CN1299880A - Aluminium-free deoxidant for steel smelting - Google Patents
Aluminium-free deoxidant for steel smelting Download PDFInfo
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- CN1299880A CN1299880A CN 00136269 CN00136269A CN1299880A CN 1299880 A CN1299880 A CN 1299880A CN 00136269 CN00136269 CN 00136269 CN 00136269 A CN00136269 A CN 00136269A CN 1299880 A CN1299880 A CN 1299880A
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Abstract
The chemical composition of aluminium-free deoxidant iron alloy cousists of (wt%) Si 30-60%, Ba 5-20%, Ca 3-20%, Sr 2-15% and the rest is Fe and inevitable impurity. In the above-mentioned composition one kind of more than one of the following ingredients of Mn 1-10%, Mg 1-8% and RE 1-10% also can be added. The invented aluminium-free deoxidant iron alloy not only can make deoxygenation but also can implement desulfurization, and possesses the advantages of large specific weight (3.2g/sq.cm), low melting point (1160 deg.C) and no atomizing. Because it has no Al2O3, it can prevnet tapping hole from producing heels, and is favourable for continuous casting.
Description
The present invention uses the aluminium-free deoxidant iron alloy for steel-making, and it has deoxidizing capacity preferably, is better than having the aluminium deoxidizer iron alloy.
At present, the steel making deoxidant great majority contain aluminium, because China's steel-making has now realized continuous casting mostly, reductor has contained the aluminium height, because the existence of aluminium is arranged, will produce Al in deoxidation process
2O
3, causing nozzle clogging, influence is produced and output.Simultaneously, some steel grade does not need to contain aluminium, and has the aluminium existence can cause that Al is arranged in the steel
2O
3Be mingled with, and influence steel product quality.In view of above-mentioned two reasons, be badly in need of carrying out deoxidation with the reductor of no aluminium.
The object of the present invention is to provide a kind of aluminium-free deoxidant iron alloy of novel steel-making usefulness.
The Chemical Composition (weight %) that the invention provides the aluminium-free deoxidant iron alloy is: Si 30～60%, and Ba 5～20%, and Ca 3～20%, and Sr 2～15%, and surplus is Fe and unavoidable impurities.
Aluminium content is Al≤5% in the described impurity.
In addition, in above-mentioned composition, can also contain in the following component one or more:
Mn 1～10%, and Mg 1～8%, RE (rare earth) 1～10%.
The preparation method of reductor of the present invention is:
Raw material is made in reducing and smelting in the hot stove in stoichiometric calculation ratio (weight) input ore deposit.Raw materials used is (allocating according to used product composition): silica, lazurite, barite, Wingdale or lime, steel cuttings.Reductive agent is coal, coke, charcoal etc.Above-mentioned raw materials and reductive agent mixing are placed in the hot stove in ore deposit, and one time reducing and smelting becomes required silicon barium strontium Ca-Fe alloy.
Described reductor can carry out the second-heating remelting, carries out the adjustment of discrete component, produces the product that contains Mg and RE.
Composite deoxidant provided by the invention, owing to do not contain aluminium, so there is not Al in the steel
2O
3Inclusion.Calcium constituent in the described reductor not only avidity with oxygen is very strong, and also very strong with the avidity of sulphur.So can not only deoxidation can play desulfidation again.Barium among the present invention and strontium can make steel inclusion nodularization sex change, and itself has very strong deoxidizing capacity again simultaneously.Barium and strontium chemically reactive are strong, and the overwhelming majority reacts with oxygen in the adding molten steel, forms low-melting silicate, and its fusing point is 1270～1327 ℃, and formed deoxidation products floats easily.Barium and strontium also can play a part crystal grain thinning.The thin non-metallic inclusion that produces in the solidification of molten steel process of strontium impels more disperse of primary solidification structure, thereby can improve the dispersity and the uniformity coefficient of steel crystal structure in addition.In addition, this product also has than great (3.2g/cm
3), fusing point low (1160 ℃), advantages such as not efflorescence.What is more important is because no Al
2O
3, nozzle clogging when having avoided continuous casting of molten steel, very favourable to continuous casting.
Calcium element content is suitable among the present invention, thereby has overcome the shortcoming that produces smog, contaminate environment in the deoxidation process in the past.
The invention will be further described by following embodiment:
Embodiment 1:
Press silica 90kg, barite 30kg, lazurite 15kg, Wingdale 5kg, coke 70kg, the ratio batching of steel cuttings 8kg, and be placed in the hot stove in 3200KVA ore deposit, smelted 2 hours, it is Si 47% that primary smelting goes out Chemical Composition (weight %), and Ba 16%, and Ca 5%, Sr 6%, and surplus is the composite deoxidant of Fe.This product advantages of good crystallization, hard, fusing point low (1160 ℃), proportion is 3.2g/cm
3, store no efflorescence all the year round.Is example with it to the Q235-B steel-deoxidizing, and oxygen content in steel is 16ppm after the deoxidation, is mingled with total amount 0.0019, and the sulfide disperse distributes, and oxide compound is point-like, spherical, and in addition, part is the mixture of said two devices.The grain fineness number of the crystal grain more than 95% is 10 grades, and the Q235-B steel of handling with this reductor does not have Al
2O
3Inclusion, the comprehensive mechanical performance of steel, especially unit elongation be improved significantly.
Embodiment 2:
(composition is Si 47%, and Ba 16%, and Ca 5% being smelt silicon barium calcium strontium-iron alloy, Sr 6%, surplus is Fe) afterwards, pass through the main frequency furnace secondary fusion with 8% magnesium again, obtain silicon barium calcium strontium Mg-Fe alloy, its Chemical Composition (weight %) is: Si 45%, Ba 15%, and Ca 4.5%, and Sr 5%, magnesium 5%, surplus are Fe.Be used for the deoxidation of 60kg Properties of Heavy Rail Steel By, oxygen content in steel is 15.6ppm as a result, and being mingled with total amount is 0.0068; Sulfide and silicate are strip and distribute, and that the mixture of said two devices partly is is a little spherical, spin the Duo shape, and the oxide inclusion particle is the disperse distribution.The tensile strength of steel 〉=1030 (mpa), unit elongation (%) 〉=9, the macroscopic examination result is good.
Embodiment 3:
(Si 47%, and Ba 16%, and Ca 5%, and Sr 6% at above-mentioned silicon barium calcium strontium-iron alloy, surplus is Fe) add the 8kg manganese ore in the starting material, producing composition (weight %) with the hot stove in ore deposit is Si 44%, and Ba 15%, and Ca 4%, Sr 5%, and Mn 5%, and surplus is the iron alloy of Fe.Be used for the deoxidation of 20 MnSi steel, oxygen content in steel is 12ppm, and it is 0.0051 that steel is mingled with total amount.Inclusion is sulfide and oxide compound, and it is irregular to distribute, and partial vulcanization thing and oxide compound are compound.The steel mechanical property also has raising: yield-point δ
s310～320 (mpa), tensile strength δ
b440～460 (mpa), unit elongation δ 20～21%.
Claims (3)
1, a kind of aluminium-free deoxidant iron alloy, it is characterized in that the Chemical Composition (weight %) of described alloy is: Si 30～60, and Ba 5～20, and Sr 2～15, and Ca 3～20, and surplus is Fe and unavoidable impurities.
2, a kind of aluminium-free deoxidant iron alloy, it is characterized in that the Chemical Composition (weight %) of described alloy is: Si 30～60, and Ba 5～20, Sr 2～15, and Ca 3～20, and one or more in the following composition (weight %): Mn 1～10, Mg 1～8, and RE 1～10.
3, a kind of preparation method as reductor iron alloy as described in the claim 2 is characterized in that:
Raw material is made in reducing and smelting in the hot stove in stoichiometric calculation ratio (weight) input ore deposit, raw materials used is silica, lazurite, barite, Wingdale or lime, steel cuttings, reductive agent is coal, coke, charcoal etc., above-mentioned raw materials and reductive agent mixing are placed in the hot stove in ore deposit, and one time reducing and smelting becomes required silicon barium strontium Ca-Fe alloy; The silicon barium strontium Ca-Fe alloy that is smelt is carried out the second-heating remelting, carry out the adjustment of discrete component, produce the product that contains Mg and RE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001362690A CN1151282C (en) | 2000-12-26 | 2000-12-26 | Aluminium-free deoxidant for steel smelting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001362690A CN1151282C (en) | 2000-12-26 | 2000-12-26 | Aluminium-free deoxidant for steel smelting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1299880A true CN1299880A (en) | 2001-06-20 |
| CN1151282C CN1151282C (en) | 2004-05-26 |
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|---|---|---|---|
| CNB001362690A Expired - Fee Related CN1151282C (en) | 2000-12-26 | 2000-12-26 | Aluminium-free deoxidant for steel smelting |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100387729C (en) * | 2006-02-27 | 2008-05-14 | 沈阳东北大学冶金技术研究所 | Molten-steel deoxidation agent |
| CN100408700C (en) * | 2005-07-01 | 2008-08-06 | 刘治国 | Silicon barium calcium manganese magnesium iron alloy and its preparation method |
| CN102453584A (en) * | 2010-10-29 | 2012-05-16 | 曲靖花山化工原料厂 | Furnace calcification desulphurization mineral powder material |
| CN102618775A (en) * | 2011-01-28 | 2012-08-01 | 谢应旭 | Alkaline earth-rare earth composite iron alloy and preparation method thereof |
| CN103981333A (en) * | 2014-05-30 | 2014-08-13 | 苏州大学 | Preparation method of iron-manganese-magnesium alloy deoxidizer for non-aluminum deoxidized steel |
| CN104212941A (en) * | 2014-06-10 | 2014-12-17 | 上海中捷有色金属有限公司 | Novel aluminum-free composite deoxidizer for stainless steel smelting, and its preparation method |
| CN104451029A (en) * | 2014-11-24 | 2015-03-25 | 中原特钢股份有限公司 | Silicon-calcium-barium-magnesium desoxidant for steelmaking and/or electroslag |
| CN108018401A (en) * | 2017-12-28 | 2018-05-11 | 新乡市新兴冶金材料有限公司 | A kind of silico-calcium strontium alloy core-spun yarn |
| CN108754070A (en) * | 2018-08-17 | 2018-11-06 | 安徽信息工程学院 | A kind of method of deoxidation of cast steel |
| CN109022679A (en) * | 2018-08-17 | 2018-12-18 | 安徽信息工程学院 | A kind of rare earth calcium silicon manganese dioxidation agent and preparation method thereof |
| CN109082499A (en) * | 2018-08-17 | 2018-12-25 | 安徽信息工程学院 | A kind of cast steel and preparation method thereof |
| CN110527787A (en) * | 2019-10-18 | 2019-12-03 | 谢应凯 | Silicon barium magnesium manganeisen and preparation method |
-
2000
- 2000-12-26 CN CNB001362690A patent/CN1151282C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100408700C (en) * | 2005-07-01 | 2008-08-06 | 刘治国 | Silicon barium calcium manganese magnesium iron alloy and its preparation method |
| CN100387729C (en) * | 2006-02-27 | 2008-05-14 | 沈阳东北大学冶金技术研究所 | Molten-steel deoxidation agent |
| CN102453584A (en) * | 2010-10-29 | 2012-05-16 | 曲靖花山化工原料厂 | Furnace calcification desulphurization mineral powder material |
| CN102453584B (en) * | 2010-10-29 | 2014-02-26 | 曲靖花山化工原料厂 | Furnace calcification desulphurization mineral powder material |
| CN102618775A (en) * | 2011-01-28 | 2012-08-01 | 谢应旭 | Alkaline earth-rare earth composite iron alloy and preparation method thereof |
| CN103981333B (en) * | 2014-05-30 | 2015-12-30 | 苏州大学 | A kind of preparation method of non-Al deoxidization steel ferrimanganic magnesium alloy reductor |
| CN103981333A (en) * | 2014-05-30 | 2014-08-13 | 苏州大学 | Preparation method of iron-manganese-magnesium alloy deoxidizer for non-aluminum deoxidized steel |
| CN104212941A (en) * | 2014-06-10 | 2014-12-17 | 上海中捷有色金属有限公司 | Novel aluminum-free composite deoxidizer for stainless steel smelting, and its preparation method |
| CN104451029A (en) * | 2014-11-24 | 2015-03-25 | 中原特钢股份有限公司 | Silicon-calcium-barium-magnesium desoxidant for steelmaking and/or electroslag |
| CN108018401A (en) * | 2017-12-28 | 2018-05-11 | 新乡市新兴冶金材料有限公司 | A kind of silico-calcium strontium alloy core-spun yarn |
| CN108754070A (en) * | 2018-08-17 | 2018-11-06 | 安徽信息工程学院 | A kind of method of deoxidation of cast steel |
| CN109022679A (en) * | 2018-08-17 | 2018-12-18 | 安徽信息工程学院 | A kind of rare earth calcium silicon manganese dioxidation agent and preparation method thereof |
| CN109082499A (en) * | 2018-08-17 | 2018-12-25 | 安徽信息工程学院 | A kind of cast steel and preparation method thereof |
| CN110527787A (en) * | 2019-10-18 | 2019-12-03 | 谢应凯 | Silicon barium magnesium manganeisen and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1151282C (en) | 2004-05-26 |
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Effective date of registration: 20020826 Address after: 117100 Changjiang Road in Liaoning province Benxi County town No. 549 Benxi smelter Applicant after: Xie Yansheng Address before: 117100 Changjiang Road in Liaoning province Benxi County town No. 549 Benxi smelter Applicant before: Yuan Xide Co-applicant before: Xie Tingsheng |
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Correction item: Patentee Correct: Xie Tingsheng False: Xie Yansheng Number: 21 Volume: 20 |
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