CN1301798A - Spray anti-slip agent and its preparing method - Google Patents

Spray anti-slip agent and its preparing method Download PDF

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Publication number
CN1301798A
CN1301798A CN 99124995 CN99124995A CN1301798A CN 1301798 A CN1301798 A CN 1301798A CN 99124995 CN99124995 CN 99124995 CN 99124995 A CN99124995 A CN 99124995A CN 1301798 A CN1301798 A CN 1301798A
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CN
China
Prior art keywords
petroleum resin
solvent oil
rosin
rubber
glue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 99124995
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Chinese (zh)
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CN1100840C (en
Inventor
杨岩峰
张敬杰
宋广智
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Institute of Photographic Chemistry of CAS
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Institute of Photographic Chemistry of CAS
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Publication date
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Priority to CN99124995A priority Critical patent/CN1100840C/en
Publication of CN1301798A publication Critical patent/CN1301798A/en
Application granted granted Critical
Publication of CN1100840C publication Critical patent/CN1100840C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

A spray anti-slip agent is prepared through the processes of plasticization of plasticized natural or synthesized rubber 10-40 wt% and adjuvant 1-5 wt.% to produce plasticized rubber sheet with plasticity being controlled at 0.7-0.9; swelling the plasitcized rubber sheet with solvent oil; dissolving esterified rosin or petroleum resin 10-40 wt% with solvent oil with the total amount of solvent oil being 20-50 wt%; mixing the said two dissolved components into glue solution; filling first the glue solution and then the aerosol in the weight ratio of 1 to 0.5-2.5 into aerosol preparation tank. The product is easy to use as pollutionless, and is used in anti-slip for pedestrians and vehicle in snowy weather.

Description

Spray anti-slip agent and preparation method thereof
The invention belongs to the adhesive technology field, particularly a kind of spray anti-slip agent and preparation method thereof.
Be generally used for winter the pedestrian and the antiskid product of vehicle in sleety weather be safety stud and antiskid chain, this method both uses inconvenient, skidproof effect is also undesirable.
The object of the present invention is to provide a kind of spray anti-slip agent and preparation method thereof.This slipproofing agent can be protected the driving safety of pedestrian and vehicle in the winter time in the sleety weather, and easy to use, pollution-free.
Spray anti-slip agent provided by the invention, it is characterized in that constituting wherein said glue (weight percent) composed of the following components: the natural rubber of plastification or synthetic rubber 10~40% in 1: 0.5~1: 2.5 with weight ratio by glue and aerosol; Esterified rosin or petroleum resin 10~40%; Solvent oil 20~50%; Auxiliary agent 1~5%;
Wherein the synthetic rubber of plastification is isoprene-isobutylene rubber, cis-1,4-polybutadiene rubber or styrene-butadiene rubber(SBR); Esterified rosin is glycerine esterification rosin, rosin pentaerythritol ester or polymerized rosin; Petroleum resin are C 5Petroleum resin, C 9Petroleum resin or C 5Petroleum resin and C 9The mixture of any weight ratio of petroleum resin; Solvent oil is 120 #Or 200 #Solvent oil; Auxiliary agent is softening agent or inorganic fillings, and softening agent is dibutyl phthalate or dioctyl phthalate (DOP); Inorganic fillings is light calcium carbonate, titanium dioxide or zinc oxide.
Aerosol is third butane.
The preparation method of spray anti-slip agent of the present invention is:
At first prepare glue: be that the natural rubber of 10~40% plastification or synthetic rubber and weight percent are that 1~5% auxiliary agent is plasticated with weight percent, make sheet, the control plasticity number is 0.7~0.9; With the solvent oil swelling of the sheet after plasticating; Be that 10~40% esterified rosin or petroleum resin dissolve with solvent oil simultaneously with weight percent, total weight percent of solvent oil is 20~50%; Then with esterified rosin or the two miscible glue of making of petroleum resin after sheet behind the swelling and the dissolving;
Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 0.5~1: 2.5, makes spray anti-slip agent.
Purposes of the present invention: it is anti-skidding that spray anti-slip agent of the present invention can be used for winter sleety weather pedestrian Motor vehicles.
Advantage of the present invention: product of the present invention is easy to use, the preparation method is simple, pollution-free.
Embodiment 1
At first prepare glue: weight percent is 10% natural rubber and the weight percent of plastification of (100 gram) is that titanium dioxide and 0.4% (4 gram) dibutyl phthalate of 0.1% (1 gram) is plasticated, and makes sheet, controls plasticity number 0.7; Sheet weight percent after plasticating is 0.5% dibutyl phthalate and the weight percent of (5 gram) be 30% (300 restrain) 120 #The solvent oil swelling; The glycerine esterification rosin that with weight percent is 39% (390 gram) simultaneously is 20% (200 gram) 120 with weight percent #The solvent oil dissolving; Then with the two the miscible glue of making of glycerine esterification rosin after sheet behind the swelling and the dissolving; Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 0.5, makes spray anti-slip agent.
Embodiment 2
At first prepare glue: weight percent is 25% isoprene-isobutylene rubber and the weight percent of plastification of (250 gram) is that the light calcium carbonate of 5% (50 gram) is plasticated, and makes sheet, controls plasticity number 0.8; Sheet weight percent after plasticating is 20% (200 gram) 200 #The solvent oil swelling; The rosin pentaerythritol ester that with weight percent is 35% (350 gram) simultaneously is 15% (150 gram) 200 with weight percent #The solvent oil dissolving; Then with the two the miscible glue of making of rosin pentaerythritol ester after sheet behind the swelling and the dissolving; Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 1, makes spray anti-slip agent.
Embodiment 3
At first prepare glue: weight percent is 33% cis-1,4-polybutadiene rubber and the weight percent of plastification of (330 gram) is that the titanium dioxide of 2% (20 gram) is plasticated, and makes sheet, controls plasticity number 0.85; Sheet weight percent after plasticating is 20% (200 gram) 120 #The solvent oil swelling; The polymerized rosin that with weight percent is 35% (350 gram) simultaneously is 10% (100 gram) 200 with weight percent #The solvent oil dissolving; Then with the two the miscible glue of making of polymerized rosin after sheet behind the swelling and the dissolving; Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 1.2, makes spray anti-slip agent.
Embodiment 4
At first prepare glue: weight percent is 40% styrene-butadiene rubber(SBR) and the weight percent of plastification of (400 gram) is that the zinc oxide of 5% (50 gram) is plasticated, and makes sheet, controls plasticity number 0.9; Sheet weight percent after plasticating is 25% (250 gram) 200 #The solvent oil swelling; Be the C of 35% (350 gram) simultaneously with weight percent 5Petroleum resin are 20% (200 gram) 200 with weight percent #The solvent oil dissolving; Then with the C after sheet behind the swelling and the dissolving 5The two miscible glue of making of petroleum resin; Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 2.5, makes spray anti-slip agent.

Claims (6)

1. a spray anti-slip agent is characterized in that being made of in 1: 0.5~1: 2.5 with weight ratio glue and aerosol, and wherein said glue is made up of following component and proportioning (weight percent):
The natural rubber of plastification or synthetic rubber 10~40%;
Esterified rosin or petroleum resin 10~40%;
Solvent oil 20~50%;
Auxiliary agent 1~5%;
Aerosol is third butane.
2. spray anti-slip agent as claimed in claim 1, the synthetic rubber that it is characterized in that described plastification is isoprene-isobutylene rubber, cis-1,4-polybutadiene rubber or styrene-butadiene rubber(SBR); Described esterified rosin is glycerine esterification rosin, rosin pentaerythritol ester or polymerized rosin; Described petroleum resin are C 5Petroleum resin, C 9Petroleum resin or C 5Petroleum resin and C 9The mixture of any weight ratio of petroleum resin; Described solvent oil is 120 #Or 200 #Solvent oil; Described auxiliary agent is softening agent or inorganic fillings.
3. spray anti-slip agent as claimed in claim 1 or 2 is characterized in that described softening agent is dibutyl phthalate or dioctyl phthalate (DOP); Described inorganic fillings is light calcium carbonate, titanium dioxide or zinc oxide.
4. the method for making of a kind of spray anti-slip agent as claimed in claim 1 is characterized in that
At first prepare glue: be that the natural rubber of 10~40% plastification or synthetic rubber and weight percent are that 1~5% auxiliary agent is plasticated with weight percent, make sheet, the control plasticity number is 0.7~0.9; With the solvent oil swelling of the sheet after plasticating; Be that 10~40% esterified rosin or petroleum resin dissolve with solvent oil simultaneously with weight percent, total weight percent of solvent oil is 20~50%; Then with esterified rosin or the two miscible glue of making of petroleum resin after sheet behind the swelling and the dissolving;
Secondly above-mentioned glue is injected in the aerosol jar, pour into aerosol again, wherein the weight ratio of glue and aerosol is 1: 0.5~1: 2.5, makes spray anti-slip agent.
5. the method for making of a kind of spray anti-slip agent as claimed in claim 4, the synthetic rubber that it is characterized in that described plastification is isoprene-isobutylene rubber, cis-1,4-polybutadiene rubber or styrene-butadiene rubber(SBR); Described esterified rosin is glycerine esterification rosin, rosin pentaerythritol ester or polymerized rosin; Described petroleum resin are C 5Petroleum resin, C 9Petroleum resin or C 5Petroleum resin and C 9The mixture of any weight ratio of petroleum resin; Described solvent oil is 120 #Or 200 #Solvent oil; Described auxiliary agent is softening agent or inorganic fillings.
6. as claim 4 or 5 described spray anti-slip agents, it is characterized in that described softening agent is dibutyl phthalate or dioctyl phthalate (DOP); Described inorganic fillings is light calcium carbonate, titanium dioxide or zinc oxide.
CN99124995A 1999-12-24 1999-12-24 Spray anti-slip agent and its preparing method Expired - Fee Related CN1100840C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN99124995A CN1100840C (en) 1999-12-24 1999-12-24 Spray anti-slip agent and its preparing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN99124995A CN1100840C (en) 1999-12-24 1999-12-24 Spray anti-slip agent and its preparing method

Publications (2)

Publication Number Publication Date
CN1301798A true CN1301798A (en) 2001-07-04
CN1100840C CN1100840C (en) 2003-02-05

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CN99124995A Expired - Fee Related CN1100840C (en) 1999-12-24 1999-12-24 Spray anti-slip agent and its preparing method

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1297620C (en) * 2005-05-10 2007-01-31 山东师范大学 Anti-skid intensifier for smooth brick masonry surface and method for preparing same
CN104403426A (en) * 2014-12-09 2015-03-11 苏州明轩地坪涂料有限公司 Nonslip paint
CN108285524A (en) * 2017-12-29 2018-07-17 浙江华峰新材料股份有限公司 On-slip type polyurethane elastomer stoste and its preparation method and application
CN113045887A (en) * 2021-04-20 2021-06-29 佛山市发润新材料科技有限公司 Modified anti-skid TPU

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5248579A (en) * 1975-10-15 1977-04-18 Sumitomo Chem Co Ltd Antislipping composition for polyolefin packing material
DE4339642A1 (en) * 1993-11-20 1995-05-24 Henkel Kgaa Aqueous anti-slip agent
CN1128779A (en) * 1995-02-07 1996-08-14 青州铝箔纸总公司 Glue for pretreatment of raw material paper for solid state vacuum aluminium plating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1297620C (en) * 2005-05-10 2007-01-31 山东师范大学 Anti-skid intensifier for smooth brick masonry surface and method for preparing same
CN104403426A (en) * 2014-12-09 2015-03-11 苏州明轩地坪涂料有限公司 Nonslip paint
CN108285524A (en) * 2017-12-29 2018-07-17 浙江华峰新材料股份有限公司 On-slip type polyurethane elastomer stoste and its preparation method and application
CN113045887A (en) * 2021-04-20 2021-06-29 佛山市发润新材料科技有限公司 Modified anti-skid TPU

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