CN1354124A - Preparation equipment of high-purity chlorinedioxide stable liquor and its preparation process - Google Patents
Preparation equipment of high-purity chlorinedioxide stable liquor and its preparation process Download PDFInfo
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- CN1354124A CN1354124A CN 01138049 CN01138049A CN1354124A CN 1354124 A CN1354124 A CN 1354124A CN 01138049 CN01138049 CN 01138049 CN 01138049 A CN01138049 A CN 01138049A CN 1354124 A CN1354124 A CN 1354124A
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Abstract
The present invention relates to an equipment for preparing high-purity chlorinedioxide stable liuqor and its process. Said equipment is formed from two raw liquor tanks, a reactor, a purifier and two series-connected absorbers, and the interior of reactor. The purifier and absorber is respectively equipped with several gas jetting bubbling, tubes. The sodium chlorate, sulfuric acid and sodium chlroide are mixed according to a certain mixing ratio, heated and reacted in the reactor under the positive gas jetting bublbing action to produce mixed gas containing chlorinedioxide and chlorine gas. Then the mixed gas is passed through the purifier and purified by sodium chloride saturated solution, and the chlorine gas being ni the mixed gas can be reacted with sodium chlorite to produce chlorinedioxide, then the chlorinedioxide gas is fed into two series-connected absorbers, and absorbed and stabilized by mixed solution containing sodium hydroxide, sodium percarbonate and pH buffering agent to obtain stable chlorinedioxide solution whose purity can be up to 98%.
Description
One, affiliated technical field
The present invention relates to a kind of efficient universality sterilizing agent preparation facilities and preparation technology, particularly a kind of chlorine dioxide with high purity stable liquid preparation facilities and technology.
Two, background technology
Dioxide peroxide is very wide as a kind of efficient its Application Areas of universality sterilizing agent, but the storage stability of dioxide peroxide is relatively poor, so can only instantly join, stable ClO 2 solution also arises at the historic moment, stable ClO 2 solution generally adopts sodium chlorate and two kinds of medicaments of hydrochloric acid to carry out the prepared in reaction dioxide peroxide at present, this method low price, but transformation efficiency is low and the product that obtains in contain a large amount of chlorine, the mol ratio of dioxide peroxide and chlorine is 2: 1, not only purity of chlorine dioxide is lower, and chlorine wherein causes the halohydrocarbon in the water body to exceed standard easily.The mixing that existing stable ClO 2 solution adopts negative-pressure gas to stir mostly and strengthens reactant contacts, but partly volume is less for the reactor of this kind equipment, negative pressure inlet amount in the reactor is limited, and gas enters behind the liquid because gas speed is slow, and stirring action is little, and it makes that the mixedness of reaction liquid is not high, reaction conversion ratio is also less, this kind system adopts the spray absorption process simultaneously, and the gas-to-liquid contact area is little, and assimilated efficiency is lower.Chinese patent ZL99112023.5, denomination of invention is " based on the process for preparing stable ClO 2 solution of hydrochloric acid ", it discloses a kind of production method of stable ClO 2 solution, it is to be oxygenant with the sodium chlorate, with hydrochloric acid is that reductive agent reacts, generate chlorine dioxide, stablize with sodium hydroxide or hydrogen peroxide again and absorb, finally produce stable solutions.Above-mentioned preparation method is when concrete reaction, and have following defective: 1. system carries out with the negative pressure form, so the gentle speed of the air input of reactor is limited, does not reach the gentle effect of proposing of enough stirrings; 2. be to form negative pressure with absorption liquid by water sprayer in system, with chlorine dioxide inspiration reactor, spray absorption, this method gas-to-liquid contact area is little, and assimilated efficiency is low, and soak time is long, and the energy consumption height is big to the corrodibility of pump; 3. contain higher dioxide peroxide in the tail gas after absorbing, promptly caused waste, caused the pollution of surrounding environment again; 4. the dioxide peroxide transformation efficiency of this method acquisition is lower, has only 45%～60% usually.
Three, summary of the invention
The object of the present invention is to provide a kind of sufficient reacting, the transformation efficiency height, can cut down the consumption of energy simultaneously and system architecture simple, cost is low, the high strength dioxide peroxide stable liquid preparation facilities and the preparation technology thereof of easy handling.
The objective of the invention is to realize in the following manner, chlorine dioxide with high purity stable liquid preparation facilities, it comprises two former liquid baths, a reactor, a purifier, it is characterized in that it also comprises two placed in-line resorbers, be equipped with 3～16/100cm in reactor, purifier and two resorbers
2Injection bubbling pipe, reactor lower part is provided with stoste import and waste liquid outlet, the stoste import links to each other with two former liquid baths by two well heaters respectively, reactor head is provided with inlet mouth, the product outlet is arranged at top, it links to each other with purifier top inlet mouth, the purifying agent import is arranged at the purifier bottom, the dioxide peroxide outlet is arranged at top, it links to each other with the inlet mouth of previous placed in-line absorber overhead, the air outlet, top of this resorber links to each other with the inlet mouth of back one absorber overhead again, the fluid inlet at last resorber middle part links to each other with the leakage fluid dram of one resorber bottom, back, the top of back one resorber and the venting port that the middle part is respectively equipped with residual gas and the fluid inlet of absorption liquid, the last stable ClO 2 solution outlet that generates of system is arranged on the bottom of last resorber.According to above-mentioned preparation facilities, the preparation of chlorine dioxide with high purity is an oxygenant with saturated sodium chlorate respectively, with hydrochloric acid, clorox is a reductive agent, with sulfuric acid is souring agent, with saturated Textone is purifying agent, with SPC-D, the mixed solution of sodium hydroxide and pH value damping fluid is an absorption agent, its preparation technology is: 1. with saturated sodium chlorate solution and 33～33.5% hydrochloric acid, sulfuric acid and chlorine bleach liquor be (1.5～2) in molar ratio: (0.5～1.0): (0.4～1.0): (0.1～0.5) is respectively by being heated to 45～70 ℃, deliver to the jet blistering reactor and react, reaction time is 35～45 minutes; 2. with the dioxide peroxide, chlorine and the unreacted hydrogen chloride gas mixture that generate in purifier with saturated sodium chlorite solution's reaction purification, make wherein chlorine and hydrogenchloride and Textone reaction generation dioxide peroxide; 3. the mixing solutions that the chlorine dioxide that generates is passed through SPC-D, sodium hydroxide and pH value damping fluid in two placed in-line resorbers absorbs, the inlet amount of the volume pump of the absorption liquid of the interlock of the signal by pH value is simultaneously regulated liquid pH value after control absorbs between 8.2～9.2; 4. system adopts the sudden and violent gas of Iatm malleation, and the gas flow rate of injection bubbling pipe is 8～22 meter per seconds, adopts the volume pump charging in addition, and the resultant traffic direction of the feedstock direction of absorption liquid and reaction goes in the same direction.
The present invention compared with prior art, its remarkable advantage is: 1. this apparatus system adopts the sudden and violent gas of positive-pressure type, tolerance and air pressure can adjustings in a big way in as required, make reaction solution under the effect of injection bubbling pipe, mix fully, do not stir the dead angle, reaction solution is torn by high velocity air, in solution, form micro-bubble, thereby increased the gas-to-liquid contact area, improved gas and proposed effect, made reaction more abundant, transformation efficiency improves greatly, and the transformation efficiency in reactor reaches 98%; 2. adopt two placed in-line resorbers, make chlorine dioxide after purified under the effect of jet blistering resorber, being absorbed liquid fully absorbs, the traffic direction of absorption liquid and chlorine dioxide adopts flow path direction simultaneously, increased assimilation effect more, reduce the exhaust emissions of dioxide peroxide, reduced energy consumption simultaneously; 3. this system adopts the volume pump charging, and it makes reacts accurate measurement, transformation efficiency and dioxide peroxide stable liquid purity height, and the dioxide peroxide stable liquid purity that makes through this system can reach 99%; 4. the system architecture of this device is simple, the low and easy handling of use cost.
Four, description of drawings
Accompanying drawing is the structural principle synoptic diagram of chlorine dioxide with high purity stable liquid preparation facilities of the present invention.
Five, embodiment
Below in conjunction with accompanying drawing the present invention is described in further detail.
Form by former liquid bath (1), former liquid bath (2), reactor (5), purifier (10) and two placed in-line resorbers (14) and (20) according to chlorine dioxide with high purity stable liquid preparation facilities of the present invention.In raw material tank (1) and raw material tank (2), add saturated sodium chlorate reaction solution and 0.65～33.5 hydrochloric acid respectively, sulfuric acid and chlorine bleach liquor, their mass ratio is (1.66): (0.65): (0.8): (0.3), reaction solution is transported in well heater (3) and the well heater (4) by volume pump respectively and is heated to 70 ℃, enter in the reactor (5) through reaction solution import (6) again, inlet mouth (7) input pressure air by top in the reactor (5), under the effect of injection bubbling pipe (24), gas forms the micro-bubble of a large amount of parallel injections, two kinds of reaction liquids are fully stirred, make it to react completely, the parallel injection of micro-bubble has increased gas-liquid contact time and contact area simultaneously, improve gas and proposed effect, reaction is carried out to the resultant direction, increased reaction efficiency, shortened the reaction times.Dioxide peroxide that generates and chlorine and mixed gas are by being positioned at the top product outlet (8) of jet blistering reactor (5), the top inlet mouth (11) of purified device (10) enters in the purifier (10), purifying agent is that the inlet pipe (12) by the bottom of purifier (10) enters, generate dioxide peroxide with the chlorine reaction in the gas, chlorine dioxide behind the purifying enters two placed in-line jet blistering resorbers (14) and (20) from the top outlet (13) of purifier (10), with be fixed in the solution after yellow soda ash the absorption liquid that enters from resorber (26) centre inlet (23) and the sodium hydroxide reaction, surplus air after the absorption is discharged by the top relief outlet (22) of jet blistering resorber (20), and the stable ClO 2 solution for preparing is discharged by the lower part outlet (15) of jet blistering resorber (14).Wherein jet blistering resorber (14) middle part fluid inlet (18) links to each other with the leakage fluid dram (19) of jet blistering resorber (20).The traffic direction of absorption liquid and chlorine dioxide is a kind of to flow path direction, has increased assimilation effect.
Injection bubbling pipe (24) in reactor (5), purifier (10), resorber (14) and the resorber (20) adopts the corrosion-resistant pipe of Φ 20～Φ 60 to make, the bottom of pipe is totally-enclosed, below side, open equidistant parallel long square opening or circular port, the arrangement of injection bubbling pipe (24) is arranged on the back up pad (25) by equilateral triangle or rectangle, and emission intensity is 3～16/100cm
2, it is between 11.5～12.8 that absorption liquid is prepared into PH.
Claims (4)
1, a kind of chlorine dioxide with high purity stable liquid preparation facilities, it comprises two former liquid baths [1], [2], reactor [5], purifier [10] is characterized in that it also comprises in two placed in-line resorbers [14] and [20] reactor [5], purifier [10], resorber [14] and [20] to be provided with 3～16 100cm
2Root injection bubbling pipe [24], reactor [5] bottom is provided with stoste import [6] and waste liquid product [9], stoste import [6] is respectively by two well heaters [3], [4] with former liquid bath [1], [2] link to each other, reactor [5] top is provided with inlet mouth [7], product outlet [8] is established on top, it links to each other with purifier [10] top inlet mouth [11], purifying agent import [12] is arranged at purifier [10] bottom, top has dioxide peroxide outlet [13] to link to each other with resorber [14] top inlet mouth [16], the air outlet [17] on resorber [14] top links to each other with the inlet mouth [21] at resorber [20] top, the fluid inlet [18] at resorber [14] middle part links to each other with the leakage fluid dram [19] of resorber [20] bottom, the top of resorber [20] and middle part are respectively equipped with residual gas venting port [22] and absorption liquid import [23], and stable ClO 2 solution outlet [15] is arranged on the bottom of resorber [14].
2, chlorine dioxide with high purity stable liquid preparation facilities according to claim 1, it is characterized in that described injection bubbling pipe [24] presses equilateral triangle or square pitch arrangement on [25] on the back up pad, back up pad [25] is separately fixed at the top in reactor [5], purifier [10], resorber [14] and the resorber [20].
3, chlorine dioxide with high purity stable liquid preparation facilities according to claim 1 and 2 is characterized in that the closed bottom of above-mentioned injection bubbling pipe [24], has 2 to 3 equidistant holes in the lower side of pipe.
4, the chlorine dioxide with high purity stable liquid technology for preparing according to the described device of claim 1, it is characterized in that it is an oxygenant with saturated sodium chlorate respectively, with hydrochloric acid and clorox is reductive agent, with saturated sodium chlorite solution is purifying agent, is absorption agent with the mixed solution of SPC-D, sodium hydroxide and pH value damping fluid; Its technology is hydrochloric acid, sulfuric acid and chlorine bleach liquor that 1. will saturated sodium chlorate solution and 33～33.5% (1.5～2) in molar ratio: (0.5～1.0): (0.4～1.0) (0.1～0.5) is passed through respectively and is heated to 45～70 ℃, deliver to the jet blistering reactor and react, reaction time is 35～45 minutes; 2. with the dioxide peroxide, chlorine and the unreacted hydrogen chloride gas mixture that generate in purifier with saturated sodium chlorite solution's reaction purification, make wherein chlorine and hydrogenchloride and Textone reaction generation dioxide peroxide; 3. the mixing solutions that the chlorine dioxide that generates is passed through SPC-D, sodium hydroxide and pH value damping fluid in two placed in-line resorbers absorbs, the inlet amount of the volume pump of the absorption liquid of the interlock of the signal by PH is simultaneously regulated liquid pH value after control absorbs between 8.2～9.2; 4. system adopts the sudden and violent gas of Iatm malleation, and the gas flow rate of injection bubbling pipe is 8～22 meter per seconds, adopts the volume pump charging, and the resultant traffic direction of the feedstock direction of absorption liquid and reaction goes in the same direction in addition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011380497A CN1177755C (en) | 2001-12-28 | 2001-12-28 | Preparation equipment of high-purity chlorinedioxide stable liquor and its preparation process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011380497A CN1177755C (en) | 2001-12-28 | 2001-12-28 | Preparation equipment of high-purity chlorinedioxide stable liquor and its preparation process |
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| CN1354124A true CN1354124A (en) | 2002-06-19 |
| CN1177755C CN1177755C (en) | 2004-12-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB011380497A Expired - Fee Related CN1177755C (en) | 2001-12-28 | 2001-12-28 | Preparation equipment of high-purity chlorinedioxide stable liquor and its preparation process |
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| CN (1) | CN1177755C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105417497A (en) * | 2015-12-15 | 2016-03-23 | 刘学思 | Production device and technology for high-concentration steady chlorine dioxide solution |
| CN107188296A (en) * | 2017-07-28 | 2017-09-22 | 辽东学院 | The method that chlorine dioxide mixed oxidization method handles amino phenols waste water from dyestuff |
| CN108529810A (en) * | 2018-05-24 | 2018-09-14 | 广西金圆环保科技有限公司 | A kind of garbage percolation liquid treating system |
| CN110200011A (en) * | 2019-07-05 | 2019-09-06 | 四川齐力绿源水处理科技有限公司 | A kind of preparation method of composite chlorine dioxide |
| CN111232928A (en) * | 2020-03-05 | 2020-06-05 | 山东德洋计量检测有限公司 | Chlorine dioxide preparation and purification device and preparation method thereof |
| CN114684789A (en) * | 2022-03-16 | 2022-07-01 | 华南理工大学 | Preparation method of high-purity chlorine dioxide stable solution |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100350843C (en) * | 2004-10-26 | 2007-11-28 | 淄博华润科贸有限责任公司 | Device for preparing pure chlorine dioxide disinfection liquid |
| CN102090417B (en) * | 2010-12-22 | 2013-07-03 | 韶关蓝威消毒药业有限公司 | Preparation method of living disinfectant |
-
2001
- 2001-12-28 CN CNB011380497A patent/CN1177755C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105417497A (en) * | 2015-12-15 | 2016-03-23 | 刘学思 | Production device and technology for high-concentration steady chlorine dioxide solution |
| CN105417497B (en) * | 2015-12-15 | 2017-12-08 | 刘学思 | A kind of process units and technique of high concentration of chlorine dioxide stable state liquid |
| CN107188296A (en) * | 2017-07-28 | 2017-09-22 | 辽东学院 | The method that chlorine dioxide mixed oxidization method handles amino phenols waste water from dyestuff |
| CN107188296B (en) * | 2017-07-28 | 2020-08-18 | 辽东学院 | Method for treating aminophenol dye wastewater by chlorine dioxide mixed oxidation method |
| CN108529810A (en) * | 2018-05-24 | 2018-09-14 | 广西金圆环保科技有限公司 | A kind of garbage percolation liquid treating system |
| CN110200011A (en) * | 2019-07-05 | 2019-09-06 | 四川齐力绿源水处理科技有限公司 | A kind of preparation method of composite chlorine dioxide |
| CN111232928A (en) * | 2020-03-05 | 2020-06-05 | 山东德洋计量检测有限公司 | Chlorine dioxide preparation and purification device and preparation method thereof |
| CN114684789A (en) * | 2022-03-16 | 2022-07-01 | 华南理工大学 | Preparation method of high-purity chlorine dioxide stable solution |
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| Publication number | Publication date |
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| CN1177755C (en) | 2004-12-01 |
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