CN1408472A - Microporous filtering adsorbing, sterilizing and algae killing material - Google Patents

Microporous filtering adsorbing, sterilizing and algae killing material Download PDF

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Publication number
CN1408472A
CN1408472A CN 02135420 CN02135420A CN1408472A CN 1408472 A CN1408472 A CN 1408472A CN 02135420 CN02135420 CN 02135420 CN 02135420 A CN02135420 A CN 02135420A CN 1408472 A CN1408472 A CN 1408472A
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parts
sterilizing
algae killing
ingredients
absorption according
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CN1140334C (en
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孙传斌
孙新
孙锋
戚思锋
许振东
司维忠
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孙传斌
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Abstract

The microporous filtering, filtering, adsorbing, sterilziing and algaecidal material consists of Al2O3 10-70 wt% and SiO2 25-85 wt% and is prepared with inorganic mineral material and inflammable material and through mixing, forming and baking. The raw material includes clay, quartz and inflammable material in the fineness of 40-1000 mesh. After being semi-dry pressurizing formed, it is stoved and baked in the similar process of producing refractory material. The microporous material is used in desalting sea water, purifying sewage, sterilizing, killing algae, etc.

Description

Micro porous filtration absorption, sterilizing and algae killing material
Technical field
The present invention relates to a kind of micro porous filtration absorption, sterilizing and algae killing material, be used for desalinization, sewage water filtration purification, sterilization algae removal.
Background technology
Desalinization, sewage water filtration purify, sterilization algae removal is that people make great efforts the problem that solves always for many years, and everyway has bigger progress from technology to equipment etc., but effect still is not very desirable.
Summary of the invention
Technical problem to be solved by this invention is: a kind of micro porous filtration absorption, sterilizing and algae killing material of new composition are provided, and filtration, purified treatment, sterilization algae removal are effective, and cost is low, easily make.
Micro porous filtration absorption of the present invention, sterilizing and algae killing material have micropore on the material piece, and it contains following weight percent forms: Al 2O 310~70%, SiO 225~85%.
Aluminium, silicon composition are effective to desalinization, sewage water filtration purified treatment, and microcellular structure filters, excellent adsorption, improves serviceability.
Described sorbing material by mineral inorganic raw material and flammable decomposing materials through mixing, after the moulding, burn till again and make, inorganic material, the life-span is long, pollute little, also renewable recycling.The mineral inorganic raw material contains the sterilization algae removal rare earth element, makes the product of acquisition have the sterilization algae removal function.
Described absorption, sterilizing and algae killing material, ingredients by weight is formed and is comprised:
1~10 part of clay, 0.5~10 part in quartz, 1~15 part of flammable decomposing materials.
Flammable decomposing materials wherein is at high temperature to burn, to decompose the material that disappears, to form micropore, commonly used have sawdust, faggot, charcoal, active carbon, paper pulp, papermaking wastewater, grain chaff, straw, plastics, starch, cellulose, lignin, vinasse, furfural, another name for sugar, inositol, phytic acid and residue thereof or the like, cost is low, obtains easily.Every kind of flammable decomposing materials can use separately, also can two or more fit applications, and use can temper.In order to form micropore, also can make expanding foam solution and use, as the oily class of foaming, colophony powder liquid etc. with organic matter.
On the batching basis, add rare earth element raw material 0.1~2%, can increase the sterilization algae removal function.
Preferred ingredients by weight is formed and is comprised: 5 parts of clays, 5 parts in quartz, 10 parts in sawdust;
Or 10 parts of 5 parts of clays, quartzy 5 parts, active carbon;
Or 10 parts of 5 parts of clays, quartzy 5 parts, starch;
Or 5 parts of clays, quartzy 5 parts, 10 parts of starch, add boron oxide 0.7%;
Or 5 parts of clays, quartzy 5 parts, 10 parts of starch, add nickel oxide 0.4%;
Or 6 parts of 3 parts of clays, quartzy 4 parts, the black liquid of oven dry;
Or 4 parts of clays, quartzy 6 parts, 5 parts in sawdust, 0.1 part in aluminum sulfate;
Or 4 parts of 6 parts of clays, quartzy 8 parts, the last plastic microsphere of bubble;
Or 5 parts of 5 parts of clays, quartzy 5 parts, nano-colloid combustible.
Or can select in the aluminium oxide, silica, magnesia, iron oxide, calcium oxide, zirconia respectively add 5~50 parts, 1~15 part of flammable decomposing materials, add sterilization algae removal rare earth element 0.1~2%, preferred group becomes: select in aluminium oxide, silica, magnesia, iron oxide, calcium oxide, the zirconia respectively to add 15~30 parts, 6~10 parts of flammable decomposing materials add sterilization algae removal rare earth element 0.5~1%.Wherein the sterilization algae removal rare earth element has silver, nickel, boron etc., can add with the form of oxide.This batching is formed in conjunction with ceramic production technology, can produce domestic ceramics utensil waterproof and ventilative and the energy sterilization algae removal, and as domestic ceramics food and drink sanitary equipment, bathroom facilities, bathing pool brick, bathtub etc., sterilization algae removal ceramic product purposes is more extensive.
On the basis that common domestic ceramics is produced, adopt the conventional batching of producing, in batching, add an amount of sterilization algae removal rare earth element, also can obtain sterilization and algae killing ceramic material.The household china production technology is produced and is got final product routinely, as forms roll forming, moulding by casting etc.
In practical operation, clay, quartz can have bastard coal rock ballast, ceramic waste residue, boiler ash sediment etc. in order to the substitute that replaces, and alternative addition is 3 parts.In addition, also can in prescription, add other composition in the composition as required, to improve, to adjust the respective performances of sorbing material, as: the salt that adds aluminium salt, molysite, zinc salt and copper, boron, barium, nickel, magnesium, potassium, ammonium etc., reach calcium, siliceous alkaline matter, or acidic materials, or strong oxide or the like.
Described absorption, sterilizing and algae killing material, the fineness of its batching material is controlled to be: cross the powder of 40~1000 mesh sieves, improve the raw material activity, the performance of reinforcing material; Additive is thin more good more, and some additive can be crushed to nano level powder, as colloid combustible etc.Molding mode is half-dried pressure pressure moulding, and batching is added moisture, uses forcing press compression moulding, and moulding is less demanding, as long as be pressed into certain shape, does not need very high intensity.Sorbing material after the moulding burns till through 600~1500 ℃ of temperature, makes finished product, and firing process control gets final product with reference to oven dry, the firing process of the refractory product of refractory industry.Sorbing material can become piece to use, and also can be ground into unsetting powder and use, need be by container when Formless material uses.
Micro porous filtration absorption of the present invention, sterilizing and algae killing material, batching is simple, makes easily, and production cost is low, filters, purified treatment is effective, is used for desalinization, sewage water filtration purification, sterilization algae removal etc.Sorbing material can form the absorption filtering material of macropore, micropore, ultramicropore, and micro-pore diameter can have Centimeter Level, millimeter level, micron order, nanoscale etc.Because micropore has the absorption barrier effect to organic matter in the handled water respectively, the interpolation component that cooperates other again can form organic implicit bridge formation, to strengthen the adsorption effect of micropore, enhancing is to the treatment effect of water, and rare earth element has increased the sterilization algae removal function of product.
Description of drawings
Fig. 1, embodiment of the invention structural representation.
The specific embodiment
Form in conjunction with the foregoing description accompanying drawing and following examples that the present invention is further illustrated.
As shown in the figure, of the present invention kind of micro porous filtration absorption, sterilizing and algae killing material have micropore 2 on the material piece 1, contain following weight percent and form: Al 2O 310~70%, SiO 225~85%.
Test is selected, and preparing burden is mineral inorganic raw material and flammable decomposing materials, and batching is through mixing, after the moulding, burning till and make.Ingredients by weight is formed and is comprised: 1~10 part of Laiwu clay or Suzhou clay, Xintai City's quartz or 0.5~10 part in Zibo quartz, 1~15 part of flammable decomposing materials.
The better ingredients by weight of test is formed to be had:
(1) 5 kilograms of clays, 5 kilograms in quartz, 10 kilograms in sawdust.
Wherein wt content: Al 2O 320~25%, SiO 260~75%.
Raw material is crossed 300 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1350 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal.
(2) 5 kilograms of clays, 5 kilograms in quartz, 10 kilograms of active carbons.
Wherein wt content: Al 2O 322~25%, SiO 260~75%.
Raw material is crossed 250 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1300 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal.
(3) 5 kilograms of clays, 5 kilograms in quartz, 10 kilograms of starch.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 350 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1350 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal.
(4) 5 kilograms of clays, quartzy 5 kilograms, 10 kilograms of starch, add boron oxide 0.7%.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 330 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1300 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.
(5) 5 kilograms of clays, quartzy 5 kilograms, 10 kilograms of starch, add nickel oxide 0.4%.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 360 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1320 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.
(6) black liquid of 3 kilograms of clays, 4 kilograms in quartz, oven dry is 6 kilograms.
Wherein wt content: Al 2O 320~25%, SiO 260~80%.
Raw material is crossed 300 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1200~1350 ℃ of temperature, is used for desalinization and sewage disposal.
(7) 3 kilograms of clays, quartzy 4 kilograms, cellulose, furfural are 6 kilograms.
Wherein wt content: Al 2O 315~25%, SiO 250~80%.
Raw material is crossed 320 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1350 ℃ of temperature, is used for desalinization and sewage disposal, sterilization algae removal.
(8) 4 kilograms of clays, 6 kilograms in quartz, 5 kilograms in sawdust, 0.1 kilogram in aluminum sulfate.
Wherein wt content: Al 2O 344~48%, SiO 265~80%.
Raw material is crossed 120 mesh sieves, and after interpolation water was moistening, the half-dried molded special-shaped fragment of brick of making after the oven dry, burnt till under 800~1000 ℃ of temperature, is used for desalinization and sewage disposal.
(9) 4 kilograms of clays, 6 kilograms in ceramic waste residue, 5 kilograms in sawdust, 0.1 kilogram in aluminum sulfate.
Wherein wt content: Al 2O 328~30%, SiO 230~35%.
Raw material is crossed 260 mesh sieves, and after interpolation water was moistening, the half-dried molded special-shaped fragment of brick of making after the oven dry, burnt till under 800~1000 ℃ of temperature, is used for desalinization and sewage disposal.
(10) 6 kilograms of clays, 8 kilograms in quartz, 4 kilograms of the last plastic microspheres of bubble.
Wherein wt content: Al 2O 322~25%, SiO 260~70%.
Raw material is crossed 80 mesh sieves, and after interpolation water was moistening, the half-dried molded fragment of brick of making after the oven dry, burnt till under 1150~1200 ℃ of temperature, is used for desalinization and sewage disposal.
(11) 7 kilograms of clays, 5 kilograms in quartz, 9 kilograms in sawdust, 0.3 kilogram of brium carbonate.
Wherein wt content: Al 2O 345~55%, SiO 230~40%.
Raw material is crossed 200 mesh sieves, and after interpolation water was moistening, the half-dried molded fragment of brick of making after the oven dry, burnt till under 800~900 ℃ of temperature, is used for desalinization and sewage disposal.
(12) aluminium oxide, silica, zirconia are respectively 30 kilograms, add nickel oxide 0.2%, boron oxide 0.4%, 9 kilograms of starch.
Wherein wt content: Al 2O 330~34%, SiO 230~34%.
Raw material is crossed 250 mesh sieves, and after interpolation water was moistening, the half-dried molded fragment of brick of making after the oven dry, burnt till under 1000~1300 ℃ of temperature, is used for desalinization and sewage disposal, sterilization algae removal.
(13) aluminium oxide, silica, magnesia, zirconia are respectively 25 kilograms, add nickel oxide 0.3%, boron oxide 0.5%, 7 kilograms of starch.
Wherein wt content: Al 2O 324~26%, SiO 224~26%.
Raw material is crossed 220 mesh sieves, and after interpolation water was moistening, the half-dried molded fragment of brick of making after the oven dry, burnt till under 900~1200 ℃ of temperature, is used for desalinization and sewage disposal, sterilization algae removal.
(14) 5 kilograms of clays, quartzy 5 kilograms, 10 kilograms of starch, add nickel oxide 0.2%, boron oxide 0.5%.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 350 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1320 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.
(15) 5 kilograms of clays, quartzy 5 kilograms, 0.2 kilogram of Xintai City's feldspar, 10 kilograms of starch, add nickel oxide 0.3%, boron oxide 0.5%.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 350 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1100~1300 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.
(16) 5 kilograms of clays, 5 kilograms in quartz, 5 kilograms of nano-colloid combustibles.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 350 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1100~1200 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.
(17) 5 kilograms of clays, quartzy 5 kilograms, 10 kilograms of starch, add silver nitrate 0.6%.
Wherein wt content: Al 2O 323~24%, SiO 260~70%.
Raw material is crossed 350 mesh sieves, and is half-dried molded after interpolation water is moistening, after the oven dry, burns till under 1150~1300 ℃ of temperature, is ground into bulk cargo, is used for desalinization and sewage disposal, sterilization algae removal.

Claims (10)

1, a kind of micro porous filtration absorption, sterilizing and algae killing material have micropore on the material piece, it is characterized in that containing following weight percent and form: Al 2O 310~70%, SiO 225~85%.
2, absorption according to claim 1, sterilizing and algae killing material is characterized in that by mineral inorganic raw material and flammable decomposing materials through mixing, after the moulding, burning till and make.
3, absorption according to claim 2, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
1~10 part of clay, 0.5~10 part in quartz, 1~15 part of flammable decomposing materials.
4, absorption according to claim 3, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
1~10 part of clay, quartzy 0.5~10 part, 1~15 part of flammable decomposing materials, add rare earth element raw material 0.1~2%.
5, absorption according to claim 3, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
10 parts of 5 parts of clays, 5 parts in quartz, sawdust or active carbon or starch.
6, absorption according to claim 3, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
6 parts of the black liquids of 3 parts of clays, 4 parts in quartz, oven dry.
7, absorption according to claim 3, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
4 parts of clays, 6 parts in quartz, 5 parts in sawdust, 0.1 part in aluminum sulfate.
8, absorption according to claim 3, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
6 parts of clays, 8 parts in quartz, 4 parts of the last plastic microspheres of bubble.
9, absorption according to claim 4, sterilizing and algae killing material is characterized in that its ingredients by weight composition comprises:
Select in aluminium oxide, silica, magnesia, iron oxide, calcium oxide, zirconia, the medical stone respectively to add 5~50 parts, 1~15 part of flammable decomposing materials adds sterilization algae removal rare earth element 0.1~2%.
10, absorption according to claim 3, sterilizing and algae killing material, the material fineness that it is characterized in that preparing burden is controlled to be:
Cross 40~1000 mesh sieves, molding mode is half-dried pressure pressure moulding.
CNB021354200A 2002-08-13 2002-08-13 Microporous filtering adsorbing, sterilizing and algae killing material Expired - Fee Related CN1140334C (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337931C (en) * 2005-06-20 2007-09-19 许庆华 Attapulgite algicide
CN101450856B (en) * 2007-12-03 2011-09-07 北京有色金属研究总院 Oxide ceramic filtering material and preparation method thereof
CN102350127A (en) * 2011-09-07 2012-02-15 蚌埠市华顺电动机械厂 Porous composite filter element and preparation method thereof
CN103551108A (en) * 2013-09-25 2014-02-05 蚌埠德美过滤技术有限公司 Long-handle flat peach pit shell modified active carbon catalysis adsorbent and preparation method thereof
CN110143828A (en) * 2019-07-02 2019-08-20 陈两坚 A kind of health ceramic purifying filter and preparation method thereof
CN110734277A (en) * 2019-08-23 2020-01-31 福建贝迪陶瓷科技有限公司 artificial corallite formula and its making process

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337931C (en) * 2005-06-20 2007-09-19 许庆华 Attapulgite algicide
CN101450856B (en) * 2007-12-03 2011-09-07 北京有色金属研究总院 Oxide ceramic filtering material and preparation method thereof
CN102350127A (en) * 2011-09-07 2012-02-15 蚌埠市华顺电动机械厂 Porous composite filter element and preparation method thereof
CN102350127B (en) * 2011-09-07 2014-07-16 蚌埠市华顺电动机械厂 Porous composite filter element and preparation method thereof
CN103551108A (en) * 2013-09-25 2014-02-05 蚌埠德美过滤技术有限公司 Long-handle flat peach pit shell modified active carbon catalysis adsorbent and preparation method thereof
CN110143828A (en) * 2019-07-02 2019-08-20 陈两坚 A kind of health ceramic purifying filter and preparation method thereof
CN110734277A (en) * 2019-08-23 2020-01-31 福建贝迪陶瓷科技有限公司 artificial corallite formula and its making process

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