CN1321719C - Smoke suppressor for electrical fire - Google Patents
Smoke suppressor for electrical fire Download PDFInfo
- Publication number
- CN1321719C CN1321719C CNB200410036248XA CN200410036248A CN1321719C CN 1321719 C CN1321719 C CN 1321719C CN B200410036248X A CNB200410036248X A CN B200410036248XA CN 200410036248 A CN200410036248 A CN 200410036248A CN 1321719 C CN1321719 C CN 1321719C
- Authority
- CN
- China
- Prior art keywords
- smoke
- water
- surfactant
- electrical fire
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000779 smoke Substances 0.000 title abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 150000001447 alkali salts Chemical class 0.000 claims description 6
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- IVKNZCBNXPYYKL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 IVKNZCBNXPYYKL-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- 229960002233 benzalkonium bromide Drugs 0.000 claims description 2
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 18
- 239000002245 particle Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002341 toxic gas Substances 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 159000000011 group IA salts Chemical class 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
- 239000003500 flue dust Substances 0.000 description 9
- 230000008030 elimination Effects 0.000 description 6
- 238000003379 elimination reaction Methods 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000010616 electrical installation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The electric fire smoke suppressor is an atomized smoke suppressor containing a surfactant and a binder, can realize high efficiency, remove toxic gas and quickly settle smoke particles, and has the use effect of no corrosivity. The electric fire smoke suppressor comprises the following components in parts by weight: 84-99% of solvent water; alkaline salt: 0.5-10%; surfactant : 0.1-5%; adhesive: 0.01 to 1 percent. In the formula of the electric fire smoke suppressor, water is an effective solvent of various additive components on one hand, and on the other hand, the water can settle smoke particles and can dissolve toxic gases which are easy to dissolve in water, such as carbon monoxide, hydrogen chloride and the like, so that a certain smoke suppression effect is achieved.
Description
Technical field
The present invention relates to a kind of antismoke agent that produces toxic smog when being used to eliminate electrical fire.
Background technology
Along with the development of computer and electrical technology, all kinds of civil and military electrical equipments, instrument and electric equipment are used widely, have brought facility and high efficiency for daily life and work.Owing to outside transmission of electricity accident, use error or maintain the power supply overload that causes not in place, short circuit accident, electrical fire causes in regular meeting.After fire took place, what be accompanied by raging flames was the dense smoke that the burning of cable outer layer rubber-like clad material and the toxic and harmful that produces and the flue dust that produces because of imperfect combustion form.
The smokescope that electrical fire produces is big, and visibility is extremely low.Leave even under the situation that the intensity of a fire has been extinguished, still slowly be difficult to.This not only has a strong impact on the rescue work of fire, and toxic gas can be to the big toxic and side effect of human body generation, and the dust deposition of Chan Shenging is difficult to cleaning to electrical equipment in addition, thereby makes troubles for follow-up cleaning work.
At the elimination of toxic smog in the electrical fire, normally take physics smoke evacuation and water smoke smoke elimination means at present.Wherein the physics fume exhausting type requires to answer the space of electrical installation to have satisfactory smoke evacuation space, and this gives spatial design and use and has proposed additional requirement, and this type of physics smoke exhaust method must have limitation.
The shortcoming of taking water smoke smoke evacuation method is for removal toxic gas poor effect, and actual depositing dust efficient is not high.After electrical equipment spoons a large amount of water, probably equipment is caused and damage even scrap; Not so also must need just can come into operation again after the thorough baking/dry processing.
Summary of the invention
Electrical fire antismoke agent of the present invention, its purpose is to address the above problem and is not enough and design a kind of atomizing type antismoke agent that contains surfactant and binding agent, can realize efficient, remove toxic gas and rapid subsidence smoke particle, have non-corrosive result of use concurrently simultaneously.
Described electrical fire antismoke agent, its prescription composition is by weight:
Aqueous solvent, 84~99%;
Basic salt: 0.5~10%;
Surfactant: 0.1~5%;
Binding agent: 0.01~1%.
In the prescription of described electrical fire antismoke agent, water is the active solvent of various adding ingredients on the one hand, on the other hand water self can the sedimentation smoke particle, and can dissolve toxic gases soluble in water such as carbon monoxide, hydrogen chloride, thereby reach certain smoke effect.
Add the basic salt purpose and be to carry out acid-base neutralization.Usually the flue dust of electrical fire has faintly acid, can quicken the elimination of the acid ingredients such as oxide, sulfur oxide and chlorion of carbon by chemical reaction behind the adding basic salt, thereby improves smoke elimination efficient.
The purpose that adds surfactant is to improve wetting effect.This is can form the aerosol system because flue dust floats in air, and existing interfacial tension between its surface and the air forms one deck air film on small flue dust surface.Soot dust granule is more little, and then air film is just firm more.This class air film has hindered the cohesion of water smoke to the moistening and grit of grit, makes in air floating small flue dust both be difficult for flocking settling and also is difficult for colliding into wet dirt with water smoke.The anionic surfactant that is added has polarity and non-polar group simultaneously.Its polar group possess hydrophilic property, non-polar group has hydrophobicity, after the hydrophobic lattice absorption surface activating agent on cigarette ash surface, hydrophilic radical is towards air, hydrophobic grouping is towards the flue dust surface, makes the cigarette ash surface produce hydrophilic interaction, thereby easilier makes the wetting heavy burden of cigarette ash and fall.On-the-spot cleaning was more prone to after surfactant made and eliminates smoke simultaneously.
Add binding agent and can condense into the bigger soot dust granule of diameter by the flue dust that particle diameter is less.Realize that the soot dust granule volume increases, then in air, will increase, thereby easilier make the wetting weightening finish of smoke particle, lose diffusivity, be more prone to sedimentation with the machine that contacts of droplet.On the other hand, make loose flue dust form bulk, also can accelerate the speed of landing, thereby reach the purpose of quick smoke elimination.
In addition, under surfactant and binding agent acting in conjunction, this antismoke agent can be brought into play the sustained release agent function, can effectively avoid antismoke agent to use metal material in the scope because of corrosion that water smoke caused.
In the prescription of above-mentioned electrical fire antismoke agent,
Basic salt can be selected the wherein at least a of sodium carbonate, sodium acid carbonate, sodium phosphate, sodium metasilicate for use;
Surfactant can be selected the wherein at least a of neopelex, TW-80, succinate sodium sulfonate, OP-10, potassium laurate, benzalkonium bromide for use;
Binding agent can adopt the wherein at least a of water soluble adhesives such as polyvinyl alcohol, polypropylene glycol, polyacrylamide.
As mentioned above, the advantage of electrical fire antismoke agent of the present invention is comparatively outstanding, compares to make water or other smoke elimination approach separately, and its smoke effect significantly improves bigger.The aspects such as speed of can be respectively landing at chemical characteristic, particle size increase, soot build-up, the caking of flue dust play a role, and reach fast and smoke effect efficiently.
The specific embodiment
Embodiment 1, described electrical fire antismoke agent, and its prescription composition is by weight:
Water: 96.7%;
Sodium carbonate: 3%,
Neopelex: 0.2%;
Polypropylene glycol: 0.1%.
Embodiment 2, described electrical fire antismoke agent, and its prescription composition is by weight:
Water: 96.7%;
Sodium metasilicate: 1%;
Sodium phosphate: 2%;
Potassium laurate: 0.2%;
Polyvinyl alcohol: 0.1%.
As above-mentioned embodiment content, antismoke agent can be removed toxic gas fast by the efficient component of adding in water, the smoke particle of sedimentation simultaneously, and consumption is little, efficient is high and non-corrosiveness, helps the cleaning of scene of fire.
Claims (1)
1. electrical fire antismoke agent is characterized in that: its prescription is formed and is by weight,
Aqueous solvent, 84~99%;
Basic salt: 0.5~10%;
Surfactant: 0.1~5%;
Binding agent: 0.01~1%,
Described basic salt is selected sodium carbonate, sodium acid carbonate, sodium phosphate, sodium metasilicate for use;
Described surfactant is selected neopelex, TW-80, succinate sodium sulfonate, OP-10, potassium laurate, benzalkonium bromide for use;
Described binding agent adopts polyvinyl alcohol, polypropylene glycol, polyacrylamide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200410036248XA CN1321719C (en) | 2004-11-08 | 2004-11-08 | Smoke suppressor for electrical fire |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200410036248XA CN1321719C (en) | 2004-11-08 | 2004-11-08 | Smoke suppressor for electrical fire |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1772336A CN1772336A (en) | 2006-05-17 |
CN1321719C true CN1321719C (en) | 2007-06-20 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB200410036248XA Expired - Fee Related CN1321719C (en) | 2004-11-08 | 2004-11-08 | Smoke suppressor for electrical fire |
Country Status (1)
Country | Link |
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CN (1) | CN1321719C (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103721554B (en) * | 2013-12-10 | 2016-01-06 | 中国华电工程(集团)有限公司 | The electric defogging method of the fine particle in trapping wet-method desulfurized fume and device |
CN107174769A (en) * | 2016-03-09 | 2017-09-19 | 江丰明 | Use the anti-haze personal respiratory protection device of anti-haze composition |
CN106823758B (en) * | 2017-02-28 | 2019-04-09 | 中国矿业大学 | A kind of method that haemachrome solution ultrasonic atomizatio spray eliminates the CO in restricted clearance |
CN108176167B (en) * | 2017-12-29 | 2020-12-08 | 西安科技大学 | Dedusting and denitration active agent for coal-fired power plant, preparation method, use method and application |
CN113577946B (en) * | 2021-07-29 | 2022-09-09 | 中国矿业大学 | Micro-bubble type smoke suppressor and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19756779A1 (en) * | 1996-12-20 | 1998-07-16 | Dynamit Nobel Ag | Agent which cools pyrotechnically produced gas containing an aerosol |
CN1192163A (en) * | 1995-06-07 | 1998-09-02 | 安松公司 | Colloidal particles of solid flame retardant and smoke suppressant compounds and methods for making them |
US6116348A (en) * | 1998-07-17 | 2000-09-12 | R-Amtech International, Inc. | Method and apparatus for fire extinguishing |
CN1386554A (en) * | 2001-05-17 | 2002-12-25 | 郭鸿宝 | Fire-extinguishing aerosol without toxicity and corrosion for electric appliance |
-
2004
- 2004-11-08 CN CNB200410036248XA patent/CN1321719C/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1192163A (en) * | 1995-06-07 | 1998-09-02 | 安松公司 | Colloidal particles of solid flame retardant and smoke suppressant compounds and methods for making them |
DE19756779A1 (en) * | 1996-12-20 | 1998-07-16 | Dynamit Nobel Ag | Agent which cools pyrotechnically produced gas containing an aerosol |
US6116348A (en) * | 1998-07-17 | 2000-09-12 | R-Amtech International, Inc. | Method and apparatus for fire extinguishing |
CN1386554A (en) * | 2001-05-17 | 2002-12-25 | 郭鸿宝 | Fire-extinguishing aerosol without toxicity and corrosion for electric appliance |
Non-Patent Citations (1)
Title |
---|
气溶胶灭火剂的研究及发展现状 徐晓楠,消防技术与产品信息 2002 * |
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Publication number | Publication date |
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CN1772336A (en) | 2006-05-17 |
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PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070620 Termination date: 20131108 |