CN1309540A - Soft tissue achieved by applying solid hydrophilic lotion - Google Patents

Soft tissue achieved by applying solid hydrophilic lotion Download PDF

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Publication number
CN1309540A
CN1309540A CN98808161A CN98808161A CN1309540A CN 1309540 A CN1309540 A CN 1309540A CN 98808161 A CN98808161 A CN 98808161A CN 98808161 A CN98808161 A CN 98808161A CN 1309540 A CN1309540 A CN 1309540A
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Prior art keywords
compositions
molecular weight
polyethylene glycol
high molecular
weight polyethylene
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CN98808161A
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CN1129377C (en
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D·G·克日什斯克
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Kimberly Clark Worldwide Inc
Kimberly Clark Corp
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Kimberly Clark Worldwide Inc
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)

Abstract

A superior soft tissue product, such as facial tissue, bath tissue or paper towels and the like, can be made applying, on the surface(s) of the tissue, large numbers of individual deposits of a melted hydrophilic composition comprising a high molecular weight polyethylene glycol, a fatty alcohol (C14-C30) and lipophilic emollients or solvents, including water, and thereafter resolidifying the composition to form a distribution, preferably a uniform distribution, of solid deposits on the surface(s) of the tissue. Because the composition is a solid at room temperature and rapidly solidifies after deposition, it has less tendency to penetrate and migrate into the sheet. These solid deposits are characterized by a penetration hardness of from about 5 to about 360 millimeters.

Description

The soft Water adsorption towel that the applying solid hydrophilic lotion is made
Background of invention
The Water adsorption towel product is used for absorb body fluids and make skin be in drying regime as face-cloth, bath towel etc. always.Yet except absorption fluids, the Water adsorption towel skin that also can rub in use often can not make the skin bone dry, and have the absorbent body fluid of Water adsorption towel or not.Frequency blow one's nose or the wiping anus around the time, often because friction makes red swelling of the skin, once touching bitterly.In order to reduce friction to skin, can on Water adsorption towel, be coated with the Water adsorption towel additive formulations, provide lubricity by this additive formulations during use, Water adsorption towel is slided along skin surface; Perhaps this additive formulations leaves napkin and is deposited on the skin.Up to now, these preparations all are liquid, perhaps are fat base semisolid or fat base solid (hydrophobic material) material under the room temperature.These liquid or fat base semisolid type preparation need to add in Water adsorption towel a large amount of, give it and alleviate the stimulation of skin and the effect of hyperemia, because these preparations all are absorbed in the Water adsorption towel, only stay on the surface this effect seldom is provided.Fat base solid preparation can heat the surface that (adding to higher slightly than preparation fusing point) is coated on Water adsorption towel or towel; said preparation is solidified again on the Water adsorption towel surface; at this moment preparation is easy to transfer on the skin of user, and protecting skin not irritated with hyperemia or avoid further with very low cost stimulates and hyperemia.Yet,, be difficult to add hydrophilic or water miscible surfactant, beauty treatment material or active component sometimes because these preparations are lipophilic.
Therefore, need a kind of hydrophilicly basically and can be coated on preparation on the Water adsorption towel, and they still transfer on the skin of user easily, can be with very low cost protection skin irriate and congested or avoid further stimulating and congested not.
Brief summary of the invention
Have now found that by making senior soft Water adsorption towel product at the individual deposit of a large amount of fusion hydrophilic compositions of the surface coated of napkin, described compositions comprises high-molecular weight Polyethylene Glycol, aliphatic alcohol (C 14～C 30) and emollient or comprise the solvent of water, said composition is solidified again, form solid deposits in the lip-deep a kind of distribution of Water adsorption towel, preferably distribution uniformly.Because said composition is a solid under the room temperature, the deposition back is rapid solidifies, and infiltration is just seldom arranged and immerse the interior tendency of lamella.Compare with the Water adsorption towel of handling with liquid preparation, this Water adsorption towel stays the interpolation compositions of bigger percentage ratio in its surface, and said composition can and be transferred on the skin with the contact skin of user like this, with the benefit that provides the front to say.Have again, can provide same effect with less addition, because said composition is distributed on the surface of product basically effectively with low cost.
Therefore, on the one hand, the invention reside in and contain about 30～90wt% hydrophilic solvent, about 10～approximately its molecular weight of 50wt% about 720 or higher high molecular weight polyethylene glycol, about 5～approximately C of 40wt% 14～C 30The softening compositio of aliphatic alcohol, the fusing point of described compositions are about 30～about 70 ℃, and it is about 5～approximately 360mm that pin is gone into hardness.
On the other hand, the invention reside in a kind of Water adsorption towel product, wherein the one or both sides of product external surfaces are solidified with a kind of deposit of compositions, said composition contains about 30～approximately 90wt% hydrophilic solvents, about 10～approximately 50wt% high molecular (be defined as at room temperature is solid) Polyethylene Glycol and about 5～approximately aliphatic alcohol of 40wt%, the fusing point of described compositions is about 30～about 70 ℃, and it is that about pin is gone into 5～approximately 360mm that pin is gone into hardness.
Another aspect, the invention reside in a kind of method of making soft Water adsorption towel or towel products, this method comprises: the compositions that (a) will contain hydrophilic solvent, high molecular weight polyethylene glycol and aliphatic alcohol is heated to above the temperature of said composition fusing point, make the said composition fusion, the fusing point of described compositions is about 30～about 70 ℃; (b) fused compositions is coated on the one or both sides on Water adsorption towel stock surface equably with the deposit form of separating of having living space; And (c) deposit of this melt composition is solidified again.Again the curing of this deposit can almost take place immediately, if the temperature of said composition heating is only high slightly or just be heated to the fusing point of compositions than the fusing point of compositions, does not then need the chiller of outside, such as the chilling roller.Yet, if wish to quicken solidification process again, can be before the coating melt or use later on outside chiller, as the chilling roller.Solidifying again immediately like this tended to hinder in the said composition infiltration napkin, and it is retained on the surface of napkin, and this is favourable.Can preferably be higher than about 10 ℃ or still less of fusing point such as, the temperature of fused compositions, particularly be higher than about 5 ℃ or still less, be higher than about 2 ℃ or still less more especially.General temperature when melt composition is during near fusing point, and the viscosity of melt composition will increase, and this has further strengthened melt composition and has been trapped in surperficial tendency.
Be used for this paper purpose, " fusing point " is the temperature of most of material when fusion occurring, it is believed that fusion is actually to take place in a temperature range.The fusing point of the present composition can be about 30～about 70 ℃, particularly about 40～about 70 ℃, and more especially about 50～about 60 ℃.
In addition, be used for this paper purpose, " pin is gone into hardness " is according to ASTM D1321, the needle penetration in mm of " needle penetration of pertroleum wax ".Low more pin is gone into hardness number, and to be equivalent to material hard more.It can be about 5～approximately 360mm that the pin of the present composition is gone into hardness, the about 200mm of particularly about 5-, more especially about 5～approximately 150mm, especially about 5～approximately 100mm.(with ASTM D1321 method not energy measurement go into the preparation of hardness greater than the 360mm pin).For two reasons, the hardness of preparation of the present invention is important.At first, preparation is soft more, and preparation is just easy more to flow, and makes the internal layer of the easier immersion napkin of said preparation, and this is undesirable.Secondly, softer preparation tends to have greasy sense of touch, and this also is undesirable.In general, that pin is gone into hardness is about 200～and approximately the preparations of 360mm feel to resemble cream has greasy feeling when the poorest slightly, and slickness poor slightly (difference that depends on additive).Pin is gone into about 5～approximately preparations of 200mm of hardness and is felt as the smooth butter that resembles at most of silk, very smooth (difference that depends on additive).
Hydrophilic solvent comprises water (if present), and its consumption can be about 30～approximately 90wt%, more especially about 40～approximately 70wt%, more especially about again 50～approximately 60wt%.As employed in this article, suitable hydrophilic solvent includes, but is not limited to following material: (molecular weight is less than 720 for water, propylene glycol, low molecular poly, at room temperature be liquid), methoxyl group isopropyl alcohol, PPG-2 propyl ether, PPG-2 butyl ether, PPG-2 methyl ether, PPG-3 methyl ether, dipropylene glycol propyl ether, dipropylene glycol butyl ether, dipropylene glycol, methyl propanediol, propylene glycol carbonate, water solublity/water can disperse polypropylene glycol, glycerol, Sorbitol, hydrogenated starch hydrolysate and the silicone glycol of polypropylene glycol, ethoxylation.
The consumption of high molecular polypropylene glycol can be about 10～approximately 50wt% in the compositions, particularly about 10～approximately 30wt%, more especially about 15～approximately 25wt%.As used herein, high molecular weight polyethylene glycol is mean molecule quantity 720 or bigger Polyethylene Glycol.At room temperature these materials are not liquid.The molecular weight of the high molecular weight polyethylene glycol of particularly suitable can be 720～about 1,840,000, particularly about 1,400～about 440,000, more especially about 1,760～about 10,570.
The consumption of aliphatic alcohol is about 5～approximately 40wt% in the compositions, particularly about 10～approximately 30wt%, more especially about 15～approximately 25wt%.It is C that the aliphatic alcohol that is suitable for includes, but is not limited to carbon chain length 14～C 30Alcohol, comprise spermol, stearyl alcohol, arachidic alcohol and 22 carbon alcohol.
In order to strengthen interests, can use additional composition to consumer.The kind and the corresponding effects of these compositions include, but is not limited to: the anti-acne activating agent (a kind ofly is used for reducing the acne fault; acne lump; the medicine of blackhead and milium number); foam reducing composition (in the process of processing, reducing the tendency of foaming); antimicrobial activities; the antifungal activity agent; anticorrosion activating agent; antioxidant activity agent (integrity of product); convergence cosmetics (being included in tightening on the skin feels or the set sense); convergence medicine (a kind of medicine; do the time spent when being coated on skin or the mucosa and by the protein of cohesion; it stops oozes out; discharge or separate out); physiological additives (strengthen the performance of product or to the captivation of consumer); coloring agent (giving product colour); deodorant (reduces or eliminates undesirable abnormal smells from the patient; prevent to form bad smell) at body surface; emollient (mat its skin surface or in cortex as lubricant; reduce scurf and the ability of improving skin appearance; help to keep the softness of skin; smooth and submissive outward appearance); outside analgesic (a kind of medicine of topical application; it has local analgesia by the sensation receiver of chafe; anesthesia or itching relieving effect); film former (thereby when dry form successive film on the skin surface active component is remained on the skin); flavouring agent (to the captivation of consumer); wetting agent (increasing the water content of skin surface); natural humidizer (NMF) and in prior art known other skin moisturizing composition; opacifier (reducing the clarity or the transparent appearance of product); skin conditioning agent; remove the furfur agent and (strengthen the composition of Skin Cell conversion speed; such as 'alpha '-hydroxy acids and beta-hydroxy acid); Derma-Guard (is protected skin or mucomembranous surface injured or that expose; make it not to be subjected to the medicine of deleterious or painful stimulation); solvent (being used for being dissolved in the liquid of useful components in cosmetics or the medicine); sunscreen (absorb the ultraviolet of wavelength 290～320nm of at least 85%, but see through the ultraviolet composition that wavelength is longer than 320nm) and surfactant are (as detergent; emulsifying agent; solubilizing agent and suspending agent).
In addition, for these compositions, use anion, both sexes, cation, nonionic and/or zwitterionic surfactant, can be easy to about 0.01～approximately oily molten/oil-dispersing property or lipophilic substance of 20wt% is emulsified in the preparation.Lipophilic substance includes, but is not limited to polysiloxanes/organic modified polyorganosiloxane (protective effect, make that Water adsorption towel is water-fast, lubricity, Water adsorption towel flexibility), oils (mineral oil, vegetable oil and animal oil), fatty ester etc.In prescription, also can disperse to strengthen lubricity, oil absorbing, the powder of skin care, convergence, shading etc. and the composition of micro encapsulation be provided.
Based on the gross weight of Water adsorption towel, the total amount that Water adsorption towel adds compositions can be about 0.5～approximately 40wt%, particularly about 5～approximately 30wt%, more especially about 10～approximately 15wt%.Addition will depend on wishes that said composition is to properties of product role and the kind that depends on concrete compositions.It is intaglio offset that the compositions that heats is uniformly applied to the lip-deep method for optimizing of Water adsorption towel stock, can be direct, also can be indirect,, can carry out maximum control the distribution and the transfer velocity of compositions because this is the most accurate printing process.Yet, can use other printing process, such as aniline printing or dust the printing as WEKO.
As employed in this article, the scope that all consumptions of enumerating, temperature, molecular weight and pin are gone into hardness all means the preferred range once more that comprises within the cited scope, even do not point out specially.
As employed in this article, " Water adsorption towel product " can be face-cloth, bath towel, napkin, napkin etc. equally.Water adsorption towel product of the present invention can be monolayer, bilayer, trilaminar or multiwalled.In all cases, treat product drying after, described compositions is coated on the outer surface or two outer surfaces of product.Can after ply of paper lumps together or in the past, said composition be coated with.Can (evenly) of monolayer wrinkling or not corrugated ply of paper be closed or mix by dry-pressing or wet pressing.Be surprised to find that the substrate of blended Water adsorption towel substrate and lamination provides the same performance, so the fiber stratification is not necessary.
Embodiment
Embodiment 1
Prepare pin composed as follows and go into hardness, the soft chemical preparation (softish semi-solid jelly) of Water adsorption towel that fusing point is about 28 ℃ greater than 360mm:
wt％
1) propylene glycol 40.00
2) the Stearalkonium chloride 85% 1.00
3) cetomacrogol 1000 40.00
4) glycerol 19.00
Propylene glycol is heated to 45～50 ℃, adds Stearalkonium chloride and cetomacrogol 1000, mix until fusion.Add glycerol then and mix until evenly.At this moment preparation can use, and is coated on Water adsorption towel or the towel substrate by intaglio offset.This preparation is softish semisolid.It is too soft can not to be fixed on the surface of substrate, but has provided soft effect.In this prescription, used glycerol, provide the humidification effect to skin.
Embodiment 2
Prepare pin composed as follows and go into hardness, the soft chemical preparation (softish semi-solid jelly) of Water adsorption towel that fusing point is about 29 ℃ greater than 360mm:
wt％
1) propylene glycol 20.00
2) the Stearalkonium chloride 85% 1.10
3) cetomacrogol 1000 40.00
4) glycerol 38.90
Propylene glycol is heated to 45～50 ℃, adds Stearalkonium chloride (the Mackernium SDC-85 of McIntyre company) and cetomacrogol 1000, mix until fusion.Add glycerol then and mix until evenly.At this moment preparation can use, and it is coated on Water adsorption towel or the towel substrate.This preparation is softish semisolid, with 5% of Water adsorption towel weight, is coated on not corrugated on the one side of air dried bath towel by the aniline printing method.This bath towel is very soft.Yet because this preparation is semisolid, said preparation can not be fixed on the surface of substrate.
Embodiment 3 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 170mm, the soft chemical preparation (pliable solid) of Water adsorption towel that fusing point is about 44 ℃:
wt％
1) propylene glycol 15.00
2) the Stearalkonium chloride 75% 1.00
3) cetomacrogol 1000 50.00
4) spermol 10.00
5) hydrogenated starch hydrolysate 24.00
Propylene glycol is heated to 45～50 ℃, adds Stearalkonium chloride, cetomacrogol 1000 and spermol, mix until fusion.Add hydrogenated starch hydrolysate then and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of napkin or towel.This preparation is a pliable solid, when being coated with, can be fixed on the surface of substrate.In this prescription, use hydrogenated starch hydrolysate, provide the humidification effect to skin, and cost is lower than glycerol.It is not counted as the such VOC of propylene glycol (VOC) yet, can partly replace propylene glycol.
Embodiment 4 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 130mm, the soft chemical preparation (pliable solid) of Water adsorption towel that fusing point is about 45 ℃:
wt％
1) propylene glycol 15.00
2) the Stearalkonium chloride (75%) 1.00
3) cetomacrogol 1000 25.00
4) Polyethylene Glycol 3,350 25.00
5) spermol 10.00
6) hydrogenated starch hydrolysate 24.00
Propylene glycol is heated to 45～50 ℃, adds Stearalkonium chloride, cetomacrogol 1000 and 3350 and spermol, mix until fusion.Add hydrogenated starch hydrolysate then and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.This preparation is the solid harder than front embodiment, because used Polyethylene Glycol 3350.
Embodiment 5 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 135mm, the soft chemical preparation (solid) of Water adsorption towel that fusing point is about 57 ℃:
wt％
1) propylene glycol 20.00
2) the Stearalkonium chloride 85% 5.00
3) cetomacrogol 1000 25.00
4) Polyethylene Glycol 8,000 25.00
5) hydrogenated starch hydrolysate 25.00
Propylene glycol is heated to 50～55 ℃, adds cetomacrogol 1000 and 8000, mix until fusion.Add hydrogenated starch hydrolysate then and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.This preparation is harder than each embodiment of front, because used Polyethylene Glycol 8000.
Embodiment 6 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 94mm, the soft chemical preparation (solid) of Water adsorption towel that fusing point is about 55 ℃:
wt％
1) propylene glycol 20.00
2) PEG400 10.00
3) cetomacrogol 1000 25.00
4) Polyethylene Glycol 8,000 25.00
5) hydrogenated starch hydrolysate 20.00
Propylene glycol and PEG400 are heated to 55～60 ℃, add cetomacrogol 1000 and 8000 then, mix until fusion.Add hydrogenated starch hydrolysate then and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.
Embodiment 7 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 238mm, the soft chemical preparation (solid) of Water adsorption towel that fusing point is about 50 ℃:
wt％
1) propylene glycol 10.00
2) PEG400 10.00
3) cetomacrogol 1000 20.00
4) Polyethylene Glycol 8,000 30.00
5) hydrogenated starch hydrolysate 20.00
6) dimethicone copolyol 10.00
Propylene glycol and PEG400 are heated to 55～60 ℃, add cetomacrogol 1000 and 8000, mix until fusion.Add hydrogenated starch hydrolysate and dimethicone copolyol (190 surfactants of Dow Corning company) then and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.In this prescription, use dimethicone copolyol that more soft/more slick feel is provided to substrate surface.
Embodiment 8～10 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 10～65mm, the soft chemical preparation (solid) of the napkin that contains different glycols hydrophilic solvents that fusing point is about 50～54 ℃:
8wt％ 9wt％ 10wt％
1) propylene glycol 55.00--
2) PEG400-55.00-
3) MP glycol-20.00 55.00
4) Polyethylene Glycol 8,000 20.00 20.00 20.00
5) stearyl alcohol 20.00 20.00 20.00
6) the Stearalkonium chloride 5.00 5.00 5.00
Be prepared as follows these preparations, propylene glycol, Polyethylene Glycol or MP glycol are heated to 60 ℃, add Polyethylene Glycol, mix until fusion.(the MP glycol is a methyl propanediol).Add stearyl alcohol and Stearalkonium chloride and mix until evenly.At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.
Embodiment 11～13 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 20～130mm, the soft chemical preparation (solid) of the Water adsorption towel that contains humidification component and feel improver that fusing point is about 53～60 ℃:
11wt％ 12wt％ 13wt％
The A phase
1) propylene glycol 35.00 28.00 35.00
2) Polyethylene Glycol 8,000 20.00 15.00 20.00
3) 22 carbon alcohol 10.00 10.00 10.00
4) stearyl alcohol 10.00 10.00 10.00
5) hydrogenated starch hydrolysate-15.00-
6A)Hispagel?200 10.00 - -
B)Lubrasil - 7.00 -
C)Ostar?Arriveen?PG25 - - 10.00
The B phase
7) polydimethylsiloxane 100cSt 10.00 10.00 10.00
8) myristyl myristate 5.00 5.00 5.00
" Hispagel200 " is the glycerol of Hispano Quimica S.A. company manufacturing and the mixture of polyacrylic acid glycerol ester." Lubrasil " is the poly-silanol (dimethiconol) of polymethyl acid glyceride, propylene glycol, cyclohexyl methyl polysiloxanes, dimethyl of United Gardian company manufacturing and the mixture of polysorbate 20." Ostar ArriveenPG25 " is the propylene glycol of Canamino company manufacturing and the mixture of oat extract.
Be prepared as follows the A phase: propylene glycol is heated to 60～65 ℃, adds Polyethylene Glycol 8000, mix until fusion.Add 22 carbon alcohol, stearyl alcohol and Stearalkonium chloride and mix until fusion.Add hydrogenated starch hydrolysate again and mix until evenly.Add Hispagel 200, Lubrasil or Arriveen PG25 (depending on prescription) then, and preparation is mixed until evenly.
The method for making of B phase is that dimethyl polysiloxane and myristyl myristate are mixed together, and heating is until evenly.Under vigorous stirring, B joined mutually lentamente A mutually in.
At this moment preparation can use, and by intaglio offset it is coated on the substrate of Water adsorption towel or towel.
Embodiment 14～15 (the present invention)
Preparing pin composed as follows, to go into hardness approximately be 190～200mm, the antimicrobial formulation that fusing point is about 50～55 ℃:
14wt％ 15wt％
1) propylene glycol 64.00 57.00
2) the MP glycol 5.00 10.00
3) polyethylene glycol 6000 20.00 22.00
4) stearyl alcohol 10.00 10.00
5)Nipacide?PX 1.00 1.00
Propylene glycol and MP glycol are heated to 60～60 ℃, add polyethylene glycol 6000 and stearyl alcohol, mix until fusion.Add the antibacterial Nipacide PX that the Nipa laboratory is made, mix until dissolving.By intaglio offset these antimicrobial formulations are added on two wrinkle substrates, obtain antibacterial towel.
Each embodiment of the front that provides, its purpose is to illustrate, and scope of the present invention is not construed as limiting, following claim is used for limiting the present invention, with the present invention be of equal value.

Claims (33)

1. the soft Water adsorption towel or the towel products that have two outer surfaces, wherein one or two outer surface of this product is solidified with the deposit of following compositions, and said composition comprises about 30～90wt% hydrophilic solvent, about 10～approximately 50wt% molecular weight about 720 or higher high molecular weight polyethylene glycol and C of about 5～40wt% 14～C 30Aliphatic alcohol, the fusing point of described compositions are about 30～about 70 ℃, and it is about 5～approximately 360mm that pin is gone into hardness.
2. product as claimed in claim 1, wherein based on product weight, the addition of said composition is about 0.5～approximately 30wt%.
3. product as claimed in claim 1, wherein this hydrophilic solvent comprises water.
4. product as claimed in claim 1, wherein this hydrophilic solvent comprises propylene glycol.
5. product as claimed in claim 1, wherein this hydrophilic solvent comprises low molecular poly.
6. product as claimed in claim 1, wherein this hydrophilic solvent comprises glycerol.
7. product as claimed in claim 1, wherein this hydrophilic solvent comprises hydrogenated starch hydrolysate.
8. product as claimed in claim 1, wherein this aliphatic alcohol is a spermol.
9. product as claimed in claim 1, wherein this aliphatic alcohol is a stearyl alcohol.
10. product as claimed in claim 1, wherein this aliphatic alcohol is an arachidic alcohol.
11. product as claimed in claim 1, wherein this aliphatic alcohol is 22 carbon alcohol.
12. product as claimed in claim 1, wherein the molecular weight of high molecular weight polyethylene glycol is about 720～about 1,840,000.
13. product as claimed in claim 1, wherein the molecular weight of high molecular weight polyethylene glycol is about 1400～about 440,000.
14. make the method for soft Water adsorption towel or towel products, this method comprises: the compositions that (a) will contain hydrophilic solvent, high molecular weight polyethylene glycol and aliphatic alcohol is heated to above the temperature of said composition fusing point, cause the said composition fusion, the fusing point of described compositions is about 30～about 70 ℃; (b) mode of the deposit that fused compositions is separated to have living space is coated on the one or both sides on Water adsorption towel stock surface equably; And (c) deposit of this melt composition being solidified again, it is about 5～approximately 360mm that the pin of described cured compositions is again gone into hardness.
15., wherein be coated with this fused compositions by printing as the method for claim 14.
16. contain about 30～90wt% hydrophilic solvent, about 10～approximately 50wt% molecular weight about 720 or higher high molecular weight polyethylene glycol and C of about 5～40wt% 14～C 30The softness compositions of aliphatic alcohol, the fusing point of described compositions are about 30～about 70 ℃, and it is about 5～approximately 360mm that pin is gone into hardness.
17. as the compositions of claim 16, said composition contains one or more hydrophilic solvents that is selected from water, propylene glycol, low molecular poly, glycerol, Sorbitol, hydrogenated starch hydrolysate and silicone glycol.
18. as the compositions of claim 16, aliphatic alcohol wherein is selected from spermol, stearyl alcohol, arachidic alcohol and 22 carbon alcohol.
19. as the compositions of claim 16, wherein the consumption of hydrophilic solvent is about 40～approximately 70wt%.
20. as the compositions of claim 16, wherein the consumption of hydrophilic solvent is about 50～about 60%.
21. as the compositions of claim 16, wherein the consumption of high molecular weight polyethylene glycol is about 10～approximately 30wt%.
22. as the compositions of claim 16, wherein the consumption of high molecular weight polyethylene glycol is about 15～approximately 25wt%.
23., contain the spermol of the high molecular weight polyethylene glycol of the propylene glycol of about 15wt%, about 50wt%, about 10wt% and the hydrogenated starch hydrolysate of about 25wt% as the compositions of claim 16.
24., contain the high molecular weight polyethylene glycol of the propylene glycol of about 20wt%, about 50wt% and the hydrogenated starch hydrolysate of about 20wt% as the compositions of claim 16.
25., contain the hydrogenated starch hydrolysate of the high molecular weight polyethylene glycol of the low molecular poly of the propylene glycol of about 10wt%, about 10wt%, about 50wt%, about 20wt% and the dimethicone copolyol of about 10wt% as the compositions of claim 16.
26., contain the high molecular weight polyethylene glycol of the propylene glycol of about 55wt%, about 20wt% and the stearyl alcohol of about 20wt% as the compositions of claim 16.
27., contain the high molecular weight polyethylene glycol of the methyl propanediol of the low molecular poly of about 55wt%, about 20wt%, about 20wt% and the stearyl alcohol of about 20wt% as the compositions of claim 16.
28., contain the high molecular weight polyethylene glycol of the methyl propanediol of about 55wt%, about 20wt% and the stearyl alcohol of about 20wt% as the compositions of claim 16.
29., contain the glycerol of the stearyl alcohol of the 22 carbon alcohol of the high molecular weight polyethylene glycol of the propylene glycol of about 35wt%, about 20wt%, about 10wt%, about 10wt%, about 10wt% and the dimethyl polysiloxane of polyacrylic acid glycerol ester admixture and about 10wt% as the compositions of claim 16.
30. as the compositions of claim 16, the polyacrylic acid glycerol ester, propylene glycol, cyclohexyl methyl polysiloxanes, the dimethyl that contain the hydrogenated starch hydrolysate of the stearyl alcohol of the 22 carbon alcohol of the high molecular weight polyethylene glycol of the propylene glycol of about 30wt%, about 15wt%, about 10wt%, about 10wt%, about 15wt%, about 5wt% gather the mixture of silanol and polysorbate 20 and the dimethyl polysiloxane of about 10wt%.
31., contain propylene glycol and the mixture of oat extract and the dimethyl polysiloxane of about 10wt% of the stearyl alcohol of the 22 carbon alcohol of the high molecular weight polyethylene glycol of the propylene glycol of about 35wt%, about 20wt%, about 10wt%, about 10wt%, about 10wt% as the compositions of claim 16.
32., contain the high molecular weight polyethylene glycol of the methyl propanediol of the propylene glycol of about 65wt%, about 5wt%, about 20wt% and the stearyl alcohol of about 10wt% as the compositions of claim 16.
33., contain the high molecular weight polyethylene glycol of the methyl propanediol of the propylene glycol of about 55wt%, about 10wt%, about 20wt% and the stearyl alcohol of about 10wt% as the compositions of claim 16.
CN98808161A 1997-08-15 1998-07-29 Soft tissue achieved by applying solid hydrophilic lotion Expired - Fee Related CN1129377C (en)

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AU729700B2 (en) 2001-02-08
BR9815608B1 (en) 2008-11-18
WO1999008555A1 (en) 1999-02-25
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EP1043942A1 (en) 2000-10-18
DE69826894T2 (en) 2005-02-03
KR100542169B1 (en) 2006-01-12
CN1129377C (en) 2003-12-03
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US5869075A (en) 1999-02-09
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