CN1367869A - Used paper mold ball skin for skyrocket and production method therefor - Google Patents
Used paper mold ball skin for skyrocket and production method therefor Download PDFInfo
- Publication number
- CN1367869A CN1367869A CN 00811124 CN00811124A CN1367869A CN 1367869 A CN1367869 A CN 1367869A CN 00811124 CN00811124 CN 00811124 CN 00811124 A CN00811124 A CN 00811124A CN 1367869 A CN1367869 A CN 1367869A
- Authority
- CN
- China
- Prior art keywords
- paper
- fire
- formed body
- retardant
- skyrocket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B4/00—Fireworks, i.e. pyrotechnic devices for amusement, display, illumination or signal purposes
- F42B4/06—Aerial display rockets
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Paper (AREA)
Abstract
A skyrocket ball skin which has a proper strength without sacrifice in assembling performance and in bursting performance at bursting, is low in cost, and is excellent in mass-productivity, flame proofing and moisture resistance; and a production method therefor. Used paper mold recycled cardboard (16), formed by pulping used paper such as used newspaper followed by paper-making and drying into a semi-spherical shape, is dipped in an aqueous solution of a water-soluble flame retardant and water-proofing agent and dried, and then is hot-pressed to be formed into a smooth inner skin (1) having the inner and outer peripheral surfaces thereof compression-impregnated with the flame retardant and water-proofing agent. An improved strength of the inner skin (1) by compression does not produced recesses when stars (3) and bursting charges (5) are loaded, and its smoothness does not cause stars (3) to scrape and therefore powder to peel off. In addition, stars and bursting charges are crushed into pieces when bursted to prevent hazards at falling and loss of design effects, and the flame retardant and water-proofing agent impregnated in the inner and outer surfaces can improve flame-proofing and moisture resisting performances.
Description
Technical field
The present invention relates to old paper is made paper pulp the used paper mold ball skin for skyrocket of moulding dome-type.
Background technology
That that generally view and admire usefulness is called the structure of the lift-off fireworks of " chi jade " or " cutting thing ", by shell case be contained in its inner bursting charge and constitute for a lot of stars of performing firework effect and the four elements that is drawn out to the blasting fuse of shell case outside.
Shell case generally is to be made of the solid paper that the old paper applying multilayer with old newspaper etc. forms the endothelium of semi-spherical shape and sticks thick packing cardboard or brown paper etc. in the outside of endothelium, arrange a plurality of stars that various gunpowder classes made the dumpling shape respectively in the interior usefulness of a pair of endothelium, behind the bursting charge of side filling within it, sphere will be combined between the endothelium, then, make integrated and finish at fit the thickly crust that constitutes by brown paper etc. of periphery.
The lauching method of these fireworks can be by in the launching tube that firework bomb is packed into, lights the priming in the tube and finishes.
At firework bomb in launching tube emission, light the outer end of blasting fuse by the fiery inflammation of its priming, keep suitable time delay up to reaching the desirable height of lift-off, then light inner bursting charge, when shell case is broken, scatter and burn into the chrysanthemum shape by star, form the pattern of its spark aloft in the short time.
As the function of the shell case of above structure, requirement can be given full play to the effect that scatters of the blast of bursting charge, and self becomes comminution ground and disperse, promptly, shell case do solid more firmly, the effect that scatters of the blasting energy by bursting charge is high more, can become the very big shape of scope.
, it is traditional industry substantially that above lift-off fireworks are made, and makes the requirement condition height by hand., owing to the lift-off fireworks unexpected prosperity already of various places, the fireworks requirement increases day by day recently.
Corresponding therewith, the fireworks practitioner is also adjusting the volume increase system, but in each production process, owing to being makes shell case by hand with method in the past to be unable to catch up with producing needs, it is special because endothelium is that multilayer laminated applying newspaper makes hemispheric operation, production efficiency is poor, and also needing in appearance skillfully becomes the weak link of volume increase.
For head it off, recently, replace hemispherical by former hard letterweight being made type as endothelium.
Because this cardboard compression moulding endothelium is a machinery production, so shape is even and output is high.In addition, owing to be that solid firm paper is made, so can make the effect that bursting charge scatters by endothelium.
, in fact, need big pressure during this cardboard compression moulding endothelium moulding, and must downcut periphery with cutting knife after the compacting and be processed into hemispherically, it is good to be called processing and forming thus, its cost height, and intensity is excessive, therefore, the bursting charge explosion time can not be crushed into Powdered and become a plurality of separations of fragments, if the explosion dose is few, break from commissure often and fly out, not only dangerous when falling, and hinder scattering of star, then can not get the layout effect of being imagined.
Therefore, the applicant is for solving the result that above-mentioned problem is in the past studied repeatedly with keen determination, developed old paper paper pulpization with old newspaper etc., molded copy paper become hemispherical after, carry out hot pressing, inner and outer circumferential surfaces is made the lift-off fireworks shell case of level and smooth regeneration ground paper formed body structure endothelium, and at first proposed application.Promptly, these lift-off fireworks are inexpensive and can produce in a large number with shell case, also can overcome because hardness and the too high problem that causes of intensity, and can form inner and outer circumferential surfaces smoothly after the hot pressing, peel off so can prevent the gunpowder of star outer peripheral face, and also good to the stickiness of outer peripheral face applying brown paper.
, in further afterwards the research and development.For this lift-off fireworks shell case of at first applying for, room for improvement is arranged at following point.
Promptly, owing to be with old paper paper pulpization, the molded paper of copying becomes hemispheric shell case, the reverse side that scatters is pulverized in blast by bursting charge easily, if when the inner peripheral surface of its fragment that scatters adheres to bursting charge securely, particularly during the big bullet more than making about No. 10 bullets, the residual fire of bursting charge is from being moved and may continue flameless combustion after falling earthward by chippy cataclasm.
The present invention is in order to solve above-mentioned problem, its purpose is to provide inexpensive and when producing in batches, not only can prevent because the peeling off of the outer coplanar bursting charge of problem that hardness and intensity cause or star, and the residual fire of bursting charge is moved and continue aphlogistic used paper mold ball skin for skyrocket and manufacture method thereof.
Disclosure of an invention
In order to reach the above object, the used paper mold ball skin for skyrocket that the invention of claim 1 relates to is, the old paper paper pulp of use old newspaper or corrugated board etc. is copied paper and is become the hemispheric while, inner and outer circumferential surfaces forms the used paper mold ball skin for skyrocket of regeneration ground paper formed body smoothly by hot pressing, it is characterized in that this regeneration ground paper formed body at least in the surperficial water-soluble flame retardant that infiltrates of external application.
The above endothelium of Gou Chenging, pressing pressure during according to adjustment hot pressings such as shell case sizes, no matter its size, all plastic one-tenth and the identical intensity of endothelium that in the past lamination applying newspaper obtains, the operability in the time of can remaining on inner magnitude of filling the various gunpowder classes of arrangement comparably.And, owing to copy the paper paper pulp molding, so be ground into powder easily at star bursting charge explosion time, with the compression moulding endothelium of in the past cardboard relatively, the danger in the time of can preventing to fall and the loss of pattern effect, in addition, the fragment that falls earthward after dispersing, owing to get back in the soil easy the decomposition by the bacterium in the soil, so be ecology.In addition, can obtain producing in batches effect and manufacturing easily.And then, owing to can form the internal and external circumferential surface smoothly by hot pressing, thus prevent as much as possible at inner peripheral surface because the star friction causes peeling off of gunpowder, also good to the stickiness of outer peripheral face applying brown paper etc.And then owing at the internal and external circumferential surface of shell case at least infiltration compression fire retardant, can prevent that firm attachment from moving and flameless combustion at the residual fire of the bursting charge of the inner surface of chippy fragment, fire line is good.
In addition, shown in the invention as claimed in claim 2, on the surfaces externally and internally at least of above-mentioned regeneration ground paper formed body, the compression waterproofing agent preferably also infiltrates imbibition pressure shrink dissolubility fire retardant the time.Like this during infiltration compression waterproofing agent, the moisture-proof in the time of just can improving the warehouse preservation etc. can be preserved chronically.
The lift-off fireworks of the invention shown in claim 3 manufacture method of shell case, it is characterized in that having dissociate the old paper of old newspaper or corrugated board etc. carry out paper pulpization operation and, from this paper pulp change old paper copy paper and be molded into hemispheric regeneration ground paper formed body after, carry out the dry paper of copying, drying process and, to copy paper, regeneration ground paper formed body dipping behind the drying process, infiltration make after in the aqueous solution of water miscible fire retardant its drying fire-retardant manufacturing procedure and, regeneration ground paper formed body after the fire-retardant manufacturing procedure is carried out hot pressing, with the hot pressing operation of surface smoothing compression forming.
The manufacture method of the invention of this claim 3 is, the suitable manufacture method of making the manufacturing of No. 7 shell cases below the bullet, for fire retardant, generally can use the water miscible material of the cheapness of using as Building Material House, as long as reach the bullet degree No. 7, only be to carry out drying after being immersed in short time with 1 several seconds of shell case of regeneration ground paper formed body in the aqueous solution of fire retardant, just form the infiltration layer of very thick fire retardant within it on the outer surface, and its surfaces externally and internally is easily formed level and smooth infiltration compression layer by hot pressing.Before fire-retardant processing, copy paper, drying process carries out drying, removes and closes the moisture that is immersed in regeneration body paper formed body, so the fire retardant aqueous solution permeates easily, forms the infiltration layer of abundant thickness.Thus, be ground into Powderedly easily at star bursting charge explosion time, can prevent losing of pattern effect, and also prevent peeling off of the gunpowder that causes because of the star friction at inner peripheral surface as much as possible, and can make the good shell case of fire line at an easy rate.
In addition, the invention of the manufacture method shown in the claim 4 is in above-mentioned 3, after above-mentioned fire-retardant manufacturing procedure, be provided with after regeneration ground paper formed body dipping, infiltration are in the waterproofing agent aqueous solution, carries out dry waterproof processing operation.Like this by the waterproof processing operation is set, can and then be manufactured on the good shell case of moisture-proof when preserving in the warehouse etc. at an easy rate.
The invention of the manufacture method shown in the claim 5 is to require in 4 at aforesaid right, after above-mentioned regeneration ground paper formed body dipping, infiltration are in the mixed aqueous solution of above-mentioned fire retardant and waterproofing agent, carry out drying, fire-retardant processing and waterproof processing are carried out in an operation simultaneously.By fire-retardant processing and waterproof processing are handled in fire-retardant, the waterproof processing operation of an operation simultaneously, can further improve productivity ratio, and then fire line and the good shell case of moisture-proof are provided at an easy rate like this.
The lift-off fireworks of the invention of claim 6 manufacture method of shell case, it is characterized in that having dissociate the old paper of old newspaper or corrugated board etc. carry out paper pulpization operation and, from this paper pulp change old paper copy and carry out the dry paper of copying behind the hemispheric regeneration ground paper of the paper moulding formed body, drying process and, to copy paper, regeneration ground paper formed body dipping behind the drying process, infiltration makes its dipping in the mixed aqueous solution of water miscible fire retardant and bleeding agent, the fire-retardant manufacturing procedure that infiltration back is dry and, regeneration ground paper formed body after the fire-retardant manufacturing procedure is flooded, infiltration carry out after in the mixed aqueous solution of water miscible waterproofing agent dry waterproof processing operation and, regeneration ground paper formed body after the waterproof processing operation is carried out hot pressing, with the hot pressing operation of surface smoothing compression forming.
The invention of the manufacture method of this claim 6 is the manufacturings of the big shell case of No. 7 bullets of ratio that suit.Promptly, if become, because its wall thickness becomes big, so only be that regeneration ground paper formed body is immersed in the fire-retardant manufacturing procedure about the several seconds in the aqueous solution of fire retardant than No. 7 big shell cases of bullet, the aqueous solution is difficult to fully be penetrated into inside, and the infiltration of fire retardant is not enough on the fire line.Therefore, be provided with in the aqueous solution that regeneration ground paper formed body is immersed in the fire retardant that adds bleeding agent in waterproof processing operation front flood, dry fire-retardant manufacturing procedure, by bleeding agent make that fire retardant fully infiltrates, after the drying, be immersed in the water-soluble fluid drying of waterproofing agent again, carry out waterproof processing thus.Therefore even for the shell case of the wall thickness bigger than No. 7 bullets, also be ground into Powdered easily at star bursting charge explosion time, can prevent the husband that loses of design effect, and also prevent peeling off of the gunpowder that causes because of the star friction at inner peripheral surface as much as possible, and make the good shell case of fire line and moisture-proof as much as possible at an easy rate.At this, during this waterproof processing, if mix its fireproof agent and fire retardant just better together.
The simple declaration of accompanying drawing
Fig. 1 is the stereogram of a pair of endothelium used of the lift-off fireworks of expression invention;
Fig. 2 is a process chart of roughly representing to invent the manufacture method of 2 same endothelium;
Fig. 3 is a process chart of roughly representing to invent the manufacture method of 3 same endothelium;
Fig. 4 (a)～(d) is the section key diagram of the assembling sequence of the expression lift-off fireworks that use same endothelium;
Fig. 5 is the sectional drawing of the completion status of these lift-off fireworks of expression.
Preferred plan of the present invention
Below, with reference to accompanying drawing in detail embodiment preferred of the present invention is described in detail.
Fig. 1 is that expression constitutes a pair of endothelium 1 of lift-off fireworks of the present invention with old newspaper moulding shell case.In addition, Fig. 2 is the process charts of the lift-off fireworks of expression invention 2 with an example of the manufacture method of old newspaper moulding shell case, the suitable endothelium 1 of making No. 7 following sizes of bullet of the manufacture method of this invention 2.Promptly, shown in the process chart of Fig. 2, manufacture method according to this embodiment, endothelium 1 is to make through following operation, and promptly (1) makes old newspaper etc. the paper pulp chemical industry preface of paper pulp as raw material, (2) copying paper from paper pulp forms and carries out the dry paper of copying behind the hemispheric regeneration ground paper formed body, drying process, (3) will copy paper, regeneration ground paper formed body dipping behind the drying process, infiltration makes the fire-retardant of its drying after in the mixed aqueous solution of water miscible fire retardant and waterproofing agent, the waterproof processing operation, (4) with fire-retardant, regeneration ground paper formed body after the waterproof processing operation carries out the hot pressing operation of hot pressing with the compression forming of surface smoothing ground.Below describe as an example with No. 7 bullets for above-mentioned each operation.
(1) paper pulp chemical industry preface
With old newspaper or corrugated board etc. as raw material; Old paper 10 stirs in water, dissociates and carry out paper pulpization, and water dilutes quantitatively and makes paper pulp raw material 11 when adding paper power reinforcing agent and adhesive therein.As above-mentioned paper power reinforcing agent, preferably the anionic property acrylic resin for example can be enumerated poly-Si Telong 117 (trade name Arakawa Chemical Industries, Ltd. system) etc.This poly-Si Telong 117 is for anionic property acrylic resin 15%, and water accounts for 85% the aqueous solution.
Particularly, preferably corrugated board is considered to be worth doing 40kg and put into the about 0.5m of water
3In with mixer stir decomposed in 10 minutes after, add the poly-Si Telong 117 of 2.6 liters of paper power reinforcing agents, and then use 2m
3Water dilution make paper pulp raw material 11.
(2) copy paper, drying process
Use is for example carried out moulding with above-mentioned paper pulp raw material and is copied paper by the net molding jig 14 of the semi-spherical shape of make-up machine 12 in getting a plurality of regeneration ground paper formed bodys 16 with 6 semi-spherical shape parts.Copying the time of paper copied in this moulding, preferably about 35～40 seconds.
Then, with attracting ingot stripper 18 this regeneration ground paper formed body 16 of copying the paper moulding to be carried out the demoulding, predrying about 2.2 minutes.After this is predrying, about the about 4.5mm of average wall thickness of regeneration ground paper formed body 16.
In addition, pre-dried regeneration ground paper formed body 16, and then in drier 20, carry out formal drying.At this moment, the hothouse temperature remains on 40 ± 10 ℃, hothouse humidity and remains on 40 ± 10%, dry about 5 hours.
(3) fire-retardant, waterproof processing operation
After the above-mentioned regeneration ground paper formed body 16 of copying paper, drying and moulding being immersed in the mixed aqueous solution 17 of water miscible fire retardant and waterproofing agent, carry out drying.As these fire retardants and waterproofing agent, use on the available building materials, for fire retardant, for example preferably phosphorus, the compound nitrogen series of promise south R9711-5 (trade name ball water chestnut oiling industry system) etc.In addition, this promise south R9711-5 contains 40% phosphorus, the compound nitrogen series aqueous solution.In addition, for waterproofing agent, preferably to wait fluorine system, the southern RM30 of this promise be that to contain 18% fluorine be the aqueous solution of solid composition for promise south RM30 (trade name ball water chestnut oiling industry system).At this, above-mentioned mixed aqueous solution 17 is with for 7 liters in water, and the promise of fire retardant south R9711-5 is that 3 liters, the promise south RM30 of waterproofing agent are that 0.5 liter ratio cooperates and suits.
With above-mentioned regeneration ground paper formed body 16 in well-beaten above-mentioned mixed aqueous solution 17, flood remove dropping liquid about 3 seconds after, in drier 20, carry out formal drying.Hothouse temperature and hothouse humidity remain on 40 ± 10 ℃, 40 ± 10% same as described abovely respectively, dry about 1 hour.
(4) hot pressing operation
Use net molding jig 14 copy the paper drying regeneration ground paper formed body 16 after, its inner and outer circumferential surfaces forms has fine concavo-convex asperities, and can not become level and smooth sphere.Therefore, after dry the end of a period, when using the hot pressing cutting machine 22 of interior outer mold 22a, 22b with semi-spherical shape to carry out hot pressing processing the inner and outer circumferential surfaces of its formed body 16, punching press severing semi-spherical shape part forms the endothelium 1 that the regeneration ground paper formed body of uniform 6 semi-spherical shape of thickness with level and smooth inner and outer circumferential surfaces constitutes.
At this, hot pressing type temperature is controlled at 140～150 ℃, pressing pressure is controlled at 200kg/cm
2About, carrying out twice exhaust compacting, the wall thickness after the compacting preferably makes about 3.8mm.
In addition, for above-mentioned embodiment is that fire retardant and waterproofing agent are mixed, fire-retardant processing and waterproof processing are handled in fire-retardant, the waterproof operation of same operation, but these fire-retardant processing and waterproof processing also can be handled in fire-retardant manufacturing procedure of having separated and waterproof processing operation.At this moment, for fire-retardant operation, be after regeneration ground paper formed body dipping, infiltration are in the fire retardant aqueous solution, to carry out drying, for the waterproof processing operation, after regeneration ground paper formed body dipping, infiltration are in the waterproofing agent aqueous solution, carry out drying.And fire-retardant manufacturing procedure is carried out prior to the waterproof processing operation.In addition, when shell case does not require high moisture-proof, not necessarily need above-mentioned waterproof processing operation, also can save.
Fig. 3 is that the lift-off fireworks of invention of expression claim 6 are with the process chart of an embodiment of the manufacture method of old newspaper moulding shell case, the suitable endothelium 1 of making No. 7 above sizes of bullets of the manufacture method of this invention 3.
Promptly, shown in the process chart of Fig. 3, according to manufacture method, endothelium 1 is to make through following operation, promptly (1) makes old newspaper etc. the paper pulp chemical industry preface of paper pulp as raw material, (2) copy paper from paper pulp raw material and form the paper of copying that hemispheric regeneration ground paper formed body carries out drying, drying process, (3) will copy paper, regeneration ground paper formed body dipping behind the drying process, infiltration makes the fire-retardant manufacturing procedure of its drying after in the mixed aqueous solution of water miscible fire retardant and bleeding agent, (4) the regeneration ground paper formed body after the fire-retardant manufacturing procedure is flooded, infiltration makes the fire-retardant of its drying after in the mixed aqueous solution of water miscible fire retardant and waterproofing agent, the waterproof processing operation, (5) hot pressing is fire-retardant, behind the regeneration ground paper formed body after the waterproof processing operation, compression forms the hot pressing operation on surface smoothly.
At this, the difference that the embodiment of the embodiment of the manufacture method of this invention 3 and the manufacture method of foregoing invention 2 is big is, in order to become No. 7 big endothelium 1 infiltration fire retardants more than the bullet to wall thickness reliably, before fire-retardant, waterproof processing operation, increase the fire-retardant manufacturing procedure of (3), and the hot pressing operation of fire-retardant, the waterproof processing operation of destroying paper, drying process, (4) of the paper pulp chemical industry preface of (1), (2) and (5) is identical during with above-mentioned the 1st embodiment substantially.Below, No. 10 bullets are illustrated above-mentioned each operation as an example.
(1) paper pulp chemical industry preface
Old paper 10 as raw material such as old newspaper or corrugated board is stirred in water, dissociates and carry out paper pulpization, and when adding paper power reinforcing agent and adhesive therein, water dilutes quantitatively makes paper pulp raw material 11.
As above-mentioned paper power reinforcing agent, preferably the anionic property acrylic resin for example can be enumerated poly-Si Telong 117 (trade name Arakawa Chemical Industries, Ltd. system) etc.This poly-Si Telong 117 is for anionic property acrylic resin 15%, and water is 85% the aqueous solution.
Particularly, preferably corrugated board is considered to be worth doing 50kg and put into the about 0.5m of water
3In with mixer stir dissociated in 10 minutes after, add the poly-Si Telong 117 of 3.2 liters of paper power reinforcing agents, and then use 2m
3Water dilution make paper pulp raw material 11.
(2) copy paper, drying process
Use the net molding jig 14 of the semi-spherical shape of make-up machine 12, for example above-mentioned paper pulp raw material 11 is carried out moulding in a plurality of regeneration ground paper formed bodys 16 with 6 semi-spherical shape parts and copy paper.Copying the time of paper copied in this moulding, preferably about 54～60 seconds.
Then, with attracting ingot stripper 18 this regeneration ground paper formed body 16 of copying the paper moulding to be carried out the demoulding, predrying about 2.5 minutes.After this is predrying, about the about 7.0mm of average wall thickness of regeneration ground paper formed body 16.
In addition, pre-dried regeneration ground paper formed body 16, and then in drier 20, carry out drying.At this moment, the hothouse temperature remains on 40 ± 10 ℃, hothouse humidity and remains on 40 ± 10%, dry about 6 hours.
(3) fire-retardant manufacturing procedure
After the above-mentioned regeneration ground paper formed body 16 of copying paper, drying and moulding being immersed in the mixed aqueous solution 19 of water miscible fire retardant and bleeding agent, carry out drying.As these fire retardants and waterproofing agent, can use building materials to use, for fire retardant, preferably be still phosphorus, the compound nitrogen series of promise south R9711-5 (trade name ball water chestnut oiling industry system) etc.In addition, as bleeding agent, for example preferably the Supreme Being can 1895 anion such as (trade name ball water chestnut oiling industry systems) be a surfactant.This Supreme Being can 1895 be the aqueous solution that contains 30% anionic surfactant.
With above-mentioned regeneration ground paper formed body 16 in well-beaten above-mentioned mixed aqueous solution 19, flood remove dropping liquid about 3 seconds after, in drier 20, carry out drying.Hothouse temperature and hothouse humidity remain on 40 ± 10 ℃, 40 ± 10% same as described abovely respectively, dry about 1 hour.
(4) fire-retardant, waterproof processing operation
With the regeneration ground paper formed body 16 of above-mentioned fire-retardant processing, and then be immersed in the same manner in the mixed aqueous solution 17 of promise south RM30 of the promise south R9711-5 of fire retardant and waterproofing agent behind the dipping, carry out drying with the manufacture method of foregoing invention 2.At this, above-mentioned mixed aqueous solution 17 remains with for 7 premium on currency, and promise south R9711-5 is that 3 liters, promise south RM30 are that 0.5 liter ratio suits.
Above-mentioned regeneration ground paper formed body 16 carries out drying after flooding and removing dropping liquid about 3 seconds in drier 20 in well-beaten above-mentioned mixed aqueous solution 17.Hothouse temperature and hothouse humidity remain on 40 ± 10 ℃, 40 ± 10% same as described abovely respectively, dry about 1 hour.In addition, may not necessarily add fire retardant in operation, can be that dry waterproof processing operation is carried out in dipping, infiltration behind the waterproofing agent aqueous solution.
(5) hot pressing operation
Since use 14 pairs of dryings of net molding jig regeneration ground paper formed body 16 copy paper, have fine concavo-convex asperities and can not become level and smooth sphere so its inner and outer circumferential surfaces forms.Therefore, after dry the end of a period, when the inner and outer circumferential surfaces of its formed body 16 carried out hot pressing processing in the hot pressing cutting machine 22 of interior outer mold 22a, 22b with semi-spherical shape, punching press severing semi-spherical shape part forms the endothelium 1 that the regeneration ground paper formed body of uniform 6 semi-spherical shape of thickness with level and smooth inner and outer circumferential surfaces constitutes.
At this, hot pressing type temperature is controlled at 140～150 ℃, pressing pressure is controlled at 200kg/cm
2About, carrying out twice exhaust compacting, the wall thickness after the compacting preferably makes about 6.5mm.
In addition, when old paper is carried out paper pulp, do not need bleaching, therefore, its color is a grey, behind the bonding old newspaper of lamination, with the hemispheric hemisphere that is identically formed the band flexibility of moulding.In addition,, for example when No. 5 play, copy paper and form about 3～5mm thickness by 6 hemispherical regeneration ground paper formed bodys 16 that constitute, be compressed into about 2～3mm thickness by hot pressing after, become each endothelium 1 of semi-spherical shape with these hot pressing cutting machine 22 severings.In addition, when playing, copy paper and form about 5～10mm thickness for No. 7.After being compressed into about 3～7mm thickness by hot pressing, severing becomes each endothelium 1 of semi-spherical shape.
The diameter of this endothelium 1 and wall thickness can determine various types of according to the specification of inserting its inner star and explosion dose.
That is, carry out fire-retardant processing and handle and the endothelium 1 of manufacturing, the compression of outer surface infiltration at least within it fire retardant tries hard to improve fire line.And then carry out waterproof processing to handle and the endothelium 1 of manufacturing, except fire line, also improved moisture-proof as much as possible.
In addition, by formation sphere that above-mentioned endothelium 1 is just being united two into one, but side's inner bottom part center has the hole 1a that blasting fuse is used therein.At this moment, for cardboard compression moulding endothelium in the past, because moulding poling hard, so when compression moulding, must use the hole by punching press formation blasting fuse, but, also can carry out punching processing when beginning to copy paper because its flexibility also forms the hole easily by spindle processing from behind.
In addition, also the edge portion of the mating surface of two endotheliums 1 can be formed concavo-convexly, at this moment, decide two positions when cooperating reliably.
Below, describe according to the installation steps of the lift-off fireworks that use above-mentioned endothelium 1.At first, owing to this endothelium 1 is to form with soft material, warp so might when filling gunpowder, be out of shape.Therefore, shown in Fig. 4 (a), in advance this endothelium 1 is entrenched in the assembling fixture 2 of the semi-spherical shape that constitutes by the cardboard compression moulding body that has with endothelium external diameter same inner diameter, then shown in Fig. 4 (b), all proper alignment within it is a granulated into a plurality of stars 3 of dumpling shape.At this, above-mentioned assembling fixture 2 is not limited to cardboard compression moulding body, also can be wooden, resin system etc.But,,, wish to use dielectric material, preferably without metal for this assembling fixture 2 from preventing the viewpoint of gunpowder firing accident.
Then, shown in Fig. 4 (c), will separate the interior week that paper 4 is configured in star 3 by what newspaper etc. constituted, side is filled bursting charge 5 within it.
That is, in endothelium 1, during the assembling of filling star 3 or bursting charge 5, endothelium 1 is entrenched in the assembling fixture of being made up of the non-conductive material of the inner face with the semi-spherical shape that equates with its outer radius surface 2, strengthens from outer circumferential side assembling under the state of its endothelium 1.
If finish above two operations, shown in Fig. 4 (d),, finish padding if merge two endotheliums by operating fast with anchor clamps 2, form the proper sphere shape.
In addition, on a side endothelium 1, will be incorporated into the position of bursting charge 5 by the blasting fuse 6 of its blasting fuse hole 1a in advance certainly.
Then, after adhesive tape on the mating surface periphery of endothelium 1 volume is fixing, unload lower clamp 2,, as shown in Figure 5, make the incorporate lift-off fireworks of periphery of thick crust 7 with endothelium according to the solid paper of established methodology at its periphery multilayer ground lamination applying brown paper etc.In addition, symbol 8 is the tip positions that are fixed on crust 7 among the figure, the suspension ring of available rope hanging fireworks.
The lift-off fireworks of above structure, explosion time aloft, because endothelium 1 becomes comminution ground and disperses to the four directions, so be safe from danger or for the obstruction of layout shape, in addition, owing to use old paper recycled writing paper basically, so with cardboard compression moulding endothelium ratio in the past, raw material cost reduces, and turns back to easily on the ground, also suits on ecology.
In addition, because endothelium 1 is to impose hot pressing processing compression forming, so when inserting gunpowder, inner peripheral surface can recessedly not be out of shape, in addition, owing to form inner peripheral surface glossily, so even the inner peripheral surface of the peripheral part of star 3 and endothelium 1 rubs and also prevents peeling off of gunpowder as much as possible when inserting gunpowder.And then, because also formation glossily of outer peripheral face, so the adhibit quality of brown paper etc. is also good.
And then, because the infiltration of inner and outer circumferential surfaces at least compression fire retardant and waterproofing agent at endothelium 1, so not only can prevent to move and flameless combustion, have good fire line thus, and have good moisture-proof when preserving attached to the residual fire of the bursting charge of the inner surface of chippy fragment.
In addition, for above embodiment, the lift-off fireworks of so-called bursting charge only are described, but the lift-off fireworks that are called the non-unity structure that hangs thing (ball pokes fire) also are applicable to the present invention, this need not wait to say.
The utilizability of industry
Show from the above description like that, levitation fireworks according to the present invention is with old paper moulding Shell case and manufacture method thereof play following various good effect.
(1) for the used paper mold ball skin for skyrocket of the invention of claim 1, tool Have inexpensive and production the time, can obtain with lamination applying newspaper in the past The intensity that endothelium is identical is carried out moulding, and be ground into by the bursting charge explosion time Powdered, With the compressing endothelium of in the past cardboard relatively, the danger in the time of not only can preventing from falling With lose the design effect, and since hot pressing processing compression forming smooth inside and outside Side face, thus can fully prevent when inserting gunpowder, outside the recessed distortion of inner peripheral surface and the star The inner peripheral surface friction of perimembranous and endothelium causes peeling off of gunpowder, and then to the ox-hide of outer peripheral face The stickiness of paper etc. is also good. In addition, at the internal and external circumferential surface of shell case at least imbibition pressure The contracting fire retardant is so it is residual to prevent from being attached to the bursting charge of inner surface of chippy fragment Fire is mobile and flameless combustion has good fire line thus.
Pressing pressure during according to adjustment hot pressings such as shell case sizes, no matter its size, all Can form the identical intensity of endothelium that obtains with in the past lamination applying newspaper, can protect in the same manner Operability when being held in inner magnitude of filling various gunpowder classes. And, owing to be moulding Copy paper and form paper pulp, so be ground into easily Powdered at star bursting charge explosion time. With The compressing endothelium of cardboard in the past relatively, the danger in the time of can preventing from falling and losing The design effect. In addition, can produce in batches, make at an easy rate. And then, because Form glossily the internal and external circumferential surface by hot pressing, thus prevent as much as possible star with in Side face friction causes peeling off of gunpowder, and the stickiness of the cardboard of fitting to outer peripheral face etc. Also good. And then, because at the internal and external circumferential surface of shell case at least infiltration compression fire retardant, So can prevent firm attachment moves at the residual fire of the bursting charge of the inner surface of chippy fragment Moving flameless combustion, thus good fire line had.
(2) for the used paper mold ball skin for skyrocket of the invention of claim 2, At least on the surfaces externally and internally of above-mentioned regeneration ground paper formed body, because the resistance of imbibition pressure shrink dissolubility So the combustion compression waterproofing agent that also infiltrates agent the time is the moisture-proof in the time of can improving the warehouse and preserve etc. The property, can preserve chronically.
(3) the manufacturing side of the used paper mold ball skin for skyrocket of the invention of claim 3 Method is the suitable manufacture method of making No. 7 shell cases below the bullet, for fire retardant, and one As can use the water miscible material of the cheapness of using as Building Material House, as long as reach No. 7 Bullet only is that the short time with 1 several seconds of shell case of regeneration ground paper formed body is immersed in fire-retardant Carry out drying after in the aqueous solution of agent, just form very thick resistance on the outer surface within it Fire the infiltration layer of agent, and by hot pressing its surfaces externally and internally is easily formed level and smooth soaking Ooze compression layer. In addition, before fire-retardant processing, in copying paper, drying process, carry out drying, Remove infiltration at the moisture of regeneration ground paper formed body, so the infiltration of the fire retardant aqueous solution becomes Get easily, form the infiltration layer of abundant thickness. Thus, easy at star bursting charge explosion time Be ground into and Powderedly prevent losing of design effect, and also can prevent from rubbing at the inner peripheral surface star Wiping causes peeling off of gunpowder, can make at an easy rate the good shell case of fire line.
(4) for the system of the used paper mold ball skin for skyrocket of the invention of claim 4 Making method, in the claims 3, after above-mentioned fire-retardant manufacturing procedure, because Arrange after regeneration ground paper formed body dipping, infiltration are in the waterproofing agent aqueous solution and carry out drying The waterproof processing operation, and then have good moisture-proof, can be manufactured at an easy rate the warehouse Deng in shell case with long preservation period.
(5) for the invention of the manufacture method of claim 5, in the claims 4 In and since by with above-mentioned regeneration ground paper formed body dipping, infiltration above-mentioned fire retardant and Carry out drying in the mixed aqueous solution of waterproofing agent, fire-retardant processing and waterproof processing are existed simultaneously Process in fire-retardant, the waterproof processing operation of an operation, so can further improve Productivity ratio, and then fire line and the good shell case of moisture-proof are provided at an easy rate.
(6) for the system of the used paper mold ball skin for skyrocket of the invention of claim 6 Making method arranges the aqueous solution of the fire retardant that has added bleeding agent before prior to waterproof processing The fire-retardant manufacturing procedure of middle dipping, dry regeneration ground paper formed body is abundant by bleeding agent Behind infiltration, the dry fire retardant, in the aqueous solution of waterproofing agent, make its dipping, drying, advance The row waterproof processing is even than No. 7 thick shell cases of bullet wall thickness, also can explode at the star bursting charge Shi Rongyi is ground into Powdered and the design effect that can prevent loss, and also prevents as much as possible Cause peeling off of gunpowder in the friction of inner peripheral surface star, and make at an easy rate fire line and moisture-proof Property is good shell case all. When this waterproof processing, if with its waterproofing agent and fire retardant one Rise to mix and just use better.
Claims (6)
1. used paper mold ball skin for skyrocket, it uses the old paper paper pulp of old newspaper or corrugated board etc. to copy the hemispheric while of paper moulding, inner and outer circumferential surfaces forms regeneration ground paper formed body smoothly by hot pressing, it is characterized in that the infiltration of the inner and outer circumferential lateral face at least water-soluble flame retardant at this regeneration ground paper formed body.
2. used paper mold ball skin for skyrocket according to claim 1 is characterized in that on the inner and outer circumferential lateral face at least of above-mentioned regeneration ground paper formed body, and the compression waterproofing agent also infiltrates in the time of imbibition pressure shrink dissolubility fire retardant.
3. the manufacture method of a used paper mold ball skin for skyrocket is characterized in that its manufacture method comprises that the old paper to old newspaper or corrugated board etc. dissociates and the operation of paper pulpization;
From this paper pulp change old paper copy the hemispheric regeneration ground paper of paper moulding formed body after, carry out dry paper, the drying process copied;
Make the fire-retardant manufacturing procedure of its drying after in the aqueous solution of water miscible fire retardant with copying regeneration ground paper formed body dipping behind paper, the drying process, infiltration;
Regeneration ground paper formed body after the fire-retardant manufacturing procedure is carried out hot pressing, with the thermoforming operation of its surface smoothing compression forming.
4. the manufacture method of used paper mold ball skin for skyrocket according to claim 3 is characterized in that after above-mentioned fire-retardant manufacturing procedure, is provided with after regeneration ground paper formed body dipping, infiltration are in the waterproofing agent aqueous solution to carry out dry waterproof processing operation.
5. the manufacture method of used paper mold ball skin for skyrocket according to claim 4, it is characterized in that after above-mentioned regeneration ground paper formed body dipping, infiltration are in the mixed aqueous solution of above-mentioned fire retardant and waterproofing agent, carry out drying, fire-retardant processing and waterproof processing are carried out in an operation simultaneously.
6. the manufacture method of a used paper mold ball skin for skyrocket, it is characterized in that its manufacture method comprises that old paper to old newspaper or corrugated board etc. dissociates and the operation of paper pulpization and;
From this paper pulp change old paper copy the hemispheric regeneration ground paper of paper moulding formed body after, carry out dry copy paper, drying process and;
With copy regeneration ground paper formed body dipping behind paper, the drying process, infiltration in the mixed aqueous solution of water miscible fire retardant and bleeding agent after, carry out dry fire-retardant manufacturing procedure and;
After the regeneration ground paper formed body after fire-retardant manufacturing procedure dipping, infiltration are in the mixed aqueous solution of water miscible waterproofing agent, carry out dry waterproof processing operation and;
Regeneration ground paper formed body after the waterproof processing operation is carried out hot pressing, with the hot pressing operation of its surface smoothing compression forming.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000162960A JP2001343200A (en) | 2000-05-31 | 2000-05-31 | Used paper mold spheric crust for skyrocket and method for manufacturing the same |
| JP162960/00 | 2000-05-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1367869A true CN1367869A (en) | 2002-09-04 |
| CN100406837C CN100406837C (en) | 2008-07-30 |
Family
ID=18666795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN008111243A Expired - Fee Related CN100406837C (en) | 2000-05-31 | 2000-10-31 | Used paper mold ball skin for skyrocket and production method therefor |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2001343200A (en) |
| CN (1) | CN100406837C (en) |
| WO (1) | WO2001092813A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100344933C (en) * | 2004-07-14 | 2007-10-24 | 黄焱生 | Firework outer cylinder with bottoms and method for making same |
| CN102175102A (en) * | 2011-03-25 | 2011-09-07 | 南京理工大学 | Firework with integral module explosive filling structure in open mode and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101886898A (en) * | 2010-06-25 | 2010-11-17 | 刘忠清 | Material for outer firework barrel and preparation method thereof |
| CN106568350B (en) * | 2016-10-26 | 2018-02-27 | 宁波远志立方能源科技有限公司 | The fireworks cylinder of flame-proof damp-proof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6374999U (en) * | 1986-10-31 | 1988-05-18 | ||
| JP2599783B2 (en) * | 1989-01-23 | 1997-04-16 | 旭化成工業株式会社 | Launch fireworks skin |
| CN1067116A (en) * | 1991-05-23 | 1992-12-16 | 张宗贤 | Suppress method for making special shell of fire cracker with waste paper fibre |
| JPH06287329A (en) * | 1993-02-02 | 1994-10-11 | Matsushita Electric Works Ltd | Production of prepreg and production of electrical laminate using the prepreg |
| CN1141937A (en) * | 1995-04-20 | 1997-02-05 | 王广仪 | A new type fireproof and fire-retardant liquid |
| JPH0968400A (en) * | 1995-08-31 | 1997-03-11 | Inoue Gangu Enka Kk | Smoke toy firework |
| CN1207950A (en) * | 1997-08-13 | 1999-02-17 | 刘全生 | Fireproofing agent |
| CN1195765A (en) * | 1998-02-18 | 1998-10-14 | 徐欢龙 | Process for directly manufacturing fireworks pellet ball case by using yellow plate paper pulp |
| JP2000146499A (en) * | 1998-11-09 | 2000-05-26 | Fuugetsu:Kk | Rocket fireworks ball skin, and assembling method of rocket fireworks |
-
2000
- 2000-05-31 JP JP2000162960A patent/JP2001343200A/en active Pending
- 2000-10-31 CN CN008111243A patent/CN100406837C/en not_active Expired - Fee Related
- 2000-10-31 WO PCT/JP2000/007668 patent/WO2001092813A1/en active Application Filing
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100344933C (en) * | 2004-07-14 | 2007-10-24 | 黄焱生 | Firework outer cylinder with bottoms and method for making same |
| CN102175102A (en) * | 2011-03-25 | 2011-09-07 | 南京理工大学 | Firework with integral module explosive filling structure in open mode and preparation method thereof |
| CN102175102B (en) * | 2011-03-25 | 2013-03-13 | 南京理工大学 | Firework with integral module explosive filling structure in open mode and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001092813A1 (en) | 2001-12-06 |
| JP2001343200A (en) | 2001-12-14 |
| CN100406837C (en) | 2008-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3031369C2 (en) | Pyrotechnic charge consisting of a smoke composition and an ignition charge and a method for producing the mist mixture and the ignition charge | |
| CN1250476C (en) | Ultra-light insulation material compsn. with nonelammability and thermal resistance characteristic, appts. for mfg. same and method for mfg. same by using appts. | |
| US5413746A (en) | Method for molding shaped products and an apparatus for carrying out same | |
| DE2819863C2 (en) | ||
| CN106938455B (en) | Nail shooting bullet for nail shooting fastener and manufacturing method thereof | |
| CN1367869A (en) | Used paper mold ball skin for skyrocket and production method therefor | |
| JP2005515394A5 (en) | ||
| US8578856B2 (en) | Partial decomposition projectile with a double core | |
| CN1323988C (en) | Pyrotechnic composition and method for preparation thereof | |
| US3600830A (en) | Hollow pellets for seed | |
| RU2008121581A (en) | BLOCK THROWING AND METHOD FOR ITS MANUFACTURE | |
| KR101805162B1 (en) | Organic high density material with improved water resistance and durability and producing method thereof | |
| CN106631640B (en) | A kind of electric arc nailing gun of nail shooting pill and preparation method and application the nail shooting pill | |
| NO169093B (en) | DEVICE FOR QUICK PROVISION OF A BEAUTY COVER, AND PROCEDURE FOR AA PREPARING A TEN LAYER AND FOR AA PREPARING A DEVICE WITH BEAUTY CHARGES | |
| KR101670204B1 (en) | Method of manufacturing combustible cartridge case | |
| US20090293755A1 (en) | Partial decomosition with a massive core and core made of pressed powder | |
| CN109096018A (en) | A kind of nail shooting pill for electric arc nailing gun and preparation method thereof and electric arc nailing gun | |
| KR20140071211A (en) | Natural fire log which burn with colored flame and process for making same | |
| WO2001007750A1 (en) | Method for injecting dense additive into drilling wells and composition therefore | |
| CN105345745B (en) | A kind of novel plastic shell nail shooting pill | |
| CN113061068A (en) | Method for producing multi-sound sand gun | |
| CN1302914C (en) | Coal briquette moulding apparatus | |
| DE1117014B (en) | Security explosives | |
| CN1597644A (en) | Brightness pearl for fireworks and its preparation method | |
| CN1312990C (en) | Smoke agent and its preparation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080730 Termination date: 20161031 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |