CN1376193A - Use of polyoxypropylene/polyoxyethylene compounds as degreasing agents for hard surfaces - Google Patents
Use of polyoxypropylene/polyoxyethylene compounds as degreasing agents for hard surfaces Download PDFInfo
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- CN1376193A CN1376193A CN00813204A CN00813204A CN1376193A CN 1376193 A CN1376193 A CN 1376193A CN 00813204 A CN00813204 A CN 00813204A CN 00813204 A CN00813204 A CN 00813204A CN 1376193 A CN1376193 A CN 1376193A
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- alkyl
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 89
- -1 polyoxypropylene Polymers 0.000 title claims abstract description 22
- 229920003171 Poly (ethylene oxide) Polymers 0.000 title description 2
- 238000005237 degreasing agent Methods 0.000 title description 2
- 229920001451 polypropylene glycol Polymers 0.000 title description 2
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 239000001257 hydrogen Substances 0.000 claims description 31
- 229910052739 hydrogen Inorganic materials 0.000 claims description 31
- 239000000126 substance Substances 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 229920006395 saturated elastomer Polymers 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 150000003818 basic metals Chemical group 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 10
- 125000004122 cyclic group Chemical group 0.000 claims description 10
- 229910052728 basic metal Inorganic materials 0.000 claims description 9
- 150000001721 carbon Chemical group 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 230000033444 hydroxylation Effects 0.000 claims description 3
- 238000005805 hydroxylation reaction Methods 0.000 claims description 3
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 238000005238 degreasing Methods 0.000 abstract description 4
- 235000007586 terpenes Nutrition 0.000 abstract description 4
- 125000006353 oxyethylene group Chemical group 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 39
- 239000002585 base Substances 0.000 description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
- 239000004567 concrete Substances 0.000 description 5
- 239000003129 oil well Substances 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 4
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 4
- ROKSAUSPJGWCSM-UHFFFAOYSA-N 2-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol Chemical class C1C2C(C)(C)C1CC=C2CCO ROKSAUSPJGWCSM-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000002596 correlated effect Effects 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 239000013527 degreasing agent Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229940071207 sesquicarbonate Drugs 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910001038 basic metal oxide Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- YQZZXXKFKTWDPY-UHFFFAOYSA-N propan-2-yl benzenesulfonate Chemical compound CC(C)OS(=O)(=O)C1=CC=CC=C1 YQZZXXKFKTWDPY-UHFFFAOYSA-N 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- SDTMFDGELKWGFT-UHFFFAOYSA-N 2-methylpropan-2-olate Chemical compound CC(C)(C)[O-] SDTMFDGELKWGFT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- GFMYEVPBEJFZHH-UHFFFAOYSA-N CP(O)(O)O Chemical compound CP(O)(O)O GFMYEVPBEJFZHH-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000000416 hydrocolloid Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011378 shotcrete Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3227—Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Lubricants (AREA)
- Polyethers (AREA)
- External Artificial Organs (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention concerns the use in degreasing/cleansing applications of hard surfaces, such as metal surfaces, of at least a compound derived from a terpene and comprising a number of oxypropylene units ranging between 3 and 5, and a number of oxyethylene units ranging between 6 and 10, exclusively. The compound is provided with a concentration lower than 10 g/l, more particularly between 0.01 and 5 g/l, when used.
Description
The present invention relates to comprise of the application of the terpene compound of propylene oxide and ethylene oxide unit, more particularly as the application of the oil removing/sanitising agent of metallic surface as the oil removing/sanitising agent of crust.
The cleaning of metallic surface/oil removing field requires to have extraordinary performance, especially at oil removing power and its non-foaming aspect of performance of composition therefor.But also should note this effect even all need usually under the difficulty very much in working conditions.Gunite can impel foam to occur, and uses treatment soln because be under pressure.
The compound that is used for this field at present mainly is an ethoxylated alkylphenol.This compounds has the very gratifying intrinsic oil nature of removing.But they have a significant disadvantage, have promptly encouraged foamy formation.Add defoamer such as the straight chain alcohol alcoxylates, can alleviate this using disadvantageous phenomenon.But the existence of this compounds has reduced the oil removing activity of ethoxylated alkylphenol, its be can not ignore and may be significant.Add the other alkylphenol of q.s, also can not compensate this loss of activity, and recover its initial activity level.
International Patent Application WO-A-96/01245 has described and has used the alkoxylate terpene compound as good degreaser, and it can too not encourage foamy and form.The compound of embodiment is the derivative of nopol or arbanol terpenoid compound, and contains 0-2 propylene oxide part and 3.3-10.3 ethylene oxide part.
These compounds, there is no question about at this for its importance, but in the very concrete application of treatment of hard surfaces, especially in the process metal surfaces, do not produce good result.They fail to satisfy simultaneously two required in this field standards, the active and froth breaking effect of promptly high oil removing.This means in the prescription that the compound amount must increase and/or has to add defoamer, has known shortcoming.And it is generally acknowledged that although added a large amount of this compounds, it reached removes the oil level of removing that oil level also only equals ethoxylated alkylphenol at the most.
Obviously, the compound with very high oil removing ability that does not cause a large amount of foams to occur must be available.Use these compounds that two-fold advantage is arranged, do not need a large amount of uses, need not add ancillary compound such as defoamer.
The objective of the invention is to propose especially adopt lower concentration can satisfy the concrete terpene compound of above-mentioned double standards in the cleaning/oil removing of metallic surface carrying out crust.
The present invention relates to use at least a compound with following chemical formula in hard-surface cleaning/oil removing, compound concentration described in using is the 0.01-10 grams per liter:
Z-X-[CH(R
3)-CH(R
4)-O]
n-[CH
2CH
2-O]
p-R
5
In this chemical formula:
● Z represents a dicyclo [a, b, c] heptenyl or dicyclo [a, b, c] heptyl, herein:
a+b+c＝5
A=2,3 or 4;
B=2 or 1;
C=0 or 1; Described base is optional by at least one C
1-C
6Alkyl replaces, and comprises and be selected from following pointed skeleton Z or it deducts the skeleton of two keys accordingly:
● X represents-CH
2-C (R
1) (R
2)-O-or-O-CH (R '
1)-CH (R '
2)-O-, its
In:
● R
1, R
2, R
' 1And R
' 2, can be identical or different, represent hydrogen or straight chain,
Chain or cyclic, saturated or undersaturated C
1-C
22Alkyl, preferred C
1-C
6
● R
3And R
4, can be identical or different, represent hydrogen or straight chain, side chain or ring-type
, saturated or undersaturated C
1-C
22As long as alkyl is at least one R
3Or R
4
Base is not a hydrogen;
● R
5Represent hydrogen, straight chain, side chain or cyclic, saturated or undersaturated,
The C of aromatics or non-aromatics
1-C
22Alkyl, it can be substituted, or one
Be selected from following group:
-SO
3M
-OPO
3(M)
2
-(CH
2)
r-COOM
-(CH
2)
z-SO
3M
In these chemical formulas:
● M represents hydrogen, basic metal or ammonium official energy N (R)
4 +, R wherein, but phase
With or inequality, represent hydrogen or straight chain, side chain or cyclic, saturated or not
Saturated C
1-C
22Alkyl, it also may be by hydroxylation;
● r is 1-6;
● z is 1-6;
● n is an integer or mark, and it is 3-5, comprises 3 and 5;
● p is an integer or mark, is 6-10, except the ultimate value.
According to following explanation and embodiment, further advantage of the present invention and feature can become clearer.
At first, compound of the present invention will be described.
First kind compound is equaled-CH by X wherein
2-C (R
1) (R
2The chemical formula of)-O-(I) definition.
This compound is called as (Ia) hereinafter, is equivalent to following chemical formula:
Z-CH
2-C(R
1)(R
2)-O-[CH(R
3)-CH(R
4)-O]
n-[CH
2CH
2-O]
p-R
5
Wherein Z, R
1, R
2, R
3, R
4, R
5, n and p implication the same given.
In preferred enforcement of the present invention, the Z base is selected from chemical formula c) to g).
Should be noted that what the Z base more particularly was connected with all the other chains via one of carbon atom 1 to 6; Via carbon atom 1,5 and 6 is preferred.
In addition, the Z base can be by two C on its at least one carbon atom
1-C
6Alkyl, preferred two methyl replace.
More particularly, carbon 7 is by these two alkyl, replaced by two methyl or rather.
Therefore, preferred compound of the present invention is equivalent to figure c by Z base wherein) to g) in occur those one of compound constitute d more preferably) and e) base; The Z base is methyl substituted by two on 7 in carbon.
In a more favourable enforcement of the present invention, the Z base is equivalent to chemical formula d) or e), it is connected with all the other chains via carbon 5 or carbon 1, and on carbon 7, carry two methyl substituents.
Preferably, R
1, R
2, can be identical or inequality, represent hydrogen or methyl.Preferred R
1, R
2Represent hydrogen atom.
As noted before, R
3And R
4Base can be identical or different, represents hydrogen or straight chain, side chain or cyclic, saturated or undersaturated C
1-C
22As long as alkyl is R
3Or R
4At least one is not a hydrogen in the base;
Or rather, described base is represented hydrogen or C
1-C
6Alkyl, preferable methyl or ethyl be not as long as at least one is a hydrogen in these two bases.A preferred base is represented hydrogen and another represent methylidene.
R
5Represent the C of hydrogen, straight chain, side chain or cyclic, saturated or undersaturated, aromatics or non-aromatics
1-C
22Alkyl, they can replace, or one is selected from following group :-SO
3M ,-OPO
3(M)
2,-(CH
2)
r-COOM ,-(CH
2)
z-SO
3M, in these chemical formulas:
● M represents hydrogen, basic metal or ammonium official energy N (R)
4 +, R wherein can be identical or not
Identical, represent hydrogen or straight chain, side chain or cyclic, saturated or undersaturated
C
1-C
22Alkyl, it may be by hydroxylation;
● r is 1-6;
● z is 1-6.
Work as R
5When being alkyl, this latter C that more specifically says so
1-C
6Alkyl or alkyl phenyl optional are replaced by a halogen (for example chlorine).
Preferred R
5It is hydrogen atom.
At last, n is an integer or mark, is 3-5, comprises 3 and 5, and p is an integer or mark, is 6-10, except the ultimate value.
In the present invention's first concrete enforcement, the n value is 3.
In addition, more particularly, the p value is 6.2-7, comprises ultimate value.Preferred p value is 6.3-7, comprises ultimate value.
In the present invention's second concrete enforcement, the n value is 4-5, comprises ultimate value.
In addition, the p value is preferably 7-10, comprises 7, and does not comprise 10, is preferably 8-10, comprises 8 and do not comprise 10.
Second compounds for X representative-O-CH wherein (R '
1)-CH (R '
2The chemical formula of)-O-(I) definition.
Therefore, this compound is called as compound (Ib) hereinafter, is equivalent to following chemical formula:
Z-O-CH(R’
1)-CH(R’
2)-O-[CH(R
3)-CH(R
4)-O]
n-[CH
2CH
2-O]
p-R
5
Wherein, Z, R '
1, R '
2, R
3, R
4, R
5, n and p implication the same.
In preferred enforcement of the present invention, the Z base is equivalent to c) base, dicyclic compound does not contain two keys.
Here should be noted that also more particularly that the Z base connects all the other chains via carbon atom 1 to 6; It is preferred connecting via carbon atom 1,3,4 or 6.
In addition, the Z base can be by two C on its at least one carbon atom
1-C
6Alkyl replaces, and is preferably replaced by two methyl.
More particularly, carbon 7 is replaced by these two alkyl, is replaced by two methyl or rather.
In addition, the carbon atom 2 or 5 of Z base carries a C
1-C
6Substituting group, preferable methyl.
More particularly, and as mentioned above, R
' 1And R
' 2Base can be identical or different, represents hydrogen or straight chain, side chain or cyclic, saturated or undersaturated C
1-C
22Alkyl is not as long as in these two is a hydrogen;
In concrete an enforcement of the present invention, described base is represented hydrogen or C
1-C
6Alkyl, preferable methyl.
Above-mentioned about R
3, R
4And R
5Base and the numerical value of n and p and also be used for this example about the advantageous variant of these numerical value will no longer repeat.
Especially favourable enforcement of the present invention is made of above-mentioned (Ia) type of employing compound.
This compound of the present invention can be produced by following reaction:
In order to obtain compound (Ia), use the reactant of chemical formula (IIa):
Or, use the reactant of chemical formula (IIb) in order to obtain compound (Ib):
At first, use the reactant of chemical formula (IIIop):
Then, the second, with the reactant of chemical formula (IIIoe)
Z, R
1, R
2, R
3And R
4The base definition is the same.
This reaction can be finished in the presence of catalyzer.
The suitable catalyzer that can mention is a highly basic, such as basic metal or alkaline earth metal hydroxides, or N (R)
4 +The quaternary ammonium hydroxide of type, wherein R can be identical or inequality, represents hydrogen or C
1-C
6Alkyl, preferable methyl or ethyl.Sodium hydroxide, potassium hydroxide and tetramethyl ammonium hydroxide are suitable for carrying out this reaction.
Also may use the catalyzer that is selected from basic metal or alkaline-earth alkoxides, such as methylate, ethylate or the tert butoxide of sodium or potassium.It should be noted that also may use primary, the second month in a season or tertiary amine be as catalyzer, is preferably fatty amine, this amine may comprise that other sense is such as ether official energy.An example of this type catalyst that can mention is N, the N-dimethyllaurylamine.
For basic catalyst, its quantity more particularly with respect to final product weight, is the 0.5-40 milligram.
Might be at Lewis acid such as BF
3(gas or the solution in ether), SnCl
4, or SbCl
5Carry out this reaction under existing.
More particularly, the quantity of acid catalyst is every molar reactive thing (IIa) or (IIb) 0.1-10 mmole.
Under the temperature that is enough to make reaction to take place, contact.By showing that temperature is 120-250 ℃ more particularly more than 100 ℃, is preferably 150-200 ℃.
Advantageously, this reaction is to be under the reaction conditions in inert atmosphere such as nitrogen or rare gas such as argon gas or the carbon monoxide and carries out.Nitrogen is preferred.
This reaction can or be carried out under slight overpressure in normal pressure, negative pressure.Usually, pressure is the 1-4 crust.
To reactant (IIa) and preparation (IIb), the existing description be should give reference to it in WO-A-96/01245.
Press chemical formula (I) fundamental function computerized compound (IIIop) and quantity (IIIoe), more particularly, calculate the desirable value of n and p.These two compounds add in succession, to obtain a kind of block compound with chemical formula (I).
When reaction finishes, this reaction mixture that preferably neutralizes, so that pH is 5-8, preferred 6-7.
Adopt acetate or sodium hydroxide, yellow soda ash, sodium bicarbonate to neutralize, this depends on the character of catalyst system therefor in the reaction.
When reaction finished, compound (I) was such, made R
5Base is a hydrogen.
Might carry out functionalisation step to described base, promptly at making terminal hydrogen change into another kind of as defined above R
5The step of base.Carry out etherificate or esterification operation endways on the hydrogen; This step itself is well-known; It preferably carries out after neutralization.
Below can produce:
● sulfuric ester ether (ether sulphates) (R
5=-SO
3M), as English Patent GB-A-1
111 208 or U.S. Pat-A-3 392 185 described;
● phosphoric acid ester ether (ether phosphates) (R
5=-OPO
3(M)
2), as US-A-3 331
896 is described;
● carboxylate ether (ether carboxylates) (R
5=-(CH
2)-COOM) is as US-A-2
623 900 or US-A-2 983 738 described;
● sulphonate ether (ether sulphonates) (R
5=-(CH
2)
2-S0
3M), as US-A-2
115 192, US-A-4 978 780 or K.SUGA, Austr.J.Chem., 21,
2333 (1968) is described;
● alkyl oxide (R
5=alkyl), as described in the US-A-2 913 416;
Be described among the WO-A-96/01245 about the more detailed data of functionalized pattern.
Therefore, compound of the present invention more particularly is used as the degreaser of metallic surface as the degreaser of crust.
The compounds of this invention can be used for metal treatment industry, also can be used for oil removing is carried out on this surface wherein, in any application to oil well or oily production platform oil removing.
As noted before, the consumption according to The compounds of this invention used when using is the 0.01-10 grams per liter.
More particularly, to metal sheet or sheet oil removing the time, this compound concentration is the 0.01-5 grams per liter when using.
For field of petroleum exploitation, more particularly to the platform oil removing, when using according to The compounds of this invention, compound concentration is the 0.01-10 grams per liter.
During more specifically for the cleaning oil well, use the concentration of The compounds of this invention to be preferably the 0.01-5 grams per liter.
Oil removing or detergent water medium to containing The compounds of this invention preferably use under the temperature at least about its cloud point.
For in alkaline medium to the oil formula that removes of metal sheet or sheet, except that comprising The compounds of this invention, also comprise a kind of alkaline alkali lye (alkaline lye), this alkali lye comprises at least a following compound:
● at least a pH control agent, such as oxyhydroxide, carbonate, sesquicarbonate,
Or basic metal or alkali metal bicarbonates;
● at least a polyphosphate, as basic metal, alkaline-earth metal or N (R
4 +) the type ammonium three
Poly-phosphate, pyrophosphate salt, orthophosphoric acid salt or hexametaphosphate, R representative herein
Hydrogen, the optional C that can contain a Sauerstoffatom
1-C
4Alkyl;
● at least a alkalimetal silicate, as anhydrous or other alkali metal silicate
Or its mixture (metasilicate).
In use, the concentration of alkaline alkali lye is the 1-100 grams per liter, more particularly is the 5-20 grams per liter.
This prescription also can comprise:
● at least a water-soluble ionogen, such as benzene sulfonate, list or dialkyl group (C
1-C
4)
Benzene sulfonate, toluene-, dimethylbenzene-or isopropyl benzene-sulfonate, alcohol or dibasic alcohol;
● at least a sequester reagent, such as nitrilo acetate, ethylenediamine tetraacetic acid (EDTA),
Ethylenediamine tetraacetic methyl-phosphorous acid, nitrilo trimethylene phosphonic or its salt;
● buffer reagent, such as alkanolamine, quadrol;
● metal inhibitor.
These compound concentrations can be in this field normal range.But as an illustration, each compound amount can be the 0-1.5 grams per liter during use.
Except that The compounds of this invention, the aqueous composition that is used for the oil removing of oil well platform can comprise;
● at least a water-soluble ionogen, such as benzene sulfonate, list or dialkyl group (C
1-C
4)
Benzene sulfonate, toluene-, dimethylbenzene-or isopropyl benzene-sulfonate, alcohol and dibasic alcohol;
● at least a pH control agent, as alkaline carbonate, sesquicarbonate or carbonic acid
Hydrogen salt;
● additive such as enzyme, metal inhibitor.
These compound concentrations also can be in this field normal range.But the illustrative concentration of each compound is the 0-1.5 grams per liter when using.
Except that compound of the present invention, the water-bearing media that is used to clean oil well can comprise:
● at least a pH regulator agent, as alkaline carbonate, sesquicarbonate or carbonic acid
Hydrogen salt, or basic metal or alkaline earth metal hydroxides;
● additive, such as enzyme, 5% of the total aqueous composition weight of its amount as many as, or gold
Belong to inhibiter;
● in case of necessity, can comprise weighting agent, to keep desired hydrostatic pressure in the oil well.
These examples for compounds that can mention are soluble or partly soluble at least salt, such as basic metal or alkaline earth metal halide.Also may use basic metal or alkaline earth metal sulphate, carbonate, supercarbonate, silicate or phosphoric acid salt, itself or use separately or use with mixture.Also may use organic acid salt, such as the formate or the acetate of basic metal or alkaline-earth metal.Though not preferred, also might use insoluble salt, such as alkaline earth metal sulphate, silicate or carbonate; Or the bromide of alkaline-earth metal or zinc;
● hydrocolloid, such as the plant-sourced polysaccharide, such as polygalactomannan, Mierocrystalline cellulose,
Starch and derivative thereof; Or the polysaccharide of bacterial origin, such as xanthan gum or take off acetyl
The derivative of base.
Though not preferred, scope of the present invention comprises adds tensio-active agent (anionic, cationic, zwitterionic, amphoteric), preferably low lathering surfactant reaches other additive to above-mentioned prescription.
Now enumerate explanation non-limiting example of the present invention.
Embodiment 1
This embodiment relates to and synthesizes 6,6-dimethyl dicyclo [3.1.1] hept-2-ene"-2-ethanol, and it contains propylene oxide (OP) unit and ethylene oxide (OE) unit of different numbers.
Comprise that x propylene oxide (OP) unit and y ethylene oxide (OE) are unitary 6,6-dimethyl dicyclo [3.1.1] heptan-2 alkene-2-ethanol is synthetic in the following manner:
Used 6,6-dimethyl dicyclo [3.1.1] hept-2-ene"-2-ethanol (nopol) is that Fluka sells.
Nopol (6 moles) and potassium hydroxide aqueous solution (50%, 3.1 gram) introduced in one 5 liters the ethoxylation device.
Under 120 ℃, in nitrogen gas stream, this reaction medium is dewatered.
Then, be heated to 170 ℃, introduce propylene oxide (x molar equivalent).In case behind the introducing propylene oxide, add oxyethane (y molar equivalent).
Then cool off this reaction medium, and adding acetate, it is neutralized to pH is 7.Filter gained liquid by absorption agent clay (Clarcel DIC).
See Table with aforesaid method synthetic compound.
| Compound | The number of OP (x) | The number of OE (y) |
| The present invention | ||
| ????1 | ???????3 | ????6.3 |
| ????2 | ???????3 | ????7 |
| ????3 | ???????3 | ????7.5 |
| ????4 | ???????4 | ????7 |
| ????5 | ???????4 | ????8 |
| ????6 | ???????5 | ????7 |
| ????7 | ???????5 | ????8 |
| Contrast | ||
| ????8 | ???????3 | ????6 |
| ????9 | ???????3 | ????10 |
| ????10 | ???????2 | ????5 |
Embodiment 2
This embodiment compared The compounds of this invention 1 and 3 and control compounds 10,11 and 12 and with the Igepal NP10 gained of froth breaking those remove oil nature.
● oiling
" Q-panelling " blank n with pre-oil removing
0The steel plate (0.8 * 76 * 52 millimeters) of R-36 type " matt finish " (Dull mattfinish) is immersed in the pure lubricating oil (being sold with QUAKER 6130 N by Quaker Chemicals company) to automobile steel rolling thin slice preparation 2 minutes, then hangs drip-dry in 24 hours.
● cleaning and flushing
Plate after the oiling is sent in the CIEMME LARO 350 oil removing spraying machines.Remove oil temperature being 45 ℃ is 2 crust with pressure.
Before record removes oil quality, wash 5 seconds of each face of this plate with the current of 2 ml/min flow velocitys
● the oil removing medium
Dilute moisture alkali lye 20 grams per liters that it includes 45 weight % active substances, this active substance is by equal weight potassium hydroxide, Starso (SIMET GA5, the particle of anhydrous partial silicon hydrochlorate and pentahydrate metasilicate, sell by Rhodia Chimie company) and the tetrapotassium pyrophosphate formation, and the test compounds of adding 1 grams per liter, prepare a kind of alkaline degreasing medium (pH12-13).
The results are shown in the following table:
| Compound | The oil removing time ( *) |
| 1 | 30 seconds |
| 3 | 30 seconds |
| 8 (correlated) | 45 seconds |
| 9 (correlated) | 55 seconds |
| 10 (correlated) | ＞2 minutes |
| The Igepal of froth breaking ( **) | 45 seconds |
(
*) the oil removing time is for to cover its two needed times fully with continuous moisture film.
(
*) Igepal of froth breaking is the mixture of a kind of Igepal CO-660 (nonyl phenol 10OE) and Miravon B12DF (50/50).
Obviously, product of the present invention has bigger activity than the reagent that any is used to contrast purpose.
Embodiment 3
This embodiment compared The compounds of this invention 4-7 and with the Igepal NP10 gained of non-froth breaking those remove oil nature.
● oiling
The oil of a kind of commodity Pennzoil 8OW-90 by name is (by Pennzoil ProductsCompany (Houston, Texas) sell), adopt brushing method, it is applied on 0.8 * 24 * lO1 millimeter steel plate of pre-oil removing, reaching tectum is about 0.015 gram/square centimeter.Then they are deposited in the air 24 hours.
The weight of weighing oiling front and rear panel is measured oil mass.
● cleaning and flushing
This plate is immersed in 1 liter of oil removing medium, uses magnetic agitation (100 rev/mins) 10 minutes down at 50 ℃.
Before reading the oil removing degree, wash 5 seconds of each face of this plate with current with the flow velocity of 2 ml/min, dry down in 80 ℃ then.
Operating effect calculates with the weight of oil removing media processes front and rear panel by weighing.
● the oil removing medium
Dilute a kind of moisture alkali lye that includes 1.5 grams per liter tetrapotassium pyrophosphate of 20 grams per liters, and the test compounds of adding 1 grams per liter, preparation alkaline degreasing medium (pH12-13).
The results are shown in the following table:
| Compound | Oil removing % |
| ?4 | ????58 |
| ?5 | ????62 |
| ?6 | ????54 |
| ?7 | ????72 |
| ?Igepal( *) | ????51 |
(
*) Igepal is Igepal CO-630, a kind of nonyl phenol 9OE.
Obviously, product of the present invention has bigger activity than the reagent that any is used to contrast purpose.
Embodiment 4
This embodiment has compared the compound that obtains and has used control compounds in embodiment 1-9, i.e. the foaming property of those of the Igepal of froth breaking and independent Igepal acquisition.
Foam test:
Dilute the moisture alkali lye that 20 grams per liters include 45 weight % active substances, this active substance is by potassium hydroxide, Starso (the SIMET GAS of equal weight, the particle of anhydrous partial silicon hydrochlorate and five hydration metasilicates, Rhodia Chimie company sells) and the tetrapotassium pyrophosphate formation, and the test compounds of adding 1 grams per liter, prepare a kind of alkaline degreasing medium (pH12-13).
Detection is carried out under 50 ℃.
Adopt a kind of turbo mixer (40 millimeters steam turbine, 2000 rev/mins of speed), stirred 900 gram solution 5 minutes, obtain this foam.
After making it leave standstill 5 minutes, the foam levels of record sample.
The results are shown in the following table:
| Compound | Foam levels |
| ?1 | ????20ml |
| ?3 | ????70ml |
| ?4 | ????20ml |
| ?5 | ????50ml |
| ?6 | ????20ml |
| ?7 | ????30ml |
| The Igepal of froth breaking ( *) | ????70ml |
| Independent Igepal ( **) | ????950ml |
(
*) Igepal of froth breaking is the mixture of a kind of Igepal CO-660 (nonyl phenol 10OE) and Miravon B12DF (50/50).
(
*) Igepal:Igepal CO-660 (nonyl phenol 10OE).
Last table in conjunction with former embodiment gained oil removing result, shows and has only compound of the present invention to satisfy can to mate the high oil removing power that is used for the metal sheet oil removing and the double standards of foaming level.
Claims (13)
1. at least a application of compound in the oil removing/cleaning of crust such as metallic surface with following chemical formula, this compound concentrations is grams per liter O.01-10 in using described compound process:
Z-X-[CH(R
3)-CH(R
4)-O]
n-[CH
2CH
2-O]
p-R
5
In this chemical formula:
● Z represents a dicyclo [a, b, c] heptenyl or dicyclo [a, b, c] heptyl, herein:
a+b+c＝5
A=2,3 or 4;
B=2 or 1;
C=0 or 1;
Described base is optional by at least one C
1-C
6Alkyl replaces and comprises and be selected from skeleton Z shown below or its corresponding skeleton that deducts two keys:
● X represents-CH
2-C (R
1) (R
2)-O-or-O-CH (R '
1)-CH (R '
2)-O-, wherein:
● R
1, R
2, R
' 1And R
' 2, can be identical or different, represent hydrogen or straight chain,
Side chain or cyclic, saturated or undersaturated C
1-C
22Alkyl, preferred
C
1-C
6；
● R
3And R
4, can be identical or different, represent hydrogen or straight chain, side chain or ring
Shape, saturated or undersaturated C
1-C
22As long as alkyl is R
3Or R
4In the base extremely
Few one is not hydrogen;
● R
5Represent hydrogen, straight chain, side chain or cyclic, saturated or undersaturated,
The C of aromatics or non-aromatics
1-C
22Alkyl, it can be substituted, or a kind of
Be selected from following group:
-SO
3M
-OPO
3(M)
2
-(CH
2)
r-COOM
-(CH
2)
z-SO
3M
In these chemical formulas:
● M represents hydrogen, basic metal or ammonium official energy N (R)
4 +, R wherein, but phase
With or inequality, represent hydrogen or straight chain, side chain or cyclic,
Saturated or undersaturated C
1-C
22Alkyl, it can be by hydroxylation
;
● r is 1-6;
● z is 1-6;
● n is an integer or mark, and it is 3-5, comprises 3 and 5;
● p is an integer or mark, and it is 6-10, except the ultimate value.
2. according to the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), its n equals 3.
3. according to each the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), its p is 6.2-7, comprises ultimate value, is preferably 6.3-7, comprises ultimate value.
4. according to the application of claim 1, it is characterized in that this compound is the compound of such chemical formula (I), its n is 4-5.
5. according to the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), its p is 7-10, comprises 7, but does not comprise 10, is preferably the 8-10 scope, comprises 8, but does not comprise 10.
6. according to each the application of aforementioned claim, it is characterized in that this compound is such chemical formula (I), the Z base in its carbon atom at least one carbon atom by two C
1-C
6Alkyl replaces.
7. according to each the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), X representative-CH
2-C (R
1) (R
2)-O-and wherein skeleton Z be selected from chemical formula c) to g).
8. according to each the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), skeleton Z is selected from chemical formula d) and e).
9. according to each application of claim 1-5, it is characterized in that this compound is the compound of such chemical formula (I), X representative-O-CH (R
' 1)-C (R
' 2)-0-and wherein the Z base be equivalent to skeleton c), this dicyclo skeleton does not have two keys.
10. according to the application of aforementioned claim, it is characterized in that this compound is the compound of such chemical formula (I), the Z base is by C
1-C
6Alkyl replaces, preferably on the carbon 2 of dicyclo or carbon 5 by methyl substituted.
11., it is characterized in that this compound is used for the oil removing/cleaning to metal sheet according to each the application of aforementioned claim; This compound concentration is the 0.01-5 grams per liter in application process.
12., it is characterized in that this compound is used for platform oil removing/cleaning according to each application of claim 1-10; This compound concentration is the 0.01-10 grams per liter in application process.
13., it is characterized in that this compound is used for producing well oil removing/cleaning according to each application of claim 1-10; This compound concentration is the 0.01-5 grams per liter.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR99/10559 | 1999-08-17 | ||
| FR9910559A FR2797643B1 (en) | 1999-08-17 | 1999-08-17 | USE OF POLYOXYPROPYLENE / POLYOXYETHYLENE TERPENIC COMPOUNDS AS A DEGREASING AGENT FOR HARD SURFACES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1376193A true CN1376193A (en) | 2002-10-23 |
| CN1185328C CN1185328C (en) | 2005-01-19 |
Family
ID=9549189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008132046A Expired - Lifetime CN1185328C (en) | 1999-08-17 | 2000-08-16 | Use of polyoxypropylene/polyoxyethylene compounds as degreasing agents for hard surfaces |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP1206512B1 (en) |
| JP (1) | JP3983543B2 (en) |
| KR (1) | KR100588273B1 (en) |
| CN (1) | CN1185328C (en) |
| AT (1) | ATE263826T1 (en) |
| AU (1) | AU759508B2 (en) |
| BR (1) | BR0013362B1 (en) |
| CA (1) | CA2382093C (en) |
| DE (1) | DE60009721T2 (en) |
| DK (1) | DK1206512T3 (en) |
| ES (1) | ES2214310T3 (en) |
| FR (1) | FR2797643B1 (en) |
| MX (1) | MXPA02001589A (en) |
| WO (1) | WO2001012765A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993790B (en) * | 2009-08-17 | 2012-06-06 | 中国石油化工股份有限公司 | Cleaning agent of oil refining device and preparation method thereof |
| CN111801406A (en) * | 2018-03-06 | 2020-10-20 | 瑞孚化工有限公司 | Lubricant and refrigerant compositions comprising polyalkylene glycol and uses thereof |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2918994B1 (en) * | 2007-07-20 | 2012-10-19 | Rhodia Operations | FORMULATIONS OF CARBOXYLIC ACID DIESTERS AND THEIR USE FOR TREATING MATERIALS. |
| FR2929954B1 (en) * | 2008-04-09 | 2010-04-30 | Rhodia Operations | AQUEOUS TREATMENT COMPOSITION INHIBITING CORROSION AND ACID ATTACK ON METAL SURFACES |
| FR2949116B1 (en) | 2009-08-13 | 2012-08-31 | Rhodia Operations | GRAFFITI CLEANING COMPOSITION |
| FR2950627B1 (en) | 2009-09-28 | 2011-12-09 | Rhodia Operations | DISPERSION OF A WATER-SOLUBLE POLYMER IN A LIQUID ENVIRONMENT |
| KR101673589B1 (en) * | 2009-10-30 | 2016-11-07 | 동우 화인켐 주식회사 | A detergent composition for a glass substrate of flat panel display device |
| EP3227273B1 (en) | 2014-12-02 | 2022-02-09 | Minerva Neurosciences, Inc. | Compositions comprising 2-((1-(2(4-fluorophenyl)-2-oxoethyl)piperidin-4-yl)methyl)isoindolin-1-one for treating schizophrenia |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2721921B1 (en) * | 1994-07-01 | 1996-10-31 | Rhone Poulenc Chimie | DERIVATIVES OF TERPENIC ORIGIN, SURFACTANT AND / OR PERFUMING COMPOSITION CONTAINING AND DETERGENT FORMULATION BASED ON THIS COMPOSITION |
| FR2757508B1 (en) * | 1996-12-20 | 1999-02-26 | Rhodia Chimie Sa | POLYALCOXYLATED TERPENIC COMPOUNDS, PROCESS FOR THEIR PREPARATION, AND THEIR USE AS FOAMING AGENTS |
-
1999
- 1999-08-17 FR FR9910559A patent/FR2797643B1/en not_active Expired - Lifetime
-
2000
- 2000-08-16 CN CNB008132046A patent/CN1185328C/en not_active Expired - Lifetime
- 2000-08-16 MX MXPA02001589A patent/MXPA02001589A/en active IP Right Grant
- 2000-08-16 EP EP00958691A patent/EP1206512B1/en not_active Expired - Lifetime
- 2000-08-16 KR KR1020027002017A patent/KR100588273B1/en active IP Right Grant
- 2000-08-16 BR BRPI0013362-0A patent/BR0013362B1/en not_active IP Right Cessation
- 2000-08-16 JP JP2001517651A patent/JP3983543B2/en not_active Expired - Lifetime
- 2000-08-16 WO PCT/FR2000/002325 patent/WO2001012765A1/en active IP Right Grant
- 2000-08-16 ES ES00958691T patent/ES2214310T3/en not_active Expired - Lifetime
- 2000-08-16 AT AT00958691T patent/ATE263826T1/en active
- 2000-08-16 AU AU70135/00A patent/AU759508B2/en not_active Expired
- 2000-08-16 DK DK00958691T patent/DK1206512T3/en active
- 2000-08-16 DE DE60009721T patent/DE60009721T2/en not_active Expired - Lifetime
- 2000-08-16 CA CA002382093A patent/CA2382093C/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993790B (en) * | 2009-08-17 | 2012-06-06 | 中国石油化工股份有限公司 | Cleaning agent of oil refining device and preparation method thereof |
| CN111801406A (en) * | 2018-03-06 | 2020-10-20 | 瑞孚化工有限公司 | Lubricant and refrigerant compositions comprising polyalkylene glycol and uses thereof |
| US11466225B2 (en) | 2018-03-06 | 2022-10-11 | Shrieve Chemical Products, Inc. | Lubricant and refrigerant compositions comprising polyalkylene glycols and uses thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA02001589A (en) | 2002-07-02 |
| AU7013500A (en) | 2001-03-13 |
| WO2001012765A1 (en) | 2001-02-22 |
| DE60009721D1 (en) | 2004-05-13 |
| CA2382093C (en) | 2005-10-25 |
| EP1206512B1 (en) | 2004-04-07 |
| KR20020019984A (en) | 2002-03-13 |
| EP1206512A1 (en) | 2002-05-22 |
| ATE263826T1 (en) | 2004-04-15 |
| CA2382093A1 (en) | 2001-02-22 |
| DK1206512T3 (en) | 2004-06-07 |
| ES2214310T3 (en) | 2004-09-16 |
| CN1185328C (en) | 2005-01-19 |
| FR2797643A1 (en) | 2001-02-23 |
| BR0013362A (en) | 2002-04-30 |
| JP3983543B2 (en) | 2007-09-26 |
| FR2797643B1 (en) | 2003-06-06 |
| AU759508B2 (en) | 2003-04-17 |
| DE60009721T2 (en) | 2005-03-31 |
| BR0013362B1 (en) | 2010-11-03 |
| JP2003507531A (en) | 2003-02-25 |
| KR100588273B1 (en) | 2006-06-09 |
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