CN1329489C

CN1329489C - Liquid fuel for internal combustion engine

Info

Publication number: CN1329489C
Application number: CNB038256975A
Authority: CN
Inventors: 土田敬之
Original assignee: Sangi Co Ltd
Current assignee: Sangi Co Ltd
Priority date: 2002-12-24
Filing date: 2003-08-01
Publication date: 2007-08-01
Anticipated expiration: 2023-08-01
Also published as: AU2002357511A1; WO2004058926A1; TW200411041A; WO2004058925A1; CN1717469A; US20060137243A1; JPWO2004058926A1; AU2003254796A1

Abstract

A liquid fuel for internal combustion engine, comprising 2 to 85 wt % of an alcohol component of aliphatic monohydric alcohol having 2 to 6 carbon atoms per molecule per se or a mixture thereof and 15 to 98 wt. % of a hydrocarbon component. The liquid fuel for internal combustion engine contains an aluminum corrosion inhibitor in an amount capable of inhibiting the aluminum corrosion at predetermined given temperature. The aluminum corrosion inhibitor comprises at least one member selected from among methanol, glycol hydrocarbons, ketone hydrocarbons, ester hydrocarbons and aldehyde hydrocarbons.

Description

Liquid fuel for IC engine

Technical field

The present invention relates to improvement, make to need not to change existing structure or the material that uses the oil engine of gasoline liquid fuel, just can be so that the efficient of liquid fuel and output are equal to or higher than traditional gasoline substantially.

Background technology

As a part that overcomes the effort that present environmental problem does, the air pollution problems inherent that is caused by vehicle exhaust has been subjected to serious concern.Therefore, combustion engine fuel as the conventional gasoline substitute, the Aalcohols fuel that adds alcohols in light naphthar is just causing concern, and this fuel can reduce the carbon monoxide (CO) in the vehicle exhaust and the concentration of hydrocarbon polymer (HC) significantly, and its practical application has obtained test.

Compare with light naphthar etc., because alcohols has extremely low sulphur content, this synthetic liquid fuel that therefore contains light naphthar and alcohol also preferably can reduce SO except the concentration that can reduce aforesaid carbon monoxide (CO) and hydrocarbon polymer (HC) _xDeng.Yet, contain alcohol and can cause such problem: under High Temperature High Pressure in fuel injection device etc. synthetic liquid fuel and metal, particularly, can in life-time service, cause the corrosion (elution) of aluminium, aluminium alloy etc., thereby may cause fault with the contacting of aluminium, aluminium alloy etc.

Be conceived to the problems referred to above, it is very excellent or make metal, particularly aluminium, aluminium alloy etc. can not contained the liquid fuel for IC engine that pure synthetic liquid fuel corrodes (elution) by these to an object of the present invention is to provide practicality.

Summary of the invention

For achieving the above object, liquid fuel for IC engine of the present invention contains the hydrocarbon components of pure composition and the 15 weight %～98 weight % of 2 weight %～85 weight %, described pure composition is aliphatic monobasic alcohol itself or its mixture that per molecule has 2～6 carbon atoms, wherein, when the pure composition in the liquid fuel for IC engine is N weight %, be more than or equal to 0.1 weight % of 0.002 * N weight % or gained oil engine usefulness synthetic liquid fuel the greater in the two to the water yield that wherein adds.

According to this feature, when oil engine is N weight % with the pure composition in the synthetic liquid fuel, to the water yield that wherein adds be more than or equal to 0.1 weight % of 0.002 * N weight % or gained oil engine usefulness synthetic liquid fuel the greater in the two, it is very excellent or make metal, particularly aluminium, aluminium alloy etc. can not corrode the liquid fuel for IC engine of (elution) to obtain practicality thus.

Liquid fuel for IC engine of the present invention contains the hydrocarbon components of pure composition and the 15 weight %～98 weight % of 2 weight %～85 weight %, described pure composition is aliphatic monobasic alcohol itself or its mixture that per molecule has 2～6 carbon atoms, wherein, the gained oil engine contains the aluminium corrosion inhibitor that can suppress aluminium corrosive amount under temperature given in advance with synthetic liquid fuel, and described aluminium corrosion inhibitor comprises and is selected from methyl alcohol, the glycols hydrocarbon polymer, the ketone hydrocarbon polymer, at least a composition in ester hydrocarbon and the aldehydes hydrocarbon polymer.

According to this feature, at least a composition that is selected from methyl alcohol, glycols hydrocarbon polymer, ketone hydrocarbon polymer, ester hydrocarbon and the aldehydes hydrocarbon polymer is used as the aluminium corrosion inhibitor, thereby it is very excellent or make metal not only can to obtain practicality, particularly aluminium, aluminium alloy etc. can not corrode the liquid fuel for IC engine of (elution), can also obtain low-temperature stability very excellent, maybe can avoid alcohol and the isolating at low temperatures liquid fuel for IC engine of hydrocarbon polymer.

Liquid fuel for IC engine of the present invention preferably contains the water as the aluminium corrosion inhibitor at least.

Given this, the water of cheapness is used as the part of aluminium corrosion inhibitor, thereby can be with the minimized of the relatively costly aluminium corrosion inhibitor beyond dewatering, to prevent the increase of gained oil engine with the cost of synthetic liquid fuel.

Liquid fuel for IC engine of the present invention preferably also contains at least a ether composition, and described ether composition per molecule has and is no more than 12 carbon atoms and has an ehter bond at least in molecule.

Given this, contain the ether composition and can prevent separating of in processes such as long-term the storage pure composition in the gained liquid fuel and hydrocarbon components.

Description of drawings

Fig. 1 has shown the schema of producing the method for liquid fuel for IC engine in an embodiment of the present invention;

Fig. 2 has shown the graphic representation that concerns between the concentration of dusty gas in the ratio of pure composition and hydrocarbon components in the liquid fuel and the waste gas;

Fig. 3 has shown the synoptic diagram that each prescription of embodiment is formed;

Fig. 4 has shown the synoptic diagram of test result of the prescription 1 of embodiment;

Fig. 5 has shown the synoptic diagram of test result of the prescription 2 of embodiment;

Fig. 6 has shown the synoptic diagram of test result of the prescription 3 of embodiment;

Fig. 7 has shown the synoptic diagram of test result of the prescription 4 of embodiment;

Fig. 8 has shown the synoptic diagram of test result of the prescription 5 of embodiment;

Fig. 9 has shown the synoptic diagram of test result of the prescription 6 of embodiment;

Figure 10 has shown the synoptic diagram of test result of the prescription 7 of embodiment;

Figure 11 has shown the synoptic diagram of test result of the prescription 8 of embodiment;

Figure 12 has shown the synoptic diagram of test result of the prescription 9 of embodiment;

Figure 13 has shown the synoptic diagram of test result of the prescription 10 of embodiment;

Figure 14 has shown the synoptic diagram of test result of the prescription 11 of embodiment;

Figure 15 has shown the synoptic diagram of test result of the prescription 12 of embodiment;

Figure 16 has shown the synoptic diagram of test result of the prescription 13 of embodiment;

Figure 17 has shown the synoptic diagram of test result of the prescription 14 of embodiment;

Figure 18 has shown the synoptic diagram of test result of the prescription 15 of embodiment;

Figure 19 has shown the synoptic diagram of test result of the prescription 16 (prescription 1+ ether) of embodiment;

Figure 20 has shown the synoptic diagram of test result of the prescription 17 (prescription 2+ ether) of embodiment;

Figure 21 has shown the synoptic diagram of test result of the prescription 18 (prescription 3+ ether) of embodiment;

Figure 22 has shown the synoptic diagram of test result of the prescription 19 (prescription 4+ ether) of embodiment;

Figure 23 has shown the synoptic diagram of test result of the prescription 20 (prescription 5+ ether) of embodiment;

Figure 24 has shown the synoptic diagram of test result of the prescription 21 (prescription 6+ ether) of embodiment;

Figure 25 has shown the synoptic diagram of test result of the prescription 22 (prescription 7+ ether) of embodiment;

Figure 26 has shown the synoptic diagram of test result of the prescription 23 (prescription 8+ ether) of embodiment;

Figure 27 has shown the synoptic diagram of test result of the prescription 24 (prescription 9+ ether) of embodiment;

Figure 28 has shown the synoptic diagram of test result of the prescription 25 (prescription 10+ ether) of embodiment;

Figure 29 has shown the synoptic diagram of test result of the prescription 26 (prescription 11+ ether) of embodiment;

Figure 30 has shown the synoptic diagram of test result of the prescription 27 (prescription 12+ ether) of embodiment;

Figure 31 has shown the synoptic diagram of test result of the prescription 28 (prescription 13+ ether) of embodiment;

Figure 32 has shown the synoptic diagram of test result of the prescription 29 (prescription 14+ ether) of embodiment;

Figure 33 has shown the synoptic diagram of test result of the prescription 30 (prescription 15+ ether) of embodiment;

Figure 34 has shown the synoptic diagram of test result of the prescription 0 of embodiment;

Figure 35 has shown the synoptic diagram that adds the effect of entry and aluminium corrosion inhibitor in each prescription of embodiment;

Figure 36 has shown the synoptic diagram of pure add-on and aluminium corrosive relation; With

Figure 37 has shown the prescription and the checking result of the minimum content that is used to verify water.

Embodiment

For above-mentioned methyl alcohol, glycols hydrocarbon polymer, ketone hydrocarbon polymer, ester hydrocarbon, aldehydes hydrocarbon polymer and the water that is used as alcohol, hydrocarbon polymer and the ethers of main raw material and is used as the aluminium corrosion inhibitor therein in the present invention, will be described content ratio and reason thereof in gained synthetic liquid fuel and those suitable materials that uses respectively.

As the alcohol of main raw material, described alcohol is the main component of gained synthetic liquid fuel, suitable straight chain type or the non-straight chain type alcohol that uses per molecule to have 2～6 carbon atoms.Alcohol as main raw material, carbonatoms is greater than the alcoholic acid alcohol with two carbon atoms in the use per molecule, to avoid containing a high proportion of methyl alcohol, methyl alcohol is the alcohol that contains a carbon atom with remarkable high polarity, thereby can avoid the increase of gained synthetic liquid fuel integral polarity or avoid being used to containing the expansion of rubber tubing of supply etc. of the fuel of high polarity methyl alcohol.

Main raw material alcohol comprises such as polyvalent alcohols such as the secondary alcohol and the tertiary alcohols.Yet,, therefore cause the cost of gained synthetic liquid fuel to increase, so preferably use primary alconol (monohydroxy-alcohol) because the price of this higher alcohols is high and be difficult to obtain.

The carbon number of the per molecule molecular chain that this is pure is preferably set to and is no more than 10, particularly, then is no more than 6 when considering low temperature.When carbonatoms more than or equal to 7 the time, particularly above 10 o'clock, except the obvious deterioration of volatility under normal room temperature or the low temperature, tend to prolong combustion time in burning, thereby and the difference that is easy to occur hydrocarbon combustion speed cause this synthol to be not suitable as the gasoline alternative fuel.

Main raw material alcohol not only can use separately, also can be used in combination with suitable ratio by two or more different alcohol according to the ability of price, availability, factory etc.According to being used in combination of two or more alcohol, not only can adjust the plastisied dispersion of the proportion of the synthol that produces by the plastisied dispersion of forming (dispersion) by these pure ratios of appropriate change as the hydrocarbon polymer of the light naphthar of liquid fuel or recovery, and since their rate of combustion difference is small each other, can also make rate of combustion to be complementary by suitably making up these alcohol with the rate of combustion of gasoline.Consider the operation in the use of gasoline device, such being used in combination is preferred.As the combination of alcohol, consider price and volatility etc., preferably suitably make up ethanol, n-propyl alcohol (NPA), Virahol (IPA), isopropylcarbinol (IBA), butanols, amylalcohol and hexanol etc.Particularly, owing to can improve the octane value of gained, the non-straight chain type aliphatic monobasic alcohol of therefore preferred use.Yet the present invention is not limited thereto.

The ratio of the alcohol in the synthol is preferably set to 85 weight % or still less.As shown in Figure 2, by alcohol is added into light naphthar, be in the gasolene ingredient, carbon monoxide in the waste gas (CO) and hydrocarbon polymer (HC) reduce gradually, and the ratio of alcohol is 25 weight % or the concentration substantially constant of hydrocarbon polymer (HC) in the waste gas more for a long time in the gained fuel, and the concentration of carbon monoxide (CO) descends gradually and is about 85 weight % until pure ratio simultaneously.When the ratio of alcohol surpasses about 85 weight %, the concentration of carbon monoxide in the waste gas (CO) and hydrocarbon polymer (HC) and use pure itself the time concentration equate.Yet, when pure ratio surpasses about 85 weight %, the rate of combustion of gained fuel be not approach the rate of combustion of hydrocarbon polymer but approach alcohol rate of combustion, in the oil engine of traditional use gasoline, can't obtain satisfied burning, particularly in high speed rotating, can cause the unfavorable defective of rate of combustion.

Because when adding in light naphthar as alcohol ethanol, as shown in figure 36, even in only containing 2 weight % alcoholic acid situations, also can observe in 240 hours because the weight loss that elution caused of aluminium 120 ℃ of heating, and containing ratio is 2 weight % or can obtains aluminium corrosion prevention effect of the present invention more for a long time, so the lower value of the ratio of alcohol can be set at 2 weight % or more.Therefore, based on aforesaid higher limit, the scope of the ratio of alcohol is set at 2 weight %～85 weight % in the synthol.

Because the result of Figure 36 shows when the ratio of alcohol surpasses 10 weight %, even 80 ℃ of following heating weight loss that also can cause the elution by aluminium to cause in 240 hours, and the result of Fig. 2 shows that the ratio of alcohol is lower than 15 weight % and then can causes particularly significantly increasing of hydrocarbon polymer (HC), and the ratio of alcohol may cause the problem of advancing that causes because of the incendiary asymmetry when surpassing 75 weight %, so the ratio of alcohol more preferably is set at 15 weight %～75 weight %, this asymmetry is owing to rate of combustion different cause of the above-mentioned hydrocarbon polymer that depends on the oil engine model with alcohol.

Saturated or unsaturated hydrocarbon polymer is applicable to as hydrocarbon polymer.Yet when the carbonatoms in the hydrocarbon molecules surpassed 13, its volatility descended, and caused the ignition quality deterioration of lighter for ignition or caused the increase of CO in the waste gas or HC concentration because of residue of combustion.Therefore, consider CO or the increase of HC concentration or the ignition quality of lighter for ignition etc. in the waste gas that causes owing to the incendiary resistates, can suitably select hydrocarbon polymer, the preferred use has the saturated or undersaturated hydrocarbon polymer that is no more than 9 carbon atoms.Wherein, because its price is lower, light naphthar, promptly the mixture of saturated hydrocarbon is suitable the use.

Light naphthar contains usually such as B (benzene), T (toluene) and X aromatic hydrocarbon such as (dimethylbenzene).Yet similar with the situation of Fuel Petroleum, the aromatic hydrocarbon of high density may cause in the waste gas CO or HC concentration to raise or will itself be discharged in the waste gas such as B (benzene), T (toluene) and X deleterious aromatic hydrocarbon such as (dimethylbenzene).Therefore, preferably use those to have the light naphthar of low levels such as B (benzene), T (toluene) and X aromatic hydrocarbon such as (dimethylbenzene).

The source of the concentration based on crude of the sulphur content in the light naphthar alters a great deal.Because the sulphur content of high density can cause SO in the waste gas _xIncrease, therefore preferably with the light naphthar desulfurization so that its sulphur content is 0.01% or still less.

Except light naphthar, also can use initial boiling point is that 38 ℃～60 ℃ and full boiling point are 180 ℃～220 ℃ the refining oil again that is obtained by the turning oil distillation, this turning oil is handled by petrochemical industry and is obtained, described petrochemical industry is treated to the part of plastic waste circular treatment, and a large amount of processing of plastic waste get into a difficult position now.Because at petroleum naphtha, promptly the feed stage of plastics is carried out desulfurization, and therefore refining oil can further reduce SO in the waste gas again _x

Preferably this turning oil being carried out refining again to initial boiling point is that 38 ℃～60 ℃ and full boiling point are 180 ℃～220 ℃ so that use.When initial boiling point surpasses 60 ℃, at low temperatures or the startability of cold district significantly reduce so that can't obtain the startability the same, when full boiling point is higher than 220 ℃, in the high speed rotating of engine, can't produce the power of engine by design load with gasoline.

As the ether composition, can use at least a per molecule to have and be no more than the ether that contains an ehter bond in 12 carbon atoms and the molecule at least.

Although be not always to need the ether composition, add the ether composition and preferably can prevent separating of the hydrocarbon components that causes because of secular variation etc. and pure composition.Though the ether composition changes with employed other components in proportions and composition, can suitably select the ether components in proportions of being added according to predetermined storage stability.The ratio of ether can be set at 5 weight %～30 weight % usually.When ratio is less than or equal to 5 weight %, the deleterious of storage stability, and when the ratio of ether during more than or equal to 30 weight %, fuel can produce the smell of ether, and volatility obviously increases, cause the increase of fuel vaporization amount or the storage that acts as a fuel in loss increase.

As ether to be mixed, can use the ether that in molecule, has ehter bond at least.Yet, when containing a large amount of carbon atom in the ether per molecule to be used, except its volatility worsens, improve that deliquescent ability also can worsen between alcohol and hydrocarbon polymer.And because this ether is expensive and may obtain with fuel quantity hardly, therefore the carbonatoms of ether to be used is set at and is no more than 12.

Owing to use ether to be easy to cause separating between above-mentioned hydrocarbon polymer and the alcohol with relatively large carbonatoms, therefore by use per molecule contain 2 or 2 above ehter bonds such as except that ehter bond, also contain in ether such as diethylene glycol dimethyl ether or ethylene glycol diethyl ether or the molecule hydroxyl (OH) such as ethers such as ethylene glycol monoethyl ethers, preferably can avoid separating of the hydrocarbon polymer that causes because of polarity decline and alcohol.In addition, by using the ether that has a plurality of ehter bonds in the molecule or have the hydroxyl (OH) except that ehter bond, can obtain being equal to or higher than the separation preventive effect of traditional ether with low carbon number.

Consider the solvability between volatility and hydrocarbon polymer and the alcohol, these ethers not only can use separately and can also be used in combination with the ether of low carbon number and the ether of high carbon number.

As the aluminium corrosion inhibitor, can use methyl alcohol, glycols hydrocarbon polymer, ketone hydrocarbon polymer, ester hydrocarbon, aldehydes hydrocarbon polymer and water.

As glycols hydrocarbon polymer as the aluminium corrosion inhibitor, because those viscosity with high-molecular weight glycols hydrocarbon polymer are big, can increase the viscosity of gained synthol, thereby suitable the use has relatively than the ethylene glycol of small molecular weight or propylene glycol etc.

Ketone hydrocarbon polymer as the aluminium corrosion inhibitor can use per molecule to have any hydrocarbon polymer of a ketonic bond at least.Consider that per molecule contains the high price etc. of the ketone hydrocarbon polymer of a plurality of carbon atoms, suitable use per molecule contain the relatively small amount carbon atom such as acetone, Ketene dimethyl, methyl ethyl ketone, diethyl ketone, methyl n-propyl ketone, methyl iso-butyl ketone (MIBK) or methyl ethyl diketone etc.

Ester hydrocarbon as the aluminium corrosion inhibitor can use per molecule to have any hydrocarbon polymer of an ester bond at least.Consider that per molecule contains the high price etc. of the ester hydrocarbon of a plurality of carbon atoms, suitable use per molecule contain the relatively small amount carbon atom such as methyl-formiate, ethyl formate, methyl acetate or ethyl acetate etc.

Aldehydes hydrocarbon polymer as the aluminium corrosion inhibitor can use per molecule to have any hydrocarbon polymer of an aldehyde key at least.Consider that per molecule contains the high price etc. of the aldehydes hydrocarbon polymer of a plurality of carbon atoms, suitable use per molecule contain the relatively small amount carbon atom such as acetaldehyde, propionic aldehyde or butyraldehyde etc.

Because these aluminium corrosion inhibitors liken alcohol and petroleum naphtha costliness into main raw material to, therefore the consumption as methyl alcohol, glycols hydrocarbon polymer, ketone hydrocarbon polymer, ester hydrocarbon, aldehydes hydrocarbon polymer and the water of aluminium corrosion inhibitor can be set at can be at preset temperature, the minimum that the aluminium corrosion of for example 80 ℃～120 ℃ gained synthetic liquid fuels that caused by dry corrosion suppresses.As hereinafter describing among the embodiment, although its kind with employed aluminium corrosion inhibitor becomes, its add-on maximum can be set at 10 weight % or still less.

Embodiment

Fig. 1 has shown the schema of producing the method for liquid fuel for IC engine in an embodiment of the present invention.Liquid fuel for IC engine of the present invention mainly is made of at least a aliphatic monobasic alcohol (primary alconol), saturated or unsaturated hydrocarbon polymer, ether composition (per molecule contains ether itself or its mixing that is no more than 12 carbon atoms and has ehter bond in molecule) and aluminium corrosion inhibitor (comprising water).Behind these raw materials weight percent that weighing extremely is scheduled to separately, at first add the ether of polarity less than aliphatic primary alcohol, the light naphthar that has the hydrocarbon polymer of relatively large part by weight and least polar with conduct mixes.

Add the alcohol of accurate amount and aluminium corrosion inhibitor then and mix with the mixture of light naphthar and ether.

After adding alcohol and aluminium corrosion inhibitor, measure the proportion of mixed fluid fuel, if this proportion is less than or equal to predetermined proportion, described predetermined proportion is 0.735 or bigger, then suitably adds alcohol so that proportion is adjusted to 0.755.

To the Formulation Example of the fuel composition for preparing in an embodiment according to aforesaid method be described below.In this embodiment, as shown in Figure 3, prepare various basic recipes by making up with the ratio that is added into the alcohol in the petroleum naphtha.To be added into respectively as methyl alcohol, glycols hydrocarbon polymer, ketone hydrocarbon polymer, ester hydrocarbon, aldehydes hydrocarbon polymer and the water of various aluminium corrosion inhibitors then in each basic recipe and fill a prescription with preparation, and by aluminium being immersed in each prescription and being heated to the aluminium corrosion test that predetermined high temperature carries out each prescription.In addition, according to the existence of (in this embodiment for-10 ℃) fuel segregation at low temperatures/the do not exist low-temperature stability of assessing each prescription.

Based on Fig. 3～34 in the situation that the aluminium corrosion inhibitor is added into each prescription to aluminium corrosion test result and at normal temperatures with low temperature under the result of storage stability assessment be described.

The testing method of the elution of aluminium (weight loss) and the testing method of storage stability are as follows.

＜aluminium elution test 〉

(1) fuel sample and the water (distilled water) of weighing predetermined amount in the ball mill jar made from SUS (300ml), total amount is 100ml.

(2) fine aluminium test specimen (A1050) is immersed in the jar of (1), and when immersing it in sample fuel, provide 5 spots (flaw) (purpose is to remove the lip-deep oxide film of aluminium test specimen) for the aluminium test specimen with file.

(3) the atmosphere gas in the ball mill jar is replaced into nitrogen, and covers rapidly.

The ball mill jar that (4) will obtain is thus put into the thermostatic drier that preset temperature is set at 80 ℃～120 ℃.

(5), the ball mill jar is taken out and in air-flow, cool off through after the scheduled time.

(6) measure the weight loss of aluminium test specimen, when observing because during part variable color or pitting attack cause slight weight loss, even weight loss also is described as 1 with it less than 0.

＜storage-stability property testing 〉

After fuel mix, observation is at room temperature placed the state of the fuel after 1 hour and is put into the state that refrigerator (11 ℃) stores the fuel after one day respectively.Those fuel that dissolve each other each other are evaluated as 100, and those are muddy or cause the fuel of fuel segregation to be evaluated as 0.

E2, promptly Formulation Example 0 has and contains 98 weight % petroleum naphthas and 2 weight % alcoholic acid essentially consists, and wherein ethanol is as alcohols, and consumption is only for causing aluminium corrosive minimum proportion.As shown in figure 34, when 120 ℃ of heating 120 hours the time, even as E-2, have the weight loss that aluminium corrosion that the prescription of minimum pure ratio also can cause causing because of dry corrosion is produced.

When the water with 0.1 weight % added among the E2,120 ℃ of weight loss that caused by the aluminium corrosion disappeared, and erosion resistance improves.When further adding water with the amount of 0.2 weight % and 0.4 weight %, layer occurring at-10 ℃ in the add-on of 0.2 weight % separates, even at room temperature also occurring layer in the add-on of 0.4 weight % separates, and the prescription that those add-ons of not adding water or those water are 0.1 weight % does not promptly store performance issue at-10 ℃ under the low temperature.Therefore, corrosion is effectively to aluminium in the interpolation of water, but storage stability can worsen because of the interpolation of water.

In Figure 34 name is called the prescription of " E2-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, when add-on was 0.5 weight %, the erosion resistance of aluminium improved.In addition, the add-on of those methyl alcohol is that the prescription of 0.5 weight % does not cause layer to separate under room temperature or low temperature, and makes normal temperature and low temperature storage performance be improved by adding methyl alcohol.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

In Figure 34 name is called the prescription of " E2-PG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, when adopting the 0.5 weight % add-on identical with methyl alcohol, the erosion resistance of aluminium improves, even wherein 120 ℃ of erosion resistances that also can obtain gratifying aluminium, and make normal temperature and cryogenic storage performance improve and can not cause layer separation normal temperature or low temperature under by adding ethylene glycol.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

In Figure 34 name is called the prescription of " E2-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding acetone separately, when add-on is 2.0 weight %, at 120 ℃ of erosion resistance and ambient stable and low-temperature stabilities that obtain gratifying aluminium.Therefore, acetone can be used as the aluminium corrosion inhibitor satisfactorily.

Obviously can see from the result of the combination of interpolation water shown in Figure 34 " E2-Ac " and acetone,, also can obtain gratifying aluminium erosion resistance and ambient stable and low-temperature stability even the add-on of acetone minimizes by using aqueous acetone.In addition, by mixing acetone,, and when adding water itself, can not obtain this low temperature storage performance even be also can obtain gratifying low temperature storage performance under the situation of 0.2 weight % in water content.Therefore, acetone has the effect of improving low-temperature stability, and glassware for drinking water has the effect that reduces the acetone add-on.

In being called the prescription of " E2-GE ", Figure 34 name shown that only adding ethyl formate replaces the result of water and the result that itself and water combination are added as ester.Do not add under the situation of water adding ethyl formate separately, when add-on is 2.0 weight %, obtain gratifying aluminium erosion resistance and ambient stable and low-temperature stability at 120 ℃.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Result by the ethyl formate of the interpolation shown in Figure 34 " E2-GE " and water combination, by using the ethyl formate that makes up with water, even the add-on of ethyl formate minimizes erosion resistance and the ambient stable and the low-temperature stability that also can obtain gratifying aluminium.In addition, by mixing ethyl formate,, and when adding water itself, can not obtain this low temperature storage property even be also can obtain gratifying low temperature storage performance under the situation of 0.2 weight % in water content.Therefore, ethyl formate has the effect of improving low-temperature stability, and glassware for drinking water has the effect that reduces the ethyl formate add-on.

In being called the prescription of " E2-BA ", Figure 34 name shown that only adding butyraldehyde replaces the result of water and the result that itself and water combination are added as aldehyde.Do not add under the situation of water adding butyraldehyde separately, when add-on is 1.5 weight %, can obtain gratifying aluminium erosion resistance and ambient stable and low-temperature stability at 120 ℃.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

By the result of the butyraldehyde of the interpolation shown in Figure 34 " E2-BA " and water combination, by using the butyraldehyde with the water combination, even the add-on of butyraldehyde minimizes erosion resistance and the ambient stable and the low-temperature stability that also can obtain gratifying aluminium.And, by mixing butyraldehyde,, and when adding water itself, can not obtain this low temperature storage property even be also can obtain gratifying low temperature storage performance under the situation of 0.2 weight % in water content.Therefore, butyraldehyde has the effect of improving low-temperature stability, and glassware for drinking water has the effect that reduces the butyraldehyde add-on.

E10, promptly Formulation Example 1 has and contains 90 weight % petroleum naphthas and 10 weight % alcoholic acid essentially consists, wherein only with ethanol as the alcohol that has relatively than small proportion.Similar to shown in the above-mentioned aluminium corrosion test (Figure 36) in 240 hours Corrosion results of 80 ℃ of heating, as shown in Figure 4, when 100 ℃ of heating 120 hours or 120 ℃ of heating after 24 hours, even as E-10, have the weight loss that aluminium corrosion that the prescription of less relatively pure ratio also can cause causing because of dry corrosion is produced.

When adding entry to 0.1 weight % and when adding entry to 0.4 weight % for 120 ℃, corrode the weight loss disappearance that causes by aluminium in E10 at 100 ℃, erosion resistance improves.Yet, when the add-on of water is 0.4 weight %, genetic horizon separates in-10 ℃ storage performance test, corrode the weight loss that causes because of aluminium 120 ℃ of generations, even at room temperature also can separate by genetic horizon when adding the water of 0.5 weight %, the wherein excessive water that adds 0.1 weight %, purpose provides the permission to corrosion protection, and those do not add prescription water or that added 0.1 weight % water at-10 ℃, promptly do not store performance issue under the low temperature.Therefore, corrosion is effectively to the aluminium that causes because of dry corrosion in the interpolation of water, but when attempting at 120 ℃, promptly under the high temperature by making water when guaranteeing gratifying aluminium corrosion protection, can cause storage stability to worsen because of the interpolation of water.

In Fig. 4 name is called the prescription of " E10-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the improvement of aluminium erosion resistance is basic same with the water that adds 0.4 weight %, be that the situation of 0.4 weight % is compared wherein with the add-on of water, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability also improves and can not cause layer to separate.In addition, when the add-on of methyl alcohol is 0.5 weight %,, and can not cause layer separation room temperature or low temperature under by adding methyl alcohol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that yet obtain the aluminium erosion resistance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

In Fig. 4 name is called the prescription of " E10-PG ", shown and added propylene glycol replaces water as glycol result, under the situation of adding propylene glycol, the improvement of aluminium erosion resistance is basic same with the water that adds 0.4 weight %, be that the situation of 0.4 weight % is compared wherein with the add-on of water, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability also improves and can not cause layer to separate.When the add-on of propylene glycol is 0.5 weight %,, and can not cause layer separation room temperature or low temperature under by adding propylene glycol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that yet obtain the aluminium erosion resistance.Therefore, propylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

In Figure 34 name is called the prescription of " E10-DEK ", shown and added that Ketene dimethyl replaces the result of water as ketone and its result with water combination interpolation.Do not add in the situation of water adding Ketene dimethyl separately, in the add-on of 3.5 weight %, can obtain gratifying aluminium erosion resistance, and in the add-on of 4.5 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, Ketene dimethyl can be used as the aluminium corrosion inhibitor satisfactorily.

Obviously see from the result of the diethyl ketone of the interpolation shown in Fig. 4 " E10-DEK " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause gained fuel storage stability under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation diethyl ketone.Therefore, diethyl ketone is effective for the add-on that reduces water with improving low-temperature stability.

In being called the prescription of " E10-GE ", Figure 34 name shown that only adding ethyl formate replaces the result of water and the result that itself and water combination are added as ester.Do not add in the situation of water adding ethyl formate separately, in the add-on of 3.0 weight %, can obtain gratifying aluminium erosion resistance, and in the add-on of 4.0 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Obviously see from the result of the ethyl formate of the interpolation shown in Fig. 4 " E10-GE " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.When the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation ethyl formate.Therefore, ethyl formate is to the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 34 name is called the prescription of " E10-PA ", shown and added that propionic aldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding propionic aldehyde separately, when add-on is 1.5 weight %, can obtain gratifying aluminium erosion resistance, and when add-on is 2.0 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In two prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, propionic aldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Obviously see from the result of the propionic aldehyde of the interpolation shown in Fig. 4 " E10-PA " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation propionic aldehyde.Therefore, propionic aldehyde is to the add-on that reduces water and to improve low-temperature stability be effective.

For " E10-E ", promptly except that E10, also contain the basic recipe of ether, add water, methyl alcohol, propylene glycol, diethyl ketone, ethyl formate and propionic aldehyde with the same mode of E10 and test aluminium erosion resistance and storage stability by using.The result as shown in figure 19.From result shown in Figure 19, can obviously see, add ether and also can obtain the effect identical with the situation of E10.Therefore, water, methyl alcohol, propylene glycol, Ketene dimethyl, ethyl formate and propionic aldehyde also can be used in those prescriptions that contain ether effectively.

E20 promptly has the Formulation Example 2 of the essentially consist that is made of 80 weight % petroleum naphthas and 20 weight % ethanol, wherein surpasses content among the E10 of Formulation Example 1 as the alcoholic acid content of alcohol.In E20, as shown in Figure 5, along with the rising of pure ratio, at 100 ℃ with surpassed above-mentioned E10 in the increase of 120 ℃ of weight loss that cause by aluminium corrosion.This shows that the increase of alcohol is easy to promote dry corrosion takes place, and has increased the weight loss that the aluminium corrosion is caused.

When adding entry to 0.1 weight % and in E20 when adding entry to 0.9 weight % for 120 ℃ at 100 ℃, for example, as shown in Figure 5, the weight loss that the aluminium corrosion is caused disappears, and erosion resistance improves.Yet, when the add-on of water is 0.9 weight %, in-10 ℃ low temperature storage performance test layer having taken place separates, corrode the weight loss that causes at 120 ℃ of no aluminium, even and the add-on of water when being 1.1 weight % at room temperature also genetic horizon separate, and those prescriptions that not add add-on water or water be 0.1 weight % are at-10 ℃, and promptly low temperature does not have the storage performance issue down.Therefore, water add that corrosion is effectively to the aluminium that caused by dry corrosion, but when at 120 ℃, promptly attempt under the high temperature when making water guarantee gratifying aluminium corrosion protection, the interpolation of water can cause the deterioration of storage stability.

In Fig. 5 name is called the prescription of " E20-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, when add-on was 0.5 weight %, the aluminium erosion resistance was improved, even wherein also can obtain gratifying aluminium erosion resistance at 120 ℃, and low-temperature stability is also satisfactory.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

In Fig. 5 name is called the prescription of " E20-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the improvement of aluminium erosion resistance is identical with the methyl alcohol that adds 0.5 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 120 ℃, and low-temperature stability is also satisfactory.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

In Fig. 5 name is called the prescription of " E20-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water separately adding acetone, when add-on is 3.0 weight %, can obtain gratifying aluminium erosion resistance, and add-on can obtain gratifying aluminium erosion resistance at 120 ℃ when being 4.0 weight % at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, acetone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetone of the interpolation shown in Fig. 5 " E20-Ac " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation acetone.Therefore, acetone is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 5 name is called the prescription of " E20-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 6.0 weight %, can obtain gratifying aluminium erosion resistance, and when add-on is 8.0 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl-formiate of the interpolation shown in Fig. 5 " E20-GM " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation methyl-formiate.Therefore, methyl-formiate is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 5 name is called the prescription of " E20-BA ", shown and added that butyraldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding butyraldehyde separately, when add-on is 2.0 weight %, can obtain gratifying aluminium erosion resistance, and when add-on is 2.5 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the butyraldehyde of the interpolation shown in Fig. 5 " E20-BA " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.When the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation butyraldehyde.Therefore, butyraldehyde is to the add-on that reduces water and to improve low-temperature stability be effective.

For " E20-E ", promptly except that E20, also contain the basic recipe of ether, add water, methyl alcohol, ethylene glycol, acetone, methyl-formiate, butyraldehyde with the same mode of E10 and test aluminium erosion resistance and storage stability by using.The result as shown in figure 20.From result shown in Figure 20, can obviously see, also can obtain the effect identical with the situation of E20 even add ether.Therefore, water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde also can be used in those prescriptions that contain ether effectively.

E50 promptly has the Formulation Example 3 of the essentially consist that is made of 50 weight % petroleum naphthas and 50 weight % ethanol, wherein surpasses content among the E20 of Formulation Example 2 as the alcoholic acid content of alcohol.In E50, as shown in Figure 6, along with the rising of pure ratio, at 100 ℃ with surpassed above-mentioned E20 in the increase of 120 ℃ of weight loss that cause by aluminium corrosion.This shows that the increase of alcohol is easy to promote dry corrosion takes place, and has increased the weight loss that the aluminium corrosion is caused.

When adding entry to 0.1 weight % and in E50 when adding entry to 3.4 weight % for 120 ℃ at 100 ℃, for example, as shown in Figure 6, the weight loss that the aluminium corrosion is caused disappears, and erosion resistance improves.Yet, when the add-on of water is 3.4 weight %, in-10 ℃ low temperature storage performance test layer having taken place separates, corrode the weight loss that causes at 120 ℃ of no aluminium, even and the add-on of water when being 3.6 weight % at room temperature also genetic horizon separate, and those prescriptions that not add add-on water or water be 0.1 weight % are at-10 ℃, and promptly low temperature does not have the storage performance issue down.Therefore, water add that corrosion is effectively to the aluminium that caused by dry corrosion, but when at 120 ℃, promptly attempt under the high temperature when making water guarantee gratifying aluminium corrosion protection, the interpolation of water can cause the deterioration of storage stability.

In Fig. 6 name is called the prescription of " E50-Me ", shown and added the result that methyl alcohol replaces water.Adding under the situation of methyl alcohol, the aluminium erosion resistance 100 ℃ and 120 ℃ when add-on is respectively 0.8 weight % and 1.0 weight % is improved, and wherein low-temperature stability is also satisfactory.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

In Fig. 6 name is called the prescription of " E50-EG ", shown and added ethylene glycol replaces water as glycol result.In the situation of adding ethylene glycol, the improvement of aluminium erosion resistance is identical with the methyl alcohol that adds 0.7 weight %, and also can obtain gratifying aluminium erosion resistance at 120 ℃ when add-on is 1.0 weight %, and wherein low-temperature stability is also satisfactory.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

In Fig. 6 name is called the prescription of " E50-MEK ", shown and added that methyl ethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl ethyl ketone separately, when add-on is 4.0 weight %, can obtain gratifying aluminium erosion resistance, and when add-on is 6.0 weight %, can obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl ethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl ethyl ketone of the interpolation shown in Fig. 6 " E50-MEK " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation methyl ethyl ketone.Therefore, methyl ethyl ketone is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 6 name is called the prescription of " E50-GE ", shown and added that ethyl formate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water separately adding ethyl formate, be improved 100 ℃ and 120 ℃ of aluminium erosion resistances when add-on is respectively 6.0 weight % and 10.0 weight %.In addition, in two prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethyl formate of the interpolation shown in Fig. 6 " E50-GE " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.When the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation ethyl formate.Therefore, ethyl formate is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 6 name is called the prescription of " E50-AA ", shown and added that acetaldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water separately adding acetaldehyde, be improved 100 ℃ and 120 ℃ of aluminium erosion resistances when add-on is respectively 3.0 weight % and 4.0 weight %.In addition, in two prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, acetaldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetaldehyde of the interpolation shown in Fig. 6 " E50-AA " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.When the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation acetaldehyde.Therefore, acetaldehyde is to the add-on that reduces water and to improve low-temperature stability be effective.

For " E50-E ", promptly except that E50, also contain the basic recipe of ether, add water, methyl alcohol, ethylene glycol, methyl ethyl ketone, ethyl formate and acetaldehyde with the same mode of E50 and test aluminium erosion resistance and storage stability by using.The result as shown in figure 21.From result shown in Figure 21, can obviously see, add ether and also can obtain the effect identical with the situation of E50.Therefore, water, methyl alcohol, ethylene glycol, methyl ethyl ketone, ethyl formate and acetaldehyde also can be used in those prescriptions that contain ether effectively.

IN40 promptly has the Formulation Example 4 of the essentially consist that is made of 60 weight % petroleum naphthas, 20 weight % Virahols and 20 weight % propyl carbinols, wherein uses two kinds of alcohol, or carbon number more than alcoholic acid Virahol and propyl carbinol as alcohol.In IN40, as shown in Figure 7, can observe the weight loss that the aluminium corrosion that by dry corrosion caused identical with E50 caused.

When 90 ℃ and 120 ℃ respectively when IN40 adds entry to 0.1 weight % and 3.6 weight %, for example, the weight loss that the aluminium corrosion causes disappears, as shown in Figure 7, and erosion resistance improves.Yet, when the add-on of water is 3.6 weight %, in-10 ℃ low temperature storage performance test layer having taken place separates, corrode the weight loss that causes at 120 ℃ of down no aluminium, even and the add-on of water when being 3.8 weight % at room temperature also genetic horizon separate, and those prescriptions that not add add-on water or water be 0.1 weight % are at-10 ℃, and promptly low temperature does not have the storage performance issue down.Therefore, water add that corrosion is effectively to the aluminium that caused by dry corrosion, but when at 120 ℃, promptly attempt under the high temperature when making water guarantee gratifying aluminium corrosion protection, the interpolation of water can cause the deterioration of storage stability.

In Fig. 7 name is called the prescription of " IN40-Me ", shown and added methyl alcohol replaces water as alcohol result.Under the situation of adding methyl alcohol, even also can obtain gratifying aluminium erosion resistance at 100 ℃ when add-on is 0.8 weight %, wherein low-temperature stability is also satisfactory.In addition, when add-on is 1.7 weight %,, and can improves the storage performance normal temperature and low temperature under and can under room temperature or low temperature, not cause a layer separation by adding methyl alcohol 120 ℃ of gratifying results that also can obtain the aluminium erosion resistance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Fig. 7 " IN40-Me " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.When the add-on of water with add water itself when identical, can improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 7 name is called the prescription of " IN40-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance is improved when add-on is 1.5 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 3.0 weight %, can obtains gratifying aluminium erosion resistance at 120 ℃, and can under room temperature or low temperature, not cause layer to separate by adding ethylene glycol can improve the storage performance under normal temperature and the low temperature.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethylene glycol of the interpolation shown in Fig. 7 " IN40-EG " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, ethylene glycol is to the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 7 name is called the prescription of " IN40-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding acetone separately, when add-on is 0.2 weight %, can obtain gratifying aluminium erosion resistance, and can obtain ambient stable and low-temperature stability at 100 ℃ and 120 ℃.Therefore, acetone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetone of the interpolation shown in Fig. 7 " IN40-Ac " and water combination, even the add-on of water reduces also to obtain gratifying aluminium erosion resistance, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation acetone.Therefore, acetone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 7 name is called the prescription of " IN40-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 1.5 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl-formiate of the interpolation shown in Fig. 7 " IN40-GM " and water combination, even the add-on of water reduces also to obtain gratifying aluminium erosion resistance, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl-formiate.Therefore, methyl-formiate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 7 name is called the prescription of " IN40-BA ", shown and added that butyraldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding butyraldehyde separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when being 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ when add-on at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the butyraldehyde of the interpolation shown in Fig. 7 " IN40-BA " and water combination, also can obtain gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, butyraldehyde is effective for the add-on that reduces water.

For " IN40-E ", promptly except that IN40, also contain the basic recipe of ether, use the mode identical with IN40, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde.The result as shown in figure 22.By result shown in Figure 22, also can obtain the effect identical even add ether with the situation of IN40, therefore, water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde also can be used in those prescriptions that contain ether effectively.

IN15 promptly has the Formulation Example 5 of the essentially consist that is made of 85 weight % petroleum naphthas, 10 weight % Virahols and 5 weight % propyl carbinols, wherein, and low in the ratio " IN40 " of alcohol.

When adding entry to 0.1 weight % and in IN15 when adding entry to 0.6 weight % for 120 ℃ at 90 ℃, for example, the weight loss that causes because of the aluminium corrosion disappears, and as shown in Figure 8, and erosion resistance improves.Yet, when water is added into 0.6 weight %, layer having occurred in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer at room temperature also occurred under the situation of 0.8 weight % to separate even be in the add-on of water, and those prescriptions that not add add-ons water or those water be 0.1 weight % are at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Fig. 8 name is called the prescription of " IN15-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, when being 0.5 weight %, add-on obtains gratifying aluminium erosion resistance at 100 ℃, and wherein low-temperature stability also makes us satisfactory.When add-on is 1.5 weight %, can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Fig. 8 " IN15-Me " and water combination, also can obtain gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is for the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 8 name is called the prescription of " IN15-PG ", shown and added propylene glycol replaces water as glycol result.Under the situation of adding propylene glycol, the aluminium erosion resistance was improved when add-on was 2.0 weight %, and wherein, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.Can obtain gratifying aluminium erosion resistance at 120 ℃ when add-on is 4.0 weight %, and can under room temperature and low temperature, not cause layer to separate by adding propylene glycol can improve normal temperature and cryogenic storage performance.Therefore, propylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propylene glycol of the interpolation shown in Fig. 8 " IN15-PG " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propylene glycol is effective for the add-on that reduces water.

In Fig. 8 name is called the prescription of " IN15-MBK ", shown and added that methyl iso-butyl ketone (MIBK) replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl iso-butyl ketone (MIBK) separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl iso-butyl ketone (MIBK) can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl iso-butyl ketone (MIBK) of the interpolation shown in Fig. 8 " IN15-MBK " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl iso-butyl ketone (MIBK).Therefore, methyl iso-butyl ketone (MIBK) is for the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 8 name is called the prescription of " IN15-GE ", shown and added that ethyl formate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding ethyl formate separately, when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 5.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethyl formate of the interpolation shown in Fig. 8 " IN15-GE " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the add-on of water reduce can also cause improving the storage stability of synthol under room temperature and low temperature.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation ethyl formate.Therefore, ethyl formate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Fig. 8 name is called the prescription of " IN15-PA ", shown and added that propionic aldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding propionic aldehyde separately, when add-on is 0.2 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.4 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, propionic aldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propionic aldehyde of the interpolation shown in Fig. 8 " IN15-PA " and water combination, even the add-on that reduces water also can obtain the corrosion protection of gratifying aluminium and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propionic aldehyde is effective for the add-on that reduces water.

For " IN15-E ", promptly except that IN15, also contain the basic recipe of ether, use the mode identical with IN15, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, propylene glycol, methyl iso-butyl ketone (MIBK), ethyl formate and propionic aldehyde.The result as shown in figure 23.By result shown in Figure 23, under the situation of adding ether, also can obtain the effect identical with the situation of IN15, water, methyl alcohol, propylene glycol, methyl iso-butyl ketone (MIBK), ethyl formate and propionic aldehyde also can be used in those prescriptions that contain ether effectively.

IN75 promptly has the Formulation Example 6 of the essentially consist that is made of 25 weight % petroleum naphthas, 35 weight % Virahols and 40 weight % propyl carbinols, and wherein Chun ratio is greater than above-mentioned " IN15 ".In IN75, as shown in Figure 9, observed the weight loss that the aluminium corrosion that causes because of dry corrosion identical in the situation with IN15 is caused.

Even the water with 0.1 weight % in the time of 90 ℃ is added among the IN75, because the alcohols total amount that is comprised in the fuel is up to about 75 weight %, so can't obtain gratifying aluminium erosion resistance.When the add-on of water reaches 0.2 weight %, when promptly surpassing total amount by alcohol and multiply by 0.002 resulting value 0.15 weight %, can obtain gratifying aluminium erosion resistance.In addition, under 120 ℃ temperature, when being added into 0.8 weight %, water can obtain gratifying aluminium erosion resistance at 120 ℃.Therefore, the interpolation of water is effective to the aluminium corrosion that is caused by dry corrosion.

In Fig. 9 name is called the prescription of " IN75-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, when being 0.1 weight %, add-on obtains gratifying aluminium erosion resistance at 100 ℃, and wherein low-temperature stability is also satisfactory.When add-on is 2.0 weight %,, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and low temperature storage stability 120 ℃ of gratifying results that can obtain the aluminium erosion resistance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl alcohol of the interpolation shown in Fig. 9 " IN75-Me " and water combination, can obviously see, by methyl alcohol is mixed with water, methyl alcohol with less content just can be guaranteed gratifying aluminium corrosion protection, and can guarantee gratifying storage stability simultaneously under room temperature and low temperature.Therefore, water is effective for the add-on that reduces methyl alcohol.

In Fig. 9 name is called the prescription of " IN75-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance improved when add-on was 3.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 6.0 weight %, can obtain gratifying aluminium erosion resistance, can under room temperature and low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance at 120 ℃.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the ethylene glycol of the interpolation shown in Fig. 9 " IN75-EG " and water combination, can obviously see, by ethylene glycol is mixed with water, ethylene glycol with less content just can be guaranteed gratifying aluminium corrosion protection, and can guarantee gratifying storage stability simultaneously under room temperature and low temperature.Therefore, water is effective for the add-on that reduces ethylene glycol.

In Fig. 9 name is called the prescription of " IN75-MPK ", shown and added that methyl n-propyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl n-propyl ketone separately, when add-on is 0.2 weight %, can obtain gratifying aluminium erosion resistance at 100 ℃ and 120 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl n-propyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl n-propyl ketone of the interpolation shown in Fig. 9 " IN75-MPK " and water combination, can obviously see, by methyl n-propyl ketone is mixed with water, methyl n-propyl ketone with less content just can be guaranteed gratifying aluminium corrosion protection, and can guarantee gratifying storage stability simultaneously under room temperature and low temperature.Therefore, water is effective for the add-on that reduces methyl n-propyl ketone.

In Fig. 9 name is called the prescription of " IN75-GE ", shown and added that ethyl formate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding ethyl formate separately, when add-on is 2.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 3.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Result by the ethyl formate of the interpolation shown in Fig. 9 " IN75-GE " and water combination, by ethyl formate is mixed with water, ethyl formate with less content just can be guaranteed gratifying aluminium corrosion protection, and can guarantee gratifying storage stability simultaneously under room temperature and low temperature.Therefore, water is effective for the add-on that reduces ethyl formate.

In Fig. 9 name is called the prescription of " IN75-AA ", shown and added that acetaldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding acetaldehyde separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.6 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, acetaldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the acetaldehyde of the interpolation shown in Fig. 9 " IN75-AA " and water combination, can obviously see, by acetaldehyde is mixed with water, acetaldehyde with less content just can obtain gratifying aluminium corrosion protection, and can obtain gratifying storage stability simultaneously under room temperature and low temperature.Therefore, water is effective for the add-on that reduces acetaldehyde.

For " IN75-E ", promptly except that IN75, also contain the basic recipe of ether, use the mode identical with IN75, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, methyl n-propyl ketone, ethyl formate and acetaldehyde.The result as shown in figure 24.By result shown in Figure 24, in the situation of adding ether, also can obtain the effect identical with the situation of IN75, water, methyl alcohol, ethylene glycol, methyl n-propyl ketone, ethyl formate and acetaldehyde also can be used in those prescriptions that contain ether effectively.

Next, EIB40 promptly has the Formulation Example 7 of the essentially consist that is made of 60 weight % petroleum naphthas, 20 weight % ethanol and 20 weight % isopropylcarbinols, and wherein employed alcohol is different with the prescription of IN40.In EIB40, as shown in figure 10, can observe the weight loss that the aluminium corrosion that because of dry corrosion cause identical with above-mentioned E50 and IN40 caused.

When at 90 ℃ with when in EIB40, adding entry to 0.1 weight % and 4.8 weight % respectively for 120 ℃, for example,, aluminium disappears because of corroding the weight loss that causes, and as shown in figure 10, and erosion resistance improves.Yet, when water is added into 4.8 weight %, layer having occurred in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer at room temperature also occurred under the situation of 5.1 weight % to separate even be in the add-on of water, and the prescription that those add-ons of not adding water or water are 0.1 weight % is at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 10 name is called the prescription of " EIB40-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, even also can obtain gratifying aluminium erosion resistance at 100 ℃ when add-on is 1.5 weight %, wherein low-temperature stability is also satisfactory.When add-on is 2.0 weight %, can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 10 " EIB40-Me " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, methyl alcohol is effective for the add-on that reduces water.

In Figure 10 name is called the prescription of " EIB40-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance is improved when add-on is 1.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 2.0 weight %, also can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethylene glycol of the interpolation shown in Fig. 7 " EIB40-EG " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, ethylene glycol is effective for the add-on that reduces water.

In Figure 10 name is called the prescription of " EIB40-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding acetone separately, the aluminium erosion resistance is improved when add-on is 0.2 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 3.0 weight %,, and can obtains the gratifying result of normal temperature and low temperature storage stability and can under room temperature or low temperature, not cause layer to separate 120 ℃ of gratifying results that also can obtain the aluminium erosion resistance.Therefore, acetone can be used as the aluminium corrosion inhibitor satisfactorily.

Result by the acetone of the interpolation shown in Figure 10 " EIB40-Ac " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation acetone.Therefore, acetone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 10 name is called the prescription of " EIB40-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 2.5 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 5.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl-formiate of the interpolation shown in Figure 10 " EIB40-GM " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl-formiate.Therefore, methyl-formiate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 10 name is called the prescription of " EIB40-BA ", shown and added that butyraldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding butyraldehyde separately, when add-on is 0.6 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the butyraldehyde of the interpolation shown in Figure 10 " EIB40-BA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation butyraldehyde.Therefore, butyraldehyde is for the add-on that reduces water and to improve low-temperature stability be effective.

For " EIB40-E ", promptly except that EIB40, also contain the basic recipe of ether, use the mode identical with EIB40, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde.The result as shown in figure 25.Can see obviously that from result shown in Figure 25 also can obtain the effect identical with the situation of EIB40 in the situation of adding ether, water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde also can be used in those prescriptions that contain ether effectively.

EIB15 promptly has the Formulation Example 8 of the essentially consist that is made of 85 weight % petroleum naphthas, 5 weight % ethanol and 10 weight % isopropylcarbinols, and wherein employed alcohol is different with the prescription of IN15.In EIB15, can observe the weight loss that the aluminium corrosion that because of dry corrosion cause identical with above-mentioned E10 and IN15 caused as shown in figure 11.

When at 90 ℃ with when in EIB15, adding entry to 0.1 weight % and 0.6 weight % respectively for 120 ℃, for example,, aluminium disappears because of corroding the weight loss that causes, and as shown in figure 11, and erosion resistance improves.Yet, when water is added into 0.6 weight %, layer having occurred in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer at room temperature also occurred under the situation of 0.8 weight % to separate even be in the add-on of water, and those prescriptions that not add add-ons water or those water be 0.1 weight % are at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 11 name is called the prescription of " EIB15-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the aluminium erosion resistance is improved when add-on is 1.0 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 1.5 weight %,, can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that can obtain the aluminium erosion resistance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 11 " EIB15-Me " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, methyl alcohol has the effect of the add-on that reduces water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is for the add-on that reduces water and to improve low-temperature stability be effective.

In the prescription of the prescription " EIB15-PG " of Figure 11, shown and added propylene glycol replaces water as glycol result.Under the situation of adding propylene glycol, the aluminium erosion resistance was improved when add-on was 1.5 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.Also can be when add-on is 3.0 weight % 120 ℃ of gratifying results that obtain the aluminium erosion resistance, can under room temperature or low temperature, not cause layer to separate by adding propylene glycol can improve normal temperature and cryogenic storage performance.Therefore, propylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propylene glycol of the interpolation shown in Figure 11 " EIB15-PG " and water combination, can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propylene glycol is effective for the add-on that reduces water.

In Figure 11 name is called the prescription of " EIB15-DEK ", shown and added that diethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding diethyl ketone separately, the aluminium erosion resistance was improved when add-on was 1.0 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When being 1.5 weight %, add-on, can under room temperature or low temperature, not cause layer to separate by adding diethyl ketone can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that yet can obtain the aluminium erosion resistance.Therefore, diethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily

Can obviously see from the result of the diethyl ketone of the interpolation shown in Figure 11 " EIB15-DEK " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation diethyl ketone.Therefore, diethyl ketone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 11 name is called the prescription of " EIB15-SM ", shown and added that methyl acetate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl acetate separately, when add-on is 2.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl acetate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl acetate of the interpolation shown in Figure 11 " EIB15-SM " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl acetate.Therefore, methyl acetate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 11 name is called the prescription of " EIB15-PA ", shown and added that propionic aldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding propionic aldehyde separately, when add-on is 0.6 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, propionic aldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propionic aldehyde of the interpolation shown in Figure 11 " EIB15-PA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propionic aldehyde is effective for the add-on that reduces water.

For " EIB15-E ", promptly except that EIB15, also contain the basic recipe of ether, use the mode identical with EIB15, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, propylene glycol, diethyl ketone, methyl acetate and propionic aldehyde.The result as shown in figure 26.Can find out obviously that from result shown in Figure 26 also can obtain the effect identical with the situation of EIB15 in the situation of adding ether, water, methyl alcohol, propylene glycol, diethyl ketone, methyl acetate and propionic aldehyde also can be used in those prescriptions that contain ether effectively.

EIB75 promptly has the Formulation Example 9 of the essentially consist that is made of 25 weight % petroleum naphthas, 35 weight % ethanol and 40 weight % isopropylcarbinols, wherein compares with EIB40, and the ratio of alcohol increases.In EIB75, as shown in figure 12, also can observe the weight loss that the aluminium corrosion that because of dry corrosion cause identical with the situation of EIB40 caused.

Even be added among the EIB75, because the pure total amount that is comprised in the fuel is up to about 75 weight %, so can't obtain gratifying aluminium erosion resistance at 90 ℃ of water with 0.1 weight %.When the add-on of water reaches 0.2 weight %, when promptly surpassing total amount by alcohol and multiply by 0.002 resulting value 0.15 weight %, can obtain gratifying aluminium erosion resistance.In addition, at 120 ℃, when being added into 1.2 weight %, water can obtain gratifying aluminium erosion resistance at 120 ℃.Therefore, the interpolation of water is effective to the aluminium corrosion that is caused by dry corrosion.

In Figure 12 name is called the prescription of " EIB75-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the aluminium erosion resistance is improved when add-on is 1.5 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.Also can obtain gratifying aluminium erosion resistance at 120 ℃ when add-on is 2.0 weight %, can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and cryogenic storage performance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl alcohol of the interpolation shown in Figure 11 " EIB75-Me " and water combination, can obviously see, by methyl alcohol is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the methyl alcohol of less content.Therefore, glassware for drinking water has the effect that reduces the methyl alcohol add-on.

In Figure 12 name is called the prescription of " EIB75-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance was improved when add-on was 3.0 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 5.0 weight %, also can obtain gratifying aluminium erosion resistance, can under room temperature or low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance at 120 ℃.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the ethylene glycol of the interpolation shown in Figure 12 " EIB75-EG " and water combination, can obviously see, by ethylene glycol is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the ethylene glycol of less content.Therefore, glassware for drinking water has the effect that reduces the ethylene glycol add-on.

In Figure 12 name is called the prescription of " EIB75-MEK ", shown and added that methyl ethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl ethyl ketone separately, when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 5.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl ethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl ethyl ketone of the interpolation shown in Figure 12 " EIB75-MEK " and water combination, can obviously see, by methyl ethyl ketone is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the methyl ethyl ketone of less content.Therefore, water is effective for the add-on that reduces methyl ethyl ketone.

In Figure 12 name is called the prescription of " EIB75-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 4.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 8.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl-formiate of the interpolation shown in Figure 12 " EIB75-GM " and water combination, can obviously see, by methyl-formiate is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the methyl-formiate of less content.Therefore, glassware for drinking water has the effect that reduces the methyl-formiate add-on.

In Figure 12 name is called the prescription of " EIB75-AA ", shown and added that acetaldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding acetaldehyde separately, when add-on is 0.8 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, acetaldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the acetaldehyde of the interpolation shown in Figure 12 " EIB75-AA " and water combination, can obviously see, by methyl alcohol is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the acetaldehyde of less content.Therefore, glassware for drinking water has the effect that reduces the acetaldehyde add-on.

For " EIB75-E ", promptly except that EIB75, also contain the basic recipe of ether, use the mode identical with EIB75, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, methyl ethyl ketone, methyl-formiate and acetaldehyde.The result as shown in figure 27.Can see obviously that from result shown in Figure 27 also can obtain the effect identical with the situation of EIB75 under the situation of adding ether, water, methyl alcohol, ethylene glycol, methyl ethyl ketone, methyl-formiate and acetaldehyde also can be used in those prescriptions that contain ether effectively.

PNB30 promptly has the Formulation Example 10 of the essentially consist that is made of 70 weight % petroleum naphthas, 10 weight % Virahols, 10 weight % propyl carbinols and 10 weight % isopropylcarbinols, has wherein used three kinds of alcohol.

When 80 ℃ and 120 ℃ respectively when PNB30 adds entry to 0.1 weight % and 1.8 weight %, the weight loss that causes because of the aluminium corrosion disappears, as shown in figure 13, and erosion resistance improves.Yet, when water is added into 1.8 weight %, layer having occurred in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, add-on at water is under the situation of 2.0 weight %, separate even layer at room temperature also occurred, and those prescriptions that not add add-ons water or those water be 0.1 weight % are at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 13 name is called the prescription of " PNB30-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, obtain gratifying aluminium erosion resistance at 100 ℃ when add-on is 1.0 weight %, and its low-temperature stability is also satisfactory.When add-on is 1.5 weight %, can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol also can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 13 " PNB30-Me " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 13 name is called the prescription of " PNB30-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance improved when add-on was 2.0 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 2.5 weight %, also can obtain gratifying aluminium erosion resistance, can under room temperature or low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance at 120 ℃.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethylene glycol of the interpolation shown in Figure 13 " PNB30-EG " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, ethylene glycol is effective for the add-on that reduces water.

In Figure 13 name is called the prescription of " PNB30-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding acetone separately, when add-on is 0.2 weight %, obtain gratifying aluminium erosion resistance at 100 ℃ and 120 ℃.In addition, can obtain gratifying ambient stable and low-temperature stability.Therefore, acetone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetone of the interpolation shown in Figure 13 " PNB30-Ac " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation acetone.Therefore, acetone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 13 name is called the prescription of " PNB30-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 1.5 weight %, obtained gratifying aluminium erosion resistance, and when add-on is 2.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl-formiate of the interpolation shown in Figure 13 " PNB30-GM " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl-formiate.Therefore, methyl-formiate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 13 name is called the prescription of " PNB30-BA ", shown and added that butyraldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding butyraldehyde separately, when add-on is 0.4 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the butyraldehyde of the interpolation shown in Figure 13 " PNB30-BA " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, butyraldehyde is effective for the add-on that reduces water.

For " PNB30-E ", promptly except that PNB30, also contain the basic recipe of ether, use the mode identical with PNB30, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde.The result as shown in figure 28.Can see obviously that from result shown in Figure 28 also can obtain the effect identical with the situation of PNB30 in the situation of adding ether, water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde also can be used in those prescriptions that contain ether effectively.

PNB15 promptly has the Formulation Example 11 of the essentially consist that is made of 85 weight % petroleum naphthas, 5 weight % Virahols, 5 weight % propyl carbinols and 5 weight % isopropylcarbinols, wherein to have used three kinds of alcohol than small proportion.In PNB15, as shown in figure 14, observed with other Formulation Examples in the identical weight loss that caused of the aluminium corrosion that causes by dry corrosion.

When at 80 ℃ with add entry to 0.1 weight % (120 hours treatment times) and 0.5 weight % when (24 hours treatment times) to PNB15 respectively at 120 ℃, the weight loss that causes because of the aluminium corrosion disappears, and as shown in figure 14, and erosion resistance improves.Yet, when water is added into 0.5 weight %, layer having occurred in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer also occurred in room temperature under the situation of 0.7 weight % to separate even be in the add-on of water, and those prescriptions that not add add-ons water or those water be 0.1 weight % are at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 14 name is called the prescription of " PNB15-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the aluminium erosion resistance was improved when add-on was 0.8 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.Also can obtain gratifying aluminium erosion resistance at 120 ℃ when add-on is 1.5 weight %, can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and cryogenic storage performance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 14 " PNB15-Me " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 14 name is called the prescription of " PNB15-PG ", shown and added propylene glycol replaces water as glycol result.Under the situation of adding propylene glycol, the aluminium erosion resistance was improved when add-on was 3.0 weight %, even also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.Also can obtain gratifying aluminium erosion resistance at 120 ℃ when add-on is 4.0 weight %, can under room temperature or low temperature, not cause layer to separate by adding propylene glycol can improve normal temperature and cryogenic storage performance.Therefore, propylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propylene glycol of the interpolation shown in Figure 14 " PNB15-PG " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propylene glycol is effective for the add-on that reduces water.

In Figure 14 name is called the prescription of " PNB15-MPK ", shown and added that methyl n-propyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl n-propyl ketone separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl n-propyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl n-propyl ketone of the interpolation shown in Figure 14 " PNB15-MPK " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by interpolation methyl n-propyl ketone.Therefore, methyl n-propyl ketone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 14 name is called the prescription of " PNB15-SM ", shown and added that methyl acetate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl acetate separately, when add-on is 1.5 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 6.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, methyl acetate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl acetate of the interpolation shown in Figure 14 " PNB15-SM " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl acetate.Therefore, methyl acetate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 14 name is called the prescription of " PNB15-AA ", shown and added that acetaldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding acetaldehyde separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain the gratifying result of ambient stable and low-temperature stability.Therefore, acetaldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetaldehyde of the interpolation shown in Figure 14 " PNB15-AA " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, acetaldehyde is effective for the add-on that reduces water.

For " PNB15-E ", promptly except that PNB15, also contain the basic recipe of ether, use the mode identical with PNB15, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, propylene glycol, methyl n-propyl ketone, methyl acetate and acetaldehyde.The result as shown in figure 29.Can obviously see from result shown in Figure 29, also can obtain the effect identical with the situation of PNB15 in the situation of adding ether, water, methyl alcohol, propylene glycol, methyl n-propyl ketone, methyl acetate and acetaldehyde also can be used in those prescriptions that contain ether effectively.

PNB75 promptly has the Formulation Example 12 of the essentially consist that is made of 25 weight % petroleum naphthas, 25 weight % Virahols, 25 weight % propyl carbinols and 25 weight % isopropylcarbinols, has wherein used three kinds of alcohol with the pure ratio of height.

Even be added into (120 hours treatment times) among the PNB75, because the total content of the alcohol that is comprised in the fuel is up to about 75 weight %, so can't obtain gratifying aluminium erosion resistance at 80 ℃ of water with 0.1 weight %.When the add-on of water reaches 0.2 weight %, when promptly surpassing total amount by alcohol and multiply by 0.002 resulting value 0.15 weight %, can obtain gratifying aluminium erosion resistance.When with water for example, (24 hours treatment times) can obtain gratifying aluminium erosion resistance when being added into 10.0 weight % for 120 ℃.Yet, layer having occurred when water is added into 10.0 weight % in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, even layer at room temperature also having occurred in the add-on of water is the situation of 10.5 weight % separates, and the prescription that those add-ons of not adding water or water are 0.1 weight % or 0.2 weight % is at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 15 name is called the prescription of " PNB75-Me ", shown and added the result that methyl alcohol replaces water.Adding under the situation of methyl alcohol, even also can obtain gratifying aluminium erosion resistance at 100 ℃ when add-on is 1.0 weight %, wherein low-temperature stability is also satisfactory.When add-on is 2.0 weight %, also can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol also can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 15 " PNB75-Me " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl alcohol.Therefore, methyl alcohol is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 15 name is called the prescription of " PNB75-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance was improved when add-on was 4.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.In addition, when add-on is 6.0 weight %,, can under room temperature and low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that can obtain the aluminium erosion resistance.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethylene glycol of the interpolation shown in Figure 15 " PNB75-EG " and water combination, also can guarantee gratifying aluminium erosion resistance even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, ethylene glycol is effective for the add-on that reduces water.

In Figure 15 name is called the prescription of " PNB75-MEK ", shown and added that methyl ethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl ethyl ketone separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl ethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl ethyl ketone of the interpolation shown in Figure 15 " PNB75-MEK " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl ethyl ketone.Therefore, methyl ethyl ketone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 15 name is called the prescription of " PNB75-GE ", shown and added that ethyl formate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding ethyl formate separately, when add-on is 4.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 6.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, ethyl formate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethyl formate of the interpolation shown in Figure 15 " PNB75-GE " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation ethyl formate.Therefore, ethyl formate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 15 name is called the prescription of " PNB75-PA ", shown and added that propionic aldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding propionic aldehyde separately, when add-on is 0.3 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, propionic aldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propionic aldehyde of the interpolation shown in Figure 15 " PNB75-PA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propionic aldehyde is effective for the add-on that reduces water.

For " PNB75-E ", promptly except that PNB75, also contain the basic recipe of ether, use the mode identical with PNB75, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, methyl ethyl ketone, ethyl formate and propionic aldehyde.The result as shown in figure 30.Can see obviously that from result shown in Figure 30 also can obtain the effect identical with the situation of PNB75 in the situation of adding ether, water, methyl alcohol, ethylene glycol, methyl ethyl ketone, ethyl formate and propionic aldehyde also can be used in those prescriptions that contain ether effectively.

EIPP30 promptly has the Formulation Example 13 of the essentially consist that is made of 70 weight % petroleum naphthas, 10 weight % ethanol, 10 weight % Virahols and 10 weight %1-amylalcohols, and wherein the combination of Chun kind is different with PNB30.

When at 80 ℃ with add entry to 0.1 weight % (120 hours treatment times) and 2.5 weight % when (24 hours treatment times) to EIPP30 respectively at 120 ℃, for example, the weight loss that causes because of the aluminium corrosion disappears, and as shown in figure 16, and erosion resistance improves.Yet, layer having occurred when water is added into 2.5 weight % in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer at room temperature also occurred under the situation of 3.0 weight % to separate even be in the add-on of water, and those do not add add-on water or water be 0.1 weight % at-10 ℃, i.e. the following no inventory problem of low temperature.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 16 name is called the prescription of " EIPP30-Me ", shown and added the result that methyl alcohol replaces water.In adding the situation of methyl alcohol, even also can obtain gratifying aluminium erosion resistance at 100 ℃ when add-on is 1.5 weight %, wherein low-temperature stability is also satisfactory.When add-on is 2.5 weight %, can obtain gratifying aluminium erosion resistance, and can under room temperature or low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and low temperature storage stability at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 16 " EIPP30-Me " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, methyl alcohol is effective for the add-on that reduces water.

In Figure 16 name is called the prescription of " EIPP30-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance improved when add-on was 2.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 5.0 weight %,, can under room temperature and low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that can obtain the aluminium erosion resistance.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the ethylene glycol of the interpolation shown in Figure 16 " EIPP30-EG " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, ethylene glycol is effective for the add-on that reduces water.

In Figure 16 name is called the prescription of " EIPP30-Ac ", shown and added that acetone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding acetone separately, when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 4.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, acetone can make us satisfactorily as the aluminium corrosion inhibitor.

Can obviously see from the result of the acetone of the interpolation shown in Figure 16 " EIPP30-Ac " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation acetone.Therefore, acetone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 16 name is called the prescription of " EIPP30-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 1.5 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 6.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl-formiate of the interpolation shown in Figure 16 " EIPP30-GM " and water combination, even the add-on that reduces water also can be guaranteed the anti-corrosion protective of gratifying aluminium and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl-formiate.Therefore, methyl-formiate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 16 name is called the prescription of " EIPP30-BA ", shown and added that butyraldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding butyraldehyde separately, when add-on is 0.6 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, butyraldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the butyraldehyde of the interpolation shown in Figure 16 " EIPP30-BA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, butyraldehyde is for the add-on that reduces water and to improve low-temperature stability be effective.

For " EIPP30-E ", promptly except that EIPP30, also contain the basic recipe of ether, use the mode identical with EIPP30, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde.The result as shown in figure 31.Know that from result shown in Figure 31 also can obtain the effect identical with the situation of EIPP30 in the situation of adding ether, water, methyl alcohol, ethylene glycol, acetone, methyl-formiate and butyraldehyde also can be used in those prescriptions that contain ether effectively.

EIPP15 promptly has the Formulation Example 14 of the essentially consist that is made of 85 weight % petroleum naphthas, 5 weight % ethanol, 5 weight % Virahols and 5 weight %1-amylalcohols, and wherein the combination of Chun sharp class is different with above-mentioned PNB30, and the ratio of alcohol it is little.

When at 80 ℃ with add entry to 0.1 weight % (120 hours treatment times) and 0.8 weight % when (24 hours treatment times) at 120 ℃ to EIPP15, the weight loss that causes because of the aluminium corrosion disappears, and as shown in figure 17, and erosion resistance improves.Yet, layer having occurred when water is added into 0.8 weight % in-10 ℃ low temperature storage performance test separates, do not occur corroding the weight loss that causes at 120 ℃ because of aluminium, layer at room temperature also occurred under the situation of 1.0 weight % to separate even be in the add-on of water, and those prescriptions that not add add-on water or water be 0.1 weight % are at-10 ℃, i.e. low temperature no inventory problem down.Therefore, corrosion is effectively to the aluminium that caused by dry corrosion in the interpolation of water, but when at 120 ℃, promptly attempts under the high temperature when making water guarantee gratifying aluminium corrosion protection, and the interpolation of water can cause the deterioration of storage stability.

In Figure 17 name is called the prescription of " EIPP15-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the aluminium erosion resistance improved when add-on was 1.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 2.0 weight %,, can under room temperature and low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that yet can obtain the aluminium erosion resistance.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl alcohol of the interpolation shown in Figure 17 " EIPP15-Me " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, methyl alcohol is effective for the add-on that reduces water.

In Figure 17 name is called the prescription of " EIPP15-PG ", shown and added propylene glycol replaces water as glycol result.Under the situation of adding propylene glycol, the aluminium erosion resistance improved when add-on was 2.5 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 4.0 weight %,, can under room temperature and low temperature, not cause layer to separate by adding propylene glycol can improve normal temperature and cryogenic storage performance 120 ℃ of gratifying results that yet can obtain the aluminium erosion resistance.Therefore, propylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propylene glycol of the interpolation shown in Figure 17 " EIPP15-PG " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propylene glycol is effective for the add-on that reduces water.

In Figure 17 name is called the prescription of " EIPP15-DEK ", shown and added that diethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding diethyl ketone separately, when add-on is 2.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, diethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the diethyl ketone of the interpolation shown in Figure 17 " EIPP15-DEK " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation diethyl ketone.Therefore, diethyl ketone is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 14 name is called the prescription of " EIPP15-SM ", shown and added that methyl acetate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl acetate separately, when add-on is 1.2 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 4.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl acetate can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the methyl acetate of the interpolation shown in Figure 17 " EIPP15-SM " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.In addition, when the add-on of water with add water itself when identical, can also improve the low-temperature stability of gained liquid fuel by further interpolation methyl acetate.Therefore, methyl acetate is for the add-on that reduces water and to improve low-temperature stability be effective.

In Figure 14 name is called the prescription of " EIPP15-PA ", shown and added that propionic aldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding propionic aldehyde separately, when add-on is 0.5 weight %, obtain gratifying aluminium corrosion protection, and when add-on is 0.8 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, propionic aldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the propionic aldehyde of the interpolation shown in Figure 17 " EIPP15-PA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, propionic aldehyde is effective for the add-on that reduces water.

For " EIPP15-E ", promptly except that EIPP15, also contain the basic recipe of ether, use the mode identical with EIPP15, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, propylene glycol, diethyl ketone, methyl acetate and propionic aldehyde.The result shown in figure 32.Can see obviously that from result shown in Figure 32 also can obtain the effect identical with the situation of EIPP15 in the situation of adding ether, water, methyl alcohol, propylene glycol, diethyl ketone, methyl acetate and propionic aldehyde also can be used in those prescriptions that contain ether effectively.

EIPP75 promptly has the Formulation Example 15 of the essentially consist that is made of 25 weight % petroleum naphthas, 25 weight % ethanol, 25 weight % Virahols and 25 weight %1-amylalcohols, wherein with the pure ratio of height use with PNB75 in three kinds of different alcohol.In EIPP75, as shown in figure 18, also can observe the weight loss that the aluminium corrosion that is caused by dry corrosion identical in the situation with EIPP15 is caused.

Even in EIPP75, add entry to 0.1 weight % (120 hours treatment times) at 80 ℃ and since in the fuel total content of the alcohol that comprised up to about 75 weight %, so can't obtain gratifying aluminium erosion resistance, as shown in figure 18.When the add-on of water reaches 0.2 weight %, when promptly surpassing total amount by alcohol and multiply by 0.002 resulting value 0.15 weight %, can obtain gratifying aluminium erosion resistance.In addition, under 120 ℃ temperature, when being added into 1.7 weight %, water can obtain gratifying aluminium erosion resistance at 120 ℃.Therefore, the interpolation of water is effective to the aluminium corrosion that is caused by dry corrosion.

In Figure 18 name is called the prescription of " EIPP75-Me ", shown and added the result that methyl alcohol replaces water.Under the situation of adding methyl alcohol, the aluminium erosion resistance improved when add-on was 2.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.When add-on is 3.0 weight %, also can obtain gratifying aluminium erosion resistance, can under room temperature and low temperature, not cause layer to separate by adding methyl alcohol can improve normal temperature and cryogenic storage performance at 120 ℃.Therefore, methyl alcohol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl alcohol of the interpolation shown in Figure 18 " EIPP75-Me " and water combination, can obviously see, by methyl alcohol is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the methyl alcohol of less content.Therefore, water is effective for the add-on that reduces methyl alcohol.

In Figure 18 name is called the prescription of " EIPP75-EG ", shown and added ethylene glycol replaces water as glycol result.Under the situation of adding ethylene glycol, the aluminium erosion resistance improved when add-on was 4.0 weight %, even wherein also can obtain gratifying aluminium erosion resistance at 100 ℃, and low-temperature stability is also satisfactory.In addition, when add-on is 8.0 weight %, can obtain gratifying aluminium erosion resistance, can under room temperature and low temperature, not cause layer to separate by adding ethylene glycol can improve normal temperature and cryogenic storage performance at 120 ℃.Therefore, ethylene glycol can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the ethylene glycol of the interpolation shown in Figure 18 " EIPP75-EG " and water combination, can obviously see, by methyl alcohol is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the ethylene glycol of less content.Therefore, water is effective for the add-on that reduces ethylene glycol.

In Figure 18 name is called the prescription of " EIPP75-MEK ", shown and added that methyl ethyl ketone replaces the result of water as ketone and its result with water combination interpolation.Do not add under the situation of water adding methyl ethyl ketone separately, when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 5.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl ethyl ketone can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl ethyl ketone of the interpolation shown in Figure 18 " EIPP75-MEK " and water combination, can obviously see, by methyl ethyl ketone is mixed with water, methyl ethyl ketone with less content just can obtain gratifying aluminium corrosion protection, and also can with room temperature and low temperature under gratifying storage stability.Therefore, water is effective for the add-on that reduces methyl ethyl ketone.

In Figure 18 name is called the prescription of " EIPP75-GM ", shown and added that methyl-formiate replaces the result of water as ester and its result with water combination interpolation.Do not add under the situation of water adding methyl-formiate separately, when add-on is 3.0 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 9.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, methyl-formiate can be used as the aluminium corrosion inhibitor satisfactorily.

From the result of the methyl-formiate of the interpolation shown in Figure 18 " EIPP75-GM " and water combination, can obviously see, by methyl-formiate is mixed with water, just can obtain gratifying storage stability under gratifying aluminium corrosion protection and room temperature and the low temperature with the methyl-formiate of less content.Therefore, water is effective for the add-on that reduces methyl-formiate.

In Figure 18 name is called the prescription of " EIPP75-AA ", shown and added that acetaldehyde replaces the result of water as aldehyde and its result with water combination interpolation.Do not add under the situation of water adding acetaldehyde separately, when add-on is 0.5 weight %, obtain gratifying aluminium erosion resistance, and when add-on is 1.0 weight %, obtain gratifying aluminium erosion resistance at 120 ℃ at 100 ℃.In addition, in two kinds of prescriptions, all can obtain gratifying ambient stable and low-temperature stability.Therefore, acetaldehyde can be used as the aluminium corrosion inhibitor satisfactorily.

Can obviously see from the result of the acetaldehyde of the interpolation shown in Figure 18 " EIPP75-AA " and water combination, also can guarantee gratifying aluminium corrosion protection even reduce the add-on of water, and the improvement that reduces to cause the storage stability of gained fuel under room temperature and low temperature of the add-on of water.Therefore, acetaldehyde is effective for the add-on that reduces water.

For " EIPP75-E ", promptly except that EIPP75, also contain the basic recipe of ether, use the mode identical with EIPP75, test aluminium erosion resistance and storage stability by adding water, methyl alcohol, ethylene glycol, methyl ethyl ketone, methyl-formiate and acetaldehyde.The result as shown in figure 33.Can obviously see from result shown in Figure 33, also can obtain the effect identical with the situation of EIPP75 in the situation of adding ether, water, methyl alcohol, ethylene glycol, methyl ethyl ketone, methyl-formiate and acetaldehyde also can be used in those prescriptions that contain ether effectively.

Above embodiments of the invention have been described based on Fig. 3～34.In Figure 35, summed up the addition effect of water and every kind of aluminium corrosion inhibitor in each prescription.

As shown in figure 35, methyl alcohol, glycol, ketone, ester and aldehyde used to provide by independent interpolation as the aluminium corrosion inhibitor prevent aluminium corrosive effect, or by reducing the water that is added and the add-on that reduces water provides the effect of improving storage stability.Therefore, by using these materials, can obtain aluminium corrosion protection more excellence and the more stable fuel of storage stability.

In addition, can confirm aluminium corrosive protection effect by adding water in all prescriptions, this interpolation that shows water is to preventing that the aluminium corrosion from being effective.

Amount for water to be added, as shown in the example of the interpolation water in the Formulation Example 0～15, by (wherein the ratio of alcohol is lower than 50 weight % in the gained liquid fuel) interpolation 0.1 weight % or more water, can guarantee to wait under the low temperature the corrosive effect at 80 ℃ in zone with low pure ratio.Yet, the water that adds 0.1 weight % in some cases can not prevent the weight loss that causes because of corrosion, when the ratio of alcohol is 50 weight % or when bigger, as shown in IN75, EIB75, PNB75 and EIPP75, just can prevent to corrode the weight loss that causes by the water that adds 0.2 weight %.From this fact, the ratio when alcohol of it is believed that is 50 weight % or when bigger, is 0.1 weight %～0.2 weight % according to the minimum add-on of the ratio water of alcohol.Therefore, carried out validation test as shown in figure 37.

In this validation test, as shown in figure 37, use the formula I PB75 that constitutes by 25 weight % petroleum naphthas, 35 weight % Virahols and 35 weight % isopropylcarbinols, carry out the aluminium corrosion test by the add-on that changes water with 0.05 weight %.

As shown in figure 37, in the result, the weight loss that similarly caused because of corrosion in the situation with IN75, EIB75, PNB75 and EIPP75 has taken place in the add-on of water when being 0.1 weight %, with respect to 75 weight % (ratio of alcohol), this amount is equivalent to 0.13%, and the weight loss that is caused does not appear corroding when adding the water of 0.15 weight %, with respect to 75 weight % (ratio of alcohol), this amount is equivalent to 0.2% (=part by weight * 0.002).Therefore, when the ratio of alcohol is 50 weight % or when bigger, with respect to the ratio of alcohol, the addition of water can be for more than or equal to 0.2% (=part by weight * 0.002).

Because the interpolation of water itself can cause the deterioration of aforesaid low-temperature stability or room temperature stability, so based on the environment for use of gained fuel etc., the upper limit of the add-on of water to be added is set at the minimum value that aluminium corrosion prevention effect can be provided.

Though by the above embodiments preferred implementation of the present invention is described, the present invention is not limited to these embodiment.Can carry out the implication that equates with claim and the various variations in the scope arbitrarily or replenish, or interpolation can significantly not change interior other crude fuels or the additive (comprising metal etc.) of scope of the characteristic of combustion engine fuel of the present invention, obviously the present invention includes this area, i.e. technician in the gained combustion engine fuel field.

In the above embodiments, mainly Fuel Petroleum is described, but the present invention is not limited to Fuel Petroleum, and other oil engines that use diesel oil etc. also are suitable for.

Claims

1. liquid fuel for IC engine, this liquid fuel contains the hydrocarbon components of pure composition and the 15 weight %～98 weight % of 2 weight %～85 weight %, described pure composition is aliphatic monobasic alcohol itself or its mixture that per molecule has 2～6 carbon atoms, wherein, when the pure composition in the described liquid fuel for IC engine is N weight %, be more than or equal to 0.1 weight % of 0.002 * N weight % or gained oil engine usefulness synthetic liquid fuel the greater in the two to the water yield that wherein adds.

2. liquid fuel for IC engine as claimed in claim 1, wherein said liquid fuel for IC engine contain at least a ether composition, and described ether composition per molecule has and is no more than 12 carbon atoms and has an ehter bond at least in molecule.

3. liquid fuel for IC engine, this liquid fuel contains the hydrocarbon components of pure composition and the 15 weight %～98 weight % of 2 weight %～85 weight %, described pure composition is aliphatic monobasic alcohol itself or its mixture that per molecule has 2～6 carbon atoms, wherein, the gained oil engine contains the aluminium corrosion inhibitor that can suppress aluminium corrosive amount under temperature given in advance with synthetic liquid fuel, and described aluminium corrosion inhibitor comprises and is selected from the glycols hydrocarbon polymer, the ketone hydrocarbon polymer, at least a composition in ester hydrocarbon and the aldehydes hydrocarbon polymer.

4. liquid fuel for IC engine as claimed in claim 3 wherein contains water at least as described aluminium corrosion inhibitor.

5. as claim 3 or 4 described liquid fuel for IC engine, wherein said liquid fuel for IC engine contains at least a ether composition, and described ether composition per molecule has and is no more than 12 carbon atoms and has an ehter bond at least in molecule.