CN1331267A - Natural water-base fire-retarding adhesive - Google Patents
Natural water-base fire-retarding adhesive Download PDFInfo
- Publication number
- CN1331267A CN1331267A CN 00111194 CN00111194A CN1331267A CN 1331267 A CN1331267 A CN 1331267A CN 00111194 CN00111194 CN 00111194 CN 00111194 A CN00111194 A CN 00111194A CN 1331267 A CN1331267 A CN 1331267A
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- China
- Prior art keywords
- water
- starch
- tackiness agent
- fire
- borax
- Prior art date
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- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 27
- 239000008107 starch Substances 0.000 claims abstract description 27
- 235000019698 starch Nutrition 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910021538 borax Inorganic materials 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004327 boric acid Substances 0.000 claims abstract description 12
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 12
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 12
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 9
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 9
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 8
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 8
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 235000019270 ammonium chloride Nutrition 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical group [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 3
- 235000010338 boric acid Nutrition 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000779 smoke Substances 0.000 abstract description 4
- 239000002518 antifoaming agent Substances 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 11
- 239000003063 flame retardant Substances 0.000 description 11
- 239000000123 paper Substances 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000006481 Colocasia esculenta Nutrition 0.000 description 2
- 244000205754 Colocasia esculenta Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- -1 is toxic agent Chemical compound 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000005996 Blood meal Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000292211 Canna coccinea Species 0.000 description 1
- 235000005273 Canna coccinea Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- PSLIMVZEAPALCD-UHFFFAOYSA-N ethanol;ethoxyethane Chemical compound CCO.CCOCC PSLIMVZEAPALCD-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A water-base fire-retarding adhesive is proportionally prepared from water, starch, boric acid, borax, ammonium sulfate (or chloride), ammonium phosphate, and optional plasticizer, defoaming agent and/or surfactant. Its advantages include high quality, fire-retarding effect and water-proofing nature, low smoke density and high strengthening action to composition.
Description
The invention belongs to a kind of tackiness agent, particularly a kind of fire retardant adhesive.
The organic synthesis polymer binder is various in style, and it has excellent high-strength, water resistance, is convenient to suitability for industrialized production and use, particularly is widely used at matrix material, building material industry.But the organic synthesis tackiness agent has pollution to human and environment, and hazardness is big, and fire line is poor, the cost height.Particularly the fire line aspect in order to improve its fire resistance, adds fire retardant in prescription, and fire retardant has varied, and effect is different.In any case but it catches fire, smoke density is big, discharges poison gas content height.At present, more and more higher to the fire protection requirement of indoor building materials, the organic synthesis material comprises that the rate of utilization of organic composite adhesives is more and more lower.Applicating history natural and inorganic adhesive is remote, and economical cost is low, and toxicity is low or nontoxic, aboundresources, but the tackiness agent quality of stability is poor, and waterproof, moistureproofness are poor, use to have limitation.With starch is that the tackiness agent that raw material is made is the tackiness agent that utilizes natural matter to make, and prescription is had nothing in common with each other.In adhesive formula, also have and use boric acid or borax, but amount to be all fewer, boric acid mainly is toxic agent, mildew-resistant, mainly as linking agent, they use separately borax.
The purpose of this invention is to provide a kind of natural water-base fire-retarding adhesive, flame retardant properties is good, steady quality, and waterproof, pollution-free, it also is suitable for paper especially or/and bonding between fabric makes matrix material fire-retardant, the intensity height.
Natural water-base fire-retarding adhesive of the present invention is characterized in that in parts by weight, comprises starch 3～25, boric acid 0.5～10, borax 0.5～8, ammonium sulfate 3～25 or ammonium chloride 1～20 and ammonium phosphate 1～15 in 100 parts of water.
The present invention utilizes natural sizing starch, with addition of boric acid, borax, ammonium sulfate or ammonium phosphate and ammonium chloride all be fire-retardant unit, these fire-retardant unit make tackiness agent of the present invention have excellent flame-retardant jointly, and boric acid also plays mildew-resistant, preservative activity simultaneously, also has the function of thinner; Borax also has the effect of linking agent, gains in strength and improves water-repellancy.Ammonium sulfate also has dilution, reduces the effect of viscosity.Ammonium chloride and ammonium phosphate can replace ammonium sulfate, and wherein ammonium chloride also has the effect of thinner.Add ammonium sulfate in the prescription and relatively be fit to the bonding of paper material, ammonium chloride and ammonium phosphate relatively are fit to fabric (fiber).The present invention utilizes natural sizing, is that prior art is unexistent with addition of these fire-retardant unit simultaneously.Starch can be the common starch that utilizes various crops to make, and comprises seed and the taro class of corn, rice, wheat, barley, achira, taro, Ipomoea batatas, sweet potato, cassava, the made starch of potato ball root, and its technology all is known.
Below the embodiment that preferably forms for the present invention is for example:
Comprise starch 5～10, boric acid 1～7, borax 1～6, ammonium sulfate 5～16 in 100 parts of water.
Comprise starch 8～15, boric acid 1～7, borax 1～6, ammonium chloride 3～15 and ammonium phosphate 2～10 in 100 parts of water.
Starch cost of the present invention is low, and its also available soybean protein, casein, blood meal replace, but these material economy cost height.
Also can comprise softening agent 0.5～3 weight part and defoamer 0.1～1 weight part in the tackiness agent of the present invention.Softening agent such as glycerine, ethylene glycol, calcium chloride are preferably selected glycerine for use, and defoamer can be ethanol, ether, lipid acid higher alcohols, tributyl phosphite, silicone antifoam agent etc., preferably selects ethanol, ether for use.
The present invention can also add tensio-active agent, is 0.02～1% of other each component gross weight, mainly is to prevent the adherend surface ag(e)ing, improves wetting property.Can be sodium soap or the senior alcohol ester sodium of using always of sulfuric acid, as sodium stearate.
Manufacture craft is: the gelatinization of starch elder generation, cooling mixes with other each component then.Test its pH value as required, make its PH be preferably 6～8.Starch pasting technology is that prior art is known, simply is listed below several prior art processes:
1, starch and water heat under 2～3 normal atmosphere, and take out the cooling back, adds ethanol again, and Zulkovsky starch is just separated out, and Zulkovsky starch is the starch of gelatinization.
2, starch and glycerine are warm altogether, and the cooling back adds ethanol, and the throw out of being separated out is a Zulkovsky starch, is the starch of gelatinization of the present invention.
3, acid system: double centner starch and 200 milliliters of concentrated nitric acids, hydrochloric acid 300 milliliters (with the dilution of 10 premium on currency) mixes the back 50 ℃ of following dryings again 110～140 ℃ of heating, acid can the evaporation escape in calcining.
4, alkaline process: 10～20 parts of starch, 80～90 parts in water, 10%NaOH6～10 part mixing.
5, hot method: 5～10 parts of starch, 90～100 parts of Hybrid Heating multiviscosisty of water.
Need to prove: the water yield in the present invention's prescription does not comprise the needed water of starch pasting.
Advantage of the present invention:
Nontoxic or low toxicity is produced and is used harmlessly to environment and operator, and economical cost is low, and manufacture craft is simple, aboundresources.The compound sticking that is used for papery, fabric, metal, timber particularly is widely used for calligraphy and painting mounting, carton making, fire prevention firecrackers and makes, and the fire prevention coating of paper product, fabric, the composite material of paper and lamination paper product and fabric.Through overtesting, steady quality, good flame resistance, waterproof, particularly not only itself has flame retardant effect, by infiltration and infiltration, make the matrix material of paper product and fabric have flame retardant effect, smoke density is low, simultaneously the intensity of reinforced composite, can have the same intensity of glass reinforced plastic, with the matrix material of its making, lightweight, do not have to expand, anti-aging, the life-span is long, thermal conductivity is low, environmentally safe, belong to the green material of Sustainable development, this tackiness agent helps developing this paper product or Fabric composites.Described fabric comprises the textile cloth, organic synthesis nonwoven fabric of synthetic fibre of natural organic, synthetic organic and inorganic fibre etc., as cotton, canvas, chemical fibre and blended fabric.Through surveying, tackiness agent of the present invention is to the bond strength (kilogram/inch) 〉=60 of timber, and water resistant test was peeled off after 25 minutes.Utilize paper that this tackiness agent makes or cardboard, fabric (as canvas) matrix material oxygen index OI 〉=32, smoke density SDR≤60, average char length≤80mm, average afterflame time≤1 second, average continuous time≤1 second burned, narcoticness and pungency reach the accurate safe ZA3 level of GA132 fully, meet the GA159-1997 standard fully.
Embodiment:
But the glycerine among the above embodiment also spent glycol replaces.Tensio-active agent is a sodium stearate.
| Component embodiment | Starch | Water | Boric acid | Borax | Ammonium sulfate | Ammonium chloride | Ammonium phosphate | Glycerine | Ether | Ethanol | Tensio-active agent (accounts for the percentage ratio of other component gross weight |
| ?1 | ?7 | ?100 | ?5 | ?4 | ?10 | ||||||
| ?2 | ?10 | ?100 | ?7 | ?5 | ?15 | ?0.6 | |||||
| ?3 | ?5 | ?100 | ?3 | ?1 | ?7 | ||||||
| ?4 | ?6 | ?100 | ?1 | ?3 | ?5 | ||||||
| ?5 | ?9 | ?100 | ?6 | ?6 | ?16 | ||||||
| ?6 | ?10 | ?100 | ?5 | ?4 | ?8 | ?6 | ?0.02 | ||||
| ?7 | ?15 | ?100 | ?7 | ?5 | ?15 | ?8 | |||||
| ?8 | ?12 | ?100 | ?3 | ?1 | ?3 | ?4 | ?2 | ?4 | ?0.05 | ||
| ?9 | ?9 | ?100 | ?1 | ?3 | ?5 | ?2 | |||||
| ?10 | ?14 | ?100 | ?6 | ?6 | ?12 | ?10 | ?1 | ||||
| ?11 | ?20 | ?100 | ?10 | ?8 | ?25 | ?3 | ?1 | ||||
| ?12 | ?10 | ?100 | ?7 | ?5 | ?15 | ?3 | ?0.6 | ||||
| ?13 | ?5 | ?100 | ?3 | ?1 | ?7 | ?0.5 | ?0.8 | ||||
| ?14 | ?3 | ?100 | ?0.5 | ?0.7 | ?3 | ?0.6 | ?0.1 | ?0.02 | |||
| ?15 | ?25 | ?100 | ?8 | ?7 | ?20 | ?15 | ?2 | ?1 | ?0.7 | ||
| ?16 | ?15 | ?100 | ?5 | ?4 | ?1 | ?1 | ?1 | ?0.9 | ?0.06 | ||
| ?17 | ?4 | ?100 | ?0.8 | ?0.5 | ?4 | ||||||
| ?18 | ?22 | ?100 | ?9 | ?8 | ?18 | ?13 |
Claims (9)
1, a kind of natural water-base fire-retarding adhesive is characterized in that in parts by weight, comprises starch 3～25, boric acid 0.5～10, borax 0.5～8, ammonium sulfate 3～25 or ammonium chloride 1～20 and ammonium phosphate 1～15 in 100 parts of water.
2, tackiness agent according to claim 1 is characterized in that comprising in 100 parts of water starch 5～10, boric acid 1～7, borax 1～6, ammonium sulfate 5～16.
3, tackiness agent according to claim 1 is characterized in that comprising in 100 parts of water starch 8～15, boric acid 1～7, borax 1～6, ammonium chloride 3～15 and ammonium phosphate 2～10.
4,, it is characterized in that comprising defoamer 0.1～1 and softening agent 0.5～3 according to the described tackiness agent of one of claim 1～3.
5, according to the described tackiness agent of one of claim 1～3, it is characterized in that comprising tensio-active agent, be 0.02～1% of each component gross weight.
6, tackiness agent according to claim 4 is characterized in that comprising tensio-active agent, is 0.02～1% of each component gross weight.
7, tackiness agent according to claim 4 is characterized in that defoamer is ethanol or ether.
8, tackiness agent according to claim 4 is characterized in that softening agent is glycerine, ethylene glycol.
9, tackiness agent according to claim 6 is characterized in that tensio-active agent is a sodium stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00111194 CN1127549C (en) | 2000-06-26 | 2000-06-26 | Natural water-base fire-retarding adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00111194 CN1127549C (en) | 2000-06-26 | 2000-06-26 | Natural water-base fire-retarding adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1331267A true CN1331267A (en) | 2002-01-16 |
| CN1127549C CN1127549C (en) | 2003-11-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00111194 Expired - Fee Related CN1127549C (en) | 2000-06-26 | 2000-06-26 | Natural water-base fire-retarding adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1127549C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798779A (en) * | 2010-04-07 | 2010-08-11 | 浙江凯恩特种材料股份有限公司 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
| CN102189579A (en) * | 2010-10-09 | 2011-09-21 | 李海滨 | Small dimension wood poplar flame-retardant integrated plate producing method and wood modification liquid |
| CN101724413B (en) * | 2008-10-17 | 2012-03-21 | 陈万利 | Retardant and preparation method thereof |
| CN102732178A (en) * | 2011-03-29 | 2012-10-17 | 北京祝邦新技术研究所 | Flame retardant covering adhesive for buildings |
| CN103437182A (en) * | 2013-09-02 | 2013-12-11 | 徐文 | Improved fireproof flame retardant for textiles |
| CN103498384A (en) * | 2013-09-25 | 2014-01-08 | 李鸿光 | Fireproof paper for art painting |
| CN104562434A (en) * | 2015-01-04 | 2015-04-29 | 上海特安纶纤维有限公司 | Polysulfonamide permanent flame-retardant heat-insulation warm-keeping fabric sheet and preparation method thereof |
| CN106272785A (en) * | 2016-08-28 | 2017-01-04 | 桐乡市美意家具有限公司 | A kind of using method of wood fire retardant |
| CN109337608A (en) * | 2018-09-30 | 2019-02-15 | 嘉力丰科技股份有限公司 | A kind of starch-based adhesive and preparation method thereof having flame retarding function |
| CN109486427A (en) * | 2018-11-28 | 2019-03-19 | 贵州众旺包装有限公司 | A kind of dedicated burning-resistant type adhesive of carton and preparation method thereof |
| WO2021038348A1 (en) | 2019-08-29 | 2021-03-04 | 3M Innovative Properties Company | Pressure sensitive adhesive having broad compatibility with non-halogenated flame retardants |
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2000
- 2000-06-26 CN CN 00111194 patent/CN1127549C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724413B (en) * | 2008-10-17 | 2012-03-21 | 陈万利 | Retardant and preparation method thereof |
| CN101798779A (en) * | 2010-04-07 | 2010-08-11 | 浙江凯恩特种材料股份有限公司 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
| CN101798779B (en) * | 2010-04-07 | 2012-01-04 | 浙江凯恩特种材料股份有限公司 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
| CN102189579B (en) * | 2010-10-09 | 2016-06-29 | 李海滨 | The production method of the fire-retardant integrated sheet material of a kind of small dimension wood poplar and Wooden modifying liquid |
| CN102189579A (en) * | 2010-10-09 | 2011-09-21 | 李海滨 | Small dimension wood poplar flame-retardant integrated plate producing method and wood modification liquid |
| CN102732178A (en) * | 2011-03-29 | 2012-10-17 | 北京祝邦新技术研究所 | Flame retardant covering adhesive for buildings |
| CN103437182A (en) * | 2013-09-02 | 2013-12-11 | 徐文 | Improved fireproof flame retardant for textiles |
| CN103437182B (en) * | 2013-09-02 | 2015-06-24 | 苏州市轩德纺织科技有限公司 | Improved fireproof flame retardant for textiles |
| CN103498384A (en) * | 2013-09-25 | 2014-01-08 | 李鸿光 | Fireproof paper for art painting |
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| CN106272785A (en) * | 2016-08-28 | 2017-01-04 | 桐乡市美意家具有限公司 | A kind of using method of wood fire retardant |
| CN109337608A (en) * | 2018-09-30 | 2019-02-15 | 嘉力丰科技股份有限公司 | A kind of starch-based adhesive and preparation method thereof having flame retarding function |
| CN109486427A (en) * | 2018-11-28 | 2019-03-19 | 贵州众旺包装有限公司 | A kind of dedicated burning-resistant type adhesive of carton and preparation method thereof |
| WO2021038348A1 (en) | 2019-08-29 | 2021-03-04 | 3M Innovative Properties Company | Pressure sensitive adhesive having broad compatibility with non-halogenated flame retardants |
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