CN1413778A - Disposal technology for refuse incineration slag and its technology - Google Patents

Disposal technology for refuse incineration slag and its technology Download PDF

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Publication number
CN1413778A
CN1413778A CN02137160A CN02137160A CN1413778A CN 1413778 A CN1413778 A CN 1413778A CN 02137160 A CN02137160 A CN 02137160A CN 02137160 A CN02137160 A CN 02137160A CN 1413778 A CN1413778 A CN 1413778A
Authority
CN
China
Prior art keywords
refuse incineration
incineration slag
solidifying agent
halogen
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN02137160A
Other languages
Chinese (zh)
Inventor
韩路
平剑
高峻
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHONGSHENG INDUSTRY DEVELOPMENT Co Ltd SHANGHAI
Original Assignee
ZHONGSHENG INDUSTRY DEVELOPMENT Co Ltd SHANGHAI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHONGSHENG INDUSTRY DEVELOPMENT Co Ltd SHANGHAI filed Critical ZHONGSHENG INDUSTRY DEVELOPMENT Co Ltd SHANGHAI
Priority to CN02137160A priority Critical patent/CN1413778A/en
Publication of CN1413778A publication Critical patent/CN1413778A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

A process for treating the garbage dregs generated after burning features that the said garbage dregs are mixed with the solidifying agent prepared from light burnt magnesium, halogen flaks or powder, water and regulator, and the mixture can be used for backfill in engineering, brick, road, etc.

Description

Refuse incineration slag disposal technology and technology thereof
Technical field
Refuse incineration slag disposal technology of the present invention and technology thereof relate to the technology and the product of a kind of disposal of garbage and regeneration.
Background technology
Can produce the slag and the flying dust of 25%~35% (weight percent) after the waste incineration, major part in the slag can be used as building materials after through correct the processing, according to German environment department 52 burning disposal factories are investigated, wherein there are 39 to be equipped with the slag treatment facility, have 38 incineration plant can utilize slag after nineteen ninety-five as road-making material.The waste incineration industry of China should be at the early-stage, particularly the lime-ash processing and utilizing after burning is not also had the technology of suitable moulding, down, presses for for burning slag roasting processing and research in light of this situation.
Summary of the invention
The object of the present invention is to provide and a kind ofly can be used for material of construction or as the refuse incineration slag and the preparation technology thereof of road foundation material.
The purpose of this patent can be achieved through the following technical solutions: a kind of refuse incineration slag, be that the refuse incineration slag fritter that forms certain particle size with deironing, broken back is a main raw material, the weight percentage of its each component is: refuse incineration slag 65~95%, solidifying agent 35~5%.
Wherein, described solidifying agent is made up of magnesia unslacked, halogen sheet or halogen powder, water and adjustment agent, and the weight percent of this solidifying agent is: magnesia unslacked 52~58%, halogen sheet or halogen powder 20~25, water 20~25%, adjustment agent 0.1~0.5%.This refuse incineration slag solidified solidifying agent has mainly selected for use low-cost ore deposit raw material light-burning magnesium powder and salt to pay product halogen sheet or halogen powder, and not only associativity is good, and low price.
MgO content in the described light-burning magnesium powder is 75~90%, the MgCl in described halogen sheet or the halogen powder 2Content is 42~46%.
Described adjustment agent is a kind of or several combinations in ferrous sulfate, copper sulfate, sal epsom, potassium permanganate, urea-formaldehyde resin, ammonium chloride, hydrochloric acid, phosphoric acid, the silicone emulsion.
Refuse incineration slag preparation technology is: with the water that accounts for solidifying agent weight part 20~25% halogen sheet or halogen powder are dissolved to the solution that degree Beaume is 23~25 degree earlier, add 0.1~0.5% adjustment agent then, again deployed solution is added to stir in the magnesia unslacked and makes solidifying agent, in refuse incineration slag, add the solidifying agent mixing and stirring at last and make.
Refuse incineration slag preparation technology also can be: with the water that accounts for solidifying agent weight part 20~25% halogen sheet or halogen powder are dissolved to the solution that degree Beaume is 23~30 degree earlier in changing stock tank, flow into and add 0.1~0.5% adjustment agent behind the former stock tank, 52~58% the magnesia unslacked of in the magnesia unslacked batch bin, pressing the solidifying agent weight part through feeding machine to grout mixer, simultaneously deployed solution is pumped into to stir the grout mixer from material-compound tank and make solidifying agent, at last components by weight percent 65~95% refuse incineration slags are added stirrer, 35~5% solidifying agent being pumped into stirrer simultaneously from grout mixer mixes and stirs, pour in-mold molding into or directly be transported to the construction site, pave, compacting.Technology of the present invention can be applicable to scale operation.
The purposes of refuse incineration slag of the present invention comprises: utilize refuse incineration slag to produce road foundation material and other material of construction.A kind of production technique that refuse incineration slag solidify is replaced Stabilized Soil and makes building materials is provided, and the different proportionings according to solidifying agent and refuse incineration slag are widely used in the engineering backfill, make clay brick, materials such as making roadbed, artificial hillock.For realizing that low cost, large-scale treating refuse burning slag provide a new approach.
Superiority of the present invention is effectively to utilize waste, becomes Fei Weibao, and production technique is simple and easy to do, and it can be widely used in the engineering backfill, makes clay brick, making roadbed, artificial hillock etc., is beneficial to environment protection.
Embodiment
Embodiment 1, a kind of refuse incineration slag, be that the refuse incineration slag fritter that forms certain particle size with deironing, broken back is a main raw material, the weight percentage of its each component is: refuse incineration slag 65~95%, solidifying agent 35~5%, wherein, solidifying agent is made up of magnesia unslacked, halogen sheet or halogen powder, water and adjustment agent, and part weight percent of respectively giving of this solidifying agent is: magnesia unslacked 52~58%, halogen sheet or halogen powder 20~25, water 20~25%, adjustment agent 0.1~0.5%.
By above-mentioned prescription, adopt following technology: in changing stock tank, 21% halogen sheet is dissolved to the solution that degree Beaume is 25 degree with the water that accounts for solidifying agent 23%, add then and adjust agent, this adjustment agent such as is at parts by weight of ferrous sulfate, potassium permanganate, hydrochloric acid, deployed solution is added in 55.4% the magnesia unslacked and stirs, making solidifying agent, is 1: 5~1: 15 mixing and stirring with solidifying agent and refuse incineration slag at last in proportion, makes finished product.Directly be transported to building-site and be used for stemming operation.
Embodiment 2: by above-mentioned prescription, adopt following technology: in changing stock tank, 22% halogen powder is dissolved to the solution that degree Beaume is 26 degree with the water that accounts for solidifying agent 21%, add then and adjust agent, account for solidifying agent weight part each component in this adjustment agent and be divided into ferrous sulfate 0.5 ‰, copper sulfate 0.45 ‰, sal epsom 0.45 ‰, potassium permanganate 0.45 ‰, urea-formaldehyde resin 0.55 ‰, ammonium chloride 0.05 ‰, hydrochloric acid 5.5 ‰, deployed solution is added in the magnesia unslacked of 56.2% weight part and stirs, make solidifying agent, be 1: 2~1: 10 mixing and stirring in proportion with solidifying agent and refuse incineration slag at last, to going into die for molding, make the waste incineration slag brick.

Claims (7)

1, a kind of refuse incineration slag is that the refuse incineration slag fritter that forms certain particle size with deironing, broken back is a main raw material, it is characterized in that the weight percentage of refuse incineration slag each component is: refuse incineration slag 65~95%, solidifying agent 35~5%.
2, refuse incineration slag according to claim 1, it is characterized in that described solidifying agent is made up of magnesia unslacked, halogen sheet or halogen powder, water and adjustment agent, the weight percent of this solidifying agent is: magnesia unslacked 52~58%, halogen sheet or halogen powder 20~25, water 20~25%, adjustment agent 0.1~0.5%.
3, refuse incineration slag according to claim 2 is characterized in that, the MgO content in the described light-burning magnesium powder is 75~90%, the MgCl in described halogen sheet or the halogen powder 2Content is 42~46%.
4, refuse incineration slag according to claim 2 is characterized in that, the adjustment agent is a kind of or several combinations in ferrous sulfate, copper sulfate, sal epsom, potassium permanganate, urea-formaldehyde resin, ammonium chloride, hydrochloric acid, phosphoric acid, the silicone emulsion.
5, according to claim 1 gained refuse incineration slag preparation technology, it is characterized in that: with the water that accounts for solidifying agent weight part 20~25% halogen sheet or halogen powder are dissolved to the solution that degree Beaume is 23~25 degree earlier, add 0.1~0.5% adjustment agent then, again deployed solution is added to stir in the magnesia unslacked and makes solidifying agent, in refuse incineration slag, add the solidifying agent mixing and stirring at last and make.
6, according to claim 1 gained refuse incineration slag preparation technology, it is characterized in that: in changing stock tank, halogen sheet or halogen powder are dissolved to the solution that degree Beaume is 23~30 degree earlier with the water that accounts for solidifying agent weight part 20~25%, flow into and add 0.1~0.5% adjustment agent behind the former stock tank, 52~58% the magnesia unslacked of in the magnesia unslacked batch bin, pressing the solidifying agent weight part through feeding machine to grout mixer, simultaneously deployed solution is pumped into to stir the grout mixer from material-compound tank and make solidifying agent, at last components by weight percent 65~95% refuse incineration slags are added stirrer, 35~5% solidifying agent being pumped into stirrer simultaneously from grout mixer mixes and stirs, pour in-mold molding into or directly be transported to the construction site, pave, compacting.
7, the purposes according to claim 1 gained refuse incineration slag is characterized in that: utilize refuse incineration slag to produce road foundation material, engineering backfill, make clay brick, artificial hillock and other material of construction.
CN02137160A 2002-09-26 2002-09-26 Disposal technology for refuse incineration slag and its technology Pending CN1413778A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN02137160A CN1413778A (en) 2002-09-26 2002-09-26 Disposal technology for refuse incineration slag and its technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN02137160A CN1413778A (en) 2002-09-26 2002-09-26 Disposal technology for refuse incineration slag and its technology

Publications (1)

Publication Number Publication Date
CN1413778A true CN1413778A (en) 2003-04-30

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Country Link
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103170488A (en) * 2013-02-07 2013-06-26 中国恩菲工程技术有限公司 Waste incineration fly ash curing agent and treatment method of waste incineration fly ash
CN104773989A (en) * 2015-03-29 2015-07-15 安徽盛运环保(集团)股份有限公司 High efficiency waste incineration fly ash solidifying agent
CN105299657A (en) * 2015-11-03 2016-02-03 华中科技大学 Co-processing method for red mud and household garbage incineration fly ash
CN106013588A (en) * 2016-07-22 2016-10-12 杜建国 Water-free and plastering-free dry-masonry self-locking wall brick and manufacturing method thereof
CN108442200A (en) * 2018-03-29 2018-08-24 湖北工业大学 A kind of composite reinforced roadbed of domestic refuse incineration ash composite soil and its construction method
CN113956018A (en) * 2021-09-26 2022-01-21 华东理工大学 Ceramsite concrete and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103170488A (en) * 2013-02-07 2013-06-26 中国恩菲工程技术有限公司 Waste incineration fly ash curing agent and treatment method of waste incineration fly ash
CN103170488B (en) * 2013-02-07 2016-06-01 中国恩菲工程技术有限公司 The treatment process of incineration of refuse flyash solidifying agent and incineration of refuse flyash
CN104773989A (en) * 2015-03-29 2015-07-15 安徽盛运环保(集团)股份有限公司 High efficiency waste incineration fly ash solidifying agent
CN105299657A (en) * 2015-11-03 2016-02-03 华中科技大学 Co-processing method for red mud and household garbage incineration fly ash
CN106013588A (en) * 2016-07-22 2016-10-12 杜建国 Water-free and plastering-free dry-masonry self-locking wall brick and manufacturing method thereof
CN108442200A (en) * 2018-03-29 2018-08-24 湖北工业大学 A kind of composite reinforced roadbed of domestic refuse incineration ash composite soil and its construction method
CN108442200B (en) * 2018-03-29 2020-11-03 湖北工业大学 Domestic garbage incineration ash mixed soil composite reinforced roadbed and construction method thereof
CN113956018A (en) * 2021-09-26 2022-01-21 华东理工大学 Ceramsite concrete and preparation method thereof

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