CN1335279A - High-performance concrete pumping agent and its prepn process - Google Patents
High-performance concrete pumping agent and its prepn process Download PDFInfo
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- CN1335279A CN1335279A CN 00119482 CN00119482A CN1335279A CN 1335279 A CN1335279 A CN 1335279A CN 00119482 CN00119482 CN 00119482 CN 00119482 A CN00119482 A CN 00119482A CN 1335279 A CN1335279 A CN 1335279A
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- pumping agent
- water
- condensation
- formaldehyde
- performance concrete
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The high-performance concrete pumping agent has the main ingredients including modified naphthalenesulfonic acid-formaldehyde condensate, hexonic dicalcium, methyl cellulose, gleditschia, horrida immersion fluid, sodium sulfate and water. It has the functions of reducing water, pumping aiding, delaying coagulation, etc. and may be used widely in the production of concrete and mortar, especially high grade and self leveling high-strength concrete.
Description
The present invention relates to cement class material of construction, belong to concrete especially with adding pumping agent.
Concrete is building materials important in the construction industry, along with the civil engineering technical development, more and more higher to concrete requirement, require to use C60, C80 to C100 strong concrete more and more widely must mix admixture for this reason, and in most commerical ready-mixed concretes productions, water-reducing rate is 20～25%, chloride ion content 0.3～0.5%, and therefore making the above concrete pump-feed agent of C80 is scientific research personnel's direction.
The purpose of this invention is to provide a kind of high performance concrete pumping agent and technology thereof.It can improve water-reducing rate effectively, lowers chloride ion content.
The present invention seeks to be achieved through the following technical solutions, the weight percent of pumping agent component is:
Modified naphthalene sulfonate formaldehyde condensate 25～40%
Hexose dicalcium 5～10%
Methylcellulose gum 1～5%
Chinese honey locust infusion 1～3%
Sodium sulphate 1～3%
Water 40～60%
The pumping agent technical process is:
(1) modified naphthalene sulfonate formaldehyde condensate technology: the refined naphthalene of rectifying to 95 on rectifying tower～99%, with refined naphthalene and sulfuric acid gas SO
3Carry out sulfonation reaction, its mole ratio is a naphthalene: sulfuric acid=1: 1.5, temperature is 155～165 ℃, generate the sulfonation reaction thing, the sulfonation reaction thing is hydrolyzed in glassed steel reaction vessels again, its mole ratio is a sulfonated bodies: water=1: 11.5, with acidity control 24～27%, 95～100 ℃ of temperature, hydrolyzate and formaldehyde carry out condensation then, and the condensation mole ratio is a hydrolyzate: formaldehyde=1: 0.7～1.0, under a normal atmosphere, temperature is 110～115 ℃, and 12 hours condensation time, condensation is finished, neutralize with the calcium hydroxide lysate, being neutralized to pH value is 9～11, refilters, and removes calcium sulfate precipitation.
(2) pumping agent complex process; With ratio is 1: 1 Chinese honey locust and water, is heated to 95～100 ℃, and digestion 24 hours adds hexose dicalcium 5～10%, formaldehyde Mierocrystalline cellulose 1～5%, sodium sulphate 1～3%, deionized water with leach liquor, is re-dubbed finished product in agitator kettle.
Prescription and technology that the present invention adopts, the pumping agent that makes, make the diminishing ability improve 100%, thereby can make greatly mobile strong concrete such as high-grade concrete and self-leveling concrete, by pre-treatment and employing high efficiency separation purifying technique to raw material, make chloride ion content reduce more than 10 times, detect proof through Shanghai Construction Science Research Inst.: water-reducing rate reaches 30%～35%, chloride ion content is 0.03%～0.05%, thereby eliminated the hidden danger of Rust of Rebar in Concrete, composite multiple auxiliary agent makes the present invention have diminishing, slow setting, help pump, guarantor's effect such as collapse, cost is low, can be widely used in the production of commerical ready-mixed concrete and commodity mortar.
Below be the embodiment of the invention:
The composition proportion of pumping agent is:
Modified naphthalene sulfonate formaldehyde condensate 30%
Hexose dicalcium 8%
Methylcellulose gum 4%
Chinese honey locust infusion 2%
Sodium sulphate 1%
Water 55%
Pumping agent technology;
(1) modified naphthalene sulfonate formaldehyde condensate technology; Purification rectifying is 160 ℃ to the temperature of 99% refined naphthalene sulfonation reaction, and acidity control is 25% during hydrolysis, and temperature is 100 ℃, and during condensation, hydrolyzate was than formaldehyde=1: 0.8, and temperature is 110 ℃.
(2) pumping agent complex process; Chinese honey locust 1kg and water 1kg Heating temperature are 100 ℃.Behind the digestion 24 hours, add modified naphthalene sulfonate formaldehyde condensate 30kg, hexose dicalcium 8kg, methylcellulose gum 4kg, sodium sulphate 1kg and composite the forming of water 53kg dissolving.
Claims (2)
1. high performance concrete pumping agent is characterized in that this pumping agent is made up of following each weight percentages of components:
Modified naphthalene sulfonate formaldehyde condensate 25～40%
Hexose dicalcium 5～10%
Methylcellulose gum 1～5%
Chinese honey locust infusion 1～3%
Sodium sulphate 1～3%
Water 40～60%
2. high performance concrete pumping agent technology is characterized in that:
(1) modified naphthalene sulfonate formaldehyde condensate technology;
The refined naphthalene of rectifying to 95 on rectifying tower～99% is with refined naphthalene and sulfuric acid gas SO
3Carry out sulfonation reaction, its mole ratio is a naphthalene: sulfuric acid=1: 1.5, temperature is 155～165 ℃, generate the sulfonation reaction thing, the sulfonation reaction thing is hydrolyzed in glassed steel reaction vessels again, its mole ratio is a sulfonated bodies: water=1: 11.5, with acidity control 24～27%, 95～100 ℃ of temperature, hydrolyzate and formaldehyde carry out condensation then, and the condensation mole ratio is a hydrolyzate: formaldehyde=1: 0.7～1.0, under a normal atmosphere, temperature is 110～115 ℃, and 12 hours condensation time, condensation is finished, neutralize with the calcium hydroxide lysate, being neutralized to pH value is 9～11, refilters, and removes calcium sulfate precipitation.
(3) pumping agent complex process;
With ratio is 1: 1 Chinese honey locust and water, is heated to 95～100 ℃, and digestion 24 hours adds hexose dicalcium 5～10%, formaldehyde Mierocrystalline cellulose 1～5%, sodium sulphate 1～3%, deionized water with leach liquor, is re-dubbed finished product in agitator kettle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00119482 CN1108281C (en) | 2000-07-20 | 2000-07-20 | High-performance concrete pumping agent and its prepn process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00119482 CN1108281C (en) | 2000-07-20 | 2000-07-20 | High-performance concrete pumping agent and its prepn process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1335279A true CN1335279A (en) | 2002-02-13 |
| CN1108281C CN1108281C (en) | 2003-05-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00119482 Expired - Fee Related CN1108281C (en) | 2000-07-20 | 2000-07-20 | High-performance concrete pumping agent and its prepn process |
Country Status (1)
| Country | Link |
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| CN (1) | CN1108281C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101762A (en) * | 2010-12-29 | 2011-06-22 | 山东宏艺科技股份有限公司 | Exposed concrete pumping agent and preparation method thereof |
| CN102795806A (en) * | 2012-08-14 | 2012-11-28 | 山东大元实业股份有限公司 | Chlorine salt-free ammonia-free liquid concrete anti-freezing pumping agent |
| CN105130262A (en) * | 2015-08-25 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Concrete non-toxic pumping agent and preparation method therefor |
| CN109503023A (en) * | 2018-12-27 | 2019-03-22 | 山西黄腾化工有限公司 | A kind of pumping agent for concrete and its production technology |
| CN110790879A (en) * | 2019-10-08 | 2020-02-14 | 安徽生源化工有限公司 | Production process of water reducing agent |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331799C (en) * | 2006-04-24 | 2007-08-15 | 蒋德双 | Concrete pump and preparation method thereof |
-
2000
- 2000-07-20 CN CN 00119482 patent/CN1108281C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101762A (en) * | 2010-12-29 | 2011-06-22 | 山东宏艺科技股份有限公司 | Exposed concrete pumping agent and preparation method thereof |
| CN102101762B (en) * | 2010-12-29 | 2013-07-31 | 山东宏艺科技股份有限公司 | Exposed concrete pumping agent and preparation method thereof |
| CN102795806A (en) * | 2012-08-14 | 2012-11-28 | 山东大元实业股份有限公司 | Chlorine salt-free ammonia-free liquid concrete anti-freezing pumping agent |
| CN105130262A (en) * | 2015-08-25 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Concrete non-toxic pumping agent and preparation method therefor |
| CN109503023A (en) * | 2018-12-27 | 2019-03-22 | 山西黄腾化工有限公司 | A kind of pumping agent for concrete and its production technology |
| CN110790879A (en) * | 2019-10-08 | 2020-02-14 | 安徽生源化工有限公司 | Production process of water reducing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1108281C (en) | 2003-05-14 |
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| CF01 | Termination of patent right due to non-payment of annual fee |