CN1288979C - Chlorfluazuron mixed pesticide - Google Patents
Chlorfluazuron mixed pesticide Download PDFInfo
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- CN1288979C CN1288979C CN 200410016948 CN200410016948A CN1288979C CN 1288979 C CN1288979 C CN 1288979C CN 200410016948 CN200410016948 CN 200410016948 CN 200410016948 A CN200410016948 A CN 200410016948A CN 1288979 C CN1288979 C CN 1288979C
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Abstract
The present invention belongs to the technical field of compounding pesticide, more specifically to chlorfluazuron compounding pesticide. The chlorfluazuron compounding pesticide is characterized in that the chlorfluazuron compounding pesticide comprises 0.5 to 10% of chlorfluazuron, 10 to 60% of chlorpyrifos and 5 to 30% of quinalphos; the chlorfluazuron compounding pesticide has cotoxicity coefficient of 134.6 to 880.6, has the advantages of high speed, good durability, wide disinsection spectrum and low cost, has cost reduced by 39% to 70% than that of chlorfluazuron single preparations and is good pesticide for preventing and treating lepidoptera pests, coleoptera pests, hymenoptera pests, diptera pests, thysanoptera pests, etc.
Description
Technical field
The invention belongs to technical field of compounded pesticide.
Background technology
The pyridine worm is grand to be a kind of phenyl formoxyl urea insecticide, insect based on stomach poison function, is had concurrently stronger action of contace poison, poor permeability, no systemic action.It is a little matter enzyme inhibitors of insect, suppresses chitinous formation, hinders insect and normally casts off a skin, and makes ovum hatching, larval molting, pupa development deformity, and the emergence of adult, lays eggs etc. to be obstructed and to bring into play insecticidal action.Very high to the insect activity, but speed of action is slower, can very fast death behind the larva contact medicine, but food ingestion obviously weakens.
This medicine has very high activity to some insects such as multiple lepidoptera pest and orthoptera, coleoptera, Hymenoptera, dipteras, is the insecticide of comparison wide spectrum.The insect that insecticides such as organic phosphor, carbamate, pyrethroid are developed immunity to drugs has good control efficiency.Safer to natural enemy, honeybee, fish, but silkworm is had certain toxicity, be to be more satisfactory insecticide in the current integrated pest control.Control to beet armyworm, cotton bollworm, prodenia litura insect is imitated, the lasting period is long, toxicity is low, but quick-acting is poor, medicine valency cost is higher.
Therefore, if adopt the present production scale of China big, quick-acting good in, the hypotoxicity agricultural chemicals carry out with it reasonably composite, reach increase quick-acting, the reduction pesticide cost is the key point of chlorfluazuron mixed pesticides.
Summary of the invention
In view of the above problems, the object of the invention is to provide a kind of quick-acting and lasting effect good, insecticidal spectrum broad, the technical scheme of the chlorfluazuron mixed pesticides that cost is low.
Described a kind of chlorfluazuron mixed pesticides is characterized in that: contain the pyridine worm and swell 1～3%, chlopyrifos 20～30%.
Described a kind of chlorfluazuron mixed pesticides is characterized in that: the grand content of pyridine worm is 1～2%, and chlopyrifos content is 20～30%.
Described a kind of chlorfluazuron mixed pesticides is characterized in that: contain the pyridine worm and swell 1～3%, quinalphos 10～15%.
Described a kind of chlorfluazuron mixed pesticides is characterized in that: the grand content of pyridine worm is 1～2%, and quinalphos content is 10～15%.
The grand chemical name of pyridine worm is: 1-[3,5-chloro-4-(3-chloro-5-trifluoromethyl-2-pyridine oxygen base) phenyl]-3-(2, the 6-difluoro benzoyl) urea, be known substance, can buy by Japanese Ishihara Sangyo Kaisha, Ltd. or China Yangzhou insecticide factory.
The chemical name of chlopyrifos is: O, and O ,-diethyl-O-(3,5, the 6-trichloro-2-pyridyl) thiophosphate is known substance, can be buied by Xinanjiang River chemical industry joint-stock company or Zhejiang Xinnong Chemical Co., Ltd.
The chemical name of quinalphos is: O, O ,-diethyl-O-(quinoxaline-2-yl) thiophosphate, be known substance, can buy by Wuxian, Jiangsu insecticide factory.
Described a kind of chlorfluazuron mixed pesticides can be made into missible oil, and promptly former medicine adds organic solvent and emulsifier.
Described a kind of chlorfluazuron mixed pesticides, co-toxicity coefficient reaches 134.6-880.6, quick-acting and lasting effect are good, the insecticidal spectrum broad, cost is low, than having reduced by 39%～70%, be insects such as control Lepidoptera, coleoptera, Hymenoptera, diptera, thrips insecticides preferably with the grand single agent cost of pyridine worm.Proportioning in patent application of the present invention is weight content.
Embodiment
The following stated embodiment describes the present invention in detail.In an embodiment, unless otherwise indicated, all percentages all are weight percentage.
Prescription one: the pyridine worm is grand: 1.0%, and chlopyrifos 24%.
Prescription two: the pyridine worm is grand: 1.5%, and chlopyrifos 23.5%.
Prescription three: the pyridine worm is grand: 2.0%, and chlopyrifos 23%.
Prescription four: the pyridine worm is grand: 2.5%, and chlopyrifos 22.5%.
Prescription five: the pyridine worm is grand: 3.0%, and chlopyrifos 22%.
Prescription six: the pyridine worm is grand: 1.0%, and quinalphos: 14%.
Prescription seven: the pyridine worm is grand: 1.5%, and quinalphos: 13.5%.
Prescription eight: the pyridine worm is grand: 2.0%, and quinalphos: 13%.
Prescription nine: the pyridine worm is grand: 2.5%, and quinalphos: 12.5%.
Prescription ten: the pyridine worm is grand: 3.0%, and quinalphos: 12%.
The Recompounded pesticide of above-mentioned prescription and 5% pyridine worm mamaplasty oil, 40% chlorpyrifos ec, 25% quintiofos cream compare test to prodenia litura, and its co-toxicity coefficient and test of pesticide effectiveness data are as follows:
25% pyridine worm is grand measures the statistics table with chlopyrifos to the co-toxicity coefficient of prodenia litura
| Medicament | LC50 mg/ml | The toxicity regression line | 95% confidence interval | Co-toxicity coefficient |
| 5% pyridine worm mamaplasty oil | 0.0430 | Y＝3.203X+20.085 | [0.000025～0.016763] | |
| 40% chlorpyrifos ec | 0.1716 | Y＝7.991X+3.906 | [0.1291～0.2016] | |
| 25% pyridine worm is swelled chlopyrifos (prescription one) missible oil | 0.0290 | Y＝1.489X+11.748 | [0.000018～0.00008] | 528.5 |
| 25% pyridine worm is swelled chlopyrifos (prescription two) missible oil | 0.0250 | Y＝1.881X+13.649 | [0.000017～0.00004] | 582.0 |
| 25% pyridine worm is swelled chlopyrifos (prescription three) missible oil | 0.0170 | Y＝2.648X+17.640 | [0.00001～0.000022] | 814.5 |
| 25% pyridine worm is swelled chlopyrifos (prescription four) missible oil | 0.0150 | Y＝1.794X+13.645 | [0.000005～0.000022] | 880.6 |
| 25% pyridine worm is swelled chlopyrifos (prescription five) missible oil | 0.0200 | Y＝3.203X+20.085 | [0.000014～0.000024] | 631.4 |
15% pyridine worm is grand measures the statistics table with quinalphos to the co-toxicity coefficient of prodenia litura
| Medicament | LC50 mg/ml | The toxicity regression line | 95% confidence interval | Co-toxicity coefficient |
| 5% pyridine worm grand (pressing down hooligan) missible oil | 0.043 | Y＝1.384X+11.041 | [0.00003～0.01676] | |
| 25% quintiofos cream | 0.035 | Y＝2.281X+15.174 | [0.00002～0.00005] | |
| 15% pyridine worm is swelled quinalphos (prescription six) missible oil | 0.018 | Y＝2.085X+14.900 | [0.00001～0.00003] | 196.9 |
| 15% pyridine worm is swelled quinalphos (prescription seven) missible oil | 0.021 | Y＝3.079X+19.389 | [0.00001～0.00003] | 169.8 |
| 15% pyridine worm is swelled quinalphos (prescription eight) missible oil | 0.021 | Y＝1.921X+13.972 | [0.00001～0.00003] | 170.9 |
| 15% pyridine worm is swelled quinalphos (prescription nine) missible oil | 0.018 | Y＝1.926X+14.119 | [0.00001～0.00002] | 200.7 |
| 15% pyridine worm is swelled quinalphos (prescription ten) missible oil | 0.027 | Y＝1.960X+13.942 | [0.00002～0.00004] | 134.6 |
40% chlorpyrifos ec is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.4 | 20 | 18 | 90 | 90 |
| 0.27 | 20 | 16 | 80 | 80 |
| 0.2 | 20 | 13 | 65 | 65 |
| 0.16 | 20 | 9 | 45 | 45 |
| 0.133 | 20 | 6 | 30 | 30 |
5% pyridine worm mamaplasty oil is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00001 | 20 | 5 | 25.0 | 13.9 |
| 0.0000125 | 20 | 6 | 30.0 | 18.9 |
| 0.0000167 | 20 | 7 | 35.0 | 23.9 |
| 0.000025 | 20 | 10 | 50.0 | 38.9 |
| 0.00005 | 20 | 11 | 55.0 | 43.9 |
25% pyridine worm is swelled the test of pesticide effectiveness of chlorpyrifos ec (prescription one) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.0000125 | 22 | 8 | 36.4 | 25.3 |
| 0.0000156 | 18 | 7 | 38.9 | 27.8 |
| 0.0000208 | 16 | 7 | 43.9 | 32.6 |
| 0.0000313 | 17 | 11 | 64.7 | 53.6 |
| 0.0000625 | 23 | 16 | 69.6 | 58.5 |
25% pyridine worm is swelled the test of pesticide effectiveness of chlorpyrifos ec (prescription two) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.0000125 | 26 | 8 | 30.8 | 19.7 |
| 0.0000156 | 20 | 9 | 45.0 | 33.9 |
| 0.0000208 | 19 | 9 | 47.4 | 36.3 |
| 0.0000313 | 20 | 14 | 70.0 | 58.9 |
| 0.0000625 | 20 | 15 | 75.0 | 63.9 |
25% pyridine worm is swelled the test of pesticide effectiveness of chlorpyrifos ec (prescription three) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.0000125 | 23 | 9 | 39.1 | 28.0 |
| 0.0000156 | 21 | 10 | 47.6 | 36.5 |
| 0.0000208 | 23 | 16 | 69.6 | 58.5 |
| 0.0000313 | 20 | 17 | 85.0 | 73.9 |
| 0.0000625 | 20 | 18 | 90.0 | 78.9 |
25% pyridine worm is swelled the test of pesticide effectiveness of chlorpyrifos ec (prescription four) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.0000125 | 19 | 9 | 47.4 | 36.3 |
| 0.0000156 | 20 | 11 | 55.0 | 43.9 |
| 0.0000208 | 22 | 15 | 68.2 | 57.1 |
| 0.0000313 | 22 | 16 | 72.7 | 61.6 |
| 0.0000625 | 24 | 21 | 87.5 | 76.4 |
25% pyridine worm is swelled the test of pesticide effectiveness of chlorpyrifos ec (prescription five) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.0000125 | 23 | 7 | 30.4 | 19.3 |
| 0.0000156 | 21 | 9 | 42.9 | 31.7 |
| 0.0000208 | 22 | 15 | 68.2 | 57.1 |
| 0.0000313 | 21 | 15 | 71.4 | 60.3 |
| 0.0000625 | 22 | 21 | 95.5 | 84.3 |
25% quintiofos cream is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00025 | 27 | 26 | 96.3 | 85.2 |
| 0.000083 | 21 | 18 | 85.7 | 74.6 |
| 0.00005 | 22 | 16 | 72.7 | 61.6 |
| 0.0000375 | 20 | 11 | 55.0 | 43.9 |
| 0.0000278 | 21 | 9 | 42.9 | 31.7 |
5% pyridine worm mamaplasty oil is to the test of pesticide effectiveness of prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00005 | 20 | 11 | 55.0 | 43.9 |
| 0.000025 | 20 | 10 | 50.0 | 38.9 |
| 0.0000167 | 20 | 7 | 35.0 | 23.9 |
| 0.0000125 | 20 | 6 | 30.0 | 18.9 |
| 0.00001 | 20 | 5 | 25.0 | 13.9 |
15% pyridine worm is swelled the test of pesticide effectiveness of quintiofos cream (prescription six) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00015 | 27 | 26 | 96.3 | 85.2 |
| 0.00005 | 21 | 18 | 85.7 | 74.6 |
| 0.00003 | 22 | 17 | 77.3 | 66.2 |
| 0.0000214 | 20 | 12 | 60.0 | 48.9 |
| 0.0000167 | 21 | 10 | 47.6 | 36.5 |
15% pyridine worm is swelled the test of pesticide effectiveness of quintiofos cream (prescription seven) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00015 | 26 | 26 | 100 | 88.9 |
| 0.00005 | 20 | 17 | 85.0 | 73.9 |
| 0.00003 | 23 | 17 | 73.9 | 62.8 |
| 0.0000214 | 19 | 11 | 57.9 | 46.8 |
| 0.0000167 | 15 | 6 | 40.0 | 28.9 |
15% pyridine worm is swelled the test of pesticide effectiveness of quintiofos cream (prescription eight) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00015 | 22 | 21 | 95.5 | 84.3 |
| 0.00005 | 23 | 18 | 78.3 | 67.1 |
| 0.00003 | 17 | 11 | 64.7 | 53.6 |
| 0.0000214 | 18 | 10 | 55.6 | 44.4 |
| 0.0000167 | 25 | 12 | 48.0 | 36.9 |
15% pyridine worm is swelled the test of pesticide effectiveness of quintiofos cream (prescription nine) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00015 | 26 | 24 | 92.3 | 81.2 |
| 0.00005 | 26 | 23 | 88.5 | 77.4 |
| 0.00003 | 23 | 19 | 82.6 | 71.5 |
| 0.0000214 | 19 | 9 | 47.4 | 36.3 |
| 0.0000167 | 18 | 8 | 44.4 | 33.3 |
15% pyridine worm is swelled the test of pesticide effectiveness of quintiofos cream (prescription ten) to prodenia litura
| Dosage (mg/ml) | The examination borer population | Dead borer population | Lethality (%) | Corrected mortality (%) |
| 0.00015 | 26 | 24 | 92.3 | 81.2 |
| 0.00005 | 20 | 15 | 75.0 | 63.9 |
| 0.00003 | 24 | 14 | 58.3 | 47.2 |
| 0.0000214 | 19 | 10 | 52.6 | 41.5 |
| 0.0000167 | 18 | 6 | 33.3 | 22.2 |
It is as follows that 25% pyridine worm is swelled the field control prodenia litura test of pesticide effectiveness correction data of the grand phoxim emulsifiable concentrate (autogamy) of chlorpyrifos ec (autogamy), 26% pyridine worm, the grand DDVT missible oil (autogamy) of 40% pyridine worm, 5% pyridine worm mamaplasty oil, 40% chlorpyrifos ec, 40% phoxim emulsifiable concentrate, 80%DDVT missible oil, the grand quintiofos cream (autogamy) of 15% pyridine worm, 20% quintiofos cream, blank group:
Grand and composite dose of the control efficiency test of pyridine worm to prodenia litura
| Medicament | Working concentration (doubly) | Borer population (head) before the medicine | Behind the medicine 3 days | Behind the medicine 7 days | ||||
| Borer population (head) | Insect population slip (%) | Proofread and correct preventive effect (%) | Borer population (head) | Insect population slip (%) | Proofread and correct preventive effect (%) | |||
| 25% pyridine worm is swelled chlorpyrifos ec | 1000 | 44 35 subtotals 79 | 1 1 2 | 97.5 | 96.6 | 0 0 0 | 100 | 100 |
| 2000 | 23 18 subtotals 41 | 2 2 4 | 90.2 | 86.5 | 0 0 0 | 100 | 100 | |
| 26% pyridine worm is swelled phoxim emulsifiable concentrate | 1000 | 40 40 subtotals 80 | 1 1 2 | 97.5 | 96.6 | 0 0 0 | 100 | 100 |
| 2000 | 15 27 subtotals 42 | 2 2 4 | 90.5 | 86.9 | 1 0 1 | 97.7 | 92.2 | |
| 40% pyridine worm is swelled DDVT missible oil | 1000 | 13 15 subtotals 28 | 1 1 2 | 92.8 | 90.1 | 1 0 1 | 96.4 | 87.7 |
| 2000 | 25 18 subtotals 43 | 2 2 4 | 90.7 | 87.1 | 1 0 1 | 97.7 | 92.2 | |
| 5% pyridine worm mamaplasty oil | 1000 | 36 33 subtotals 69 | 4 6 10 | 85.5 | 80.0 | 0 0 0 | 100 | 100 |
| 40% chlorpyrifos ec | 500 | 26 24 subtotals 50 | 2 2 4 | 92.0 | 89.0 | 0 1 1 | 98.0 | 93.2 |
| 40% phoxim emulsifiable concentrate | 500 | 14 24 subtotals 38 | 2 3 5 | 86.8 | 81.8 | 1 1 2 | 94.7 | 81.9 |
| 80%DDVT missible oil | 500 | 32 21 subtotals 53 | 4 5 9 | 83.0 | 76.5 | 4 4 8 | 84.9 | 48.6 |
| Blank | 27 24 subtotals 51 | 21 19 40 | 27.5 | 9 6 15 | 70.6 |
15% pyridine worm is grand to be tested with composite dose of control efficiency to prodenia litura of quinalphos
| Medicament | Working concentration (doubly) | Borer population (head) before the medicine | Behind the medicine 3 days | Behind the medicine 7 days | ||||
| Borer population (head) | Insect population slip (%) | Proofread and correct preventive effect (%) | Borer population (head) | Insect population slip (%) | Proofread and correct preventive effect (%) | |||
| 15% pyridine worm is swelled quintiofos cream | 1000 | 38 42 subtotals 80 | 1 1 2 | 97.5 | 96.6 | 0 0 0 | 100 | 100 |
| 2000 | 29 35 subtotals 64 | 1 2 3 | 95.3 | 94.9 | 0 1 1 | 98.4 | 94.5 | |
| 5% pyridine worm mamaplasty oil | 1000 | 36 33 subtotals 69 | 4 6 10 | 85.5 | 80.0 | 0 0 0 | 100 | 100 |
| 20% quintiofos cream | 1000 | 28 32 subtotals 60 | 4 5 9 | 85.0 | 76.5 | 3 4 7 | 88.3 | 81.3 |
| The clear water contrast | 27 24 subtotals 51 | 21 19 40 | 27.5 | 9 6 15 | 70.6 | |||
Analyze above-mentioned data, measurement result shows: the co-toxicity coefficient of pyridine worm mamaplasty oil, chlorpyrifos ec different proportion prescription all has the notable synergistic effect greater than 100, but, can be used as optimization of C and select with the grand chlopyrifos of 25% pyridine worm (prescription three) missible oil from land for growing field crops result of use and cost consideration;
The co-toxicity coefficient of pyridine worm mamaplasty oil, quintiofos cream different proportion prescription all has the notable synergistic effect greater than 100, but considers from reagent cost and insecticide effect, and 15% pyridine worm swell quinalphos (prescription six) missible oil and can be used as the optimization of C selection.
Imitating test through the field control prodenia litura shows: prodenia litura 3～4 instar larvaes that take place with the taro field are object, 1000 times of 25% UC 62644 chlorpyrifos ecs (autogamy) (mu medication 50ml), behind the medicine 3 days, control efficiency was 96.6%, behind the medicine 7 days, control efficiency reached 100%; With behind 2000 times of (mu medication 25ml) medicines 3 days and 7 days, control efficiency was respectively 86.5% and 100%.Single with 5% UC 62644 missible oil 1000 (mu medication 50ml), behind the medicine 3 days, control efficiency was 80%, and behind the medicine 7 days, control efficiency was 100%; Single control efficiency was 89% with behind 500 times of 40% chlopyrifos (mu medication 100ml) medicine 3 days, and behind the medicine 7 days, control efficiency was 93.2%.As seen the control efficiency of 1000 times of liquid of 25% UC 62644 chlorpyrifos ec (autogamy) (mu 50ml) and 2000 times of liquid (mu medication 25ml) is all good than two kinds of single agent;
Prodenia litura 3～4 instar larvaes that take place with the taro field are object, and with 1000 times of 15% UC 62644 quintiofos creams (autogamy) (mu medication 50ml), behind the medicine 3 days and 7 days, control efficiency was respectively 96.6% and 100%; With behind 2000 times of (mu medication 25ml) medicines 3 days and 7 days, control efficiency was respectively 94.9% and 94.5%.Single with 5% UC 62644 missible oil 1000 (mu medication 50ml), 3 days, 7 days control efficiency is respectively 80% and 100% behind the medicine; Single with 1000 times of 20% quintiofos creams (mu medication 50ml), 3 days, 7 days control efficiency is 76.5% and 81.3% behind the medicine.The control efficiency that shows 1000 times of liquid of 15% UC 62644 quintiofos cream is all good than two single agent.
Claims (4)
1. a chlorfluazuron mixed pesticides is characterized in that: contain the pyridine worm and swell 1～3%, chlopyrifos 20～30%.
2. a kind of chlorfluazuron mixed pesticides as claimed in claim 1 is characterized in that: the grand content of pyridine worm is 1～2%, and chlopyrifos content is 20～30%.
3. a chlorfluazuron mixed pesticides is characterized in that: contain the pyridine worm and swell 1～3%, quinalphos 10～15%.
4. a kind of chlorfluazuron mixed pesticides as claimed in claim 4 is characterized in that: the grand content of pyridine worm is 1～2%, and quinalphos content is 10～15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410016948 CN1288979C (en) | 2004-03-12 | 2004-03-12 | Chlorfluazuron mixed pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410016948 CN1288979C (en) | 2004-03-12 | 2004-03-12 | Chlorfluazuron mixed pesticide |
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| CN1561738A CN1561738A (en) | 2005-01-12 |
| CN1288979C true CN1288979C (en) | 2006-12-13 |
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| CN 200410016948 Expired - Fee Related CN1288979C (en) | 2004-03-12 | 2004-03-12 | Chlorfluazuron mixed pesticide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100360033C (en) * | 2005-04-12 | 2008-01-09 | 中国水稻研究所 | Re-compounded pesticide of chlorfluazuron and profenofos or DDVP |
| CN101180971B (en) * | 2007-12-19 | 2010-06-09 | 海南利蒙特生物农药有限公司 | Compounded pesticide of quinalphos and hexaflumuron |
| CN104839183B (en) * | 2015-02-12 | 2017-05-24 | 四川利尔作物科学有限公司 | Pesticide combination and application thereof |
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