CN1331741A - Methods for laundering delicate garments in washing machine - Google Patents
Methods for laundering delicate garments in washing machine Download PDFInfo
- Publication number
- CN1331741A CN1331741A CN99815017A CN99815017A CN1331741A CN 1331741 A CN1331741 A CN 1331741A CN 99815017 A CN99815017 A CN 99815017A CN 99815017 A CN99815017 A CN 99815017A CN 1331741 A CN1331741 A CN 1331741A
- Authority
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- Prior art keywords
- washing
- clothes
- composition
- detergent composition
- liquid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
Classifications
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- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
- D06F35/005—Methods for washing, rinsing or spin-drying
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass
- A47L25/08—Pads or the like for cleaning clothes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/20—Organic compounds containing oxygen
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- C11D3/2041—Dihydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F3/00—Hand rubbing apparatus
- D06F3/04—Hand rubbers, e.g. gloves with corrugated surfaces
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F95/00—Laundry systems or arrangements of apparatus or machines; Mobile laundries
- D06F95/002—Baskets or bags specially adapted for holding or transporting laundry; Supports therefor
- D06F95/004—Bags; Supports therefor
- D06F95/006—Bags for holding the laundry during washing
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C11D2111/12—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2048—Dihydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2051—Dihydric alcohols cyclic; polycyclic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
Abstract
The invention relates to a product and process for laundering delicate or dry-clean only garments in a conventional home washing machine. The process represents a home version of the commercial wet-cleaning processes for cleaning of delicate garments. The product comprises a liquid combination washing/conditioning composition and optionally a wash pretreatment composition, a flexible wrap container within which the garments are contained during washing and a pretreatment applicator.
Description
Benefit in the U.S. Provisional Patent Application 60/105,539 that the application applied on October 24th, 1.
Technical field
The present invention relates to a kind of in conventional domestic washing machine laundering delicate garments or product and method that can only dry-cleaning of garments.
Background of invention
By definition, term " dry-cleaning " is used to describe the method with non-aqueous solvent washing textiles.Dry-cleaning is a kind of ancient technology with solvent wash, is recorded in Britain the sixties in 19th century first.Typically, dry-cleaning method for example is used for being easy to generate the wool or the silk of shrinkage or being considered to be worth costliness or too exquisite and exquisite fabric that can not wash in washing.Usually this has above class clothes or discerns clothes and " can only dry-clean " or provide some other suitable labels that wash caution.Over nearest more than 50 years, the non-aqueous solvent of the widespread use of Commerical dryclean is a tetrachloroethylene always.
Although tetrachloroethylene is more superior than its institute's alternate non-aqueous solvent, it still has some shortcomings.Especially tetrachloroethylene is regarded as the air pollutant of harm always by the U.S. environment protection tissue, and is thought that for a long time the neural system with the workman is relevant with the kidney disorder.Nineteen fifty-five environment protection tissue divides tetrachloroethylene into " human possible carcinogenic substance ".The carcinogenic influence of tetrachloroethylene potential is not limited in the workman or those are the people that base-material is dry-cleaned with the tetrachloroethylene: to Commerical dryclean shop, New York studies show that recently, many drycleaner's make those wear the client who has just dry-cleaned clothes and suck the tetrachloroethylene of capacity and increased carcinogenic risk slightly with the tetrachloroethylene dry-cleaning of garments of a large amount.Because therefore a series of harmful characteristic of tetrachloroethylene administers with the dry-cleaning method of tetrachloroethylene is essential commercial field.This is not only inconvenient and cost an arm and a leg, and can expose the quality of exquisite clothes and clothes dry-cleaning process that might be very expensive and the unstable of clothes nursing.Many clients that article are delivered to the Commerical dryclean shop state not the essential factor excessive shrinkage, decolour and tear and damage product.The Commerical dryclean shop causes being discontented with of client because of the use tetrachloroethylene is tending towards staying " chemistry " smell on clothes.
And, although the dry-cleaning method based on solvent is very effective to removing oil stain and spot, but to removing the sugar that degranulation such as clay or water-soluble spot for example be present in fruit juice and the soda pop usually is not the best, and needs special processing just can remove protein contaminants.
Based on above-mentioned, continuous a kind of like this method of demand or process, it can provide has extremely good washing effect to multiple spot and dirt, does not use dangerous or detrimental substance is given exquisite clothes or can only be given the smell of a kind of " pure and fresh " and " cleaning " by dry-cleaning of garments.Therefore, the invention is characterized in the method that the nontoxic and non-hazardous chemical substance laundering delicate garments of a kind of usefulness and the clothes that can only dry-clean is provided and multiple dirt and spot is had good washing effect.This method or process are also quite convenient and cheap, can not the infringement clothes and " chemistry " smell due to the Commerical dryclean sometimes not.
Ideally, use detergent ingredients and particle and the protein contaminants and the oil stain spot of the more similar operational condition of method for washing comparison conventional dry washing method being removed on the fabric.This method for washing also can constantly inject the smell of fabric " pure and fresh " and " cleaning ", rather than often finds to come from " chemistry " smell with tetrachloroethylene or other non-aqueous solvent.
Perhaps, the method for washing of widespread use is, he or she is dipped into client clothes in the conventional domestic washing machine that is placed with the aqueous cleaning agent solution and carries out.This method shows for a long time has good washing effect to decontamination and whole clothes, and does not use dangerous or deleterious chemical substance in the operating process.And it is in fact all extremely convenient and cheap than any other clothes washing method to wash method in conventional washing machine with water.
Yet, being applied to exquisite clothes and the clothes that can only dry-clean on a large scale as the time by woolen clothes, this method can produce not received result.Wool fabric, by one with another root by a series of " scale " (Scales) interconnective fiber make.Usually, these connect scales and can not one move by another, and wool fabric has become blocky relatively textiles as a result.Yet when wool fabric becomes wet or moist, water just provides lubrication, if apply enough power in the ideal direction, scale utilizes this lubricated just can one moving by the ideal direction by another; This power can be provided by the agitating function of washing machine.When fiber moved by this ideal orientation, woolen clothes will shrink.This contraction can not be unfolded, because these " scales " can only move each other according to the ideal direction.Apply enough power in the direction opposite and can not launch these contractions with ideal orientation.Therefore, woolen clothes will produce contraction after washing, will spoil a dress inevitably.Artificial silk similarly, suction water after, become soft unusually, in typical method for washing through constantly stirring and wearing and tearing probably not only can badly damaged clothes but also can make clothes seriously wrinkling.Similarly, exquisite fabric such as silk not only can be seriously wrinkling, and can lose the soft feel(ing) of its expectation.
Silk garment is subjected to easily not only that conventional washing machine is churned mechanically to be influenced, and is subjected to the influence of typical detergent for washing clothes especially easily, because these washing composition contain the composition that stimulates exquisite fabric.Another benefit of the present invention provide a kind of adapt to the washing of conventional washing machine and to by as wool, artificial silk, silk, acrylics, triacetate fibre, carefully cotton and front mention that the clothes that the fabric of these raw mixs makes is harmless.
The present invention has designed a cover system for traditional washing methods, makes behind above-mentioned exquisite clothes and the fabric washing that can only dry-clean blast and pure and fresh and can not be harmful to.This system uses a flexible polymer outer container.Clothes is put into this container safely, and clothes can cushion and slow down power and the pressure that is produced by agitator.This system also uses liquid detergent composition, and exquisite clothes is modified and made it soft.First kind of liquid detergent composition is used for stain is carried out pre-treatment, thereby improves the washing effect to stain.This system also provide a spreader (pretreatment compositions is dispersed in the stain surface) and randomly a user clothes is put into the special stain of pre-treatment stain absorbs liner before the washing machine.In addition, the present invention also uses second kind of detergent composition by cleaning combination and amendment combination, with the advantage of improving color fidelity, giving crease-resistant advantage and reduce the fabric friction and other fabric nursing is provided.
When described method is used herein, this system offers a kind of convenience of user, cheap and effectively laundering delicate garments and method that can only dry-cleaning of garments at home.
The invention summary
The invention provides a kind of washing and renovate the clothes made from extra care clothes and can only dry-cleaning and the tool kit (kit) of the washing methods that does not spoil a dress and this method of enforcement.Especially conceive the method for in conventional domestic washing machine, washing.Therefore, the present invention has satisfied the long-term needs of the cheaply and easily washing methods of washing can only be dry-cleaned in conventional domestic washing machine clothes and other exquisite clothes.Use the effect of whole clothes of tetrachloroethylene washing superior on an equal basis in method of the present invention and the Commerical dryclean shop, but do not use dangerous chemical substance or deposition stench chemical substance on clothes.A kind of important component of the present invention is a kind of liquid combination washing/care composition, contains anion surfactant, quaternary ammonium surfactant, polysiloxane tenderizer and emulsifying agent randomly; The weight ratio of anion surfactant and quaternary ammonium surfactant is about 2: about 3: 1 of 1-.This tool kit also contain a flexible jacket container and in conventional domestic washing machine with the working instructions of this container washing clothes.
This flexible jacket Vessel Design becomes to contain and protects the clothes made from extra care clothes or only dry-cleaning to avoid the stirring action of washing machine.The essential part of this flexible jacket container is to knit the system polyester or knit the flexible rectangular panel that the system nylon layer constitutes.
The present invention also provides the method for a kind of usefulness tool kit washing of the present invention clothes.This method comprises fabric and textiles is placed in the above-mentioned flexible jacket container, then this flexible jacket container is put into washing machine with the liquid combination washing/care composition of significant quantity, then by manufacturer's description operation washing machine.
Except as otherwise noted, all per-cents, ratio and ratio herein all by weight.All documents of quoting in the relevant portion are incorporated herein by reference.
The accompanying drawing summary
Fig. 1 is the side-view of flexible jacket container 122.
Figure 1A is the side-view of flexible jacket container 122, and has shown two continuous baffle plates, and first baffle plate 111 is not stacked on the panel, and second baffle plate 112 is folded on the panel.
Fig. 2 is the side-view of the flexible jacket container 125 of expansion.In this embodiment, two overcoat things link to each other and form a flexible jacket container 125 that enlarges by being positioned at the coupling device 107 adjacent with panel 101 bottom margins of each flexible jacket container 122 each other.
Fig. 3 describes bag 110 and the securing gear when two flexible jacket containers link to each other the expansion flexible jacket container that forms Fig. 2 that links to each other with the panel 100 of the flexible jacket container that the tyre storage area is provided in detail.
Fig. 3 A is the bag 110 of describing the storage band side cross-sectional view with the securing gear in continuous bag when forming as shown in Figure 2 expansion flexible jacket container of linking to each other when two flexible jacket containers.
Fig. 4 is the enlarged section view of material bed profile in the preferred implementation that shows flexible jacket container 122.
Detailed Description Of The Invention
The invention provides one " kit ", it contains makes the necessary material that the user can the clothes that laundering delicate garments maybe can only be dry-cleaned in having the conventional washing machine of good scourability, and not typically obvious destruction or the negative effect relevant with the washing clothes. At least, this kit contains through liquid cleaning compositions, rinse cycle conditioner and the flexible jacket container of special preparation with processing and laundering delicate garments and the clothes that can only dry-clean.
This kit also comprises: a washing pretreatment compositions, and one or more washing preliminary treatment spreaders, one is used for disperseing the device of rinse cycle conditioner and multi-absorption spot to receive backing plate.
Flexible jacket container disclosed in this invention obviously is better than current used like device. Specifically, it provides a good self-protection and the device of sealing, the chance that clothes overflows and damages when being limited in thus washing in the washing machine. In addition, the thickness of flexible jacket container is isolated and protected wherein contained clothes not to be subjected to the agitator of washing machine and pressure and the wearing and tearing that other inner body produces. This flexible jacket container is also given extensibility and the multipurpose of can not see in other this kind equipment: this flexible jacket container is not only large than competition (product) element, and a series of jockeys are arranged (for example, snap set (snap)), it links together two identical flexible jacket containers to offer the user and has the former capacious additional flexibility outer container of twice and do not need extra charge. This has further improved the present invention and has kept full-sized advantage.
The present invention also provides the washing preliminary treatment spreader of planning with the finger filling, is used for the washing pretreatment compositions is applied to the stained area of clothes. This washing preliminary treatment spreader is a kind of useful especially instrument, can be the convenient stained area with effectively being applied to clothes of detergent height by it.
When the assembly that these are separated was taken out and use together, the result was the tool kit that a brand-new method and is implemented this method, can wash method washing and pure and fresh exquisite clothes thus with water and not spoil a dress with the clothes that can only dry-clean.Especially conceivable is to carry out method for washing in conventional domestic washing machine.
Definition
Herein " aqueous composition " is meant the composition that contains most of water.
" solution " herein is meant the liquid mixture of each component." solution " used herein does not comprise and only has a kind of liquid phase or solid phase.Neither refer to describe even solvent/solute system.
" significant quantity " herein is meant any amount that improves from the ground measured of the spot of clothes regional area removal.Generally, this quantitative change scope is very wide.
" washing " herein is meant dirt and the spot of removing on the fabric.
" contact " contacting that the one side of the fur that is meant by making the brush device that comprises equipment and stained area clashes into as for washing pre-treatment spreader with stained area.Receive backing plate " with the stained area contact " and be meant that the face in the textile stains district relative with washing the pre-treatment spreader directly impinges upon on the receptor and with it and closely link to each other as for absorbing spot.
Be described in more detail below the assembly and the using method thereof of present device.
Washing pretreatment compositions and combination washing/conditioning detergent composition
The too coarse and clothes that can not handle refining clothes and only can dry-clean of some laundry detergent compositions.Specifically, for example the detergent component of some tensio-active agent, enzyme and SYNTHETIC OPTICAL WHITNER may cause serious destruction (particularly clothes decolouring) to refining clothes and the clothes that only can dry-clean.Therefore, liquid washing agent of the present invention should most preferably almost not have SYNTHETIC OPTICAL WHITNER and contains the enzyme batching lower than the harsh feeling of the enzyme that is usually used in laundry detergent composition.In other words, the liquid cleaning compositions of this paper is through preparation, so that it is not because of causing decolouring, wearing and tearing or other negative impact to destroy fabric.
Therefore, although often being mixed with, traditional detergent for washing clothes provides good washing to cotton/polyester mixed goods, the composition of this paper must be through preparation, so that also can securely and effectively wash and the mixture of refreshing fabrics such as wool, silk, regenerated fiber, Aloysia gratissima alpaca, thin cotton and above-mentioned fabrics.In addition, the composition of this paper contain through special selection and preparation so that fugitive dye remove minimized component.
Therefore, the present invention had both comprised the washing pretreatment compositions, comprised combination washing/care composition again, and the latter provides washing-cleaning advantage and conditioning and softening advantage with single composition.By using spreader (this paper describes in detail) will wash the surface that pretreatment compositions is distributed in the clothes stained area, afterwards optionally with this clothes stained area of water rinse.
Then in washing machine, will wash in a usual manner then/care composition mixes with water and forms the suitable moisture detergent for washing clothes solution that the cleaning clothes is used that soaks.
Have now found that, when using spreader, washing/care composition and washing pretreatment compositions in mode as herein described, even these detergent composition are mixed with soft light good spot and the greasiness removal performance of also obtaining specifically.Except aforementioned consideration, washing pretreatment compositions used herein is preferably through preparation, so that it is easy to disperse and unlikely in essence sticking the difficult or difficult use of spreader that makes greasiness removal.Obviously, used " coagent " material can change according to the required end-use process of final composition.Below only plan these coagents of non-limitative illustration, the makers-up of this area is easy to expect more example.
First part: washing pretreatment compositions
Washing pretreatment compositions as optional components of the present invention can be selected from the following suitable component of discussing continuously now.
Detergent surfactant-known surface promoting agent has the coarse effect of potential to fabric.Typically, the composition of this paper contains the about 40wt% of the 3%-that has an appointment, the more preferably from about about 25wt% of 10%-, the detergent surfactant of the about 20wt% of 15%-most preferably from about.
The non-limitative example of tensio-active agent used herein comprises unsaturated vitriol, for example oleyl sulfate, C
10-C
18Alkyl alkoxy sulfate (" AE
xS "; EO 1-7 ethoxy sulfate particularly), C
10-C
18Alkyl alkoxy carboxylate salt (particularly EO 1-5 ethoxy carboxylate) and primary, side chain and random C
10-C
20Alkyl-sulphate (" AS "), formula CH
3(CH
2)
x(CHOSO
3 -M
+) CH
3And CH
3(CH
2)
y(CHOSO
3 -M
+) CH
2CH
3(wherein x and (y+1) be at least about 7, preferably at least about 9 integer, and M is water-soluble cationic, particularly sodium ion) C
10-C
18Secondary (2,3) alkyl-sulphate, C
10-C
18Glyceryl ether, C
10-C
18APG and corresponding sulfated polysaccharides glycosides and C
12-C
18α-sulfated fatty acid ester.If necessary, all containing conventional nonionic and amphoterics in the composition, for example comprise the C of so-called narrow peak alkylethoxylate
12-C
18Alkylethoxylate (" AE ") and C
6-C
12Alkylphenol alcoxylates (particularly ethoxylate and mixing oxyethyl group/propoxy-), C
12-C
18Trimethyl-glycine and sultaine (" sultaines "), C
10-C
18Amine oxide etc.Also can use C
10-C
18N-alkyl polyhydroxy fatty amide.Typical example comprises C
12-C
18The N-methyl glucose amide.Referring to WO9206154.Other comprises N-alkoxyl group polyhydroxy fatty acid amide, for example C by the tensio-active agent that sugar obtains
10-C
18N-(3-methoxy-propyl) glucamide.Can use the C of N-propyl group to the N-hexyl
12-C
18The minimizing foam of glucamide.Can also use C
10-C
20Conventional soap.High if desired foam can use side chain C
10-C
16Soap.The mixture of negatively charged ion and nonionogenic tenside is particularly useful, and also can use positively charged ion and amphoterics.Other conventional surfactant is listed in the standard textbook.
Washing assistant-composition of the present invention preferably contains one or more detergent builder compounds or builder system.When sometimes, these compositions typically contain the about 35wt% of the 0.01%-that has an appointment, the more preferably from about about 25wt% of 1%-, the about 8wt% detergent builder compound of 2%-most preferably from about.
Be applicable to that organic detergent builder compound of the present invention includes, but not limited to various polycarboxylic acid salt compounds." polycarboxylate " used herein is meant the compound with many carboxylate groups, preferably at least 3 carboxylate salts.The polycarboxylate washing assistant can sour form add in the composition usually, but can also the neutral salt form add.When using, preferably as the basic metal or the alkanol ammonium salts of sodium, potassium and lithium with salt form.
The Citrate trianion washing assistant, for example citric acid and soluble salt thereof (particularly sodium salt), because its utilizability and biological degradability thereof from renewable origin, so it is the polycarboxylate washing assistant to this detergent body particularly important.
Lipid acid also is important carboxylate salt washing assistant of the present invention.Lipid acid disclosed herein can contain about 10 ethylene oxide units of the 1-that has an appointment in hydrocarbon chain.The saturated fatty acid that preferably contains about 16 carbon atoms of the 12-that has an appointment.
Suitable saturated fatty acid can be by the natural source acquisition of for example plant or animal ester (for example through steam stripped palm-kernel oil, the steam stripped plam oil of process and Oleum Cocois) or through synthetic preparation (for example process petroleum oxidate or process Fisher-Tropsch process hydrogenation carbon monoxide).The example that is suitable for the saturated fatty acid of the present composition comprises capric acid, lauric acid, tetradecanoic acid, coconut and palm kernel fatty acid.Preferred saturated coconut fatty acid, about 5: 1-1: 1 (preferred about 3: the 1) lauric acid of weight ratio and mixture of tetradecanoic acid, have a small amount of (for example 10%-30% total fatty acids) oleic said mixture and pass through steam stripped palm kernel fatty acid.
In this polycarboxylate washing assistant, contain multiple useful matter.The important polycarboxylate washing assistant of one class contains the ether polycarboxylate, comprises the oxo disuccinate, as US3128287 that authorized Berg in April 7 in 1964 and the US3635830 that authorized people such as Lamberti on January 18th, 1972.Also authorize " TMS/TDS " washing assistant of people's such as Bush US4663071 referring on May 5th, 1987.Suitable ether polycarboxylate also comprises ring compound, alicyclic compound is particularly authorized people's such as Crutchfield US4120874 and authorized described in people's such as Crutchfield the US4102903 those on July 25th, 1978 US4158635, on October 17th, 1978 of for example authorized the US3923679 of Rapko on December 2nd, 1975, authorizing people such as Crutchfield on June 19th, 1979.
Other useful detergent builder compound comprises the multipolymer, 1 of ether hydroxy-polycarboxylate, maleic anhydride and ethene or vinyl methyl ether, 3,5-trihydroxybenzene-2,4,6-trisulfonic acid and carboxy methoxy-succinic acid, as Different Alkali metal, ammonium and the substituted ammonium salt of the poly-acetate of ethylenediamine tetraacetic acid (EDTA) and nitrilotriacetic acid(NTA) and polycarboxylate for example benzene hexacarboxylic acid, succsinic acid, oxo disuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxy methoxy-succinic acid and soluble salt thereof.
Other suitable polycarboxylate is disclosed in US4144226 that authorized people such as Crutchfield on March 13rd, 1979 and the US3308067 that authorized Diehl on March 7th, 1967.Also referring to the US3723322 of Diehl.
Enzyme-for fabric washing purpose widely comprises and removes protein-based, carbohydrate-based or triglyceride level base spot; In order to prevent that fugitive dye from shifting, and can comprise enzyme in the goods of this paper.Some enzyme is also by decomposing and the degraded textiles, and particularly lip-deep loose the and wearing and tearing fiber of the textiles of being made by silk or wool is given fabric and recovered benefit.
The enzyme that adds comprises proteolytic enzyme, amylase, lipase and mannase and composition thereof.Also can comprise other fermentoid.They can be from any suitable source, for example plant, animal, bacterium, fungi and yeast source.Yet its selection is subjected to controls such as Several Factors such as pH-activity and/or optimal stabilityization, thermostability, stability-activated detergent, washing assistant.Because proteolytic enzyme has known cleaning advantage to the large amount of organic spot, so proteolytic enzyme is acceptable enzyme.Because for example the enzyme of cellulase and peroxidase is to the potential coarse influence of refining clothes, so these enzymes are little ideal, and do not have them in the best group compound.
Usually enough provide up to about 5mg weight with every gram composition, the amount of the about 3mg organized enzyme of more typically about 0.01mg-adds these enzymes.In other words, it is about 5% that the composition of this paper typically contains the 0.001%-that has an appointment, preferred 0.01%-1.0wt% industrial enzyme preparation.Proteolytic enzyme in these industrial enzyme preparations exists with the amount that the peaceful unit of 0.005-0.1 (AU) activity/gram composition enough is provided usually.
Other example that is suitable for enzyme of the present invention can be at the pending trial provisional application P﹠amp that be entitled as " the hydrotropic detergent composition that contain raising " of people such as Boutique in application on August 23rd, 1999; G case 7692P2 finds in the sequence number 60/150233.
Enzyme stabilising system-composition of the present invention can contain the about 10wt% of the 0.001%-that has an appointment, the preferably about 8wt% of about 0.005%-, the enzyme stabilising system of the about 6wt% of 0.01%-most preferably.This enzyme stabilising system can be can be compatible with detersive enzyme any stabilising system.This kind of enzyme can provide by other preparation actives inherently, perhaps adds individually, and for example makers-up or the manufacturer by the washing composition alternation enzyme provides.These stabilising systems for example can contain calcium ion, boric acid, propylene glycol, short chain carboxy acid, boracic acids and composition thereof, and can be according to the type and the different stable problem of physical form design solution of detergent composition.
A kind of possible stable scheme is to use borate family.US4537706 referring to Severson.When using the borate stablizer, its amount can for up to composition 10% or more, although more typically up to the boric acid or for example borax or the suitable liquid washing agent use of orthoboric acid salt of other borate compound of about 3wt% amount.The boric acid that replaces for example phenyl-boron dihydroxide, butane boric acid, bromobenzene boric acid etc. be can be used for substituting boric acid, and can make by the boron derivative that uses these replacements that total boron content reduces in the detergent composition.
Stabilising system in some cleaning compositions can also contain the about 10wt% of 0%-, the preferred chlorine bleach scavenging agent of the about 6wt% of about 0.01%-, add them and attack enzyme and make enzyme deactivation, particularly under alkaline condition to prevent the chlorine bleach class in many waterworkss.Although cl content may be considerably less in the water, typically be the about 1.75ppm of about 0.5ppm-, obtainable chlorine in the overall ponding that contacts with enzyme, for example in the fabric washing process, can be quite big; Therefore, enzyme has problems sometimes to the stability of chlorine in the use.Suitable chlorine scavenger negatively charged ion is for well-known and be easy to obtain, if you are using, and can be for containing the salt of ammonium cation and inferior sulfate radical, weight inferior sulfate radical, hyposulfurous acid root, thiosulfate anion, iodide ion etc.The antioxidant, organic amine that can use for example carbamate, ascorbate salt etc. equally for example ethylenediamine tetraacetic acid (EDTA) (EDTA) or its an alkali metal salt, Monoethanolamine MEA BASF (MEA), and composition thereof.
Composition of the present invention can contain any water-soluble formate described in the US4318818 that authorizes people such as Letton March 9 nineteen eighty-two, and it is added herein by reference.The amount of formate is about 5%, preferred about 2%, the 0.4%-about 1.5% most preferably from about of about 0.2%-of about 0.05%-of composition weight.
The suitable detergent component of other that can add is enzyme stabilizers or the oxydasis scavenging agent described in the pending trial european patent application of applying on January 31st, 1,992 92870018.6.The example of these oxydasis scavenging agents has ethoxylation tetrem alkene polyamine class.
Be applicable to that enzyme of the present invention is stable and chlorine is removed other compound and technology can be at the pending trial provisional application P﹠amp that be entitled as " in washing machine the method for detergent clothing clothes " of people such as Curry in application on October 1st, 1999; G case 7315P2, sequence number _ in find.
Dirt particles removal/anti redeposition agent-composition of the present invention can also randomly contain the water-soluble ethoxylated amines with dirt particles removal and antiredeposition performance.Liquid detergent composition typically contains the 0.01%-that has an appointment about 5%.
Most preferred decontamination and anti redeposition agent are ethoxylation tetraethylene-pentamine (" TEPA ").On average in tetraethylene-pentamine in each hydrogen position with the ethoxylation of 15-18 mole ethylene oxide.The ethoxylated amines of illustration also is described in authorized among the US4597898 of VanderMeer on July 1st, 1986.Another organize preferred particulate decontamination-anti redeposition agent be on June 27th, 1984 disclosed Oh and the european patent application 111965 of Gosselink described in cation compound.Operable other dirt particles removal/anti redeposition agent comprises ethoxylated amine polymer in the european patent application 111984 that is disclosed in disclosed Gosselink on the 27th June in 1984, be disclosed in the amphoteric ion polymer in the european patent application 112592 of disclosed Gosselink on the 4th July in 1984 and be disclosed in oxidation amine among the US4548744 that authorized Connor on October 22nd, 1985.Other dirt particles as known in the art removes and/or anti redeposition agent also can be used in the composition of this paper.Another kind of preferred anti redeposition agent comprises carboxymethyl cellulose (CMC) material.These materials are known in this area.
Dye transfer inhibitor-integral part of the present invention is to protect look to providing according to refining clothes that contains water cleaning method washing as herein described and fabric.Therefore, composition of the present invention can also contain one or more and suppress dyestuff is transferred to another fabric from a kind of fabric material effectively in washing process.Usually, these dye transfer inhibitors comprise multipolymer, manganese phthalocyanine pigment, peroxidase of polyvinylpyrrolidonepolymers polymers, polyamine N-oxide pllymers, N-vinyl pyrrolidone and N-vinyl imidazole and composition thereof.If you are using, it is about 10% that these reagent typically contain about 0.01%-of composition weight, and preferably about 0.01%-is about 5%, and more preferably from about 0.05%-about 2%.
More particularly, the polyamine N-oxide pllymers that is preferred for this paper contains following structural formula unit: R-A
x-P; Wherein P is a polymerizable unit, can connect on it that N-O group or N-O group can form the part polymerizable unit or the N-O group can be connected on two unit; A be one of following structure :-NC (O)-,-C (O) O-,-S-,-O-,-N=; X is 0 or 1; R is aliphatic series, aliphatic, the aromatics of ethoxylation, heterocycle or alicyclic group or its combination, and can connect N-O group or N-O group on it is the part of these groups.Preferred polyamine N-oxide is that R is those of heterocyclic group of for example pyridine, pyrroles, imidazoles, pyrrolidone, piperidines and derivative thereof.
The N-O group can be represented by following formula:
R wherein
1, R
2, R
3Be aliphatic series, aromatics, heterocycle or alicyclic group or its combination; X, y and z are 0 or 1; N in the N-O group can link to each other or form the part of any aforementioned group with any aforementioned group.Amine oxide unit in the polyamine N-oxide has pKa＜10, preferred pKa＜7, more preferably pKa＜6.
The example of dye transfer inhibitor has poly-(4-vinylpridine-N-oxide compound), it can be referred to as " PVNO ".Suitable N-vinyl pyrrolidone and N-vinyl imidazole polymer class (being referred to as " PVPVI " class) and Polyvinylpyrolidone (PVP) (" PVP ") in addition.These are disclosed in the US5759208 that authorized people such as Zhen on June 2nd, 1998 in detail, and it is added herein by reference.
Other colour protecting agent-except that dye transfer inhibitor, the present invention also contains and gives other reagent that protects the look benefit: 30 polyethylene imine based, PEI 600 E20 have following general formula:
Wherein B is continuing of polyethylene imine based main chain branching.E is the ethoxy unit of following formula:
-(CH
2CH
2O) mH wherein m have about 20 mean value." mean value 20 " meaning in this article is enough ethylene oxide or other suitable reagent and polyethylene imine based raw material reactions, thereby with the complete ethoxylation to 20 in each a N-H unit degree of ethoxylation.Yet, it will be understood by those skilled in the art that to, the hydrogen atom in some N-H unit will be lower than 20 ethoxy unit and replace that some are replaced greater than 20 ethoxy units, therefore, ethoxylation mean number is 20.
The unit that constitutes polyethylene imine based main chain is for making main chain and any side chain terminated following formula primary amine unit:
H
2N-CH
2CH
2]-and-NH
2The secondary amine unit of following formula (after the modification, having the hydrogen atom that is replaced by average 20 ethoxy units):
Tertiary amine unit with following formula:
It has the branch point of main chain and secondary main chain, and B represents continuing of branched structure.These uncle unit do not have interchangeable hydrogen atom, therefore can not use the ethoxy unit substituting modification.In forming polyamine main chain process, cyclisation may take place, therefore, a certain amount of ring polyamine may be present in the parent polyalkyleneimine main chain mixture.Each primary and secondary amine unit in the ring alkylene imine carries out modification in the mode identical with the side chain polyalkyleneimine with straight chain by adding the alkylene oxide group unit.
The value of index w, x and y makes that the molecular-weight average of modification polyethylene imine based main chain before is about 600 dalton.In addition, one of ordinary skill in the art would recognize that each side chain must be unit terminated with primary amine, so the value of index w is y+1, do not have the cyclammonium main chain in this case.Each ethylidene backbone units-NCH
2CH
2-molecular-weight average be about 43 dalton.
Polyamine of the present invention can by for example under just like the situation of the catalyzer of carbonic acid gas, sodium bisulfite, sulfuric acid, hydrogen peroxide, spirit of salt, acetate etc. the polymerization ethylenimine make.Authorize people's such as Crowther US2806839 US2208095, September 17 nineteen fifty-seven of authorizing people such as Esselmann in US3033746, on July 16th, 1940 that the concrete grammar for preparing these polyamine main chains is disclosed in the US2182306 that authorizes people such as Ulrich December 5 nineteen thirty-nine, authorized people such as Mayle on May 8th, 1962 and authorize the US2553696 of Wilson May 21 nineteen fifty-one; They are added herein by reference.
The compound that suds suppressor-can reduce being used for or suppress foam forms adds composition of the present invention.In the what is called described in US4489455 and 4489574 " high density washing methods " and in the muzzle-loading Europe class washing machine, pressing down the bubble effect may particularly important.
Many materials can be used as suds suppressor, and suds suppressor is known for a person skilled in the art.Referring to for example " Kirk Othmer Encyclopedia of ChemicalTechnology " the 3rd edition the 7th volume 430-447 page or leaf (John Wiley﹠amp; Sons, Inc., 1979).The interested especially suds suppressor of one class comprises monocarboxylic acid lipid acid and soluble salt thereof.Authorize the US2954347 of Wayne St.John referring to September 27 nineteen sixty.This monocarboxylic acid lipid acid and salt thereof as suds suppressor typically have about 24 carbon atoms of 10-, the hydrocarbon chain of preferred 12-18 carbon atom.Suitable salt comprises for example an alkali metal salt and the ammonium salt and the alkanol ammonium salts of sodium, potassium and lithium salts.
The detergent composition of this paper can also contain the nonsurfactant suds suppressor.These for example comprise: as the high-molecular-weight hydrocarbons of paraffin, fatty acid ester (for example fatty acid glyceryl ester), the fatty acid ester of monovalent alcohol, aliphatic C
18-C
40Ketone (for example stearone) etc.Other suds suppressor comprises N-alkylation aminotriazine class, for example three to six alkyl melamines or two to tetraalkyl diammonium chloride triazine and a stearyl phosphoric acid ester as a stearyl alcohol phosphoric acid ester and a stearyl two basic metal (for example K, Na and Li) phosphoric acid salt and phosphoric acid ester.For example the hydro carbons of paraffin and halo paraffin can liquidly use.Liquefied hydrocarbon should be liquid under room temperature and normal atmosphere, and should have approximately-15 ℃ to about 50 ℃ pour point, and minimum boiling point is not less than about 110 ℃ (normal atmosphere).Also known utilization preferably has fusing point and is lower than about 100 ℃ content of wax hydro carbons.These hydro carbons constitute the suds suppressor of the detergent composition of a preferred type.The hydrocarbon suds suppressor for example is described in the US4265779 that authorized people such as Gandolfo on May 5th, 1981.Therefore these hydrocarbon comprise the aliphatic series with about 70 carbon atoms of about 12-, alicyclic, the saturated or unsaturated hydrocarbons of aromatics and heterocycle family.Used term " paraffin " is meant the mixture that comprises true paraffin and cyclic hydrocarbon in this suds suppressor is discussed.
Another preferred class nonsurfactant suds suppressor comprises the polysiloxane suds suppressor.This type comprises uses poly organic silicon oil, for example the composition of the dispersion liquid of polydimethylsiloxane, organopolysiloxane or resin or emulsion and organopolysiloxane and silica dioxide granule (wherein this organopolysiloxane chemisorption or fusion are on this silicon-dioxide).The polysiloxane suds suppressor is known in the art, for example is disclosed in the US4265779 that authorized people such as Gandolfo on May 5th, 1981 and February 7 nineteen ninety by the disclosed european patent application 89307851.9 of M.S.Starch.
Other suds suppressor can be selected from below the application, discuss about those polysiloxane in the polysiloxane tenderizer section and above the US5579208 that authorizes people such as Zhen on June in 1998 2 that introduces.
Other optional components in the composition of other component-this paper includes, but is not limited to hydrotropic agent, antiseptic-germicide, other enzyme stabilizers and spices.It is desirable to antishrinking agent, anti wrinkling agent, fabric refreshers (crisping agent) and other fabric colour protecting agent especially.The pH of composition disclosed herein is 5-9.
Second section: the washing/care composition of combination
The invention still further relates to washing/care composition, it not only provides washing and cleaning effect to the clothes that only can dry-clean, and provides omnidistance washing softening and conditioning.For the user, owing to when the beginning cycles of washing, add amendment, and then in rinse cycle, need not add amendment, so this has improved the accessibility of whole process greatly.Except its cleaning effect, the washing/conditioning solution of combination provides many important benefits: the wearability of the color fidelity of Ti Gaoing, raising and prevent excessive gauffer for example.Fabric softener also helps and keeps for example pliability of silk one kind fabric clothes, and they may have coarse sensation after the washing in the washing washing composition.Therefore this combination washing/care composition is particularly importantly played the additive of antishrinking agent, anti wrinkling agent, fabric refreshers and other fabric colour protecting agent effect.
Wash pretreatment compositions Duan Zhongyi in the above and described the component of many washing/care compositions, no longer repeat here.Except these components, below optional and necessary component selects to be used for this washing/care composition by this area makers-up.Be applicable to that other component of the present invention also is disclosed in the US5460736 that authorizes people such as Trinh October 24 nineteen ninety-five, authorized people's such as Baker the US5562849 that authorizes people such as Wahl in US5545350, on October 8th, 1996 on August 13rd, 1996; They all are added herein by reference.
It is about 10% that the essential component of quaternary ammonium surfactant-conduct, the combination washing/care composition of this paper contain the 1%-that has an appointment, and preferably about 2%-is about 7%, more preferably from about the following formula quaternary ammonium surfactant of about 5% weight of 3%-:
R wherein
1And R
2Be selected from respectively: C
1-C
4Alkyl, C
1-C
4Hydroxyalkyl, benzyl and-(C
2H
4O)
xH, wherein x is about 2-about 5; X is a negatively charged ion; And (1) R
3And R
4C respectively does for oneself
6-C
14Alkyl or (2) R
3Be C
6-C
18Alkyl, and R
4Be selected from: C
1-C
10Alkyl, C
1-C
10Hydroxyalkyl, benzyl and-(C
2H
4O)
xH, wherein x is 2-5.
Preferred quaternary ammonium surfactant is muriate, bromide and Methylsulfate.The example of a preferred chain alkyl quaternary ammonium surfactant be following those: R
1, R
2And R
4Methyl and R respectively do for oneself
3Be C
8-C
16Alkyl; Perhaps R
3Be C
8-C
18Alkyl, R
1, R
2And R
4Be selected from methyl and hydroxyalkyl.Preferred especially Trimethyllaurylammonium chloride, chlorination myristyl trimethyl ammonium, chlorination palmityl trimethyl ammonium, chlorination coconut trimethyl ammonium, methylsulfuric acid coconut trimethyl ammonium, chlorination coconut dimethyl-monohydroxy-ethyl ammonium, methylsulfuric acid coconut dimethyl-a hydroxyethyl ammonium, chlorination stearyl-dimethyl-monohydroxy-ethyl ammonium, methylsulfuric acid stearyl-dimethyl-a hydroxyethyl ammonium, chlorination two-C
12-C
14The alkyl dimethyl ammonium, and composition thereof.
Ratio-the anion surfactant of anion surfactant and quaternary ammonium surfactant and quaternary ammonium surfactant all are necessary components of the present invention.When they exist together with certain weight ratio, they form the mixed micelle system in composition, so that when this washing/care composition sticks to enough suspension polysiloxane tenderizer solution and other polymkeric substance, said composition is unlikely to thickness and can not pours out from the Detergent bottle of adorning them easily and easily to them.
In order to reach the optimum balance of phase stability/suspension benefit and product viscosity, the weight ratio of preferred anionic tensio-active agent and quaternary ammonium surfactant is about 2: about 3: 1 of 1-, preferred about 2.2: about 2.8: 1 of 1-.Although US5759208 also discloses the combination of anion surfactant and quaternary ammonium surfactant, the ratio (above 5: 1) of anion surfactant and quaternary ammonium surfactant is apparently higher than the used ratio of the present invention.
Enzyme-as mentioned above, enzyme has improved cleaning and the removal to the various spots that comprise protein-based, carbohydrate-based or triglyceride level base spot.In this combination washing/care composition, also by decomposing and the degraded textiles, particularly the lip-deep loose of being made by silk or wool of textiles given the fabric recovery effects with wearing and tearing fiber to some enzyme.Because mannase and amylase have the benefit of removing spot, therefore preferably they are used for this washing/cleaning compositions.As above mentioned, little wish to have for example enzyme of cellulase and peroxidase.
Particularly preferred amylase is NATALASE , and it can be specifically as α-Dian Fenmei, by Phadebas alpha-amylase activity mensuration, has the specific activity than the specific activity height at least 25% of Termamyl under the pH value of 25-55 ℃ and 8-10.
Polysiloxane tenderizer and emulsion-the present invention thereof can also contain various silicone oil (preferably with emulsion form preparation), have found that it gives tangible smooth sensation to most of fabric type, and have reduced gauffer formation amount significantly.This polysiloxane tenderizer can the emulsion form exist, and also can not exist with the emulsion form.
The polysiloxane tenderizer comprises poly-alkyl shown in the following formula or poly-aryl siloxanes:
Wherein R is an aliphatic series, preferred alkyl or alkenyl or aryl, and R can through replacement or without replacement, x be the integer of 1-about 8000.Suitable unsubstituted R group comprises alkoxyl group, aryloxy, aralkyl, aralkenyl, alkylamino and ether replacement, hydroxyl replacement and halogenated aliphatic and aromatic group.Suitable R group also comprises cationic amine and quaternary ammonium group.
Replacement aliphatic series or aromatic group at the polysiloxane chain substitution can be arbitrary structures, as long as it is liquid that the gained polysiloxane at room temperature keeps, hydrophobic, both do not damaged in the time of on being applied to textiles and do not had other destruction yet, can with other component compatibility in the detergent composition, chemically stable under commonly used and holding conditions, and can be deposited on the textiles of the method for summing up according to the present invention and to it and nurse one's health.
Two R groups on the Siliciumatom of each monomer siloxane unit can be represented identical or different group.Preferably, these two R groups are represented identical group.
Preferred alkyl and alkenyl substitutents are C
1-C
5Alkyl and alkenyl, more preferably C
1-C
4, C most preferably
1-C
2Other aliphatic series part that contains the group (for example alkoxyl group, aralkyl and alkylamino) of alkyl, alkenyl or alkynyl group can be for straight or branched and is preferably had a 1-5 carbon atom, more preferably have 1-4 carbon atom, even more preferably 1-3 carbon atom, most preferably 1-2 carbon atom.
R group preferably comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxane is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Preferred especially polydimethylsiloxane.Other suitable R group comprises methyl, methoxyl group, oxyethyl group, polyethoxye, propoxy-and aryloxy.Three R groups on the polysiloxane end-blocking can also be identical or different group.
Other preferred polysiloxane comprises the polydimethylsiloxane of nonionic polyalkylene oxide modification, and it is effective especially aspect the minimizing gauffer.These polysiloxane fluids can obtain with title SIL WET from the meticulous product of OSI company.Preferred especially SIL WET L77, it is the seven methyl trisiloxanes of 84% polyalkylene oxide modification and the mixture of 16% allyloxy methoxypolyethylene glycol.
Other that is applicable to silicone oil of the present invention discussed and example can be authorized on February 23rd, 1999 among people's such as Kaiser the US5874073 and finds, it is added herein by reference.Can be ideally add emulsifying agent with the concentration of this polysiloxane amendment of effective emulsification.(" emulsifying agent " used herein comprises suspension agent.) emulsifying agent and suspension agent have more detailed discussion in US5874073 and US5759208, they all add in the above.Disclosed emulsifying surfactant among the preferred especially US5759208 will form emulsion in its adding polysiloxane fluid.
Cyclic amine based polymer, oligopolymer or multipolymer-preferred combination washing/care composition of the present invention contains one or more cyclic amine based polymers, oligopolymer or multipolymer.Found that these materials give many outward appearance advantages to the fabric and the textiles that wash in the water lotion, this water lotion is that the detergent composition by the mixture of cellulose-based polymer that contains cyclic amine based polymer, oligopolymer or multipolymer and hydrophobically modified or oligopolymer fabric treating material forms.These appearance of fabrics advantages can comprise that improvement overall appearance, minimizing balling-up and the fine, soft fur of the fabric of for example doing washing form, prevent to fade, improve wear resistance etc.The cyclammonium based fabric treated substance that is used for this paper composition and method can provide these appearance of fabrics advantages, simultaneously because of adding the clean-up performance almost not reduction or not reduction satisfactorily that these materials provide laundry detergent composition.
Cyclic amine based polymer in the composition of this paper, oligopolymer or copolymer component can contain the combination of these cyclammonium base-materials.For example, the mixture of piperidines and epihalohydrin condenses can be combined the treatment effect of the fabric that reaches required with the mixture of morpholine and epihalohydrin condenses.And described in following embodiment, the molecular weight of cyclammonium based fabric handled thing can change in mixture.
As understood by one of ordinary skill in the art, oligopolymer is the molecule of only being made up of several monomeric units, although polymkeric substance comprises more monomeric unit.For the purpose of the present invention, oligopolymer is defined as molecular-weight average and is lower than about 1000 molecule, and polymkeric substance is a molecular-weight average greater than about 1000 molecule.Multipolymer is two or more different monomers through simultaneously or successively polymeric polymkeric substance or oligopolymer.Multipolymer of the present invention can comprise for example by the uncle's cyclammonium base monomer of for example piperidines and the secondary cyclammonium monomer mixture polymeric polymkeric substance or the oligopolymer of for example morpholine.
The cellulose-based polymer of the cyclic amine based polymer in this paper detergent composition, oligopolymer or multipolymer and hydrophobically modified or the mixture of oligopolymer account for about 0.01%-about 5% of detergent composition weight usually.More preferably, it is about 4% that the cellulose-based polymer of cyclic amine based polymer, oligopolymer or multipolymer and hydrophobically modified or the mixture of oligopolymer account for about 0.1%-of detergent composition weight, and most preferably from about 0.75%-about 3%.Yet, as discussed above, when as the washings additive, promptly when the mixture of the cellulose-based polymer of cyclic amine based polymer, oligopolymer or multipolymer and hydrophobically modified or oligopolymer was not added to detergent composition, the cellulose-based polymer of cyclic amine based polymer, oligopolymer or multipolymer and hydrophobically modified or the mixture concentration of oligopolymer can account for about 0.1%-about 80% of additive weight of material.
Be applicable to laundry operations and provide preferred cyclic amine based polymer, oligopolymer or the multipolymer of required appearance of fabrics and complete effect to be described in more detail in people such as Panandiker in the common pending trial temporary patent application sequence number 60/148053, the P﹠amp that are entitled as " laundry detergent composition " of application on August 10th, 1999 with combination of cyclic amine based polymer and hydrophobically modified carboxy methyl cellulose; G case 7292P2 is added herein by reference it.
Polymerization stain remover (Polymeric Soil Release Agent)-can use stain remover in the present invention.If so, it is about 10.0% that they account for about 0.01%-of this paper detergent composition weight usually, and typically about 0.1%-is about 5%, preferably about 0.2%-about 3.0%.
Any polymerization stain remover well known by persons skilled in the art can be chosen wantonly and be used for the compositions and methods of the invention.The polymerization stain remover is characterised in that both have the hydrophilic segment that makes the hydrophobic fiber surface hydrophilic, polyester and composition thereof for example has again and is deposited on the hydrophobic fiber and adheres on it in the whole process of washing and rinse cycle and therefore be used as the hydrophobic fragment of the fixture of hydrophilic segment.This makes the spot of existence can use detergent-treatment, thus easy cleaning more in the washing step in the back.
The useful especially polymerization stain remover of this paper is comprised having following stain remover: (a) one or more are mainly by the following nonionic hydrophilic component of forming: (i) have the polymerization degree and be at least 2 polyoxyethylene fragment, perhaps (ii) propylene oxide or have the polyoxypropylene fragment that the polymerization degree is 2-10, wherein said hydrophilic segment does not comprise any propylene oxide unit, unless it is connected with adjacent part at each end by ehter bond, the mixture that perhaps (iii) contains the oxyalkylene units of about 30 propylene oxide units of ethylene oxide and 1-, wherein said mixture contains the ethylene oxide unit of capacity, so that hydrophilic component has enough big wetting ability, to increase these surperficial wetting abilities on the normal polyester synthon surface by this stain remover is deposited on, described hydrophilic segment preferably contains at least about 25% ethylene oxide unit, particularly, more preferably have at least about 50% ethylene oxide unit for having these components of about 20-30 propylene oxide unit; Perhaps (b) contains one or more following hydrophobic components: (i) C
3Oxyalkylene terephthalate fragment, wherein, if described hydrophobic components also contains terephthalic acid oxidation second diester, terephthalic acid oxidation second diester and C so
3The ratio of oxyalkylene terephthalate is about 2: 1 or lower, (ii) C
4-C
6Alkylidene group or oxidation C
4-C
6Alkylidene group fragment, or its mixture, (iii) poly-(vinyl acetate) fragment, ethylene polyvinyl acetate has the polymerization degree and is at least 2, perhaps (iv) C
1-C
4Alkyl oxide or C
4Hydroxyalkyl ether substituent or its mixture, wherein said substituent is with C
1-C
4Alkyl oxide or C
4The form of hydroxyalkyl ether derivatived cellulose or its mixture exists, and these derivatived celluloses are amphiphilic, and they have capacity C thus
1-C
4Alkyl oxide and/or C
4The hydroxyalkyl ether unit in case stick on these conventional synthon surfaces, has just increased the fiber surface wetting ability, perhaps (a) and combination (b) to be deposited on the normal polyester synthon surface and to keep the capacity hydroxyl.
Other suitable polymerization stain remover is disclosed in the US5415807 that authorizes Gosselink May 16 nineteen ninety-five, and it is added herein by reference.
Although the combination of fabric care composition-they can use separately effectively, but preferred multipolymer, manganese phthalocyanine pigment and peroxidase with cyclic amine based polymer/oligopolymer/multipolymer and dye transfer inhibitor such as polyvinyl pyrrolidone polymers, polyamine N-oxide pllymers, N-V-Pyrol RC and N-ethene imidazoles (described in the top washing pretreatment compositions section) be used in combination, make between the clothes, the dye transfer in the particularly assorted look load (promptly being mixed with the fabric of light colour and black) obtains optimal inhibition.
The flexible jacket container
The effect of agitator makes upgrading textile be subjected to enough wearing and tearing and stress and causes that may to produce havoc existing for a long time in the known washing machine.As a result, developed and can be used in the washing machine and prevent that these clothes from being worn and torn and the bag of stress.Yet because a variety of causes, these have confirmed unsatisfactory.At first, they are too little usually and can not pack anything into, can only adorn one, two little clothes, even they may make these clothes flock together and aggravate gauffer and distortion.Secondly, many these bags do not have reliable enclosed appts, and therefore bag is often opened in washing process, and the clothes that loses the bag protection can the imagination can provide friction and wear also might make it to increase to clothes.The 3rd, these bags often are built into to have to be made by grid network and allow washings to contact the shell that cleaning effect is provided with clothes; But stay phase apposition impression on the clothes that these trellis patterns can also be adorned therein.In fact this pattern can not plate.The 4th, these bags are too thin usually and can not provide enough bufferings to friction and the stress that refining clothes may stand in washing machine.
Be shown in Fig. 1,1A and 2 according to the present invention preparation and the preferred flexible outer container (" overcoat ") that remedied these problems.Overcoat 122 contains single, is preferably rectangle, panel 100.Panel 100 is of a size of the about 91cm of wide about 31em-, and long is the about 117cm of about 55cm-, and the about 81cm of more preferably wide about 41cm-is about the about 107cm of 66em-, and the about 71cm of most preferably wide about 51em-is about the about 97cm of 76cm-.In the described rectangle embodiment of Fig. 1, panel 102 upper limbs to the distance of panel 101 lower rims greater than the distance of panel 103 right hand edges to panel 104 left hand edges.
This overcoat also comprises one or morely is with 108, and they link to each other with the upper limb of panel 102.Have one can fix and for good and all link to each other with 108 at the end of each band so that first securing gear 109 of its invariant position on tape with each, second securing gear 106 preferably makes band be connected to each by this securing gear and is with, change its position on tape by this way, the length with 105 can increase or reduce.First and second securing gear cooperate to guarantee that the flexible jacket container is curly form (referring to for example Fig. 7) in use.In addition, two pockets 110 are adjacent to link to each other with the panel upper limb with mode shown in 3 with Fig. 1,1A, 2.This outer container, with it preferred embodiment, the pending trial provisional application (P﹠amp of being entitled as of the people such as Curry of Yin Ruing " method of detergent clothing clothes in washing machine " in the above; G case 7315P2) has more in and go through.
Washing pre-treatment spreader
Being used for washing pre-treatment spreader of the present invention may mainly be not have friction tool arbitrarily, and people use it the washing pretreatment compositions of significant quantity can be applied to the stained area of clothes, and the mechanical effect that assists in removing spot is provided simultaneously effectively.Therefore can use simply object as finger as washing pre-treatment spreader.Be disclosed in the people's such as Curry that introduce above the pending trial provisional application (P﹠amp that is entitled as " method of detergent clothing clothes in washing machine " as the preferred implementation of spreader; G case 7315P2) in.
Receive stain receiver
The absorption stain receiver that the present invention uses comprises the absorbing material that absorbs liquid composition.In preferred operating method, the stain receiver specialized designs becomes liquid composition from stained region " suction is opened " or " siphoning away ".Absorb stain receiver and must be white or do not print to avoid dyestuff to transfer on the clothes from receptor.Can use the disposable tissues of not printing, as BOUNTY
TMThe board paper handkerchief, clean cloth waste etc.Preferred receptor is made of the non-woven fabrics pad.Can be used as the additional materials that absorbs stain receiver and be disclosed in people's co pending provisional application such as Curry, its name is called " method of detergent clothing clothes in washing machine ", P﹠amp; The G case number is 7315P2, and above content is incorporated by reference.
The method embodiment
The application of following more detailed description present device, composition and method.These are disclosed as the illustrative the present invention of being not limited to.
Although to the present invention is not essential or essential, preferably use a pre-treatment step to improve the efficient of removing spot from the stained area of clothes.This pre-treatment step comprises pretreatment compositions is poured on stained area, uses washing pre-treatment spreader by applying slight brushing campaign pretreatment compositions to be applied to the stained area of clothes then, thereby pretreatment compositions is dispersed in around the stained area.Randomly water rinses out pretreatment compositions then.
In more detail, the pretreatment process that can following mode carries out this paper.Can under the situation that does not deviate from spirit and scope of the invention, change this method.
1, absorbs on the absorption stain receiver of backing plate or paper handkerchief (be preferably white or do not print the nonwoven backing plate) or other stain receiver arbitrarily as herein described and be in contact with it on for example desk-top etc. any suitable surface stained area of clothes being placed on FAM for example in order to avoid dyestuff is transferred on the clothes from paper handkerchief.To wash pretreatment compositions and be poured on stained area.
2, use washing pre-treatment spreader pretreatment compositions to be coated stained area, make local stained area saturated, and its peripheral region is unsaturated, attempt then as far as possible fully spot to be removed with slight brushing campaign.
3, randomly, make composition infiltration spot about 1-3 minute.
4, randomly, more pretreatment compositions is applied to stained area.
5, randomly, the stained area rinsing that will handle with cool tap water.
6, after this preprocessing process, carry out following all clear and wash process.
Comprise above-mentioned preprocessing process and be used to handle the whole process of the whole fabric surface area of clothes, therefore may further comprise the steps:
(i) randomly, carry out preprocessing process according to above-described step 1-6 at the stained area of clothes.
(ii) the pretreated clothes of process of step (i) is put into washing tool in mode as herein described and with the washing tool sealing, so that it is not opened during laundry in washing machine.
(iii) washing tool is put into washing machine with the combination washing/care composition of measured quantity.
(iv) with its most slight agitation cycle running washing machine and in washing and rinse cycle, all use cold water lasting at least about 6 minutes, typically about 4 minutes-Yue 12 minutes.
(v) from washing machine, take out the flexible jacket container that clean clothes is housed, from the flexible jacket container, take out clothes, and or make it through dry air or at first they are put into the shake up minimum possible clothesdrier (heating) of the clothes that the clothes-drying machine or be provided for of (not heating) made by regenerated fiber or regenerated fiber mixture of the air that is provided for silk garment.Heavier clothes should keep in moisture eliminator 8-10 minute, and light clothes should keep 4-6 minute.Should and make it with these clothes taking-ups then through dry air.The wool clothes should not put into clothes-drying machine.
With regard to step (ii) with regard to, can expect that the fabric of commute gauffer does not preferably make washing tool used herein overload.
Step (iii) in, washing machine can have be installed in or substantial horizontal or perpendicular axle on agitator.Typically, the add-on of liquid scrubbing/care composition should make the concentration of the active ingredient in the washings be about 300ppm-2500ppm, the more preferably from about about 2000ppm of 400ppm-, the most preferably from about about 1600ppm of 500ppm-.Step (iv) can be carried out longly or short according to user's needs, and this depends on for example following factor: textile stains degree and type, spot character, textile properties, fabric load capacity etc.
Example I
Embodiment (1) is for being used for the preferred washing pretreatment compositions of preprocessing process; Washing/the care composition that adds during (2) for cycles of washing.Using these compositions in this way after the preparation in detail.
The washing pretreatment compositions
Component Wt%
Nonionogenic tenside 0.50
N-cocoa base N-methylglucosamine 1.60
Anion surfactant 16.00
Amine cosurfactant 0.40
Citric acid 2.50
Lipid acid (12-16) 2.00
Ethanol 2.59
Monoethanolamine MEA BASF 0.75
Sodium formiate 0.062
Propylene glycol 5.08
Tosylate 0.36
Borax pre-composition 2.50
Sodium hydroxide 2.62
Fabric care agent 2.70
Enzyme 0.15
Surplus (water, defoamer, spices, 61.67
Colour stabilizer)
Washing/care composition
| Component | ????Wt％ |
| Anion surfactant 1 | ????14.40 |
| Nonionogenic tenside 2 | ????4.00 |
| Trimethyllaurylammonium chloride | ????5.33 |
| Citric acid | ????0.70 |
| Ethanol | ????2.10 |
| Monoethanolamine MEA BASF | ????0.75 |
| Sodium formiate | ????0.06 |
| Propylene glycol | ????3.67 |
| Tosylate | ????0.36 |
| The borax pre-composition | ????2.50 |
| Sodium hydroxide | ????0.1 |
| The ethoxylation tetraethylene-pentamine | ????0.90 |
| ?PVNO | ????0.37 |
| Cyclic polymer 3 | ????0.55 |
| Enzyme | ????0.50 |
| The polysiloxane tenderizer 4 | ????5.00 |
| Spices, dyestuff and other submember | ????0.50 |
| Water | Surplus |
1:C12-15 alkyl ethoxy sulfonate contains average 1.8 oxyethyl groups.
2：Neodol?45-7
3: imidazoles-Biao (imidazoles and the condensation oligopolymer of table chloro-hydrin(e)) with ratio condensation in 1: 4: 1 generation.Composition have an appointment 94% oligopolymer and 6% free imidazoles.
4: the polysiloxane tenderizer can be the dimethicone that contains average 3 oxyethyl groups and the mixture of alkylsulphonic acid ammonium, perhaps can be the SILWET L77 tensio-active agent of the mixture of the seven methyl trisiloxanes (" activity " composition) of 84% polyoxyalkylene modification and 16% allyloxy methoxypolyethylene glycol.These polysiloxane tenderizers can be the emulsion form.
Step 1, select to wait the one or more clothes that wash and renovate.Differentiate on the clothes from the spot in for example ink, lipstick, salad sauce, collar dirt and other similar source then and select pre-treatment.In order to carry out pre-treatment, the local stained area of clothes is placed on the paper handkerchief and handles by the direct washing prefinished products of coating about 0.5-5ml (depending on the spot size) example I, it is with washing the pre-treatment spreader clothes slightly to be operated.Rinse out excessive liquid product with the cool tap water of mobile then.
Step 2, the flexible jacket container is lain on the flat surfaces of platform for example or clothes-drying machine.First clothes such as jacket are placed on outer putting.Other elongated portion of sleeve and clothes should be folded up if necessary, clothes is not exposed at outside the overcoat periphery.First clothes is placed on after outer the putting, the overcoat baffle plate is folded up the covering clothes, whole clothes is surrounded by overcoat.With above-mentioned identical step other clothes is placed on the folding baffle plate then, clothes is exposed at outside the flexible jacket container perimeter.
Step 3, then overcoat is rolled, seem that people roll a sleeping bag.Along the direction parallel, from almost beginning to roll overcoat with the approaching edge of coupling device with the overcoat longest edge.After bag is rolled, by band and fastening piece it is sealed, making is the band tension of bag.
Step 4, the overcoat that then clothes will be housed are put into washing machine.Preferably with two much at one the overcoat that clothes is housed of weight be placed in the washing machine simultaneously so that counterweight balance.Washing machine should be arranged to: the medium water yield (about 17 gallons), cold water and the most slight stirring setting.Combination washing/the care composition of the example I of 2 lid amounts (about 66ml) is poured in the washing machine; The liquid product of the 66ml example I in 17 gallons waters is meant that the total concn of the liquid detergent compositions in washing composition/aqueous solution is about 1090ppm.
Step 5, after washing machine is finished its all circulations, the overcoat that clothes is housed is taken out from washing machine, and the clothes in the overcoat is taken out from overcoat.Except that man's necktie and wool clothes, these clothes can be placed in the clothes-drying machine, and this clothes-drying machine be transferred to the air that is used for silk garment is shaken up (not heating) or the minimum possible heat drying shelves of the clothes that is used for being made by regenerated fiber and regenerated fiber mixture.Heavy clothes should keep in moisture eliminator 8-10 minute, and light clothes should keep 4-6 minute.Then should the humidity clothes from moisture eliminator, take out and with its hang-up or set level, thus the drying of finishing.For man's necktie and wool, this drying step is not suitable for, and begins dry air after they should being taken out from washing machine immediately.
Step 6, if necessary to clothes flatiron or steam flatiron.
Claims (23)
1. the liquid combination cleaning composition of suitable washing and conditioning upgrading textile, contain:
(a) anion surfactant;
(b) quaternary ammonium surfactant;
(c) polysiloxane tenderizer; With
(d) randomly, emulsifying agent;
Wherein the weight ratio of anion surfactant and quaternary ammonium surfactant is about 2: about 3: 1 of 1-, preferred about 2.2: about 2.8: 1 of 1-.
2. liquid detergent composition as claimed in claim 1 also contains the enzyme that is selected from mannase, amylase and composition thereof.
3. liquid detergent composition as claimed in claim 1, wherein said composition is cellulase or peroxidase not.
4. liquid detergent composition as claimed in claim 1, wherein said quaternary ammonium surfactant is selected from following material and composition thereof:
R wherein
1And R
2Be selected from respectively: C
1-C
4Alkyl, C
1-C
4Hydroxyalkyl, benzyl and-(C
2H
4O)
xH, wherein x is about 2-about 5; X is a negatively charged ion; And (1) R
3And R
4C respectively does for oneself
6-C
14Alkyl or (2) R
3Be C
6-C
18Alkyl, and R
4Be selected from: C
1-C
10Alkyl, C
1-C
10Hydroxyalkyl, benzyl and-(C
2H
4O)
xH, wherein x is 2-5.
5. liquid detergent composition as claimed in claim 1 also comprises being selected from following fabric care composition: the multipolymer of cyclic amine based polymer, oligopolymer and multipolymer, polyvinyl pyrrolidone polymers, polyamine N-oxide pllymers, N-V-Pyrol RC and N-ethene imidazoles, manganese phthalocyanine pigment, peroxidase and composition thereof.
6. liquid detergent composition as claimed in claim 1 also comprises cyclic amine based polymer, oligopolymer or multipolymer and polyamine N-oxide pllymers.
7. liquid detergent composition as claimed in claim 1, described polysiloxane tenderizer is selected from:
Wherein R is an aliphatic series, and preferred alkyl or alkenyl or aryl, R can be through replacing or without replacement, and x is the integer of 1-about 8000.
8. liquid detergent composition as claimed in claim 1 also comprises α-Dian Fenmei, and it by Phadebas alpha-amylase activity mensuration, has the specific activity than the specific activity height at least 25% of Termamyl under the pH value of 25-55 ℃ and 8-10.
9. liquid detergent composition as claimed in claim 1, wherein said polysiloxane tenderizer is selected from: polydimethylsiloxane, poly-di-ethyl siloxane, PSI and composition thereof.
10. liquid detergent composition as claimed in claim 1, wherein said polysiloxane tenderizer are the polydimethylsiloxane of polyalkylene oxide modification.
11. liquid detergent composition as claimed in claim 1, wherein said emulsifying agent are emulsifying surfactant.
12. a tool kit comprises:
(a) a flexible jacket container comprises:
The flexible panel that one right hand edge, a left hand edge, a upper limb and a lower rim are arranged;
At least one band is used for first securing gear with curly form hermetically sealed case container with linking to each other with described band;
First baffle plate that links to each other with the described right hand edge of described flexible panel; With
Second baffle plate that links to each other with the described left hand edge of described flexible panel, wherein said first and second baffle plate are when overlapping during edge fold separately along it;
(b) working instructions of flexible jacket container, this specification sheets are attached in the container of adorning this tool kit or on it; With
(c) liquid detergent composition of suitable washing and conditioning upgrading textile comprises:
I) anion surfactant;
Ii) quaternary ammonium surfactant;
Iii) polysiloxane tenderizer; With
Iv) randomly, emulsifying agent;
Wherein the weight ratio of anion surfactant and quaternary ammonium surfactant is about 2: about 3: 1 of 1-, preferred about 2.2: about 2.8: 1 of 1-.
13. as the tool kit of claim 12, wherein said tool kit also contains the washing pretreatment compositions that comprises tensio-active agent, enzyme and water.
14. as the tool kit of claim 12, wherein the flexible jacket container has greater than about 1g/cm under standard temperature and pressure (STP)
3Density.
15. as the tool kit of claim 13, wherein said washing pretreatment compositions also comprises and is selected from following component: detergent surfactant, enzyme, dye transfer inhibiting polymers, stain remover, washing auxiliary detergent, non-detergent surfactant, polymer dispersant, water, ethanol and composition thereof.
16. a method may further comprise the steps:
(a) clothes is put into the flexible jacket container, described flexible jacket container comprises:
(i) knit the system polyester by being selected from, knit the flexible panel of the material construction of system nylon or its combination; Described flexible panel has a right hand edge, a left hand edge, a upper limb and a lower rim;
(ii) at least two adjacent continuous devices that are positioned at flexible panel lower rim are used for this flexible jacket container is linked to each other with second flexible jacket container;
(iii) first and second band, each band and flexible adjacent linking to each other of panel upper limb; With
(iv) first securing gear, it can be fixed and for good and all link to each other with second band with described first, so that first securing gear invariant position on tape; And second securing gear, it makes band be connected to first or second by second securing gear and is with, and changes second securing gear position on tape by this way, and the length of band can increase or reduce;
(b) the flexible jacket container is put into washing machine with the suitable washing of significant quantity and the liquid detergent composition of conditioning upgrading textile, wherein said detergent composition comprises:
I) anion surfactant;
Ii) quaternary ammonium surfactant;
Iii) polysiloxane tenderizer; With
Iv) randomly, emulsifying agent;
Wherein the weight ratio of anion surfactant and quaternary ammonium surfactant is about 2: about 3: 1 of 1-, preferred about 2.2: about 2.8: 1 of 1-; With
(c) as manufacturer's description operation washing machine.
17. as the method for claim 16, wherein in step (a) before, this method also comprises step:
(i) will wash pretreatment compositions and be coated directly onto on the spot, described spot contacts with the absorbing material of the regional area of the clothes that covers the plan washing;
(ii) step (i) applies mechanical effect by washing pre-treatment spreader to described spot afterwards, thus spot is transferred in the absorbing material; With
(iii) randomly, rinse out the washing pretreatment compositions of clothes regional area.
18. as the tool kit of claim 12, wherein said polysiloxane tenderizer is the polydimethylsiloxane of polyalkylene oxide modification.
19. as the method for claim 16, wherein said polysiloxane tenderizer is the polydimethylsiloxane of polyalkylene oxide modification.
20., the ironing efficiency of clothes is improved as the method for claim 16.
21., the gauffer of clothes is reduced as the method for claim 20.
22. as the method for claim 20-21, wherein said clothes is made up of silk fiber.
23. liquid detergent composition as claimed in claim 1 also comprises mannase.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10553998P | 1998-10-24 | 1998-10-24 | |
| US60/105539 | 1998-10-24 | ||
| US60/105,539 | 1998-10-24 | ||
| US15739999P | 1999-10-01 | 1999-10-01 | |
| US15708299P | 1999-10-01 | 1999-10-01 | |
| US60/157399 | 1999-10-01 | ||
| US60/157082 | 1999-10-01 | ||
| US60/157,399 | 1999-10-01 | ||
| US60/157,082 | 1999-10-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1331741A true CN1331741A (en) | 2002-01-16 |
| CN1214098C CN1214098C (en) | 2005-08-10 |
Family
ID=27379944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB998150177A Expired - Fee Related CN1214098C (en) | 1998-10-24 | 1999-10-22 | Methods for laundering delicate garments in washing machine |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1123377B1 (en) |
| JP (1) | JP2002528598A (en) |
| CN (1) | CN1214098C (en) |
| AT (1) | ATE260967T1 (en) |
| AU (1) | AU1321000A (en) |
| BR (1) | BR9914801A (en) |
| CA (1) | CA2346543C (en) |
| DE (1) | DE69915329T2 (en) |
| MX (1) | MX227951B (en) |
| WO (1) | WO2000024860A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108226352A (en) * | 2016-12-12 | 2018-06-29 | 邢玉伟 | Application of the LHJ solubilizer in the quantitative determination of indissoluble food additives |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001025525A2 (en) * | 1999-10-01 | 2001-04-12 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine |
| MXPA02011958A (en) * | 2000-06-05 | 2003-04-22 | Procter & Gamble | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process. |
| EP1162254A1 (en) * | 2000-06-09 | 2001-12-12 | Clariant International Ltd. | Liquid all-purpose cleaners |
| US20020183226A1 (en) * | 2001-02-28 | 2002-12-05 | Chandrika Kasturi | Liquid detergent composition exhibiting enhanced alpha-amylase enzyme stability |
| GB0212157D0 (en) | 2002-05-27 | 2002-07-03 | Unilever Plc | Fabric conditioning composition |
| US20050059571A1 (en) * | 2003-09-12 | 2005-03-17 | John Mahdessian | Comprehensive stain removal kit and method with absorbent backing material |
| WO2007049188A1 (en) * | 2005-10-24 | 2007-05-03 | The Procter & Gamble Company | Fabric care compositions and systems comprising organosilicone microemulsions and methods employing same |
| DE102007029485B4 (en) | 2007-06-26 | 2010-06-17 | D'heureuse, Hans-Joachim | Process for cleaning in particular sensitive cleaning goods |
| US8470053B2 (en) | 2009-02-02 | 2013-06-25 | Fariborz Dawudian | Compositions for laundering and subsequently drying delicate garments without incurring any damage and methods to use them |
| CN105793410B (en) * | 2013-12-06 | 2019-05-10 | 狮王株式会社 | Liquid detergent |
| CN103776983B (en) * | 2014-01-27 | 2015-08-05 | 甘肃省交通科学研究院有限公司 | Ground drying and watering cycle experimental provision |
| JP6598356B2 (en) * | 2014-07-31 | 2019-10-30 | ライオン株式会社 | Liquid detergent for textile products |
| CN104297453B (en) * | 2014-11-03 | 2015-12-09 | 中国地质大学（武汉） | A kind of robotization rock sample wetting-drying test instrument |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54108812A (en) * | 1978-02-15 | 1979-08-25 | Kao Corp | Detergent composition for dry cleaning |
| EP0835340B1 (en) * | 1995-06-20 | 2002-01-02 | The Procter & Gamble Company | Dry cleaning with enzymes |
| US5723426A (en) * | 1996-02-29 | 1998-03-03 | Zhen; Yueqian | Liquid laundry detergent compositions containing surfactants and silicone emulsions |
-
1999
- 1999-10-22 CN CNB998150177A patent/CN1214098C/en not_active Expired - Fee Related
- 1999-10-22 JP JP2000578415A patent/JP2002528598A/en not_active Withdrawn
- 1999-10-22 WO PCT/US1999/024938 patent/WO2000024860A1/en active IP Right Grant
- 1999-10-22 BR BR9914801-3A patent/BR9914801A/en not_active Application Discontinuation
- 1999-10-22 CA CA002346543A patent/CA2346543C/en not_active Expired - Fee Related
- 1999-10-22 AU AU13210/00A patent/AU1321000A/en not_active Abandoned
- 1999-10-22 EP EP99956653A patent/EP1123377B1/en not_active Expired - Lifetime
- 1999-10-22 AT AT99956653T patent/ATE260967T1/en not_active IP Right Cessation
- 1999-10-22 DE DE69915329T patent/DE69915329T2/en not_active Expired - Fee Related
-
2001
- 2001-04-24 MX MXPA01004087 patent/MX227951B/en active IP Right Grant
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108226352A (en) * | 2016-12-12 | 2018-06-29 | 邢玉伟 | Application of the LHJ solubilizer in the quantitative determination of indissoluble food additives |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1123377B1 (en) | 2004-03-03 |
| MXPA01004087A (en) | 2001-08-01 |
| MX227951B (en) | 2005-05-23 |
| DE69915329T2 (en) | 2005-03-17 |
| AU1321000A (en) | 2000-05-15 |
| CA2346543A1 (en) | 2000-05-04 |
| CN1214098C (en) | 2005-08-10 |
| EP1123377A1 (en) | 2001-08-16 |
| WO2000024860A1 (en) | 2000-05-04 |
| ATE260967T1 (en) | 2004-03-15 |
| DE69915329D1 (en) | 2004-04-08 |
| JP2002528598A (en) | 2002-09-03 |
| BR9914801A (en) | 2001-07-10 |
| CA2346543C (en) | 2005-12-06 |
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