CN1315971C - High performance cement-base sealing up leading stoppage material - Google Patents

High performance cement-base sealing up leading stoppage material Download PDF

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Publication number
CN1315971C
CN1315971C CNB2004100165759A CN200410016575A CN1315971C CN 1315971 C CN1315971 C CN 1315971C CN B2004100165759 A CNB2004100165759 A CN B2004100165759A CN 200410016575 A CN200410016575 A CN 200410016575A CN 1315971 C CN1315971 C CN 1315971C
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CN
China
Prior art keywords
cement
water
present
reducing agent
gypsum
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2004100165759A
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Chinese (zh)
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CN1560171A (en
Inventor
孙振平
蒋正武
张冠伦
王玉吉
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Tongji University
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Tongji University
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Priority to CNB2004100165759A priority Critical patent/CN1315971C/en
Publication of CN1560171A publication Critical patent/CN1560171A/en
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Publication of CN1315971C publication Critical patent/CN1315971C/en
Anticipated expiration legal-status Critical
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

Abstract

The present invention belongs to the technical field of building materials, particularly to a high performance cement-base water seal and leak stoppage material. The present invention is composed of portland cement, high alumina cement, 0.16 to 2.5mm of quartz sand, cellulose, water reducing agent, gypsum and quicklime powder. The present invention can mix mortar which is quickly condensed and hardened and can carry out the water seal and leak stoppage treatment for the water penetration positions of buildings(structure) such as roofs, wall surfaces, ground, large dams, tunnels, pools, etc. in high efficiency. Accordingly, leak is thoroughly treated and living environment is greatly improved. The service life of concrete structure(structure) is prolonged. The present invention is suitable for constructions such as reinforced concrete, light aggregate concrete, industrial and civil constructions, underground chambers, bridge beams, large dams, tunnels, etc.

Description

A kind of cement based sealing patching materials
Technical field
The invention belongs to building material technical field, be specifically related to a kind of high-performance cement-based sealing patching materials.
Background technology
Current, owing to do not take into full account the impermeability of concrete material and the brittle cracking of concrete structure when design and construction, the seepage disease of various degrees such as many large-sized concrete buildingss, concrete diaphragm wall, vault, tunnel has had a strong impact on its functions of use.And the difficulty that these works are repaired is very big.Common way has following two kinds:
1) with admixture the sand-cement slurry of water reducer, water-resisting agent and/or micro-expanding agent etc. wipe one's face;
2) brushing polyurethane waterproofing coating, silicon rubber waterproof coating or organosilicon etc. on metope.
These two kinds of methods can improve the anti-leakage of concrete body to a certain extent, but, the seepage phenomenon often occur in delivered and the engineering that comes into operation in, at this moment because water pressure is bigger, use first method, because the cohesiveness of conventional cement mortar and basic unit is relatively poor and time of coagulation is longer, is usually just washed away by pressure water before its setting and harden is set up intensity; If adopt a kind of method in back, these waterproof paints all are solvent type on the one hand, can't combine with wet metope, and on the other hand, Bao coating is difficult to the effect of renitency water like this.So these two kinds of common practices all can not effectively solve the sealing leak stopping problem of the concrete structure that seepage takes place.
Summary of the invention
The object of the present invention is to provide a kind of high-performance cement-based sealing patching materials that can effectively carry out quick blocking to concrete structure (structures) penetrating passage.
The high-performance cement-based sealing patching materials that the present invention proposes, by ordinary Portland cement, high-alumina cement, 0.16-2.5mm quartz sand, Mierocrystalline cellulose, water reducer, gypsum, calcium lime powder are formed, and the weight ratio of each component is:
Ordinary Portland cement 100
High-alumina cement 20-35
0.16-2.5mm quartz sand 90-120
Mierocrystalline cellulose 0.02-0.08
Water reducer 0.5-0.9
Gypsum 2.0-3.5
Calcium lime powder 2.0-4.0
The preferable weight ratio of each component is:
Ordinary Portland cement 100
High-alumina cement 23-32
0.16-2.5mm quartz sand 95-112
Mierocrystalline cellulose 0.04-0.06
Water reducer 0.5-0.7
Gypsum 2.0-3.1
Calcium lime powder 2.0-3.1
Among the present invention, water reducer is the naphthalene sulfonic acidformaldehyde condensation product high efficiency water reducing agent, sulfamate high-effective water-reducing agent, melamine high-efficiency water-reducing agent, polycarboxylate high-efficiency water reducing agent a kind of.
Preparation method of the present invention is: by aforementioned each part by weight weighing each component, above raw material is mixed by physical mechanical, stir, promptly obtain this product.
Among the present invention, ordinary Portland cement is as inorganic coagulation material, can with mixing water generation hydration reaction, produce hydrated product, the sclerosis back produces intensity, and can be bonded together with base part, forms whole.Hydration and hardening speed was fast after water was met in the effect of high-alumina cement, made this product have ideal rapid coagulation Hardenability, was beneficial to set up intensity immediately after the percolating water place crammed.0.16-2.5mm the effect of quartz sand is the skeleton that serves as hardened cement paste, can gain in strength and reduces contraction.Mierocrystalline cellulose helps to improve the cohesive strength between this product and the leak stopping place substrate; The effect of water reducer is plasticizing water-reduction that mortar is played, thereby gains in strength.The effect of gypsum is to provide a certain amount of SO for the slurry system 4 2-, react with the hydrated product of high-alumina cement, form and have certain volume expansible ettringite, the volumetric shrinkage of compensation mortar.The effect of unslaked lime only is aquation early, not only emits certain heat, quickens the aquation of silicate cement and high-alumina cement, and the alkali environment of high density is provided for the formation of high-alumina cement participation ettringite.
The present invention is a grey dry powder material, and during use, suitable amount of water is the 10%-25% of dry powder material weight, and concrete amount of water is determined by test according to the required flowability that slurry is reached.
The present invention uses as the sealing patching materials, effective shutoff percolating water passage, have time of coagulation fast, and basic unit's cohesive strength height, shrinking percentage low, product original characteristic such as construct on being particularly suitable at the bottom of the wet basis.
Cohesive force at the bottom of the present invention and the wet basis is big, and time of coagulation is extremely short, the back pressure-proof and snap-resistent intensity height that condenses, and have very ideal compensate for shrinkage.
The present invention can be widely used in the sealing leak stopping of structures such as concrete structure, bridge, tunnel, vault, dam, pond, water tower to the effect of inside concrete reinforcing bar non-corroding.
Embodiment
Embodiment 1, high-performance cement-based sealing patching materials is pressed ordinary Portland cement 40.79% (mass percent, down together), high-alumina cement 12.24%, 0.16-2.5mm quartz sand 44.87%, Mierocrystalline cellulose 0.016%, sulfamate high-effective water-reducing agent 0.248%, gypsum 1.02%, calcium lime powder 0.816% is formulated.After water that adding accounts for dry powder material 11% stirred, the product presetting period was 4min, and final setting time is 7min, sclerosis back 28d ultimate compression strength is 65MPa, and folding strength is 11.4MPa, and adhesive tensile resistance intensity reaches 1.40MPa, the 28d degree of free swelling is 0.045% in the water, and anti-penetration grade is greater than S15.
Embodiment 2, and high-performance cement-based sealing patching materials is pressed ordinary Portland cement 43.45%, high-alumina cement 10.86%, 0.16-2.5mm quartz sand 43.52%, Mierocrystalline cellulose 0.022%, polycarboxylate high-efficiency water reducing agent 0.261%, gypsum 0.877%, calcium lime powder 1.01% is formulated.After water that adding accounts for dry powder material 12% stirred, the product presetting period was 14min, and final setting time is 19min, and sclerosis back 28d ultimate compression strength is 56MPa, and folding strength is 10MPa, and adhesive tensile resistance intensity reaches 1.50MPa, and anti-penetration grade is greater than S15.
Embodiment 3, high-performance cement-based sealing patching materials is pressed ordinary Portland cement 40.45%, high-alumina cement 10.884%, 0.16-2.5mm quartz sand 45.258%, Mierocrystalline cellulose 0.032%, naphthalene sulfonic acidformaldehyde condensation product high efficiency water reducing agent 0.364%, gypsum 1.402%, calcium lime powder 1.61% is formulated.After water that adding accounts for dry powder material 12% stirred, the product presetting period was 9min, and final setting time is 16min, and sclerosis back 28d ultimate compression strength is 61MPa, and folding strength is 10MPa, and adhesive tensile resistance intensity reaches 1.50MPa, and anti-penetration grade is greater than S15.

Claims (4)

1, a kind of cement based sealing patching materials is characterized in that by ordinary Portland cement, high-alumina cement, 0.16-2.5mm quartz sand, and Mierocrystalline cellulose, water reducer, gypsum, calcium lime powder are formed, and the weight ratio of each component is:
Ordinary Portland cement 100
High-alumina cement 20-35
0.16-2.5mm quartz sand 90-120
Mierocrystalline cellulose 0.02-0.08
Water reducer 0.5-0.9
Gypsum 2.0-3.5
Calcium lime powder 2.0-4.0.
2, cement based sealing patching materials according to claim 1 is characterized in that the each component weight ratio is:
Ordinary Portland cement 100
High-alumina cement 23-32
0.16-2.5mm quartz sand 95-112
Mierocrystalline cellulose 0.04-0.06
Water reducer 0.5-0.7
Gypsum 2.0-3.1
Calcium lime powder 2.0-3.1.
3, cement based sealing patching materials according to claim 1 is characterized in that water reducer is the naphthalene sulfonic acidformaldehyde condensation product high efficiency water reducing agent, sulfamate high-effective water-reducing agent, melamine high-efficiency water-reducing agent, polycarboxylate high-efficiency water reducing agent a kind of.
4, a kind of using method of the sealing of cement based according to claim 1 patching materials is characterized in that adding the water of this material weight 10%-25%, stirs.
CNB2004100165759A 2004-02-26 2004-02-26 High performance cement-base sealing up leading stoppage material Expired - Fee Related CN1315971C (en)

Priority Applications (1)

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CNB2004100165759A CN1315971C (en) 2004-02-26 2004-02-26 High performance cement-base sealing up leading stoppage material

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Application Number Priority Date Filing Date Title
CNB2004100165759A CN1315971C (en) 2004-02-26 2004-02-26 High performance cement-base sealing up leading stoppage material

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CN1315971C true CN1315971C (en) 2007-05-16

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Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100334307C (en) * 2005-06-03 2007-08-29 上海知兴科贸有限公司 Leak preventing and stopping method and material
CN100366569C (en) * 2006-07-25 2008-02-06 刘让 Composite for blocking under ground building cracks
CN101775266B (en) * 2010-01-08 2012-08-08 李洪生 Plugging permeability-preventing agent
CN103922685A (en) * 2014-03-13 2014-07-16 安徽理工大学 Sprayed hybrid fiber desulfurized gypsum concrete for underground construction
CN106007610B (en) * 2016-05-17 2018-07-13 上海胜创环保科技有限责任公司 A kind of waterproof dam material, its application method and application based on ardealite base
CN106479460B (en) * 2016-10-17 2021-03-02 西南石油大学 Permeable cement slurry for steam huff-puff to steam flooding oil layer transformation
CN107285723A (en) * 2017-08-03 2017-10-24 上海欧卓实业发展有限公司 A kind of improved loss circulation material
CN109184003B (en) * 2018-09-25 2020-08-04 江苏四知堂工程服务有限公司 Concrete floor waterproof and leaking stoppage construction method
CN111807799A (en) * 2020-06-28 2020-10-23 武汉长江科创科技发展有限公司 Anti-seepage leak-stopping material and application thereof in hydraulic engineering
CN115557764B (en) * 2022-02-15 2023-09-22 上海牛元工贸有限公司 Waterproof enhanced inorganic plugging material and preparation method thereof
CN114656276A (en) * 2022-05-10 2022-06-24 湖南科技大学 Nano self-expansion curing foam fire prevention and extinguishing material and preparation method thereof

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Publication number Priority date Publication date Assignee Title
US4523755A (en) * 1981-05-28 1985-06-18 Egon Turba Surface for sports areas, particularly tennis courts, and its manufacture
SU1694526A1 (en) * 1988-11-23 1991-11-30 Научно-исследовательский и проектно-конструкторский институт строительных материалов им.С.А.Дадашева Putty
CN1261092A (en) * 1999-01-15 2000-07-26 中国建筑材料科学研究院 Quick leakage-stopping agent
CN1271696A (en) * 1999-04-28 2000-11-01 吴德燕 High-strength super-fluidized expanding cement grout
CN1456629A (en) * 2002-05-09 2003-11-19 吉林科龙装饰工程有限公司 Powder binder
CN1458113A (en) * 2003-06-05 2003-11-26 同济大学 High performance no-contraction cement base grouting material and its preparing method

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
US4523755A (en) * 1981-05-28 1985-06-18 Egon Turba Surface for sports areas, particularly tennis courts, and its manufacture
SU1694526A1 (en) * 1988-11-23 1991-11-30 Научно-исследовательский и проектно-конструкторский институт строительных материалов им.С.А.Дадашева Putty
CN1261092A (en) * 1999-01-15 2000-07-26 中国建筑材料科学研究院 Quick leakage-stopping agent
CN1271696A (en) * 1999-04-28 2000-11-01 吴德燕 High-strength super-fluidized expanding cement grout
CN1456629A (en) * 2002-05-09 2003-11-19 吉林科龙装饰工程有限公司 Powder binder
CN1458113A (en) * 2003-06-05 2003-11-26 同济大学 High performance no-contraction cement base grouting material and its preparing method

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Granted publication date: 20070516

Termination date: 20120226