CN1354304A - Decorative paper with high opaqueness - Google Patents
Decorative paper with high opaqueness Download PDFInfo
- Publication number
- CN1354304A CN1354304A CN01137694.5A CN01137694A CN1354304A CN 1354304 A CN1354304 A CN 1354304A CN 01137694 A CN01137694 A CN 01137694A CN 1354304 A CN1354304 A CN 1354304A
- Authority
- CN
- China
- Prior art keywords
- paper
- talcous
- pulp
- titanium dioxide
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/73—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/20—Chemically or biochemically modified fibres
- D21H11/22—Chemically or biochemically modified fibres cationised
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
Abstract
A decorative base paper for decorative coating materials contains a pigment mixture of titanium dioxide and talc, wherein the talc has a particle size distribution D50 of less than approximately 3.0 mum, and both the decorative base paper and the decorative paper have a high capacity.
Description
The present invention relates to a kind of facing paper and thus obtained upholstery cover material that includes titanium dioxide and talcous pigment composition.
Upholstery cover material, just so-called decorative panel or facing paper (this paper floods with synthetic resin) are preferably as furniture item and indoor surface coating.Known decorative panel can be with the cardboard that prints or do not print of synthetic resin dipping, also can select the surface of this cardboard is handled.Decorative panel is glued or be bonded on the backboard.
According to the kind of impregnation process, between decorative panel made from the refill of thorough impregnation and the decorative panel made by pre-preg significant difference is arranged, in pre-preg is handled, paper only on paper machine the part flood.Molded laminated material (high-pressure laminating material) is the stratiform thing of being made by the letterweight system of which floor dipping.The structure of these molded laminated materials generally includes: a hyaline layer (coating), and this hyaline layer has produced high surface stability; One facing paper, this used for decorative paper synthetic resin dipping; And one or more layers uses the brown paper of resin impregnating.Molding fiber board and shaving board and glued board can be as the substrates of this laminated material.
In the laminated material of making by the short period method (low-pressure lamination material), with the facing paper of synthetic resin dipping by low pressure directly with substrate for example shaving board suppress.The facing paper that is used for above-mentioned clad material is a white or colored, can also be with or without other imprinted pattern.
The basic paper of so-called decoration has special requirement, for example: very high opacity is arranged, so that covered substrate better; The structure of thin plate and gram number average are even, so that evenly absorb resin; Very high photostability; The purity and the uniformity of color are higher, so that reproduce printed pattern better; Higher wet strength is so that carry out dip operation stably; Suitable absorbability is so that obtain required resin impregnation degree; And dry strength, this dry strength is very important in the printing process of the recoil operation of paper machine and printing machine.
Decorating basic paper and made by the white sulfate pulp of height usually, mainly is bardwood pulp, and pigment, filler, wet strength retention agent and fixative up to 45% are arranged.It is different with common paper to decorate basic paper, and decorating has the more filler of high-load in the basic paper, and does not have internal sizes (sizing) or surperficial sizing material, and it is generally used in the paper and for example alkyl ketene dimer of known sizing material agent is arranged.
Opacity is a most important characteristic of decorating basic paper.This is the required characteristic of its covered substrate.
The height opacity of decorating basic paper also can obtain by adding Chinese white.Titanium dioxide is usually as Chinese white.This pigment can guarantee to decorate height opacity, high brightness and the high whiteness of basic paper.But, shortcoming is that the titanium dioxide price is higher.
Replace in the titanium dioxide part or all to have a negative impact with other Chinese white to these characteristics.Suitable opacity can only obtain by increasing pigment content.But, the increase that pigment content can not be unlimited, because at this moment will have a negative impact to certain physical characteristics, for example confining force of pulp suspension, intensity, light resistance and resin absorbability.
The purpose of this invention is to provide a kind of cheap facing paper, this facing paper has also reduced the content of titanium dioxide when having very high opacity.
This purpose is to obtain by the decoration base paper that is used for the upholstery cover material, and wherein, the basic paper bag of described decoration contains titanium dioxide and talcous pigment composition.Talcum powder used according to the invention has very limited particle size distribution, D50 is arranged less than about 3 μ m.The diameter of talcum powder particle that this means 50% weight is less than about 3 μ m.Especially preferably, talcous particle size distribution is that D50 is less than about 2 μ m.
According to another embodiment, facing paper or decorative panel comprise the basic paper of aforementioned decoration.
The talcous specific area used according to the present invention is greater than about 30000m
2/ kg, perhaps according to particularly preferred embodiment, this specific area is greater than about 40000m
2/ kg.On the other hand, common talcous specific area is 8000 to 16000m
2/ kg.This specific area is determined according to DIN66126.
Preferably, talcous amount is 0.1 to 25% (weight ratio) of pigment total amount in the pigment composition.
The titanium dioxide that is preset at the pigment composition that is used for the basic paper of decoration of the present invention can be the common titanium dioxide that is used for facing paper.This titanium dioxide can be buied by market, and can be used for the modification of rutile or anatase.Especially preferably adopt the titanium dioxide of rutile type.
Also can adopt other filler, for example zinc sulphide, calcium carbonate, kaolin or their mixture.
In decorating basic paper, the amount of filler can reach 55% (weight ratio) of paper weight, particularly 11 to 50% (weight ratios) or 20 to 45% (weight ratios).The weight of the basic paper of decoration of the present invention can be 30 to 300g/m
2, normally 40 to 200g/m
2This weight is selected according to special-purpose.
Softwood pulp (long fibered pulp) or bardwood pulp (staple fibre paper pulp) can be used as cellulose pulp, are used to produce facing paper of the present invention.Also can use cotton fiber, or the cellulosic mixture of the above-mentioned type.For example, ratio is 10: 90 to 90: 10 the softwood pulp and the mixture of bardwood pulp, and especially preferably ratio is 30: 70 to 70: 30 the softwood pulp and the mixture of bardwood pulp.According to Schopper-Riegler, this paper pulp can have making beating (beating) degree of 20 to 60 SR.
The cellulose paper pulp mixture preferably has the cation-modified cellulose fiber content based at least 5% (weight ratio) of cellulose mixtures weight.Contain 10 to 50% (weight ratios) in the cellulose paper pulp mixture, especially the cation-modified content of cellulose of 10 to 20% (weight ratios) is proved to be particularly advantageous.
For example, cation-modified cellulose pulp can be by periodical Das Papier, and 1980 the 12nd volume 575-579 pages or leaves as can be known.
In certain embodiments of the invention, the cation-modified cellulosic effective cationic charge that comprises in paper pulp is 20 to 300mmol/kg paper pulp, this is that internalist methodology no.4 according to Darmstadt Polytechnics measures, preferably, the charge density of cellulosic pulp fibers is 30 to 100mmol/kg.Term " effectively cationic charge " is meant the charge density that the charge density with the cellulose pulp of non-cationicization (non-cationized) balances each other.The charge density of cellulose pulp depends on the amount of used cationics, and the amount of this cationic agent can be 0.005 to 200g/kg cellulose pulp.
Cellulosic pulp fibers cation-modified can be by fiber and epichlorohydrin resins and tertiary amine reaction or the reaction by fiber and aliquat realize that this aliquat is chloro hydroxypropyl-trimethyl ammonium chloride or glycidyl trimethyl ammonium chloride for example.
In a preferred embodiment of the invention, adopted cellulosic pulp fibers, it realizes cation-modified by making quaternary ammonium compound with glycidyl function group and cellulosic hydroxyl group carry out addition reaction.
The facing paper of producing in batches according to the present invention can contain wet strength agent for example polyamide/polyamine-epichlorohydrin resins, other polyamine derivatives or polyamide derivative, cationic polyacrylate, modification melamine-formaldehyde resin or cationic starch.These all add in the pulp suspension.Equally, can also add retention agent and other material, for example organic and inorganic pigment, dyestuff, fluorescent whitening agent and dispersant.
The facing paper of producing in batches according to the present invention can be produced on Fourdrinier paper machine or Yankee paper machine.Like this, can to make beating degree be that 30 to 45 SR, pulp density are the paper pulp of 2 to 4% (weight ratios) to the cellulose paper pulp mixture.In tempering tank, filler for example titanium dioxide and talcum powder and wet strength agent adds in this cellulose paper pulp mixture and with this pulp mixture and mixes well.To be diluted to pulp density be about 1% (weight ratio) to the thickened pulp of Sheng Chenging like this, when needing, also can add other additive for example retention agent, foam in hibitors, aluminum sulfate and other aforesaid additive.The paper pulp of this dilution is sent into wet end by the hopper of paper machine.Form non-woven fibre, after draining water, generate and decorate basic paper, make this decorate basic paper drying then.
In order to produce facing paper, by common synthetic resin dispersant this is decorated basic paper and flood.For example, the common synthetic resin dispersant of realizing purpose comprises based on the synthetic resin dispersant of polyacrylate or polymethacrylates, polyvinyl acetate, polyvinyl chloride or based on the synthetic resin solvent of phenolic aldehyde precondensate, urea urea aldehyde precondensate or melamine formaldehyde (MF) precondensate or their compatible blend.
Dipping can also be realized when the gluing compacting of paper machine.This dipping of decorating basic paper can the incomplete mode of flooding of this paper carry out.This facing paper also is pre-preg.At this moment, 25 to 30% (weight ratios) by the dipping weight that to introduce this amount of decorating the resin in the basic paper be paper.
After the drying, the paper of dipping can also apply and print, and is attached to substrate then for example on the plank.This coating and selectively the product that forms of printing be commonly referred to decorative panel.
The following examples are used for further explaining the present invention.If not explanation in addition, the amount of given percentage by weight is based on the weight of cellulose pulp.
Example 1
The cellulose paper pulp mixture and 0.6% (weight ratio) that a kind of cork sulfate pulp of the eucalyptus pulps and 30% (weight ratio) by 70% (weight ratio) constitutes, mix and as stock blend as the foam in hibitors of the retention agent and 0.03% (weight ratio) of the epichlorohydrin resins, 0.11% (weight ratio) of wet strength agent.Three percentages in back are based on the weight of paper pulp.The pH value of this mixture transfers to 6.5 by aluminum sulfate.Then, the talcous pigment composition of the titanium dioxide and 5.2% (weight ratio) of this mixture and 55.8% (weight ratio) mixes.Utilize the Fourdrinier paper machine, generating the gram number is 105g/m
2Facing paper.The content of titanium dioxide is 33.5g/m
2(weight ratio is 31.9%), talcous content is 3.1g/m
2(weight ratio is 2.95%).Talcous particle size distribution D50 is 1.9 μ m, and specific area is 44300m
2/ kg.
Example 2
The talcous pigment composition of the titanium dioxide and 14.7% (weight ratio) of 50.3% (weight ratio) is added in the stock blend in the example 1.Utilize the Fourdrinier paper machine, generating the gram number is 105g/m
2Facing paper.The content of titanium dioxide is 30.2g/m
2(weight ratio is 28.8%), talcous content is 8.8g/m
2(weight ratio is 8.4%).Talcous particle size distribution D50 is 1.9 μ m, and specific area is 44300m
2/ kg.
Example 3
The talcous pigment composition of the titanium dioxide and 3.3% (weight ratio) of 64.5% (weight ratio) is added in the stock blend in the example 1.Utilize the Fourdrinier paper machine, generation weight is 105g/m
2Facing paper.The content of titanium dioxide is 38.7g/m
2(weight ratio is 36.5%), talcous content is 2.0g/m
2(weight ratio is 1.9%).Talcous particle size distribution D50 is 1.9 μ m, and specific area is 44300m
2/ kg.
Example 4
The talcous pigment composition of the titanium dioxide and 11.3% (weight ratio) of 53.9% (weight ratio) is added in the stock blend in the example 1.Utilize the Fourdrinier paper machine, generation weight is 105g/m
2Facing paper.The content of titanium dioxide is 32.3g/m
2(weight ratio is 30.8%), talcous content is 6.8g/m
2(weight ratio is 6.5%).Talcous particle size distribution D50 is 1.5 μ m, and specific area is 47100m
2/ kg.
Comparison example 1
Example 1 as a comparison, only has the titanium dioxide dispersant of 62% (weight ratio) to add in the stock blend in the example 1.Utilize the Fourdrinier paper machine, generation weight is 120g/m
2And the content of titanium dioxide is 37.2g/m
2The facing paper of (weight ratio is 31%).
Comparison example 2
The talcous pigment composition of the titanium dioxide and 14.4% (weight ratio) of 50.8% (weight ratio) is added in the stock blend in the example 1.Generating weight on the Fourdrinier paper machine is 105g/m
2Facing paper.The content of titanium dioxide is 30.5g/m
2(weight ratio is 29%), talcous content is 8.7g/m
2(weight ratio is 8.3%).Talcous particle size distribution D50 is 3.7 μ m, and specific area is 8600m
2/ kg.
Utilize the ACE color measuring instrument of Data Color and determine the opacity of the paper test specimen of example B1 to B4 and comparison example V1 and V2 according to DIN53146.Decorating the content of titanium dioxide of basic paper determines according to DIN54370.The result summarizes in following table.
| Test specimen | Opacity (%) | Talcum powder content is based on total pigment (%) | Talcum powder content (g/m 2) |
| ????B1 | ????92.68 | ????8.5 | ????3.1 |
| ????B2 | ????92.55 | ????22.6 | ????8.8 |
| ????B3 | ????92.61 | ????4.9 | ????2.0 |
| ????B4 | ????92.62 | ????17.3 | ????6.8 |
| ????V1 | ????92.71 | ????0.0 | ????0.0 |
| ????V2 | ????90.28 | ????22.2 | ????8.7 |
Opacity measured value result shows that even content of titanium dioxide reduces significantly, talcum powder used according to the invention also can reach very high opacity.
Claims (6)
1. decoration base paper that is used for the upholstery cover material, it is characterized in that: this is decorated basic paper bag and contains titanium dioxide and talcous pigment composition, and this talcous particle size distribution D50 is less than about 3.0 μ m.
2. the basic paper of decoration according to claim 1 is characterized in that: this talcous specific area is greater than about 30000m
2/ kg.
3. the basic paper of decoration according to claim 1 and 2 is characterized in that: this talcous weight content is 0.1 to 25% of a pigment total amount.
4. according to the basic paper of each described decoration in the claim 1 to 3, it is characterized in that: this paper bag cation modified cellulose fibre.
5. the basic paper of decoration according to claim 4 is characterized in that: this cellulose fibre is by quaternary ammonium compound and glycidyl effect and modification.
6. facing paper or decorative panel comprise according to the basic paper of each described decoration in the claim 1 to 5.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10057294.4 | 2000-11-17 | ||
| DE10057294A DE10057294C5 (en) | 2000-11-17 | 2000-11-17 | Decorative paper with high opacity, as well as decorative paper or decorative foil |
| US10/006,318 US6783631B2 (en) | 2000-11-17 | 2001-11-13 | Decorative paper with a high opacity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1354304A true CN1354304A (en) | 2002-06-19 |
| CN1237226C CN1237226C (en) | 2006-01-18 |
Family
ID=27623823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN01137694.5A Expired - Fee Related CN1237226C (en) | 2000-11-17 | 2001-11-16 | Decorative paper with high opaqueness |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1207233B1 (en) |
| CN (1) | CN1237226C (en) |
| BR (1) | BR0105275B1 (en) |
| CA (1) | CA2363357C (en) |
| DE (1) | DE10057294C5 (en) |
| PL (1) | PL201227B1 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104053837A (en) * | 2012-01-16 | 2014-09-17 | 纳幕尔杜邦公司 | Dispersions made from treated inorganic particles for making decor paper having improved optical performance |
| CN104066890A (en) * | 2012-01-16 | 2014-09-24 | 纳幕尔杜邦公司 | Paper laminates made from decor paper having improved optical performance comprising treated inorganic particles |
| WO2014186953A1 (en) * | 2013-05-22 | 2014-11-27 | Dow Global Technologies Llc | Paper composition and process for making the same |
| CN104254449A (en) * | 2012-03-20 | 2014-12-31 | 科尔登霍夫路浩有限公司 | Decorative paper |
| CN104919114A (en) * | 2013-01-09 | 2015-09-16 | 纳幕尔杜邦公司 | Decor paper having improved optical performance comprising treated inorganic particles |
| CN104937168A (en) * | 2012-10-30 | 2015-09-23 | 穆恩克斯祖阿尔什公司 | Decorative paper for layered products |
| CN105648838A (en) * | 2014-11-27 | 2016-06-08 | 舍尔勒尔电子元件两合公司 | Paper with high opacity |
| CN106436451A (en) * | 2016-08-18 | 2017-02-22 | 徐英豪 | Application of talc powder-titanium dioxide composition in papermaking filler |
| CN106480776A (en) * | 2016-08-18 | 2017-03-08 | 徐英豪 | The application in papermaking of silicon powder and titanium white compound powder |
| TWI628216B (en) * | 2014-05-15 | 2018-07-01 | 歐米亞國際公司 | Fiber board product comprising a calcium carbonate-containing material |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8043715B2 (en) | 2005-06-07 | 2011-10-25 | E. I. Du Pont De Nemours And Company | Paper and paper laminates containing modified titanium dioxide |
| DE102008030955B3 (en) * | 2008-07-02 | 2009-11-19 | Hülsta-Werke Hüls Gmbh & Co. Kg | Use of printing paper printed with a decor for flat components |
| DE102013100353A1 (en) | 2012-01-12 | 2013-08-22 | Bene_Fit Systems Gmbh & Co. Kg | Reactive composite, useful as filler in paper, comprises carrier and titanium dioxide that are connected to form stable aggregates, and organic reaction product as binder adapted to form chemical and/or physical bond by a reaction |
| DE102013009635A1 (en) | 2012-06-28 | 2014-05-22 | Kronos International, Inc. | Titanium dioxide-containing and carbonate-containing composite pigments and process for their preparation |
| DE202013009496U1 (en) | 2013-10-24 | 2013-11-14 | Samtastic Products GmbH | Multilayer decorative plastic sheet or plate |
| EP2883917A1 (en) | 2013-12-13 | 2015-06-17 | Kronos International, Inc. | Composite pigments containing calcium phosphate and method for their preparation |
| CN104313936B (en) * | 2014-08-26 | 2016-08-24 | 淄博欧木特种纸业有限公司 | Composite decoration paper of wood-based plate and preparation method thereof |
| EP3081602A1 (en) | 2015-04-17 | 2016-10-19 | Kronos International, Inc. | Composite pigments containing aluminium hydroxide and method for their preparation |
| DE102015002946A1 (en) | 2015-03-10 | 2016-09-15 | Kronos International, Inc. | Aluminum hydroxide-containing composite pigments and process for their preparation |
| CN107250288A (en) | 2015-03-10 | 2017-10-13 | 克罗内斯国际公司 | Composite pigment of aluminium hydroxide and preparation method thereof |
| EP3307531A4 (en) * | 2015-06-09 | 2019-02-27 | Imerys USA, Inc. | Compositions and methods for reducing or extending titanium dioxide in paper |
| EP4202117A1 (en) | 2021-12-23 | 2023-06-28 | Schoeller Technocell GmbH & Co. KG | Two-layer decorative paper for improving print quality |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02265679A (en) * | 1989-04-06 | 1990-10-30 | Fuji Kobunshi Kk | Preparation of pearl printing pattern decorative panel excellent in color developability |
| US5268204A (en) * | 1992-02-28 | 1993-12-07 | The Mead Corporation | Method for producing decorative paper using a slot coater, decorative paper, and decorative laminates prepared therefrom |
| JP4029942B2 (en) * | 1996-03-28 | 2008-01-09 | 株式会社興人 | Artificial solid cosmetics |
| DE19728796A1 (en) * | 1997-07-05 | 1999-01-07 | Robert Cordier Ag | Raw decorative paper |
| FR2773180B1 (en) * | 1997-12-30 | 2000-02-04 | Arjo Wiggins Sa | DECORATIVE PAPER SHEET COMPRISING A TITANIUM DIOXIDE COMPOSITION AND DECORATIVE LAMINATE COMPRISING SAME |
| DE19912149C2 (en) * | 1999-03-18 | 2003-05-15 | Technocell Dekor Gmbh & Co Kg | Decorative paper with improved dry strength as well as decor paper or decorative foil produced with it |
-
2000
- 2000-11-17 DE DE10057294A patent/DE10057294C5/en not_active Expired - Fee Related
-
2001
- 2001-11-08 EP EP01126632A patent/EP1207233B1/en not_active Revoked
- 2001-11-15 CA CA002363357A patent/CA2363357C/en not_active Expired - Fee Related
- 2001-11-16 CN CN01137694.5A patent/CN1237226C/en not_active Expired - Fee Related
- 2001-11-16 BR BRPI0105275-6A patent/BR0105275B1/en not_active IP Right Cessation
- 2001-11-16 PL PL350718A patent/PL201227B1/en unknown
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104066890B (en) * | 2012-01-16 | 2017-03-29 | 纳幕尔杜邦公司 | It is fit by ply of paper inorganic particle, made by the facing paper with the optical property for improving processed comprising Jing |
| CN104066890A (en) * | 2012-01-16 | 2014-09-24 | 纳幕尔杜邦公司 | Paper laminates made from decor paper having improved optical performance comprising treated inorganic particles |
| CN104053837A (en) * | 2012-01-16 | 2014-09-17 | 纳幕尔杜邦公司 | Dispersions made from treated inorganic particles for making decor paper having improved optical performance |
| CN104254449A (en) * | 2012-03-20 | 2014-12-31 | 科尔登霍夫路浩有限公司 | Decorative paper |
| CN104937168B (en) * | 2012-10-30 | 2017-10-27 | 穆恩克斯祖阿尔什公司 | Facing paper for layered articles |
| CN104937168A (en) * | 2012-10-30 | 2015-09-23 | 穆恩克斯祖阿尔什公司 | Decorative paper for layered products |
| CN104919114A (en) * | 2013-01-09 | 2015-09-16 | 纳幕尔杜邦公司 | Decor paper having improved optical performance comprising treated inorganic particles |
| CN105209687A (en) * | 2013-05-22 | 2015-12-30 | 陶氏环球技术有限责任公司 | Paper composition and process for making the same |
| WO2014186953A1 (en) * | 2013-05-22 | 2014-11-27 | Dow Global Technologies Llc | Paper composition and process for making the same |
| CN105209687B (en) * | 2013-05-22 | 2018-04-17 | 陶氏环球技术有限责任公司 | Paper composition and its manufacture method |
| US10392752B2 (en) | 2013-05-22 | 2019-08-27 | Dow Global Technologies Llc | Paper composition and process for making the same |
| TWI628216B (en) * | 2014-05-15 | 2018-07-01 | 歐米亞國際公司 | Fiber board product comprising a calcium carbonate-containing material |
| CN105648838A (en) * | 2014-11-27 | 2016-06-08 | 舍尔勒尔电子元件两合公司 | Paper with high opacity |
| CN106436451A (en) * | 2016-08-18 | 2017-02-22 | 徐英豪 | Application of talc powder-titanium dioxide composition in papermaking filler |
| CN106480776A (en) * | 2016-08-18 | 2017-03-08 | 徐英豪 | The application in papermaking of silicon powder and titanium white compound powder |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1207233A2 (en) | 2002-05-22 |
| PL201227B1 (en) | 2009-03-31 |
| CN1237226C (en) | 2006-01-18 |
| EP1207233A3 (en) | 2003-12-03 |
| EP1207233B1 (en) | 2005-01-05 |
| CA2363357A1 (en) | 2002-05-17 |
| DE10057294C1 (en) | 2002-06-27 |
| BR0105275A (en) | 2002-06-25 |
| BR0105275B1 (en) | 2012-03-20 |
| PL350718A1 (en) | 2002-05-20 |
| DE10057294C5 (en) | 2005-06-30 |
| CA2363357C (en) | 2004-05-25 |
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