloride, two cetyl bromination ammoniums, dilauryl ammonium chloride, the dilauryl ammonium bromide, distearyl ammonium chloride, the distearyl ammonium bromide, two cetyl ammonio methacrylates, two cetyl methyl ammonium bromide, the dilauryl ammonio methacrylate, dilauryl methyl ammonium bromide, the distearyl ammonio methacrylate, VARISOFT TA100, distearyl methyl ammonium bromide and composition thereof.Other quaternary ammonium salt comprises wherein C ₁₂-C ₂₂Alkyl carbon chain be by tallow acid or coconut fatty acid deutero-those.Term " Adeps Bovis seu Bubali " is meant that it is C normally by the deutero-alkyl of tallow acid (normally hydrogenant tallow acid) ₁₆-C ₁₈The mixture of alkyl chain.Term " Oleum Cocois " is meant that it is C normally by the deutero-alkyl of coco-nut oil fatty acid ₁₂-C ₁₄The mixture of alkyl chain.Comprise ditallow dimethyl ammonium chloride by these Adeps Bovis seu Bubali fat and the deutero-quaternary ammonium salt example of Oleum Cocois, ditallow dimethyl methyl ammonium sulfate, two (h-tallow base) alkyl dimethyl ammonium chloride, two (h-tallow base) dimethyl acetic acid ammonium, ditallow dipropyl ammonium phosphate, ditallow dimethyl ammonium nitrate, two (Oleum Cocois alkyl) alkyl dimethyl ammonium chloride, two (Oleum Cocois alkyl) dimethyl ammonium bromide, tallow ammonium chloride, Oleum Cocois ammonium chloride, the amino propyl group pg dimonium chloride of stearoyl phosphate, the amino propyl group ethyl of stearoyl dimethyl ethyl ester ammonium sulfate, amino propyl-dimethyl (myristyl acetas) ammonium chloride of stearoyl, the amino propyl-dimethyl spermaceti of stearoyl/stearyl ammonium tosylate, the amino propyl-dimethyl ammonium chloride of stearoyl, amino propyl-dimethyl DL-Lactic acid ammonium salt. of stearoyl and composition thereof.

Being used for preferred cationic surfactants of the present invention comprises and is selected from following those: dilauryl alkyl dimethyl ammonium chloride, VARISOFT TA100, myristyl alkyl dimethyl ammonium chloride, two palmityl alkyl dimethyl ammonium chlorides, VARISOFT TA100 and composition thereof.

Chelating agen

Articles for use of the present invention can also comprise the chelating agen of safe and effective amount." chelating agen " used herein thus be meant and can metal ion be removed from system make metal ion be not easy to participate in or the activating agent of catalyzed chemical reaction by forming complex.Add the protective effect that chelating agen can be particularly useful for providing the protective effect (ultraviolet radiation can cause that undue decortication or skin matter structure change) of anti-ultraviolet radiation and resist other environment agent that can cause skin injury.

The chelating agen of safe and effective amount can be added in the present composition, it is about 10% that its content is preferably the about 0.1%-that accounts for compositions, and more preferably from about 1%-about 5%.The example that can be used for chelating agen of the present invention is disclosed in the following document: the people's such as Bissett of promulgation on January 30th, 1996 United States Patent (USP) 5,487,884; People's such as Bush the world discloses 91/16035, publishes October 31 nineteen ninety-five; And the world of publishing people such as Bush October 31 nineteen ninety-five discloses 91/16034.The preferred chelating agen that can be used in the present composition is furil-dioxime and derivant thereof.

Flavonoid

Articles for use of the present invention can be chosen wantonly and comprise flavonoids.United States Patent (USP) 5,686 discloses flavonoid in 082 and 5,686,367 fully.These two pieces of patent documentations are introduced the present invention with for referencial use.Be applicable to that flavonoid of the present invention is to be selected from following flavanone: unsubstituted flavanone, mono-substituted flavanone and their mixture; Be selected from following chalcone derivative: unsubstituted chalcone derivative, mono-substituted chalcone derivative, dibasic chalcone derivative, trisubstituted chalcone derivative and their mixture; Be selected from following flavone: unsubstituted flavone, mono-substituted flavone, dibasic flavone and their mixture; One or more isoflavone; Be selected from following coumarin: unsubstituted coumarin, mono-substituted coumarin, dibasic coumarin and their mixture; Be selected from following chromone: unsubstituted chromone, mono-substituted chromone, dibasic chromone and their mixture; One or more dicoumarols; One or more benzodihydropyrones (chromanone); One or more benzodihydropyran alcohol; Their isomer (for example cis/trans isomer); With their mixture.Term used herein " replacement " is meant such flavonoid, and wherein the one or more hydrogen atoms on the flavonoid are substituted by following radicals independently: hydroxyl, C ₁-C ₈Alkyl, C ₁-C ₄Alkoxyl, O-glycosides etc. or these substituent mixture.

The example of suitable flavonoid includes but not limited to unsubstituted flavanone; the monohydroxy flavanone (for example 2 '-the hydroxyl flavanone; 6-hydroxyl flavanone; 7-hydroxyl flavanone etc.); one alkoxyl flavanone (5-methoxyl group flavanone for example; 6-methoxyl group flavanone; 7-methoxyl group flavanone; 4 '-the methoxyl group flavanone etc.); unsubstituted chalcone derivative (especially not replacing trans-chalcone derivative); the monohydroxy chalcone derivative (for example 2 '-hydroxy chalcone; 4 '-hydroxy chalcone etc.); the dihydroxy chalcone derivative (for example 2 '; 4-dihydroxy chalcone derivative; 2 '; 4 '-the dihydroxy chalcone derivative; 2; 2 '-the dihydroxy chalcone derivative; 2 '; 3-dihydroxy chalcone derivative; 2 '; 5 '-dihydroxy chalcone derivative etc.) and the trihydroxy chalcone derivative (for example 2 '; 3 '; 4 '-the trihydroxy chalcone derivative; 4; 2 '; 4 '-the trihydroxy chalcone derivative; 2; 2 '; 4 '-the trihydroxy chalcone derivative etc.); unsubstituted flavone; 7; 2 '-dihydroxyflavone; 3 '; 4 '-dihydroxy naphtho-flavone; 4 '-flavonol; 5; 6-benzoflavone and 7; the 8-benzoflavone; unsubstituted isoflavone; isoflavone aglycone (daidzein) (7; 4 '-dihydroxy isoflavone); 5,7-dihydroxy-4 '-the methoxyl group isoflavone; soybean isoflavone (from the mixture of Semen sojae atricolor extraction); unsubstituted coumarin; 4 hydroxy coumarin; umbelliferone; the 6-hydroxy-4-methylcoumarin; unsubstituted chromone; the 3-formacyl chromone; 3-formoxyl-6-isopropyl chromone; unsubstituted dicoumarol; unsubstituted benzodihydropyrone; pure and mild their mixture of unsubstituted benzodihydropyran.

Be preferred for of the present invention be unsubstituted flavanone, methoxyl group flavanone, unsubstituted chalcone derivative, 2 ', 4-dihydroxy chalcone derivative and their mixture.Most preferably unsubstituted flavanone, unsubstituted chalcone derivative (especially transisomer) and their mixture.

They can be synthetics, also can be the extracts that obtains from natural origin (for example plant).Can also be with the further derivatization of natural goods (for example extracting glucosides, ester or the ether derivant of back preparation) from natural origin.Can be used for flavonoids of the present invention can obtain from a plurality of sources, IndofineChemical Company for example, Inc. (Somerville, New Jersey); Steraloids, and Inc. (Wilton, NewHampshire) with Aldrich Chemical Company, Inc. (Milwaukee, Wisconsin).

Can also use the mixture of above-mentioned flavonoids.

It is about 20% that described flavonoids amount in the present invention is preferably about 0.01%-, and more preferably from about 0.1%-is about 10%, most preferably is about 0.5%-about 5%.

Sterol

Articles for use of the present invention can comprise one or more sterol compounds of safe and effective amount.The example of spendable sterol compound comprises sitosterol, stigmasterol, campesterol, brassicasterol, lanosterol, 7-dehydrocholesterol and composition thereof.They can be synthetic, and are also natural, as the mixture (for example plant sterol) from plant extraction.

Anti-superabundant fats agent

Articles for use of the present invention can also comprise the anti-superabundant fats agent (anti-celluliteagent) of safe and effective amount.Suitable anti-superabundant fats agent includes but not limited to Xanthine compounds (for example caffeine, theophylline, theobromine and aminophylline).

Skin lightening agent

Articles for use of the present invention can comprise skin lightening agent.When using, the present composition comprises preferably that to account for the about 0.1%-of composition weight about 10%, and more preferably from about 0.2%-is about 5%, also the preferred skin lightening agent of about 0.5%-about 2%.Suitable skin lightening agent comprise well known by persons skilled in the art those, comprise kojic acid, arbutin, ascorbic acid and derivant thereof, for example other salt of magnesium ascorbyl phosphate or sodium ascorbyl phosphate or sodium ascorbyl phosphate.Be applicable to that skin lightening agent of the present invention also is included in those that describe in the following file: the patent application 08/479 that the common unsettled name with Hillebrand was submitted to June 7 nineteen ninety-five, 935, this application is corresponding to the PCT application US95/07432 of nineteen ninety-five December submission on the 12nd; With common unsettled at Kalla L.Kvalnes, Mitchell A.DeLong, Barton J.Bradbury, the patent application 08/390 that the name of Curtis B.Motley and John D.Carter was submitted to February 24 nineteen ninety-five, 152, this application is applied for US95/02809 corresponding to the PCT in the publication on the 8th of nineteen ninety-five JIUYUE that submits in March 1 nineteen ninety-five.

Binding agent

Articles for use of the present invention can randomly comprise binding agent.Binding agent or adhesive material are used to seal between the layer and layer of articles for use of the present invention, keep the integrity of these articles for use thus.Binding agent can be various forms of, includes but not limited to that spray, that knot, independent stratum, binder fibre etc.Suitable binding agent comprises latex, polyamide, polyester, polyolefin and their combination.

Extra play

In another embodiment, articles for use of the present invention can comprise one or more extra plays, those of ordinary skills will be appreciated that described extra play be independent of be different from nonwoven layers but the layer that links to each other with nonwoven layers in some site.Extra play is suitable for improving with hands or other and surface that is cleaned is applied the whole grasping force of immediate articles for use one side of instrument of mechanism.In addition, extra play also is suitable for strengthening the soft feel of articles for use one side that contacts with the zone that is cleaned.In all cases, except two basic layers of articles for use of the present invention, these extra plays can be called as the layer of continuous counter, for example the 3rd layer and the 4th layer.

Suitable extra play can be (the macroscopically expanded) of macroscopic view expansion." macroscopic view expansion " used herein is meant the surperficial corresponding to net, ribbon and the film that produce with three-dimensionally formed structure, so that all demonstrating corresponding to the three-dimensionally formed graphic surface of the macro cross-section of this formation structure, two surface departs from, wherein when observer's eye and this netted planar vertical dimension are about 12 inches, comprise that this graphic surface departs from the common bore hole of can respectively doing for oneself (the common bore hole that promptly has 20/20 vision) and discern.

" embossing " used herein is meant that it mainly is the pattern that protrudes that the formation structure of article demonstrates.On the other hand, " back-pressure flower (debossed) " is meant that it mainly is recessed trickle netted pattern that the formation structure of article demonstrates.

Preferred macroscopical expanded film comprises that structure is like resilient formed film.The people's such as Roe of JIUYUE in 1996 promulgation on the 10th United States Patent (USP) 5,554,145 has been described this class film.The document is incorporated herein by reference.

Be applicable to that thickness is at least the net that material in 1 millimeter the extra play includes but not limited to record in people's such as Chappell the United States Patent (USP) 5,518,801 of promulgation on May 21st, 1996.The document is incorporated herein by reference.

Manufacture method

Personal-care supplies of the present invention will be treated useful component by conventional means and are added on the suitable nonwoven synusia and make, and described means include but not limited to spread, (for example pressure roll or touch roll) shifted in dip-coating, spraying, slot coated, roller.All the other synusia are placed on this first synusia then, this first synusia is preferred, but not always, is positioned on the useful component of treatment.Adopt conventional encapsulating method that these lamellas are sealed together, described encapsulating method includes but not limited to heating, pressurization, gluing, ultrasonic etc.Apparatus for heat sealing has different designs, and sealing can be implemented by the low-melting heat-sealable fiber web layer that inserts, can use between two-layer among this fiber web layer such as this embodiment or other embodiment be called Wonder Under (make by Pellon, can be available from H.Levinson﹠amp; Co., Chicago, Fypro net IL), they can not change the effect or the practicality of articles for use.Lamella with sealing is divided into the unit that uses for client then.Optional manufacturing step can comprise the smooth articles for use of calendering, drying, wrinkling, shrinkage, extension or other mechanical shaping step.

Cleaning skin and hair and to the method for skin and hair transmission treatment or beauty treatment benefit materials

The invention still further relates to method with personal-care supplies cleaning skin of the present invention and/or hair.These methods comprise the following steps: a) moistening is done basically, disposable personal care articles for use, described articles for use comprise the water-insoluble substrate that contains nonwoven layers; With with the useful component of treatment of the adjacent setting of nonwoven layers; Wherein said component comprises the treatment advantageous compositions of the about 10%-about 1000% that accounts for water-insoluble substrate weight, the treatment advantageous compositions comprises hydrophilic conditioner, when these articles for use contact with water, this conditioner show have in the time of 5 minutes less than about 25% and at 30 minutes less than 50% leaching value; With b) contact skin or hair with the articles for use of moistening.

Articles for use of the present invention are that water is activatory, therefore should use water-wet before use." water is activatory " used herein is meant that articles for use of the present invention are presented in client with anhydrous form, uses after with water-wet.It is found that when articles for use of the present invention comprise lathering surfactant they produce foam when contacting with water and further stirring or are " activated ".Therefore, articles for use of the present invention can be by being immersed in the water or placing it in moistening in the current.When articles for use of the present invention comprise lathering surfactant, by at these articles for use with before skin or hair contact or these articles for use of period of contact mechanical agitation and/or make this articles for use distortion can produce foam.The foam that is produced can be used for cleaning skin or hair.At cleaning course with subsequently between the water flush period, all therapeutic or beauty treatment benefit materials are deposited on skin or the hair.Therapeutic or the beauty treatment benefit materials deposition can by substrate contact with the physics of skin or hair and by comprise one or more deposition aids obtain the promotion.

Embodiment

The following example has further described and has demonstrated the specific embodiments in the scope of the invention.In the following example, all the components is all listed with active quantities.These embodiment only are illustrative, are not to be used for limiting the scope of the invention, because can carry out multiple change under the condition that does not deviate from spirit and scope of the invention.

Composition shows with chemical name or CTFA title.

I. cleaning component

Embodiment 1

Preparation is used for the representative cleaning component of articles for use of the present invention in the following manner.

Scrape the soap slab that 53.0gms comprises following component:

Composition	Wt％
		The cocoyl sodium isethionate	27.77

Paraffin (paraffin)	16.72
		Alkyl glycerol sodium sulfonate (AGS)	14.90
Soap	11.41
		Glycerol	8.57
Water	5.50
		Stearic acid	5.74
Sodium isethionate	3.04
		Sodium chloride	1.41
EDTA	0.10
		Etidronic acid	0.10
Polyox	0.03
		Spice	0.70
Various other materials (comprising pigment)	4.01
		Amount to	100

Soap slab is scraped bits to be mixed with 37.0gms glycerol (99.7%), 9.5gms water and 0.5gms spice.Under continue stirring with mixture heated to 200.On standard three roller mills, the mixture cold roll is ground, and cleaning component is stored in the suitable sealed container.

Embodiment 2

Preparation is used for the representative cleaning component of articles for use of the present invention in the following manner.

Scrape the soap slab that 40.0gms comprises following component:

Composition	Wt％
		Soda soap	52.40
Alkyl glycerol sodium sulfonate (AGS)	16.50
		Magnesium soap	13.40
Glycerol	0.19
		Water	5.50
Stearic acid	1.60
		Sodium isethionate	3.00
Sodium chloride	3.89
		EDTA	0.10

Etidronic acid (etidronic acid)	0.10
		Spice	0.70
Various other materials (comprising pigment)	2.62
		Amount to	100

Soap slab is scraped bits to be mixed with 45.0gms glycerol (99.7%), 4.5gms water and 0.5gms spice.Under continuous stirring with mixture heated to 200.On standard three roller mills, the mixture cold roll is ground, and cleaning component is stored in the suitable sealed container.

Embodiment 3

Preparation is used for the representative powder cleaning component of articles for use of the present invention in the following manner.

Scrape the soap slab that 40.0gms comprises following component:

Composition	Wt％
		Soap (magnesium and sodium)	80.16
Water	11.50
		Stearic acid	5.70
Sodium chloride	1.10
		EDTA	0.25
Spice	1.15
		Various other materials (comprising pigment)	0.14
Amount to	100

The soap slab fragment is stored in the suitable sealed container.

Embodiment 4

Preparation is used for the representative powder cleaning component of articles for use of the present invention in the following manner.

Scrape the soap slab that 40.0gms comprises following component:

Composition	Wt％
		Soap (magnesium and sodium)	80.16
Water	11.50
		Stearic acid	5.70
NaCl	1.10
		EDTA	0.25
Spice	1.15

Various other materials (comprising pigment)	0.14
		Amount to	100

The soap slab fragment is mixed with 90: 10 weight ratios with sodium bicarbonate.In 3 roller mills of standard, this mixture is ground twice.Collect fragment and it is stored in the suitable sealed container.

Embodiment 5

Preparation is used for the representative cleaning component of articles for use of the present invention in the following manner.The cleaning component of embodiment 2 is mixed with the protease that accounts for soap slab fragment weight 0.1%.Then, the gained mixture is mixed with the dry hydrocolloid, the sodium carboxymethyl cellulose that account for cleaning component weight 2%, and mill.The enzyme cleaning component is stored in the suitable sealed container.

Embodiment 6

Preparation comprises the representative cleaning liquid component of following ingredients.

Composition	Wt％
		Cocos nucifera oil alkyl glycerol base sodium sulfonate (AGS)	7.2
Ammonium lauryl sulfate (ALS)	10.4
		Alkyl laureth sulfate (AE3S)	10.4
Poly-(ethylene oxide) (PolyOx WSR N-3000, Union Carbide)	0.5
		Xanthan gum	1.4
Water	70.1

Embodiment 7

Preparation is used for the representative cleaning component of articles for use of the present invention in the following manner.The soap of 3lbs embodiment 2 is scraped bits to be heated till all soaps fusings with 3/4 glass of isopropyl alcohol (99%).When soap melts, add remaining alcohol.Adding 10oz. (ounce) is dissolved in the table sugar in the least possible water.About 4tsp. dyestuff is mixed in the 8oz. glycerol.Add glycerol (99.7%), stir.Continue heating fallen rope form band on denseness becomes by mixing tool from thin liquid, and on dropping in cold surface the time, the hardened material of aliquot.This mixture is poured in the suitable containers with sclerosis.The advantage of this mixture is, but refuse when heating, and this makes it be easy to processing with the preparation articles for use.

Embodiment 8

Preparation comprises the cleaning liquid component of the representative flawless (tear-free) of following ingredients.

Composition	????Wt％
		Cocoamidopropyl	????17.1

The tridecyl polyethenoxy ether sodium sulfate	????8.3
		POE 100 anhydro sorbitol monooleates	????7.5
Other composition (comprising spice, antiseptic, dyestuff)	????2.0
		Water	????65.1

The distinguishing characteristics of said composition is that it is to skin and eyes nonirritant.

Embodiment 9

Preparation comprises the representative cleaning liquid component of following ingredients.

Composition	Wt％
		Polyquaternary amine 10	0.50
Lauric acid both sexes sodium acetate	5.4
		Laureth-3 sodium sulfate	11.6
The EDTA disodium salt	0.20
		Trisodium citrate dihydrate	0.50
Anhydrous citric acid	1.0
		PEG-6 caprylic/capric glyceride	2.0
Coconut monoethanol amide	2.0
		Glycerol	3.5
MgSO 4-7H 2O (Epsom salts)	1.5
		The Oleum Glycines of maleic acid esterification	2.5
The Oleum Glycines of taste removal	5.0
		Other composition (comprising spice, caustic, coloring agent)	1.5
Water	62.8

This mixture is gentle on being used for sensitive skin the time.

Embodiment 10

Preparation comprises the representative cleaning liquid component of following ingredients.

Composition	Wt％
		Onamer M 0	0.1
Sodium sulfate	1.5
		Lauryl alcohol	0.3
Sodium laureth sulfate	5.8

Anhydrous citric acid	0.2
		Cocoamidopropyl	15.5
Sodium N-lauroyl sarcosinate	1.5
		Other composition (comprising spice, blue colorant)	1.0
Water	74.1

Embodiment 11

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		The decyl polydextrose	12.0
Cocoamidopropyl	12.0
		Sodium N-lauroyl sarcosinate	12.0
Butanediol	3.6
		PEG?14M	1.8
Onamer M 0	0.9
		The Dex pantothenylol	0.7
Phenyl phenol	0.5
		Benzyl alcohol	0.5
Methyl parahydroxybenzoate	0.45
		Propyl p-hydroxybenzoate	0.25
The EDTA disodium salt	0.2
		Water	55.1

Embodiment 12

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		EGDS	3.1
Cocoamidopropyl	4.0
		TEA soap (molecular weight is about 330)	9.5
One alkylphosphonic	15.0
		The cocos nucifera oil amine oxide	7.5
1, the 2-propylene glycol	1.0

Ethanol	3.0
		Other (spice, coloring agent, antiseptic)	8.9
Water	48.0

With this mixture heated to 50 ℃, continue to stir, reduce by 38% initial weight until this mixture, and have pasty consistency.Advantageously, cleaning component is easy to process on hypothallus, and does not need further drying.

Embodiment 13

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		SEFA *Cottonate	57.5
Citric acid	0.30
		Cocoamidopropyl	3.5
Sodium N-lauroyl sarcosinate	10.7
		Ethylene vinyl acetate polymer (Elvax 40W)	8.0
Siloxane polymer microballon (Tospearly 145A)	20.0

^*SEFA is the acronym of fatty acid cane sugar ester (sucrose esters of fatty acids).

Under 90 ℃ and high shear mixing condition, ethylene vinyl acetate polymer is melted in the SEFA.Add surfactant powder and citric acid and mixing.Add the siloxane polymer microballon, mix, and be cooled to and condense.Compositions can melt again, and is easy to be infiltrated up to or be coated on the fabric.

Embodiment 14

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		Laureth-10 carboxylic acid sodium (Empicol CB5S *)	50.0
C 12-14, 12EO alcohol ethoxylate (Empilan KB12 *)	50.0

^*Available from Albright﹠amp; Wilson.

With the alcohol ethoxylate fusing, mix until evenly with carboxylate, be cooled to curing until easy to use.Compositions can melt again, and is easy to be infiltrated up to or be coated on the fabric.

Embodiment 15

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		Lauroyl glutamate one sodium	22.0
Cocoamidopropyl	2.0
		Sodium chloride	1.0
Glycerol	2.5
		Water	72.5

These compositions are heated together and gentle agitation until evenly.

Embodiment 16

Preparation comprises the representative cleaning component of following ingredients.

Composition	Wt％
		Triethanolamine	2.9
Polyquaternary amine-39	0.1
		One Laurel based phosphates	4.0
C 12-C 14N-methyl glucoside amide 1	5.0
		Cocos nucifera oil acylamino-propyl hydroxy sulfobetaines 2	2.0
Sodium decyl sulfate	0.5
		The citric acid monohydrate compound	0.3
Spice, antiseptic and other composition	4.0
		Water	81.2

¹Available from Hoechst Celanese.

²Available from Rhone Poulenc.

60 ℃ add in the following sequence component until each components dissolved in water: TEA, lauryl phosphate, glucose amide.Be cooled to 45 ℃, add sulfobetaines, polyquaternary amine-39 and sulfate, and stir as mentioned above.Add spice, antiseptic, and be cooled to room temperature.

Embodiment 17

By being mixed, following ingredients prepares representative cleaning component.

Composition	Wt％
		The lauroyl polydextrose 1	20.0
The cetyl trimethylammonium bromide	4.0
		Spice, antiseptic and other composition	4.0
Water	72.0

¹With Plantaren 1200 available from Henkel

II. treat useful component

Embodiment 18-22

Prepare representational skin condition component by mixing following ingredients.

Composition	Embodiment 18	Embodiment 19	Embodiment 20	Embodiment 21	Embodiment 22
						SEFA *Cottonate	48.0	?75.0	33.5	?40.0	?80.0
SEFA *Behenate	12.0	?25.0	8.4	?10.0	?10.0
						Vaseline	10.0	?-	7.0	?-	?-
Mountain Yu acid glycerol three esters	5.0	?-	3.5	?-	?-
						Stearyl alcohol	-	?-	-	?5.0	?-
Paraffin	-	?-	-	?15.0	?-
						Cholesterol ester	25.0	?-	17.5	?-	?-
Ceresine	-	?-	-	?-	?10.0
						Glycerol	-	?-	28.0	?-	?-
Triglycerin base monostearate	-	?-	1.9	?-	?-
						Ten glyceryl dipalmitates	-	?-	0.2	?-	?-
The nonyl phenol polyglyceryl ether 1	-	?-	-	?30.0	?-

^*SEFA is the acronym of fatty acid cane sugar ester.

¹Hamplex?TNP，Hampshire?Chemical?Co.。

Embodiment 23-27

Prepare representational skin condition component by mixing following ingredients.

Composition	Embodiment 23	Embodiment 24	Embodiment 25	Embodiment 26	Embodiment 27
						Vaseline (in vain)	35.87	?35.87	?-	-	34.0
Mineral oil	11.0	?13.0	?-	-	10.0
						Jojoba oil	-	?-	?-	4.5
Oleum Ricini	10.0	?9.0	?-	-
						Oleum Cocois	-	?-	?-	-	5.0
Two iso stearyl trimethyl propane siloxysilicate materials	20.0	?20.0	?-	-
						Polydimethylsiloxane,	-	?-	?0.7	1.5

500 centistoke liquid
						Decamethylcyclopentasiloxane	-	?-	-	16.5
Octamethylcy-clotetrasiloxane	-	?-	-	10.0
						Polydimethylsiloxane, natural gum	-	?-	5.9	7.5
Stearyl polymethyl siloxane wax	-	?-	-	3.0
						Polybutene	-	?-	-	4.5
Candelilla wax	4.6	?4.6	-	-	?6.0
						Paraffin	-	?-	-	15.0	?2.0
Microwax	-	?-	-	6.0	?4.0
						Cera Flava	3.0	?3.0	-	-	?4.0
Ceresine	6.0	?6.0	-	-
						Brazil wax	3.0	?3.0	-	-
Castor oil hydrogenated	0.50	?0.50	4.0	-
						Silicon dioxide	-	?-	-	4.5
Sodium silicate magnesium	-	?-	-	1.5
						Tocopherol	0.03	?0.03	-	-
Cyclopolymethyl siloxane	-	?-	59.0	-
						Stearyl alcohol	-	?-	25.5	-	?9.0
Spermol					?9.0
						The glyceryl stearate	-	?-	2.6	-
The acetylation monoglyceride					?15.0
						Maleic acid two iso stearyl esters 1	-	?-	-	6.0
The glyceryl distearate	-	?-	-	9.5
						Glycerol	-	?-	-	6.0
Water	-	?-	-	3.0
						The nonyl phenol polyglyceryl ether 2	-	?-	5.0	-
Micronized titanium dioxide		?5.0	-	-
						Methoxy cinnamic acid octyl group ester	5.0	?-	-	-
Spice, other composition	1.0	?1.0	1.0	1.0	?2.0

¹With Myvacet 7-07, make an appointment with half acetylation, available from Eastman Chemical Co..

²With Hamplex TNP available from Hampshire Chemical Co..

Embodiment 28

Prepare representational skin condition component by mixing following ingredients.

Composition	Embodiment 28
		Poly decene 1	53.3
Stearyl alcohol	7.7
		The 12-hydroxy stearic acid	13.5
The nonyl phenol polyglyceryl ether	25.0
		Methoxy cinnamic acid octyl group ester	1.5

¹Puresyn?3000，Mobil?Chemical?Co.。

Embodiment 29-31

Prepare representational skin condition component by mixing following ingredients.

Composition	Embodiment 29	Embodiment 30	Embodiment 31
				Glycerol	95.0	?95.0	?94.0
Ten glyceryl dipalmitates 1	5.0	?1.0	?5.0
				Ten glyceryls, two behenates		?4.0
Mountain Yu acid glycerol three esters (tribehenin)			?1.0

¹With Polyaldo 10-2-P available from Lonza.

Embodiment 32-36

Preparation is used for the representative conditioning component of articles for use of the present invention in the following manner.

Composition	Embodiment 32	Embodiment 33	Embodiment 34	Embodiment 35	Embodiment 36
Hydrophobic phase:
						SEFA *cottonate	4.65	?4.65	15.5	15.5
SEFA *Behenate	0.35	?0.35	8.0	8.0
						Mountain Yu acid glycerol three esters			6.0	6.0
Vaseline			4.0	4.0	4.4
						Oleum Cocois					15.5
C 10-C 30Cholesterol/lanosterol ester			13.0	13.0
						C 30-C 45The alkyl polymethyl siloxane 1

Polyglyceryl-4 isostearate (with) the cetyl dimethione (with) lauric acid hexyl ester 2	5.0	?5.0
						PEG 30 dimerization hydroxy stearic acid esters 3			?3.0
Four glyceryl monostearates				2.1
						Ten glyceryl dipalmitates				0.90
Ceresine					5.5
						Cera Flava					7.0
The lecithin of purification					10.0
						The 1-monostearin					10.0
						Aqueous favoring:
Glycerol	70.0	?66.5	?42.30	42.30	40.0
						Water		?3.5			5.0
The PVM/MA decadiene crosslinked polymer 4			?0.25	0.25
						Sodium hydroxide (10% solution)			?0.25	0.25
Gelatin					2.6
Active skin care ingredient:
						Pantothenylol	20.0	?10.0	?2.50
Nicotiamide		?5.0	?2.50	3.0
						Carbamide		?5.0	?2.50	2.50
Allantoin			?0.20	0.20
						Acetylamino oxypropyl trimethyl ammonium chloride				2.0

^*SEFA is the acronym of fatty acid cane sugar ester.

¹As AMS-C ₃₀Can be available from Dow Corning.

²Can be as Abil WE-09 available from Goldschmidt.

³Can be as Arlacel P135 available from ICI.

⁴Can be as Stabileze 06 available from ISP.

The preparation method of all Emulsions

With hydrophobic heat phase to 70 ℃, add hydrophobic viable skin care component, and stir until evenly.With hydrophilic phase components and the premixing of hydrophilic active skin nursing component, mild heat is with its dissolving or dispersion if necessary.It is added to thin aqueous phase lentamente, continues to stir.Homogenize (high-shear mixer; Ultrasonic homogenizer; Or high-pressure homogenizer for example can be available from the Micro Fluid bed of Microfluidics Corp.).Be applied to immediately on the stromal surface, perhaps in ice or frozen water, promptly be cooled to room temperature.In the middle storage that controls environment.If necessary, can under nitrogen, store to keep chemically stable.

Embodiment 37-41

As described in embodiment 32-26, prepare representative conditioning component with following ingredients.

Composition	Embodiment 37	Embodiment 38	Embodiment 39	Embodiment 40	Embodiment 41
Hydrophobic phase:
						SEFA *cottonate			15.0	16.0
SEFA *Behenate			7.5	4.0
						Mountain Yu acid glycerol three esters			6.0
Vaseline			4.0	4.0	4.4
						Oleum Cocois					15.5
Poly decene 1	50.0	46.5
						C 10-C 30Cholesterol/lanosterol ester			13.0	l0.5
PEG 30 dimerization hydroxyl-stearates			3.0	3.0
						Ceresine					5.5
Cera Flava					7.0
						Aluminium hydroxystearate/magnesium in mineral oil 2				7.5
C 30-38Alkene/maleic acid isopropyl esters copolymer 3				2.5
						Tissuemat E 4				1.0
Lecithin, purification					10.0
						Spice, other composition			1.0
The 1-monostearin					10.0
Aqueous favoring:

Glycerol	30.0	25.0	34.80	20.0	?38.0
						Water	8.0	8.0			?5.0
PEG?2000				17.0
						The PVM/MA decadiene crosslinked polymer			0.25
Sodium hydroxide (10% solution)			0.25
						Gelatin	9.50	9.50			?2.6
Active skin care ingredient:
						Nicotiamide			2.50
Menthol in 50% beta-schardinger dextrin-		2.50
						Ascorbic acid (natural)		2.50
Tocopherol (natural)		1.00		2.50
						Sorbitol			2.50
Lactic acid	2.5
						Carbamide			2.50
Allantoin			0.20
						Triclosan					?1.50
Chlorhexidine					?0.50
						Benzoyl peroxide			5.0
15% salicylic PPG 14 butyl ester solution				12.0
						Salicylic acid			2.5

¹With Puresyn 3000 titles available from Mobil.

²With Gilugel Min title available from Giulini Chemie.

³With Performa 1608 titles available from New Phase Technologies.

⁴With Performalene 400 titles available from New Phase Technologies.

Embodiment 42-46

As described in embodiment 32-36, prepare representative conditioning component with following ingredients.

Composition	Embodiment 42	Embodiment 43	Embodiment 44	Embodiment 45	Embodiment 46
Hydrophobic phase:

SEFA *cottonate	20.5	15.5			?16.0
						Mineral oil			?7.50
SEFA *Behenate	8.0	?8.0			?8.0
						Mountain Yu acid glycerol three esters	9.5	?6.0			?6.0
Vaseline (white or ultrawhite)	4.0	?4.0	?22.6	?3.0	?4.0
						Candelilla wax			?4.50
Paraffin			?3.00	?14.0
						Microwax			?1.50
Cera Flava			?3.00
						C 10-C 30Cholesterol/lanosterol ester	18.0	13.0			?13.0
Lauryl polymethyl siloxane polyol 1				?5.0
						The acetylation monoglyceride 2			?11.3
Stearyl alcohol			?6.8
						Spermol			?6.8
Stearic acid
						PEG 30 dimerization hydroxyl stearates	4.5	3.0
Ten glyceryl dipalmitates 3					?0.90
						Four glyceryl monostearates					?2.10
Spice, other composition	1.0		?3.0	?2.0
Aqueous favoring:
						Glycerol	22.8	27.5	?25.0	?38.0	?41.0
Ten glyceryl dipalmitates 3	2.5
						The calcium silicates microsphere 4		15.0
						Active skin care ingredient:
Rhaball Gum CG-M 8M	1.00
						The Chitosan glycolate		2.50
Nicotiamide	1.50	2.50	?2.50
						0.2%Carbopol 940 aqueous solutions, pH6.0				?38.0

Retinol					2.50
						Phytantriol 5	1.00
Carbamide	2.50	?3.0	?2.50
						Vitamin C					2.50
Borage oil (Borage Oil)					2.50
						Ascorbyl palmitate					1.50
Acetylamino oxypropyl trimethyl ammonium chloride 6	2.50

¹Derive from Dow Corning with Dow Q2-5200.

²With Myvacet 7-07, make an appointment with half acetylation, available from Eastman Chemical Co..

³With Polyaldo 10-2-P available from Lonza.

⁴With Celite C available from Celite Co..

⁵With Hydagen CMF available from Henkel.

⁶With Incromectant AQ available from Croda.

Embodiment 43: glycerol is incorporated in the microsphere, is mixed into then in the liquid phase of fusing, and cooling is to store or to be coated onto on the substrate.

Embodiment 47-52

As described in embodiment 32-36, prepare representative conditioning component with following ingredients.

Composition	Embodiment 47	Embodiment 48	Embodiment 49	Embodiment 50	Embodiment 51	Embodiment 52
Hydrophobic phase:
							SEFA *cottonate	16.0	?16.0	?16.0	?16.0	?16.0	?16.0
Mineral oil
							SEFA *Behenate		?8.0	?8.0	?8.0	?8.0	?8.0
Mountain Yu acid glycerol three esters	6.0	?6.0	?6.0	?6.0	?6.0	?6.0
							Vaseline (white or ultrawhite)	4.0	?4.0	?4.0	?4.0	?4.0	?4.0
C 10-C 30Cholesterol/lanosterol ester	13.0	?13.0	?13.0	?13.0	?13.0	?13.0
							Stearyl dimethicone wax	2.0
The polydimethylsiloxane hydroxy stearic acid ester	4.0
							The dimethicone copolyol mountain	2.0

The Yu acid esters
							PEG 30-dimerization hydroxy stearic acid ester			?3.00		?3.00
Sodium lauroyl glutamate				?2.00
							The stearyl sodium lactate				?2.00
Calcium stearate						?5.0
							Ten glyceryl dipalmitates	0.90	?0.90		?0.90		?0.90
Four glyceryl monostearates	2.10	?2.10		?2.10		?2.10
							Spice, other composition	1.00	?1.00	?1.00	?1.00	?1.00	?1.00
							Aqueous favoring:
Glycerol	44.5	?42.5	?35.5	?35.5	?25.0	?43.0
							The aqueous solution of 75% polyethylene-imines 1pH6.5			?4.50	?4.50
Water						?2.0
							Ten glyceryl dipalmitates			?2.50	?2.50
Sootiness silicon dioxide (fumed silica)					?20.0
							Propylene glycol alginate 2						?2.0
							Active skin care ingredient:
Nicotiamide		?2.00			?2.00
							Chitosan		?1.50
Green tea extract	4.50
							Aloe vera gel		?3.0
Vitamin C			?2.50
							Ascorbyl palmitate			?2.00	?2.50
Acetylamino oxypropyl trimethyl ammonium chloride			?2.00		?2.00

¹With Epomin SP-018 available from Nippon Shokubai Co..

²With Kelcoloid HVF available from Kelco.

Embodiment 53-55

Preparation is used for the representative conditioning component of articles for use of the present invention in the following manner.

Composition	Embodiment 53	Embodiment 54	Embodiment 55
Hydrophobic phase:
				Lecithin, purification 1	15.4	?10.3	?10.8
Decane	28.6	?19.2	?15.0
				Mineral oil			?5.0
Tricosyl PVP 2			?26.0
				Stearyl alcohol		?13.0
The 12-hydroxy stearic acid		?19.4
Aqueous favoring:
				Glycerol	28.0	?18.8	?19.6
Propylene glycol	28.0	?18.8	?19.6
Active skin care ingredient:
				Triclosan		?0.20
Salicylic acid		?0.40
				Nicotiamide			?4.0

¹Derive from Lucas Meyer with Epikuron 200.

²Derive from ISP with Ganex WP-660.

All components is stirred together until forming microemulsion.At first skin care ingredient is added to its solubility parameter be complementary most mutually in.When adding wax, be heated to wax fusing point just lentamente, make its dispersion by stirring, be added on the substrate or be cooled to room temperature and also store.

Embodiment 56-58

Preparation is used for the representative conditioning component of articles for use of the present invention in the following manner.

Composition	Embodiment 56	Embodiment 57	Embodiment 58
Hydrophobic phase:
				2-Methylpentadecane	42.29	?43.0	?28.3
Dioctyl sodium sulfosuccinate	10.62	?7.0	?7.1

?? 2
Aqueous favoring:
				Glycerol	??35.17	??19.0	??23.6
Water	??11.72	??19.0	??7.8
				Brazil wax			??29.0
Gelatin		??6.0
Active skin care ingredient:
				Triclosan	??0.20
Cosmetic titanium dioxide			??4.2
				Micronized titanium dioxide		??4.2
Salicylic acid		??1.8

¹With Epikuron 200 available from Lucas Meyer.

²With Aerosol OT available from Pfaltz andBauer.

At first skin care ingredient is added to its solubility parameter be complementary most mutually in.Then all components is stirred together until forming microemulsion.Be coated on the stromal surface.

Embodiment 59-64

Preparation is used for the representative conditioning component of articles for use of the present invention in the following manner.

The A part	Embodiment 59	Embodiment 60	Embodiment 61	Embodiment 62	Embodiment 63	Embodiment 64
Lauroyl ether sodium sulfate (SLES adds with 27% valid density)	15.0	?6.51	?6.20			?5.9
							Cocoamidopropyl 1	13.5	?5.85	?5.57	?5.82	?5.19	?5.3
Sodium N-lauroyl sarcosinate 2	1.35	?0.60	?0.57	?6.01	?5.36	?0.54
							The decyl polydextrose 3				?5.80	?5.18
Lauryl alcohol	1.31	?0.56	?0.54			?0.54
							Polymine 4	7.87	?3.38	?3.22	?2.64	?2.36	?3.2
Citric acid	0.32	?0.11	?0.11			?0.09

(adding) with 50% aqueous solution
							EDTA four sodium	0.28
Sulphuric acid	5.4	?2.37	?2.25			?2.2
							Antiseptic, spice	0.62	?0.45	?0.43	?2.86	?2.55	?0.3
Sodium sulfate	7.9	?3.47	?3.21			?3.0
							Glycerol	26.45	?56.7	?46.4	?44.1	?39.36	?44.8
Sorbitol			?5.0
							SEFA *cottonate					?12.8
SEFA *Behenate					?8.0

B moiety-polymer gellant

Gelatin					4.2
							Polyacrylamide and isoparaffin 5				7.5
Polyurethane rubber latex in 50% isopropyl alcohol 6						34.1
							Acrylate copolymer 7				7.5
The polystyrolsulfon acid ester copolymer 8			1.1
							Kytamer L			5.4

C part-physics gellant

12-hydroxyl-stearic acid	????10.0			????10.66
							Stearyl alcohol	????10.0	????20.0	????20.0	????7.11	????15.0

^*SEFA is the acronym of fatty acid cane sugar ester.

¹With Tegobetaine F title available from Goldschmidt.

²With Hamposyl L-30 (type 721) title available from Hampshire Chemical, 31% active substance.

³With Plantaren 2000NP title available from Henkel.

⁴With Epomin SP-018 title, molecular weight is about 1800, available from Nippon Shokubai Co..

⁵With Carbopol Ultrez available from B.F.Goodrich.

⁶, make available from B.F.Goodrich with Sancure 2710 as the premix that contains 20% polymer of having an appointment, 30% water, 50%IPA.

⁷With Sepigel 305 available from Seppic Corp..

⁸With AQ38S available from Eastman Chemical.

With low speed impeller blender surfactant is mixed with aliphatic alcohol, be heated to 65 ℃ simultaneously.Remove heater, be cooled to 65 ℃, continue simultaneously to mix.Add cationic polymer, and stir until evenly.Under agitation add remaining A part component lentamente.Homogenize is so that SEFA is separated into emulsion.Reach about 6.5 with the concentrated sulphuric acid titration until pH.By A part compositions is coated on the tray (tray), and in suitable (vacuum or convection current) baking oven, do not prepare dried mixture until remaining moisture content basically with the temperature drying that is no more than 65 ℃.The polymerization gellant of exsiccant A part component with the B part mixed, be heated to dissolving or dispersion.Resulting composition is mixed with the physics gellant.Be heated to fusing, and gellant is dissolved in the compositions.The gained mixture is applied on the stromal surface, perhaps is cooled to room temperature and storage.

Embodiment 65-70

Use the following ingredients preparation to be used for the representative conditioning component of articles for use of the present invention according to the method for in embodiment 59-64, describing.

The A part	Embodiment 65	Embodiment 66	Embodiment 67	Embodiment 68	Embodiment 69	Embodiment 70
Sodium N-lauroyl sarcosinate 1	8.87			?11.4	?10.8	?10.8
							Polymine 2	7.39	7.50	?7.50	?9.5	?9.0	?9.0
Water	4.43	3.00	?3.00	?5.7	?5.4	?5.4
							Sulphuric acid	6.36	QS	?QS	?8.1	?7.7	?7.7
Spice, other composition
							Glycerol	34.45	52.5	?45.0	?41.3	?39.25	?34.25
Propylene glycol	2.50
							Carbamide		2.50	?2.50	?2.0	?1.9	?1.9
Pantothenylol				?2.0	?1.9	?1.9
							Nicotiamide		2.50	?2.50	?2.0	?1.9	?1.9
Salicylic acid
							Poly methyl silsesquioxane 3					?4.20	?4.20
Muscovitum, pearling agent					?3.85	?3.85
							Stearyl polymethyl siloxane wax						?5.0
SEFA?cottonate			?5.0

Vaseline

5.0

B moiety-polymer gellant

Gelatin						0.1
							Polyacrylamide and isoparaffin 4	16.0	?12.0	?12.0

C part-physics gellant

The 12-hydroxy stearic acid	12.0	12.0	10.5
							Brazil wax				18.0	14.1	14.1
Stearyl alcohol	8.0	8.0	7.0

¹With Hamposyl L-95 available from Hampshire Chemical, drying.

²With Epomin SP-018 title, molecular weight is about 1800, available from Nippon Shokubai Co..

³With Tospearl 145A available from Kobo, Inc..

⁴With Sepigel 305 available from Seppic Corp..

Embodiment 71-74

Preparation comprises the representative skin condition component of following component.

Composition	Embodiment 71	Embodiment 72	Embodiment 73	Embodiment 74
					SEFA *Cottonate		62.0	?52.0
Vaseline			?4.5
					Stearyl alcohol	4.0
Stearic acid	3.0
					Lanoline		20.0	?13.0
Ethylene vinyl-acetic ester polymer 1		10.0	?10.0
					Poly decene 2			?2.0	?2.0
Sodium N-lauroyl sarcosinate 3	25.0	3.00	?3.0
					Lauryl betaine 4		1.50	?2.0
Lauric acid both sexes-acetate 5				?5.25
					Laureth-3 sodium sulfate 6				?10.5
Coconut monoethanol amide 7				?2.80
					Sulphuric acid	QS
Rhaball Gum CG-M 8M	0.50		?0.50
					Cholesterol 8	9.0	1.0

The nonyl phenol polyglyceryl ether 9			5.0
					Micronized titanium dioxide			4.0
Methoxy cinnamic acid octyl group ester			4.0
					Nicotiamide		2.5
Glycerol	10.0			3.00
					Water	48.5			55.95
PEG 6 caprylic/capric glyceride				3.40
					The Oleum Glycines of maleic acid esterification				1.50
Oleum Glycines (taste removal)				8.0
					Palm kernel fatty acid				2.60
Onamer M 0				0.40
					Spice, antiseptic, other composition				4.60

^*SEFA is the acronym of fatty acid cane sugar ester.

¹With Elvax 40W available from DuPont.

²With Puresyn 3000 titles available from Mobil.

³With Hamposyl L95 (solid) or L30 (aqueous solution of 30% activating agent) title available from HampshireChemical, for example.

⁴With Empigen BS98 title available from Albright﹠amp; Wilson (80% betanin, 20% salt);

⁵With Empigen CDL60 title available from Albright﹠amp; Wilson;

⁶With Empicol ESC3 title available from Albright﹠amp; Wilson;

⁷With Empilan CME/G title available from Albright﹠amp; Wilson;

⁸With Super Hartolan title available from Croda;

⁹Hamplex?TNP，Hampshire?Chemical?Co.

The described lipidic component of fusion adds entry (if suitable) and one or more wetting agents, adds surfactant and continue to heat and stir until homogenize.Cool to room temperature also adds one or more skin care actives and deposition agent.With sulphuric acid pH is transferred to about 7.0.Before the packing it is put on substrate and dry (if aqueous words) through spraying, rolling, dipping or alternate manner.

III. personal-care supplies

Embodiment 75

Prepare representative skin cleaning article in the following manner.

The cleaning component of 4 gram embodiment 11 is applied to a side of the permeable meltable net of making by the heat sealable Fypro of low melting point.This permeable net is the Wonder Under that Pellon produces, can be available from H.Levinson﹠amp; Co., Chicago, IL.Cleaning component is applied on the elliptical region that size is about 13cm * 18cm.Cleaning component is air-dry.The size one deck 2oz/yd identical with net will be cut into ²(ounce per square yard) polyester bat is placed on the meltable net.The basis weights of polyester bat is 2oz/yd ², and be that the fibre blend of about 23 microns and 40 microns constitutes by average diameter, at least some fibers curl.The thickness of the bat of measuring when about 5gsi is about 0.23in.It is believed that bat is a thermal, does not use any binding agent.With one deck non-woven fleece be placed on meltable net below, to form second side of articles for use of the present invention.Described non-woven fleece is with 70% staple fibre of styrene-butadiene adhesives and the spunlaced mixture (spunlace blend) of 30%PET fiber, it carried out the water pore-forming forming the hole that diameter is about 2mm, and its basis weights is about 70gsm.The shape of articles for use is about 122mm * 160mm ellipses.Use the heat seal mould with the some combination of mesh model each layer to be sealed, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, and Hyannis, the Sentinel Model 808 heat seal machines of MA.The point combination is the diameter of the about 4mm of tolerance respectively, and the seal point of 51 equipartitions is arranged approximately.Articles for use are pruned and are prepared use.

Embodiment 76

Prepare representative skin cleaning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier (denier) PET fiber, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the rectangle articles for use of the about 120mm * 160mm that independently has the angle, garden, and every articles for use have about altogether 51 seal points.

Embodiment 77

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 34 are applied to the whole articles for use of embodiment 75, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 78

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 18 are applied to the whole articles for use of embodiment 75, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 79

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 65 are applied to the whole articles for use of embodiment 75, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 80

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 34 are applied to the whole articles for use of embodiment 76, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 81

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 18 are applied to the whole articles for use of embodiment 76, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 82

Prepare representational skin clean and conditioning article in the following manner.

The skin conditioning compositions of 3 gram embodiment 65 are applied to the whole articles for use of embodiment 76, every side half and half.Said composition is uniformly applied to the surface of these articles for use by slit with the said composition liquid (60-70 ℃) of heat, and every side of these articles for use is used half described compositions.

Embodiment 83

Prepare representative skin cleaning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the articles for use of the about 120mm * 480mm that respectively has the angle, garden.

Embodiment 84

Prepare representative skin cleaning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.Second substrate net for fluffy low-density bat that gas shop method is made is added on first substrate continuously, so that second substrate net contacts with the layer that contains surfactant.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the articles for use of the about 120mm * 90mm that respectively has the angle, garden.

Embodiment 85

Prepare representative skin cleaning article in the following manner.

The cleaning component of 4 gram embodiment 12 is applied to a side of the permeable meltable net of making by the heat sealable Fypro of low melting point.This permeable net is the Wonder Under that Pellon produces, can be available from H.Levinson﹠amp; Co., Chicago, IL.Cleaning component is applied on the elliptical region that size is about 13cm * 18cm.Cleaning component is air-dry.Be placed on the meltable net being cut into size one deck 2oz/sq yd polyester bat identical with net.The basis weights of polyester bat is 2oz/yd ², and be that the fibre blend of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are (creped) that curl.The thickness of the bat of measuring at about 5gsi is about 0.23in.The breathability of this bat is about 1270cfm/ft ², and foam permeability critical pressure is about 2.7cmH ₂O.It is believed that bat is a thermal, does not use any binding agent.With one deck non-woven fleece be placed on meltable net below, to form second side of articles for use of the present invention.Described non-woven fleece is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.The shape of articles for use is about 122mm * 160mm ellipses.Use the heat seal mould with the some combination of mesh model each layer to be sealed, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, and Hyannis, the Sentinel Model 808 heat seal machines of MA.The diameter of each point in the some combination is about 4mm, and the seal point of 51 equipartitions is arranged approximately.Articles for use are pruned and are prepared use.

Embodiment 86-88

Cleaning component with embodiment 1,2 and 5 prepares representative skin cleaning article in the following manner.

8 gram cleaning component are applied to a side of permeability, meltable net, this net comprises low-melting heat-sealable fiber, form about 10 inches * 12 inches rectangle of four quadrants, between edge and quadrant, allow some leeway so that seal each layer in the place that does not have surfactant.This permeability net is a kind of fibroid, low density polyethylene (LDPE) (LDPE or LLDPE) material, usually can be available from the sewing product supplier.Be placed on the meltable net being cut into size one deck 4oz/sq yd polyester bat identical with net.The basis weights of this polyester bat is 4oz/sq yd ², it comprises average diameter is about 30 microns polyester fiber and is adhesives, can be with the trade name of Mountain MistExtra Heavy Batting#205 available from Steams Textiles, Cincinnati, OH.Fiber non-woven is placed on meltable off the net, described nonwoven layers is the water entanglement mixture of 55% cellulose and 45% polyester, its fabric weight unit be about 65gsm (can Technicloth II title available from The TexwipeCompany, Saddle River, NJ).Use the heat seal mould each layer to be sealed with the pane window shape, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA, wherein this operation is to carry out so that bat fusion and flowing in the ground floor forms the appropriateness sealing thus with enough temperature and pressures, and the mechanical pressure sealing 6-10 that typically uses about 300 degrees Fahrenheit and 30psi is enough second.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.After the cooling,, the corner is pruned shaped, store in order to using with the cutting of this articles for use.

Embodiment 89-90

Cleaning component powder with embodiment 3 and 4 prepares representative skin clean and conditioning article in the following manner.

The dried Cleasing compositions powder of 4 grams is applied to a side of the permeable meltable net of making by the heat sealable fiber of low melting point.This permeable net is the Wonder Under that Pellon produces, can be available from H.Levinson﹠amp; Co., Chicago, IL.This powder is sprinkling upon equably on the oval face of about 17cm * 19cm.The size one deck 2oz/yd identical with net will be cut into ²The polyester bat is placed on the meltable net.The basis weights of polyester bat is 2oz/yd ², and be that the fibre blend of about 23 microns and 40 microns constitutes by average diameter, at least some fibers curl.The thickness of the bat of measuring at about 5gsi is about 0.23 inch.The breathability of this bat is about 1270cfm/ft ², and foam permeability critical pressure is about 2.7cm H ₂O.It is believed that bat is a thermal, does not use any binding agent.Second nonwoven layers of preparation water pore-forming, described nonwoven layers comprises the polyester fiber that diameter is about 10 microns, and within it portion contain have diameter be about 150 microns fiber, with the rare yarn of the polypropylene that interweaves (scrim) of about 0.8cm interleaved.The second layer is cut into than the big size of required articles for use size, and places 150 ℃ convection oven to place about 10 minutes, be contracted to about 70% its original dimension until the X-and the Y-size of this layer, this layer has the macroscopic thickness of the about 0.12in that measures at 5gsi.This layer has the average basis weights of macroscopic view of about 64gsm and the average diameter hole for about 0.5mm before shrinkage.Place under the meltable net and use the heat seal mould each layer to be sealed the second layer in the point bonding mode of mesh model and along the wide sealing of peripheral 2mm, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA.The diameter of each point in the some combination is about 3mm, and the seal point of 51 equipartitions is arranged approximately.Articles for use are pruned, and by use fluffy bat layer one side that compositions is applied to the skin conditioning composition of 2.5g embodiment 25 articles for use via the tourelle of trough of belt, described tourelle has mechanical crack and the charging storage of 1.5mm, and is maintained at about 60 ℃.Said composition is prepared against in the rapid cooling in articles for use surface and with the metal film package storage of sealing to be used.

Embodiment 91-96

Cleaning liquid component with embodiment 6,8,9,15,16 and 17 prepares representative skin clean and conditioning article in the following manner.

By coating the cleaning liquid component is applied to first substrate one side with brush in the windowpane mode of avoiding edge and sealing position, until being applied with 2 gram solid cleaning components.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.With substrate in convection oven in 45 ℃ air-dry 6 hours, perhaps be dried to tangibly degree.To be added to continuously on first substrate by second substrate that gas shop method makes, so that second substrate contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).Use the heat seal mould each layer to be sealed with the pane window shape, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA, wherein this operation is to carry out so that bat fusion and flowing in the ground floor forms the appropriateness sealing thus with enough temperature and pressures, and the mechanical pressures sealing 6-10 that typically use about 300 and 30psi are enough second.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.After the cooling, articles for use are pruned, and by use compositions via the tourelle of trough of belt the skin conditioning composition of 3g embodiment 26 is applied to fluffy bat layer one side of articles for use, described tourelle has mechanical crack and the charging storage of 1.5mm, and is maintained at about 60 ℃.Said composition is prepared against in the rapid cooling in articles for use surface and with the metal film package storage of sealing to be used.

Embodiment 97-102

With the cleaning liquid component of embodiment 7 and the skin conditioning composition of embodiment 19-24, prepare representative skin clean and conditioning article in the following manner.

4 cleaning liquid components are extruded on first mobile net continuously, and this net is the method processing of gas shop, fluffy, low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, its basis weights is about 100 gram/square metre (gsm), and is that gas is spread method and do not used the binding agent hot adhesion to make.The cleaning liquid component is heated to fusing point, and in storage in about 65 ℃ of maintenances, and by being pumped in the extruder head 4 cylindrical wires of this extruder head continuous metering, place on the net with even interval, to obtain the final addition of the about 5 gram compositionss of each whole articles for use.To be applied to continuously on first net for second net of micropore and macropore formed film (United States Patent (USP) 4,629,643 formed film), with macropore protrusion one side towards bat and cleaning component.Skin conditioning composition evenly is applied to the bat surface of exposure through slit under heating, spreading rate be each whole articles for use 3 gram, and cooling articles for use surface makes it curing.Net is sealed continuously, and use the thermometal roller and be cut into the rectangle of the 120mm * 160mm with fillet towards the pressure roll that forms film one side.Pack these articles for use in order to using.

Embodiment 103-105

With the cleaning liquid component of embodiment 6 and the skin conditioning composition of embodiment 56,57 and 58, prepare representative skin clean and conditioning article in the following manner.

By coating the cleaning liquid component is applied to first substrate one side with brush in the windowpane mode of avoiding edge and sealing position, until being applied with 2 gram solid surfactants.This substrate is the low-density bat that gas shop method makes, comprise 30%15 Denier PET fibers, 35%3 Denier and have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, its basis weights is about 100 gram/square metre (gsm).With the cleaning component drying.To have high fluffy and basis weights be placed on the side that contacts with cleaning component of described bat for second substrate of the cellulose napkin of the adhesives of the high wet strength of about 53gsm.A kind of spendable napkin can be available from The Procter﹠amp; Gamble Company and with Bounty Rinse﹠amp; Reuse  is commercially available, and this napkin still keeps its Z-direction height when moistening, and its thickness is about 0.047 inch when 5gsi, and pine/softness ratio is about 1.28.Use the pressing plate apparatus for heat sealing, for example available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA use the heat seal mould with the pane window shape each layer to be sealed, and wherein this operation is to carry out to form the sealing of appropriateness with enough temperature and pressures.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.Prune this articles for use, apply compositions with the slit roller device that is maintained at about 60 ℃ reinforced storehouse, and 1.5 gram skin conditioning compositions are applied to equably fluffy bat one side of these articles for use by having 1.5mm machined hole.Said composition is prepared against in the rapid cooling in articles for use surface and with the metal film package storage of sealing to be used.

Embodiment 106

Prepare representational skin clean and conditioning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 12, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate net that gas shop method makes, so that second substrate contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, and 35%3 Denier have the mixture and 35%10 Denier of the bicomponent fibre of PET nuclear and PE skin to be examined-the bicomponent fibre compositions of Pi equally, and its basis weights is about 100 to restrain/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.The skin condition liquid of embodiment 53 is sprayed on the net with the applied amount that about 25 grams of every side or each whole articles for use about 0.5 restrain compositions.Net is cut into the rectangular separate good of about 120mm * 90mm with fillet, and packing is with standby.

Embodiment 107-108

With the skin conditioning composition of embodiment 54 and 55, prepare representative skin clean and conditioning article in the following manner.

With three roller mills with the active cleaning component of the low water of embodiment 2 and aluminosilicate (with Advera401 N available from The PQ Corporation, Valley Forge, PA, it will be owing to exothermic reaction produces heat when contacting with water) with 1: 1 ratio grinding.10 gram cleaning component are applied to a side of bat layer.This bat is the fluffy low-density bat that gas shop method makes, comprise 30%15 Denier PET fibers, 35%3 Denier and have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, its basis weights is about 100 gram/square metre (gsm).Surfactant is applied on the fiber, forms about 10 inches * 12 inches rectangle of four quadrants, between edge and quadrant, allow some leeway so that do not have each layer of lower seal what have a surfactant.Second nonwoven layers of preparation water pore-forming, described nonwoven layers comprises the polyester fiber that diameter is about 10 microns, and portion comprises the fibre diameter that crosses this adhesive-bonded fabric and is about 100 microns interweave rare yarn and be about 250 microns the scrim that interweaves with horizontal vertical fibre diameter within it.Described rare yarn that interweaves is (connection) with the interleaved of about 1cm.The rare yarn of this class can be available from Conwed plastics, Minneapolis, MN.The basis weights of this second kind of adhesive-bonded fabric is about 70gsm, and because the tension force of the net during the manufacturing of this adhesive-bonded fabric and tensile subsequently lax, this fabric is slightly corrugated.Use the heat seal mould in the point bonding mode and along the wide sealing of peripheral 2mm each layer to be sealed, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, and Hyannis, the SentinelModel 808 heat seal machines of MA.The diameter of each point in the some combination is about 3mm, and the seal point of 51 equipartitions is arranged approximately.Prune this articles for use, apply compositions with the slit roller device that is maintained at about 60 ℃ reinforced storehouse, four gram skin conditioning compositions are applied to equably fluffy bat one side of these articles for use by having 1.5mm machined hole.Said composition is prepared against in the rapid cooling in articles for use surface and with the metal film package storage of sealing to be used.

Embodiment 109-116

Skin conditioning composition with embodiment 59,60,61,62,63,68,69 and 70 prepares representative skin clean and conditioning article in the following manner.

The cleaning component of four gram embodiment 11 is uniformly applied on the fluffy bat with hands.This bat be gas shop method make for fluffy low-density bat, comprise 30%15 Denier PET fibers, 35%3 Denier and have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, its basis weights is about 100 gram/square metre (gsm).Nonwoven layers is placed bat one side that has been coated with cleaning component, this nonwoven layers is the water entanglement mixture of 55% cellulose and 45% polyester, its basis weights be about 65gsm (can Technicloth II available from TheTexwipe Company, Saddle River, NJ).The interlock sealing plate of the plate of heating seals together with these layers with having not, and described not hot plate has the sleeve pipe bank with the evenly spaced counter-rotating of hexagon mesh model.The base diameter of this sleeve pipe bank is about 1.2cm, and the spacing distance of its center to center is about 2cm.The area between the shrinkage pool on the hot plate is not inside recessed several millimeters concave surface, forms and makes it interconnected groove.This hot plate has the ectoloph that accurately adapts to the groove on the hot plate area not.Make this hot plate contact and use the pressing plate apparatus for heat sealing with cellulose/polyester matrix, for example available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA carry out heat seal.Bat one side of the uncompleted articles for use of gained has the tangible sleeve-shaped of projection, has more shallow shrinkage pool or " button " in cellulose/polyester matrix one side of these articles for use, so that these both sides all are easy to grasping.These articles for use are cut apart rectangle into about 120mm * 160mm.Skin conditioning composition shifted being added in the groove with the amount of 3 gram/piece articles for use, this moment said composition be heat and make it cooling and solidify.Pack these articles for use in order to using.

Embodiment 117

Prepare representational skin clean and conditioning article in the following manner.

The cleaning liquid component of the cleaning component of 8 gram embodiment 10 is applied to a side of the meltable net of permeability that constitutes by low-melting heat-sealable fiber by brush, form about 10 inches * 12 inches rectangle net with four quadrants, between edge and quadrant, allow some leeway so that seal each layer in the place that does not have cleaning component.This permeability net is a kind of fibroid, low density polyethylene (LDPE) (LDPE or LLDPE) material, usually can be available from the sewing product supplier.Make the said composition drying.Be placed on the meltable net being cut into size one deck 4oz/sq yd polyester bat identical with net.The basis weights of this polyester bat is 4oz/sq yd ², it comprises average diameter is about 30 microns polyester fiber and is adhesives, trade name that can Mountain Mist Extra Heavy Batting#205 is available from Steams Textiles, Cincinnati, OH.Fiber non-woven is placed on meltable off the net, described nonwoven layers is the water entanglement mixture of 55% cellulose and 45% polyester, its fabric weight unit be about 65gsm (can be with Technicloth II title available from The Texwipe Company, Saddle River, NJ).Use the heat seal mould each layer to be sealed with the pane window shape, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model808 heat seal machine of MA, wherein this operation is to carry out so that bat fusion and flowing in the ground floor forms the appropriateness sealing thus with enough temperature and pressures, and typically using the mechanical pressure sealing 6-10 of about 300 degrees Fahrenheit and 30psi, it is enough second.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.Be applied on the articles for use with the care composition of brush with 5 gram embodiment 64, every side is the amount of half respectively, and once more with the articles for use drying.This articles for use are pruned, and the corner is shaped and store in order to using.

Embodiment 118-119

With the skin conditioning composition of embodiment 66 and 67, prepare representative skin clean and conditioning article in the following manner.

Be applied on first substrate by increasing by the about 8 cleaning liquid components that restrain embodiment 15 until weight during the part matrix impregnation of 120mm * 160mm is bathed to said composition.This substrate is to comprise the bat that 30%15 Denier PET fibers, 35%3 Denier have the mixture of the bicomponent fibre of PET core and PE skin and the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).With the substrate drying.One second substrate tablet is placed on first substrate, described second substrate is with 70% staple fibre of styrene-butadiene adhesives and the spunlaced mixture of 30%PET fiber, it carried out the water pore-forming forming the hole that diameter is about 2mm, and its basis weights is about 70gsm.With the ultrasonic sealing machine these substrate are sealed together, the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.Apply compositions by having 1.5mm machined hole with the slit roller device that is maintained at about 60 ℃ reinforced storehouse, four gram skin conditioning compositions are applied to equably the both sides of these articles for use.Said composition is prepared against in the rapid cooling in articles for use surface and with the metal film package storage of sealing to be used.

Embodiment 120-124

Skin conditioning composition with embodiment 27 to 31 prepares representative skin clean and conditioning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate net that gas shop method makes, so that second substrate net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.Skin conditioning composition is pumped into slit die through the both sides of slot coated to this substrate net by the bank from heat, amount coating (every side is with the add-on of about 140gsm) with each whole articles for use 3 gram skin conditioning composition, make it pass through cooling fan, compositions is cooled off rapidly at the outer surface of articles for use of the present invention thus.This net is divided into the articles for use of the about 120mm * 90mm that respectively has the angle, garden.

Embodiment 125-145

Skin conditioning composition with embodiment 32 to 52 prepares representative skin clean and conditioning article in the following manner.

Be applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein be to be applied to continuously at interval to be respectively on 4 lines of 20mm, 40mm and 20mm, described spacing distance is along the cross measure of net, paints the pair of parallel line on each side of net.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate net that gas shop method makes, so that second substrate net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.Skin conditioning composition is pumped into slit die through the both sides of slot coated to this substrate net by the bank from heat, amount coating (every side is with the add-on of about 140gsm) with each whole articles for use 3 gram skin conditioning composition, make it pass through cooling fan, compositions is cooled off rapidly at the outer surface of articles for use of the present invention thus.The bank of continuous stirring slot coated is to keep the stability of emulsion.This net is trimmed to the articles for use of the about 120mm * 90mm that respectively has the angle, garden.

Embodiment 146-147

Skin clean and care composition with embodiment 71 and 74 prepare representative skin clean and conditioning article in the following manner.

First substrate and second substrate are cut into about 12 inches * 9 inches rectangle.This first substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.This second substrate is to comprise the bat that 30%15 Denier PET fibers, 35%3 Denier have the mixture of the bicomponent fibre of PET core and PE skin and the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).Use the heat seal mould described substrate to be sealed with the pane window shape, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA, wherein this operation is to carry out so that bat fusion and flowing in the ground floor forms the appropriateness sealing thus with enough temperature and pressures, and the mechanical pressures sealing 6-10 that typically use about 300 and 30psi are enough second.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.After the cooling, these articles for use are cut into about 11 inches * 8.5 inches, and with brush 10 gram skin cleans and care compositions are applied to the outside of both sides, every side is used the described compositions of half amount.Dry said composition third is stored articles for use in order to using.

Embodiment 148-149

With the skin conditioning composition of embodiment 72 and 73, prepare representative skin clean and conditioning article in the following manner.

First substrate and second substrate are cut into about 12 inches * 9 inches rectangle.This first substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.This second substrate is to comprise the bat that 30%15 Denier PET fibers, 35%3 Denier have the mixture of the bicomponent fibre of PET core and PE skin and the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).Use the heat seal mould described substrate to be sealed with the pane window shape, described heat seal mould has used the pressing plate apparatus for heat sealing, for example can be available from Sencorp, Hyannis, the Sentinel Model808 heat seal machine of MA, wherein this operation is to carry out so that bat fusion and flowing in the ground floor forms the appropriateness sealing thus with enough temperature and pressures, and typically using the mechanical pressure sealing 6-10 of about 300 degrees Fahrenheit and 30psi, it is enough second.Sealing is carried out along continuous edge, and have an independent X and Y to width be the windowpane cross unit of about 2mm.After the cooling, these articles for use are cut into about 11 inches * 8.5 inches, and with 8 gram skin cleans and care composition slot coated to articles for use of the present invention, make the compositions of every side 4 grams be evenly distributed in this articles for use surface with the X-Y slide plate, this X-Y slide plate is the metering system of a sequencing control, and this system comprises a motorization X-Y coordinated control system that is maintained at about bank, pump, switch valve, the slit head of 70 ℃ heating and is used for dispense tip.With compositions cooling rapidly on the articles for use surface.Pack these articles for use in order to using.

Embodiment 150-152

Prepare representational skin clean and conditioning article in the following manner.

Preparation comprises the cleaning liquid component of following ingredients.

Composition	Embodiment 150	Embodiment 151	Embodiment 152
				Laureth-3 sodium sulfate			3.60
C 13/C 14Methyl branch sodium sulfate	5.00	5.60	4.50
				The alkane sodium sulfonate		6.40
The alpha-olefin sodium sulfonate			5.20
				Sodium lauryl sulfate	5.50

Lauric acid both sexes sodium acetate	4.50	?5.30	?3.65
				Coconut monoethanol amide	3.55	?3.20	?2.80
Succinic acid	2.80	?5.70	?6.00
				Sodium succinate	0.10	?0.14	?0.30
Citric acid	3.00	?4.30	?5.00
				Sodium citrate	1.60	?1.10	?1.40
Malonic acid	4.00	?2.20
				Glycerol	10.00	?15.00	?8.50
Palm kernel 12-18 fatty acid	2.00		?3.00
				Spice	1.00	?1.20	?1.00
MgSO 4-7H 2O	0.89	?0.90	?0.80
				Water	54.21	?47.61	?52.25
Salicylic acid	1.85
				Triclosan		?0.25
Amolden MCM 400		?1.10
				Pyrrole sulfur zinc			?2.00

By spread coating cleaning component is applied to a side of first substrate, until 10 gram compositionss are added to 11 inches * 8.5 inches parts.This substrate is fluffy, low-density bat, wherein comprise 30%15 Denier PET fibers, 35%3 Denier bicomponent fibres (having PET core and PE skin) and the 35%10 Denier bicomponent fibres chemical compound of (having identical core-skin forms), and basis weights is about 100gsm.With first substrate drying.Use the ultrasonic sealing machine that second hypothallus is pressed onto on the side that is untreated of first substrate, these nets are continued to send in the ultrasonic sealing machine, carry out the point type sealing, constitute the grid of the 4mm diameter seal point that evenly separates at interval with 2cm on the net with the sealing machine.Second substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.The skin conditioning composition of embodiment 19 evenly is applied to the whole surface of second substrate through slit, and spreading rate is each articles for use 3 gram, makes it cooling and packing in order to using.Articles for use of the present invention have been given the antiviral, antifungal and the antibacterial activity that continue of anti-Gram-negative and Gram-positive microorganism, and foam is abundant, and gentle to skin.

Embodiment 153

Prepare representational skin clean and conditioning article in the following manner.

The cleaning component of four gram embodiment 11 is uniformly applied in the fluffy bat with hands.This bat is the 4oz/sq yd polyester bat that is cut into 130mm * 175mm size, it comprises average diameter is about 30 microns polyester fiber and is adhesives, can be with the trade name of Mountain Mist ExtraHeavy Batting#205 available from Stearns Textiles, Cincinnati, OH.Fiber non-woven is placed on bat one side that has been coated with surfactant, described nonwoven layers is the water entanglement mixture of 55% cellulose and 45% polyester, its fabric weight unit is that about 65gsm (can be with Technicloth II title available from The Texwipe Company, Saddle River, NJ).The interlock sealing plate of the plate of heating seals together with these layers with having not, and described not hot plate has the sleeve pipe bank with the evenly spaced counter-rotating of hexagon mesh model.The base diameter of sleeve pipe bank is 1.5cm for the spacing distance of about 1.2cm and center to center.The area between the shrinkage pool on the hot plate is not a convex surface protruding upward several millimeters, forms to make it interconnected groove.This hot plate has the ectoloph that accurately adapts to the groove on the hot plate area not.Make this hot plate contact and use the pressing plate apparatus for heat sealing with cellulose/polyester matrix, for example available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA carry out heat seal.The uncompleted articles for use both sides of gained all have the shape characteristic, and this helps foamy generation and makes it be easy to grasping during use and slip over skin surface.These articles for use are cut apart rectangle into about 120mm * 160mm.

Be prepared as follows the contrary emulsifiable paste of the skin condition that is used for articles for use of the present invention:

Composition	Percentage composition
		PEG 30-dimerization hydroxy stearic acid ester	3.0
SEFA?cottonate	20.0
		Vaseline	4.0
Mountain Yu acid glycerol three esters	5.0
		C 10-C 30Cholesterol/lanosterol ester	13.0
The SEFA behenate	5.0
		Glycerol	50.0

Under agitation liposoluble constituent is heated to 70 ℃.Under the vigorous stirring, add glycerol lentamente.Make the said composition homogenization.The contrary emulsifiable paste of 3 these skins of gram is shifted while hot the recessed region of cellulose/polyester one side that is added to this product.Make said composition be cooled to semi-solid paste fast.Pack these articles for use in order to using.

Embodiment 154-158

With the skin conditioning composition of embodiment 19,29,34,55 and 60, prepare representative skin condition articles for use in the following manner.

By extruding via dispense tip this care composition being applied on the side of first substrate, wherein is to be applied to continuously on the 4 wide bands of the 5mm that is respectively at interval 20mm, 40mm and 20mm, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.For each whole articles for use, the extrusion capacity of said composition is 3 grams.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second net and a side contacts that does not contain skin conditioning composition for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the rectangle articles for use of the about 120mm * 160mm that independently has the angle, garden, and every articles for use have about altogether 51 seal points.

Embodiment 159-163

With the skin conditioning composition of embodiment 19,28,34,55 and 69, prepare representative skin condition articles for use in the following manner.

By extruding via dispense tip this care composition is applied on the side of first substrate, is successive 4 bands, every 5mm is wide, is respectively at interval 20mm, 40mm and 20mm, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.Said composition is extruded with the amount of each whole articles for use 1.1 gram compositions.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second net and a side contacts that does not contain skin conditioning composition for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 80 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the rectangle articles for use of the about 120mm * 90mm that independently has the angle, garden, and every articles for use have about altogether 51 seal points.These articles for use conveniently are applied to the skin of small size, as face, ancon, cervical region and/or foot.

Embodiment 164

Prepare representative skin cleaning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.This cleaning component is extruded with the amount of each whole articles for use 0.40 gram cleaning component.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate that gas shop method makes, so that second substrate contacts with the layer of surfactant for fluffy low-density bat.This bat comprises 10%15 Denier PET fibers, 50%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 40%10 Denier is formed, and its basis weights is about 80 gram/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the articles for use of the about 120mm * 90mm that respectively has the angle, garden.

Embodiment 165-169

Skin conditioning composition with embodiment 19,28,34,55 and 69 prepares representative skin clean and conditioning article in the following manner.

Being applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein is to be applied to continuously to be respectively on 4 lines of 20mm, 40mm and 20mm at interval, and described spacing distance is along the cross measure of net.On each side of net, paint the pair of parallel line.This cleaning component is extruded with the amount of each whole articles for use 0.52 gram cleaning component.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate net that gas shop method makes, so that second substrate net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 10%15 Denier PET fibers, 50%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 40%10 Denier is formed, and its basis weights is about 80 gram/square metre (gsm).It is online three the substrate net identical with second substrate net to be added to second substrate continuously, so that it contacts with second matrix phase.These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.Skin conditioning composition is pumped into slit die through the both sides of slot coated to this substrate net by the bank from heat, amount coating (every side is with the add-on of about 55gsm) with each whole articles for use 1.25 gram skin conditioning composition, make it pass through cooling fan, compositions is cooled off rapidly at the outer surface of articles for use of the present invention thus.This net is divided into the articles for use of the about 120mm * 90mm that respectively has the angle, garden.

Embodiment 170

Prepare representational skin clean and conditioning article series in the following manner.

The preparation skin cleaning article.Be applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein be to be applied to continuously at interval to be respectively on 4 lines of 20mm, 40mm and 20mm, described spacing distance is the cross measure along net, and paints the pair of parallel line on each side of net.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second substrate net contacts with the layer that contains surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the articles for use of the about 120mm * 480mm that respectively has the angle, garden.

Preparation skin condition articles for use.Be applied on the side of first substrate by the care composition of extruding via dispense tip embodiment 34, be successive 4 bands, every 5mm is wide, be respectively 20mm, 40mm and 20mm at interval, described spacing distance is along the cross measure of net, paints the pair of parallel line on each side of net.For each whole articles for use, the extrusion capacity of said composition is 3 grams.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second net that gas shop method makes, so that second net and a side contacts that does not contain skin conditioning composition for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the rectangle articles for use of the about 120mm * 160mm that independently has the angle, garden, and every articles for use have about altogether 51 seal points.

Skin cleaning article and skin condition articles for use are packaged in the same packing.

Embodiment 171

Prepare representational skin clean and conditioning kit utility (kit) in the following manner.

The preparation skin cleaning article.Be applied on the side of first substrate by the cleaning component of extruding via dispense tip embodiment 11, wherein be to be applied to continuously at interval to be respectively on 4 lines of 20mm, 40mm and 20mm, described spacing distance is along the cross measure of net, paints the pair of parallel line on each side of net.Cleaning component is extruded with the ratio of 4.4 a gram cleaning component/whole articles for use.This substrate is 70% staple fibre and the spunlaced mixture of 30%PET fiber with the styrene-butadiene adhesives, and it carried out the water pore-forming and is about the hole of 2mm with the formation diameter, and its basis weights is about 70gsm.To be added to continuously on first substrate by second substrate net that gas shop method makes, so that second substrate net contacts with the layer of surfactant for fluffy low-density bat.This bat comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).These nets are continued to send in the ultrasonic sealing machine, and the sealing machine carries out the point type sealing, is formed in the grid of the 4mm diameter seal point of online equidistant intervals.This net is divided into the articles for use of the about 120mm * 480mm that respectively has the angle, garden.

Preparation skin condition articles for use.Prepare a kind of like this substrate, it is to have softer, thin Denier fiber in a side, has the Hydroentangled mixture of more coarse-fibred fiber at opposite side.This substrate is paved into the net that two on net comprises 10 Denier polyester (PET) fibers through gas and makes, and one of them net is positioned at another top, and described net has the basis weights of about 20gsm separately.With diameter be about 100 microns, with about 0.8cm at interval the rare yarn cut substrate of polypropylene of embossing (lace) be added to continuously on the above-mentioned fleece as the 3rd net.To comprise that the 4th of 3 Denier polyester fibers and the 5th net are paved into net with the amount of about 20gsm on above-mentioned net through gas respectively.With the net hydro entanglement, and be fixed into a net unit, and dry until water content not on exsiccator, and produce about 20% crimp contraction because rare yarn takes place to relax.To hang down T with touch roll _gThe water-containing acrylic acid binder copolymer of (about 5 ℃) is added to crude fibre one side of this net with the wet addition of about 7gsm, and dry.Be added to continuously on this net by the skin conditioning composition of following manner embodiment 21: with the amount of the about 25gsm of every side with compositions equably slot coated on the both sides of net.This substrate net is cut into the rectangle separate good with angle, garden of about 120mm * 100mm with the thermal cutting roller, and when articles for use were cut, thermal cutting caused the slight shrinkage in cutting fibre personal articles edge.

Skin cleaning article and skin condition articles for use are packaged in the same packing.

Embodiment 172

Prepare representational skin clean and conditioning article in the following manner.

Prepare first substrate.This first substrate comprises 30%15 Denier PET fibers, 35%3 Denier have the bicomponent fibre of PET core and PE skin and the mixture of the bicomponent fibre that the same core-skin of 35%10 Denier is formed, and its basis weights is about 100 gram/square metre (gsm).This bat with definite shape, the concavo-convex roller of heating carries out embossing, make the impression area round projection, the button-like repetitive, its shape is like bulb, it forms the representative materials of the loop part of a kind of hook loop (hook-and-loop) fastening system.This material can be available from PGI Nonwovens, Benson, NC.The skin cleansing compositions of 4.4 gram embodiment 11 is applied to equably the dorsal part (a smooth side) of first substrate of rectangle of 10 inches * 8.5 inches.To be the size that second substrate of the cellulose napkin of fluffy adhesives for high wet strength is cut into about 10 inches * 8.5 inches sizes, the basis weights of this napkin be about 53gsm.A kind of spendable napkin can be available from The Procter﹠amp; Gamble Company and with Bounty Rinse﹠amp; Reuse  title is commercially available.This napkin still keeps its Z-direction height when moistening, and its thickness is about 0.047 inch when 5gsi, and pine/softness is than for about 1.28, and definite shape be with moistening the time have high wrinkle silk than (crepe ratio).Use the pressing plate apparatus for heat sealing, for example available from Sencorp, Hyannis, the Sentinel Model 808 heat seal machines of MA are in 4 some places of articles for use edge and articles for use central authorities (5mm diameter, each interval and identical with the most approaching edge distance) this substrate of hot adhesion.Prune this articles for use, and the skin care compositions and methods of 3 gram embodiment 18 is applied to while hot the both sides of these articles for use with brush.Use is prepared against in articles for use cooling and packing.

Claims (11)

1. disposable personal care articles for use of doing basically is characterized in that described articles for use comprise:

A) comprise nonwoven layers water-insoluble substrate and

B) with the useful component of treatment of the adjacent setting of described water-insoluble substrate, wherein said component comprises the treatment advantageous compositions that accounts for water-insoluble substrate weight 10%-1000%, said composition comprises hydrophilic conditioning agent, wherein when described articles for use contact with water, this conditioner showed the leaching value less than 25% in the time of 1 minute, showed the leaching value less than 50% in the time of 5 minutes.

2. the articles for use of claim 1, wherein said nonwoven layers comprises the fiber that is selected from natural fiber, synthetic fibers and combination thereof.

3. the articles for use of aforementioned each claim, wherein said fiber is the synthetic fibers that are selected from nylon fiber, staple fibre, polyolefine fiber, polyester fiber and combination thereof.

4. the articles for use of aforementioned each claim, wherein said nonwoven layers comprises the material that is selected from cellulose adhesive-bonded fabric, sponge, formed film, bat and combination thereof.

5. the articles for use of aforementioned each claim, wherein said treatment advantageous compositions comprises the treatment benefit materials that is selected from hydrophilic conditioning agent, hydrophobicity conditioner and combination thereof.

6. the articles for use of aforementioned each claim, wherein said treatment advantageous compositions is a microemulsion.

7. the articles for use of aforementioned each claim, wherein said treatment advantageous compositions are the compositionss that forms coacervate.

8. the articles for use of aforementioned each claim, the useful component of wherein said treatment also comprise and are selected from following treatment benefit materials: element-vitamine compound, skin-care agent, anti-acne active substance, anti-wrinkle active substance, anti-skin atrophy actives matter, anti-inflammatory activity material, local anesthetic, artificial tanned activating agent and promoter, anti-microbial active matter, antifungus active substance, antiviral agent, enzyme, sunscreen actives, antioxidant, decorticating agent, hydrophobicity conditioner, hydrophilic conditioning agent and their combination.

9. the method for therapeutic nursing skin and/or hair said method comprising the steps of:

A) articles for use of moistening claim 1; With

B) articles for use with this moistening contact with skin and/or hair.

10. the articles for use of aforementioned each claim, wherein said articles for use also contain lathering surfactant.

11. the method for cleaning skin and/or hair said method comprising the steps of:

A) articles for use of moistening claim 10; With

B) articles for use with this moistening contact with skin and/or hair.