CN1362452A - Caster oil type polyurethane material and its prepn - Google Patents
Caster oil type polyurethane material and its prepn Download PDFInfo
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- CN1362452A CN1362452A CN 02115440 CN02115440A CN1362452A CN 1362452 A CN1362452 A CN 1362452A CN 02115440 CN02115440 CN 02115440 CN 02115440 A CN02115440 A CN 02115440A CN 1362452 A CN1362452 A CN 1362452A
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- viscotrol
- tin
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Abstract
The formula of castor oil type polyurethane macromolecular polymer contains (by 1000g of finished product):(dewatered) castor oil 320-324g, 2,4-tolylene diisocyanate 118-122g, methyl phenolic resin 107-110g, polytin glycol acid ester 12-16g, styrene 155-159g, ethyl acrylate 30-40g, acrylonitrile 228-232g, benzoyl peroxide 5.5-5.75g, dibutyl dilauryltin 2.3-2.5g and N'N-methyl toluidine 1.4-1.5g. Said material is a liquid polymer, can be placed in any mould at room temp. for 8-24 hr, and can be formed. It possesses excellent wear-resistance, hydrolysis, resistance, gas corrosion resistance, acid-proofing property, resistant to alkali, resistant to salt and high strength and high elasticity.
Description
Technical field
The present invention relates to type material, especially a kind of caster oil type polyurethane material and preparation method.
Background technology
China impregnating material system with in the glass steel lining, epoxy steel, fiber glass fiber reinforced plastic, furan south glass reinforced plastic, bad oxygen clay, siliceous clay, polyoxyethylene resin, polyethylene is stuck with paste and pitch prill etc.Mostly be that system is hard, system software is pasted to the position again, or be in harmonious proportion with powder and use that cost an arm and a leg, purposes is single, the constructing operation complexity causes quite difficulty to the user, does not reach protection effect again, only polishing rust cleaning engineering unusual difficulty just just.
Interpenetrating net polymer is called for short IPN and is the novel multiphase polymer material of a class that two or more polymkeric substance IPN is become the interleaving network shape with chemical process.This material is that the seventies begins to develop in the world, and has caused people's attention widely.But, also make production technique too complicated because this material require is at high temperature synthetic and curing, thereby has limited their use range.
The applicant had once proposed the patent of invention that a kind of name is called " interpenetrating polymer networks material of castor oil type polyurethane fat and poly-substituted ethylene and preparation method " on April 20th, 1998 to Patent Office of the People's Republic of China, and application number is: 98113508.0.This patent application also is not very perfect technically.
Summary of the invention
Main purpose of the present invention is to provide a kind of can synthesize the also caster oil type polyurethane material of curing molding at normal temperatures, make it have the good anti-mill performance of dashing, hydrolysis, gasproof erosion, acid-and base-resisting, salt, solvent also possess high strength and snappiness, and technical mature and reliable.
Above-mentioned purpose of the present invention is achieved through the following technical solutions.A kind of caster oil type polyurethane material, its special character are that the composition of raw materials of this material is (is benchmark with the 1000g finished product):
Viscotrol C (dehydration) 320-324g
2.4 tolylene diisocyanate 118-122g
Sylvan urea formaldehyde 107-110g
Poly-tin two alkyd fat 12-16g
Vinylbenzene 155-159g
Ethyl propenoate 36-40g
Vinyl cyanide 228-232g
Benzoyl peroxide 5.5-5.75g
Dibutyl two bay tin 2.3-2.5g
N ' N xylidine 1.4-1.6g
Another goal of the invention of the present invention provides the preparation method of above-mentioned caster oil type polyurethane material.
For realizing this goal of the invention, the preparation method that the present invention adopts is: at first the raw material in the above-mentioned prescription (by 1000g) is divided into three components, first component is got Viscotrol C 171-175g and 2.4 tolylene diisocyanates and the sylvan urea formaldehyde in the prescription, they are mixed stirring 2-2.5 hour, become white shape, pack with light-proof material; Second component is got remaining Viscotrol C and vinylbenzene in the prescription, Ethyl acrylate ester, vinyl cyanide, earlier Viscotrol C was stirred separately 2-2.5 hour, become white shape, add vinylbenzene and Ethyl acrylate ester, vinyl cyanide then, mix, pack with light-proof material; The 3rd component is got the benzoyl peroxide in the prescription, and dibutyl two bay tin and N ' N xylidine are packed them respectively, at last above-mentioned three components are mixed, and stir and can use in 30-40 minute.
Material of the present invention is a kind of liquid polymers, is the interpenetrating(polymer)networks thing that substituted ethylene things such as Viscotrol C 2.4 tolylene diisocyanates and vinylbenzene form, it at room temperature, be placed in the arbitrary mould 8-24 hour just plastic, can make various packing rings.As protective layer as various apparatuses, with this material brushing or spary on the surface, about 4 hours promptly curable (doing solid work).As conversion and prevention paint of rust, need not eliminate rust and directly to coat this material.
This material has insulation, nontoxic, hydrolysis, anti-aging, acidproof, alkaline-resisting, salt tolerant, gasproof erosion, oil resistant erosion, can paste sealing, the elasticity height, toughness by force, the resistance to compression damping, the sea water resistance microorganism prevents excellent properties such as marine alga.This material has been applied to units such as Ge Zhou Ba, Wuhan Iron and Steel Company, shipyard, Wuchang, 37091 armies, facts have proved excellent performance.
This material has extensive use in fields such as national defence, military project, coal, electric power, water power, chemical industry, weaving, building, machinery, metallurgy.It is applicable to the anti-mill veneer coating and the mould material of dashing at dam most critical position.Can make the various wear washers that valve, water pump are used, rubber screen (replacement mesh screen), sneakers.Can also be as various steel, apparatus protective layer made of iron; gasproof erosion on the hydroelectric generator blade, the water-fast erosion layer of turbo-generator, the protection against corrosion in various mechanical means, warehouse, corrosion; the gas defence material is oozed in the leak stopping of tunnel civil air defense constructions and installations, also can be used as a kind of conversion and prevention paint of rust.
The technical indicator of this material:
Tensile strength＞230KG/cm
2Elongation 100%
Hardness (Shao Shi) 80
Wind sand rifle dashes mill experiment consume＜5 Grams Per Hours (wind speed 70 meter per seconds, sand content 5%).
The Danjiangkou dashes mill experiment consume zero (water speed 14 meter per seconds, sand content 2% was dashed mill 24 hours).
(50 ℃, 100 hours) weight loss is zero in 3% acid, alkali, the salt solution, and performance does not reduce.
Soak in 30% vitriol oil, weight loss is zero, and performance does not reduce.
Stripping strength (bonding) with steel:
Paste: 15Kg/cm
2Cast: 30Kg/cm
2
Stripping strength (bonding) with the cement face:
Paste: 20Kg/cm
2Cast: 30Kg/cm
2
The coating technology index:
Tunic sticking power 1-2 level film shock strength 50Kg/cm
2(not having crackle)
Working temperature :-30 ℃ to 120 ℃
Work-ing life is more than 10 years.
Embodiment
Embodiment 1:
Prescription:
Viscotrol C (dehydration) 320g
2.4 tolylene diisocyanate 118g
Sylvan urea formaldehyde 107g
Poly-tin two alkyd fat 12g
Vinylbenzene 155g
Ethyl propenoate 36g
Vinyl cyanide 228g
Benzoyl peroxide 5.5g
Dibutyl two bay tin 2.3g
N ' N xylidine 1.4g
The preparation method:
Raw material in the prescription is divided into three components:
First component is got Viscotrol C 175 gram after the dehydration and 2.4 tolylene diisocyanates and the sylvan urea formaldehyde in the prescription, it is mixed stirred 2-2.5 hour, becomes white shape, deposits with lighttight black bucket, prevents that light or moisture content from entering.
Second component is got Viscotrol C 145 gram after the remaining dehydration and poly-tin two alkyd fat, vinylbenzene, Ethyl acrylate and the vinyl cyanide in the prescription, earlier Viscotrol C was stirred separately 2-2.5 hour, become white shape, adding poly-tin two alkyd fat, vinylbenzene, ethyl propenoate and vinyl cyanide then mixes, deposit with lighttight black bucket, prevent that light or moisture content from entering.
The 3rd component is got benzoyl peroxide, dibutyl two bay tin and the N ' N xylidine in the prescription, and they are packed respectively.
Above three components are mixed stirring can be used after 30-40 minute.Can be poured into the required part of system in the arbitrary mould, also can brush or be sprayed on the surface of required object.
Embodiment 2:
Prescription: by producing 1 kilogram of product.
Viscotrol C (dehydration) 322g
2.4 tolylene diisocyanate 120g
Sylvan urea formaldehyde 109g
Poly-tin two alkyd fat 14g
Vinylbenzene 157g
Ethyl propenoate 38g
Vinyl cyanide 230g
Benzoyl peroxide 5.6g
Dibutyl two bay tin 2.4g
N ' N xylidine 1.5g
The preparation method:
First component is got Viscotrol C 171 gram after the dehydration and 2.4 tolylene diisocyanates and the sylvan urea formaldehyde in the prescription, all the other with identical among the embodiment 1.
Second component is got Viscotrol C 151 gram after the remaining dehydration and poly-tin two alkyd fat, vinylbenzene, ethyl propenoate and the vinyl cyanide in the prescription, and all the other are identical with embodiment 1.
The 3rd component is got benzoyl peroxide, dibutyl two bay tin and the N ' N xylidine in the prescription, and they are packed respectively.
Operation steps last and among the embodiment 1 is identical.
Embodiment 3:
Prescription:
Viscotrol C (dehydration) 324g
2.4 tolylene diisocyanate 122g
Sylvan urea formaldehyde 110g
Poly-tin two alkyd fat 16g
Vinylbenzene 159g
Ethyl propenoate 40g
Vinyl cyanide 232g
Benzoyl peroxide 5.75g
Dibutyl two bay tin 2.5g
N ' N xylidine 1.6g
The preparation method:
First component is got Viscotrol C 173 gram after the dehydration and 2.4 tolylene diisocyanates and the sylvan urea formaldehyde in the prescription, all the other with identical among the embodiment 1.
Second component is got Viscotrol C 151 gram after the remaining dehydration and poly-tin two alkyd fat, vinylbenzene, Ethyl acrylate and the vinyl cyanide in the prescription, and all the other are identical with embodiment 1.
The 3rd component is got benzoyl peroxide, dibutyl two bay tin and the N ' N xylidine in the prescription, and they are packed respectively.
Operation steps last and among the embodiment 1 is identical.
Claims (2)
1, a kind of caster oil type polyurethane material is characterized in that its composition of raw materials is (in the 1000g finished product):
Viscotrol C (dehydration) 320-324g
2.4 tolylene diisocyanate 118-122g
Sylvan urea formaldehyde 107-110g
Poly-tin two alkyd fat 12-16g
Vinylbenzene 155-159g
Ethyl propenoate 36-40g
Vinyl cyanide 228-232g
Benzoyl peroxide 5.5-5.75g
Dibutyl two bay tin 2.3-2.5g
N ' N xylidine 1.4-1.6fg
2, a kind of preparation method of caster oil type polyurethane material, raw material in it is characterized in that at first will filling a prescription (by 1000 grams) is divided into three components, first component is got Viscotrol C 171-175 gram and 2.4 tolylene diisocyanates and the sylvan urea formaldehyde in the prescription, they are mixed stirring 2-2.5 hour, become white shape, pack with light-proof material; Second component is got remaining Viscotrol C and vinylbenzene in the prescription, ethyl propenoate, vinyl cyanide, earlier Viscotrol C is stirred separately 2-2.5 hour, becomes white shape, adds vinylbenzene and Ethyl acrylate ester, vinyl cyanide then, mixes, and packs with light-proof material; The 3rd component is got benzoyl peroxide, dibutyl two bay tin and the N ' N xylidine in the prescription, and they are packed respectively, above-mentioned three components is mixed to stir 30-40 minute at last.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021154406A CN1172992C (en) | 2002-01-17 | 2002-01-17 | Caster oil type polyurethane material and its prepn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021154406A CN1172992C (en) | 2002-01-17 | 2002-01-17 | Caster oil type polyurethane material and its prepn |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1362452A true CN1362452A (en) | 2002-08-07 |
| CN1172992C CN1172992C (en) | 2004-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021154406A Expired - Fee Related CN1172992C (en) | 2002-01-17 | 2002-01-17 | Caster oil type polyurethane material and its prepn |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1172992C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100535050C (en) * | 2007-05-29 | 2009-09-02 | 中山大学 | Unsaturated monopol polyester foaming plastic and preparation method thereof |
| CN101125927B (en) * | 2007-07-23 | 2010-05-19 | 孝感学院 | Polyurethane interpenetrating network polymer, preparation method and use thereof |
| CN109689722A (en) * | 2016-07-08 | 2019-04-26 | 巴斯夫欧洲公司 | Hybrid composition |
-
2002
- 2002-01-17 CN CNB021154406A patent/CN1172992C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100535050C (en) * | 2007-05-29 | 2009-09-02 | 中山大学 | Unsaturated monopol polyester foaming plastic and preparation method thereof |
| CN101125927B (en) * | 2007-07-23 | 2010-05-19 | 孝感学院 | Polyurethane interpenetrating network polymer, preparation method and use thereof |
| CN109689722A (en) * | 2016-07-08 | 2019-04-26 | 巴斯夫欧洲公司 | Hybrid composition |
| US11053344B2 (en) | 2016-07-08 | 2021-07-06 | Basf Se | Hybrid composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1172992C (en) | 2004-10-27 |
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| SE01 | Entry into force of request for substantive examination | ||
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Granted publication date: 20041027 Termination date: 20140117 |