CN1283708C - Nanometer additive and plastic and pharmaceutical ion source containing the same - Google Patents
Nanometer additive and plastic and pharmaceutical ion source containing the same Download PDFInfo
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- CN1283708C CN1283708C CN 02154671 CN02154671A CN1283708C CN 1283708 C CN1283708 C CN 1283708C CN 02154671 CN02154671 CN 02154671 CN 02154671 A CN02154671 A CN 02154671A CN 1283708 C CN1283708 C CN 1283708C
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- nanometer additive
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- 239000000654 additive Substances 0.000 title claims abstract description 30
- 230000000996 additive effect Effects 0.000 title claims abstract description 30
- 239000004033 plastic Substances 0.000 title claims abstract description 24
- 229920003023 plastic Polymers 0.000 title claims abstract description 24
- 150000002500 ions Chemical class 0.000 claims abstract description 54
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940070527 tourmaline Drugs 0.000 claims abstract description 4
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 4
- 239000011032 tourmaline Substances 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims description 64
- 229910052684 Cerium Inorganic materials 0.000 claims description 6
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000008676 import Effects 0.000 claims description 3
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- UUWCBFKLGFQDME-UHFFFAOYSA-N platinum titanium Chemical compound [Ti].[Pt] UUWCBFKLGFQDME-UHFFFAOYSA-N 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 206010006451 bronchitis Diseases 0.000 abstract description 14
- 201000007100 Pharyngitis Diseases 0.000 abstract description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 208000006673 asthma Diseases 0.000 abstract description 3
- 208000023504 respiratory system disease Diseases 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 230000002888 effect on disease Effects 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 19
- 201000010099 disease Diseases 0.000 description 13
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 13
- 239000002994 raw material Substances 0.000 description 10
- 208000018569 Respiratory Tract disease Diseases 0.000 description 6
- 206010006458 Bronchitis chronic Diseases 0.000 description 5
- 230000001154 acute effect Effects 0.000 description 5
- 208000007451 chronic bronchitis Diseases 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 206010014561 Emphysema Diseases 0.000 description 4
- 230000001684 chronic effect Effects 0.000 description 4
- 101150038956 cup-4 gene Proteins 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000036541 health Effects 0.000 description 4
- 206010022000 influenza Diseases 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 201000006306 Cor pulmonale Diseases 0.000 description 3
- 208000004186 Pulmonary Heart Disease Diseases 0.000 description 3
- 206010039085 Rhinitis allergic Diseases 0.000 description 3
- 201000010105 allergic rhinitis Diseases 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 210000002345 respiratory system Anatomy 0.000 description 3
- 230000001225 therapeutic effect Effects 0.000 description 3
- 201000009267 bronchiectasis Diseases 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 238000005213 imbibition Methods 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 230000000414 obstructive effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000002560 therapeutic procedure Methods 0.000 description 2
- 208000017667 Chronic Disease Diseases 0.000 description 1
- 206010010970 Cor pulmonale chronic Diseases 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 206010035664 Pneumonia Diseases 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 206010044302 Tracheitis Diseases 0.000 description 1
- 201000004427 acute laryngopharyngitis Diseases 0.000 description 1
- 206010001093 acute tonsillitis Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 208000026636 chronic pulmonary heart disease Diseases 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
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- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicinal Preparation (AREA)
Abstract
The present invention relates to a nanometer additive agent, plastic containing the nanometer additive agent and a medicinal ion stream generator for processing the plastic into a medicinal cup, and the nanometer additive agent is used for treating upper respiratory diseases. The nanometer additive agent comprises by weight materials as follows: 15 to 25 grams of nanometer tourmaline, 5 to 10 grams of nanometer titanium oxide, 5 to 10 grams of nanometer zirconium dioxide and a proper quantity of nanometer cerium oxide or nanometer yttrium oxide. The medicinal ion stream generator is composed of a voltage boosting device (2), a control circuit (1), a medicinal cup (4), an isolating device (3) and a metal electrode (5), wherein the metal electrode (5) has multiple pointed ends and is in the shape of a plum blossom. The medicinal ion stream generator can generate oriented and high-concentration medicinal ion streams and has curative effects on diseases, such as asthma, bronchitis, pharyngitis, etc.; the medicinal ion stream generator also has the advantages of high safety and no ozone generation.
Description
Affiliated technical field
The present invention relates to a kind of medicine ion stream medical or family expenses medicine equipment and health care instrument that is used for the nanometer additive of plastics and is used for the treatment of upper respiratory disease.More specifically say so a kind of can the directed medicine ion producer that produces medicine ion stream.
Background technology
Trachitis, bronchitis are a kind of common diseases, frequently-occurring disease.Though this disease age size, cough, expectoration, the asthma in its when morbidity, misery unbearably, with advancing age, the prolongation in years, the state of an illness increases the weight of year by year, finally causes pulmonary emphysema, pulmonary heart disease, jeopardizes health and lives.Medical circle is taked measure to put prevention first to such treatment of diseases for these years, does not have effective treatment means, is considered as chronic disease by medical circle.People explore and study prevention and treatment of diseases efficient ways such as trachitis, bronchitis also in continuous effort simultaneously.
CN 1339622A patent provides a kind of functional materials that can produce negative ion, and this material is by Al
2O
3, ZrO
2, SiO
2, CrO, Fe
2O
3, TiO
2, SnO
2, Ce
2O
3, Pr
2O
3, Nd
2O
3, Sm
2O
3Form Deng raw material, be mainly used in the fibre product, the negative ion of generation has the effect that strengthens tissue activity.But the raw material that this material adopted is very complicated, and has comprised Pr
2O
3, Nd
2O
3, Sm
2O
3Three kinds of compositions, therefore, this material has certain radioactivity, is deleterious to human body, in real life, does not have using value.
August 30 nineteen ninety-five, Chinese patent CN 1107373A disclosed gaseous negative ion medicine therapy health device patent by name, disclosed a kind of novel method of utilizing gaseous negative ion medicine to prevent and treating trachitis, bronchitis class disease.This method has adopted nonmetal thing imbibition electrode new technology and the charged formula new principle of fluid molecule.Can produce liquid negative ion stream with this method, and not produce ozone.
Though this patented technology has adopted nonmetal thing imbibition electrode, does not produce ozone, the concentration of the gaseous medication molecule that produces with this method far can not be used for the treatment of disease, can not produce the medicine ion stream of directed flow.Because the emission tip of gaseous negative ion medicine therapy health device directly is connected with pilot circuit, increasing apparatus, when the patient uses,, certain danger is arranged simultaneously, damage circuit simultaneously easily if touch transmitting terminal.And for preventing danger, transmitting terminal is surrounded, will directly influence the generation of medicine ion stream.This is the technical barrier that the present invention will solve.
Summary of the invention
For overcoming the deficiencies in the prior art part, the objective of the invention is to develop a kind of nanometer additive that can produce negative ion, add it plastic raw materials of the medicine cup that is used for making the medicine ion producer to, thereby realize impelling medicine ion volatilization and medicine ion generation orientation movement.
It is of the present invention that a purpose is arranged again is the plastics that development and production go out to contain nanometer additive of the present invention.
Purpose in addition of the present invention is to design a kind of safety, can produce concentration and be not less than 1 * 10
7Individual/cm
3The medicine ion producer.By the effect of nanometer additive, impel the volatilization of medicine ion, produce the directed medicine ion stream that moves, more effectively utilize the therapeutic action and the health-care effect of medicine ion.
First purpose of the present invention takes following technical scheme to realize.
Nanometer additive of the present invention is made up of nano-tourmaline, nano-titanium oxide, nano zircite, nano oxidized Cerium or nano yttrium oxide, and their weight ratio is that nano-tourmaline 15 ~ 25 grams, nano-titanium oxide 5 ~ 10 grams, nano zircite 5 ~ 10 grams, nano oxidized Cerium or nano yttrium oxide are an amount of.
Second purpose of the present invention takes following technical scheme to realize.
At the plastic raw materials that is used for making the medicine cup, add the nanometer additive of the present invention of 2 ~ 20% weight ratios, make a kind of plastics that contain nanometer additive of the present invention.
Can be processed into medicine cup required for the present invention with this plastics.
Because the thermo-effect of infrared radiation and the nanometer specific surface energy effect of nanometer additive of the present invention, can quicken a glass Chinese traditional medicine ion volatilization, because this nanometer additive has the effect that produces negative ion and electronics, can form negative electric field again, impel medicine ion to produce directed moving at the frosting of cup.
Of the present invention also have a purpose to take following technical scheme to realize.
The medicine ion producer that contains this nanometer additive comprises increasing apparatus 2, pilot circuit 1, medicine cup 4, it is characterized in that also comprising disrupter 3 and plum blossom shape multi-stylus end metal electrode 5, and the medicine cup is to be formed by the plastic working that contains nanometer additive of the present invention.
Pilot circuit 1 is connected with increasing apparatus 2 by lead, increasing apparatus 2 is connected with disrupter 3, negative ion, electronics that increasing apparatus 2 produces, be not directly released in the air, still by after the regathering of disrupter 3, the plum blossom shape multi-stylus end metal electrode 5 that passes to the rim of a cup position that is arranged in the medicine cup 4 that contains nanometer additive by lead is discharged into air, forms medicine ion stream.
Medicine ion producer of the present invention after improving; owing to increased disrupter; its increasing apparatus, pilot circuit directly are not communicated with emission tip; reduced because of running into emission tip accidentally or because of reasons such as wet weather, dust, soups in the external world; make short circuit and cause danger; improve the security of medicine ion producer of the present invention, also increasing apparatus and pilot circuit have been played provide protection simultaneously, improved its work-ing life.On the other hand, because medicine ion producer of the present invention has had disrupter, security improves greatly, its emission tip 5 can directly expose outside, do not need other safety guards, eliminated because of safety guard to the resorbent influence of the ionic current that is produced, improved greatly and be released to airborne ion-flow rate.Disrupter, adopted the principle that regathers to negative ion, the negative ion that secondary discharges after collecting, the content of ozone is few, and after adopting plum blossom shape multi-stylus end metal electrode technology, can form the intensive medicine ion stream that is loaded with negative electricity, improve medicine ion flow-generator result of treatment of the present invention, prove that it is to the treatment of upper respiratory diseases such as trachitis, bronchitis through Clinical Laboratory, efficient reaching more than 95%.
Below we illustrate beneficial effect of the present invention with three groups of clinical experiment reports.
Gloomy safe medicine ion treatment machine treatment various respiratory tract disease patient curative effect table
The sick kind | The example number | Curative effect | |||
Recovery from illness | Produce effects | Take a turn for the better | Invalid | ||
Chronic bronchitis chronic bronchial pulmonary emphysema pulmonary heart disease bronchiectasis acute laryngopharyngitis flu allergic rhinitis sum percentage | 25 6 3 2 21 19 5 81 100% | 5 0 0 0 12 14 3 24 42.0% | 10 3 1 1 5 2 1 23 28.4% | 7 1 1 1 3 3 1 17 21.0% | 3 2 1 0 1 0 0 7 8.6% |
From table, see that this instrument treatment various respiratory tract disease has better curative effect, account for 76%, produce effects 40% as the validity of 25 routine chronic bronchitis acute infection period relief of symptoms.
50 routine airway reactivities increase the patient alleviates the mode comparison sheet for two kinds
Group | Number | The alleviation mode | Time | FEV1 | t | P |
Medicine gas is had a rest | 26 24 | Medicine ion rest natural remission | 20 minutes 20 minutes | 33.6 14.3 | 3.256 | <0.05 |
From table as can be known: alleviate the effect that airway reactivity increases with the medicine gas ion and obviously be better than the rest natural remission, pulmonary function FEV1 index (first second forced expiratory volume) is recovered comparatively fast, the percentage ratio height (33.6%) of rising.
Hence one can see that gloomy safe medicine ion therapeutic equipment is in conjunction with negative ion and the herbal medicine acute infection period to chronic bronchitis, chronic obstructive emphysema, pulmonary heart disease, bronchiectasis etc., acute pharyngolaryngitis, flu and various respiratory tract disease patient such as allergic rhinitis obtain 42.0% cure rate and 28.4% obvious effective rate and 21.0% improvement rate.Efficient 91.4%.
Airway reactivity increases in patient's 50 examples 24 examples and has a rest naturally and alleviate air flues 14.3%, 26 example that only rose in 20 minutes and with the rising 33.6% in 20 minutes of medicine gas ion alleviation air flue tangible difference (P<0.05) is arranged.Further the airway reactivity due to the prompting medicine gas ion alleviation BPT increases respond well.
Medicine air ion therapeutic equipment treatment chronic pharyngitis, acute tracheitis curative effect table
The course of disease | The example number | Curative effect | |||
Recovery from illness in the recent period | Produce effects | Take a turn for the better | Invalid | ||
The total routine hundreds of marks of chronic pharyngitis acute bronchitis | 73 26 99 100% | 18 5 23 23.2% | 36 13 49 49.5% | 19 7 26 26.3% | 0 1 1 1% |
From table, see, this machine treatment chronic pharyngitis and these two kinds of common diseases of bronchitis, frequently-occurring disease has significant curative effect, efficiently reaches 99%, and its recovery from illness near-mid term is 23.2%, transfers 49.5% significantly well to and transfers 26.3% to well.
Description of drawings
In conjunction with the accompanying drawings technical scheme of the present invention is further described again below:
Fig. 1 is a medicine ion flow-generator structural representation of the present invention, comprises pilot circuit 1, increasing apparatus 2, disrupter 3, medicine cup 4 and emission tip 5.
Fig. 2 is medicine cup 4 and quincunx emission tip 5.
Fig. 3 is quincunx emission tip 5.
Fig. 4 is a disrupter 3, comprises lead import 6 and wire outlet 7.
Fig. 5 is a disrupter 3aa ' line sectional view, comprises lead import 6 and wire outlet 7 and disrupter inwall metal level 8.
Embodiment
Embodiment 1: the nanometer additive component is weight ratio nano tourmalinite 15 grams, nano-titanium oxide 10 grams, nano zircite 5 grams and nano yttrium oxide 0.01 gram, add in the plastic raw materials, content is 2% of plastic raw materials gross weight, becomes the medicine cup with this plastic working again.This medicine cup and pilot circuit, increasing apparatus, disrupter, the plum blossom shape multi-stylus end metal electrode that contains nanometer additive formed medicine ion producer of the present invention.In the medicine cup, splash into the medicine of the treatment respiratory tract disease of 0.5ml, 123 routine diseases of respiratory system are treated, asthma 46 examples wherein, last sense 8 examples, acute bronchitis 12 examples, acute episode of chronic bronchitis 15 examples, chronic pharyngolaryngitis 18 examples, acute tonsillitis 15 examples, pneumonia 8 examples, expansion pulmonary infection 1 example.Its clinical effectiveness is as follows: 123 examples all through treating 10 times, each 25-30 minute, cured, and accounts for 30.09%, 52 routine produce effects by 38 examples, accounts for 42.3%, 28 example and take a turn for the better, and accounts for 22.3%, total effective rate 95.5%.
Embodiment 2: the nanometer additive component is weight ratio nano tourmalinite 25 grams, nano-titanium oxide 8 grams, nano zircite 8 grams and nano yttrium oxide 0.01 gram, nano oxidized Cerium 0.01 gram, add in the plastic raw materials, content is 10% of plastic raw materials gross weight, becomes the medicine cup with this plastic working again.This medicine cup and pilot circuit, increasing apparatus, disrupter, the plum blossom shape multi-stylus end metal electrode that contains nanometer additive formed medicine ion producer of the present invention.In the medicine cup, splash into the medicine of the treatment respiratory tract disease of 0.8ml, 81 routine diseases of respiratory system are treated, comprising: chronic bronchitis, chronic obstructive emphysema, chronic pulmonary heart disease, a gas expansion etc. and acute pharyngolaryngitis, flu and allergic rhinitis.Its clinical effectiveness is as follows: all through treating 2 courses of treatment, 5 days per courses of treatment, every day 2 times, each 30 minutes, 24 examples were complete, account for 42.0%, 23 routine produce effects, accounted for 28.4%, 17 example and took a turn for the better for 81 examples, and it is invalid to account for 21.0%, 7 example, accounts for 8.6%, total effective rate 76%.
Embodiment 3: the nanometer additive component is weight ratio nano tourmalinite 20 grams, nano-titanium oxide 5 grams, nano zircite 10 grams and nano oxidized Cerium 0.01 gram, add in the plastic raw materials, content is 20% of plastic raw materials gross weight, becomes the medicine cup with this plastic working again.This medicine cup and pilot circuit, increasing apparatus, disrupter, the plum blossom shape multi-stylus end metal electrode that contains nanometer additive formed medicine ion producer of the present invention.In the medicine cup, splash into the medicine of the treatment respiratory tract disease of 1ml, 99 routine diseases of respiratory system are treated, comprise; Acute bronchitis 26 examples, chronic pharyngitis 73 examples.Its clinical effectiveness is as follows: all through treating 1 course of treatment, be 10 days per course of treatment to 99 examples, and every day twice, each 30 minutes, 23 examples were complete, account for 23.2%, 49 routine produce effects, accounted for 49.5%, 26 example and took a turn for the better, and it is invalid to account for 26.3%, 1 example, accounts for 1%, total effective rate 99%.
Claims (8)
1, a kind of nanometer additive comprises nano-tourmaline, nano-titanium oxide, nano zircite, it is characterized in that also comprising at least a in nano oxidized Cerium and the nano yttrium oxide.
2, a kind of nanometer additive according to claim 1, it is characterized in that comprising that weight is: 15 ~ 25 parts of nano-tourmalines, 5 ~ 10 parts of nano-titanium oxides, 5 ~ 10 parts of nano zircites, and>0 to 1 part nano oxidized Cerium or/and>0 to 1 part nano yttrium oxide.
3, a kind of plastics is characterized in that adding that to account for the plastics gross weight be 2 ~ 20% the described nanometer additive of claim 1.
4, a kind of plastics according to claim 3 is characterized in that the weight of nanometer additive accounts for 2 ~ 10% of plastics gross weight.
5, a kind of medicine ion producer comprises increasing apparatus (2), pilot circuit (1), emission tip (5), it is characterized in that also comprising disrupter (3) and containing the medicine cup (4) that right requires 1 described nanometer additive.
6, a kind of medicine ion producer according to claim 5 is characterized in that disrupter is a sealed vessel, and container inner wall is covered with metal level (8), and the disrupter top has a wire outlet (7), and the bottom has a lead import (6).
7, a kind of medicine ion producer according to claim 5 is characterized in that emission tip is a plum blossom shape multi-stylus end electrode.
8, a kind of medicine ion producer according to claim 7 is characterized in that plum blossom shape multi-stylus end metal electrode, is platinum titanium alloy or stainless steel.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02154671 CN1283708C (en) | 2002-12-03 | 2002-12-03 | Nanometer additive and plastic and pharmaceutical ion source containing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02154671 CN1283708C (en) | 2002-12-03 | 2002-12-03 | Nanometer additive and plastic and pharmaceutical ion source containing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1504501A CN1504501A (en) | 2004-06-16 |
CN1283708C true CN1283708C (en) | 2006-11-08 |
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CN 02154671 Expired - Fee Related CN1283708C (en) | 2002-12-03 | 2002-12-03 | Nanometer additive and plastic and pharmaceutical ion source containing the same |
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CN (1) | CN1283708C (en) |
Families Citing this family (1)
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CN1317041C (en) * | 2004-10-26 | 2007-05-23 | 深圳市金士吉康复用品科技有限公司 | Ultra-fine highly effective anion powder material and its preparation method |
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2002
- 2002-12-03 CN CN 02154671 patent/CN1283708C/en not_active Expired - Fee Related
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