CN1288031A - Acrylic acid type energy stroage and liminous water paint and its prepn. method - Google Patents
Acrylic acid type energy stroage and liminous water paint and its prepn. method Download PDFInfo
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- CN1288031A CN1288031A CN 00123901 CN00123901A CN1288031A CN 1288031 A CN1288031 A CN 1288031A CN 00123901 CN00123901 CN 00123901 CN 00123901 A CN00123901 A CN 00123901A CN 1288031 A CN1288031 A CN 1288031A
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Abstract
The present invention relates to aqueous energy-storing luminescent paint and its preparation method. In includes film forming substance acrylic acid emulsion, luminescent material with structural formula (0.15-2.0)Mo.Al2O3.(0-1.0) SiO2:(0.02-0.10)Eu2O3, (0.02-0.10)R2O3 and high quality pigment, other common paint assistant and water. The invented aqueous acrylic acid energy-storing luminescent paint is non-toxic and harmless, and possesses strong or luminescent brightness after radiated by natural light, lamp light, etc. and afterglow period as long as 12 hours.
Description
The present invention relates to a kind of environmental friendliness water energy-storing luminescent paint and preparation method thereof, belong to technical field of coatings.
The luminous paint in past adopts transition metal activated ZnS series luminescent material more.Because such luminescent material twilight sunset can only reach 1-2 hour, be subjected to uviolizing or contact the perishable inefficacy in back with oxygen, eliminated by market gradually.The luminescent material of the rare-earth activated alkali earth metal aluminate series steady persistence that the nineties grows up, can reach more than 12 hours its time of persistence, and have heat-resisting, advantage such as antioxidant property good, nontoxic, "dead" harm and be able to Application and Development in coating.In recent years, will use SrAl abroad
2O
4: Eu
2+The luminous paint of series luminescent materials is progressively promoted in water transport, traffic and fire-fighting domain.For example, January 8 " World Report " in 2000, (" World Reporter " January 18,2000) introduced the hydrophobic luminous ship coating of a kind of acroleic acid resin, and this coating adopts ZnS and two kinds of luminescent materials of strontium aluminate as twinkler.United States Patent (USP) (US 5874491) is introduced the Resins, epoxy aqueous luminous paint, and wherein luminescent material is europkium-activated alkali earth metal aluminate.United States Patent (USP) (US 5665793, and US 5472737) has been introduced the composition of acrylic acid modified polyurethane aqueous road paint respectively.Domestic is the existing patent report of luminous paint of pigment with rare-earth activated aluminate luminescent material, for example, Chinese invention patent publication number CN1084535A, introduced a kind of luminescent coating, this coating is with europkium-activated luminous alkali earth metal aluminate luminescent material 20%～70%, finished product paint 20%～75%, or the transparent compound resin 30%～70% that forms such as epoxy, alkyd, peroxide ethene, melamine resin, admixtion 0～15%.1998 the 7th phases " coatings industry " 8-12 has reported " Luminescence Study of Modified Porous of strontium europium aluminate class Long Persistance Phosphorescent Coating ".Strontium aluminate class luminescent material is adopted in this research, has prepared unsaturated polyester resin and epoxypaint.2000 the 3rd phases, " Chinese coating " 40-41 also reported " novel wall luminous paint ", and this coating is twinkler with rare-earth activated aluminate, is a kind of solvent based coating.There is following defective in above-mentioned domestic and international luminous paint, and many luminous paints are solvent based coating on the one hand, and environment is produced harm; On the other hand, existing aqueous epoxide resin paint is a two-component coating, construction inconvenience; The aqueous polyurethane coating weather resisteant is relatively poor, is unfavorable for using in the field of environment difference.
The objective of the invention is to overcome the deficiencies in the prior art, a kind of eco-friendly acrylic acid type energy stroage and liminous water paint is provided.
The present invention is achieved through the following technical solutions.
Acrylic acid type energy stroage and liminous water paint of the present invention is formed and is comprised the main film forming substance acrylic emulsions, and structural formula is: (0.15～2.0) MOAl
2O
3(0～1.0) SiO
2: (0.02～0.10) Eu
2O
3, (0.02～0.10) R
2O
3Luminescent material, and pigment extender, other coatings additive(s) commonly used and water, its weight part is: 50～80 parts of acrylic emulsions, 15～40 parts of luminescent materials, 1.0～6.5 parts of pigment extenders, other coatings additive(s)s are 1.0～8.5 parts, 40～80 parts in water.The assisted activation element R of luminescent material wherein is: one or more of dysprosium, cerium, neodymium, praseodymium, samarium, terbium, holmium, erbium, thulium, ytterbium, MO be strontium oxide and calcium oxide, barium oxide, magnesian one or more.
Aforesaid propylene acids emulsion is one or more of pure-acrylic emulsion, acrylate and vinyl acetate emulsion, benzene emulsion.
Above-mentioned pigment extender is one or more of light calcium carbonate, wilkinite, superfine talcum powder and aerosil.
Other coatings additive(s) commonly used is:
Film coalescence aid ester alcohol 12 or propylene glycol phenylate,
Dispersant polycarboxylate (molecular weight is 4000～8000,
Defoamer acetic acid tri-n-butyl,
The mould inhibitor pentachlorophenol,
Thickening material alkali swelling property vinylformic acid.
The luminescent material of above-mentioned luminous paint is handled through coating.The coating material is: one or more of vinylformic acid wax, polyethylene wax, silane coupling agent, coating quantity is that the per-cent of luminescent material weight is: 0.1～1.5%.The coating solvent is one or more of dehydrated alcohol, dimethylbenzene, N-BUTYL ACETATE, and solvent load is 45～65% of a luminescent material weight.
Prepare above-mentioned acrylic acid type energy stroage and liminous water paint method comprise that step is as follows:
1) the coating material fully is dissolved in the solvent, adds the luminescent material fine powder in proportion, ball milling is 1～3 hour in ball mill, pulp, and vacuum-drying obtains the coating luminescent powder.
2) join water, film coalescence aid, acrylic emulsions, pigment extender and coating luminescent powder in the material-compound tank successively, stir, then, pouring grinding in ball grinder into mixed 30～60 minutes, add coatings additive(s)s commonly used such as dispersion agent, defoamer, mould inhibitor, thickening material, ball milling is 10～20 minutes again, and pulp obtains finished product coating.
The present invention be a kind of be pigment with rare-earth activated alkali earth metal aluminate, aluminosilicate luminescent material, be the mono-component aqueous energy-accumulating luminous paint of main film forming substance with the acrylic emulsions.This acrylic acid type energy stroage and liminous water paint is nontoxic, environmental friendliness has stronger luminosity after irradiations such as natural light, light, be longer than luminous time of persistence 12 hours, can be coated in various body surfaces, be widely used in fields such as road, boats and ships, building, fire symbol, label.
The invention will be further described below in conjunction with embodiment:
Embodiment 1
1) take by weighing vinylformic acid wax 300 grams, be dissolved in 50 liters of xylene solutions, add the bluish-green luminescent powder of double centner, ball milling 2 hours, pulp, vacuum-drying obtains blue-greenish colour coating luminescent powder.The structural formula of bluish-green luminescent powder is: 0.75SrOAl
2O
3: 0.045Eu
2O
3, 0.060Dy
2O
3
2) measuring 50 kg water pours in the material-compound tank, take by weighing 12 kilograms of film coalescence aid ester alcohol respectively, 0.8 kilogram of dispersant polycarboxylate (molecular weight 5040), 54 kilograms of pure-acrylic emulsions, 3.6 kilograms of superfine talcum powders, 36 kilograms of coating luminescent powders join in the material-compound tank successively, stir, joined in the ball mill ball milling then 40 minutes, take by weighing 0.6 kilogram of defoamer acetic acid tri-n-butyl, 0.5 kilogram of mould inhibitor pentachlorophenol, 0.7 kilogram in thickening material alkali swelling property vinylformic acid, join in the ball mill, ball milling is 15 minutes again, pulp, finished product packing.
This luminous paint in the dark sends bluish-green coloured light, is coated on 0.3 millimeter of plastics, wood surface, reaches 3658mcd/m according to German DIN67510 standard test luminous intensity
2, 10 hours twilight sunset 21.6mcd/m
2
Embodiment 2
Used coating luminescent powder is with embodiment 1.
Measuring 50 kg water pours in the material-compound tank, take by weighing 12 kilograms of film coalescence aid ester alcohol respectively, 0.8 kilogram of dispersant polycarboxylate (molecular weight 6000), 70 kilograms of benzene emulsions, 1.6 kilograms in lime carbonate, 1.6 kilograms of superfine talcum powders, 0.6 kilogram of aerosil, 20 kilograms of coating luminescent powders join in the material-compound tank successively, stir, joined in the ball mill ball milling then 50 minutes, take by weighing 0.8 kilogram of defoamer acetic acid tri-n-butyl, 0.4 kilogram of mould inhibitor pentachlorophenol, 0.8 kilogram in thickening material alkali swelling property vinylformic acid, join in the ball mill, ball milling is 15 minutes again, pulp, finished product packing.
This luminous paint in the dark sends bluish-green coloured light, is coated on 0.3 millimeter of plastics, metallic surface, reaches 3130mcd/m according to German DIN67510 standard test luminous intensity
2, 10 hours twilight sunset 10.6mcd/m
2
Embodiment 3
1) take by weighing polyethylene wax 350 grams, be dissolved in 60 liters of dehydrated alcohols, add the yellowish green luminescent powder of double centner, ball milling 1.5 hours, pulp, vacuum-drying obtains yellow-green colour coating luminescent powder.The structural formula of yellowish green luminescent powder is: SrOAl
2O
30.1SiO
2: 0.035Eu
2O
3, 0.040Dy
2O
3
2) measuring 50 premium on currency pours in the material-compound tank, take by weighing 12 kilograms of film coalescence aid ester alcohol respectively, 0.8 kilogram of dispersant polycarboxylate (molecular weight 4500), 66 kilograms of pure-acrylic emulsions, 6.0 kilograms of wilkinites, 20 kilograms of coating luminescent powders join in the material-compound tank successively, stir, joined in the ball mill ball milling then 50 minutes, take by weighing 1.0 kilograms of defoamer acetic acid tri-n-butyls, 0.8 kilogram of mould inhibitor pentachlorophenol, 1.2 kilograms in thickening material alkali swelling property vinylformic acid, join in the ball mill, ball milling is 15 minutes again, pulp, finished product packing.
This luminous paint in the dark sends yellow-green light, is coated on 0.3 millimeter of cement, plank or metallic surface, reaches 3740mcd/m according to German DIN67510 standard test luminous intensity
2, 10 hours twilight sunset 9.6mcd/m
2
Embodiment 4
Used coating luminescent powder is with embodiment 3.
Measuring 50 premium on currency pours in the material-compound tank, take by weighing 4.6 kilograms of PPHs respectively, 0.8 kilogram of dispersant polycarboxylate (molecular weight 6500), 70 kilograms of acrylate and vinyl acetate emulsions, 2.0 kilograms in lime carbonate, 1.6 kilograms of superfine talcum powders, 0.8 kilogram of aerosil, 18 kilograms of coating luminescent powders join in the material-compound tank successively, stir, joined in the ball mill ball milling then 50 minutes, take by weighing 0.8 kilogram of defoamer acetic acid tri-n-butyl, 0.4 kilogram of mould inhibitor pentachlorophenol, 1.0 kilograms in thickening material alkali swelling property vinylformic acid, join in the ball mill, ball milling is 15 minutes again, pulp, finished product packing.
This luminous paint in the dark sends yellow-green light, is coated on 0.3 millimeter of plastics, wood surface, reaches 3420mcd/m according to German DIN67510 standard test luminous intensity
2, 10 hours twilight sunset 7.6mcd/m
2
Claims (6)
1. acrylic acid type energy stroage and liminous water paint, it is characterized in that composition comprises: main film forming substance acrylic emulsions, structural formula are (0.15～2.0) MOAl
2O
3(0～1.0) SiO
2: (0.02～0.10) Eu
2O
3, (0.02～0.10) R
2O
3Luminescent material, and pigment extender, other coatings additive(s) commonly used and water, the weight part of each component is: 50～80 parts of acrylic emulsions, 15～40 parts of luminescent materials, 1.0～6.5 parts of pigment extenders, other coatings additive(s)s are 1.0～8.5 parts, 40～80 parts in water; Wherein, the assisted activation element R of luminescent material is: one or more of dysprosium, cerium, neodymium, praseodymium, samarium, terbium, holmium, erbium, thulium, ytterbium, MO be strontium oxide and calcium oxide, barium oxide, magnesian one or more.
2. acrylic acid type energy stroage and liminous water paint as claimed in claim 1 is characterized in that, described acrylic emulsions is one or more of pure-acrylic emulsion, acrylate and vinyl acetate emulsion, benzene emulsion.
3. acrylic acid type energy stroage and liminous water paint as claimed in claim 1 or 2 is characterized in that, described pigment extender is one or more of light calcium carbonate, wilkinite, superfine talcum powder and aerosil.
4. acrylic acid type energy stroage and liminous water paint as claimed in claim 1 or 2 is characterized in that, other coatings additive(s) commonly used is:
Film coalescence aid ester alcohol 12 or propylene glycol phenylate,
The dispersant molecule amount is 4000～8000 polycarboxylates,
Defoamer acetic acid tri-n-butyl,
The mould inhibitor pentachlorophenol,
Thickening material alkali swelling property vinylformic acid.
5. acrylic acid type energy stroage and liminous water paint as claimed in claim 1 or 2, it is characterized in that, described luminescent material is handled through coating, the coating material is: one or more of vinylformic acid wax, polyethylene wax, silane coupling agent, coating quantity is that the per-cent of luminescent material weight is: 0.1～1.5%, the coating solvent is one or more of dehydrated alcohol, dimethylbenzene, N-BUTYL ACETATE, and solvent load is 45～65% of a luminescent material weight.
One kind prepare the described acrylic acid type energy stroage and liminous water paint of claim 1～5 method, comprise that step is as follows:
(1) the coating material fully is dissolved in the solvent, adds the luminescent material fine powder in proportion, ball milling is 1～3 hour in ball mill, pulp, and vacuum-drying obtains the coating luminescent powder;
(2) join water, film coalescence aid, acrylic emulsions, pigment extender and coating luminescent powder in the material-compound tank successively, stir, then, pouring grinding in ball grinder into mixed 30～60 minutes, add coatings additive(s)s commonly used such as dispersion agent, defoamer, mould inhibitor, thickening material, ball milling is 10～20 minutes again, and pulp obtains finished product coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123901 CN1123612C (en) | 2000-09-29 | 2000-09-29 | Acrylic acid type energy stroage and liminous water paint and its prepn. method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123901 CN1123612C (en) | 2000-09-29 | 2000-09-29 | Acrylic acid type energy stroage and liminous water paint and its prepn. method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1288031A true CN1288031A (en) | 2001-03-21 |
| CN1123612C CN1123612C (en) | 2003-10-08 |
Family
ID=4590199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00123901 Expired - Fee Related CN1123612C (en) | 2000-09-29 | 2000-09-29 | Acrylic acid type energy stroage and liminous water paint and its prepn. method |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286235A (en) * | 2010-06-17 | 2011-12-21 | 纬创资通股份有限公司 | Water-based single solution type coating and method for forming a high lustrous coating layer by using the same |
| CN102732112A (en) * | 2011-04-02 | 2012-10-17 | 盘锦辽河油田金宇建筑材料有限公司 | Energy-storing long-acting luminescent coating |
| CN103113798A (en) * | 2012-12-25 | 2013-05-22 | 王娟 | Luminescent external wall paint |
| CN103351759A (en) * | 2013-07-29 | 2013-10-16 | 星庄园化工（上海）有限公司 | Outdoor luminous water-based woodenware paint and preparation method thereof |
| CN103602131A (en) * | 2013-10-14 | 2014-02-26 | 南宁丽康涂料有限公司 | Luminescent traffic paint |
| CN103612449A (en) * | 2013-11-15 | 2014-03-05 | 英利能源（中国）有限公司 | Insulating luminescent material, solar battery back plate comprising insulating luminescent material, and solar battery component |
| CN105153840A (en) * | 2015-08-28 | 2015-12-16 | 东来涂料技术（上海）有限公司 | Automotive interior energy-storage fluorescent paint and preparation method thereof |
| CN105694633A (en) * | 2016-04-20 | 2016-06-22 | 杨荣纯 | Night lighting material and preparation method and application thereof |
| CN105733380A (en) * | 2014-12-12 | 2016-07-06 | 张文知 | Energy-storing luminous paint used for roads |
| CN107694885A (en) * | 2017-09-20 | 2018-02-16 | 阜南县星光工艺品有限公司 | A kind of preparation method of the strong luminous Wood craft of water resistance |
| CN108003724A (en) * | 2017-12-11 | 2018-05-08 | 山西省交通科学研究院 | A kind of energy-accumulating luminous paint for highway anticollision wall and preparation method thereof |
| CN108300023A (en) * | 2016-08-22 | 2018-07-20 | 青岛环秀涂料有限公司 | A kind of water energy-storing luminescent paint, preparation method and its construction method |
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| CN109868024A (en) * | 2018-07-14 | 2019-06-11 | 宁波高新区诠宝绶新材料科技有限公司 | A kind of method of the in-situ method preparation outer layer of leather containing europium finishing agent |
| CN110564222A (en) * | 2019-09-01 | 2019-12-13 | 合众（佛山）化工有限公司 | Rare earth hybrid luminescent radiation-proof water-based paint and preparation method thereof |
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| CN110903729A (en) * | 2019-12-13 | 2020-03-24 | 湖北科迪雅科技有限公司 | Energy storage type luminous paint for environment-friendly plastic base and preparation method thereof |
| CN111234641A (en) * | 2020-03-23 | 2020-06-05 | 深圳安盾海洋新材料有限公司 | Water-based acrylic energy-storage luminescent paint and preparation method thereof |
| CN113214824A (en) * | 2021-05-11 | 2021-08-06 | 齐齐哈尔北方集团北方化学工业有限责任公司 | Composite energy-storage luminescent material, water-based energy-storage luminescent coating and preparation method thereof |
-
2000
- 2000-09-29 CN CN 00123901 patent/CN1123612C/en not_active Expired - Fee Related
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| CN102286235A (en) * | 2010-06-17 | 2011-12-21 | 纬创资通股份有限公司 | Water-based single solution type coating and method for forming a high lustrous coating layer by using the same |
| CN102732112A (en) * | 2011-04-02 | 2012-10-17 | 盘锦辽河油田金宇建筑材料有限公司 | Energy-storing long-acting luminescent coating |
| CN103113798A (en) * | 2012-12-25 | 2013-05-22 | 王娟 | Luminescent external wall paint |
| CN103351759B (en) * | 2013-07-29 | 2016-06-08 | 星庄园化工（上海）有限公司 | A kind of aqueous woodware paint of outdoor noctilucence and preparation method thereof |
| CN103351759A (en) * | 2013-07-29 | 2013-10-16 | 星庄园化工（上海）有限公司 | Outdoor luminous water-based woodenware paint and preparation method thereof |
| CN103602131A (en) * | 2013-10-14 | 2014-02-26 | 南宁丽康涂料有限公司 | Luminescent traffic paint |
| CN103602131B (en) * | 2013-10-14 | 2016-01-13 | 南宁丽康涂料有限公司 | A kind of Luminescent traffic paint |
| CN103612449A (en) * | 2013-11-15 | 2014-03-05 | 英利能源（中国）有限公司 | Insulating luminescent material, solar battery back plate comprising insulating luminescent material, and solar battery component |
| CN105733380A (en) * | 2014-12-12 | 2016-07-06 | 张文知 | Energy-storing luminous paint used for roads |
| CN105153840A (en) * | 2015-08-28 | 2015-12-16 | 东来涂料技术（上海）有限公司 | Automotive interior energy-storage fluorescent paint and preparation method thereof |
| CN105694633A (en) * | 2016-04-20 | 2016-06-22 | 杨荣纯 | Night lighting material and preparation method and application thereof |
| CN108300023A (en) * | 2016-08-22 | 2018-07-20 | 青岛环秀涂料有限公司 | A kind of water energy-storing luminescent paint, preparation method and its construction method |
| CN107694885A (en) * | 2017-09-20 | 2018-02-16 | 阜南县星光工艺品有限公司 | A kind of preparation method of the strong luminous Wood craft of water resistance |
| CN108003724A (en) * | 2017-12-11 | 2018-05-08 | 山西省交通科学研究院 | A kind of energy-accumulating luminous paint for highway anticollision wall and preparation method thereof |
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| CN110593148A (en) * | 2019-09-03 | 2019-12-20 | 华北水利水电大学 | Road anti-reverse sign |
| CN110593148B (en) * | 2019-09-03 | 2021-05-07 | 华北水利水电大学 | Road anti-reverse sign |
| CN110903729A (en) * | 2019-12-13 | 2020-03-24 | 湖北科迪雅科技有限公司 | Energy storage type luminous paint for environment-friendly plastic base and preparation method thereof |
| CN111234641A (en) * | 2020-03-23 | 2020-06-05 | 深圳安盾海洋新材料有限公司 | Water-based acrylic energy-storage luminescent paint and preparation method thereof |
| CN111234641B (en) * | 2020-03-23 | 2021-11-19 | 深圳安盾海洋新材料有限公司 | Water-based acrylic energy-storage luminescent paint and preparation method thereof |
| CN113214824A (en) * | 2021-05-11 | 2021-08-06 | 齐齐哈尔北方集团北方化学工业有限责任公司 | Composite energy-storage luminescent material, water-based energy-storage luminescent coating and preparation method thereof |
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| Publication number | Publication date |
|---|---|
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