CN1335281A - Sliding sprue tile for smelting high-oxygen steel and calcium treated steel - Google Patents
Sliding sprue tile for smelting high-oxygen steel and calcium treated steel Download PDFInfo
- Publication number
- CN1335281A CN1335281A CN 01126439 CN01126439A CN1335281A CN 1335281 A CN1335281 A CN 1335281A CN 01126439 CN01126439 CN 01126439 CN 01126439 A CN01126439 A CN 01126439A CN 1335281 A CN1335281 A CN 1335281A
- Authority
- CN
- China
- Prior art keywords
- steel
- smelting
- oxygen
- calcium treated
- treated steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 28
- 239000010959 steel Substances 0.000 title claims abstract description 28
- 238000003723 Smelting Methods 0.000 title claims abstract description 16
- 239000011575 calcium Substances 0.000 title claims abstract description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 13
- 239000001301 oxygen Substances 0.000 title claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 20
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011819 refractory material Substances 0.000 claims abstract description 11
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 9
- 239000011029 spinel Substances 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000001095 magnesium carbonate Substances 0.000 abstract description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract description 2
- 235000014380 magnesium carbonate Nutrition 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- WGACMNAUEGCUHG-VYBOCCTBSA-N (2s)-2-[[(2s)-2-[[(2s)-2-acetamidopropanoyl]amino]propanoyl]amino]-n-[(2s)-6-amino-1-[[(2s)-1-[(2s)-2-[[(2s)-1-[[(2s)-5-amino-1-[[(2s)-1-[[(2s)-1-[[(2s)-6-amino-1-[[(2s)-1-amino-3-(4-hydroxyphenyl)-1-oxopropan-2-yl]amino]-1-oxohexan-2-yl]amino]-3-hydroxy- Chemical compound CC(=O)N[C@@H](C)C(=O)N[C@@H](C)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCCN=C(N)N)C(=O)N1CCC[C@H]1C(=O)N[C@@H](CO)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CCCN=C(N)N)C(=O)N[C@@H](CO)C(=O)N[C@@H](CCCCN)C(=O)N[C@H](C(N)=O)CC1=CC=C(O)C=C1 WGACMNAUEGCUHG-VYBOCCTBSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 108010074544 myelin peptide amide-12 Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
Abstract
The refractory material for the sliding tap-hole block consists of magnesite and/or magnesia alumina spinel refractory material 90-100 % with the rest being zirconia or titanium oxide refractory material. The sliding tap-hole block of the present invention has excellent mechanical performance, chemical stability, corrosion resistance, metal burn-out resistance and oxidation resistance at high temperature, and when it is used in smelting high-oxygen steel and calcium treated steel, it has long service life, light weight and low cost.
Description
(1) technical field:
The present invention relates to a kind of sliding sprue tile for smelting, particularly a kind of high-oxygen steel and calcium treated steel sliding sprue tile for smelting.
(2) background technology:
The sliding sprue tile for smelting that uses mainly contains Al at present
2O
3-C (as Japanese kokai publication hei 11-36012), MgO-C and ZrO
2Carbon containing refractories such as-C and contain aluminium oxynitride (as Chinese CN85109111A) material.For high-oxygen steel, total oxygen height in the steel, FeO height, carbon containing refractory is inefficient with containing the aluminium oxynitride material thus, it will produce oxidation and cause material loose, be to influence its long-lived major reason, thereby limited carbonaceous material and the application that contains aluminium oxynitride; Al
2O
3Material and zirconia material antagonism FeO aggressiveness also are very poor refractory materialss.For the calcium treated steel that has 20～40ppm free [Ca] in the steel, salic, silicon oxide, mullite material are inefficient, and it will cause damage serious owing to generating eutectic, limit the application of such material; Though zirconia material satisfies the requirement of calcium treated steel, there is big, the expensive problem of weight.
(3) summary of the invention:
The object of the present invention is to provide a kind of high-oxygen steel and calcium treated steel sliding sprue tile for smelting, improve its work-ing life, reduce its cost.
For achieving the above object, the present invention adopts following technical scheme:
A kind of high-oxygen steel and calcium treated steel sliding sprue tile for smelting is characterized in that its refractory materials by weight percentage, consist of: one or both are 90～100% in the refractory materials of magnesia and aluminum-spinel, and surplus is the refractory materials of zirconium white or titanium oxide.
Magnesia is purity greater than 97% magnesia.
Aluminum-spinel is for by weight percentage, and content of magnesia is greater than 28% aluminum-spinel.
By weight percentage, join 0～4% MgCl outward
2
The present invention compared with prior art, have following outstanding feature and remarkable advantage: sliding sprue tile for smelting provided by the invention, contain the magnesia more than 90% and the refractory materials of aluminum-spinel, at high temperature has the favorable mechanical performance, the chemical stability height, corrosion-resistant, and anti-molten metal and resistance of oxidation are strong.Under the high-oxygen steel working conditions, its work-ing life will be longer than carbon containing slide gate nozzle and zirconium white slide gate nozzle.Under the calcium treated steel working conditions, its work-ing life will be longer than salic, silicon oxide, mullite slide gate nozzle; Compare with the zirconium white slide gate nozzle, have in light weight and the low advantage of price.
Compare with traditional carbon containing sliding sprue tile for smelting, this sliding sprue tile for smelting also has following characteristics:
1. do not add carbon raw material such as graphite, carbon black etc. in the batching, free from environmental pollution, workman's working conditions is greatly improved;
2. the oxidation products of carbonaceous material is CO or CO
2, oxidation tail skid short texture forms a large amount of apparent pores, causes molten steel and slag to infiltrate, and finally causes erosion-resisting characteristics to descend.
(4) specific embodiment:
Following table is listed sliding sprue tile for smelting composition (percentage by weight) and the characteristic of 5 embodiment:
| Embodiment | 1 | 2 | 3 | 4 | 5 |
| Highly-purity magnesite | 80 | - | 100 | 88 | 98 |
| Aluminum-spinel | 15 | 100 | - | 10 | - |
| Zirconia | 5 | - | - | - | - |
| Titanium oxide | 2 | 2 | |||
| MgCl 2, join outward | 3 | 3 | 3 | 3 | 3 |
| Body is close, g/cm3 | 3.1 | 3.05 | 3.2 | 3.12 | 3.2 |
| Apparent pore, % | 14 | 14 | 10 | 13 | 9 |
| Compressive resistance, MPa | 100 | 120 | 145 | 110 | 115 |
| Rupture strength, MPa | 12 | 14 | 10 | 9 | 8 |
| Anti-oxidant | Fine | Fine | Fine | Fine | Fine |
| Anti-FeO performance | Fine | Fine | Good | Fine | Good |
| Anti-CaO, [Ca] performance | Good | Good | Fine | Good | Fine |
Claims (4)
1. high-oxygen steel and calcium treated steel sliding sprue tile for smelting, it is characterized in that its refractory materials by weight percentage, consist of: one or both are 90～100% in the refractory materials of magnesia and aluminum-spinel, and surplus is the refractory materials of zirconium white or titanium oxide.
2. high-oxygen steel according to claim 1 and calcium treated steel sliding sprue tile for smelting is characterized in that magnesia is purity greater than 97% magnesia.
3. high-oxygen steel according to claim 1 and calcium treated steel sliding sprue tile for smelting is characterized in that aluminum-spinel for by weight percentage, and content of magnesia is greater than 28% aluminum-spinel.
4. according to claim 1 or 2 or 3 described high-oxygen steels and calcium treated steel sliding sprue tile for smelting, it is characterized in that outer by weight percentage 0～4% the MgCl that joins
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01126439 CN1209317C (en) | 2001-08-10 | 2001-08-10 | Sliding sprue tile for smelting high-oxygen steel and calcium treated steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01126439 CN1209317C (en) | 2001-08-10 | 2001-08-10 | Sliding sprue tile for smelting high-oxygen steel and calcium treated steel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1335281A true CN1335281A (en) | 2002-02-13 |
| CN1209317C CN1209317C (en) | 2005-07-06 |
Family
ID=4666456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01126439 Expired - Fee Related CN1209317C (en) | 2001-08-10 | 2001-08-10 | Sliding sprue tile for smelting high-oxygen steel and calcium treated steel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1209317C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325435C (en) * | 2004-06-30 | 2007-07-11 | 宝山钢铁股份有限公司 | Chromium free refractory material for RH vacuum furnace lining |
| CN101580381A (en) * | 2009-06-22 | 2009-11-18 | 河北理工大学 | Magnesium aluminate spinel- zirconium oxide-titanium oxide composite material and preparation method thereof |
| CN101580402A (en) * | 2009-06-22 | 2009-11-18 | 河北理工大学 | Magnesia alumina spinel-zirconia-ferric oxide composite material and preparation method thereof |
| CN102249718A (en) * | 2011-06-10 | 2011-11-23 | 鞍山浦项特种耐火材料有限公司 | Aluminum magnesium carbon sliding plate brick for stopping slag at steel tapping hole of converter |
| CN101519309B (en) * | 2008-02-27 | 2012-01-11 | 宝山钢铁股份有限公司 | Zirconium spinel carbon based slide gate nozzle brick |
| CN102442829A (en) * | 2011-09-28 | 2012-05-09 | 中钢集团耐火材料有限公司 | Metal composite impermeable and unfired magnesia spinel brick for furnace liner of refining furnace and preparation method of magnesia spinel brick |
| CN102584293A (en) * | 2012-02-24 | 2012-07-18 | 辽宁科技大学 | Method for preparing magnesium-zirconium-carbon slide gate nozzle |
| CN101786889B (en) * | 2009-12-24 | 2012-07-18 | 上海宝威陶瓷新材料有限公司 | Zirconia/spinel nozzle brick |
| CN102643099A (en) * | 2012-05-15 | 2012-08-22 | 武汉科技大学 | Magnesium-zirconium ring of slide plate for calcium-treated steel and preparation method thereof |
| CN102924095A (en) * | 2012-08-08 | 2013-02-13 | 营口青花耐火材料股份有限公司 | Magnesium-zirconium-aluminum bricks used in vacuum degassing furnace, and preparation method thereof |
| CN102992782A (en) * | 2011-09-14 | 2013-03-27 | 中钢集团耐火材料有限公司 | Refractory brick used for oxygen-fuel combustion glass kiln |
-
2001
- 2001-08-10 CN CN 01126439 patent/CN1209317C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325435C (en) * | 2004-06-30 | 2007-07-11 | 宝山钢铁股份有限公司 | Chromium free refractory material for RH vacuum furnace lining |
| CN101519309B (en) * | 2008-02-27 | 2012-01-11 | 宝山钢铁股份有限公司 | Zirconium spinel carbon based slide gate nozzle brick |
| CN101580381A (en) * | 2009-06-22 | 2009-11-18 | 河北理工大学 | Magnesium aluminate spinel- zirconium oxide-titanium oxide composite material and preparation method thereof |
| CN101580402A (en) * | 2009-06-22 | 2009-11-18 | 河北理工大学 | Magnesia alumina spinel-zirconia-ferric oxide composite material and preparation method thereof |
| CN101786889B (en) * | 2009-12-24 | 2012-07-18 | 上海宝威陶瓷新材料有限公司 | Zirconia/spinel nozzle brick |
| CN102249718A (en) * | 2011-06-10 | 2011-11-23 | 鞍山浦项特种耐火材料有限公司 | Aluminum magnesium carbon sliding plate brick for stopping slag at steel tapping hole of converter |
| CN102249718B (en) * | 2011-06-10 | 2013-06-19 | 鞍山浦项特种耐火材料有限公司 | Aluminum magnesium carbon sliding plate brick for stopping slag at steel tapping hole of converter |
| CN102992782A (en) * | 2011-09-14 | 2013-03-27 | 中钢集团耐火材料有限公司 | Refractory brick used for oxygen-fuel combustion glass kiln |
| CN102442829A (en) * | 2011-09-28 | 2012-05-09 | 中钢集团耐火材料有限公司 | Metal composite impermeable and unfired magnesia spinel brick for furnace liner of refining furnace and preparation method of magnesia spinel brick |
| CN102442829B (en) * | 2011-09-28 | 2015-12-09 | 中钢集团耐火材料有限公司 | The antiseepage of refining furnace furnace lining metal composite does not burn magnesia-spinel brick and preparation method thereof |
| CN102584293A (en) * | 2012-02-24 | 2012-07-18 | 辽宁科技大学 | Method for preparing magnesium-zirconium-carbon slide gate nozzle |
| CN102584293B (en) * | 2012-02-24 | 2014-12-03 | 辽宁科技大学 | Method for preparing magnesium-zirconium-carbon slide gate nozzle |
| CN102643099A (en) * | 2012-05-15 | 2012-08-22 | 武汉科技大学 | Magnesium-zirconium ring of slide plate for calcium-treated steel and preparation method thereof |
| CN102924095A (en) * | 2012-08-08 | 2013-02-13 | 营口青花耐火材料股份有限公司 | Magnesium-zirconium-aluminum bricks used in vacuum degassing furnace, and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1209317C (en) | 2005-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1209317C (en) | Sliding sprue tile for smelting high-oxygen steel and calcium treated steel | |
| CN101037341A (en) | Non-oxide composite low-carbon magnesia-carbon brick | |
| CN101391897A (en) | Air brick for magnesia carbon ladle and method for producing the same | |
| WO2022237727A1 (en) | Corrosion-resistant refractory material, preparation method therefor, and use thereof | |
| CN110922167A (en) | Magnesia carbon brick added with rare earth oxide | |
| CN100364931C (en) | Novel aluminum-zirconium-carbon slide brick for flow control in metallurgy industry | |
| EP4349797A1 (en) | Ca6-based refractory material with medium volume density, preparation method therefor, and use thereof | |
| CN1865189A (en) | Method for preparing electro-fused magnesia alumina spinel | |
| JP2000103665A (en) | Carbon-including unburned refractory material, and vessel for molten metal | |
| CN1304325C (en) | Synthetic refractory material for refractory product and its production method | |
| KR890000485B1 (en) | Magnesia-carbon refractory | |
| CN109776101B (en) | CA (certificate Authority)6-MA-Cr2O3-Al2O3Ladle lining castable and preparation method thereof | |
| JP2001114571A (en) | Castable refractory for trough of blast furnace | |
| CN107382345B (en) | Preparation method of micro-nano spinel toughened MgO-MA aggregate | |
| CN1415447A (en) | Slide gate nozzle brick utilized in metallurgic cast and prepn. thereof | |
| CN101519309B (en) | Zirconium spinel carbon based slide gate nozzle brick | |
| CN1759077A (en) | Batch for producing a refractory ceramic shaped body, shaped body made therefrom, and a use thereof | |
| KR100689154B1 (en) | Refractory materials for mgo-c brick | |
| CN1251991C (en) | Zircon carbon brick | |
| JP3121442B2 (en) | Refractory | |
| CN1280043A (en) | Slide sprue brick containg sialon | |
| CN115537497B (en) | Eddy current erosion resistant EBT steel-tapping hole tail brick for electric furnace and preparation method and application thereof | |
| CN1212209C (en) | Metal ceramic sliding water gap bricks | |
| CN117534486A (en) | Preparation method for tundish lining material protective coating for clean steel smelting | |
| CN1401612A (en) | Burnt aluminum-carbon brick for torpedo hot metal mixer car and mfg. method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050706 Termination date: 20130810 |