CN1390894A - Electrically conductive paint for internal surface of battery shell and its preparing process - Google Patents
Electrically conductive paint for internal surface of battery shell and its preparing process Download PDFInfo
- Publication number
- CN1390894A CN1390894A CN 02134252 CN02134252A CN1390894A CN 1390894 A CN1390894 A CN 1390894A CN 02134252 CN02134252 CN 02134252 CN 02134252 A CN02134252 A CN 02134252A CN 1390894 A CN1390894 A CN 1390894A
- Authority
- CN
- China
- Prior art keywords
- electrically conductive
- internal surface
- battery shell
- conductive paint
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Conductive Materials (AREA)
Abstract
An electrically conductive paint for the inner surface of battery shell is prepared from one or more of polyurethane resin, acrylic resin and epoxy resin (10-20 wt portions), electric conducting powder (30-50) and organic solvent (30-60) through mixing said resin with disperser, and sequentially adding organic solvent, electric conducting powder and assistant. Its advantages are use of spray coating, high stability and no pollution.
Description
Technical field
The present invention relates to the paint field field, in more detail electrically conductive paint for internal surface of battery shell.
The invention still further relates to the preparation method of this coating.
Background technology
China's alkaline cell adopts electroplate liquid to carry out electronickelling technology plating to battery case in producing more, and is seriously polluted, and the bore of battery case is little simultaneously, and body is long, can form deep hole, blind hole.Galvanized distribution of current relationship makes inner walls of deep holes be difficult to cover coating fully, equably, and interior wall coating often [approach partially, make the percentage of A-class goods lower, battery electrical property in preservation period descends naturally, and the SC short circuit current is 4-6.
Summary of the invention
The object of the present invention is to provide a kind of electrically conductive paint for internal surface of battery shell, this coating does not need to apply with electro-plating method, and uses the Airless spraying method, and internal surface of battery shell is covered fully, and coating thickness is even, steady quality, and percentage of A-class goods height, pollution-free.
The present invention also aims to provide the preparation method of above-mentioned coating.
The parts by weight of electrically conductive paint for internal surface of battery shell of the present invention are composed as follows:
Resin 10-20
Conducting powder 30-50
Organic solvent 30-60
Described resin be polyurethane resin, acrylic resin, Resins, epoxy one or more.
Described conducting powder is metal powder and/or the carbon dust with electroconductibility, and described metal powder comprises: copper powder, silver powder, nickel powder wherein one or more; Described carbon dust is acetylene carbon black and/or Graphite Powder 99.
Described organic solvent is the solvent of resin, comprises acetone, butanone, chloroform, gasoline or benzene.Wherein butanone is optimal selection.
In order to obtain steady quality, uniform coating, can in coating, add dispersion agent 0.1-1 part weight.
Described dispersion agent is polyurethane resin to be scattered in the solvent and the tensio-active agent that forms colloidal solution.Nonionogenic tenside ethoxylation methyl glucoside stearate for example, the methyl glucoside stearate, lauroyl diethanolamine, propylene glycol monostearate, Arlacel-20, Arlacel-40, Arlacel-60, Arlacel-80, tween 20, Tween-40, Tween-60, tween-80, glyceryl monostearate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene stearic acid ester, sucrose fatty ester, polyethylene oxide-poly(propylene oxide), Brij92, polyoxyethylene (n) cocounut oil acyl thanomin, the polyoxypropylene butyl ether, Protanal Ester SD-LB, BYK163 wherein one or more.The contriver is through dispersant effect the best of exploration discovery commodity BYK163 by name.
In order further to improve the conductivity of coating, can add conductive auxiliary agent 0.5-2 part weight in the coating.The contriver is through the conductive auxiliary agent best results of exploration discovery commodity EFKA781 by name.
The preparation method of coating of the present invention mixes said components, can use.
The blended preferred order is first with polyurethane resin and dispersant, adds organic solvent and conducting powder, adds conductive auxiliary agent at last.
Preparation method's top condition of coating of the present invention is to stir polyurethane resin and mixture of dispersing agents 15-35 minute; Add organic solvent and conducting powder, stirred 5-20 minute, be ground to particle diameter less than 10 microns; Add conductive auxiliary agent, stirred 2-10 minute.
The present invention's advantage compared with prior art is:
(1) Fa Ming electrically conductive paint for internal surface of battery shell makes the production technique of battery change almost free of contamination Airless spraying into by polluting bigger water plating, reaches environmental requirement.
(2) Fa Ming electrically conductive paint for internal surface of battery shell makes the production technique of battery can adopt the Airless spraying method, and coat-thickness is even, steady quality, and the percentage of A-class goods reaches 100%, and SC circuit reaches 14-16.
Embodiment
Stirred 5 kilograms of polyurethane resin and 0.5 kilogram of BYK163 mixture 20 minutes; Add 40 jin of 45 kilograms in acetone and Graphite Powder 99s, stirred 10 minutes, be ground to particle diameter less than 8 microns; Add 1 kilogram of conductive auxiliary agent EFKA781, stirred 5 minutes, filter the dress bag.Can be used for spraying.
Obtain coating property: color black
The outward appearance viscous liquid
Proportion 1.5
Solids content 56% weight
15 ℃ of burning-points
20 ℃ of viscosity 1500cps
Validity period 1 year
Internal surface of battery shell paint film property: color black
Hardness HB
Sticking power 100%
Electroconductibility 1.2 ohm/cm
104 ℃ of heatproofs
Claims (10)
1, a kind of electrically conductive paint for internal surface of battery shell is characterized in that its parts by weight are composed as follows:
Resin 10-20
Conducting powder 30-50
The described resin of organic solvent 30-60 be polyurethane resin, acrylic resin, Resins, epoxy one or more.
2, electrically conductive paint for internal surface of battery shell according to claim 1 is characterized in that described conducting powder is metal powder and/or the carbon dust with electroconductibility.
3, electrically conductive paint for internal surface of battery shell according to claim 2 is characterized in that described metal powder comprises: copper powder, silver powder, nickel powder wherein one or more; Described carbon dust is acetylene carbon black and/or Graphite Powder 99.
4, electrically conductive paint for internal surface of battery shell according to claim 1 and 2 is characterized in that described organic solvent is the solvent of resin, comprises acetone, butanone, chloroform, gasoline or benzene.
5, electrically conductive paint for internal surface of battery shell according to claim 1 and 2 is characterized in that also comprising dispersion agent 0.1-1 part weight, and described dispersion agent is polyurethane resin to be scattered in the solvent and the tensio-active agent that forms colloidal solution.
6, electrically conductive paint for internal surface of battery shell according to claim 1 and 2 is characterized in that described organic solvent is the solvent of resin, comprises acetone, butanone, chloroform, gasoline or benzene; Also comprise dispersion agent 0.1-1 part weight, described dispersion agent is polyurethane resin to be scattered in the solvent and the tensio-active agent that forms colloidal solution.
7, electrically conductive paint for internal surface of battery shell according to claim 5 is characterized in that described dispersion agent is an ethoxylation methyl glucoside stearate, the methyl glucoside stearate, lauroyl diethanolamine, propylene glycol monostearate, Arlacel-20, Arlacel-40, Arlacel-60, Arlacel-80, tween 20, Tween-40, Tween-60, tween-80, glyceryl monostearate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene stearic acid ester, sucrose fatty ester, polyethylene oxide-poly(propylene oxide), Brij92, polyoxyethylene (n) cocounut oil acyl thanomin, the polyoxypropylene butyl ether, Protanal Ester SD-LB wherein one or more.
8, electrically conductive paint for internal surface of battery shell according to claim 1 and 2 is characterized in that also comprising the conductive auxiliary agent EFKA781 of 0.5-2 part weight.
9, the preparation method of the described electrically conductive paint for internal surface of battery shell of claim 1 is characterized in that elder generation with polyurethane resin and dispersant, adds organic solvent and conducting powder, adds conductive auxiliary agent at last.
10, the preparation method of electrically conductive paint for internal surface of battery shell according to claim 9 is characterized in that stirring polyurethane resin and mixture of dispersing agents 15-35 minute; Add organic solvent and conducting powder, stirred 5-20 minute, be ground to particle diameter less than 10 microns; Add conductive auxiliary agent, stirred 2-10 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02134252 CN1390894A (en) | 2002-06-27 | 2002-06-27 | Electrically conductive paint for internal surface of battery shell and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02134252 CN1390894A (en) | 2002-06-27 | 2002-06-27 | Electrically conductive paint for internal surface of battery shell and its preparing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1390894A true CN1390894A (en) | 2003-01-15 |
Family
ID=4747648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02134252 Pending CN1390894A (en) | 2002-06-27 | 2002-06-27 | Electrically conductive paint for internal surface of battery shell and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1390894A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935489A (en) * | 2010-08-24 | 2011-01-05 | 中国科学院宁波材料技术与工程研究所 | Concave-convex rod conductive coating and preparation method thereof |
| CN102424740A (en) * | 2011-11-25 | 2012-04-25 | 珠海天威飞马打印耗材有限公司 | Outer layer protective aqueous conductive coating for hard rubber charging roller |
| CN102558986A (en) * | 2011-12-30 | 2012-07-11 | 清华大学 | Heavy water reactor fuel canning graphite emulsion paint and preparation method thereof |
| CN102618107A (en) * | 2012-03-31 | 2012-08-01 | 深圳市贝特瑞纳米科技有限公司 | Conductive graphite cream and preparation method thereof |
| CN102952439A (en) * | 2012-11-13 | 2013-03-06 | 西安交通大学 | Composite carbon conductive coating and preparation method thereof |
| CN103342913A (en) * | 2013-06-17 | 2013-10-09 | 哈尔滨工业大学 | Conductive coating material for insulating-ceramic electrosparking technology and method for preparing auxiliary electrode by the conductive coating material |
| CN103396711A (en) * | 2013-06-26 | 2013-11-20 | 南京市荣达树脂有限公司 | Preparation method of conductive resin coating |
| CN103773178A (en) * | 2014-01-20 | 2014-05-07 | 南通天明光电科技有限公司 | Anticorrosive conductive coating |
| CN103773181A (en) * | 2014-01-20 | 2014-05-07 | 南通天明光电科技有限公司 | Magnetic-shielding conductive coating |
| CN104064255A (en) * | 2014-05-31 | 2014-09-24 | 恒天海龙股份有限公司 | Conductive graphite grease for preparing conductive fibers and preparation method thereof as well as method for preparing cellulosic fiber by graphite grease |
| CN104479476A (en) * | 2014-11-18 | 2015-04-01 | 安徽创业机电设备有限公司 | Method for preparing conductive anticorrosive coating from acrylic acid |
| CN105754462A (en) * | 2016-02-26 | 2016-07-13 | 沈阳航天新光集团有限公司 | Composite electric heating paint for flexible base material as well as preparation method and use thereof |
| CN106010155A (en) * | 2016-07-14 | 2016-10-12 | 夏嘉伟 | Composite electromagnetic shielding conductive coating |
| CN106221560A (en) * | 2016-08-03 | 2016-12-14 | 代长华 | A kind of electrochemical sensor electrodes coating material and preparation method thereof |
| CN108346759A (en) * | 2017-12-28 | 2018-07-31 | 江苏海德森能源有限公司 | A kind of lithium battery of high intensity and preparation method thereof |
| CN108816685A (en) * | 2018-07-11 | 2018-11-16 | 张家港市金帆箱柜有限公司 | A kind of anticorrosion process of power battery cabin |
| CN110534229A (en) * | 2019-08-30 | 2019-12-03 | 湖南诺尔得材料科技有限公司 | A kind of conductive silver paste and the preparation method and application thereof that sintering temperature is low |
| CN110534228A (en) * | 2019-08-30 | 2019-12-03 | 湖南诺尔得材料科技有限公司 | A kind of conductive nano silver paste and the preparation method and application thereof |
| CN112409858A (en) * | 2020-11-10 | 2021-02-26 | 横店集团东磁股份有限公司 | Conductive coating for battery case, preparation method and application thereof |
| CN113843462A (en) * | 2021-11-05 | 2021-12-28 | 南京航空航天大学 | Method for improving wire cut electrical discharge machining efficiency of semiconductor by using chemical plating process |
-
2002
- 2002-06-27 CN CN 02134252 patent/CN1390894A/en active Pending
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935489A (en) * | 2010-08-24 | 2011-01-05 | 中国科学院宁波材料技术与工程研究所 | Concave-convex rod conductive coating and preparation method thereof |
| CN102424740A (en) * | 2011-11-25 | 2012-04-25 | 珠海天威飞马打印耗材有限公司 | Outer layer protective aqueous conductive coating for hard rubber charging roller |
| CN102558986B (en) * | 2011-12-30 | 2013-10-16 | 清华大学 | Heavy water reactor fuel canning graphite emulsion paint and preparation method thereof |
| CN102558986A (en) * | 2011-12-30 | 2012-07-11 | 清华大学 | Heavy water reactor fuel canning graphite emulsion paint and preparation method thereof |
| CN102618107A (en) * | 2012-03-31 | 2012-08-01 | 深圳市贝特瑞纳米科技有限公司 | Conductive graphite cream and preparation method thereof |
| CN102618107B (en) * | 2012-03-31 | 2014-10-08 | 深圳市贝特瑞纳米科技有限公司 | Conductive graphite cream and preparation method thereof |
| CN102952439A (en) * | 2012-11-13 | 2013-03-06 | 西安交通大学 | Composite carbon conductive coating and preparation method thereof |
| CN103342913A (en) * | 2013-06-17 | 2013-10-09 | 哈尔滨工业大学 | Conductive coating material for insulating-ceramic electrosparking technology and method for preparing auxiliary electrode by the conductive coating material |
| CN103396711A (en) * | 2013-06-26 | 2013-11-20 | 南京市荣达树脂有限公司 | Preparation method of conductive resin coating |
| CN103773178A (en) * | 2014-01-20 | 2014-05-07 | 南通天明光电科技有限公司 | Anticorrosive conductive coating |
| CN103773181A (en) * | 2014-01-20 | 2014-05-07 | 南通天明光电科技有限公司 | Magnetic-shielding conductive coating |
| CN103773181B (en) * | 2014-01-20 | 2015-11-18 | 南通天明光电科技有限公司 | Magnetic shielding electrically conducting coating |
| CN104064255A (en) * | 2014-05-31 | 2014-09-24 | 恒天海龙股份有限公司 | Conductive graphite grease for preparing conductive fibers and preparation method thereof as well as method for preparing cellulosic fiber by graphite grease |
| CN104479476A (en) * | 2014-11-18 | 2015-04-01 | 安徽创业机电设备有限公司 | Method for preparing conductive anticorrosive coating from acrylic acid |
| CN105754462A (en) * | 2016-02-26 | 2016-07-13 | 沈阳航天新光集团有限公司 | Composite electric heating paint for flexible base material as well as preparation method and use thereof |
| CN106010155A (en) * | 2016-07-14 | 2016-10-12 | 夏嘉伟 | Composite electromagnetic shielding conductive coating |
| CN106221560A (en) * | 2016-08-03 | 2016-12-14 | 代长华 | A kind of electrochemical sensor electrodes coating material and preparation method thereof |
| CN108346759A (en) * | 2017-12-28 | 2018-07-31 | 江苏海德森能源有限公司 | A kind of lithium battery of high intensity and preparation method thereof |
| CN108816685A (en) * | 2018-07-11 | 2018-11-16 | 张家港市金帆箱柜有限公司 | A kind of anticorrosion process of power battery cabin |
| CN108816685B (en) * | 2018-07-11 | 2021-07-20 | 张家港市金帆箱柜有限公司 | Anticorrosion technology of power battery compartment |
| CN110534229A (en) * | 2019-08-30 | 2019-12-03 | 湖南诺尔得材料科技有限公司 | A kind of conductive silver paste and the preparation method and application thereof that sintering temperature is low |
| CN110534228A (en) * | 2019-08-30 | 2019-12-03 | 湖南诺尔得材料科技有限公司 | A kind of conductive nano silver paste and the preparation method and application thereof |
| CN112409858A (en) * | 2020-11-10 | 2021-02-26 | 横店集团东磁股份有限公司 | Conductive coating for battery case, preparation method and application thereof |
| CN112409858B (en) * | 2020-11-10 | 2022-06-07 | 横店集团东磁股份有限公司 | Conductive coating for battery case, preparation method and application thereof |
| CN113843462A (en) * | 2021-11-05 | 2021-12-28 | 南京航空航天大学 | Method for improving wire cut electrical discharge machining efficiency of semiconductor by using chemical plating process |
| CN113843462B (en) * | 2021-11-05 | 2023-09-26 | 南京航空航天大学 | Method for improving wire cutting efficiency of semiconductor electric discharge machine by using electroless plating process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1390894A (en) | Electrically conductive paint for internal surface of battery shell and its preparing process | |
| CN105001759B (en) | Molybdate Doped polypyrrole/epoxy resin self-healing coatings and its preparation and application | |
| KR100671000B1 (en) | Coating materials for electromagnetic interference shielding and manufacturing method thereof | |
| CN109627829A (en) | A kind of liquid metal conductive coating and its preparation method and application | |
| CN102002294A (en) | Electromagnetic shielding waterborne paint and preparation method thereof | |
| DE60103937T2 (en) | Electroconductive liquid silicone rubber compound | |
| CN114334219A (en) | Low-temperature curing silver paste for heterojunction solar cell and preparation method and application thereof | |
| CN1202531C (en) | Low-content nanometer conducting silver paste and its prepn | |
| CN1441014A (en) | Environment protecting nano conducting paint composite and its prepn | |
| CN102702918A (en) | Conductive coating composition and preparation method thereof | |
| CN114226724A (en) | Copper @ silver core-shell structure particle and related preparation method and application | |
| CN103525223B (en) | A kind of electromagnetic shielding use conducting paint composite and preparation method thereof | |
| CN1490363A (en) | Conductive electromagnetic shielding paint and application thereof | |
| CN101824264B (en) | Nuclear shell conductive polyaniline aqueous antistatic coating and preparation method thereof | |
| CN109360673A (en) | A kind of wicker copper conductive copper paste and preparation method thereof | |
| CN1056165C (en) | Preparation of mixed polyaniline aqueous solution and dispersant liquid | |
| CN113831856A (en) | Multifunctional conductive adhesive and preparation method thereof | |
| CN111341485B (en) | Conductive silver paste for LED aluminum oxide substrate and preparation method thereof | |
| CN103992677B (en) | A kind of nanometer silver flexible conductive paint and preparation method thereof | |
| CN114350238A (en) | Conductive lubricating anticorrosive paint and preparation method thereof | |
| CN111826035B (en) | Conductive coating and preparation method and application thereof | |
| CN1168789C (en) | Electrostatically conductive oil-tolerant paint containing rich zinc and silicic acid | |
| CN113773740A (en) | Environment-friendly conductive coating and preparation method thereof | |
| CN117050634A (en) | Preparation method of conductive water-based paint | |
| KR100526338B1 (en) | Aqueous Coating Composition For EMI Shielding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |