CN1284611C - Oxidation type antidote for residual agricultural chemicals in fruits and vegetables - Google Patents

Oxidation type antidote for residual agricultural chemicals in fruits and vegetables Download PDF

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Publication number
CN1284611C
CN1284611C CN 03158224 CN03158224A CN1284611C CN 1284611 C CN1284611 C CN 1284611C CN 03158224 CN03158224 CN 03158224 CN 03158224 A CN03158224 A CN 03158224A CN 1284611 C CN1284611 C CN 1284611C
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CN
China
Prior art keywords
fruits
pesticide residue
vegetables
antidote
fruit
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 03158224
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Chinese (zh)
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CN1524595A (en
Inventor
温鲁
唐玉玲
宋虎卫
张宝叶
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Huaiyin Normal University
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Huaiyin Normal University
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Priority to CN 03158224 priority Critical patent/CN1284611C/en
Publication of CN1524595A publication Critical patent/CN1524595A/en
Application granted granted Critical
Publication of CN1284611C publication Critical patent/CN1284611C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention discloses an oxidization type fruit and vegetable pesticide residue toxicide which belongs to the field ofagricultural chemistry. The powdery, tabular or granular fruit and vegetable pesticide residue toxicide is prepared from strong oxidation substances, such as solid peroxodisulfate, peroxocarbonate or ferrate, etc. After the fruit and vegetable pesticide residue toxicide is added with water and is used for soaking vegetables and fruits, the fruit and vegetable pesticide residue toxicide can oxidize and degrade pesticide residue on the vegetables and the fruits. The oxidization type fruit and vegetable pesticide residue toxicide can be used for sterilization and storing refreshment.

Description

Oxidizing fruits and vegetables pesticide residue antidote
Affiliated technical field
The invention belongs to agrochemical field, be specifically related to Oxidizing fruits and vegetables pesticide residue antidote.
Background technology
Along with the raising of economic development and living standards of the people, people attract great attention to food security.Because of the vegetable and fruit residues of pesticides cause the report of poisoning by food, common all spaces in a newspaper.Although can take market access rule, the vegetable and fruit that inaccurate residues of pesticides exceed standard comes into the market, but can only carry out most small and medium-sized cities even some big cities in part big city and economically developed medium-sized city, also be difficult to accomplish this point, said nothing of vast rural area.The detoxification machine of oxidative degradation residues of pesticides has appearred coming with ozone in market now, detoxifying effect is fine, but because disposable input is higher, therefore apply unsatisfactory, also having company to release does not need " the fruits and vegetables detoxifcation spirit " of special equipment, but belonging to washing type preparation, is " washing " rather than degrading pesticide after all.
Summary of the invention
The objective of the invention is to: Oxidizing fruits and vegetables pesticide residue antidote is provided, makes people with effectively degrade residues of pesticides in the vegetable and fruit of lower input, with the edible safety of practical assurance vegetable and fruit.
Technical solution of the present invention is: the good solid strong oxidizing property material of employing security comes the residues of pesticides in the oxidative degradation vegetable and fruit, these strong oxidizing property materials comprise persulfate or ferrate, make powdery, sheet or graininess, soak vegetable and fruit after adding water.
Antidote of the present invention, lower than the cost of liquid dosage form, easy to use than gaseous ozone, to compare detoxifying effect remarkable with the preparation of tool cleaning function.
The specific embodiment
This antidote is made powdery, sheet or graininess by solid strong oxidizing property material and is formed, and strong oxidation material comprises persulfate or ferrate.
Persulfate mainly contains sodium peroxydisulfate, potassium peroxydisulfate or ammonium persulfate, and the oxidation-reduction potential of its over cure acid group is 2.01, slightly inferior to ozone 2.07, and can be as the remains of pesticide on the effective degraded fruits and vegetables of ozone.With sodium peroxydisulfate Na 2S 2O 8Be example, after the residues of pesticides oxidation Decomposition, self be reduced to sodium sulphate Na 2SO 4, harmless, and it is clean to be easy to rinsing.
Ferrate mainly contains potassium ferrate K 2FeO 4Or Na2Fe04 Na 2FeO 4, FeO 4 2-Oxidation-reduction potential up to 2.20, also higher than ozone, oxidation Decomposition residues of pesticides very capable, self then is reduced into Fe 3+, once be used for purifying of drinking water, also be the good material of security.
Antidote of the present invention can be gathered at vegetable and fruit and be used before the back extremely eats, and dissolves in the water by metering during use, puts into vegetable and fruit, soaks about 20 minutes, can be with residues of pesticides oxidative degradation, and taking-up gets final product with the clear water rinsing.In degrading pesticide residues, also have the sterilizing effect, can kill various germs, virus and parasitic ovum, prevent that effectively illness finds its way in by the mouth, and can prolong the time of storage fresh-keeping.
Antidote of the present invention all can be made pulvis, tablet or granule by commonsense method, is convenient to packing and metering.
Antidote of the present invention is lower than the packing cost of liquid dosage form; Than the necessary on-the-spot gaseous ozone that produces, not only easy to use, and do not need special equipment; With only have " detoxifcation spirit " of cleaning function and compare, detoxifying effect significantly strengthens.
Embodiment 1: make detecting instrument with the TFC-NY type pesticide residue rapid detector that the prosperous and powerful analytical instrument in Beijing manufacturing center produces, learn from else's experience and detect the green vegetables 0.5kg that residues of pesticides are arranged, in basin, put the 2kg clear water, add content and be 98% sodium peroxydisulfate 2-3g, put into green vegetables after the dissolving, soak 20min, take out green vegetables, use the clear water rinsing, drain, use above-mentioned instrument detecting again, non agricultural chemical residuum.
Embodiment 2: use the same instrument, learn from else's experience and detect the apple 1kg that residues of pesticides are arranged, put the 2kg clear water in basin, add content and be 95% Na2Fe04 1-2g, put into apple, soak 20min, take out rinsing, survey non agricultural chemical residuum again.

Claims (4)

1, a kind of Oxidizing fruits and vegetables pesticide residue antidote, this antidote are that raw material is made with solid strong oxidizing property material, it is characterized in that: its solid strong oxidizing property material comprises persulfate or ferrate.
2, Oxidizing fruits and vegetables pesticide residue antidote according to claim 1 is characterized in that: persulfate is sodium peroxydisulfate, potassium peroxydisulfate or ammonium persulfate.
3, Oxidizing fruits and vegetables pesticide residue antidote according to claim 1 is characterized in that: ferrate is Na2Fe04 or potassium ferrate.
4, Oxidizing fruits and vegetables pesticide residue antidote according to claim 1 is characterized in that: this antidote can be made into pulvis, tablet or granule.
CN 03158224 2003-09-12 2003-09-12 Oxidation type antidote for residual agricultural chemicals in fruits and vegetables Expired - Fee Related CN1284611C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 03158224 CN1284611C (en) 2003-09-12 2003-09-12 Oxidation type antidote for residual agricultural chemicals in fruits and vegetables

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 03158224 CN1284611C (en) 2003-09-12 2003-09-12 Oxidation type antidote for residual agricultural chemicals in fruits and vegetables

Publications (2)

Publication Number Publication Date
CN1524595A CN1524595A (en) 2004-09-01
CN1284611C true CN1284611C (en) 2006-11-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 03158224 Expired - Fee Related CN1284611C (en) 2003-09-12 2003-09-12 Oxidation type antidote for residual agricultural chemicals in fruits and vegetables

Country Status (1)

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CN (1) CN1284611C (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1730326A4 (en) 2004-01-16 2008-05-28 Battelle Memorial Institute Methods and apparatus for producing ferrate (vi)
DE602005027490D1 (en) * 2004-11-12 2011-05-26 Battelle Memorial Inst Columbus DECONTAMINATION AGENT
WO2008112657A1 (en) 2007-03-09 2008-09-18 Battelle Memorial Institute Ferrate(vi)-containing compositions and methods of using ferrate(vi)
EP2268345A1 (en) 2008-03-26 2011-01-05 Battelle Memorial Institute Apparatus and methods of providing diatomic oxygen (o2) using ferrate(vi)-containing compositions
EP2342291A1 (en) 2008-10-17 2011-07-13 Battelle Memorial Institute Corrosion resistant primer coating
CN103081903A (en) * 2012-10-17 2013-05-08 王浅肃 Pesticide residue remover for agricultural products
CN103081902A (en) * 2012-10-17 2013-05-08 王浅肃 Method for detoxicating pesticide residue
CN103081899A (en) * 2012-10-17 2013-05-08 王浅肃 Preparation method of pesticide residue remover
CN103081904A (en) * 2012-10-17 2013-05-08 王浅肃 Pesticide residue toxinicide for agricultural products
CN103081901A (en) * 2012-10-17 2013-05-08 王浅肃 Preparation method of pesticide residue degrading agent
CN103081900A (en) * 2012-10-17 2013-05-08 王浅肃 Pesticide residue degrading agent for agricultural products
CN103081898A (en) * 2012-10-17 2013-05-08 王浅肃 Pesticide residue remover for agricultural products
CN103081905A (en) * 2012-10-17 2013-05-08 王浅肃 Preparation method of pesticide residue toxinicide for agricultural products
CN103081897A (en) * 2012-10-17 2013-05-08 王浅肃 Preparation method of pesticide residue remover
CN103081734A (en) * 2012-10-17 2013-05-08 王浅肃 Method for removing pesticide residues
CN103081733A (en) * 2012-10-17 2013-05-08 王浅肃 Method for eliminating pesticide residues
CN103168774B (en) * 2013-03-15 2014-05-07 邹根荣 Tea leaf and tobacco leaf detoxification agent and application method thereof
CN103719647B (en) * 2014-01-14 2015-08-26 大连交通大学 A kind of compound prescription fruits and vegetables agricultural chemicals falls residual dose
CN106281787A (en) * 2015-06-09 2017-01-04 彭晨 Fruit and vegerable scavenger specially based on mineral salt
CN108517261A (en) * 2018-03-19 2018-09-11 昆明理工大学 A kind of antidote of fruit-vegetable pesticide residues
CN112457931A (en) * 2020-10-31 2021-03-09 仇晓锋 Fruit and vegetable pesticide residue scavenger
CN114680350B (en) * 2020-12-31 2023-04-18 广东美的白色家电技术创新中心有限公司 Cleaning device

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Publication number Publication date
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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Huai'an Kaiyue Technology Development Co., Ltd.

Assignor: Huaiyin Normal College

Contract fulfillment period: 2009.2.20 to 2015.2.19 contract change

Contract record no.: 2009320000888

Denomination of invention: Oxidation type antidote for residual agricultural chemicals in fruits and vegetables

Granted publication date: 20061115

License type: Exclusive license

Record date: 2009.5.14

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.2.20 TO 2015.2.19; CHANGE OF CONTRACT

Name of requester: HUAIAN KAIYUE SCIENCE AND TECHNOLOGY DEVELOPMENT C

Effective date: 20090514

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20061115

Termination date: 20100912