CN1412539A - Chemical information modification method for quickly quantitatively analyzing complex mixture and spectrograph - Google Patents
Chemical information modification method for quickly quantitatively analyzing complex mixture and spectrograph Download PDFInfo
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- CN1412539A CN1412539A CN 02145347 CN02145347A CN1412539A CN 1412539 A CN1412539 A CN 1412539A CN 02145347 CN02145347 CN 02145347 CN 02145347 A CN02145347 A CN 02145347A CN 1412539 A CN1412539 A CN 1412539A
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Abstract
The chemical information modification method for quick quantitative analysis of complex mixture includes the following steps: preparing sample liquor, preparing control sample; measuring absorption spectrum, simulation adding "new compound", displaying absorption spectrum y, xs, y' and yr, differential operation, solving derivative spectrum value (dy'd/ lambda)c and (dxs/d lambda), solving ratio value R, and solving the concentration Cx of tested component in the mixture sample. Its spectral analysis equipment includes deuterium lamp or tungsten lamp, achromatic condenser, optical gate, slit, holographic grating, optical fiber and probe, CCD detector and others.
Description
Technical field
The chemical information that the present invention relates to a kind of fast quantitative analysis complex mixture is modified method and spectroanalysis instrument thereof, belongs to analytical chemistry and Instrument technology field thereof.
Background technology
Nearly all industry relevant with chemistry all has complex mixture, the task of particularly complicated organic mixture fast quantitative analysis as biology, life science, materia medica, environmental science etc.Having a class maybe can reduce class sample to be analyzed in the described complex mixture is to be mixed by a kind of known component to be measured and unknown disturbances component, the purpose of analyzing is in the presence of unknown disturbances, directly this known component to be measured is carried out fast quantitative analysis, this be in the actual analysis work experience difficulties at most, urgent problem.
At present, the main stream approach of measuring this class complex mixture is the chromatographic resolution analytic approach.Chromatographic advantage is that applied range, separation efficiency height, amount of samples are few, highly sensitive.But also have following point: instrument price height, operation more loaded down with trivial details time-consuming, technical requirement is high, organic solvent consumption is big, and more serious environmental issue is arranged.
In recent years, analytical chemistry circle has developed the not method for separating and analyzing of complex mixture, this is the particularly modern analysis method of computer science later development of a class set physical optics, electronics, mathematics, statistics, easy, quick, accurate, environmental protection is arranged and be easy to realize the advantage of intellectuality, robotization.The not method for separating and analyzing that has worked out at present unknown disturbances coexistence system has vector to proofread and correct and tens kinds of matrix correction methods.[Liang Yiceng: " complicated many proximate analysiss system of baihuixiong and Chemical Measurement algorithm thereof ", Hunan science tech publishing house, Changsha in 1996].During though wherein the complex mixture that carries out in some laboratories of some method is analyzed, gratifying result obtained, but with regard to solving practical problems, all also do not walk out the laboratory.Studying its main cause is: can not mate well between the chemical information feature of the mathematical model of analytic method and system to be measured.In decades, domestic and international nearly all stoichiometry scholar is studying new algorithm untiringly, want to go to mate the Protean chemical information feature of actual COMPLEX MIXED objects system to be measured by setting up different mathematical models, plenty of time and energy have been expended for this reason, but this thinking and way are in the face of the diversity of actual complex mixture chemical information feature to be measured, and real difficulty reaches its intended purposes.Vector bearing calibration " local curve fitting method (LCFN) " { Analytical Chemistry as Karstang and Kvalhein proposition, 63 (1991) 767-772}, its main thought is: if unknown disturbances spectrum has maximum value, can utilize the maximum value of interference spectrum to proofread and correct.Spectrum is carried out differential, and the derivative spectrum that the maximum value place of interference spectrum disturbs will be zero, promptly disturb not measure the quantitative test of component to be measured on this wavelength points and bring influence, disturb thereby reach to eliminate, accurately the effect of quantitative test component to be measured.The unsatisfactory reason of this method still is that the chemical information feature of mathematical model and actual testing mixture system does not match.Because the interference of actual COMPLEX MIXED objects system to be measured is unknown fully, can't judge whether interference spectrum has maximum value, if interference spectrum does not have maximum value, can't measure; If interference spectrum has maximum value, but can not determine the wavelength location of interference spectrum maximum value, also can't measure by known conditions.Document is introduced two kinds of methods of estimating unknown disturbances spectrum maximum value wavelength location, but all infeasible through facts have proved.
Summary of the invention
The technical problem to be solved in the present invention is that the chemical information that proposes a kind of express-analysis complex mixture is modified method.This method utilization mathematical measure is transformed the chemical information feature of complex mixture to be measured, makes it meet the coupling requirement of specifying mathematical model, thereby can carry out fast quantitative analysis to the component to be measured in the complex mixture sample to be measured under the situation of unknown disturbances coexistence.
The present invention is resolved above-mentioned technical matters by following scheme.The chemical information of a kind of fast quantitative analysis complex mixture that explanation the present invention earlier now is related is modified method, it is characterized in that operation steps comprises:
The preparation of first step complex mixture M to be measured sample liquid
By the requirement of spectroanalysis instrument permission maximum absorbance, it is an amount of that precision takes by weighing complex mixture M sample to be measured, uses the appropriate solvent dissolving such as water, ethanol, is diluted to the complex mixture M sample liquid to be measured that concentration is suitable for spectral analysis, standby;
The preparation of second step component a standard reference material liquid to be measured
By the requirement of spectroanalysis instrument permission maximum absorbance, it is an amount of that precision takes by weighing component a standard reference material to be measured, uses and the identical dissolution with solvents of last step solvent for use, is diluted to the component a standard reference material liquid to be measured that is suitable for spectral analysis, and concentration is Cs, and is standby;
The 3rd step measured absorption spectrum
On spectroanalysis instrument, record the absorption spectrum y and the xs of complex mixture M sample liquid to be measured and component a standard reference material liquid to be measured respectively;
' noval chemical compound ' added in the 4th step emulation
Make the spectroanalysis instrument execution that (((x-c)/b^2)) is that ' noval chemical compound ' emulation of sign is added on the operation in the complex mixture M sample liquid to be measured with Gaussian function probe yr=a*exp with one, parameter by the Gaussian function probe of keyboard input through selecting and proofreading and correct, be peak height a, peak width b and peak position c, spectroanalysis instrument is at the functional value that adds on the measuring value of absorption spectrum y each point on the Gaussian function probe yr corresponding point, be about to have the absorption spectrum superposition of Gaussian function probe yr form on absorption spectrum y, obtain absorption spectrum y ', y '=y+yr through the complex mixture M sample liquid to be measured of mathematics modification;
The 5th step showed absorption spectrum y, xs, y ' and yr
Make spectroanalysis instrument with absorption spectrum y, xs, y ' and yr are presented on the display screen;
The 6th step derivation operation
Make spectroanalysis instrument successively to absorption spectrum y ', yr and xs carry out derivation operation, derivative spectrum dy '/d λ, dxs/d λ and dyr/d λ, and they are presented on the display screen, derivative spectrum dyr/d λ wavelength for peak position c place 0;
The 7th step spectral value (dy '/d λ) of differentiating
c(dxs/d λ)
c
Make spectroanalysis instrument carry out the spectral value of differentiating (dy '/d λ) successively
c(dxs/d λ)
cOperation;
The 8th step was asked ratio R
Make spectroanalysis instrument carry out ratio calculated R=(dy '/d λ)
c/ (dxs/d λ)
cOperation, the R value;
The 9th step was asked the concentration C x of component a to be measured in the complex mixture M sample to be measured
Make spectroanalysis instrument carry out the operation of calculating Cx=CsR, get the Cx value, be the concentration of component a to be measured in the complex mixture M sample, then, also can represent the requirement of mode according to quantitative analysis results, utilize the amount of this concentration and complex mixture M sample to be measured, calculate the Ying Youliang of component a to be measured in this mixture M and the number percent of actual measured amount.
Principle of work.The ordinate of absorption spectrum and horizontal ordinate are respectively absorbance A and wavelength X.The absorption spectrum of complex mixture M sample liquid to be measured and component a standard reference material liquid to be measured is respectively y and xs, y=Rxs+y again
Disturb, R is a ratio coefficient of hereinafter addressing.Method of the present invention is intended to y
DisturbThe content of component a to be measured in the complex mixture M sample liquid to be measured, i.e. concentration C x are obtained in coexistence down.Concentration C
xWith concentration known Cs in the standard reference material liquid following relation: Cx=RCs is arranged.For asking Cx, must make y at certain
Disturb=0 wavelength (being made as λ ') is located, by relational expression y (
λ')/xs (
λ')=R, obtain the R value earlier.Asking this wavelength value is one of key of the present invention.
Another key of the present invention emulation in the complex mixture M sample liquid to be measured adds that (((x-c)/b^2) characterizes ' noval chemical compound ', makes complex mixture absorption spectrum the y '=y+yr=Rxs+y after the interpolation ' noval chemical compound ' with Gaussian function pointer yr=a*exp
Disturb+ yr=Rxs+ (y
Disturb+ yr).y
Disturb+ yr forms synthetic unknown disturbances.Should synthetic unknown disturbances y
DisturbThe feature of+yr is the peak to be arranged and fixedly peak position is arranged, and can satisfy the coupling requirement of derivative spectrophotometry mathematical model.Dyr/d λ wavelength for peak position c place 0, in the minizone about λ=c, dyr/d λ is from the occasion of becoming negative value, y through 0
DisturbChange slowly dy
Disturb/ d λ no matter be on the occasion of or negative value, its absolute value is minimum.Therefore, in this minizone, a wavelength value λ ' must be arranged, synthetic unknown disturbances (y at this wavelength place
Disturb+ yr) derivative spectrum is 0.Because this wavelength value λ ' is with very approaching through the peak position c that selects and proofread and correct, so get this wavelength=peak position c, the error that causes is less.Try to achieve after wavelength value is peak position c, it is rational doing following the processing: dy '/d λ=Rdxs/d λ+d (y
Disturb+ yr)/and d λ, be peak position c place at wavelength, (dy '/d λ) c=R (dxs/d λ) c+ (d (y
Disturb+ yr)/and d λ) c, because (d (y
Disturb+ yr)/and d λ) c ≈ 0, so R=(dy '/d λ) c/ (dxs/d λ) c.(dy '/d λ) c and (dxs/d λ) c be respectively corresponding derivative spectrum at the ordinate value of wavelength for peak position c place, can obtain by the measuring light spectrogram, the utilization measured value is obtained R again, utilizes formula Cx=RCs at last, the Cs that substitution is known obtains concentration C x.
Another technical matters that will solve of the present invention is to release a kind of spectroanalysis instrument of modifying method work by the chemical information of above-mentioned fast quantitative analysis complex mixture.The present invention is resolved by making above-mentioned technical matters by the following technical solutions.Explanation in detail in conjunction with the accompanying drawings now: a kind of chemical information of pressing the fast quantitative analysis complex mixture is modified the spectroanalysis instrument of method work, comprise deuterium lamp or tungsten lamp 1, achromatic condenser 2, optical gate 3, slit 4, holographic grating 5, optical fiber and pop one's head in 6, CCD detecting device and amplifier 7, display device 10, printing equipment 11, deuterium lamp or tungsten lamp 1, achromatic condenser 2, optical gate 3, slit 4, holographic grating 5, optical fiber and pop one's head in 6, CCD detecting device and amplifier 7 formations are applicable to and measure the chemical information detection system of material ultraviolet to short wavelength's near-infrared band 200～1100nm spectral information, it is sampling thief, it is characterized in that, also comprise A/D and D/A converter 8, chemical information is modified generator 9, A/D and D/A converter 8, chemical information is modified generator 9, display device 10 and printing equipment 11 constitute spectral analysis workstation1 2, be inserted with in the expansion slot of spectral analysis workstation1 2 and contain the template that A/D and D/A converter 8 and chemical information are modified generator 9, the storeies that chemical information is modified in the generator 9 are to be solidified with commander to carry out following operation: measure and show four curves of spectrum; Produce and demonstration Gaussian function probe yr=a*exp (((x-c)/b^2)); Two curve of spectrum superpositions are become a synthetic spectrum curve; Obtain and show the derivative spectrum of four absorption spectrums; Measure the value of derivative spectrum at any wavelength place; The ROM (read-only memory) of the instruction of basic mathematical computing, the chemical information detection system links by the expansion slot and the spectral analysis workstation1 2 of PCMCIA expansion slot and spectral analysis workstation1 2.
Workflow: optical signals deuterium lamp or tungsten lamp 1 are through achromatic condenser 2, optical gate 3, slit 4, holographic grating 5, optical fiber and pop one's head in 6, the optical fiber and signal process CCD detecting device and the amplifier 7 of 6 acquisition samples of popping one's head in to light (absorbing or diffuse reflection), enter chemical information modification generator 9 through A/D and D/A8, the spectral analysis workstation1 2 preparation curves of spectrum; Add suitable mathematics probe in the suitable wavelength position, make unknown background interference be set to the peak, produce maximum value in specific bit; Correct definite zero crossing that disturbs is eliminated and is disturbed; Also can emulation interpolation ' noval chemical compound ' make the requirement that meets the interference of corresponding mathematics model elimination system; Calculate the quantitative measurement result of component to be measured in the potpourri,, also can be transferred to asynchronous communication devices such as universal automatic computer by the communication output interface of spectral analysis workstation1 2 by display device 10, printing equipment 11 outputs.
Compare with background technology, the present invention has following outstanding effect: can be implemented in the components contents known to be measured in the following quantitative test complex mixture quick and precisely of unknown disturbances coexistence.
Description of drawings
Fig. 1 is the abosrption spectrogram (a top curve of spectrum is caffeine and sodium benzoate injection y, below a curve of spectrum be Sodium Benzoate xs) of COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured and known component standard reference material Sodium Benzoate to be measured.
Fig. 2 is that the abosrption spectrogram that characterizes ' noval chemical compound ' back COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured and known component standard reference material Sodium Benzoate to be measured and ' noval chemical compound ' with Gaussian function is added in emulation.Among the figure from bottom to top three absorption spectrums be respectively ' noval chemical compound ' Gaussian function probe, the absorption spectrum of known component standard reference material Sodium Benzoate to be measured and the COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured modified through mathematics: yr, xs and y '.The parameter of yr is set to peak height 0.6, peak width 1, peak position 5.
Fig. 3 is the first derivative spectrum figure that measures Sodium Benzoate content in the caffeine and sodium benzoate injection, among the figure from bottom to top three derivative spectrums be respectively dy '/d λ, dyr/d λ and dxs/d λ.
Fig. 4 is the structural representation of complex mixture fast quantification spectroanalysis instrument, and 1 is deuterium lamp or tungsten lamp among the figure, the 2nd, and achromatic condenser, the 3rd, optical gate, the 4th, slit, the 5th, holographic grating, the 6th, optical fiber and probe, the 7th, CCD detecting device and amplifier, the 8th, A/D and D/A converter, the 9th, chemical information is modified generator, the 10th, display device, the 11st, printing equipment, the 12nd, spectral analysis workstation.
Embodiment
Embodiment
By method of the present invention, in spectroanalysis instrument of the present invention, implement under the unknown disturbances coexistence caffeine and sodium benzoate injection in Sodium Benzoate content, the i.e. mensuration of concentration.
Operation steps:
The preparation of first step complex mixture sample liquid to be measured
Complex mixture sample liquid to be measured is a caffeine and sodium benzoate injection.It is an amount of that precision is got caffeine and sodium benzoate injection, and the water dissolved dilution becomes the caffeine sodium benzoate solution of debita spissitudo, and the absorption maximum degree value that records under this concentration is no more than used spectroanalysis instrument and allows to survey accurate maximal value, and is standby.This example preparation 8 duplicate samples, wherein component concentration to be measured known (using for the survey time yield) in 4 duplicate samples is numbered an1～an4 respectively, component concentration the unknown to be measured in 4 duplicate samples in addition, numbering difference an5～an8.
The preparation of second step component standard reference material liquid to be measured
Component standard reference material liquid to be measured is Sodium Benzoate solution.It is an amount of that precision takes by weighing the Sodium Benzoate reference substance, and the water dissolved dilution becomes debita spissitudo (being made as Cs) to be suitable for the Sodium Benzoate solution of spectral analysis, and standby, Cs is known, is 7.308 μ g/ml.
The 3rd step measured absorption spectrum
On spectroanalysis instrument, record the absorption spectrum y and the xs of caffeine sodium benzoate solution and Sodium Benzoate solution respectively, initial wavelength is 212nm, at interval 2nm, totally four ten test points.This example is got wavelength coverage the 11st point～the 40th point, and totally 30 points are done later chemical information mathematics modification.As shown in Figure 1.
' noval chemical compound ' added in the 4th step emulation
Make the spectroanalysis instrument execution that (((x-c)/b^2)) is that ' noval chemical compound ' emulation of sign is added on the operation in the caffeine sodium benzoate solution with Gaussian function probe yr=a*exp with one, import the parameter of Gaussian function probe by the keyboard of spectral analysis workstation1 2, if Gaussian function probe initial parameter value a=3, b=1, c=15, calculate the spectra values yr of emulation ' noval chemical compound ', initial wavelength is 212nm, be spaced apart 2nm, get wavelength coverage the 11st point～the 40th point, totally 30 points are done the modification of information mathematics.Spectroanalysis instrument obtains caffeine sodium benzoate solution absorption spectrum the y '=y+yr that modifies through mathematics at the spectra values yr that adds on the measuring value of absorption spectrum y each point on emulation ' noval chemical compound ' respective points.
The 5th step showed absorption spectrum y, xs, y ' and yr
Make spectroanalysis instrument with absorption spectrum y, xs and yr are presented on the display screen.Fig. 1 is the abosrption spectrogram of COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured and component standard reference material Sodium Benzoate to be measured.Fig. 2 is that the abosrption spectrogram that characterizes ' noval chemical compound ' back COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured and component standard reference material Sodium Benzoate to be measured and ' noval chemical compound ' with the Gaussian function probe is added in emulation.
The 6th step derivation operation
Make spectroanalysis instrument respectively to absorption spectrum y ', xs and yr carry out derivation operation, get derivative spectrum dy '/d λ, dyr/d λ and dxs/d λ, and they are presented on the display screen, Fig. 3 is that the derivative spectrum figure that characterizes ' noval chemical compound ' back COMPLEX MIXED matter sample caffeine and sodium benzoate injection to be measured and component standard reference material Sodium Benzoate to be measured and ' noval chemical compound ' with the Gaussian function probe is added in emulation.Derivative spectrum dyr/d λ wavelength for peak position c place 0.
The 7th step differentiate spectral value (dy '/d λ) c and (dxs/d λ) c
Make spectroanalysis instrument carry out the operation of the spectral value of differentiating (dy '/d λ) c and (dxs/d λ) c respectively, the derivative spectrum value of trying to achieve leaves in the internal memory of spectral analysis workstation1 2.
The 8th step was asked ratio R
Make spectroanalysis instrument carry out the operation of ratio calculated R=(dy '/d λ) c/ (dxs/d λ) c, the R value of trying to achieve leaves in the internal memory of spectral analysis workstation1 2.
The 9th step was asked the operation of known components contents Cx=RCs to be measured, got Cx, the i.e. content of Sodium Benzoate.This measurement result can be shown in display screen, also can be printed on the paper through printing equipment 11.
The measurement result of 8 duplicate samples:
Addition (μ g/ml) amount of the recording recovery (%)
an1 7.308 7.105 97.23
an2 6.090 6.139 100.8
an3 7.308 7.546 103.2
an4 8.526 8.455 99.17
Average recovery rate 100.1% RSD2.5% labelled amount (μ g/ml) amount of recording accounts for labelled amount percent (%)
an5 7.8 7.683 98.50
an6 7.8 7.780 99.75
an7 7.8 7.489 96.02
an8 7.8 7.540 96.66
Claims (2)
1. the chemical information of a fast quantitative analysis complex mixture is modified method, it is characterized in that operation steps comprises:
The preparation of first step complex mixture M to be measured sample liquid
By the requirement of spectroanalysis instrument permission maximum absorbance, it is an amount of that precision takes by weighing complex mixture M sample to be measured, uses the appropriate solvent dissolving such as water, ethanol, is diluted to the complex mixture M sample liquid to be measured that concentration is suitable for spectral analysis, standby;
The preparation of second step component a standard reference material liquid to be measured
By the requirement of spectroanalysis instrument permission maximum absorbance, it is an amount of that precision takes by weighing component a standard reference material to be measured, uses and the identical dissolution with solvents of last step solvent for use, is diluted to the component a standard reference material liquid to be measured that is suitable for spectral analysis, and concentration is Cs, and is standby;
The 3rd step measured absorption spectrum
On spectroanalysis instrument, record the absorption spectrum y and the xs of complex mixture M sample liquid to be measured and component a standard reference material liquid to be measured respectively;
' noval chemical compound ' added in the 4th step emulation
Make the spectroanalysis instrument execution that (((x-c)/b^2)) is that ' noval chemical compound ' emulation of sign is added on the operation in the complex mixture M sample liquid to be measured with Gaussian function probe yr=a*exp with one, parameter by the Gaussian function probe of keyboard input through selecting and proofreading and correct, be peak height a, peak width b and peak position c, spectroanalysis instrument is at the functional value that adds on the measuring value of absorption spectrum y each point on the Gaussian function probe yr corresponding point, be about to have the absorption spectrum superposition of Gaussian function probe yr form on absorption spectrum y, obtain absorption spectrum y ', y '=y+yr through the complex mixture M sample liquid to be measured of mathematics modification;
The 5th step showed absorption spectrum y, xs, y ' and yr
Make spectroanalysis instrument with absorption spectrum y, xs, y ' and yr are presented on the display screen;
The 6th step derivation operation
Make spectroanalysis instrument successively to absorption spectrum y ', yr and xs carry out derivation operation, derivative spectrum dy '/d λ, dxs/d λ and dyr/d λ, and they are presented on the display screen, derivative spectrum dyr/d λ wavelength for peak position c place 0;
The 7th step spectral value (dy '/d λ) of differentiating
c(dxs/d λ)
c
Make spectroanalysis instrument carry out the spectral value of differentiating (dy '/d λ) successively
c(dxs/d λ)
cOperation;
The 8th step was asked ratio R
Make spectroanalysis instrument carry out ratio calculated R=(dy '/d λ)
c/ (dxs/d λ)
cOperation, the R value;
The 9th step asked the concentration C x of component a to be measured in the complex mixture M sample to be measured to make spectroanalysis instrument carry out the operation of calculating Cx=CsR, get the Cx value, be the concentration of component a to be measured in the complex mixture M sample, then, also can represent the requirement of mode according to quantitative analysis results, utilize the amount of this concentration and complex mixture M sample to be measured, calculate the Ying Youliang of component a to be measured in this mixture M and the number percent of actual measured amount.
2. modify the spectroanalysis instrument of method work by the chemical information of the described fast quantitative analysis complex mixture of claim 1, comprise deuterium lamp or tungsten lamp (1), achromatic condenser (2), optical gate (3), slit (4), holographic grating (5), optical fiber and probe (6), CCD detecting device and amplifier (7), display device (10), printing equipment (11), deuterium lamp or tungsten lamp (1), achromatic condenser (2), optical gate (3), slit (4), holographic grating (5), optical fiber and probe (6), CCD detecting device and amplifier (7) formation is applicable to and measures the chemical information detection system of material ultraviolet to short wavelength's near-infrared band 200～1100nm spectral information, it is sampling thief, it is characterized in that, also comprise A/D and D/A converter (8), chemical information is modified generator (9), A/D and D/A converter (8), chemical information is modified generator (9), display device (10) and printing equipment (11) constitute spectral analysis workstation (12), be inserted with in the expansion slot of spectral analysis workstation (12) and contain the template that A/D and D/A converter (8) and chemical information are modified generator (9), the storer that chemical information is modified in the generator (9) is to be solidified with commander to carry out following operation: measure and show four curves of spectrum; Produce and demonstration Gaussian function probe yr=a*exp (((x-c)/b^2)); Two curve of spectrum superpositions are become a synthetic spectrum curve; Obtain and show the derivative spectrum of four absorption spectrums; Measure the value of derivative spectrum at any wavelength place; The ROM (read-only memory) of the instruction of basic mathematical computing, the chemical information detection system links by the expansion slot and the spectral analysis workstation (12) of PCMCIA expansion slot and spectral analysis workstation (12).
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108780037A (en) * | 2018-04-09 | 2018-11-09 | 深圳达闼科技控股有限公司 | Spectroscopic analysis methods, device, electronic equipment and computer readable storage medium |
| CN110214271A (en) * | 2017-01-19 | 2019-09-06 | 株式会社岛津制作所 | Analyze data analysis method and analysis data analysis device |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110214271A (en) * | 2017-01-19 | 2019-09-06 | 株式会社岛津制作所 | Analyze data analysis method and analysis data analysis device |
| US11423331B2 (en) | 2017-01-19 | 2022-08-23 | Shimadzu Corporation | Analytical data analysis method and analytical data analyzer |
| CN110214271B (en) * | 2017-01-19 | 2022-11-15 | 株式会社岛津制作所 | Analysis data analysis method and analysis data analysis device |
| CN108780037A (en) * | 2018-04-09 | 2018-11-09 | 深圳达闼科技控股有限公司 | Spectroscopic analysis methods, device, electronic equipment and computer readable storage medium |
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