CN1293278A - Health-care far infrared and negative oxygen ion fabric and its preparing process - Google Patents
Health-care far infrared and negative oxygen ion fabric and its preparing process Download PDFInfo
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- CN1293278A CN1293278A CN 00132606 CN00132606A CN1293278A CN 1293278 A CN1293278 A CN 1293278A CN 00132606 CN00132606 CN 00132606 CN 00132606 A CN00132606 A CN 00132606A CN 1293278 A CN1293278 A CN 1293278A
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Abstract
A health-care far-infrared and negative oxygen ion fabric features that a composite inorganic particle (30-100 nm) mixture is contained on at least one surface of the fabric or between fibres or yarns of the fabric. The weight ratio of said mixture to fabric is 0.5-5.0%. Said mixture contains calcium carbide powder and far-infrared powder in weight ratio of (1-50):(1-50). Its fabric can generate nagative oxygen ions, and emit for-infrared ray for regulating the surrounding atmosphere and taking care of health.
Description
The present invention relates to a kind of fabric, particularly relate to a kind of health-care far infrared and negative oxygen ion fabric, the invention still further relates to the preparation method of this health care fabric with plurality of health care functions.
Negative oxygen ion extensively is present in the Nature, in the high place of content as forest, seashore, waterfall district etc., it makes the people feel in a good mood, is the various diseases of representative and the people is in the low place of negative oxygen ion content particularly air-conditioned enclosed type office for a long time, dwelling house can bring out with the air conditioner disease.Medically, cytoactive can be strengthened after negative oxygen ion entered blood, the transmission of electrolyte such as Na, K and refuse, the frequency of exchange also can be accelerated, make the ion in the body keep balance, thereby improve the vis medicatrix naturae and the immunity of human body, activate parasympathetic nerve simultaneously, people's mind peacefulness, blood pressure drops, mood are loosened.It is of great advantage to health that suck an amount of negative oxygen ion every day.
Infrared ray is a kind of electromagnetic wave between visible light and microwave, and wavelength is between 0.76～1000 micron.Its medium wavelength is the most useful to human body at the far infrared of 4～15 micron wavebands.Can produce thermogenetic effect in subcutaneous 3～5 centimetres of depths behind the far infrared of this wave band of absorption of human body, hydrone in the cell tissue is activated, be in upper state, help the synthetic of biology enzyme, therefore can strengthen body's immunity and power of regeneration, the expansion capillary, microcirculation improvement enhances metabolism and blood flow.
In the prior art, existing many foreign literatures have carried out deep argumentation and discussion to the negative oxygen ion far IR fibre.The fiber and the fabric that possess this function also come into the market, and wherein " IOLINA " fiber of " HOLIC " fiber of island weaving, big and weaving applies in Japan, " IONAGE " fiber that day is spun clearly is more representative.These fibers all adopt the technology of co-blended spinning, only limit the use of in synthetic fiber such as terylene, polypropylene fibre, then can reduce effect with natural fibre blended, more can not be used for natural fabric, so the serviceability of its product are subjected to certain limitation.
It is base stock that the present invention adopts the natural silicate mineral based on silicon oxide-containing, aluminium oxide, through being ground to the ultrafine dust of average grain diameter between 30～100 nanometers after screening, the purification, is aided with the ordinary far infrared particulate of same particle size again, for example TiO
2, ZnO, Fe
2O
3, ZrO
2, composition such as MnO and composition thereof makes and inspires each other between them, reaches the best effect that multiplies each other.Afterwards; with this inorganic particles mixture; make it securely attached on the fabric or between yarn by pad dyeing, coating process; make fabric have the far health care of negative oxygen ion; and do not lose the original style of fabric; can make people in dressing, sleeping, pass through Transdermal absorption, obtain health-care physical therapy.
One of purpose of the present invention provides the multifunctional far infrared type health care fabric of a kind of negative oxygen ion.
Two of purpose of the present invention provides the preparation method of the multifunctional far infrared type health care fabric of this negative oxygen ion.
These and other objects of the present invention will further be set forth and illustrate by following description.
The said health-care far infrared and negative oxygen ion fabric fabric of the present invention; it is characterized in that comprising the composite inorganic particle mixture that fineness is 30～100 nanometers on the one side at least of fabric or between the fiber of fabric, yarn; than between 0.5～5.0% (o.w.f), the weight ratio of tourmaline and far-infrared powder is 50: 1～1: 50 to the composite inorganic particle mixture in the said composite inorganic particle mixture to fabric weight.
This nano_scale particle used in the present invention is extremely tiny, and specific area is very big, so just can reach good effect as long as add few amount.And because addition is considerably less, to the original feel of fabric, comfortableness all almost without any influence.This particulate even can go deep into fibr tissue inside, thus washability improved.
Include natural silicate mineralogical composition in the composite inorganic particle mixture of Shi Yonging in the present invention, i.e. tourmaline, English name tourmaline.It is the natural minerals that self forever has electromagnetic field, exist extremely faint electric current between its crystal, though electric current is very weak, voltage can reach 1,000,000 electron-volts, thereby make air generation ionization, the electronics of emitting combines with carbon dioxide in air, water and produces negative oxygen ion.Therefore, its generation of negative oxygen ion in fabric is nonvolatil.
In health care fabric of the present invention, cooperate the far-infrared powder of sneaking under the effect of tourmaline, can be encouraged, thereby can launch far infrared efficiently, make the water activityization that accounts for human body body weight 60%, more help the absorption of human body negative oxygen ion.
Negative oxygen ion has very strong redox, can destroy the activity of cell membrane or the cellular plasm organized enzyme of bacterium, thereby reaches the purpose of antibiotic and sterilizing.It can make it to decompose again with foul smell such as ammonia, different lucky oxalic acid reaction, reaches the smelly purpose that disappears.
The preparation method of the said health-care far infrared and negative oxygen ion fabric of the present invention, it comprises the following steps:
(1) preparation dressing liquid, said dressing liquid comprises that based on the weight meter of this dressing liquid (a) 1.0%～5.0% fineness is the composite inorganic particle mixture of 30～100 nanometers, the weight ratio 50: 1～1: 50 of tourmaline particles and far-infrared powder in this composite inorganic particle mixture; (b) 0.5%～5.0% emulsifying agent; (c) 1.0%～15.0% binder;
(2) use this dressing liquid to fabric pad, coating or spray treatment, the one side at least of fabric is gone up or the fiber of fabric, yarn between comprise this composite inorganic particle mixture, its percentage by weight to fabric is 0.5～5.0%.
Preferably, the content of tourmaline particles should be higher in this composite inorganic particle mixture, as be not less than 50% of mixture total weight amount.In dressing liquid, the content of this composite inorganic particle mixture is not less than 1.0%, generally should be between 1.0%～5.0%, and also can be higher.It is undesirable to be lower than 1.0% effect, is higher than 5.0% feel hardening that can make fabric, pliability, comfortableness variation.
In the preparation process of dressing liquid, the effect of emulsifying agent is very important.Being fit to emulsifying agent of the present invention can be nonionic, also can be anionic or cationic, selects any proportioning with the composite inorganic particle mixture relevant, preferably adopts the emulsifying agent of nonionic.Suitable emulsifying agent can be polyol esters of fatty acids, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, fatty acid ethanol amide, polyethers, polyethoxy alkyl ether, alkylsulfonate, fatty alcohol sulfate salt, sulphosuccinates, fatty amine quaternary ammonium salt, also can be cellulose sulfate ester sodium salt, phenolic resins sulfonate etc., perhaps adopt their composition.The addition of emulsifying agent should be decided on emulsifier type, is generally 0.5～5.0% of dressing liquid weight.
More particularly, dressing liquid of the present invention can be prepared as follows:
Add emulsifying agent and water in mixer, low speed is stirred well to uniform solution, adds an amount of above-mentioned composite inorganic particle mixture then, and high-speed stirred is even, and is stand-by.Adding the binder that accounts for dressing liquid weight about 1.0%～15.0% before using, for example can be acrylate polymer self-cross linking type binder, and its exact concentration depends on the needs.
Can also in dressing liquid, add as required as other conventional auxiliary agents such as softener, fire retardant, antistatic additive, bactericide.
More particularly, the present invention can handle fabric with dressing liquid in the following manner:
Use aforesaid dressing liquid, with coating process or pad method or spraying method is handled fabric.Be preferably to adopt and pad method, i.e. fabric padding finishing liquid behind boiling-off, mercerising, bleaching, dyeing or stamp, one soaks one rolls or two soaks two and roll, and pick-up rate is 70%～80%, 100～180 ℃ of following heat treatments 2～3 minutes, makes it bone dry then.Padding finishing liquid can carry out before dyeing or stamp, also can after carry out, perhaps carry out with bathing, fabric can be a natural fabric, the independent or BLENDED FABRIC of synthetic fiber can be woven fabric or knitted fabric or bondedfibre fabric.
Product through the dressing liquid processing, lead wet, the ventilative characteristics such as good, beautiful in colour as soft, absorbing sweat except possessing the original performance of fabric, can also produce negative oxygen ion adjusting surrounding environment is benefited people's body and mind, emitting far-infrared play warming, stimulate circulation and have health cares such as antibacterial and deodorizing, be the material of a kind of desirable underwear, nightwear, shirt, socks, shoe-pad, bedding, curtain, tablecloth, carpet etc.
To specify the present invention by embodiment below, should be understood that the content of this embodiment does not limit the invention.
Embodiment 1
Take by weighing 2 kilograms of fatty glycerides and add in 98 kg of water, stirring at low speed is even.Take by weighing inorganic far-infrared powder (the principal component TiO of CBD400 of 2.4 kilograms of average grain diameters Haikang Bi Da Scientific and Technical Industry Co., Ltd on the tourmaline particles between 30～100 nanometers and 0.6 kilogram of same particle size
2) add wherein, with 3500 rev/mins rotating speed high-speed stirred extremely evenly.Adding 3 kilograms of acrylic resin binders then stirs.The dressing liquid that obtains to feed chute, is padded the all-cotton knitting lining with 80% pick-up rate, under 150 ℃, baked 3 minutes then.Its composite inorganic fraction of particle of the lining that obtains like this is about 2.0% weight.
The lining that obtains is through the test of fiber product inspection center of Chinese chemical fibre industry association, and the average content of negative oxygen ion is 280 in the every cc of air of fabric face, and peak value can reach 4000.Adopting IRE-1 type infrared radiometer test far infrared transmissivity through Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 85%.The test bacteriostasis rate is between the 85-99.9% through Shanghai City health and epidemic prevention station.
Embodiment 2
Take by weighing 1 kilogram of phenolic resins sulfonate AT-H841 and add in 99 kg of water, stirring at low speed is even.The inorganic far-infrared powder of CBD400 (principal component ZnO) that takes by weighing 4.9 kilograms of average grain diameters Haikang Bi Da Scientific and Technical Industry Co., Ltd on the tourmaline particles between 30～100 nanometers and 0.1 kilogram of same particle size adds wherein, with 3500 rev/mins rotating speed high-speed stirred extremely evenly.Adding 4 kilograms of acrylic resin binders then stirs.The dressing liquid that obtains to feed chute, is padded polyester fabric with 80% pick-up rate, under 150 ℃, baked 3 minutes then.Its composite inorganic fraction of particle of the lining that obtains like this is about 4.0% weight.
The lining that obtains is through the test of fiber product inspection center of Chinese chemical fibre industry association, and the average content of negative oxygen ion is 350 in the every cc of air of fabric face, and peak value can reach 5000.Adopting IRE-1 type infrared radiometer test far infrared transmissivity through Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 89%.The test bacteriostasis rate is between the 85-99.9% through Shanghai City health and epidemic prevention station.Embodiment 3
Take by weighing 3 kilograms of dioctyl sodium sulfosuccinates and add in 97 kg of water, stirring at low speed is even.Take by weighing inorganic far-infrared powder (the principal component TiO of CBD400 of 0.1 kilogram of average grain diameter Haikang Bi Da Scientific and Technical Industry Co., Ltd on the tourmaline particles between 30～100 nanometers and 3.9 kilograms of same particle size
2, ZnO) add wherein, with 3500 rev/mins rotating speed high-speed stirred to even.Adding 2 kilograms of acrylic resin binders then stirs.The dressing liquid that obtains to feed chute, is padded the polypropylene fibre lining with 70% pick-up rate, under 150 ℃, baked 3 minutes then.Composite inorganic fraction of particle between its surface of the lining that obtains like this or yarn is about 2.0%.
The lining that obtains is through the test of fiber product inspection center of Chinese chemical fibre industry association, and the average content of negative oxygen ion is 90 in the every cc of air of fabric face, and peak value is 350.Adopting IRE-1 type infrared radiometer test far infrared transmissivity through Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 81%.The test bacteriostasis rate is between the 70-80% through Shanghai City health and epidemic prevention station.
Embodiment 4
Take by weighing 0.8 kilogram of 16 carbocyclic aliphatic amine quaternary ammonium salt 1631 surfactant and add in 99.5 kg of water, stirring at low speed is even.Take by weighing inorganic far-infrared powder (the principal component TiO of CBD400 of 1.9 kilograms of average grain diameters Haikang Bi Da Scientific and Technical Industry Co., Ltd on the tourmaline particles between 30～100 nanometers and 0.1 kilogram of same particle size
2, ZnO) add wherein, with 3500 rev/mins rotating speed high-speed stirred to even.Adding 3 kilograms of acrylic resin binders then stirs.The dressing liquid that obtains to feed chute, is padded the all-cotton knitting lining with 80% pick-up rate, under 150 ℃, baked 3 minutes then.Composite inorganic fraction of particle between its surface of the lining that obtains like this or yarn is about 0.8%.
The lining that obtains is through the test of fiber product inspection center of Chinese chemical fibre industry association, and the average content of negative oxygen ion is 150 in the every cc of air of fabric face, and peak value can reach 800.Adopting IRE-1 type infrared radiometer test far infrared transmissivity through Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 87%.The test bacteriostasis rate is between the 80-90% through Shanghai City health and epidemic prevention station.
Embodiment 5
Take by weighing 1.5 kilograms of naphthenic acids glycollic amides and add in 98.5 kg of water, stirring at low speed is even.Take by weighing 1.0 kilograms between average grain diameter 30～100 nanometers tourmaline particles and inorganic far-infrared powder (the principal component TiO of CBD400 of the last Haikang Bi Da Scientific and Technical Industry Co., Ltd of 1.0 kilograms of same particle size
2, ZnO) add wherein, with 3500 rev/mins rotating speed high-speed stirred to even.Adding 3 kilograms of acrylic resin binders then stirs.The dressing liquid that obtains to feed chute, is padded 50:50 terylen cotton knitting lining with 75% pick-up rate, under 150 ℃, baked 2 minutes then.Its composite inorganic fraction of particle of the lining that obtains like this is about 1.5% weight.
The lining that obtains is through the test of fiber product inspection center of Chinese chemical fibre industry association, and the average content of negative oxygen ion is 180 in the every cc of air of fabric face, and peak value can reach 2000.Adopting IRE-1 type infrared radiometer test far infrared transmissivity through Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 88%.The test bacteriostasis rate is between the 85-95% through Shanghai City health and epidemic prevention station.
Claims (10)
1. health-care far infrared and negative oxygen ion fabric; it is characterized in that comprising the composite inorganic particle mixture that fineness is 30～100 nanometers on the one side at least of fabric or between the fiber of fabric, yarn; than between 0.5～5.0%, the weight ratio of tourmaline and far-infrared powder is 50: 1～1: 50 to the composite inorganic particle mixture in the said composite inorganic particle mixture to fabric weight.
2. the said fabric of claim 1, wherein said fabric be natural fabric or synthetic fiber separately or BLENDED FABRIC, woven fabric, knitted fabric or bondedfibre fabric.
3. the preparation method of any one said health-care far infrared and negative oxygen ion fabric among the claim 1-2, it comprises the following steps:
(1) preparation dressing liquid, said dressing liquid comprises that based on the weight meter of this dressing liquid (a) 1.0%～5.0% fineness is the composite inorganic particle mixture of 30～100 nanometers, the weight ratio 50: 1～1: 50 of tourmaline particles and far-infrared powder in this composite inorganic particle mixture; (b) 0.5%～5.0% emulsifying agent; (c) 1.0%～15.0% binder;
(2) use this dressing liquid to fabric pad, coating or spray treatment, the one side at least of fabric is gone up or the fiber of fabric, yarn between comprise this composite inorganic particle mixture, it is 0.5～5.0% to the fabric weight ratio.
4. the said preparation method of claim 3, wherein the content of tourmaline particles is not less than 50% of this mixture total weight amount in this composite inorganic particle mixture.
5. the said preparation method of claim 3, wherein said emulsifying agent is polyol esters of fatty acids, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, fatty acid ethanol amide, polyethers, polyethoxy alkyl ether, alkylsulfonate, fatty alcohol sulfate salt, sulphosuccinates, fatty amine quaternary ammonium salt, cellulose sulfate ester sodium salt or phenolic resins sulfonate and their composition.
6. the said preparation method of claim 3, wherein said binder is an acrylate polymer self-cross linking type binder.
7. the said preparation method of claim 3 wherein adds softener, fire retardant, antistatic additive or bactericide in said dressing liquid.
8. the said preparation method of claim 3, wherein step (2) adopts and pads method, fabric is padding finishing liquid behind boiling-off, mercerising, bleaching, dyeing or stamp, one soaks one rolls or two soaks two and roll, pick-up rate is 70%～80%, 100～180 ℃ of following heat treatments 2～3 minutes, make it bone dry then.
9. the said preparation method of claim 8, wherein said padding can be carried out before dyeing or stamp, also can after carry out, perhaps carry out with bath.
10. any one said preparation method among the claim 3-9, wherein said fabric be natural fabric or synthetic fiber separately or BLENDED FABRIC, woven fabric or knitted fabric or bondedfibre fabric.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001326066A CN1141438C (en) | 2000-11-16 | 2000-11-16 | Health-care far infrared and negative oxygen ion fabric and its preparing process |
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|---|---|---|---|
| CNB001326066A CN1141438C (en) | 2000-11-16 | 2000-11-16 | Health-care far infrared and negative oxygen ion fabric and its preparing process |
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| CN1293278A true CN1293278A (en) | 2001-05-02 |
| CN1141438C CN1141438C (en) | 2004-03-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB001326066A Expired - Fee Related CN1141438C (en) | 2000-11-16 | 2000-11-16 | Health-care far infrared and negative oxygen ion fabric and its preparing process |
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| WO2005118010A1 (en) * | 2004-06-03 | 2005-12-15 | Poon, Saukuen | A sanitary napkin or pad including an anion blue core layer |
| US7048771B2 (en) * | 2001-10-22 | 2006-05-23 | University Of California | Dyeing textiles using nanoparticles |
| WO2007118430A1 (en) * | 2006-04-17 | 2007-10-25 | Mengjun Yang | A functional composite material with good curative effect and preparation, uses thereof |
| CN101954112A (en) * | 2010-09-13 | 2011-01-26 | 彭蕾 | Raw material of anion far-infrared nutrient sanitary towel functional body chip and preparation method thereof |
| CN101387077B (en) | 2008-09-25 | 2011-06-01 | 吴张江 | Fabric antipruritic treatment method and treatment liquid |
| CN101509188B (en) * | 2009-03-06 | 2012-08-08 | 东华大学 | Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof |
| CN102691206A (en) * | 2012-06-18 | 2012-09-26 | 曾技 | Tourmaline-containing cloth and production process thereof |
| CN102772089A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile nutrient added tablecloth |
| CN103147274A (en) * | 2013-03-27 | 2013-06-12 | 海安县联强纺织有限公司 | Method for processing underwear fabric with anion additive |
| CN103405099A (en) * | 2013-08-20 | 2013-11-27 | 吴江市帛乔纺织有限公司 | Multifunctional tablecloth |
| CN103696079A (en) * | 2013-11-27 | 2014-04-02 | 湖州织里童装发展有限公司 | Manufacturing method of antibacterial warm-keeping plus material |
| CN103966852A (en) * | 2014-05-15 | 2014-08-06 | 蒋国琴 | Cloth capable of releasing active negative oxygen ion |
| CN104489947A (en) * | 2014-12-23 | 2015-04-08 | 东莞市诺之漫服饰有限公司 | Production method of tourmaline far red health care closing and health care closing with red far health care function |
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| CN105316931A (en) * | 2015-10-21 | 2016-02-10 | 吴江耀迪纺织品有限公司 | Antibacterial and flame-retardant cloth capable of releasing negative oxygen ions |
| CN106049070A (en) * | 2016-07-15 | 2016-10-26 | 义乌市麻尚生针织品有限公司 | Yarn made by blending fiber having anions and far-infrared function and hemp-cotton fiber |
| CN106917262A (en) * | 2017-03-21 | 2017-07-04 | 无锡贝旭环球电子商务有限公司 | A kind of far infrared Rachael blanket and preparation method thereof |
| CN108265519A (en) * | 2018-04-17 | 2018-07-10 | 海宁市依丽袜业有限公司 | A kind of anti-hook silk stocking |
| CN109371707A (en) * | 2018-09-29 | 2019-02-22 | 中国第汽车股份有限公司 | A kind of preparation method of antifouling negative ion fabric mask |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7048771B2 (en) * | 2001-10-22 | 2006-05-23 | University Of California | Dyeing textiles using nanoparticles |
| WO2005118010A1 (en) * | 2004-06-03 | 2005-12-15 | Poon, Saukuen | A sanitary napkin or pad including an anion blue core layer |
| WO2007118430A1 (en) * | 2006-04-17 | 2007-10-25 | Mengjun Yang | A functional composite material with good curative effect and preparation, uses thereof |
| CN101387077B (en) | 2008-09-25 | 2011-06-01 | 吴张江 | Fabric antipruritic treatment method and treatment liquid |
| CN101509188B (en) * | 2009-03-06 | 2012-08-08 | 东华大学 | Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof |
| CN101954112A (en) * | 2010-09-13 | 2011-01-26 | 彭蕾 | Raw material of anion far-infrared nutrient sanitary towel functional body chip and preparation method thereof |
| CN101954112B (en) * | 2010-09-13 | 2014-01-29 | 彭蕾 | Raw material of anion far-infrared nutrient sanitary towel functional body chip and preparation method thereof |
| CN102772089A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile nutrient added tablecloth |
| CN102691206A (en) * | 2012-06-18 | 2012-09-26 | 曾技 | Tourmaline-containing cloth and production process thereof |
| CN102691206B (en) * | 2012-06-18 | 2013-12-25 | 曾技 | Tourmaline-containing cloth and production process thereof |
| CN103147274A (en) * | 2013-03-27 | 2013-06-12 | 海安县联强纺织有限公司 | Method for processing underwear fabric with anion additive |
| CN103405099A (en) * | 2013-08-20 | 2013-11-27 | 吴江市帛乔纺织有限公司 | Multifunctional tablecloth |
| CN103696079A (en) * | 2013-11-27 | 2014-04-02 | 湖州织里童装发展有限公司 | Manufacturing method of antibacterial warm-keeping plus material |
| CN103966852A (en) * | 2014-05-15 | 2014-08-06 | 蒋国琴 | Cloth capable of releasing active negative oxygen ion |
| CN104489947A (en) * | 2014-12-23 | 2015-04-08 | 东莞市诺之漫服饰有限公司 | Production method of tourmaline far red health care closing and health care closing with red far health care function |
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| CN105316931A (en) * | 2015-10-21 | 2016-02-10 | 吴江耀迪纺织品有限公司 | Antibacterial and flame-retardant cloth capable of releasing negative oxygen ions |
| CN106049070A (en) * | 2016-07-15 | 2016-10-26 | 义乌市麻尚生针织品有限公司 | Yarn made by blending fiber having anions and far-infrared function and hemp-cotton fiber |
| CN106917262A (en) * | 2017-03-21 | 2017-07-04 | 无锡贝旭环球电子商务有限公司 | A kind of far infrared Rachael blanket and preparation method thereof |
| CN108265519A (en) * | 2018-04-17 | 2018-07-10 | 海宁市依丽袜业有限公司 | A kind of anti-hook silk stocking |
| CN109371707A (en) * | 2018-09-29 | 2019-02-22 | 中国第汽车股份有限公司 | A kind of preparation method of antifouling negative ion fabric mask |
| CN110306337A (en) * | 2019-07-04 | 2019-10-08 | 东莞市庆鑫实业有限公司 | A kind of purification air fabric and its application |
| CN112535811A (en) * | 2020-12-11 | 2021-03-23 | 嘉兴市科富喷绘材料有限公司 | Diabetes therapeutic instrument |
| CN113818263A (en) * | 2021-11-03 | 2021-12-21 | 愉悦家纺有限公司 | White tourmaline mineral composite quick-heating warm-feeling textile and preparation method thereof |
| CN113818263B (en) * | 2021-11-03 | 2023-09-08 | 愉悦家纺有限公司 | Fast-heating warm-feeling textile compounded by tourmaline mineral and preparation method thereof |
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