CN1297705C - Process for patterning textile materials and fabrics made therefrom - Google Patents

Abstract

A process for patterning textile materials is described. The process involves applying a water soluble chemical substance designed to mechanically inhibit the wetting of underlying regions of the fabric to a textile fabric in a predetermined pattern, then dyeing the fabric in a manner conventionnally used to uniformly dye fabrics, such as by a continuous or semi-continuous dye process. The chemical substance which has been applied to the fabric functions to temporarily mechanically inhibit wetting of the underlying regions of the fabric, so that the underlying portions are dyed to a lesser extent than the surrounding regions. The resulting fabrics have good print characteristics without the physical strength degradation of irregular hand associated with patterned fabrics produced by conventional fabric patterning methods.

Description

For the textile material method for printing with by the fabric of its manufacturing

Invention field

The present invention relates generally to be the textile material method for printing.More specifically, the present invention relates to use the method and the fabric that uses this method to make that plain dyeing coloration of textile materials method is made the textile material of wounded in the battle sample that be generally used for.

Background

Textiles manufacturer is being devoted to obtain to have products unique and different outward appearances.Though the designers can create out unlimited appearance of fabrics from the teeth outwards, fabric manufacturer must consider the condition of performance characteristic that machine efficiency, the cost of raw material, labour's input and processing charges, fabric are required etc.Therefore, designers's creativeness often is subjected to the restriction that manufacturer makes the ability of this fabric effectively according to its design.

A conventional method that obtains pattern fabric is exactly the yarn of dying different colours in advance to be interweaved with making fabric in zones of different.The fabric that obtains with such method is called yarn-dyed fabric, is used for making such as woven striped wide cloth (such as in the normally used kind of Men's Suits shirt).Though yarn-dyed fabric all provides the outward appearance of wishing in many aspects, but it has some deficiency, mainly is to dye color required in product in advance.Those of ordinary skills understand easily, this has prolonged significantly makes the required lead time of this fabric (because must determine color, the yarn that is dyed will reach these colors before the fabric forming method), and the product of small lot manufacturing special color combination may be very expensive.

In addition, fabric knitting equipment (such as loom or knitting machine) must be set specially to obtain required specific style.When changing color and style, this may cause very long machine idle time.Have again, when component yarn respectively in the condition of its dyeing and processing, expose to the open air in different temperature and condition following time, yarn-dyed fabric has the tendency of differential contraction.As a result, after washing, yarn-dyed fabric often produces wrinkle along a kind of yarn and the transition region between the another kind of color yarn of color.Generally speaking, look is knitted the lead time of product and is looked and can not accept, and weaves complexity, and the product that obtains may have bad variation between a side and opposite side.

People attempt to make pattern fabric with the method except that the yarn that uses coloured differently in weaving method always.Such as, on the fabric of being everlasting, directly stamp versicolor style.In the method, the color that required design is needed be printed directly on not have to dye or dyed in advance fabric on.The shortcoming of this class stamp has two.At first, when stamping color on prestained fabric, the color of pattern is subjected to the restriction of main ground colour.This is to show that some color of using will be cannot see or change because main ground colour sees through these colors when stamp.An example is exactly the blue style of printing and dyeing on the main ground colour of yellow.After stamp, style demonstrates green.Have, the yellow style of printing and dyeing on the background color of yellow then be can't see fully again.Therefore on very dark main ground colour, there is not the dyestuff of several printing and dyeing to see.This has just limited the designers, can only use certain several color to specific main ground colour, and perhaps allowing them use does not have the base fabric of dyeing could use palette completely.

When on main ground colour, carrying out stamp with pigment, second shortcoming can running into this printing method.Generally know that by overcoming aforesaid limits of color problem being carried out stamp with pigment on the fabric face of printing and dyeing, in the middle of the plastisol stamp, coming to this usually and do.With such method, can on very dark background colour, stamp the style of white and light color even, also without limits to the selection of color.Yet resulting style but has some stiff and/or elastomeric sensation, compares with the zone that does not stamp style, in sensation and the appearance that has projection in appearance.In the application aspect many dress ornaments, this is undesirable.Moreover after washing and friction repeatedly, the style that stamps finally may become fragile, ftractures and peel off.

Normally used another kind of method is called DISCHARGE PRINTING.When DISCHARGE PRINTING, earlier with textile dyeing (generally being piece dyeing), stamp style with the slurry that contains chemicals then, wherein chemicals makes reducing dyes, has therefore just formed white style in the background of dyeing.Also can in the discharge slurry, add colorant, make to replace by the color of discharge with another kind of color.These discharge chemicals make their fabric portions feel of coating coarse and often reduce its intensity, thereby the bulk strength of fabric is descended.Another shortcoming of this class processing is, can only be chosen in the dyestuff that the effect that is subjected to chemical reducing agent bleaches easily, otherwise also color can residually be arranged in the style district.This chemicals has increased cost, has reduced the use flexibility of this method.

Another method that is used for making pattern fabric is called resisting printing.When carrying out resisting printing, prevent at the material that dyes on the fabric style that on fabric, draws with design.Use the batch dyeing method to give this textile dyeing then.In existing resisting printing method, resist agent generally is water-fast medium.Use the example of the printing method of water-fast medium to be to use the battik of wax and the tie-dyeing process of use elastic band etc. to suppress textile dyeing in the specific region.It is readily appreciated by a person skilled in the art that and use the additional process operation of these medium requirements to remove the medium that these suppress dyeing.When the inhibition dyeing medium was wax, the method for removal may be very difficult, and may damage the bottom of fabric.In dyeing method, removing elastic band is labor-intensive work.Have, the method such such as tie-dyeing process is very limited on the available design kind that they are produced again, and the wax that uses in batik makes that their part of coating can not be caught the color different with the fabric remainder simultaneously on fabric.

An other class resisting printing relates to the stain at the specific region of fabric chemical bond fiber.In general, the resist printing chemicals is printed to specific style on fabric, and then with textile dyeing.In people's such as Moore United States Patent (USP) 5,984,977, narrated an example of this method, this patents state in the method for batch dyeing, use a kind of material of design the stain of cellulosic material to be carried out the purposes of chemical barrier.Because stain by the combination of resist printing chemicals, can not caught color at the regional fabric that uses this chemicals.Though performance is fine in many application, the method still is subjected to some restrictions, because must select the resist printing chemicals that special fiber stain in the fabric is carried out chemical barrier, when the fabric that will be printed is made up of blend fibre, also has problem.Because if there is a kind of fiber to be intercepted in blend fibre, and another kind of fiber is not when being prevented from dyeing, unless the fiber that is not intercepted is not colored so, otherwise the stamp district just can not be intactly by resist printing.This will cause variegated effect on the main ground colour of fabric, so just limited the flexibility of design.In addition, at the anti-dyeing method of the chemistry of viable commercial, the marketization be used for the batch dyeing method, their speed of production all is lower than continuity method or semi-continuous method.Also have, these resist printing chemicals generally all can damage the intensity of fabric.

At last, heat is changeed the paper stamp and be used for pattern fabric.The method is used the calico paper that is printed on dyestuff, and dyestuff will distil when heating.This paper is placed to fabric directly contacts, when heating, just dyestuff is transferred on the fabric from paper by distilling.Heat is changeed the paper stamp and is used widely on polyester, and it uses DISPERSE DYES, and generally carries out under drying regime, along with heating dye diffusion is arrived in the middle of the fiber.Mainly being limited to of the method is the DISPERSE DYES that distils easily.The variation of the method is to carry out heat to shift under hygrometric state, and this just can use transfers to dyestuff kind on the fabric from paper easily in addition in vapour phase.Selection to dyestuff still is restricted, and elder generation's stamp on paper, then dye transfer is remained essential to the two-stage process on the fabric.Have again, can not realize the effect of resist printing with this method, therefore before stamp the main ground colour of fabric design has restriction to style.

Summary

Method of the present invention can be produced pattern fabric with effective and efficient manner, has avoided the desired extra process operation of method of prior art simultaneously.In addition, the method can produce the fabric with colored woven fabric appearance, avoided simultaneously look knit autofrettage intrinsic complexity, also avoided the decline of the fabric intensity that causes by other colouring methods.Have, this method can use continuous or semi-continuous dying operation to make pattern fabric again, and this has just reached the manufacturing efficient higher than general batch process.For this application aims, term " continuous or semi-continuous dying operation " refers to some following dying operations, wherein usually because fabric is to move continuously in the method, generally can make fabric stay the short relatively time in dye bath.Such as, the various continuous and semi continuous dyeing operation in the expectation of the present invention comprises that thermosol dyeing method, pad dyeing/steaming process, thermosol/pad dyeing/steaming process, pad dyeing/high-temperature steam operation, dye gigging method and pad dyeing wait method in batches.These methods generally all are non-methods of dying type to the greatest extent.Otherwise colouring method intermittently relates to fabric " criticize " and dyes, this moment fabric will be in dye mother solution incessantly placement for a long time, with by dying the Color that reaches uniformity with balance to the greatest extent.

This method relates to a kind of chemical substance of coating on fabric, and the machinery inhibition temporarily of this material is wetting to the bottom fabric district, then this fabric is carried out continuous or semi-continuous dyeing.This chemical substance wishes to comprise printing paste.In certain embodiments of the invention, this chemical substance can comprise fluoride.In some cases, this chemical substance can comprise fluoride and printing paste.In many cases, select, make it can machinery suppress bottom fabric district wetting of this chemical substance of coating, need not it be removed from fabric by other removal operation simultaneously this chemical substance.For this reason, wish that this chemical substance is water miscible, it can be removed by chemistry and/or mechanical effect in subsequently normal dyeing and arrangement process as required.

The chemical substance of selecting, it is wetting to suppress the bottom fabric layer district fully, or just part suppresses dye uptake, and the degree that the bottom fabric layer district is dyed is lighter than other zones of fabric that this chemical substance is not provided.In a kind of similar method, can select this chemical substance corresponding to the specific colouring method that will use, make the very short time before colouring method is finished remove this chemical substance, the wetness degree of the fabric portions of this chemical substance bottom will be lighter than the essential part of fabric, and the chance that fabric combines with dye molecule in this zone is smaller thus.In this manner, the part of applied this chemical substance of fabric is dyed the same color of part that fabric is not capped, but color and luster is more shallow.Therefore, just can effectively produce the fabric that has formed style because dye uptake is different in presumptive area.

This chemical substance also can comprise a kind of dyestuff, makes to have printed the color that the fabric portions of style is caught with this chemical substance, is different from the color that quilt is caught in continuous dyeing process subsequently.The invention is not restricted to single application of planting chemical substance, print and dye different styles also within the scope of the invention with more different chemical material.Such as, the chemical substance that does not comprise dyestuff is coated with into first style, will comprise simultaneously that second kind of dyestuff is designed for suppresses wetting water-soluble chemical material and is coated with into second kind of style, obtains a kind of pattern fabric of 3 looks thus.In addition, use two kinds of different chemical materials, print two or more styles, just can access 3 looks or more color effects with different resist printing characteristics.

Method of the present invention can produce has the fabric that unique look is knitted outward appearance, but does not knit the relevant shortcoming of product with look.Such as, in one aspect of the invention, the style of printing on the selection fabric makes it to adapt with the yarn of fabric construction, just can access the outward appearance of yarn-dyed fabric.In addition, all outclass look with printed definition on the ability of the method stamp and the fabric and knit product, particularly when hope has complicated design.Have, fabric keeps all its initial intensity basically, has good dye fastness and dye again, and has outstanding aesthetics and the characteristic on the function.

The accompanying drawing summary

Fig. 1 is the flow chart of an embodiment of the inventive method;

Fig. 2 is the photo (amplifying 40 times) that traditional colour is knitted product;

Fig. 3 is the photo (amplifying 40 times) of fabric made in accordance with the present invention.

Describe in detail

In the detailed description of the invention, narrate particularly preferred embodiment of the present invention below, made it possible to fully and fully understand the present invention.Should admit, not want to limit the invention in these particular preferred embodiment of being narrated, though when narration is of the present invention, used specific term, the purpose of the use of these terms to be explanation, and unrestricted the present invention.

The method of making pattern fabric according to the present invention is described with reference to accompanying drawing 1.As what noticed, in this respect the step of being implemented be on fabric printing resist printing chemicals, with this chemicals drying (choose), be coated with dyestuff, make dyestuff predrying (if desired), fixed dye, cooling fabric (if being heated in advance), be coated with required chemicals, make that this chemicals reacts if desired, laundering of textile fabrics to be to remove excessive chemicals and with fabric drying and batch.Those of ordinary skills should understand, and the particular step of use will change along with the difference of the colouring method that uses, the fabric type that is printed, the chemicals of use, the desired style that obtains.To discuss these steps in more detail below.

Obtain earlier will stamp fabric.This fabric can be an any kind of, comprises woven fabric, knit goods, supatex fabric etc.This fabric can by any can be continuously or the traditional fibre of semi continuous dyeing weave, this includes but not limited to synthetic fiber such as polyester (including but not limited to polyethylene terephthalate, polytrimethylene-terephthalate (PTT) and their modification kind), polyamide, polypropylene, aromatic polyamides, polyolefin, regenerated fiber such as polyactide base fiber (PLA) and artificial silk (as viscose, copper ammonia fibre), natural fabric is as cotton, flax, ramie, hemp and jute etc., perhaps its combination.When producing 100% polyester, 100% cotton and polyester/cotton BLENDED FABRIC, discovery the inventive method can be implemented particularly well.To select fabric, so that required weight of product final use and performance characteristic to be provided.

Wish that these fabrics are the form for preparing, this means they flush away oil, impurity etc. make and/or transportation in the thing that adheres to.Preferred dry fabric is the part of preparation method, can provide a kind of stable product for being coated with chemical substance and dyeing like this.

With a kind of design, can temporarily suppress the wetting chemical substance in bottom fabric layer district then, on this fabric, be coated with by required style.Wish this chemical substance to be applied on the fabric with printing method.These printing methods can be such as roller bed stamp, rotary screen stamp, aniline stamp, intaglio plate roller coat stamp, the jet printing of speaking out of turn (such as being narrated common the transfer in the United States Patent (USP) 4,923,743) etc.Yet other coating process that is included in the scope of the present invention includes but not limited to brushing rubbing method, supersonic spraying, foam rubbing method, printhead Decal etc.This chemical substance can be coated with into any required style.In addition, " style " of coating can be (such as resulting with the brushing method) such as random points.Should be readily appreciated that the zone of coating chemicals will determine or catch the style in the zone of different colours that the kind of coating style comes down to hard-core achromophil on final fabric.As a result, the appearance of fabrics that can the method obtains unlimited variety.

Design this chemical substance so that its physics in a period of time suppresses the wetting of bottom fabric district.In one aspect of the invention, design this chemical substance and reach a period of time, the contact time that will be longer than fabric and water soluble dyestuffs mother liquor during this period of time to prevent that bottom fabric zone is wetting.In another aspect of this invention, can suppress wetting time span or its according to it and suppress wetting degree and select this chemical substance,, allow certain wetting simultaneously to avoid the saturated of bottom region.Do not remove these chemicals because the processing in downstream requires, fabric still keeps the performance that suppresses wetting after processing.(in contrast, existing mechanical suppresses the wetting means of fabric, such as wax, then requires an independent procedure of processing to remove them, because only after removing these materials, fabric just has is enough to make its useful aesthetics and the feature on the performance).Therefore, this chemical substance wishes it is water miscible.

Change a kind of narration method, select chemical substance to suppress the wetting of bottom fabric part, preferably suppress wetting fully.When this chemical substance is designed to part when suppressing fabric wetting, can be chosen to allow the partially wetted speed of bottom fabric be lower than untreated part significantly, the time that perhaps is chosen to suppress wetting is shorter than the length of dyeing course slightly.Thus, compare with the unprocessed portion of fabric, the part that is printed on chemical substance on the fabric will expose to the open air under the dyestuff of less amount and/or expose to the open air the shorter time.As a result, will catch the base color (color) identical, but the degree of depth of color and luster is from more shallow slightly to much shallow than the district of being untreated with the peripheral region of fabric with that part of fabric that chemical substance treatment is crossed.

This chemical substance preferably contains the printing paste that comprises thickener and water.In some form of the present invention, this chemical substance comprises fluoride.In some form of the present invention, this chemical substance had both comprised printing paste, also comprised fluoride.Under any circumstance, select this chemical substance to make it can suppress bottom region wetting that fabric scribbles this material, need not it be removed from fabric by other removal operation simultaneously, this will further discuss.

The example that discovery can be implemented chemical substance of the present invention well is the printing paste of alginic acid alkali, the printing paste of xanthan matrix, the printing paste of synthetic thickening agent base, various fluoride and their combination.Select the viscosity of these chemical substances and rheological property optimizing wetting inhibition, and in the finished product fabric, reach the design outward appearance of anticipation.Those of ordinary skills should understand easily, will select the accurate prescription of this chemical substance, to adapt to used coating process, screen mesh size, required consumption etc.These parameters all are the imaginations in scope of the present invention, and every kind of used accurate prescription of fabric all is easy to discern, and do not need too much experiment.Have now found that in rotary screen Decal (used in as the embodiment at this paper), the viscosity of this chemical substance is about 8 pools～about 70 pools, preferably approximately 10 pools～about 40 pools (according to the thickener difference of using) are just fine.To under the pressure of design, be coated with this chemical substance, smooth to reach stamp, and make the substrate of specific chemical and use that suitable infiltration be arranged.Such as, find that about 3psi～approximately the pressure limit of 10psi is good for implementing above-mentioned chemical substance.In addition, select the pressure of this chemical substance of coating,, make it reach required design and obtain the smooth necessary degree of stamp product to optimize the infiltration that this chemical substance enters particular web.Similarly, the rheological property of wishing this chemical substance can provide good flowability and quick stopping performance.

In some form of the present invention, this chemical substance also will comprise dyestuff.Thus, the part that fabric is coated with this chemical substance will stamp first kind of color, and not have the base fabric zone on every side of this chemical substance will catch different colors in dyeing course basically.This chemical substance it is readily appreciated by a person skilled in the art that and use different style and different chemical substances, more than can be coated with once.Therefore, can use this method to obtain in fact the fabric style and the outward appearance of unlimited amount.Such as this chemical substance being applied on the fabric, make the style of its imitation yarn in fabric construction, such as by stamping the stripes that the strip decorative pattern is knitted with the simulation look at warp thread or weft direction.Have, this chemical substance can comprise the chemicals of other type again, such as fluorescent whitening agent, dissimilar dyestuff, copolymer, additional benefit can be provided, and can not disturb the chemicals of implementing any kind that the present invention institute must performance etc.

In most of the cases, wished before staining procedure subsequently this chemicals drying.Can carry out this drying by any conventional method of in fabric drying, using, such as fabric is passed through a baking oven.This helps to guarantee to make this chemical substance in the bottom fabric layer part.Temperature that selection is used and method are to optimize this used chemical substance and the performance of used substrate.

Then in traditional continuous or semi-continuous mode, such as thermosol dyeing method with this textile dyeing.Yet, also can use the dying operation of other type within the scope of the invention, such as pad dyeing/steaming process, thermosol/pad dyeing/steaming process, cold rollingly dye batch process, dye gigging method etc. and have different effects.Those of ordinary skills should understand easily, should select the colouring method that uses according to the type of the kind of the fabric that will process and the dyestuff that will use.Similarly, select the kind of chemical substance and consumption to optimize by the outward appearance of dyeing and weaving thing.In other words, the type of colouring method and chemical substance should be coordinated, and make the machinery inhibition to wetting that this chemical substance provided can hold out against used specific colouring method, reach by dyeing to obtain the necessary degree of required style.Similarly, the colouring method of use also will be selected, so that the particular web that will make obtains required result.Such as, in many cases, wish to use high-efficiency and continuous and semi continuous dyeing method; In these cases, the yarn of formation fabric is often encircled and is dyed.

When using thermosol/pad dyeing steaming process, general following the carrying out of these methods: the fabric of applied in the above chemical substance is by the dyestuff pad, prevent fabric by the fully wetting zone except chemical substance here, dyestuff will be saturated the remainder of fabric.Hope is carried out fabric predrying, is heated to enough temperature then, makes dye sublimation in substrate, and so dyestuff just distils and is penetrated in the middle of the fiber.Wish then this fabric to be carried out boiling, scouring and washing, to remove possibility residual any excess chemicals and dyestuff with conventional method.With fabric cools down, and can be coated with the arrangement chemicals of any needs.Such as, can provide design to promote dirt to remove and wicking according to the needs of fabric, perhaps reduce the chemicals of static and/or balling-up.In addition, can also carry out the surface dressing of any hope as required.As required fabric drying and packing are distributed then.

Also can select, with the outward appearance type that realizes wishing used dyestuff.Such as, when fabric is the polyester/cotton BLENDED FABRIC, and when wishing to have monochromatic base fabric, can use the combination dyestuff of DISPERSE DYES and reducing dye, so that polyester and cotton component can both dye.In the case, use thermosol/pad dyeing/steaming process, can be after the thermosol baking oven, and on aforesaid method, increase the additional step of boiling, scouring and washing.In addition, dye bath can comprise and only is designed to form the dyestuff that fiber dyes to a kind of, makes base fabric obtain variegated outward appearance.Such as, the polyester/cotton BLENDED FABRIC only can be exposed to the open air in DISPERSE DYES, it will make polyester components dyeing, and remaining cotton component does not dye in fact, obtains the unique look of base fabric thus.

As mentioned above, select, make the wetting of a part of fabric of its temporary transient at least inhibition, can in continuous or semi-continuous colouring method, on fabric, obtain style like this chemical substance.The character of this chemical substance makes does not need the process that is removed subsequently.In other words, the effect of colouring method, drying, arrangement and/or scouring operation is to remove to produce any chemicals that disturbs to the final performance of fabric.Such as, when this chemical substance comprised or mainly is made up of printing paste, procedure of processing subsequently generally was to be used for removing printing paste from fabric.Equally, when this chemical substance comprises or mainly is made up of fluorocarbon, wish that some fluorocarbons are retained on the fabric, so that printing area has the repellency energy for a long time.Under any circumstance, can coordinate used chemical substance and colouring method, the amount that remains in the chemical substance on the fabric after the feasible processing is controlled on the level of hope.

As the yarn-dyed fabric in comparison diagram 2 with on Fig. 3 as shown in during represented fabric of the present invention, has excellent outward appearance according to the resulting fabric of method of the present invention, approach the outward appearance of yarn-dyed fabric in many cases, the problem of but avoiding the sort of manufacture method to bring simultaneously.Such as, the problem that can avoid general relevant with yarn-dyed fabric difference to shrink is because if need the base fabric that can obtain having homogeneous texture.Fabric of the present invention also has good performance characteristic, such as the durability of physical strength, outward appearance, dyefastness, fastness to washing, design very uniformly, and in the stamp district with uniform sensation and feel do not arranged between the stamp district.

Embodiment

Obtain three kinds of commodity looks and knit the shirt fabric, be stated as Sample A, B and C below.

Sample A is vivid blue and the common poplin cloth fabric Dark grey striped, and its weight is 4.3oz/sq yd.The finished product structure is 102 warp thread of per inch, 57 weft yarns of per inch.Warp thread and weft yarn all are to be formed by 65% polyester and 35% cotton blending.Think that this fabric has carried out traditional decontamination and DP chemical treatment, and through slight polishing.

Sample B is the common poplin cloth fabric that has thin blue stripe on white background.The weight of fabric is 4.3oz/sq yd, 77 warp thread of finished product structure per inch and 59 weft yarns.Warp thread and weft yarn all are to be formed by 65% polyester and 35% cotton blending.Think that this fabric used traditional decontamination and DP chemical treatment, and through slight polishing.

Sample C is the common poplin cloth fabric with multiple color striped.The weight of fabric is 4.3oz/sq yd, and the finished product structure is 104 warp thread of per inch and 60 weft yarns.Warp thread and weft yarn are all formed by 65% polyester and 35% cotton blending.The inventor thinks that this fabric has been used common decontamination and DP chemical treatment, and slight polishing.

Sample D is 4.3oz 65/35 a polyester/cotton poplin cloth fabric.With following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/lCl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22 (in other words, this fabric is dyed the main ground colour same with following sample E).Put this fabric in order with conventional method then, on the arrangement chemicals of traditional type, carry out pad dyeing, so that the characteristic of leading wet, decontamination and DP to be provided, in a conventional manner with it by a stenter, make resin crosslinks, and the fabric width of fabric fixed.Being used in the method for narrating in the common transfer United States Patent (USP) 5,752,300 of Dischler then polishes weave machine, and be used in the common transfer United States Patent (USP) 5 of Dischler, method described in 822,835 is handled (forming microfissure in the resin chemicals) with pressure-air.The finished product structure of fabric is 102 warp thread of per inch and 47 weft yarns.

Sample E is woven into sample D same structure, after preparation with 165 purpose screen clothes of following chemical substance, form two bar styles on fabric: the synthetic back side thickener of 60g/kg fluoride (APG-85 of AdvancedPolymer company), 11g/kg, the alginates base-material printing paste of 929g/kg, it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water.(those of ordinary skills can understand, and it is in order to promote the performance of printing equipment that a spot of chelating agent, defoamer and antiseptic are provided).This chemical substance also comprises 1.35g/kg disperse red mixture, 0.41g/kg disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 320 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.36oz/sq yd, 101 warp thread of per inch and 48 weft yarns.

Sample F is woven into sample D same structure, after the preparation on fabric the coating following chemical substance form wide style: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85), 11g/kg, 929g/kg in the Advanced Polymer of New Jersey state Carlstadt company.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 370 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/lCl vat red 10 and 3.394g/l Cl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.41oz/sq yd, and structure is 101 warp thread of per inch and 48 weft yarns.

Sample G to be weaving with sample D same way as, after the preparation on fabric the following chemical substance of coating form wide style: the synthetic back side thickener of 60g/kg fluoride (APG-85), 11g/kg, 929g/kg alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) in the Advanced Polymer of New Jersey state Carlstadt company.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 350 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.36oz/sq yd, 101 warp thread of per inch and 48 weft yarns.

Sample H to be weaving with sample D same way as, after the preparation on fabric the following chemical substance of coating form two bar styles: the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water).This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 350 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.31oz/sq yd, and structure is 101 warp thread of per inch and 48 weft yarns.

Sample I to be weaving with sample D same way as, after the preparation on fabric the following chemical substance of coating form wide style: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 320 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.35oz/sq yd, 102 warp thread of per inch and 48 weft yarns.

Sample J to be weaving with sample D same way as, after the preparation on fabric the following chemical substance of coating form two bar styles: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 370 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.34oz/sq yd, and structure is 102 warp thread of per inch and 48 weft yarns.

Sample K is to weave with sample D same way as, and the following chemical substance of coating forms two bar styles on fabric then: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 385 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.4oz/sq yd, 102 warp thread of per inch and 48 weft yarns.

Sample L is to weave with sample D same way as, and the following chemical substance of coating forms wide style on fabric then: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 385 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.42oz/sq yd, 101 warp thread of per inch and 48 weft yarns.

Sample M is to weave with sample D same way as, and the following chemical substance of coating forms the mesh-shape style on fabric then: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 385 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.42oz/sq yd, and structure is 101 warp thread of per inch and 48 weft yarns.

Sample N is to weave with sample D same way as, and the following chemical substance of coating forms the mesh-shape style on fabric then: the alginates base-material printing paste (it comprises 32.5g/kg low-viscosity alginates thickener, chelating agent, defoamer, antiseptic and water) of the synthetic back side thickener of 60g/kg fluoride (APG-85 of Advanced Polymer company), 11g/kg, 929g/kg.This chemical substance also comprises the disperse red mixture of 1.35g/kg, the disperse blue 60 of 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.The viscosity of this mixture is 38 pools, and the steel edge of use 40mm is coated with it with the pressure of about 11psi.Dry this chemical substance under 385 .Use then following dye mixture under 425  in thermosol with this textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl mixing vat yellow, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.With being equivalent to the method described in the sample D fabric is put in order then.The weight of arrangement back fabric is 4.33oz/sq yd, and structure is 102 warp thread of per inch and 48 weft yarns.

Method of testing

In this test, term " industry washing " means washing methods as described below.

The industry washing test

Operation sequence:

1. weigh to sample, getting load is 15 ± 1) pound.

Attention: if desired, use 100% white cotton tester, to obtain suitable weighing load.

2. industrial washing methods technical specification (Milnor washing machine):

Process	W/L	Temperature	Time (min)	Supply	The pH value	Basicity (ppm)
								Can obtain	Amount to
						Interrupt being detained rinsing rinsing rinsing rinsing acidifying	Low Gao Gaogao height			Add steam to 165 140-155 120-130 110-120 100-110 90-100 90-100	15 5 2 2 2 2 5	16.5 IFL#15 or 50 (± 2) mL of Orthosil or 300 (± 10) mL 2.8 (± 0.2) oz of (± 1) oz does not have acid or the 7 ± 0.5mL of 0.25 (± 0.05) oz	11.5-12.5 11.0-12.0 10.2-10.8 10.2-10.8 9.0-10.0 9.0-10.0 6.5-7.0	2826 1880 148 99 50 12 -	3964 2459 299 205 173 46 -

3. signaling switch is placed the next circulation that begins.

4.W/L expression water surface elevation.Low=12 gallon, high=24 gallons.

5. (± .25) the pound that from the load of 15 (± 1) pounds, takes out 4, put into Sears Kenmore home dryer and (will guarantee that all samples all put into drying machine, if you have the sample more than 4.25 pounds, please be divided into two loads, each all has the even number sample.The remainder of each load should be made of control fabric).

6. the Cotton Sturdy of drying machine is set at 30 minutes.Guarantee to take out drying machine after the sample bone dry.

7. repeat the cycle-index that above-mentioned washing and drying steps reach regulation.

Annotate: Orthosil=Orthobrite

TENSILE STRENGTH: the TENSILE STRENGTH of on each direction of warp thread and weft yarn, measuring every fabric sample according to ASTM D-5034-95.After 10 times, 25 times, 50 times and 100 times industry washing, all test a plurality of samples.

Tear strength: according to ASTM D1424-96, use Elmendorf tearing tester on each direction of warp thread and weft yarn, to measure the tear strength of every fabric sample, after 10 times, 25 times, 50 times and 100 industry are washed, all test a plurality of samples.

Take off seam: test on the direction of warp thread and weft yarn according to the method for testing of ASTM D-434-42 and take off seam.

Crooked: according to the bending of ASTM D3885-99 test fabric on warp thread and weft yarn both direction.

Outward appearance: washing methods laundering of textile fabrics as described above, and carry out classification according to AATCC method of testing 124-1992.

Balling-up: according to the balling-up of ASTM D-3512-99A test fabric.Knit product for look, when receiving and after 10 times, 25 times and 50 times industry washing, test.For fabric of the present invention, when receiving, test its balling-up.

Color data: use 10 grades of spherical spectrophotometer measurement primary color data, the D65 minute surface with eliminating light source of UV filter is located at 0%.To be untreated the district as standard, and processed district uses following formula to calculate DE, DL, Da and Db as sample:

DL=L ₁-L ₂, L here ₁Be untreated, L ₂Handle;

Da=A ₁-A ₂, A here ₁Be untreated, A ₂Handle;

Db=B ₁-B ₂, B here ₁Be untreated, B ₂Handle;

$\mathrm{DE}=\sqrt{{\mathrm{DL}}^2+{\mathrm{Db}}^2+{\mathrm{Da}}^2}$

Area under area under the % intensity=processed district reflectivity curve/district's reflectivity curve that is untreated.

DE represents total color difference between two zones, and DL is illustrated in difference on the depth of color.Such as, DL does not have difference between two zones of 0 expression on depth of color.Difference on red/green tint that Da represents, and Db represents difference on Huang/blue color.The classification declaration of intensity is for the % of two field color differences.Do not comprise the sample of dyestuff for the resist printing chemicals, low intensity level will illustrate the amount of high resist agent.

Reported the result of each test among Table A below and the table B.

Table A

	A	B	C	D	E	F	G
								Fabric width	N/A	N/A	N/A	-	64.63	64.63	64.75
Weight oz/sq yd	4.3	4.3	4.3	4.3	4.36	4.41	4.36
								Warp thread	102	77	104	102	101	101	101
Weft yarn	57	59	60	47	48	48	48
								TENSILE STRENGTH (warp) washing	119	101	117	112	113	111	112
TENSILE STRENGTH (warp) is washed 10 times	115	110	96	-	129	121	130
								TENSILE STRENGTH (warp) is washed 25 times	110	103	97	-	116	115	109
TENSILE STRENGTH (warp) is washed 50 times	102	98	71	-	98	110	101
								TENSILE STRENGTH (warp) is washed 100 times	-	-	-	-	99	90	94
TENSILE STRENGTH (latitude) rigidly connects receipts	59	78	64	77	80	74	71
								TENSILE STRENGTH (latitude) is washed 10 times	60	78	66	-	82	79	84
TENSILE STRENGTH (latitude) is washed 25 times	51	73	56	-	82	77	79
								TENSILE STRENGTH (latitude) is washed 50 times	36	64	51	-	74	75	74
TENSILE STRENGTH (latitude) is washed 100 times	-	-	-	-	77	76	77
								Anti-tear (warp) AR	2246	2588	2096	2035	2300	2200	1900
Anti-tear (warp) washed 10 times	1958	2166	1833	-	2000	1700	1725
								Anti-tear (warp) washed 25 times	1635	1801	1440	-	1750	1650	1575
Anti-tear (warp) washed 50 times	1267	1478	1136	-	1750	1800	1700
								Anti-tear (warp) washed 100 times	-	-	-	-	1650	1475	1400
Anti-tear (latitude) AR	1401	1715	1264	2100	1950	2100	2250
								Anti-tear (latitude) washed 10 times	1305	1446	1126	-	1650	1700	1725
Anti-tear (latitude) washed 25 times	931	1267	838	-	1600	1650	1650
								Anti-tear (latitude) washed 50 times	688	976	627	-	1850	2100	1900
Anti-tear (latitude) washed 100 times	-	-	-	-	1500	1650	1550
								Take off seam (warp)	40	40	40	37	33	34	35
Take off seam (latitude)	40	40	40	40	40	40	40
								Crooked (warp)	2000	2000	2000	2000	2000	2000	2000
Crooked (latitude)	2000	2000	2000	2000	2000	2000	2000
								Outward appearance	3	3	3	3.6	3.5	3.5	3.5
Balling-up AR	4	4.5	4	-	4	4	4
								Balling-up is washed 10 times	4	4.5	4	3.5	-	-	-
Balling-up is washed 25 times	4.5	4.5	4.5	-	-	-	-
								Balling-up is washed 50 times	4.5	4.5	4.5	-	-	-	-

Table B

	H	I	J	K	L	M	N
								Fabric width	64.63	64.75	64.88	64.63	64.75	64.63	64.5
Weight oz/sq yd	4.31	4.35	4.34	4.4	4.42	4.42	4.33
								Warp thread	101	102	102	102	101	101	102
Weft yarn	48	48	48	48	48	48	48
								TENSILE STRENGTH (warp) washing	109	114	119	108	104	112	101
TENSILE STRENGTH (warp) is washed 10 times	124	119	115	110	109	123	105
								TENSILE STRENGTH (warp) is washed 25 times	113	108	114	113	118	107	105
TENSILE STRENGTH (warp) is washed 50 times	107	105	97	95	109	105	107
								TENSILE STRENGTH (warp) is washed 100 times	99	84	91	73	95	94	95
TENSILE STRENGTH (latitude) is average	77	74	74	69	76	73	70
								TENSILE STRENGTH (latitude) is washed 10 times	82	82	82	76	80	82	77
TENSILE STRENGTH (latitude) is washed 25 times	85	78	80	74	84	82	76
								TENSILE STRENGTH (latitude) is washed 50 times	80	73	72	60	65	82	77
TENSILE STRENGTH (latitude) is washed 100 times	78	77	77	68	70	74	74
								Anti-tear (warp) AR	1975	1975	2000	1850	2100	1900	2050
Anti-tear (warp) washed 10 times	1700	1750	1500	1550	1700	1750	1750
								Anti-tear (warp) washed 25 times	1600	1750	1750	1600	1675	1650	1700
Anti-tear (warp) washed 50 times	1800	1800	1900	1000	1750	1750	1800
								Anti-tear (warp) washed 100 times	1400	1450	1500	1250	1400	1500	1450
Anti-tear (latitude) AR	2100	2200	2150	1925	2200	2100	2300
								Anti-tear (latitude) washed 10 times	1700	1575	1450	1750	1600	1675	1750
Anti-tear (latitude) washed 25 times	1800	1800	1850	1625	1750	1750	1600
								Anti-tear (latitude) washed 50 times	2000	2025	1975	1500	1950	1400	1950
Anti-tear (latitude) washed 100 times	1750	1550	1600	1500	1550	1650	1575
								Take off seam (warp)	31	33	30	36	36	34	34
Take off seam (latitude)	40	40	40	40	40	40	40
								Crooked (warp)	2000	2000	2000	2000	2000	2000	2000
Crooked (latitude)	2000	2000	2000	2000	2000	2000	2000
								Outward appearance	3.5	3.5	3.5	3.5	3.5	3.5	3.5
Balling-up AR	4	4	4	4	4	4	4
								Balling-up is washed 10 times	-	-	-	-	-	-	-
Balling-up is washed 25 times	-	-	-	-	-	-	-
								Balling-up is washed 50 times	-	-	-	-	-	-	-

Sample A A makes in the laboratory to AP, use be laboratory thermosol pad dyeing steam.Fabric does not carry out the back arrangement.

Sample A A is the 65/35 polyester/cotton poplin cloth fabric of 4.3oz.Use contain the printing paste of alginic acid alkali of the synthetic back side of 11.5g/kg thickener and basic printing paste that 988.5g/kg contains alginates thickener, chelating agent, defoamer, antiseptic and water laboratory scale ooze to dye on the platform catch wide style to fabric.(as superincumbent sample, containing a small amount of chelating agent, defoamer and antiseptic is in order to promote the performance of stamp).The viscosity of slurry is 25 pools.In the NewJersey state, with this chemical substance drying, be arranged to be output as 65% on the infrared band drier in various laboratories that the Glenro company of Paterson sells, the speed of conveyer belt is 1.96m/min.Temperature is between 220～330 °.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit, with following mixed dye with this textile dyeing 50 seconds: 5.10g/l Cl disperse orange 30,11.97g/l Cl disperse blue 165 and 5.65g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A B is the base fabric identical with Sample A A.With as described in the Sample A A, but also contain 6% from New Jersey state, the alginic acid alkali printing paste of the fluoride APG 5264 of the Advanced Polymer company of Carlstadt stamps wide style to fabric.On the infrared band drier in laboratory described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 5.10g/l Cl disperse orange 30,11.97g/l Cl disperse blue 165 and 5.65g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A C is the base fabric identical with Sample A A.With as described in the Sample A A, stamp wide style to fabric but also contain 6% alginic acid alkali printing paste from the fluoride APG 85 of Advanced Polymer company.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 5.10g/l Cl disperse orange 30,11.97g/l Cl disperse blue 165 and 5.65g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A D is the base fabric identical with Sample A A.With as described in the Sample A A, stamp wide style to fabric but also contain 10% alginic acid alkali printing paste from a kind of sugar copolymer Solopol ZB30 of Stockhausen company of North Carolina state Greensboro.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 5.10g/l Cl disperse orange 30,11.97g/l Cl disperse blue 165 and 5.65g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A E is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A F is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This slurry also contains 6% the fluoride APG 5264 from AdvancedPolymer company.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A G is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This slurry also contains 6% the fluoride APG 85 from AdvancedPolymer company.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A H is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This slurry also contains a kind of sugar copolymer Solopol ZB30 of the Stockhausen company supply of 10% North Carolina state Greensboro.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A I is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This slurry also contains a kind of sugar copolymer Solopol ZB30 of Stockhausen company supply of 10% North Carolina state Greensboro and the disperse red mixture of 1.35g/kg, disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs of 0.41g/kg.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/lCl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A J is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This slurry also contains the disperse red mixture of 1.35g/kg, disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs of 0.41g/kg.In the mode described in Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A K is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This printing paste comprises the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.This slurry also contains 6% the fluoride APG 5264 from Advanced Polymer company.With this chemical substance drying, drying machine is arranged to be output as 65% on the infrared band drier in laboratory, and the speed of conveyer belt is 1.96m/min.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A L is the base fabric identical with Sample A A.With as described in the Sample A A, comprise that also the alginic acid alkali printing paste of disperse violet 57 dyestuffs of the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and 8.2g/kg stamps wide style to fabric.This slurry also contains 6% fluoride APG 85.With as the described mode of Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/lCl disperse ruby red mixture.Then with in method described in the Sample A A with this fabric drying.

Sample A M is the base fabric identical with Sample A A.With as stamp wide style at the alginic acid alkali printing paste described in the Sample A A to fabric.This printing paste also comprises the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.This slurry also contains 10% a kind of sugar copolymer Solopol ZB30 by the supply of Stockhausen company.With as in the mode described in the Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.Then with in the mode described in the Sample A A with this fabric drying.

Sample A N is the base fabric identical with Sample A A.Stamp wide style with the alginic acid alkali printing paste described in Sample A A in the above to fabric.This chemical substance also comprises the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.With as in the mode described in the Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/lCl vat black 22.Then as in the mode described in the Sample A A with this fabric drying.

Sample A O is the base fabric identical with Sample A A.Stamp wide style with the alginic acid alkali printing paste described in Sample A A in the above to fabric.This slurry also comprises 6% fluoride APG5264.This chemical substance also comprises the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.With as in the mode described in the Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then as in the mode described in the Sample A A with this fabric drying.

Sample A P is the base fabric identical with Sample A A.Stamp wide style with the alginic acid alkali printing paste described in Sample A A in the above to fabric.This slurry also comprises 6% fluoride APG85.This chemical substance also comprises the disperse blue 60 of 1.35g/kg disperse red mixture, 0.41g/kg and disperse violet 57 dyestuffs of 8.2g/kg.With as in the mode described in the Sample A A with this chemical substance drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then as in the mode described in the Sample A A with this fabric drying.

Sample A Q is the base fabric identical with Sample A A.Concentrate synthetic slurry (the trade name WTA that makes by the Abco industrial group of South Carolina state Roebuck) and a small amount of chelating agent, defoamer and antiseptic and stamp wide style to fabric with containing 17.4kg water, 12.114g/kg with the synthetic basic printing paste of promotion printing performance.This slurry is a stiff, does not therefore have tested viscosity.The infrared band drier of producing with the Glenro company of New Jersey state Paterson in various laboratories is with this slurry drying, and it is set in 65% output, and the speed of conveyer belt is 1.96m/min, and temperature is 220～330 .Under 425 , give textile dyeing 50 seconds with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit: 5.10g/l Cl disperse orange 30,11.97g/l Cl disperse blue 165 and 5.65g/l Cl disperse ruby red mixture then.Then under the temperature that is no more than 300  in the infra-red drying device with fabric drying.

Sample A R is the base fabric identical with Sample A A.Stamp wide style with the various synthetic basic printing paste described in Sample A Q in the above to fabric.Yet this printing paste also comprises 6% North Carolina state, the Hipochem FCX fluorocarbon replenishers that the High Point Chemical company of High Point sells.With as in the mode described in the Sample A Q with this fabric drying.Then under 425 , in thermosol/pad dyeing in the laboratory/steam unit with following mixed dye with textile dyeing 50 seconds: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture.Under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A S is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q.Then with as in the mode described in the Sample A Q with fabric drying.Under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then with in the mode described in the Sample A Q with this fabric drying.

Sample A T is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q.This slurry also comprises 6% HipochemFCX fluorocarbon replenishers.Then with as in the mode described in the Sample A Q with fabric drying.Under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/lCl vat red 10 and 3.394g/l Cl vat black 22.Then with in the mode described in the Sample A Q with this fabric drying.

Sample A U is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q.Also comprise 1.35g/kg disperse red mixture, 0.41g/kg disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs in this slurry.Then with as in the mode described in the Sample A Q with fabric drying.Under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A V is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q, this slurry also contains 6% HipochemFCX fluorocarbon replenishers and 1.35g/kg disperse red mixture, 0.41g/kg disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs.Then with as in the mode described in the Sample A Q with fabric drying, under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165 and 0.700g/l Cl disperse ruby red mixture.Then under the temperature that is no more than 300  in the infra-red drying device with this fabric drying.

Sample A W is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q.This slurry also comprises 1.35g/kg disperse red mixture, 0.41g/kg disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs.Then with as in the mode described in the Sample A Q with fabric drying, under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/l Cl vat red 10 and 3.394g/l Cl vat black 22.Then with in the mode described in the Sample A Q with this fabric drying.

Sample A X is the base fabric identical with Sample A A.With as catch wide style for this fabric at the various synthetic basic printing paste described in the Sample A Q.This slurry also comprises 6% HipochemFCX fluorocarbon replenishers and 1.35g/kg disperse red mixture, 0.41g/kg disperse blue 60 and 8.2g/kg disperse violet 57 dyestuffs.With as in the mode described in the Sample A Q with fabric drying, under 425 , dyeed 50 seconds to fabric with following mixed dye in thermosol/pad dyeing in the laboratory/steam unit then: 2.469g/l Cl disperse orange 30,0.729g/l Cl disperse blue 165,0.700g/l Cl disperse ruby red mixture, 1.986g/l Cl vat yellow mixture, 1.811g/lCl vat red 10 and 3.394g/l Cl vat black 22.Then as in the mode described in the Sample A Q with this fabric drying.

Use aforesaid method test color data.Calculate relative dE, dL, da, db and the intensity (fabric has the part of chemical substance with respect to the part that does not have chemical substance) of each sample.The results are shown in as among the following table C.

Table C

	dE	dL	da	db	Intensity (%)
						AA	13.858	13.764	0.092	-1.609	39.2
AB	15.391	15.359	0.161	-0.977	35.52
						AC	17.106	17.093	0.031	-0.654	31.76
AD	16.026	15.969	0.07	-1.345	33.95
						AE	16.37	16.246	1.268	1.556	34.86
AF	17.129	16.983	1.824	1.293	33.01
						AG	19.682	19.496	1.95	1.869	28.07
AH	18.319	18.182	1.359	1.755	30.67
						AI	14.75	10.127	-6.124	-8.804	50.24
AJ	13.937	8.904	-5.865	-8.976	54.23
						AK	16.551	8.624	-7.508	-11.966	55.85
AL	16.87	8.054	-7.872	-12.561	58.2
						AM	15.814	8.653	-7.604	-10.834	57.03
AN	15.939	7.56	-7.742	-11.703	61.25
						AO	18.173	6.821	-8.024	-14.811	64.18
AP	18.591	5.07	-8.062	-15.966	72.28
						AQ	5.681	5.622	-0.091	-0.808	67.8
AR	7.701	7.643	0.041	0.91	60.55
						AS	8.6	8.652	0.095	0.35	56.6
AT	10.421	10.353	0.17	1.175	51.13
						AU	7.414	2.905	-3.902	-5.595	80.85
AV	7.463	2.752	-4.63	-5.16	82.6
						AW	12.73	1.144	-6.616	-10.815	92.22
AX	12.698	0.0601	-6.914	-10.633	95.99

As what noticed from embodiment, synthetic can use the continuous dyeing legal system to produce PRINTED FABRIC with the alginates printing paste.Yet the performance of alginates is better than the specific synthetic printing paste based on specified conditions used (viscosity, pressure, sieve number etc.).Yet every kind of slurry of being tested all provides good style, and the loss of strength of fabric is minimized.Be also noted that the method for the present invention of using, the substrate of the kind by selecting the resist printing chemicals, coating process, use and dyestuff etc. just can change the degree of resist printing.Use high to basically fully the style of the style of resist printing and lower resist printing level (just accomplishing has change color slightly) all in the scope that the present invention imagines.

Can be used in any final use that PRINTED FABRIC has effectiveness according to the fabric of the present invention preparation, this includes but not limited to dress ornament, family's stuff, the tablecloth, industrial products etc.Confirm that as the product durability after the industry washing this fabric has special purposes aspect the clothing of making lease laundry market use.

The preferred embodiments of the invention are provided in this manual, though used special term, they are only used for general and illustrative meaning, hard-core purpose, and scope of the present invention defines in the claims.

Claims (32)

1. method of making pattern fabric, this method may further comprise the steps:

Zone coating chosen on fabric is designed for the water-soluble chemical material that suppresses wetting, thereby determines the processed and untreated areas that forms style;

Described fabric is exposed in the water soluble dyestuffs mother liquor dyes, reach capacity until described untreated areas, described processed zone is then fully saturated, forms pattern fabric thus.

2. the method for claim 1, wherein said chemical substance comprise the material that is selected from alginates printing paste, synthetic printing paste, fluoride and combination thereof.

3. the method for claim 1, wherein said chemical substance comprises printing paste.

4. method as claimed in claim 3, wherein said chemical substance is made up of printing paste basically.

5. the method for claim 1, wherein said chemical substance comprises fluoride.

6. the method for claim 1, wherein said chemical substance comprises fluoride and printing paste.

7. the method for claim 1, wherein said chemical substance further comprises dyestuff.

8. the method for claim 1, wherein said chemical substance comprises fluorescent whitening agent.

9. the method for claim 1, wherein said chemical substance comprises dyestuff and printing paste.

10. the method for claim 1, wherein said staining procedure is undertaken by continuous or semi-continuous colouring method.

11. the method for claim 1, wherein said staining procedure by be selected from thermosol dyeing method, pad dyeing/steaming process, thermosol/pad dyeing/steaming process, cold rolling method of dying batch process, dye gigging method and their combinations is carried out.

12. method as claimed in claim 11, the step of wherein said continuous dyeing use the thermosol dyeing method to carry out.

13. method as claimed in claim 11, the step of wherein said continuous dyeing use pad dyeing/steaming process to carry out.

14. the method for claim 1, wherein said fabric comprise the fiber that is selected from polyester, cotton, PLA, PTT, nylon, artificial silk and their blending things.

15. the method for claim 1, wherein said fabric comprises polyester, and described staining procedure uses thermosol or pad dyeing/steam-colour method to carry out.

16. the method for claim 1, wherein said staining procedure comprise that usefulness is selected from dying to textile dyeing of DISPERSE DYES, REACTIVE DYES, direct dyes, reducing dye, ACID DYES and SULPHUR DYES.

17. the fabric of Zhi Zaoing in accordance with the method for claim 1.

18. the method for claim 1 is wherein carried out step at the bottom of the described coating chemical based by the method that is selected from aniline stamp, intaglio plate roller coat stamp, roller bed stamp, rotary screen stamp, brushing rubbing method, supersonic spraying, speak out of turn jet printing and printhead Decal.

19. the method for claim 1, the step of wherein said coating chemical substance has been determined first style, and further comprise and be designed for the step that the wetting water-soluble chemical material of inhibition is coated with second style that becomes to be different from first style second kind, form multicolour cloth thus, wherein said second kind of water-soluble chemical material is different from first kind of water-soluble chemical material.

20. method as claimed in claim 19, wherein said first kind of water-soluble chemical material and second are designed at least a dyestuff that comprises in the water-soluble chemical material that suppresses wetting.

21. the method for claim 1, wherein said fabric comprises at least two types fiber, and described textile dyeing step comprises being less than the dyeing of whole part at least in described two types of fibers, forms variegated fabric thus.

22. a method of making pattern fabric, this method comprises following step:

Coating is designed for the water-soluble chemical material that suppresses wetting on fabric, thereby determines the processed district of fabric and the district of being untreated; And

Described fabric is exposed to water soluble dyestuffs, make described processed district by the wetting degree of described water soluble dyestuffs less than the described district of being untreated, because the relative difference of water soluble dyestuffs dye uptake has formed the different relatively style of color thus.

23. method as claimed in claim 22, wherein said chemical substance comprise the material that is selected from alginates printing paste, synthetic printing paste, fluoride and their combination.

24. method as claimed in claim 22, the wherein said step that fabric is exposed in the dyestuff comprises by continuous or semi-continuous colouring method to this textile dyeing.

25. method as claimed in claim 22, wherein said water-soluble chemical material comprises dyestuff, catches the color different with water soluble dyestuffs for thus the processed district of fabric.

26. fabric with the described method manufacturing of claim 22.

27. the printing textile of the described method preparation of claim 1, it has predetermined color style, this is by to more and less regional determined of the dye uptake of the same color of same coating, and less its physical strength of zone of wherein said finished product dye for fabrics dye uptake and described dyestuff dye uptake are identical than multizone on basically.

28. fabric as claimed in claim 27, wherein said fabric comprise the fiber that is selected from polyester, cotton, PLA, PTT, nylon, artificial silk and their blending.

29. fabric as claimed in claim 27 is wherein very clearly definite than the transition between multi-region and the less district at described dyestuff dye uptake.

30. fabric as claimed in claim 27, the yarn that wherein forms fabric is dyed by ring.

31. fabric as claimed in claim 27, wherein the color style of being scheduled to imitates the structure of fabric, and the outward appearance of yarn-dyed fabric is provided thus.

32. fabric as claimed in claim 27, wherein said fabric is a woven fabric, and the predetermined color style is included in the striped that extends at least one of the warp thread direction of this braided fabric and weft direction.

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