CN1307862A - Novel lasting tint system containing no hydrogen peroxide and other substitutive chemical - Google Patents
Novel lasting tint system containing no hydrogen peroxide and other substitutive chemical Download PDFInfo
- Publication number
- CN1307862A CN1307862A CN 00107992 CN00107992A CN1307862A CN 1307862 A CN1307862 A CN 1307862A CN 00107992 CN00107992 CN 00107992 CN 00107992 A CN00107992 A CN 00107992A CN 1307862 A CN1307862 A CN 1307862A
- Authority
- CN
- China
- Prior art keywords
- hair
- lasting tint
- novel lasting
- novel
- tint system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
The present invention relates to a novel permanent hair dyes system free of hydrogen peroxide and other chemicals used for replacing hydrogen peroxide, such as ammonium persulphate, sodium persulphate, potassium persulphate or peroxydol or the like. The invention is capable of providing products in one package fashion, in two packages fashion or in more than two packages fashion. The formulator has optional spaces or flexibility in the aspect of determining ammonia or ammonia-type chemicals should be added to which package bag. As the lowest request, powdery oxidizability dyes ingredients, that is (mainly)intermediate and/or couplers, must be contained in one of the packaging bags of the novel permanent hair dyes system, regardless whether ammonia-type chemicals are contained in the same packaging bag or not. And then, before being applied to the hair, the powder must be mixed with water or predetermined liquid or gel which are provided together with the powdery product but in single package fashion. The obtained colour can be compared beauty with the colour obtained from the general permanent hair dyes system.
Description
Existing lasting tint product is sold as solution, gel, unguentum and aerocolloidal form with various forms.No matter which kind of form it takes, if having water in the prescription, then these product just must be a kind of two packing material systems.Must contain following chemical substance at least in first bag: 1) oxidative dyestuff composition, they are (main) intermediate and/or colour coupler or modifier.These compositions form dyestuff by the chemical reaction that is called as " Oxidation ".This reaction is to cause by the hydrogen peroxide that adding is contained in another packing material.2) stabilizing agent and/or antioxidant etc., sodium erythorbate for example, (partially) sulfurous acid (hydrogen) sodium, sodium sulfite etc.3) ammonia maybe can discharge other chemical substance of ammonia or ammonium ion, ammonium chloride for example, ammonium hydroxide, carbamide etc.4) other chemical substance.
Another bag can be called as " developer ", wherein contains stable hydrogen peroxide at least, when with first bag in composition when mixing, hydrogen peroxide reacts initiated oxidation.Thereby formation dyestuff.Hair dyeing method is at first to mix two compositions in the packaging bag, till mixture evenly.Then, this mixture is applied on the hair up hill and dale.Developed the color about 30-60 minute, perhaps till forming required color, with afterflush and dry.
If the lasting tint product is Powdered, then can be contained in all components in the packing material.Contained whole chemical substances must be selected from their the available powder or other dry-forms in present power formulations, and the prescription of powdered hair dye is similar to two packing material systems in theory.Be that the Powdered chemical substance that ammonia or ammonium hydroxide can discharge ammonia or ammonium ion when being contacted with water replaces, for example ammonium chloride, carbamide etc.Hydrogen peroxide is replaced by other chemical substance that is called as " oxidant ", for example Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.The hair colouring methods of powdery product is that the water of goods producer's ormal weight is added in this powder, stirs this mixture subsequently, up to powder dissolution and evenly till the time.Product is applied on the whole hair up hill and dale.Developed the color about 30-60 minute or till forming required color.With afterflush and dry.
Utilizing the shortcoming of these product hair dyeings is in the hair dyeing process, and user will be experienced unpleasant ammonia abnormal smells from the patient.Because the chemical substance of using in the permanent hair dyestuff, especially and mainly be ammonia and hydrogen peroxide, comprise those chemical substances that can discharge ammonia or ammonium ion, and those materials that are called as " oxidant ", Ammonium persulfate. for example, sodium peroxydisulfate or potassium peroxydisulfate, the cause of Dexol etc., hair fiber will lose its health characteristic, for example gloss and smooth feeling.In this external hair dyeing process, these chemical substances might scalp irritation.
The purpose of this invention is to provide a kind of novel lasting tint system, it does not contain hydrogen peroxide, and any other can be used in the chemical substance that replaces hydrogen peroxide, for example Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.Be similar to conventional lasting tint system, ammonia and other chemical substance that can discharge ammonia or ammonium ion are still the key component of this novel lasting tint system.These chemical substances are to open epidermal area, and being convenient to dye molecule, to diffuse into hair fiber necessary.So, except the problem of ammonia taste, this novel lasting tint system can overcome many shortcomings, and promptly this novel lasting tint system can not damage hair fiber, and in the hair dyeing process, this novel lasting tint system can scalp irritation.
The inventor also finds by the quality of the color of novel lasting tint system generation suitable with the conventional lasting tint system that contains ammonia and hydrogen peroxide: as color and luster, tinctorial strength, spreadability, anti-shampoo, uviolresistance and anti-perspire etc.
Novel lasting tint system has suitable viscosity or gel-like consistency, so it can not stain user and does not wish painted place, for example clothes, health etc.
The present invention also will provide and utilize the proper method of this novel lasting tint system to coloring hairs.
As an example, the inventor provides three kinds of methods, but this does not mean to have only three kinds of methods to use together with this novel lasting tint system.
1) product only is made up of a sealing bag and an empty, and the powder of novel lasting tint system product is housed in the sealing bag, and the surface of empty is marked with labelling, is used to inform that user is added to the required volume of this labelling to water.In addition, also can comprise the apparatus that stirs the mixture, for example stirring rod etc.
1.1) open the sealing bag, the content in the bag is poured in the empty that provides.
1.2) in this container, add water, till institute's target labelling on the surface.
1.3) stir with the apparatus that provides, till mixture dissolves fully and is gel.
1.4) this mixture is applied on the hair up hill and dale.The combing hair is distributed to mixture on whole hair fibers with help.
1.5) colour developing 30-60 minute or till forming required color.Flushing and dry hair.
2) product is made up of two sealing bags.A sealing bag contains the powder of novel lasting tint system, and another sealing bag contains the gel finished product.Also comprise the apparatus that is used to stir in addition, for example stirring rod etc.
2.1) open the sealing bag of the powder that contains novel lasting tint system, the thing in the bag is poured in the packing material that contains gel products.
2.2) stir with the apparatus that provides, till mixture is fully evenly.
2.3) then carry out 1.4) and 1.5).
3) product is made up of two sealing bags.First sealing bag contains the powder of novel lasting tint system, and another sealing bag contains the aqueous solution that is tuned to proper pH value, and when with the powder mixes of first sealing bag, it will produce gel-like consistency.
3.1) open the sealing bag of the powder that contains novel lasting tint system, the thing in the bag is poured in the packing material that contains the aqueous solution that is tuned to proper pH value.
3.2) stir with the apparatus that provides, till the even fully also gel of mixture.
3.3) then carry out 1.4) and 1.5).
Novel lasting tint system can be effectively to various types of coloring hairs: as permanent wave, stretching, the hair that has licked, the hair that had dyed, impaired hair (physics and chemical damage), the hair (for example hair dryer etc. heating) that stands some form heating, achromachia, poliosis, the palm fibre hair to brownish black hair (comprising beard, chesk hair, moustache) and other position of health.Because the denseness of this new hair colouring systems is suitable, user can be to the coloring hairs of health different parts.
Novel lasting tint system of the present invention originates from the needs that improve and eliminate most of shortcomings of conventional tint system.Conventional tint system always contains ammonia or ammonium hydroxide, comprises that ammonia type material promptly can discharge the chemical substance of ammonia or ammonium ion, for example ammonium chloride, carbamide etc.In addition, conventional tint system must contain hydrogen peroxide or be called as the chemical substance of " oxidant ", for example Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.In the hair dyeing process, all these chemical substances can produce physics or chemical damage to hair fiber, cause bad hair characteristic, for example tarnish, bifurcated, coarse, lack smooth feeling etc.In addition, all chemical substances, especially ammonia and the hydrogen peroxide mentioned here may stimulate the skin of user.Because the viscosity of conventional tint system is lower, all are present in the equal skin that may and be easy to contact user of these chemical substances wherein.Follow long hair dyeing process, these chemical substances very likely cause stimulating to the skin of user like this.In addition, because the viscosity of conventional lasting tint system is lower, in the hair dyeing process, it may stain user and not wish painted place.
In addition, another shortcoming of Chang Gui lasting tint system is that product uses inconvenience.Like this, user dyes not only even but also well for the hair that makes them, and they must arrive the beauty parlor and have hair dyed.So just to hair dyeing, user will lose a large amount of time and moneys.
The inventor finds not contain hydrogen peroxide and other any chemical substance that replaces hydrogen peroxide that can be used in, and for example be called as the chemical substance of " oxidant ": the novel lasting tint system of Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc. can solve and improve above mentioned most of shortcoming.In addition, the quality of the color that produces by novel lasting tint system and no less than the lasting tint system of routine.Described quality of colour is meant color and luster, tinctorial strength, spreadability, anti-shampoo, uviolresistance and perspire etc.
Product of the present invention does not contain hydrogen peroxide, and other any chemical substance that can be used for replacing hydrogen peroxide.So can solve the problem of chafe and damage hair fiber basically fully.This means that degree or probability that skin irritation and hair fiber damage have significantly been reduced.But because for having hair dyed lastingly by opening epidermal area, ammonia remains essential composition, therefore the problem (be unpleasant ammonia abnormal smells from the patient) relevant with ammonia still is not resolved.However, comparing new system with conventional system will be more soft still, and be suitable for very much the coloring hairs of user to them.In addition, although new system does not contain hydrogen peroxide in prescription, by the quality of the color of novel lasting tint system generation and no less than the lasting tint system of routine.In addition, new invention has suitable viscosity or gel-like consistency; Stain undesirable place thereby also solved, for example the problem at other position of clothes, furniture, health etc.And, the hair at other position of health outside to hair, for example during hair dyeing such as chesk hair, armpit hair, moustache, beard, user is easy to the controlling liquid coating.New invention also is easy to use.Thereby user can oneself be had hair dyed, and needn't go to lose time and money to the beauty parlor.
For a long time, it is in order to form conventional lasting tint product all the time that hydrogen peroxide and other can be used for replacing the chemical substance (that is: Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.) of hydrogen peroxide, and obtains the necessary composition of lasting color in hair fiber.Obviously, novel lasting tint system of the present invention obviously is different from conventional hair colouring systems, and the inventor will point out to obtain all information and the method that this novel lasting tint system is taked now.
1) novel lasting tint system will not contain hydrogen peroxide and can be used for replacing the chemical substance of hydrogen peroxide with other, for example Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.So, can not have stabilizing agent and/or antioxidant etc. in the prescription, for example sodium erythorbate, (partially) sulfurous acid (hydrogen) sodium, sodium sulfite etc.Otherwise, just can not take place in hair fiber, producing pigment necessary (being called as Oxidation) chemical reaction.That is, this reaction is owing to existing stabilizing agent and/or antioxidant to be suppressed.Usually, the hydrogen peroxide effect of stabilizing agent and antioxidant that neutralized; Then, hydrogen peroxide causes the dyestuff composition to oxidisability, i.e. (main) oxidization of intermediates reaction.Like this, by making (main) intermediate and colour coupler or modifier coupling formation pigment.But, in novel lasting tint system, do not exist hydrogen peroxide and any other to be used to replace the chemical substance of the effect of hydrogen peroxide, for example Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.Thereby under the situation that does not have hydrogen peroxide, the formed pigment of novel lasting tint system of the present invention is to produce by another oxidation reaction that is called as " air oxidation effect " or " autooxidation ".Under the situation that has stabilizing agent and/or antioxidant, because they are to the inhibitory action of this reaction, such oxidation reaction can not produce pigment.
2) effect of stabilizing agent and/or antioxidant is to prolong the oxidative dyestuff composition, that is: the shelf life of (main) intermediate and colour coupler is especially when they are present in the aqueous system.But as mentioned above, stabilizing agent and/or antioxidant can not be present in the prescription of novel lasting tint system of the present invention.So this system can not take liquid form, aqueous system especially, for example: solution, unguentum etc.For this reason, as minimum requirements, no matter whether also will there be other powder chemistry material in same packaging bag, in a packaging bag, new system must comprise pulverous oxidative dyestuff composition, that is: (main) intermediate and/or colour coupler all the time.
3) do not exist hydrogen peroxide and any other to be used to replace the chemical substance of hydrogen peroxide effect, for example under the situation of Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc., as previously mentioned, the formed pigment of novel lasting tint system of the present invention is to produce by the oxidation reaction that is called as " air oxidation effect " or " autooxidation ".Developing time by this reaction is gratifying; That is, can in 30-60 minute, develop the color, as the lasting tint system of routine.
4) because product must be taked non-water form, therefore can not use self aqueous ammonia or ammonium hydroxide.Alternate method is to use the Powdered chemical substance that can discharge ammonia or ammonium ion when it contacts with water, i.e. ammonia type material can be: ammonium chloride, carbamide, carbonic acid (hydrogen) ammonium etc.For 1 bagged product, situation is like this.But, if the same with conventional lasting tint product, be 2 bagged products, then another bag can be gel or the aqueous solution that contains ammonia or ammonium hydroxide.In a word, amino molecule is indispensable to this prescription, and they can moisture form (for example Ammonia) use, and perhaps uses with powder type (for example carbonic acid (hydrogen) ammonium), depends on that formulator wants which bag amino molecule is added in.For example, if formulator wants amino molecule is added in the powder packets pack then selective chlorination ammonium, carbamide, carbonic acid (hydrogen) ammonium etc.If formulator is wanted amino molecule is added in another packaging bag that contains gel or aqueous solution, then select ammonium hydroxide.
The quality of the color that produces according to the described novel lasting tint system of the present invention of the information that provides above is no less than the lasting tint system of routine, and described quality is color and luster, tinctorial strength, spreadability, anti-shampoo, uviolresistance and perspire etc.
Like this, the prescription of novel lasting tint system of the present invention comprises following chemical substance: 1) oxidative dyestuff composition, they are (main) intermediate and/or colour coupler etc.2) thickening agent or gellant, that is: carbopol, xanthane glue (xanthan gum) etc.3) amino molecule or ammonium ion, for example ammonium hydroxide, carbamide, carbonic acid (hydrogen) ammonium etc.4) regulator and/or other trichotrophy chemical substance, that is: Powdered aminosal, milk powder etc.5) remove hydrogen peroxide and can be used for replacing the chemical substance of hydrogen peroxide with other, the chemical substance that for example is called as " oxidant ": outside Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, the Dexol etc., the inventor thinks any other chemical substance useful to this product.
The same as previously mentioned, as minimum requirements, no matter in same packaging bag, whether also will there be other powder chemistry material, in a packaging bag, novel lasting tint system must comprise oxidative dyestuff composition, that is: the powder of (main) intermediate and/or colour coupler all the time; So, this powder must with tap water, Emulsion or and another packaging bag of providing of powder packets pack in the liquid, aqueous or gel that provides mix, the denseness of this gel is more than 5000 centipoises.So that before being applied to this product on the hair, powder is mixed with suitable form, i.e. gel form or have the form of d spiss, this gel form or the viscosity with form of d spiss also are more than 5000 centipoises.In fact, exist multiplely, powder is transferred to the method for suitable viscosity before powder coating is to the hair.But, as an example, the inventor will provide three kinds of methods here.First method is (from the beginning) water (preferably deionized water) or Emulsion to be added to be equipped with in the packing material of powder simply, stir subsequently or mix, when mixture is dissolved and even till.Second method is applicable to 2 packed systems.A packaging bag contains Powdered oxidative dyestuff composition at least, and this oxidative dyestuff composition is (main) intermediate and/or colour coupler.In fact, in this packaging bag, also can comprise other chemical substance, as long as they help to provide suitable denseness and good colour developing.Another packaging bag contains the aqueous solution or the ammonia solution that will form gel when with powder mixes.This method is the content mix of these two packaging bags together, when mixture is transparent and even till.Subsequently, it is coated on the hair.Here the last a kind of method that provides also is applicable to 2 packed systems.Think and contain Powdered oxidative dyestuff composition in the packaging bag under the situation of other useful chemical substance that this oxidative dyestuff composition is (main) intermediate and/or colour coupler comprising or do not comprise formulator to finished product.Another packaging bag contains the modulated gel that makes, and it can contain also can not contain ammonia or ammonium ion.This method is that powdered contents and the gel that modulates are mixed, dissolved up to powdered contents, when gel becomes even till.Subsequently, it is coated on the hair.Here the gel that has modulated mentioned comprises and uses other chemical substance to make by other various chemical methodes, even can adopt commercially available those persons mile (hair gel), for example hair style person mile (stylinggel), hair care person mile etc.This also is one of advantage of novel lasting tint system of the present invention.Thereby for the user, it is very convenient that this new hair dyes system.For 2 packed systems, if formulator is wanted to add amino molecule in the powder packets pack, then selective chlorination ammonium, carbamide, carbonic acid (hydrogen) ammonium etc. if still formulator wants to add amino molecule in another packaging bag that contains gel or aqueous solution, are then selected for example ammonium hydroxide.
Can use multiple oxidative dyestuff and hair dye among the present invention, they are (main) intermediate and/or colour coupler or modifier, for example, fragrance phenol, multi-ring phenol, have (ortho position, a position, para-position) substituent hydroxy benzenes, substituent group can be for example nitro, amino, acylamino-, sulfo group, chloro, bromo and their combination.Example comprises, but is not limited to: bit amino phenol etc. between p-phenylenediamine (PPD) (para phenylenediamine), hydrochloric acid p-phenylenediamine (PPD) (paraphenylenediamine hydrochloride), sulphuric acid p-phenylenediamine (PPD) (paraphenylenediamine sulfate), sulphuric acid m-diaminobenzene. (meta phenylenediaminesulfate), ortho position, a position and para-position amino-phenol, sulphuric acid.Other oxidative dyestuff also can be used in the novel lasting tint system of the present invention's proposition.In addition, direct dyes, disperse dyes and be used in other stain in the semipermanent hair coloring system usually and also can be used for cooperating (main) intermediate and/or colour coupler or modifier in the novel lasting tint system are so that adjust, change and help to produce gratifying final color in user-hair.Example includes, but are not limited to: ortho position, a position and para-position nitrophenol, 2-nitrophenylene diamine.
Not can be used for replacing the chemical substance of hydrogen peroxide owing to do not contain hydrogen peroxide in the novel lasting tint system of the present invention with other, the chemical substance that for example is called " oxidant ": therefore Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc. have many advantages.For example, 1) user needn't be in the face of possibility of skin irritation in permanent hair dyeing process.2) painted hair fiber no longer is subjected to the damage that hydrogen peroxide and other can be used for replacing the chemical substance of hydrogen peroxide.3) owing to there is not hydrogen peroxide, natural hair color can not die down again now.
This new invention also can comprise and be called as the chemical substance that " wetting agent " usefulness is helped dissolved powders.Wetting agent includes, but are not limited to: propylene glycol (propylene glycol), Polyethylene Glycol series, sorbitol, glycerol etc.
In the past, when considering that product uses preceding commercial shelf life, because at the mixture with high pH value staining solution, the application of the perhaps unstability of protein derivatives in peroxide solutions, so protein derivatives in the lasting tint system of routine is restricted always.But new system of the present invention has a packaging bag that contains Powdered oxidative dyestuff composition all the time at least; So protein and/or protein derivatives can add in this packaging bag, and do not have problem of unstable.Protein and/or protein derivatives are, but are not limited to: milk powder, crotein Q etc.
Because glue or mixture of viscous form must be coated on all surface zone of hair fiber with good spreadability, and in the hair dyeing process, as dyestuff reservoir or dye bath, so that guaranteeing dye molecule fully diffuses in the hair fiber, therefore for dyeing course, appropriate viscosity or denseness are critical.The present invention also has gluey denseness, perhaps its also colloidal mixture, and the viscosity of gel or the denseness of jelly can be more than 5000 centipoises.So novel lasting tint system of the present invention also has following advantage: 1) the good spreadability of dye mixture on each single hair fiber.2) mixture contacts scalp hardly; Further reduced the probability that stimulates user's skin.3) colloidal mixture can not flow to that clothes, furniture and user do not want to stain other in the localities.By using carbopol, xanthane glue (xanthan gum) etc. can obtain gluey viscosity and denseness.
All compositions and chemical substance all are Powdered being mixed together.Subsequently, they are sieved, mix at last, till evenly by 60-80 purpose screen cloth.The particle size of powder is more little, and the rate of dissolution of powder is fast more.An illustration prescription of powdery product is: the oxidative dyestuff composition of 1.75 grams, it is (main) intermediate and/or colour coupler, the crotein Q of carbopol 940,0.5 grams of 0.42 gram, carbonic acid (hydrogen) ammonium of 0.85 gram.These powder will be packaged in a protection against the tide, the anti-ultraviolet packing material.
As an example, provided here before powdery product being coated on the user hair, modulated three kinds of methods of powdery product.This and do not mean that can be before being coated to powdery product on the hair, the method that is used to modulate powdery product is confined to this three kinds of methods, and just may approach for some that use in order more clearly to illustrate or to represent to be used to modulate powdery product.
1) product only is made up of a sealing bag and an empty, and the powder of novel lasting tint system of the present invention is housed in the sealing bag.The surface of this empty is marked with labelling, is used to inform water is added to this labelling the required volume of adopting of user.Powder in the sealing bag one is approximately 1 part of powder with the ratio of add water: 20-30 part water (weight ratio).In addition, also comprise the apparatus that stirs the mixture, for example stirring rod etc.Also can comprise a pair of gloves, in case stain the hands of user.Using method is:
1.1) open the sealing bag, the powder in the bag is poured in the empty that provides.
1.2) in this container, add water, till institute's target labelling on the surface.
1.3) stir with the apparatus that provides, till mixture dissolves also gel fully.
1.4) this mixture is applied on the hair.The combing hair helps mixture is distributed on the whole hair fiber.
1.5) colour developing 30-60 minute or till forming required color.Flushing and dry hair.
The viscosity of the jelly of above-mentioned formation is more than 5000 centipoises, and pH value is 7-10.In addition, above-mentioned empty can be at two differing heights of its outer surface, literally are expressed as down level and last level place is labeled, and user can be added to water the following level place of labelling earlier, and the thing in the mixer, when mixture is mixed well till; Subsequently the water of remainder is added to the last level place of labelling, and mixes, when forming cementitious mixtures or gel till.The viscosity of above-mentioned cementitious mixtures or gel is more than 5000 centipoises.
The water of above-mentioned adding can be the warm water, and the warm water not only can quicken to become the speed of colloidal mixture, and compares with room temperature water, will produce the better color effect.
2) product is made up of two sealing bags.A sealing bag contains the powder of novel lasting tint system, another sealing bag contains the gel finished product, the viscosity of this gel finished product is more than 5000 centipoises, can make simply to form gel with alkali or the neutralization of ammonia type alkali subsequently by with aqueous dispersion carbopol 940.The weight ratio of the gel finished product in the powder in the sealing bag one and another sealing bag is approximately 1 part of powder: 40-50 part gel.The viscosity of this gel finished product is more than 5000 centipoises.Also comprise the apparatus that is used to stir in addition, for example stirring rod etc. also can comprise a pair of gloves in addition.Using method is:
2.1) open the sealing bag of the powder that contains novel lasting tint system, the thing in the bag is poured in the packing material that contains gel products.
2.2) stir with the apparatus that provides, till mixture is fully evenly.
2.3) then carry out 1.4) and 1.5).
The viscosity of the uniform mixture of above-mentioned formation also is more than 5000 centipoises, and pH value is 7-10.
3) product is made up of two sealing bags.First sealing bag contains the powder of novel lasting tint system, and another sealing bag contains and is tuned to the liquid, aqueous of required pH value, and this pH value is 7-10, and when with the powder mixes of first sealing bag, it will produce gel-like consistency.This gel-like consistency is more than 5000 centipoises.The liquid, aqueous weight ratio that provides in powder in the sealing bag one and another sealing bag is approximately 1 part of powder: 20-30 part is liquid, aqueous.Using method is:
3.1) open the sealing bag of the powder that contains novel lasting tint system, the thing in the bag is poured into contained in the liquid, aqueous packing material that is tuned to required pH value.
3.2) stir with the apparatus that provides, till the even fully also gel of mixture.
3.3) then carry out 1.4) and 1.5).
The pH value of said mixture is 7-10, and viscosity is more than 5000 centipoises.
By these three kinds of methods, perhaps the colloidal mixture by any method preparation outside these three kinds of methods must once use; That is, can not preserve this mixture for use next time, even back to back also not all right next time.Be some example formulation of novel lasting tint system of the present invention below.Owing to obtaining not contain hydrogen peroxide, and in the scope of the novel lasting tint system of the present invention of other any chemical substance that can be used for replacing hydrogen peroxide, can there be many alter modes, therefore following Example is not to be used to limit the invention to these examples, but is used for illustrating the present invention clearlyer.
Example 1 crineous
| Composition | Gram/each packaging bag |
| P-phenylenediamine (PPD) | ????1.25 |
| Para-aminophenol | ????0.08 |
| M-aminophenol | ????0.03 |
| ????Carbopol?940 | ????0.5 |
| Ammonium carbonate | ????1.2 |
| Protein | ????0.2 |
Do not contain hydrogen peroxide in this prescription, and other can be used for replacing the chemical substance of hydrogen peroxide, for example be called as the chemical substance of " oxidant ": Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.This is the example of the product that can use according to above mentioned first method.It is the ready-made powdery product that can use, and does not need second packaging bag to cooperate it to use.Can form colloidal mixture by add entry in this powder, the viscosity of this colloidal mixture is 5000 centipoises, and powder is 1: 25 with the weight ratio of add water.Subsequently colloidal mixture is coated on the hair.Lose and use the remaining mixture in back.
Example 2 crineous
| Composition | Gram/each packaging bag |
| P-phenylenediamine (PPD) | ????1.25 |
| Para-aminophenol | ????0.08 |
| M-aminophenol | ????0.03 |
| Protein | ????0.2 |
Do not contain hydrogen peroxide in this prescription, and other can be used for replacing the chemical substance of hydrogen peroxide, for example be called as the chemical substance of " oxidant ": Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.This is the example of the product that can use according to above mentioned second method.It is before being coated on the hair, must and together provide the blended powdery product of gel finished product in the sealing bag two with sealing bag one.The ratio of the gel finished product in powder in the sealing bag one and the sealing bag two is 1: 45.The viscosity of gel finished product and mixture is 5000 centipoises.After the use, lose remaining mixture.In addition, this powder-product very easy to use, so that it can use together with commercially available any person mile (hair gel).As previously mentioned, formulator can add carbonic acid (hydrogen) ammonium or other when contacting with water in powder packets pack, can discharge the chemical substance of ammonia or ammonium ion.In addition, formulator can add ammonium hydroxide or dissolved carbonic acid (hydrogen) ammonium in another packaging bag that contains gel for this example, and perhaps other can discharge the chemical substance of ammonia or ammonium ion when contacting with water.
Example 3 crineous
| Composition | Gram/each packaging bag |
| P-phenylenediamine (PPD) | ????1.25 |
| Para-aminophenol | ????0.08 |
| M-aminophenol | ????0.03 |
| Protein | ????0.2 |
| ????Carbopol?940 | ????0.5 |
Do not contain hydrogen peroxide in this prescription, and other can be used for replacing the chemical substance of hydrogen peroxide, for example be called as the chemical substance of " oxidant ": Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.This is the example of the product that can use according to above mentioned the third method.Sealing bag one is equipped with the powder of this prescription, and sealing bag two contains the aqueous solution of the pH value that is adjusted to requirement, and this pH value is 8.PH value is that the ratio of 8 aqueous solution is 1: 30 in powder in the sealing bag one and the sealing bag two.This aqueous solution when with sealing bag one in powder mixes the time, will produce gluey denseness, this denseness is 5000 centipoises.After the hair dyeing process is finished, lose and use the remaining mixture in back.Also can add the wetting agent such as polyol, glycerol, sorbitol in this aqueous solution; With such as polysorbas20, cremophore RH40, be used for the dissolved surfactant of fragrance.As top example 2, formulator can add carbonic acid (hydrogen) ammonium or other when contacting with water in powder packets pack, can discharge the chemical substance of ammonia or ammonium ion.In addition, formulator can add ammonium hydroxide or dissolved carbonic acid (hydrogen) ammonium in another packaging bag that contains aqueous solution for this example, and perhaps other can discharge the chemical substance of ammonia or ammonium ion when contacting with water.
Scope of the present invention is not limited to detail discussed above.Other details can comprise: 1) except crineous, can form various color and lusters, for example aubergine, brownish red, black naturally, burgundy color (burgundy) etc.2), can change the concentration of every kind of composition in the prescription according to required final response and performance.3) can comprise additional additive in the prescription, for example polyquats etc.4) any chemical substance in the prescription can be replaced by other chemical substance that formulator sees fit, and for example replaces water etc. with Emulsion.5) except three kinds of methods that provide, be used to prepare powdery product here for the method for using.6) do not contain hydrogen peroxide with preparation and any other can be used for replacing the relevant others of scope of lasting tint product of the chemical substance of hydrogen peroxide.7) or the like ...All details of mentioning among the present invention also are not used in the present invention are limited to these details, but are used to be illustrated more clearly in the present invention.
Claims (36)
1. novel lasting tint system, it is characterized in that it to be 1 bagged product, 2 bagged products or adorn product more than 2 bags, wherein do not contain hydrogen peroxide and other can be used for replacing the chemical substance of hydrogen peroxide, as minimum requirements, no matter whether have the chemical substance that when contact water, can discharge ammonia or ammonium ion in this packaging bag, must contain Powdered oxidative dyestuff composition all the time at least one packaging bag of this system.
2. novel lasting tint system as claimed in claim 1 is characterized in that said Powdered oxidative dyestuff composition is (main) intermediate and/or colour coupler; It is described that to can be used for replacing the chemical substance of hydrogen peroxide can be Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc.
3. novel lasting tint system as claimed in claim 1 is characterized in that under the situation of 1 bagged product, must have the chemical substance that can discharge ammonia or ammonium ion when contact water in the packaging bag simultaneously.
4. as claim 1 or 3 described novel lasting tint systems, it is characterized in that the described chemical substance that can discharge ammonia or ammonium ion when contact water can be ammonium chloride, carbamide, carbonic acid (hydrogen) ammonium etc.
5. novel lasting tint system as claimed in claim 1 is characterized in that if add amino molecule in powder packets pack, then can selecting ammonium chloride, carbamide, carbonic acid (hydrogen) ammonium etc. at 2 bagged products or more than 2 bags under the situation of dress product; If in the other packaging bag that contains gel or aqueous solution, add amino molecule, then can select ammonium hydroxide.
6. novel lasting tint system as claimed in claim 2, it is characterized in that described (main) intermediate and/or colour coupler can be fragrant phenol, multi-ring phenol, have (ortho position, a position, para-position) substituent hydroxy benzenes, substituent group can be for example nitro, amino, acylamino-, sulfo group, chloro, bromo and their combination.
7. novel lasting tint system as claimed in claim 1 is characterized in that wherein also can comprising thickening agent or gellant, regulator, and can be used for regulating the characteristic of final products and other chemical substance of performance etc.
8. novel lasting tint system as claimed in claim 7, it is characterized in that wherein thickening agent or gellant can be carbopol or xanthane glue, regulator can be crotein Q or sucrose, and the wetting agent that can be used for regulating other chemical substance of the characteristic of final products and performance can be propylene glycol or glycerol.
9. prepare the method for novel lasting tint system as claimed in claim 1, it is characterized in that powdery product can be with water or other mix homogeneously such as liquid, aqueous or aqueous gel.
10. the method for preparation novel lasting tint system as claimed in claim 9, it is characterized in that described liquid, aqueous can be Emulsion, be adjusted to the aqueous solution etc. of required pH value.
11. the method for preparation novel lasting tint system as claimed in claim 10 is characterized in that described required pH value is 7-10.
12. the method for preparation novel lasting tint system as claimed in claim 9 is characterized in that water wherein can be the warm water, the warm water can not only quicken to become gelationus speed, and compares with room temperature water, will produce the better color effect.
13. novel lasting tint system as claimed in claim 1 is characterized in that its 1 bagged product can be made up of a sealing bag and an empty, and the powder of novel lasting tint system is housed in the sealing bag.
14. novel lasting tint system as claimed in claim 13, empty wherein indicates labelling in its surface, is used to inform water is added to this labelling the required volume of adopting of user.
15. novel lasting tint system as claimed in claim 14, empty wherein can be at two differing heights of its outer surface, literally be expressed as down level and last level place is labeled, user can at first be added to water the following level of labelling, and the thing in the mixer, when mixture is mixed well till; Subsequently the water of remainder is added to the last level of labelling, and mixes, when forming cementitious mixtures or gel till.
16. novel lasting tint system as claimed in claim 13 is characterized in that also can comprising the apparatus that stirs the mixture in its 1 bagged product, as stirring rod etc.
17. the using method as novel lasting tint system as described in the claim 16 is:
1) open the sealing bag, the powder in the bag poured in the empty that provides,
2) in this container, add water, till institute's target labelling on the surface,
3) stir with the apparatus that provides, till mixture dissolves also gel fully,
4) this mixture is applied on the hair, the combing hair helps mixture is distributed on the whole hair fiber,
5) colour developing 30-60 minute or till forming required color, flushing and dry hair.
18., it is characterized in that the ratio of powder and added water in the sealing bag one is approximately 1 part of powder: 20～30 parts of water as the using method of novel lasting tint system as described in the claim 17.
19. novel lasting tint system as claimed in claim 1 is characterized in that described 2 bagged products are made up of two sealing bags, a sealing bag contains the powder of novel lasting tint system, and another sealing bag contains the gel finished product.
20. novel lasting tint system as claimed in claim 19 is characterized in that the ratio of the gel finished product in powder in the sealing bag one and another sealing bag is approximately 1 part of powder: 40～50 parts of gels.
21. as claim 19 or 20 described novel lasting tint systems, it is characterized in that described gel finished product can be by with aqueous dispersion carbopol 940,, form gel and make subsequently with alkali or the neutralization of ammonia type alkali.
22. as claim 19 or 20 described novel lasting tint systems, it is characterized in that described gel finished product can make by the whole bag of tricks by other various chemical substances, and this gel finished product can be commercially available any person mile.
23. novel lasting tint system as claimed in claim 19 is characterized in that wherein also can comprising the apparatus that is used to stir, for example stirring rod etc.
24. use the method for 2 bagged products of novel lasting tint system as claimed in claim 23 to be:
1) open the sealing bag of the powder that contains new lasting tint system, the thing in the bag poured in the packing material that contains the gel finished product,
2) stir with the stirring apparatus that provides, till the mixture complete and homogeneous,
3) this mixture is applied on the hair, the combing hair helps mixture is distributed on the whole hair fiber,
4) colour developing 30-60 minute or till forming required color, flushing and dry hair.
25. novel lasting tint system as claimed in claim 1, it is characterized in that 2 bagged products wherein are made up of two sealing bags, a sealing bag contains the powder of novel lasting tint system, and another sealing bag contains and is tuned to the liquid, aqueous of required pH value.
26., it is characterized in that wherein also can comprising glove as claim 13,19 or 25 described novel lasting tint systems.
27. novel lasting tint system as claimed in claim 25 is characterized in that the liquid, aqueous ratio that provides in powder and another sealing bag in the described sealing bag one is approximately 1 part of powder: 20～30 parts of solution.
28., it is characterized in that described liquid, aqueous pH value is 7-10 as claim 25 or 27 described novel lasting tint systems.
29. use the method for 2 bagged products of novel lasting tint system as claimed in claim 25 to be:
1) open the sealing bag of the powder that contains new lasting tint system, the thing in the bag poured in the packing material that contains the aqueous solution that is tuned to required pH value,
2) stir till the even fully also gel of mixture,
3) this mixture is applied on the hair, the combing hair helps mixture is distributed on the whole hair fiber,
4) colour developing 30-60 minute or till forming required color, flushing and dry hair.
30. state novel lasting tint system as claim 5,9,19,20,21 or 22, it is characterized in that the viscosity of wherein said gel is about more than 5000 centipoises.
31. as the compound method of claim 9,15,17,24 or 25 described novel lasting tint systems, the viscosity that it is characterized in that described colloidal mixture is more than 5000 centipoises.
32. the using method of novel lasting tint system as claimed in claim 1, it is characterized in that the lasting tint system of the quality of described color no less than routine, described quality is color and luster, tinctorial strength, coverage, anti-shampoo, uviolresistance and perspire etc.
33. novel lasting tint system is characterized in that it has suitable viscosity or gluey denseness according to claim 1; Can prevent to stain and do not wish painted place, for example other position of clothes, furniture, health etc.
34. use the using method of novel lasting tint system according to claim 1, it is characterized in that at hair when for example chesk hair, armpit hair, moustache, beard etc. dyeed, user was easy to controlling liquid and applies to other position of health except that hair.
35. the using method of novel lasting tint system is characterized in that they can be effectively to various types of coloring hairs according to claim 1; For example, permanent wave, stretching, the hair that has licked, the hair that had dyed, impaired hair (physics and chemical damage), the hair (for example hair dryer etc. heating) that stands some form heating, achromachia, poliosis, palm fibre are to the brownish black hair.
36. novel lasting tint system according to claim 1, it is characterized in that it because it does not contain hydrogen peroxide and other can be used for replacing the chemical substance of hydrogen peroxide, the chemical substance that for example is called " oxidant ": Ammonium persulfate., sodium peroxydisulfate or potassium peroxydisulfate, Dexol etc., new invention have many advantages.For example, 1) in permanent hair dyeing process, the user is no longer in the face of skin irritant possibility.2) the dyed hair fiber no longer is subjected to the damage that hydrogen peroxide and other can be used for replacing the chemical substance of hydrogen peroxide.3) owing to there is not hydrogen peroxide, natural hair color can not die down now.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TH053924 | 1999-11-15 | ||
| TH053924 | 1999-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1307862A true CN1307862A (en) | 2001-08-15 |
Family
ID=21617926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00107992 Pending CN1307862A (en) | 1999-11-15 | 2000-05-31 | Novel lasting tint system containing no hydrogen peroxide and other substitutive chemical |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1307862A (en) |
-
2000
- 2000-05-31 CN CN 00107992 patent/CN1307862A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101068599B (en) | Thickened hair colourant and bleaching compositions | |
| CA2659998C (en) | A catalyzed air oxidation haircolor | |
| CN101384240A (en) | Hair colouring compositions | |
| CN101489627A (en) | Gel network surfactant based thickening systems for hair colourant and bleaching compositions | |
| CN101394828A (en) | Thickened hair colorant and bleaching compositions | |
| CN102596325A (en) | Thickened hair colourant and bleaching compositions | |
| CN1290484C (en) | Hair bleach product | |
| TWI829837B (en) | Liquid hair dye composition | |
| JPH11199454A (en) | Two-pack type oxidation hair dye and two-pack type decoloring agent | |
| CN101068526A (en) | High level carbonate and/or oxidant hair colouring compositions | |
| BRPI0714510A2 (en) | polymer-thickened hair dyeing and bleaching compositions | |
| KR100592343B1 (en) | Hair dyeing method and hair dye set | |
| JP2004083454A (en) | Hair dye composition | |
| JP2004339179A (en) | Oxidation hairdye composition, hair bleaching agent composition and oxidation hairdye set | |
| JPH08157345A (en) | Method for decoloring and dyeing hair and viscous liquid for decoloring and dyeing hair | |
| US20020192175A1 (en) | Hair relaxer and coloring system | |
| CN1307862A (en) | Novel lasting tint system containing no hydrogen peroxide and other substitutive chemical | |
| CN1307861A (en) | Novel lasting tint system containing no ammonia and hydrogen peroxide | |
| JP3793468B2 (en) | Hair dye | |
| JP2021091612A (en) | Hair dye composition | |
| US7947090B2 (en) | Catalyzed air oxidation haircolor | |
| JPH0432046B2 (en) | ||
| NO136823B (en) | PREPARATIONS FOR DYEING OF KERATE-CONTAINING FIBERS, SPECIAL HUMANS. | |
| JP5620621B2 (en) | Hair dye | |
| KR0170627B1 (en) | Creamy composition for dying hair |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |