CN1302738A - Technology for making anticorrosion huge aurobronze statue - Google Patents
Technology for making anticorrosion huge aurobronze statue Download PDFInfo
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- CN1302738A CN1302738A CN 00123686 CN00123686A CN1302738A CN 1302738 A CN1302738 A CN 1302738A CN 00123686 CN00123686 CN 00123686 CN 00123686 A CN00123686 A CN 00123686A CN 1302738 A CN1302738 A CN 1302738A
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- huge
- bronze statue
- statue
- copper
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- 238000005516 engineering process Methods 0.000 title claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052802 copper Inorganic materials 0.000 claims abstract description 21
- 239000010949 copper Substances 0.000 claims abstract description 21
- 239000004576 sand Substances 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 229910000906 Bronze Inorganic materials 0.000 claims description 43
- 239000010974 bronze Substances 0.000 claims description 43
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 33
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 30
- 238000005260 corrosion Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- 239000004411 aluminium Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052738 indium Inorganic materials 0.000 claims description 15
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 6
- 238000004458 analytical method Methods 0.000 claims description 4
- 229910000679 solder Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 239000005002 finish coating Substances 0.000 claims description 2
- 230000006698 induction Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 claims description 2
- 230000011218 segmentation Effects 0.000 claims description 2
- 241001614291 Anoplistes Species 0.000 claims 2
- 238000012856 packing Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- 230000007797 corrosion Effects 0.000 description 5
- 238000005266 casting Methods 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 239000011135 tin Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 229910000846 In alloy Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- -1 copper-aluminium-nickel-indium Chemical compound 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
An anticorrosion huge aurobronze statue is made up of alloy material containing Al (2-6%), Ni (2-4%), In (0.1-0.5%), impurities (less than 0.01%) and copper (the rest) through moulding with resin-bound sand mould.
Description
The present invention relates to metal material and smelt processing technique field, a kind of technology for making anticorrosion huge aurobronze statue.
Making for huge bronze statue, over the past thousands of years, the human tin bronze matrix that adopts more, the surface is implemented gold-decorated and the technology of gilding, because some bronze statue is to be in the right environment of self-defence of wind and weather, and long-term even seawater dipping, airborne oxygen branch gives with copper ion and combining, cause the bronze statue surface oxidation, corrosion, tarnish, influence it and view and admire and use value.
Patent of invention notification number: 1022495, name is called that to disclose a kind of in the file of " imitation gold cuprio alloy and manufacture method thereof " be the copper-based alloy material manufacture method of copper by aluminium, indium, nickel, tin, manganese or titanium, silicon or rare earth and surplus, this alloy material can be processed into thin slice, wire rod, silk material, can satisfy the specification requirement of jewellery industry.Point out in the literary composition, handle being immersed in the artificial sweat of simulation (PH=4.5 and PH=8.5 so far 240 hours through the polishing table; More than 20 days, color is constant substantially in 60% sodium chloride solution, leaves standstill under the atmospheric conditions 1 year, and slightly obfuscation situation of surface takes place.
It is described to analyze above file: one: not mentioned its can be used for the making of huge bronze statue, and the environment of living in of huge bronze statue must be more more abominable than invention environmental condition of living in, surface color, and storing may reach many decades under the atmospheric conditions, even hundreds of years, the obfuscation situation can be more solemn and just heavy.
For overcoming the above problem, the purpose of this invention is to provide a kind of technology for making anticorrosion huge aurobronze statue, solve the manufacturing technology problem of epimegetic bronze statue of Buddha as class and copper artware, reach manufacturability and sight under severe environmental conditions.
The present invention realizes the foregoing invention purpose with following technical scheme:
Contain aluminium, nickel, indium in the general alloy material that adopts of ornamental handicraft, add surplus copper, aluminium 4-7% wherein, nickel O.5-1.0%, indium 1.0-5% adds the method for surplus copper, contains aluminium 2-6% in the material that the making of the golden huge bronze statue in anti-corrosion Asia of the present invention is adopted, nickel 2-4%, indium 0.1-0.5%, surplus adds copper, impurity content ≯ 0.01; Adopt the molten model type of resin sand fabrication techniques to form.
The bronze statue base-material that adopts aforesaid material configuration ratio to make, then according to the technology moulding, layering, segmentation, piecemeal; Then, carrying out molten proplasm of resin sand and running channel design-alloy dissolves-moulding casting-wallboard processing-bronze statue assembling-welding-finish-coating protection.
The process for making of the golden huge bronze statue in described anti-corrosion Asia, the Medium frequency induction melting is adopted in the making of the molten proplasm of resin sand in its technological process, and cast temperature 1230-1250 ℃, proportion scale ± 0.5% is produced resin sand fusible pattern large tracts of land special-shaped thin wall member.
The process for making of the golden huge bronze statue in described anti-corrosion Asia, resin sand invested mould in its technological process and running channel design, phenolic sand molding, fusible pattern are polyurethane material, fixing means is fixed together for the rivet that adopts same inferior golden composition.
The process for making of the golden huge bronze statue in described anti-corrosion Asia; welding in the technological process; its solder wire material that adopts is identical with the bronze statue fertile material, and partly continuous repeatedly ingot casting-extruding-stretching-protective gas annealing-stretching φ 1.0-φ 3.0 is taked in the making of solder wire material.
Golden huge bronze statue in described anti-corrosion Asia and process for making thereof, golden bronze statue in described anti-corrosion Asia and process for making thereof, bronze statue table and processing method adopt C
2H
5OH+0.1%BTA surface purifying.The acrylic resin that adds clear, colorless adds the uvioresistant additive, adds titanium coupling agent in organic coating and the inorganic coating, coating layer thickness 100 μ.
Owing to adopt technical scheme as mentioned above, the present invention has following superiority:
Owing to adopt technical scheme as mentioned above, the present invention has following superiority:
The present invention has adopted copper-aluminium-nickel-indium alloy material to make such as epimegetic bronze statues such as the figures of buddha, and it has beautiful golden colour lustre; At marine atmosphere, SO
2, H
2S gas part does not have spot corrosion, stress corrosion, and intercrystalline corrosion, the annual corrosion depth is not more than 0.02 millimeter.Has the favorable mechanical performance again, casting character, welding performance; Anti-marine atmosphere etch; This alloy material is better than brass and tin bronze.
Special coating and the technology of specializing in has been adopted in the bronze statue surface protection, has added specialist additive, has improved the adhesion between coating and the metal, makes the bronze statue surface possess golden yellow color under marine atmosphere.
A kind of new process of resin sand model casting has been adopted in the making of huge bronze statue especially, makes this method can accurately control the wall thickness of irregularly-shaped castings, has avoided traditional handicraft die sinking, matched moulds operation, has improved casting quality.
The following describes specific embodiment:
Fig. 1 is the golden huge bronze statue manufacture craft flow chart in anti-corrosion Asia
Embodiment one:
With the high anti-corrosion Asia golden Mount Putuo kwan-yin figure of buddha of trial-production 4M is example: get aluminium by 2%, and nickel 4%, indium 0.5%, copper 92.89%, weigh respectively (weight ratio) is as follows.Copper and nickel material with whole proportionings, pack in the intermediate frequency furnace, furnace temperature rises to 1100 ℃, treats that it is all after the fusing, drop into the aluminium of proportioning, when rising to smelting temperature 1280-1300 ℃, add indium, after fully stirring, carry out on-the-spot sample analysis qualified after, the cast of coming out of the stove, front and back need 2.5 hours, and pouring temperature is controlled between 1230-1250 ℃.
Embodiment two:
To manufacture experimently high 20M, the precious picture of the inferior gold of Mount Putuo copper open-air South Sea kwan-yin that weighs 70 tons is example: get aluminium 4.5%, and nickel 2%, indium 0.3%, gold 0.31%, copper 92.88% is weighed respectively.The nickel of the copper with 2/3 and whole proportionings, put into intermediate frequency furnace, after furnace temperature rises to 1100 ℃ of fusings, put into 1/3 copper and aluminium again, furnace temperature rises to after 1280-1300 ℃ of fusing, add indium and gold, fully stir, after on-the-spot sample analysis is qualified, the cast of coming out of the stove, successively need 2.5 hours, pouring temperature is controlled between 1230-1250 ℃.
Claims (8)
1, the process for making of the golden huge bronze statue in a kind of anti-corrosion Asia adopts in the general making alloy material of ornamental handicraft and bronze statue and contains aluminium, nickel, indium, adds surplus copper, wherein aluminium 4-7%, nickel 0.5-1.0%, indium 1.0-5% adds surplus copper, it is characterized in that: the making of the huge bronze statue of the present invention, contain aluminium 2-6% in the material that adopts, nickel 2-4%, indium 0.1-0.5%, surplus adds copper, impurity content ≯ 0.01% adopts the molten model type of resin sand fabrication techniques to form.
2, the process for making of the golden huge bronze statue in anti-corrosion Asia as claimed in claim 1 is characterized in that: the process for making of described huge bronze statue: get aluminium by 2%, nickel 4%, indium 0.5%, copper 92.89%, weigh respectively (weight ratio); With the copper and the nickel material of whole proportionings, in the intermediate frequency furnace of packing into, furnace temperature rises to 1100 ℃, treats that it all after the fusing, drops into the aluminium of proportioning; When rising to smelting temperature 1280-1300 ℃, add indium, after fully stirring, carry out on-the-spot sample analysis qualified after; The cast of coming out of the stove, front and back need 2.5 hours, and pouring temperature is controlled between 1230-1250 ℃.
3, the process for making of the golden huge bronze statue in anti-corrosion Asia as claimed in claim 1 is characterized in that: the process for making of described huge bronze statue: get aluminium 4.5%, and nickel 2%, indium 0.3%, gold 0.31%, copper 92.88% is weighed respectively; The nickel of the copper with 2/3 and whole proportionings is put into intermediate frequency furnace, after furnace temperature rises to 1100 ℃ of fusings, puts into 1/3 copper and aluminium again; Furnace temperature rises to after 1280-1300 ℃ of fusing, adds indium and gold, fully stirs, after on-the-spot sample analysis is qualified; The cast of coming out of the stove successively needs 2.5 hours, and pouring temperature is controlled between 1230-1250 ℃.
4, as the process for making of the golden huge bronze statue of claim 1 or 2 or 3 described anti-corrosion Asias, it is characterized in that: the preparation method of described huge bronze statue, adopt aforesaid material configuration ratio to make the bronze statue base-material; Then, according to the technology moulding, layering, segmentation, piecemeal carry out molten proplasm of resin sand and running channel design-alloy and dissolve-moulding casting-wallboard processing-bronze statue assembling-welding-finish-coating protection.
5, as the process for making of the golden huge bronze statue of claim 1 or 4 described anti-corrosion Asias, it is characterized in that: the process for making of described huge bronze statue, the making of the molten proplasm of resin sand in its flow process, adopt the Medium frequency induction melting, cast temperature 1230-1250 ℃, proportion scale ± 0.5% is produced resin sand fusible pattern large tracts of land special-shaped thin wall member.
6, as the process for making of the golden huge bronze statue in anti-corrosion Asia as described in the claim 4, it is characterized in that: the process for making of described huge bronze statue, resin sand invested mould in its flow process and running channel design, phenolic sand molding, fusible pattern is a polyurethane material, and fixing means is fixed for the rivet that adopts same inferior golden composition.
7, implement process for making as the golden huge bronze statue in anti-corrosion Asia as described in the claim 4; it is characterized in that: the process for making of described huge bronze statue; welding in its flow process; its solder wire material that adopts is identical with the bronze statue fertile material, and partly continuous repeatedly ingot casting-extruding-stretching-protective gas annealing-stretching φ 1.0-φ 3.0 is taked in the making of solder wire material.
8, as technology for making anticorrosion huge aurobronze statue as described in claim 1 or 2 or 3, it is characterized in that: the process for making of described huge bronze statue, the surface treatment method of its bronze statue adopts C
2H
5OH+0.1%BTA surface purifying, the acrylic resin that adds clear, colorless adds the uvioresistant additive, adds titanium coupling agent in organic coating and the inorganic coating, coating layer thickness 100 μ.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123686 CN1109611C (en) | 2000-08-29 | 2000-08-29 | Technology for making anticorrosion huge aurobronze statue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123686 CN1109611C (en) | 2000-08-29 | 2000-08-29 | Technology for making anticorrosion huge aurobronze statue |
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| Publication Number | Publication Date |
|---|---|
| CN1302738A true CN1302738A (en) | 2001-07-11 |
| CN1109611C CN1109611C (en) | 2003-05-28 |
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| CN 00123686 Expired - Fee Related CN1109611C (en) | 2000-08-29 | 2000-08-29 | Technology for making anticorrosion huge aurobronze statue |
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| CN (1) | CN1109611C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104325074A (en) * | 2014-11-14 | 2015-02-04 | 江西桐青金属工艺品有限公司 | Method for casting large silver alloy buddha statue by use of gypsum mold |
| CN106111902A (en) * | 2016-07-05 | 2016-11-16 | 青海大学 | Concealed medium-sized thin wall type copper figure of buddha manufacture method |
| CN106119747A (en) * | 2016-06-23 | 2016-11-16 | 新昌县金声铜业有限公司 | A kind of imitative 24K gold heat treatment method of albronze |
| CN115305380A (en) * | 2022-08-17 | 2022-11-08 | 中科粉研(河南)超硬材料有限公司 | Cu-Al-Ni-In series copper alloy material and preparation method thereof |
-
2000
- 2000-08-29 CN CN 00123686 patent/CN1109611C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104325074A (en) * | 2014-11-14 | 2015-02-04 | 江西桐青金属工艺品有限公司 | Method for casting large silver alloy buddha statue by use of gypsum mold |
| CN104325074B (en) * | 2014-11-14 | 2018-08-21 | 江西桐青金属工艺品股份有限公司 | A method of utilizing the plaster casting large size silver alloy figure of buddha |
| CN106119747A (en) * | 2016-06-23 | 2016-11-16 | 新昌县金声铜业有限公司 | A kind of imitative 24K gold heat treatment method of albronze |
| CN106119747B (en) * | 2016-06-23 | 2018-05-04 | 新昌县金声铜业有限公司 | A kind of imitative 24K gold heat treatment method of albronze |
| CN106111902A (en) * | 2016-07-05 | 2016-11-16 | 青海大学 | Concealed medium-sized thin wall type copper figure of buddha manufacture method |
| CN106111902B (en) * | 2016-07-05 | 2018-02-23 | 青海大学 | The medium-sized thin wall type copper figure of buddha manufacture method of concealed |
| CN115305380A (en) * | 2022-08-17 | 2022-11-08 | 中科粉研(河南)超硬材料有限公司 | Cu-Al-Ni-In series copper alloy material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN1109611C (en) | 2003-05-28 |
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