CN1322599C - Novel wide temperature domain giant magnetostriction material and its preparing method - Google Patents
Novel wide temperature domain giant magnetostriction material and its preparing method Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 73
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- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 10
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- 238000010438 heat treatment Methods 0.000 claims description 9
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 9
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Abstract
The present invention discloses a novel wide temperature range giant magnetostrictive material, which has the following chemical formula: Tb#-[x]Dy#-[1-x](Fe#-[1-y]T#-[y]) #-[z], wherein X=0.01-0.43, y=0-0.30, z=1.50-2.00, T stands for the four elements: Cr, V, Co and Ni, the spin reorientation temperature of alloy is changed by a method that the proportion of the elements of Tb and Dy is adjusted and alloy elements ni Cr, V, Co and Ni are added, and the material reduces the temperature coefficient of the giant magnetostrictive material. The material of the present invention can be adapted to the requirement of aerospace space environment for large temperature change of day and night, and the material can be used for making elements for the automatic calibration of the shapes of space station reflectors, the automatic adjustment of the position of solar energy cells and the active vibration control of large-sized structural member.
Description
Technical field
The present invention relates to a kind of can be in wide temperature range (80 ℃～150 ℃) have Rare-Earth Giant Magnetostrictive Materials and this preparation methods thereof of good Magnetostrictive Properties.
Background technology
The variation of shape or size can take place in ferromagnet under the effect in magnetic field, this phenomenon is called as magnetostriction.People are according to this phenomenon exploitation and developed different types of magnetostrictive material, comprise early stage Ni-Fe-Co series and the RFe that has widely studied since the seventies
2Be alloy (R is a rare earth element, as Pr, Tb, Dy, Sm, Ho etc.), the latter is called as giant magnetostriction material owing to having very big saturation magnetostriction coefficient.But, TbFe
2And DyFe
2All have very big magnetocrystalline anisotropy energy, need very strong magnetic field just can make it saturated, differ greatly with requirement of actual application.Thereafter the ternary RE iron compound of developing utilizes two kinds of opposite compound R Fe of magnetocrystalline anisotropy constant
2And R ' Fe
2Compensation forms a kind of pseudo-binary compound R mutually
xR '
1-xFe
2, both having had great saturation magnetostriction coefficient, can in lower magnetic field, use again.
Be widely used in the Terfenol-D in high power low-frequency sonar system, the quick micro-displacement actuator of high accuracy and the vibration active control system, its chemical formula is Tb
0.27Dy
0.73Fe
1.95Its magnetocrystalline anisotropy constant is K
1=0.16 * 10
6J/m
3, polycrystalline material is 2 * 10
3Get final product saturation magnetization under the kA/m, λ s=1000ppm, and the magnetostriction coefficient λ of monocrystalline
111Reach 1640ppm.It has following characteristics: length is with the quick variation in outfield; External magnetic field changes can produce big stress; Young's modulus changes with external magnetic field; The velocity of sound changes with external magnetic field.This material is the magnetostriction better performances in temperature-10 ℃～60 ℃ scope, but magnetostriction declines to a great extent suddenly when being lower than-10 ℃ in temperature, and the rising magnetostriction with temperature when temperature is more than 60 ℃ descends very fast.
Direction of easy axis under the TbDyFe alloy normal temperature is＜111〉crystallographic direction, when the preferred orientation of crystal growth is consistent with direction of easy axis, and when promptly preferred orientation is＜111〉direction, the magnetostrictive strain maximum.But preparation crystal axially＜111〉preferred orientation is very difficult.Many researchers concentrates on preparation and＜111〉angle less＜112〉and＜110〉oriented crystal, good magnetostriction performance is also arranged.The direction of easy axis of TbDyFe alloy is undergone mutation at a certain specified temp Tr, and the critical temperature of this transformation is called the spin reorientation temperature, is lower than the spin reorientation temperature T
r,＜100〉direction is its direction of easy axis, is higher than the spin reorientation temperature T
rShi Zewei＜111〉direction, the λ of this compounds
111＞＞λ
100The spin reorientation temperature T of Terfenol-D
rBe about-10 ℃, this has limited its use under low temperature environment greatly.Ferromagnet becomes paramagnet more than Curie temperature Tc, do not possess the magnetostriction performance.Below Curie temperature Tc, reducing magnetostrictive temperature coefficient is the key technology place that this material can at high temperature use.Therefore, giant magnetostrictive material is used under hot conditions and is depended on the raising Curie temperature and reduce magnetostrictive temperature coefficient.
Based on above 2 points, the inventor reduces the spin reorientation temperature T on the one hand
r, improve Curie temperature T on the other hand
cWith reduce magnetostrictive temperature coefficient, obtain a kind of rare earth ultra-magnetostriction material that can (80 ℃～150 ℃) use in wide temperature range.Simultaneously, the inventor has successfully prepared this material＜110 〉,＜112〉preferred orientation crystal.
The adjustment of Tb/Dy ratio reduces the spin reorientation temperature T of material
rAdopt Cr, V, four kinds of elements of Co, Ni or Co element to replace the Fe element of part on this basis, adjust their ratio combination, to improve curie transition temperature T
cWith the magnetostrictive temperature coefficient of reduction, make the spin reorientation temperature T of material simultaneously
rReduce, widen the serviceability temperature scope of material.Generally, when the Tb/Dy ratio is 0.27/0.73, Tb
xDy
1-xFe
2The magnetocrystalline anisotropy minimum, its spin reorientation temperature T
r=-10 ℃; When this ratio is 0.35/0.65, the spin reorientation temperature T
r=-80 ℃, become big with this ratio, T
rResemble more negative variations in temperature.Substitute element Co can improve Curie temperature, and Cr can improve its mechanical property, and V mainly is for the magnetostriction performance under the magnetic field condition that improves, and the adding of Ni is in order to reduce the magnetocrystalline anisotropy of material.We change the amount of respectively adding element on the basis of experimental result repeatedly, make material magnetostriction performance in wide temperature range reach optimum as far as possible.
This material can be applicable to the high and low temperature environment, is the novel comparatively widely giant magnetostrictive material of a kind of application prospect.
Summary of the invention
One of purpose of the present invention provides the Rare-Earth Giant Magnetostrictive Materials that (80 ℃～150 ℃) use in a kind of wide temperature range, it is ratio by Tb and Dy element in the adjustment alloy, and add one kind of alloying elements cr, V, Co, four kinds of Ni or Co to reduce alloy spin reorientation temperature, improve Curie temperature and reduce the temperature coefficient of giant magnetostriction material.
Another object of the present invention provides the method for the Rare-Earth Giant Magnetostrictive Materials that (80 ℃～150 ℃) use in a kind of preparation wide temperature range.
A kind of wide temperature of the present invention territory giant magnetostriction material, its chemical formula is: Tb
xDy
1-x(Fe
1-yT
y)
zWherein X=0.32～0.40, y=0.05～0.20, z=1.80～1.95, T is that Cr, V, four kinds of elements of Co, Ni or T are Co element.
The advantage of material of the present invention is: this material is compared with Terfenol-D wideer serviceability temperature scope, temperature range is at-80 ℃～150 ℃, the saturation magnetostriction performance reaches more than the 1600ppm in the time of-80 ℃, the saturation magnetostriction performance reaches more than the 1300ppm in the time of 150 ℃, descend slowlyer with raise its magnetostriction coefficient of temperature, the magnetostriction temperature coefficient is lower than-1.7ppm/ ℃.
Description of drawings
The magneto-strain curve chart that Fig. 1 is a material of the present invention under the temperature of 2000 Oe magnetic fields-80 ℃～150 ℃.
Fig. 2 is material of the present invention magneto-strain curve chart under-80 ℃～150 ℃ temperature in 4000 Oe magnetic fields.
The magneto-strain curve chart that Fig. 3 is the Terfenol-D polycrystalline specimen under the temperature of 2000 Oe magnetic fields-80 ℃～150 ℃.
Fig. 4 is the X-ray diffractogram of material as cast condition sample of the present invention.
Fig. 5 is that material of the present invention has＜110〉preferred orientation X-ray diffractogram.
Fig. 6 is that material of the present invention has＜112〉preferred orientation X-ray diffractogram.
Embodiment
The present invention is the rare earth ultra-magnetostriction material that (80 ℃～150 ℃) use in a kind of wide temperature range, and its chemical formulation is:
Tb
xDy
1-x(Fe
1-yT
y)
zWherein:
X＝0.32～0.40、y＝0.05～0.20、z＝1.80～1.95，
T is that Cr, V, four kinds of elements of Co, Ni or T are Co element.
The technology that the present invention prepares above-mentioned material is:
The first step: the casting rod, will put into the water cooled copper mould of vacuum arc furnace ignition after four kinds of element weighings, the vacuum degree of vacuum chamber reaches 2 * 10
-3Pa～4 * 10
-3Pa feeds high-purity argon gas and makes protection gas, and striking also increases electric current, improves smelting temperature, treat that alloying element melts fully after, current interruption forms alloy pig, and alloy pig is overturn, and carries out melting again, melt back make for 4 to 5 times in the alloy composition as far as possible evenly; At last ingot casting is melted the back suction again and cast bar, stand-by;
Second step: the oriented crystal preparation, in homemade high-temperature gradient vaccum sensitive stove, adopt the molten directional solidification method in floating zone, charge bar is put into alundum tube, the vacuum degree of regulating in the vacuum chamber reaches 2 * 10
-3Pa～4 * 10
-3Pa feeds high-purity argon gas and makes protection gas, controls temperature gradient by the conditioning equipment heating current, directly adjusts the speed of growth, realizes high-temperature gradient directional solidification, and temperature gradient reaches 100～700 ℃/cm.When rate of crystalline growth in 30～600mm/h scope, can obtain the height＜110〉preferred orientation, as shown in Figure 5; When the speed of growth is in 600～900mm/h scope, can obtain height＜112〉preferred orientation, as shown in Figure 6.
The 3rd step: heat treatment, in the horizontal vacuum heat-treatment furnace, carry out, regulate vacuum to 2 * 10
-3Pa～4 * 10
-3Pa feeds high-purity argon gas and makes protection gas (gas pressure reaches 0.05MPa), 950～1050 ℃ of temperature, is incubated 1～24 hour.
The magnetostriction size of above-mentioned material is as shown in the table:
The magnetostriction performance unit of this material of table 1.: ppm
| The measurement temperature (℃) | Measure magnetic field (Oe) | Magneto-strain (ppm) | |
| No precompression | 10Mpa | ||
| 150 | 2000 | 714～1027 | 902～1211 |
| 4000 | 912～1312 | 1163～1601 | |
| 60 | 2000 | 789～1072 | 957～1269 |
| 4000 | 1008～1370 | 1234～1676 | |
| Room temperature (20) | 2000 | 815～1107 | 1007～1328 |
| 4000 | 1041～1415 | 1299～1754 | |
| 0 | 2000 | 823～1170 | 1024～1352 |
| 4000 | 1052～1438 | 1320～1789 | |
| -10 | 2000 | 851～1211 | 1053～1378 |
| 4000 | 1087～1547 | 1358～1820 | |
| -80 | 2000 | 909～1260 | 1082～1439 |
| 4000 | 1161～1573 | 1396～1901 |
Curie temperature: Tc=360～430 ℃
Spin reorientation temperature: Tr=-120～-80 ℃
Temperature coefficient:＜-1.7ppm/ ℃
Compression strength: 650～750MPa
Tensile strength: 25～40MPa
The tissue of giant magnetostriction material of the present invention is formed: matrix mutually for cube Laves phase structure (Tb, Dy) (Fe, T)
2Mutually and rich rare earth mutually and on a small quantity other impurity are mutually.
Material of the present invention except that polycrystalline, the axial preferred orientation after the directional solidification mainly is＜110 or＜112〉two kinds of preferred orientations, see also shown in accompanying drawing 5 and the accompanying drawing 6.Accompanying drawing 5 is＜110〉oriented crystal cross section x x ray diffraction collection of illustrative plates, and Fig. 4 is the x x ray diffraction collection of illustrative plates of as cast condition sample; As can be seen: 113 peaks of as cast condition sample are the strongest, and 220 and 440 peak intensities are big in the accompanying drawing 5, and this material is＜110〉axial preferred orientation; Equally, the material shown in the accompanying drawing 6 have＜112〉axial preferred orientation.
Embodiment 1
For prepared composition is Tb
0.4Dy
0.6(Fe
0.75V
0.05Cr
0.05Ni
0.05Co
0.10)
1.9Giant magnetostriction material 50 gram, with accurate weighing Tb 11.8593 grams of electronic balance, Dy 18.1891 grams, Fe 14.8464 grams, V 0.9028 gram, Cr 0.9215 gram, Ni 1.0401 grams, Co 2.2407 grams, melt back is 4 to 5 times in vacuum arc furnace ignition, make its composition even, cast charge bar then.The tissue of charge bar form be mutually rich rare earth phase and Laves phase (Tb, Dy) (Fe, T)
2Phase and a spot of oxide impurity etc.Charge bar is of a size of φ 6.5mm * 120mm.In the crystal growing furnace of high-frequency induction heating, sample is put into high-purity Al
2O
3Crucible, gallium indium alloy are cooling fluid, keep the temperature gradient of solid-liquid interface of 500 ℃/cm, carry out oriented growth with the setting rate of 240mm/h, obtain with＜110〉be oriented to main sample rod.Line cuts out one section long sample of 30mm, and 1050 ℃ are incubated 10 hours in vacuum heat treatment furnace, and air cooling carries out performance test to room temperature.Employing standard four contact resistance strain gauge methods carry out the magneto-strain test.Measured result and this laboratory the same terms down Terfenol-D of the having of preparation＜110〉orientation compare, shown in table 2 and table 3:
Table 2. has＜and 110〉preferred orientation Tb
0.4Dy
0.6(Fe
0.75V
0.05Cr
0.05Ni
0.05Co
0.10)
1.9Sample and Terfenol-D are in 2000 Oe magnetic fields, and the magnetostriction performance under the no precompression condition relatively
| Measure magnetic field (Oe) | The measurement temperature (℃) | Magneto-strain (ppm) | |
| Terfenol-D | Tb 0.4Dy 0.6(Fe 0.75 V 0.05Cr 0.05Ni 0.05Co 0.10) 1.9 | ||
| 2000 | 150 | 651 | 892 |
| 2000 | 60 | 852 | 998 |
| 2000 | Room temperature | 969 | 1076 |
| 2000 | 0 | 1021 | 1154 |
| 2000 | -10 | 1036 | 1189 |
| 2000 | -80 | 292 | 1254 |
Table 3. has＜and 110〉preferred orientation Tb
0.4Dy
0.6(Fe
0.75V
0.05Cr
0.05Ni
0.05Co
0.10)
1.9Other key property of sample and Terfenol-D relatively
| Terfenol-D | Tb 0.4Dy 0.6(Fe 0.75 V 0.05Cr 0.05Ni 0.05Co 0.10) 1.9 | |
| Curie temperature Tc | 370℃ | 420℃ |
| Spin reorientation temperature T r | -10℃ | -100℃ |
| The magnetostriction temperature coefficient | -2.49ppm/℃ | -1.69ppm/℃ |
| Thermal coefficient of expansion | 13.21ppm/℃ | 11.85ppm/℃ |
| Tensile strength | 28Mpa | 30Mpa |
Embodiment 2
Prepared composition is Tb
0.36Dy
0.64(Fe
0.80Co
0.20)
1.9Wide temperature territory giant magnetostriction material 40 gram, accurate weighing Tb 6.5261 grams of electronic balance, Dy 11.8638 grams, Fe 9.3769 grams, Co 2.4738 grams, melt back is 4 times in vacuum arc furnace ignition, casts the charge bar of φ 6.5mm * 100mm then.In the crystal growing furnace of high-frequency induction heating, charge bar is put into the alundum tube that internal diameter is 7.2mm, the gallium indium alloy is a cooling fluid, the temperature gradient of solid-liquid interface that keeps 100 ℃/cm, setting rate with 750mm/h is carried out oriented growth, obtain based on＜112 the sample rod of axial orientation, as shown in Figure 6.Line cuts out one section long sample of 30mm, and 1080 ℃ are incubated 5 hours in the vacuum heat treatment furnace that is connected with the high-purity argon gas protection, and air cooling carries out performance test to room temperature.Employing standard four contact resistance strain gauge methods carry out the magneto-strain test.Measured result and this laboratory the same terms down Terfenol-D of the having of preparation＜112〉orientation compare, shown in table 4 and table 5:
Table 4. has＜and 112〉preferred orientation Tb
0.36Dy
0.64(Fe
0.80Co
0.20)
1.9Sample and Terfenol-D are in 2000 Oe magnetic fields, and the magnetostriction performance under the no precompression condition relatively
| Measure magnetic field (Oe) | The measurement temperature (℃) | Magneto-strain (ppm) | |
| Terfenol-D | Tb 0.36Dy 0.64(FeO. 80Co 0.20) 1.9 | ||
| 2000 | 150 | 763 | 964 |
| 2000 | 60 | 980 | 1021 |
| 2000 | Room temperature | 1100 | 1089 |
| 2000 | 0 | 1110 | 1168 |
| 2000 | -10 | 1130 | 1197 |
| 2000 | -80 | 290 | 1288 |
Table 5. has＜and 112〉preferred orientation Tb
0.36Dy
0.64(Fe
0.80Co
0.20)
1.9Sample and Terfenol-D key property are relatively
| Terfenol-D | Tb 0.4Dy 0.6(Fe 0.75 V 0.05Cr 0.05Ni 0.05Co 0.10) 1.9 | |
| Curie temperature Tc | 370℃ | 426℃ |
| Spin reorientation temperature T r | -10℃ | -93℃ |
| The magnetostriction temperature coefficient | -2.59ppm/℃ | -1.48ppm/℃ |
| Thermal coefficient of expansion | 12.37ppm/℃ | 11.56ppm/℃ |
| Tensile strength | 27.4Mpa | 32.3Mpa |
Material of the present invention is compared with Terfenol-D wideer serviceability temperature scope, and high-temperature behavior is better, descends slower with raise its magnetostriction coefficient of temperature.Shown in accompanying drawing 1 and accompanying drawing 3, be respectively material of the present invention and the Terfenol-D temperature variant relation of strain in 2000 Oe magnetic fields.
As can be seen, the wide temperature territory giant magnetostriction material of our invention has excellent magnetostriction performance below-10 ℃ from accompanying drawing 1, and we test-80 ℃, the magnetostriction excellent performance.But Terfenol-D sharply descends in magnetostriction performance below-10 ℃, as our material-80 ℃ the time, 1288ppm under the 2000 Oe magnetic fields, and Terfenol-D has only about 290ppm.And, it can also be seen that from accompanying drawing 1 in identical magnetic field, our the wide temperature territory giant magnetostriction material of invention is slower with the rising magnetostriction decline of temperature, its magnetostriction temperature coefficient (absolute value of slope) is less in other words; Comparatively speaking, it shown in the accompanying drawing 3 Terfenol-D temperature variant curve of magneto-strain in 2000 Oe magnetic fields, the magnetostriction temperature coefficient of (10～150 ℃) (absolute value of slope) is bigger more than the spin reorientation temperature, and magneto-strain raises with temperature and reduces comparatively fast.The slope of these two straight lines relatively, material (as Fig. 1) the magnetostriction temperature coefficient of our invention is-1.48ppm/ ℃ as can be seen, Terfenol-D is-2.59ppm/ ℃; The material of our invention is in the time of 150 ℃, and 2000 Oe magnetic fields do not have that the magnetostriction performance is 964ppm under the prestressing force, and Terfenol-D is 763ppm.This material (80～150 ℃) in wide temperature range that illustrates that we invent is better than common Terfenol-D.
Material of the present invention can adapt to the requirement of big variations in temperature round the clock of space industry space environment, can utilize the shape of this material space station speculum to calibrate automatically, the Active Vibration Control of adjustment of solar battery array position and space large-sized structural parts.This material can also be applied to improve vibration transducer, the precision micro-displacement linear motor of oil exploitation rate, accurate control hydraulic valve.Utilize the villari and the AntrViedemann effect of this material, can be used for doing mechanics sensor, measure physical quantitys such as static stress, twisting resistance, vibration stress and acceleration.This material and laser diode optical fiber or PZT material match, and can make magnetometer miscellaneous.Under the spin reorientation temperature, material coefficient of thermal expansion coefficient and Young's modulus are undergone mutation, so material of the present invention can also be as the heat-sensitive sensor material of low temperature.The transducer that adopts this material to make can be converted to very strong ultrasonic energy to powerful electric energy, thereby can utilize its high-strength ultrasonic that produces to change the performance and the state of material; Also can carry out metal defect detection, immersed body detection and high-power sonar transducer etc. with this ultrasonic wave.Along with the further research that magnetostrictive material are used, this material can be brought into play the big magnetostriction characteristic of its wide temperature range aspect more.
Claims (7)
1, a kind of wide temperature territory giant magnetostriction material, it is characterized in that: chemical formula is: Tb
xDy
1-x(Fe
1-yT
y)
zWherein X=0.32～0.40, y=0.05～0.20, z=1.80～1.95, T is that Cr, V, four kinds of elements of Co, Ni or T are Co element.
2, wide temperature according to claim 1 territory giant magnetostriction material, it is characterized in that: the consumption of four kinds of elements of T is Cr=0～0.1, V=0～0.1, Co=0～0.3, Ni=0～0.1.
3, wide temperature according to claim 1 territory giant magnetostriction material, it is characterized in that: wide temperature range is-80 ℃～150 ℃.
4, wide temperature according to claim 1 territory giant magnetostriction material is characterized in that: wide temperature range be-80 ℃～-10 ℃ with 60 ℃～150 ℃.
5, wide temperature according to claim 1 territory giant magnetostriction material, it is characterized in that: chemical composition is Tb
0.4Dy
0.6(Fe
0.5V
0.05Cr
0.05Ni
0.05Co
0.10)
1.9Material.
6, wide temperature according to claim 1 territory giant magnetostriction material, it is characterized in that: chemical composition is Tb
0.36Dy
0.64(Fe
0.80Co
0.20)
1.9Material.
7, the preparation method of a kind of wide temperature territory giant magnetostriction material is characterized in that:
The first step: casting rod, Tb, Dy, Fe, Cr, V, Co, each element of Ni are put into water cooled copper mould after by the usage ratio weighing, the vacuum degree of regulating vacuum chamber reaches 2 * 10
-3Pa～4 * 10
-3Pa feeds high-purity argon gas and makes protection gas, and melting and casting becomes the bar of φ 6.5mm, and is stand-by;
Second step: the oriented crystal preparation, charge bar is put into the alundum tube that internal diameter is 7.2mm, the vacuum degree in the vacuum chamber reaches 2 * 10
-3Pa～4 * 10
-3Mpa feeds high-purity argon gas and makes protection gas, by regulating the speed of growth 30～90mm/h and 100～700 ℃/cm of temperature gradient, make it to have＜110 or＜112〉axial preferred orientation;
The 3rd step: heat treatment, at the horizontal vacuum heat-treatment furnace, regulate vacuum to 2 * 10
-3Pa～4 * 10
-3Mpa feeds high-purity argon gas and makes protection gas, 950～1050 ℃ of temperature, is incubated 1～24 hour.
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| CN113073249B (en) * | 2021-02-26 | 2022-12-02 | 湖南大学 | Preparation method of <111> + <110> preferred orientation giant magnetostrictive material TbxDy1-xFey |
| CN114752837B (en) * | 2022-04-29 | 2023-03-21 | 清华大学 | Medium-entropy magnetostrictive alloy and preparation method and application thereof |
| CN115058771A (en) * | 2022-06-22 | 2022-09-16 | 清华大学 | Preparation method and device of rare earth-iron-based magnetostrictive single crystal material |
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| US5223046A (en) * | 1988-09-29 | 1993-06-29 | Kabushiki Kaisha Toshiba | Super-magnetostrictive alloy |
| JP2877365B2 (en) * | 1988-09-29 | 1999-03-31 | 株式会社東芝 | Giant magnetostrictive alloy and actuator for micro displacement control |
| US5997660A (en) * | 1995-12-21 | 1999-12-07 | University Of Hull | Magnetic materials |
| CN1436871A (en) * | 2002-02-06 | 2003-08-20 | 徐军 | Prepn of ternary Tb-Dy-Fe alloy |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5223046A (en) * | 1988-09-29 | 1993-06-29 | Kabushiki Kaisha Toshiba | Super-magnetostrictive alloy |
| JP2877365B2 (en) * | 1988-09-29 | 1999-03-31 | 株式会社東芝 | Giant magnetostrictive alloy and actuator for micro displacement control |
| US5997660A (en) * | 1995-12-21 | 1999-12-07 | University Of Hull | Magnetic materials |
| CN1436871A (en) * | 2002-02-06 | 2003-08-20 | 徐军 | Prepn of ternary Tb-Dy-Fe alloy |
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| Title |
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| 超磁致伸缩合金TbDyFe的晶体生长过程 柳美荣，蒋成保，宫声凯，徐惠彬，材料研究学报，第16卷第3期 2002 * |
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