CN1401820A - Ordinary temp. parkerizing liquid - Google Patents
Ordinary temp. parkerizing liquid Download PDFInfo
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- CN1401820A CN1401820A CN 02135551 CN02135551A CN1401820A CN 1401820 A CN1401820 A CN 1401820A CN 02135551 CN02135551 CN 02135551 CN 02135551 A CN02135551 A CN 02135551A CN 1401820 A CN1401820 A CN 1401820A
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- nitrate
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- zinc
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Abstract
An ordinary-temp phosphating liquid for the phosphate treatment of surface of iron and steel contains phosphoric acid (2-4 wt.%), zinc oxide (0.4-0.6 wt.%), zinc nitrate (0.5-1.5 wt.%), nickel nitrate (3-5 wt.%), manganese nitrate (2-4 wt.%), sodium borofluorate (0.2-1 wt.%), sodium chlorate (2-3 wt.%), citric acid (0.5-2 wt.%), and softened water (the rest). Its advantages are high stability, long film-forming time, and high film strength and resistance to corrosion.
Description
(1) technical field
The invention belongs to the technical field of surface chemistry, particularly a kind of steel surface is carried out parkerized normal-temperature phosphorizing liquid.
(2) background technology
Steel surface is carried out bonderizing, and the phosphatization liquid use temperature height that tradition is used, power consumption are greatly, the time is long, cost is high.For resembling large-scale workpieces such as automobile chassis and component,, concerning some medium-sized and small enterprises, relatively more difficult especially if carry out the medium and high temperature phosphatization.Disclose 2 kinds of black liquid and technologies thereof of carrying out step-by-step processing as Chinese patent CN1076225, CN1077757, though step-by-step processing can obtain the black phosphating film, film forming is more loose, and technological process is long, the cost height.Reach its technology altogether as the open phosphatization liquid of Chinese patent CN1231705, its use temperature is the 15-75 degree, and cost is than higher, and film formation time is long, and film forming is loose, and solidity to corrosion is poor, is not suitable for resembling automobile chassis and is operated in the more abominable workpiece of environment like this.
(3) summary of the invention
The object of the present invention is to provide a kind of phosphatization liquid good stability, long, the one-tenth normal-temperature phosphorizing liquid that film toughness is big, solidity to corrosion is strong of film formation time.
The object of the present invention is achieved like this:
Normal-temperature phosphorizing liquid of the present invention is made up of following substances in percentage by weight,
Phosphoric acid 2.0-4.0%
Zinc oxide 0.4-0.6%
Zinc nitrate 0.5-1.5%
Nickelous nitrate 3.0-5.0%
Manganous nitrate 2.0-4.0%
Boron fluoric acid sodium 0.2-1.0%
Sodium chlorate 2.0-3.0%
Citric acid 0.5-2.0%
The softening water surplus
Normal-temperature phosphorizing liquid of the present invention owing to added compound accelerator and composite passivant---nickelous nitrate, manganous nitrate, boron fluoric acid sodium and sodium chlorate, make phosphatize phosphate coat and workpiece to combine speed fast, in conjunction with more firm.Phosphatization liquid phosphatization is speeded up, and make film forming and intensity big.
The production method of normal-temperature phosphorizing liquid of the present invention, at first that zinc oxide is moistening with mixes with small amount of water, add phosphoric acid, after the dissolving fully, add other raw material again, stirring gets final product.
Normal-temperature phosphorizing liquid of the present invention, its using method is also fairly simple, and processed workpiece earlier will be through technologies such as pre-treatment, degreasing, table accent, make workpiece surface not have oil, rustless and foul, adopt the construction of dipping or spraying method, handled at normal temperatures 3-5 minute, need not heating, save the energy, easy to operate.Processed workpiece film forming densification, even, continuous, film formation time is short, becomes film toughness big, can satisfy the requirement of workpiece such as automobile.
Therefore, normal-temperature phosphorizing liquid of the present invention has phosphatization liquid good stability, long, the one-tenth advantage that film toughness is big, solidity to corrosion is strong of film formation time.
(4) embodiment
Embodiment 1:
Normal-temperature phosphorizing liquid of the present invention, form by following substances in percentage by weight:
Phosphatase 24 .0%
Zinc oxide 0.55%
Zinc nitrate 1.5%
Nickelous nitrate 3.0%
Manganous nitrate 3.5%
Boron fluoric acid sodium 0.8%
Sodium chlorate 2.5%
Citric acid 2.0%
The softening water surplus
Embodiment 2: normal-temperature phosphorizing liquid of the present invention, form by following substances in percentage by weight:
Phosphoric acid 3.0%
Zinc oxide 0.5%
Zinc nitrate 1.0%
Nickelous nitrate 3.5%
Manganous nitrate 3.0%
Boron fluoric acid sodium 0.5%
Sodium chlorate 2.5%
Citric acid 1.0%
The softening water surplus
Claims (3)
1. normal-temperature phosphorizing liquid is characterized in that: forms by following substances in percentage by weight,
Phosphoric acid 2.0-4.0%
Zinc oxide 0.4-0.6%
Zinc nitrate 0.5-1.5%
Nickelous nitrate 3.0-5.0%
Manganous nitrate 2.0-4.0%
Boron fluoric acid sodium 0.2-1.0%
Sodium chlorate 2.0-3.0%
Citric acid 0.5-2.0%
The softening water surplus
2. normal-temperature phosphorizing liquid according to claim 1 is characterized in that: be made up of following substances in percentage by weight:
Phosphatase 24 .0%
Zinc oxide 0.55%
Zinc nitrate 1.5%
Nickelous nitrate 3.0%
Manganous nitrate 3.5%
Boron fluoric acid sodium 0.8%
Sodium chlorate 2.5%
Citric acid 2.0%
The softening water surplus
3. normal-temperature phosphorizing liquid according to claim 1 is characterized in that: be made up of following substances in percentage by weight:
Phosphoric acid 3.0%
Zinc oxide 0.5%
Zinc nitrate 1.0%
Nickelous nitrate 3.5%
Manganous nitrate 3.0%
Boron fluoric acid sodium 0.5%
Sodium chlorate 2.5%
Citric acid 1.0%
The softening water surplus
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135551 CN1259451C (en) | 2002-09-18 | 2002-09-18 | Ordinary temp. parkerizing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135551 CN1259451C (en) | 2002-09-18 | 2002-09-18 | Ordinary temp. parkerizing liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1401820A true CN1401820A (en) | 2003-03-12 |
| CN1259451C CN1259451C (en) | 2006-06-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02135551 Expired - Fee Related CN1259451C (en) | 2002-09-18 | 2002-09-18 | Ordinary temp. parkerizing liquid |
Country Status (1)
| Country | Link |
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| CN (1) | CN1259451C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605363A (en) * | 2012-04-17 | 2012-07-25 | 安徽启明表面技术有限公司 | Room-temperature type quick-drying brushing type phosphorizing liquid and preparation method thereof |
| CN101665936B (en) * | 2009-09-27 | 2012-11-28 | 大连三达奥克化学股份有限公司 | Normal-temperature phosphating agent for pre-processing before spray-coating of steel plate workpiece and preparation method thereof |
| CN103397320A (en) * | 2013-08-20 | 2013-11-20 | 安徽工业大学 | Cathodic electrophoresis pre-treatment liquor used on surface of hot-galvanized plate of automobile |
| CN103422082A (en) * | 2012-05-17 | 2013-12-04 | 中化化工科学技术研究总院 | Neodymium-iron-boron magnetic material zinc-series phosphatization liquid and application method thereof |
| CN103643229A (en) * | 2013-11-26 | 2014-03-19 | 常熟市福熙机械零部件制造有限公司 | Phosphating solution for metal fastener |
| CN103805983A (en) * | 2012-11-08 | 2014-05-21 | 北京中科三环高技术股份有限公司 | Surface treatment method for permanent magnet material by adopting phosphorization agent to carry out phosphorization treatment |
| CN104087920A (en) * | 2014-06-30 | 2014-10-08 | 姜洪俊 | Zinc phosphating liquid |
| CN104120418A (en) * | 2013-04-25 | 2014-10-29 | 国家电网公司 | Room temperature fast phosphatization solution and preparation method thereof |
| CN104674204A (en) * | 2015-02-11 | 2015-06-03 | 安徽华通铸业有限公司 | Phosphating treatment fluid for aluminum alloy casting piston |
| CN104711562A (en) * | 2015-03-18 | 2015-06-17 | 周子豪 | Ternary phosphating agent |
| CN106048574A (en) * | 2016-07-15 | 2016-10-26 | 贵州钢绳股份有限公司 | Steel wire rope composite coating agent and coating method |
| CN107338428A (en) * | 2017-06-02 | 2017-11-10 | 余卫民 | Cobalt, zinc, iron ternary system phosphate metal conditioner, preparation method and composite deposition thing |
| US9926628B2 (en) | 2013-03-06 | 2018-03-27 | Quaker Chemical Corporation | High temperature conversion coating on steel and iron substrates |
-
2002
- 2002-09-18 CN CN 02135551 patent/CN1259451C/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665936B (en) * | 2009-09-27 | 2012-11-28 | 大连三达奥克化学股份有限公司 | Normal-temperature phosphating agent for pre-processing before spray-coating of steel plate workpiece and preparation method thereof |
| CN102605363B (en) * | 2012-04-17 | 2013-11-20 | 安徽启明表面技术有限公司 | Room-temperature type quick-drying brushing type phosphorizing liquid and preparation method thereof |
| CN102605363A (en) * | 2012-04-17 | 2012-07-25 | 安徽启明表面技术有限公司 | Room-temperature type quick-drying brushing type phosphorizing liquid and preparation method thereof |
| CN103422082A (en) * | 2012-05-17 | 2013-12-04 | 中化化工科学技术研究总院 | Neodymium-iron-boron magnetic material zinc-series phosphatization liquid and application method thereof |
| CN103422082B (en) * | 2012-05-17 | 2017-07-18 | 中化化工科学技术研究总院 | Neodymium-iron-boron magnetic material Zinc phosphating solution and its application method |
| CN103805983A (en) * | 2012-11-08 | 2014-05-21 | 北京中科三环高技术股份有限公司 | Surface treatment method for permanent magnet material by adopting phosphorization agent to carry out phosphorization treatment |
| US9926628B2 (en) | 2013-03-06 | 2018-03-27 | Quaker Chemical Corporation | High temperature conversion coating on steel and iron substrates |
| CN104120418A (en) * | 2013-04-25 | 2014-10-29 | 国家电网公司 | Room temperature fast phosphatization solution and preparation method thereof |
| CN104120418B (en) * | 2013-04-25 | 2016-12-28 | 国家电网公司 | A kind of ordinary-temp fast bonderizing liquor and preparation method thereof |
| CN103397320B (en) * | 2013-08-20 | 2015-07-15 | 安徽工业大学 | Cathodic electrophoresis pre-treatment liquor used on surface of hot-galvanized plate of automobile |
| CN103397320A (en) * | 2013-08-20 | 2013-11-20 | 安徽工业大学 | Cathodic electrophoresis pre-treatment liquor used on surface of hot-galvanized plate of automobile |
| CN103643229A (en) * | 2013-11-26 | 2014-03-19 | 常熟市福熙机械零部件制造有限公司 | Phosphating solution for metal fastener |
| CN103643229B (en) * | 2013-11-26 | 2016-08-17 | 常熟市福熙机械零部件制造有限公司 | Metal fastenings Phosphating Solution |
| CN104087920B (en) * | 2014-06-30 | 2016-07-20 | 姜洪俊 | A kind of Zinc phosphating solution |
| CN104087920A (en) * | 2014-06-30 | 2014-10-08 | 姜洪俊 | Zinc phosphating liquid |
| CN104674204A (en) * | 2015-02-11 | 2015-06-03 | 安徽华通铸业有限公司 | Phosphating treatment fluid for aluminum alloy casting piston |
| CN104711562A (en) * | 2015-03-18 | 2015-06-17 | 周子豪 | Ternary phosphating agent |
| CN104711562B (en) * | 2015-03-18 | 2017-12-19 | 周子豪 | A kind of ternary bonderite |
| CN106048574A (en) * | 2016-07-15 | 2016-10-26 | 贵州钢绳股份有限公司 | Steel wire rope composite coating agent and coating method |
| CN107338428A (en) * | 2017-06-02 | 2017-11-10 | 余卫民 | Cobalt, zinc, iron ternary system phosphate metal conditioner, preparation method and composite deposition thing |
| CN107338428B (en) * | 2017-06-02 | 2019-01-11 | 余卫民 | Cobalt, zinc, iron ternary system phosphate metal conditioner, preparation method and composite deposition object |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1259451C (en) | 2006-06-14 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| DD01 | Delivery of document by public notice |
Addressee: China Heavy-Duty Car Group Co., Ltd. Document name: Notification of Termination of Patent Right |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060614 Termination date: 20140918 |
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| EXPY | Termination of patent right or utility model |