CN1376813A - Process for preparing AlTi alloy by direct electrolysis with carbon anode containing titanium oxide - Google Patents
Process for preparing AlTi alloy by direct electrolysis with carbon anode containing titanium oxide Download PDFInfo
- Publication number
- CN1376813A CN1376813A CN 01138370 CN01138370A CN1376813A CN 1376813 A CN1376813 A CN 1376813A CN 01138370 CN01138370 CN 01138370 CN 01138370 A CN01138370 A CN 01138370A CN 1376813 A CN1376813 A CN 1376813A
- Authority
- CN
- China
- Prior art keywords
- titanium oxide
- carbon anode
- titanium
- alloy
- direct electrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 20
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910045601 alloy Inorganic materials 0.000 title abstract description 11
- 239000000956 alloy Substances 0.000 title abstract description 11
- 229910017150 AlTi Inorganic materials 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 7
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 15
- UKKGMDDPINLFIY-UHFFFAOYSA-N [C+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] Chemical compound [C+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] UKKGMDDPINLFIY-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 239000004411 aluminium Substances 0.000 claims description 11
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000011294 coal tar pitch Substances 0.000 claims description 4
- 239000002006 petroleum coke Substances 0.000 claims description 4
- 229910018575 Al—Ti Inorganic materials 0.000 abstract 1
- 239000010426 asphalt Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000002008 calcined petroleum coke Substances 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 238000005304 joining Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- -1 sodium aluminum fluoride Chemical compound 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003832 thermite Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
A process for preparing Al-Ti alloy by direct electrolysis of carbon anode containing titanium oxide includes such steps as mixing calcined petroleum coke (73-81 wt.%), coal asphalt (17-25) and titanium oxide powder (0.5-5), heating while kneading for 30-45 min, shaping anode, calcining, installing said anode to electrolyzer, and electrolyzing. Its advantages are high performance of product, low cost, high uniformity and high current efficiency.
Description
(1) technical field: the present invention relates to a kind of electrolytic process direct production aluminum base alloy technology of using, particularly a kind of usefulness contains the method for the direct electrolysis production aluminum titanium alloy of titanium oxide carbon anode.
(2) background technology: the production technology of aluminum current titanium alloy mainly contains two kinds, and first kind is with fine aluminium, the molten aluminium titanium master alloy that is made into of pure titanium; Second kind is to adopt the thermite reduction mix-melting method to produce aluminium titanium master alloy with fine aluminium, titanium salt, titanium oxide; The third is directly to add titanium oxide in aluminium cell, produces aluminium titanium master alloy.Titanium content in the aluminium titanium master alloy of producing with above three kinds of methods is generally 1-5% (weight percent), if when manufacturer needs use aluminum titanium alloy, also needs fine aluminium and aluminium titanium master alloy melted once more and is made into desired aluminum titanium alloy.More than three kinds of production technique all exist long flow path (needing repeatedly molten joining), metal loss is big, molten timing energy consumption height, the shortcoming that production cost is high.The third method is that titanium oxide is added aluminium cell, direct electrolysis production aluminum titanium alloy, and this technology causes very big difficulty to the ordinary production management of aluminium cell, and titanium segregation in aluminium liquid is serious, and current efficiency is low.
(3) summary of the invention: a kind of usefulness that the objective of the invention is to develop at the problem of above existence contains the method for the direct electrolysis production aluminum titanium alloy of titanium oxide carbon anode, and its purpose one is to produce the carbon anode that contains titanium oxide.Prepare burden by weight percentage earlier, its proportioning is: after-smithing petroleum coke 73-81%, coal-tar pitch 17-25%, titanium oxide powder 0.5-5%; Batching is placed on can heat mixed pinches to mix to pinch in the pot and was made as thickener in 30-45 minute; What thickener is processed into required specification contains the titanium oxide carbon anode again, and the processing condition of producing carbon anode according to routine are carried out roasting then, and roasting becomes to contain the carbon anode of titanium oxide.Its purpose two is that the titanium oxide carbon anode that contains that roasting is good is installed on the aluminium cell, directly carries out the electrolysis production aluminum titanium alloy.Produce aluminum titanium alloy with aforesaid method, it is simple to have method, and flow process is short, the characteristics that production cost is low.It can utilize the titanium oxide powder that cheaply is easy to get to substitute expensive metal titanium; It neither needs repeatedly molten joining, and has overcome the alloy segregation of production aluminium titanium master alloy and the difficult problem of uneven components again.This method with titanium oxide is added in the electrolyzer directly to the method for electrolytic aluminum titanium master alloy and compares, solved in the production process titanium oxide and flown upward that loss is big, current efficiency is low, the unmanageable technical barrier of aluminium cell.The performance of the aluminum titanium alloy of producing with this method obviously is better than the aluminum titanium alloy produced with mix-melting method.
(4) embodiment: the present invention is described in further detail below in conjunction with embodiment.
Embodiment 1:
The first step.Production contains the carbon anode of titanium oxide: prepare burden by weight percentage earlier, proportioning is: after-smithing petroleum coke 81%, coal-tar pitch 17%, titanium oxide powder 2% take by weighing after-smithing petroleum coke 2.49Kg, coal-tar pitch 0.51Kg, titanium oxide powder 0.06Kg; The batching of 3.06Kg is placed on can heat mixed pinches to mix in the pot and pinched 30 minutes, make the 3.06Kg thickener, again the thickener of 3.06Kg made 3 diameters and be 60mm, highly contain titanium oxide right cylinder green anode piece for 150mm, pack into then and carry out roasting in the stoving oven, the top temperature of roasting is 1200 ℃, be incubated 4 hours, be cooled to room temperature, can make and contain the titanium oxide carbon anode.Below add 2% titanium oxide powder and do not add the physical and chemical index of the carbon anode that the oxidation titanium valve makes with table 1 explanation.Table 1:
Second step was carried out direct electrolysis production aluminum titanium alloy with the good titanium oxide carbon anode that contains of roasting.Use titanium oxide content be 2% contain the titanium oxide carbon anode, to contain the titanium oxide carbon anode is installed on the small aluminium electrolytic cell, the control electrolysis temperature is 950 ℃, bath voltage is 4.1 volts, pole span is 4.1 centimetres, alumina content is 3.7% in the sodium aluminum fluoride, can make titanium content and be 0.24% aluminum titanium alloy.
Claims (1)
1, a kind of usefulness contains the method for the direct electrolysis production aluminum titanium alloy of titanium oxide carbon anode, it is characterized in that: produce the carbon anode that contains titanium oxide earlier, prepare burden after-smithing petroleum coke 73-81%, coal-tar pitch 17-25%, titanium oxide powder 0.5-5% by weight percentage; Batching is placed on can heat mixed pinches to mix in the pot and pinched 30-45 minute, be made as thickener; What thickener is processed into required specification contains the titanium oxide carbon anode again; Produce the processing condition of carbon anode then routinely and carry out roasting, roasting becomes to contain the titanium oxide carbon anode; Second step was that the titanium oxide carbon anode that contains that roasting is good is installed on the aluminium cell, and direct electrolysis method is produced aluminum titanium alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 01138370 CN1253605C (en) | 2001-12-28 | 2001-12-28 | Process for preparing AlTi alloy by direct electrolysis with carbon anode containing titanium oxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 01138370 CN1253605C (en) | 2001-12-28 | 2001-12-28 | Process for preparing AlTi alloy by direct electrolysis with carbon anode containing titanium oxide |
Publications (2)
Publication Number | Publication Date |
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CN1376813A true CN1376813A (en) | 2002-10-30 |
CN1253605C CN1253605C (en) | 2006-04-26 |
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CN 01138370 Expired - Lifetime CN1253605C (en) | 2001-12-28 | 2001-12-28 | Process for preparing AlTi alloy by direct electrolysis with carbon anode containing titanium oxide |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005019501A3 (en) * | 2003-08-20 | 2005-09-15 | Materials & Electrochemical Research Corp | Thermal and electrochemical process for metal production |
EP1731631A2 (en) | 2005-06-08 | 2006-12-13 | DLR Deutsches Zentrum für Luft- und Raumfahrt e.V. | Production of a composite material |
CN100415940C (en) * | 2005-05-08 | 2008-09-03 | 北京科技大学 | Pure titanium production from titanium monoxide/titanium carbide soluble solid anode electrolysis |
US7794580B2 (en) | 2004-04-21 | 2010-09-14 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
CN101254614B (en) * | 2008-04-15 | 2010-11-17 | 焦作市东星炭电极有限公司 | Carbon electrode horizontal type bidirectional vibration molding technique |
CN101922022A (en) * | 2010-08-03 | 2010-12-22 | 湖南晟通科技集团有限公司 | Method for reducing resistivity of prebaked anode |
CN103255438A (en) * | 2013-05-24 | 2013-08-21 | 贵州师范大学 | Preparation method of modified pre-baked carbon anode containing titanium additive |
CN103409775A (en) * | 2013-08-26 | 2013-11-27 | 江苏启迪合金有限公司 | Method for producing aluminum-titanium alloy through electrolysis |
CN104099643A (en) * | 2014-07-29 | 2014-10-15 | 攀钢集团攀枝花钢铁研究院有限公司 | Preparation method for titanium-aluminium alloy |
US9150943B2 (en) | 2007-01-22 | 2015-10-06 | Materials & Electrochemical Research Corp. | Metallothermic reduction of in-situ generated titanium chloride |
CN108103325A (en) * | 2016-11-24 | 2018-06-01 | 宁波江丰电子材料股份有限公司 | The forming method of aluminium alloy |
CN109706482A (en) * | 2017-10-26 | 2019-05-03 | 遵义市吉祥富康门窗有限公司 | A kind of preparation method of titanium-aluminium alloy |
-
2001
- 2001-12-28 CN CN 01138370 patent/CN1253605C/en not_active Expired - Lifetime
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104831318A (en) * | 2003-08-20 | 2015-08-12 | 材料及电气化学研究公司 | Thermal and electrochemical method for metal production |
US7410562B2 (en) | 2003-08-20 | 2008-08-12 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
US7985326B2 (en) | 2003-08-20 | 2011-07-26 | Materials And Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
US9249520B2 (en) | 2003-08-20 | 2016-02-02 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
WO2005019501A3 (en) * | 2003-08-20 | 2005-09-15 | Materials & Electrochemical Research Corp | Thermal and electrochemical process for metal production |
US7794580B2 (en) | 2004-04-21 | 2010-09-14 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
CN100415940C (en) * | 2005-05-08 | 2008-09-03 | 北京科技大学 | Pure titanium production from titanium monoxide/titanium carbide soluble solid anode electrolysis |
EP1731631A3 (en) * | 2005-06-08 | 2008-07-23 | DLR Deutsches Zentrum für Luft- und Raumfahrt e.V. | Production of a composite material |
EP1731631A2 (en) | 2005-06-08 | 2006-12-13 | DLR Deutsches Zentrum für Luft- und Raumfahrt e.V. | Production of a composite material |
US9150943B2 (en) | 2007-01-22 | 2015-10-06 | Materials & Electrochemical Research Corp. | Metallothermic reduction of in-situ generated titanium chloride |
CN101254614B (en) * | 2008-04-15 | 2010-11-17 | 焦作市东星炭电极有限公司 | Carbon electrode horizontal type bidirectional vibration molding technique |
CN101922022A (en) * | 2010-08-03 | 2010-12-22 | 湖南晟通科技集团有限公司 | Method for reducing resistivity of prebaked anode |
CN103255438A (en) * | 2013-05-24 | 2013-08-21 | 贵州师范大学 | Preparation method of modified pre-baked carbon anode containing titanium additive |
CN103409775B (en) * | 2013-08-26 | 2015-11-11 | 江苏启迪合金有限公司 | A kind of method of electrolysis production aluminum titanium alloy |
CN103409775A (en) * | 2013-08-26 | 2013-11-27 | 江苏启迪合金有限公司 | Method for producing aluminum-titanium alloy through electrolysis |
CN104099643A (en) * | 2014-07-29 | 2014-10-15 | 攀钢集团攀枝花钢铁研究院有限公司 | Preparation method for titanium-aluminium alloy |
CN108103325A (en) * | 2016-11-24 | 2018-06-01 | 宁波江丰电子材料股份有限公司 | The forming method of aluminium alloy |
CN109706482A (en) * | 2017-10-26 | 2019-05-03 | 遵义市吉祥富康门窗有限公司 | A kind of preparation method of titanium-aluminium alloy |
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CN1253605C (en) | 2006-04-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
ASS | Succession or assignment of patent right |
Owner name: CHINESE ALUMINIUM CO., LTD. Free format text: FORMER OWNER: ZHENGZHOU INST OF LIGHT METALS Effective date: 20030103 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20030103 Applicant after: Aluminum Corporation of China Limited Applicant before: Zhengzhou Light Metal Research Institute |
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SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term |
Granted publication date: 20060426 |
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CX01 | Expiry of patent term |