CN1401709A - Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric - Google Patents
Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric Download PDFInfo
- Publication number
- CN1401709A CN1401709A CN 02133084 CN02133084A CN1401709A CN 1401709 A CN1401709 A CN 1401709A CN 02133084 CN02133084 CN 02133084 CN 02133084 A CN02133084 A CN 02133084A CN 1401709 A CN1401709 A CN 1401709A
- Authority
- CN
- China
- Prior art keywords
- ink
- dye
- jet printing
- dyestuff
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 13
- 238000007641 inkjet printing Methods 0.000 title claims abstract description 13
- 239000007921 spray Substances 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000975 dye Substances 0.000 claims description 59
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- -1 sterilant Substances 0.000 claims description 6
- 229920004933 Terylene® Polymers 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 230000001680 brushing effect Effects 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 2
- 238000010128 melt processing Methods 0.000 claims 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 3
- 230000005670 electromagnetic radiation Effects 0.000 abstract description 2
- AXXIAUCBOLNQHP-UHFFFAOYSA-N methylsulfonylformic acid Chemical group CS(=O)(=O)C(O)=O AXXIAUCBOLNQHP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 32
- 150000001875 compounds Chemical class 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000005374 membrane filtration Methods 0.000 description 4
- 238000010422 painting Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000003953 γ-lactams Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000004304 visual acuity Effects 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 125000000837 carbohydrate group Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
A water-proof ink for ink-jet printing, spray drawing, or ink-jet printing on fabric is characterized by that the dye containing carboxymethyl sulfone group is used for preparing said ink. Said dye has the formula: Dye-SO2CH2CH2CO2(-)M(+), where Dye is the mother body of dye and M is chosen from H(+), Na(+), K(+), NH4(+) and Li(+). Under the action of heat, electromagnetic radiation, or microwave of nozzle, said dye can become water-insoluble Dye-SO2CH3 or lower-solubility Dye-SO2COOH. The printed image has features of high water fastness, and high definition.
Description
Technical field
The invention belongs to the digital ink-jet printed technical field of computer ink-jet printing, color painting and yarn fabric, relate to and utilize the temporary molten type dispersed dye of water in the technology of ink jet process.
Background technology
Usually use means such as heat, microwave or electromagnetism heating in ink-jet technology, make the ink that arrives nozzle by the micropore generation bubble of vaporizing rapidly, along with expanding of bubble, the ink of jet hole is extruded and becomes little drop, sprays to matrixes such as paper, cloth.
The China ink that uses in the ink-jet technology has two kinds of water-based ink and oil-based inks.Because water-based ink cheapness, safe, pollution-free, the literal or the pattern organic solvent-resistant that form, thereby become present principal item.Water-based ink need use dyestuff (or pigment) to be dissolved in (or being scattered in) water, adds other component and forms ink.In use, the outstanding problem of water-based ink is that the literal or the image water resistance that are sprayed into are poor, and promptly color fastness to water is low.
In order to improve color fastness to water, people propose with non-water-soluble type pigment as tinting material, as USP 6113680, USP 6007339, but pigment is present in the water to disperse to form, and often existence reduces colourity, pigment particles easily stops up shower nozzle, the long-time stability that stores of dispersion system is poor than dye solution, the deficiencies such as printout scratch resistance difference of formation.
Water-soluble dye overcome the above-mentioned deficiency of pigment as matching stain, substantive dyestuff, reactive dyestuffs, basic dyestuff etc., but the color fastness to water of its water-soluble China ink is relatively poor.For this reason, USP 5250107 proposes to add the polymer salt that contains ammonium, zirconium in the composition of China ink, increases the hydrogen bond between dyestuff and matrix; USP 6106598 proposes to add the silica gel colloid in China ink; USP 6224660 proposes to add siliceous organic polymer in China ink; USP6001899 proposes to add and contains quaternary ammonium salt cationic polymer and anionic dyestuff formation sat linkage etc., all is to use the improvement that prescription proposes from dyestuff.
On the water-soluble dye molecular structure improved, people selected the big substantive dyestuff of molecular weight for use as far as possible.But molecular weight is crossed the solubleness that conference influences dyestuff.USP 6221189 proposes to introduce carbohydrate group on dye molecule, improve the avidity of dyestuff and matrix; USP 6251174 changes part sulfonic acid water soluble group in the dye molecule into hydroxy-acid group etc.These measures have improved the water tolerance of dyestuff to a certain extent.
Summary of the invention
The objective of the invention is: use a kind of novel ink-jet dyestuff, improve the literal of ink-jet formation or the water-fast character of picture.
The present invention uses a class temporarily water-soluble dyestuff, this class dyestuff makes their energy water-soluble by means of the sulfone carboxyphenyl in the molecule, but when printing, because of shower nozzle heat, microwave or electromagnetic action, the carboxyl that dyestuff (or part dyestuff) is sloughed on the molecule forms water-insoluble dyestuff, makes the dyestuff picture of formation or literal water insoluble and improve water tolerance.
The spray ink Printing dyestuff has many particular requirements.As dyestuff must obtain resolving power height, no plumage line, the waterproof fastness is good, light fastness is good, have good optical density(OD) etc.In addition, after China ink is directed onto matrix (as paper etc.) and goes up rapidly drying to prevent contamination; Prevent to make the obstruction shower nozzle because of the water in the ink volatilizees after shower nozzle from not working for a long time; Ink also must be stablized in period of storage, not decompose, do not precipitate.
Technical scheme of the present invention is: introduce carboxylic methylsulfonyl group in dyestuff, owing to the ionization of carboxyl and the reasons such as dipolar nature of molecule, it is water-soluble that dyestuff is had, and its general structure is (I), and Dye is a dye matrix in the formula, and M is H
+, N
a +, K
+, NH
4 +, L
i +Deng alkali metal cation, proton or ammonium ion.
Dye-SO
2CH
2COO
-M
+ (I)
This class dyestuff is when ink-jet, and through the heat effect of nozzle, or electromagnetic radiation or microwave action, part dye molecule decarboxylize forms water-insoluble dyestuff (II).
After the not decarboxylized dyestuff of part runs into acidic paper, can form the lower dyestuff Dye-SO of water-soluble through ion-exchange
2COOH.
Effect of the present invention and benefit are: form thus colour, black and white writings and image have water-proof characteristics, the writings and image that forms than at present used water-soluble dye ink jet type has higher color fastness to water.This class China ink does not produce the plumage line, the resolving power height simultaneously.Ink is stablized in period of storage, is not decomposed, do not precipitate.
Embodiment
Dye is the parent of any dyestuff or chromophore compound among structural formula (I), (II), or is connected with the linking group of any dyestuff or chromophore compound.Dyestuff can be azoic dyestuff, anthraquinone dye and other dyestuff.In order to strengthen the water-soluble of dyestuff, can on the molecule of dyestuff, introduce sulfonic group or carboxyl.As:
Yellow dyes:
Magenta dye:
Cyan dye:
Black dyes:
Deng, but the invention is not restricted to these structures.
The formed ink of dyestuff is formed and is contained dyestuff 0.5-20%; Water 10-90%; 2-60% such as low boiling point organic solvent such as ethanol, propyl alcohol, Virahol; 2-60% such as high boiling organic solvent such as ethylene glycol, propylene glycol, butyleneglycol, pentanediol, glycerine, glycol ether and ether thereof, Diethylene Glycol and ether thereof, tetraethylene-glycol and ether thereof, polyoxyethylene glycol, polyvinyl alcohol, 2-Pyrrolidone, N-Methyl pyrrolidone; Sterilant 0-2%; Tensio-active agent 0.001-3%; PH regulator agent such as ammoniacal liquor, sodium hydroxide, potassium hydroxide etc., regulating pH according to the solvent property of dyestuff is 6-9.5.
The dyestuff preparation can at room temperature be carried out, if dissolution rate is overflow, can be heated to 50 ℃ or higher temperature preparation down.
Join dye solution through the membrane filtration of 0.1-0.4 micron pore size, be preferably 0.2 micron.Excessive particle can cause shower nozzle to stop up.Filtering ink all should carry out in clean room in packing and last handling process, prevents that dust from entering ink and stopping up shower nozzle.
In the time of on being applied to terylene and mixed fibre thereof, the dyestuff that preferably uses no sulfonic acid group is as (III), (IV), (V), (VI), (VII), (X) etc., after ink is sprayed on the fiber, melts in the system thermal treatment 5 seconds to 5 minutes 130-220 ℃ heat again.Dyestuff after handling like this decarboxylation fully forms dyestuff (II), and energy infiltrated fiber inside, improves the water-fast of stamp and washes and light fastness.
Most preferred embodiment
Example 1. is digested compound (III) with 2 and is dissolved in 85 milliliters of 50 ℃ of water, regulating pH with ammoniacal liquor is 8.0, add 5 milliliters of ethylene glycol, 3 milliliters of glycol ethers, 2 milliliters of ethanol, 3 milliliters of 2-Pyrrolidones, 0.1 milliliter of 20%NP-10 (tensio-active agent), stir evenly the PC membrane filtration of back with 0.2 micron pore size, filtrate is yellow ink, can be used for piezoelectricity and the color ink jet printed and color painting of foaming formula, obtain the yellow literal and the picture of water-fast excellence.
Example 2. is sprayed onto example 1 gained ink on terylene or the blend polyester fiber and forms image, fabric is melted 2 minutes 180 ℃ of heat again, can get the terylene and the BLENDED FABRIC stamp thereof of water resistance excellence.
Example 3. is digested compound (XII) with 4 and is dissolved in 83 milliliters of 50 ℃ of water, be adjusted to pH8.0 with ammoniacal liquor, add 5 milliliters of ethylene glycol, 3 milliliters of glycol ethers, 2 milliliters of ethanol, 3 milliliters of 2-Pyrrolidones, 0.1 milliliter of 20%NP-10 (tensio-active agent), stir evenly the PC membrane filtration of back with 0.2 micron pore size, filtrate is cyan, can be used for piezoelectricity and the color ink jet printed and color painting of foaming formula, obtain the cyan literal or the picture of water-fast excellence.
Example 4. digests with 5 that compound (VIII), 0.5 digests compound (III), 0.5 compound (IV) is dissolved in 81 milliliters of 50 ℃ of water, regulating pH with ammoniacal liquor is 8.0, add 5 milliliters of ethylene glycol, 3 milliliters of glycol ethers, 2 milliliters of ethanol, 3 milliliters of 2-Pyrrolidones, 0.1 milliliter of 20%NP-10 (tensio-active agent), stir evenly the PC membrane filtration of back with 0.2 micron pore size, filtrate is black ink, can be used for piezoelectricity and the color ink jet printed and color painting of foaming formula, obtain the black literal or the picture of water-fast excellence.
Claims (3)
1. the ink of a waterproof ink-jet printing, air brushing and ink-jet printing of fabric is to use the dyestuff that contains the carboxylic methylsulfonyl, it is characterized in that, general formula is (I), and Dye is a dye matrix in the formula, and M is H
+, N
a +, K
+, NH
4 +, Li
+Deng.
Dye-SO
2CH
2COO
-M
+ (I)
2. the ink of a kind of waterproof ink-jet printing according to claim 1, air brushing and ink-jet printing of fabric, it is characterized in that: described dyestuff, make computer printout, air brushing and ink-jet printing of fabric ink with other component such as ethylene glycol, glycerine, glycol ether, Triethylene glycol, 2-Pyrrolidone, N-Methyl pyrrolidone, ethanol, Virahol, tensio-active agent, sterilant, water etc.
3. the ink of a kind of ink-jet printing of fabric according to claim 1 is characterized in that: after described dyestuff is sprayed on terylene and the BLENDED FABRIC thereof, melt processing 5 seconds-5 minutes through 130-220 ℃ of heat, form terylene and BLENDED FABRIC stamp.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02133084 CN1401709A (en) | 2002-09-27 | 2002-09-27 | Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02133084 CN1401709A (en) | 2002-09-27 | 2002-09-27 | Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1401709A true CN1401709A (en) | 2003-03-12 |
Family
ID=4747061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02133084 Pending CN1401709A (en) | 2002-09-27 | 2002-09-27 | Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1401709A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102174271A (en) * | 2011-03-11 | 2011-09-07 | 河南洛染股份有限公司 | Temporarily water-soluble disperse dye and preparation method and application thereof |
| CN102190925A (en) * | 2010-03-10 | 2011-09-21 | 江南大学 | Preparation method of disperse fluorescence red dye ink used in terylene ink-jet transfer printing |
| CN102199364A (en) * | 2011-03-11 | 2011-09-28 | 河南洛染股份有限公司 | Blue temporary water-soluble disperse dye, preparation method thereof and application thereof |
| CN113683904A (en) * | 2021-08-31 | 2021-11-23 | 沈阳化工研究院有限公司 | Red dye composition for dyeing and printing |
| CN113755030A (en) * | 2021-08-31 | 2021-12-07 | 沈阳化工研究院有限公司 | Red light blue liquid dye composition and application thereof in textile dyeing and printing |
| CN116622253A (en) * | 2023-05-19 | 2023-08-22 | 临沂市东裕新材料科技有限公司 | Disperse dye composition and preparation method and application thereof |
-
2002
- 2002-09-27 CN CN 02133084 patent/CN1401709A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190925A (en) * | 2010-03-10 | 2011-09-21 | 江南大学 | Preparation method of disperse fluorescence red dye ink used in terylene ink-jet transfer printing |
| CN102190925B (en) * | 2010-03-10 | 2013-10-16 | 江南大学 | Preparation method of disperse fluorescence red dye ink used in terylene ink-jet transfer printing |
| CN102174271A (en) * | 2011-03-11 | 2011-09-07 | 河南洛染股份有限公司 | Temporarily water-soluble disperse dye and preparation method and application thereof |
| CN102199364A (en) * | 2011-03-11 | 2011-09-28 | 河南洛染股份有限公司 | Blue temporary water-soluble disperse dye, preparation method thereof and application thereof |
| CN102174271B (en) * | 2011-03-11 | 2013-06-05 | 河南洛染股份有限公司 | Temporarily water-soluble disperse dye and preparation method and application thereof |
| CN102199364B (en) * | 2011-03-11 | 2014-04-09 | 河南洛染股份有限公司 | Blue temporary water-soluble disperse dye, preparation method thereof and application thereof |
| CN113683904A (en) * | 2021-08-31 | 2021-11-23 | 沈阳化工研究院有限公司 | Red dye composition for dyeing and printing |
| CN113755030A (en) * | 2021-08-31 | 2021-12-07 | 沈阳化工研究院有限公司 | Red light blue liquid dye composition and application thereof in textile dyeing and printing |
| CN113755030B (en) * | 2021-08-31 | 2023-06-02 | 沈阳化工研究院有限公司 | Red light blue liquid dye composition and application thereof |
| CN113683904B (en) * | 2021-08-31 | 2023-06-13 | 沈阳化工研究院有限公司 | Red dye composition for dyeing and printing |
| CN116622253A (en) * | 2023-05-19 | 2023-08-22 | 临沂市东裕新材料科技有限公司 | Disperse dye composition and preparation method and application thereof |
| CN116622253B (en) * | 2023-05-19 | 2024-04-12 | 临沂市东裕新材料科技有限公司 | Disperse dye composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102863818B (en) | Preparation method of pigment purple 3 | |
| DE10242875B4 (en) | Process for producing sulfonated solid particles | |
| US6797016B1 (en) | Dye composition, their production and their use | |
| CN1401709A (en) | Ink for waterproof ink-jet printing, spray drawing and ink-jet printing of fabric | |
| US6336721B1 (en) | Multicolor ink jet printing method | |
| CN103436073A (en) | Water-based dispersion liquid dye ink for ink jetting and printing of polyester textile | |
| EP0827985B1 (en) | Water soluble copper phthalocyanine dyes, their manufacture and their use | |
| CN100335572C (en) | Nano dye ink for ink jet printing and preparation method thereof | |
| DE3029581A1 (en) | WATER-INSOLUBLE SALT OF BASIC DYES | |
| CN1974694A (en) | Water-base writing ink composition | |
| CN1613924A (en) | Digital painting printing ink containing pigment and dye, preparation thereof | |
| EP0951515B1 (en) | Multicolour ink jet printing method | |
| TWI701301B (en) | Cationic dye ink composition for digital inkjet and method for manufacturing printed textile | |
| EP0832937B1 (en) | Water-soluble perylene dyes, their preparation and use | |
| DE4225357A1 (en) | Lustrous pigment of flake substrate coated with basic organic colourant - used in lacquer, printing ink, plastics, glass, ceramics and decorative cosmetic formulation. | |
| CN110872789A (en) | Cationic dye ink composition for digital ink jet and preparation method of printed textile | |
| JP3105323B2 (en) | Black anionic dyes, compositions thereof, inks comprising such dyes or compositions, printing methods for substrates and printed paper | |
| CN102618116A (en) | Anti-UV (ultraviolet) dye ink and preparation method for same | |
| CN101117470A (en) | Light-stable water-resistant microemulsion aqueous ink | |
| DE60222639T4 (en) | USE OF PIGMENT DYES FOR DISPERSION DYEING FROM AQUEOUS MEDIA | |
| EP1037950A1 (en) | Uv and water-resistant ink or china ink | |
| US7097699B2 (en) | Composition for printing recording materials | |
| JPH0657653A (en) | Ink composition for ink jet-printing | |
| DE19838298B4 (en) | dye preparations | |
| CN112094527A (en) | Concentrated ink composition for organic solvent gravure printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |