CN1294205C - Polyurethane rubber roller - Google Patents
Polyurethane rubber roller Download PDFInfo
- Publication number
- CN1294205C CN1294205C CNB2005100106609A CN200510010660A CN1294205C CN 1294205 C CN1294205 C CN 1294205C CN B2005100106609 A CNB2005100106609 A CN B2005100106609A CN 200510010660 A CN200510010660 A CN 200510010660A CN 1294205 C CN1294205 C CN 1294205C
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber roller
- polyurethane rubber
- temperature
- polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920003225 polyurethane elastomer Polymers 0.000 title claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000011187 glycerol Nutrition 0.000 claims abstract description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 polytetramethylene Polymers 0.000 claims abstract description 12
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229920002261 Corn starch Polymers 0.000 claims description 11
- 239000008120 corn starch Substances 0.000 claims description 11
- 229940099112 cornstarch Drugs 0.000 claims description 11
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 9
- 229960004418 trolamine Drugs 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 238000005987 sulfurization reaction Methods 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 abstract description 9
- 230000032683 aging Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 230000008676 import Effects 0.000 abstract description 4
- 229920002635 polyurethane Polymers 0.000 abstract description 4
- 239000004814 polyurethane Substances 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 abstract 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005662 electromechanics Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention provides a polyurethane rubber roller which is characterized by being prepared from the following raw materials in parts by mass: 100 parts of polytetramethylene glycol, 10-30 parts of glycerol, 10-40 parts of toluene diisocyanate, 20-40 parts of triethanolamine, 10-25 parts of ethanol, 5-15 parts of butanediol, 0.5-1 part of taibai powder and 10-30 parts of 3, 3 '-dichloro-4, 4' -diaminodiphenylmethane. The prepared polyurethane product has the performances of super wear resistance, high temperature resistance, corrosion resistance, aging resistance and the like, the price of the prepared polyurethane product is only 1-2 times of that of common rubber, particularly, the polyurethane rubber roller prepared by the formula is not changed in three months when used in a working environment of spraying industrial glycerin at a high rotating speed, the existing common polyurethane rubber roller cannot be used due to foaming or severe wear when used for less than one month, the comprehensive performance of the polyurethane rubber roller is also excellent compared with that of similar products abroad, and the polyurethane rubber roller is an ideal product which can completely replace import products.
Description
Technical field
The present invention relates to a kind of high rigidity and elastomeric rubber roll, especially a kind of polyurethane rubber roller between rubber and plastics.
Background technology
The durometer level broad of urethanes, be low to moderate the following low modulus rubber of Shao Er A10, high high impact-resistant resilient material to Shao Er D85, its Young's modulus can be up to hundreds of MPas, well beyond the Young's modulus scope (about 0.2～10MPa) of other rubber, so the performance range of urethanes is very wide, be between the family macromolecule material from rubber to plastics.Also just because of characteristics such as outstanding wear-resisting, the oil resistant of urethane, ageing-resistant, low temperature resistant, high rigidity, snappiness, the consumption of urethane increases sharply in recent years, range of application constantly enlarges, be widely used in industries such as petrochemical complex, mining machinery, light industry and machinery, hydro project, traffic and shoemaking, papermaking, electromechanics, replace and saved a large amount of timber, steel and various rare metal.But the result of use in some particular surroundings such as existing polyurethane rubber roller is not ideal.When especially using under long-time, high speed conditions, it is high temperature resistant, rub resistance, performance such as corrosion-resistant can obviously descend.The urethane part that uses on the overseas high speed cigarette machine as China's import, because of will be under high speed conditions long-play, the wearing and tearing of component are comparatively serious, only be 20～35 days duration of service, not only influences production efficiency, and this type component is entirely by import, therefore, running cost is higher.Therefore, be necessary prior art is improved.
Summary of the invention
The object of the present invention is to provide a kind of polyurethane rubber roller that has high-performance at aspect such as wear-resisting, corrosion-resistant, high temperature resistant.
The present invention realizes by following technical proposal: a kind of polyurethane rubber roller is characterized in that it makes with the raw material of following mass parts:
100 parts of polytetramethylene glycol
Glycerine 10-30 part
Tolylene diisocyanate 10-40 part
Trolamine 20-40 part
Ethanol 10-25
Butyleneglycol 5-15 part
Cornstarch 0.5-1 part
3,3 '-two chloro-4,4 '-diaminodiphenyl-methane 10-30 part.
Above-mentioned raw materials is the commercially available prod.
Compound method:
At first glycerine is joined in the polytetramethylene glycol, be heated to 150-170 ℃, dehydration is 1-2 hour under the vacuum, and reheat is to 150-170 ℃, dewater under the vacuum, three times so repeatedly, when treating that temperature is reduced to 40-60 ℃, add toluene di-iso-cyanide ester, trolamine, ethanol, butyleneglycol, Cornstarch, stirred 2-3 hour, and maintain the temperature at 80 ℃, and carry out vacuum defoamation, add 3 afterwards, 3 '-two chloro-4,4 '-diaminodiphenyl-methane, be poured into die needed in, under 80-150 ℃ of temperature, dry 30-60 minute, behind the shaping and demoulding, sulfuration is 10-15 hour under 50-70 ℃ of temperature, promptly gets product.
The present invention compared with prior art has following advantage and effect: adopt such scheme, the polyurethane products that preparation is come out have extraordinary wear-resisting, high temperature resistant, corrosion-resistant, performance such as ageing-resistant, its wear resistance is 9 times of natural rubber, the over-all properties of its goods is 10 times of rubber item, and price only is 1-2 times of ordinary rubber, especially use the polyurethane rubber roller of above-mentioned formulated, in the Working environment of high rotating speed and spraying industry glycerol, use three monthly any variation not take place, and existing conventional polyurethanes rubber roll, use less than one month can't use because of foaming or heavy wear, its over-all properties is also than external like product excellence, and cost is low, expense is few, is the ideal product that can substitute import fully.
Provide performance of the present invention below:
Relative density: 1.10～1.25 pull apart unit elongation: 500～1000
Shao Er hardness: 10～100 working temperatures :-20～80 ℃
Tensile strength: 0.6～70mpa thermotolerance: excellent
Winter hardiness: winning time epistasis: can
Tear strength: excellent wear resistance: splendid
Ageing resistance: excellent anti-ozone/corona: splendid
Oil-proofness: excellent water tolerance: in
Embodiment
Below in conjunction with embodiment the present invention is described further.
Embodiment 1
Take off the row marketable material:
Polytetramethylene glycol 100 grams
Glycerine 10 grams
Tolylene diisocyanate 10 grams
Trolamine 20 grams
Ethanol 10 grams
Butyleneglycol 5 grams
Cornstarch 0.5 gram
3,3 '-two chloro-4,4 '-diaminodiphenyl-methane, 10 grams
Through following method: earlier glycerine is joined in the polytetramethylene glycol, be heated to 150 ℃, dehydration is 1 hour under the vacuum, reheat to 150 ℃, dewater under the vacuum, three times so repeatedly, when treating that temperature is reduced to 40 ℃, add toluene di-iso-cyanide ester, triethanolamine, ethanol, butyleneglycol, Cornstarch, stirred 2 hours, and maintaining the temperature at 80 ℃, deaeration is 1 hour under the vacuum, adds 3 afterwards, 3 '-two chloro-4,4 '-diaminodiphenyl-methane, be poured into die needed in, under 80 ℃ of temperature, dry 60 minutes, behind the shaping and demoulding, sulfuration is 10 hours under 50 ℃ of temperature, promptly gets product.
Embodiment 2
Take off the row marketable material:
100 kilograms of polytetramethylene glycol
30 kilograms of glycerine
40 kilograms of toluene di-iso-cyanide esters
40 kilograms of triethanolamines
25 kilograms of ethanol
15 kilograms of butyleneglycols
1 kilogram of Cornstarch
3,3 '-two chloro-4,30 kilograms of 4 '-diaminodiphenyl-methanes
Through following method: earlier glycerine is joined in the polytetramethylene glycol, be heated to 170 ℃, dehydration is 2 hours under the vacuum, reheat to 170 ℃, dewater under the vacuum, three times so repeatedly, when treating that temperature is reduced to 60 ℃, add toluene di-iso-cyanide ester, triethanolamine, ethanol, butyleneglycol, Cornstarch, stirred 3 hours, and maintain the temperature at 80 ℃, and carry out vacuum defoamation, add 3 afterwards, 3 '-two chloro-4,4 '-diaminodiphenyl-methane, be poured into die needed in, under 150 ℃ of temperature, dry 30 minutes, behind the shaping and demoulding, sulfuration is 15 hours under 70 ℃ of temperature, promptly gets product.
Embodiment 3
Take off the row marketable material:
100 kilograms of polytetramethylene glycol
20 kilograms of glycerine
30 kilograms of toluene di-iso-cyanide esters
30 kilograms of triethanolamines
20 kilograms of ethanol
10 kilograms of butyleneglycols
0.8 kilogram of Cornstarch
3,3 '-two chloro-4,20 kilograms of 4 '-diaminodiphenyl-methanes
Through following method: at first glycerine is joined in the polytetramethylene glycol, be heated to 160 ℃, dehydration is 1.5 hours under the vacuum, reheat to 160 ℃, dewater under the vacuum, three times so repeatedly, when treating that temperature is reduced to 50 ℃, add toluene di-iso-cyanide ester, triethanolamine, ethanol, butyleneglycol, Cornstarch, stirred 2 hours, and maintain the temperature at 80 ℃, and carry out vacuum defoamation, add 3 afterwards, 3 '-two chloro-4,4 '-diaminodiphenyl-methane, be poured into die needed in, under 100 ℃ of temperature, dry 45 minutes, behind the shaping and demoulding, sulfuration is 12 hours under 60 ℃ of temperature, promptly gets product.
Embodiment 4
Take off the row marketable material:
Polytetramethylene glycol 100 grams
Glycerine 12.5 grams
Tolylene diisocyanate 12.6 grams
Trolamine 15.8 grams
Ethanol 12.9 grams
Butyleneglycol 13.7 grams
Cornstarch 0.5 gram
3,3 '-two chloro-4,4 '-diaminodiphenyl-methane, 15.6 grams
Method through identical with embodiment 3 can make desired product.
Claims (2)
1, a kind of polyurethane rubber roller is characterized in that it makes with the raw material of following mass parts:
100 parts of polytetramethylene glycol
Glycerine 10-30 part
Tolylene diisocyanate 10-40 part
Trolamine 20-40 part
Ethanol 10-25 part
Butyleneglycol 5-15 part
Cornstarch 0.5-1 part
3,3 '-two chloro-4,4 '-diaminodiphenyl-methane 10-30 part.
2, polyurethane rubber roller according to claim 1 is characterized in that it makes by following method; At first glycerine is joined in the polytetramethylene glycol, be heated to 150-170 ℃, dehydration is 1-2 hour under the vacuum, and reheat is to 150-170 ℃, dewater under the vacuum, three times so repeatedly, when treating that temperature is reduced to 40-60 ℃, add tolylene diisocyanate, trolamine, ethanol, butyleneglycol and Cornstarch, stirred 2-3 hour, and maintain the temperature at 80 ℃, and carry out vacuum defoamation, add 3 afterwards, 3 '-two chloro-4,4 '-diaminodiphenyl-methane, be poured into die needed in, under 80-150 ℃ of temperature, dry 30-60 minute, behind the shaping and demoulding, sulfuration is 10-15 hour under 50-70 ℃ of temperature, promptly gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100106609A CN1294205C (en) | 2005-02-21 | 2005-02-21 | Polyurethane rubber roller |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100106609A CN1294205C (en) | 2005-02-21 | 2005-02-21 | Polyurethane rubber roller |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1667043A CN1667043A (en) | 2005-09-14 |
| CN1294205C true CN1294205C (en) | 2007-01-10 |
Family
ID=35038333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100106609A Expired - Fee Related CN1294205C (en) | 2005-02-21 | 2005-02-21 | Polyurethane rubber roller |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1294205C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102166799B (en) * | 2010-12-21 | 2013-11-20 | 攀枝花钢城集团铁路设备修造有限公司 | Horizontal production process of polyurethane rubber roller |
| CN102807665A (en) * | 2012-08-27 | 2012-12-05 | 马鞍山市天鑫辊业有限责任公司 | Low-hardness pouring polyurethane rubber roller and production method thereof |
| CN103817965A (en) * | 2014-03-03 | 2014-05-28 | 上海汇聚自动化科技有限公司 | Machining method for Mecanum roller |
| CN106750133B (en) * | 2016-12-30 | 2019-08-16 | 山东一诺威聚氨酯股份有限公司 | Low hardness polyurethane rubber roller material and preparation method thereof |
| CN107746567A (en) * | 2017-10-20 | 2018-03-02 | 安徽亚源印染有限公司 | A kind of printer's roll composite material special |
| CN107629442A (en) * | 2017-10-20 | 2018-01-26 | 安徽亚源印染有限公司 | A kind of special heat-resistant antifriction compound polyurethane material of printer's roll |
| CN110591049A (en) * | 2019-09-26 | 2019-12-20 | 昆山博益鑫成高分子材料有限公司 | Permanent antistatic natural color polyurethane rubber roller |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273979A (en) * | 1999-05-17 | 2000-11-22 | 珠海市江奇家具有限公司 | Furniture core material made of polyurethane and its production method |
| CN1100828C (en) * | 1999-04-05 | 2003-02-05 | 长岛县聚氨酯制品厂 | Polyurethane and its use |
-
2005
- 2005-02-21 CN CNB2005100106609A patent/CN1294205C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100828C (en) * | 1999-04-05 | 2003-02-05 | 长岛县聚氨酯制品厂 | Polyurethane and its use |
| CN1273979A (en) * | 1999-05-17 | 2000-11-22 | 珠海市江奇家具有限公司 | Furniture core material made of polyurethane and its production method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1667043A (en) | 2005-09-14 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20070110 Termination date: 20110221 |