CN1281832A - Abrasion-resistant corundum ceramics - Google Patents
Abrasion-resistant corundum ceramics Download PDFInfo
- Publication number
- CN1281832A CN1281832A CN 99115494 CN99115494A CN1281832A CN 1281832 A CN1281832 A CN 1281832A CN 99115494 CN99115494 CN 99115494 CN 99115494 A CN99115494 A CN 99115494A CN 1281832 A CN1281832 A CN 1281832A
- Authority
- CN
- China
- Prior art keywords
- abrasion
- resistant
- corundum ceramics
- kilograms
- resistant corundum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to an abration-resistant corudum ceramic material, and its raw material formula contains calcined Al2O3 fine powder 92-95%, MgO 0.5-1%, CaO 0.5-2.5%, Cr2o3 0.5-1.5%, TiO2 0.5-1.5%, oxide of rare metal 1-1.5%, ZrO2 1-1.5%, SiO2 0.5-1.5% and additional high-temp, adhesive 3-6%. Said invention is extensive in raw material source, high in hardness, large in density and good in abrasion-resistance, toughness and resistance to impact.
Description
The present invention relates to a kind of prescription of corundum ceramic.
Corundum ceramic is because a series of good physicalies such as hardness height, high temperature resistant, wear-resistant, erosion resistant, be applied to the industrial system from the seventies in the advanced country abroad, as industrial system serious wear positions such as fuel-burning power plant, smelting iron and steel factory, mine transportations.But because corundum ceramic toughness is relatively poor, anti-impact force is weak etc., thereby external corundum ceramic is restricted in Application Areas.In order to solve or avoid the problems referred to above, external advanced country generally adopts high-grade material more to improve the wear resistance of product and toughness etc., as the SALON pottery, but, therefore also limited the widespread use in the wear-resisting system of industry of this series products because these ceramic costs are very high.
From the seventies, many universities and colleges of China and institute all begin to carry out the research of corundum ceramic.But because of grasping some gordian techniquies wherein at that time, as it is undesirable etc. to fill a prescription, and adds that research equipment does not match, as do not have the high temperature kiln about 1700 degree Celsius that therefore, product fails to reach a standard always.The early 1990s, domestic research and the production of having carried out corundum ceramic about scientific research institutions, simple 95 porcelain (95% aluminium content) are though there is certain degree of hardness but these corundum ceramics are, but wear resisting property, shock resistance are relatively poor, therefore the corundum ceramic product is used to make valve chip etc. more, fails to have breakthrough for the problem of materials at the serious position of wearing and tearing in the industries such as electric power, metallurgy, mine, light industry, chemical industry always.Therefore, high-abrasive material particularly the research of abrasion-resistant corundum ceramics just become one of difficult problem that domestic and international scientific research personnel captures with using.
Purpose of the present invention aims to provide a kind of have stronger wear resistance and shock resistance and good toughness, the abrasion-resistant corundum ceramics that hardness is high.
The objective of the invention is to realize by following manner:
Prescription of the present invention is: (by weight percentage)
Calcining Al
2O
3Micro mist 92-95% MgO 0.5-1%
CaO 0．5-2．5％ Cr
2O
3?0．5-1．5％
TiO
2The oxide compound 1-1.5% of 0.5-1.5% rare metal
ZrO
2 1-1．5％ SiO
2 0．5-1．5％
Add high-temperature agglomerant 3-6%
Wherein rare metal can be Y
2O
3Or PrO, or above-mentioned two kinds of mixing.
High-temperature agglomerant can be carboxymethyl cellulose, water glass etc.
Production process of the present invention is:
Enter factory by behind the ingredient inspection with the powdered raw material is packed, with the proportioning weighing and burden of raw material, by ball mill ball milling powdering, drying by foregoing invention.Granulate by screening, to reach best tap density.It is old to enter feed bin then, makes moisture more even, improves processability.Afterwards, can be pressed into different shape, the work in-process after the compacting are put into saggar so that burn till product according to the design requirements machine.Reinstall in the specific high temperature kiln, under the temperature about 1700 ℃, burn till about 13 hours and (contain soaking time).Finished product after burning till is taken out the kiln cooling.Product after burning till can be pieced into the definite shape size together on request so that installation and transportation.Check at last, pack, put in storage.
The technological process of production of the present invention is expressed as follows by arrow:
Old → moulding → dress alms bowl → loading of kiln that raw material powdery → packed advances the factory → check → weighing and burden → ball milling → drying → feed bin of granulating → go into → burn till → kiln discharge → piece together → check → pack → put in storage.
The present invention has overcome the deficiency that domestic and international corundum ceramic had; Has simultaneously the advantage of corundum ceramic self again.Have the hardness height, wear resisting property is good, good toughness, and anti-impact force is characteristics preferably.Raw material of the present invention Al as described
2O
3Micro mist and SiO
2, CaO, MgO, Cr
2O
3, ZrO
2Reach equal wide material sources such as high-temperature agglomerant.In prescription, add Cr2O
3, TiO
2, MgO, CaO to be to form Solid solution, reduces firing temperature, improves sintering character, adds MgO to stop grain growth, and volume density is increased, and adds SiO
2Make blank sintering functional to reduce firing temperature, porcelain base substrate stable performance and good.Add Cr
2O
3To increase blank density, improve product hardness, add ZrO
2Improve stability of the present invention and increase its toughness, add rare earth metal and improve sintering character to reduce firing temperature.
Embodiment 1:
With Al
2O
3930 kilograms of micro mists, MgO10 kilogram, CaO20 kilogram, Cr
2O
35 kilograms, TiO
25 kilograms, Y
2O
310 kilograms, ZrO
230 kilograms, SiO
215 kilograms, weighing and burden, add 5 kilograms of its Mierocrystalline celluloses of carboxylic first again after, with above-mentioned raw materials by ball mill ball milling powdering, drying.Granulate by screening, to reach best tap density.It is old to enter feed bin then, makes moisture more even, improves processability.Afterwards, can be pressed into different shape according to the design requirements machine, the compacting after work in-process put into saggar so that burn till product.Reinstall in the specific high temperature kiln, under the temperature about 1700 ℃, burn till about 13 hours and (contain soaking time).Finished product after burning till is taken out the kiln cooling.Product after burning till can be pieced into the definite shape size together on request so that installation and transportation.Check at last, pack, put in storage.
Embodiment 2:
With Al
2O
3940 kilograms of micro mists, MgO5 kilogram, CaO5 kilogram, Cr
2O
310 kilograms, TiO
25 kilograms, PrO15 kilogram, ZrO
210 kilograms, SiO
25 kilograms, weighing and burden adds 5 kilograms of its Mierocrystalline celluloses of carboxylic first again.Above-mentioned raw materials is passed through ball mill ball milling powdering, drying.Granulate by screening, to reach best tap density.It is old to enter feed bin then, makes moisture more even, improves processability.Afterwards, can be pressed into different shape according to the design requirements machine, the compacting after work in-process put into saggar so that burn till product.Reinstall in the specific high temperature kiln, under the temperature about 1700 ℃, burn till about 13 hours and (contain soaking time).Finished product after burning till is taken out the kiln cooling.Product after burning till can be pieced into the definite shape size together on request so that installation and transportation.Check at last, pack, put in storage.
The present invention can be widely used in the power industry position of serious wear in the thermoelectricity enterprise, to improve the work-ing life of unit; As coal pulverizer outlet, first and second airduct, thickness powder from device etc.; Iron and steel metallurgical industry, particularly shock resistance, anti abrasive position, and the light industry system industry etc.
Claims (3)
1, a kind of abrasion-resistant corundum ceramics is characterized in that its prescription is: (by weight percentage) calcining Al
2O
3Micro mist 92-95% MgO 0.5-1%
CaO 0．5-2．5％ Cr
2O
3?0．5-1．5％
TiO
2The oxide compound 1-1.5% of 0.5-1.5% rare metal
ZrO
2 1-1．5％ SiO
2 0．5-1．5％
Add high-temperature agglomerant 3-6 ‰
2, a kind of abrasion-resistant corundum ceramics as claimed in claim 1 is characterized in that described rare metal oxide is Y
2O
3Or PrO or both mixing.
3, a kind of abrasion-resistant corundum ceramics as claimed in claim 1 is characterized in that described high-temperature agglomerant can be carboxymethyl cellulose or water glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99115494 CN1281832A (en) | 1999-07-27 | 1999-07-27 | Abrasion-resistant corundum ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99115494 CN1281832A (en) | 1999-07-27 | 1999-07-27 | Abrasion-resistant corundum ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1281832A true CN1281832A (en) | 2001-01-31 |
Family
ID=5278440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99115494 Pending CN1281832A (en) | 1999-07-27 | 1999-07-27 | Abrasion-resistant corundum ceramics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1281832A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100372799C (en) * | 2006-07-17 | 2008-03-05 | 高振东 | High-strength compact zirconia-chromia corundum brick |
| CN101525231B (en) * | 2008-03-05 | 2011-11-16 | 邹平金刚新材料有限公司 | Process or preparing microcrystal wear-resisting alumina ceramic |
| CN102503379A (en) * | 2011-10-18 | 2012-06-20 | 陕西斯瑞工业有限责任公司 | Preparation method of ultra-low temperature curing ceramic magnetic core |
| CN102531641A (en) * | 2010-12-16 | 2012-07-04 | 淄博裕民基诺新材料有限公司 | Sintered compact aluminium oxide refractory product |
| CN101691296B (en) * | 2009-09-24 | 2012-09-05 | 中山市华山特种陶瓷有限公司 | Zircon corundum ceramics |
| CN101830710B (en) * | 2009-03-10 | 2012-10-03 | 北京嘉邦环保工程技术有限责任公司 | Ceramic anchoring piece and method for preparing same |
| CN101525230B (en) * | 2008-03-05 | 2013-03-06 | 邹平金刚新材料有限公司 | Formulation of microcrystal wear-resisting alumina ceramic |
| CN103347837A (en) * | 2011-02-15 | 2013-10-09 | 法商圣高拜欧洲实验及研究中心 | Sintered material based on doped chromium oxide |
| CN106478092A (en) * | 2015-09-01 | 2017-03-08 | 华北理工大学 | A kind of preparation method of high-intensity high-density calcium zirconate ceramics |
| CN106554194A (en) * | 2016-11-21 | 2017-04-05 | 武汉科技大学 | A kind of ceramsite sand rotary kiln liner and preparation method thereof |
| CN107266048A (en) * | 2017-06-29 | 2017-10-20 | 绵阳市美汇科技有限公司 | A kind of special, wear-resistant ceramic material |
| CN108359874A (en) * | 2018-03-02 | 2018-08-03 | 深圳市明丽达钟表有限公司 | A kind of novel artificial corundum and the wrist-watch using the Alundum |
| CN108793974A (en) * | 2018-06-25 | 2018-11-13 | 河津市锦浩特种陶瓷有限公司 | High intensity, high abrasion coffee color aluminium oxide ceramics and preparation method thereof |
| CN108863319A (en) * | 2018-06-25 | 2018-11-23 | 河津市锦浩特种陶瓷有限公司 | High-strength, high-toughness alumina is ceramic and preparation method thereof |
| CN108892489A (en) * | 2018-06-25 | 2018-11-27 | 河津市锦浩特种陶瓷有限公司 | Easy fired high alumina ceramic and preparation method thereof |
| CN108950172A (en) * | 2017-03-15 | 2018-12-07 | 王鲁洋 | A kind of experimental method that machinery welding stress is eliminated |
| CN109761590A (en) * | 2019-03-18 | 2019-05-17 | 中北大学 | A kind of high-temperature resistant aluminium oxide composite ceramic material and preparation method thereof |
| CN116063063A (en) * | 2023-02-20 | 2023-05-05 | 大城县宏大高温材料有限公司 | Erosion-resistant shaping refractory material and preparation method thereof |
| CN117417183A (en) * | 2023-12-19 | 2024-01-19 | 淄博市淄川金龙磨料磨具有限公司 | Composite corundum material and preparation method and application thereof |
-
1999
- 1999-07-27 CN CN 99115494 patent/CN1281832A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100372799C (en) * | 2006-07-17 | 2008-03-05 | 高振东 | High-strength compact zirconia-chromia corundum brick |
| CN101525231B (en) * | 2008-03-05 | 2011-11-16 | 邹平金刚新材料有限公司 | Process or preparing microcrystal wear-resisting alumina ceramic |
| CN101525230B (en) * | 2008-03-05 | 2013-03-06 | 邹平金刚新材料有限公司 | Formulation of microcrystal wear-resisting alumina ceramic |
| CN101830710B (en) * | 2009-03-10 | 2012-10-03 | 北京嘉邦环保工程技术有限责任公司 | Ceramic anchoring piece and method for preparing same |
| CN101691296B (en) * | 2009-09-24 | 2012-09-05 | 中山市华山特种陶瓷有限公司 | Zircon corundum ceramics |
| CN102531641A (en) * | 2010-12-16 | 2012-07-04 | 淄博裕民基诺新材料有限公司 | Sintered compact aluminium oxide refractory product |
| CN103347837A (en) * | 2011-02-15 | 2013-10-09 | 法商圣高拜欧洲实验及研究中心 | Sintered material based on doped chromium oxide |
| CN102503379A (en) * | 2011-10-18 | 2012-06-20 | 陕西斯瑞工业有限责任公司 | Preparation method of ultra-low temperature curing ceramic magnetic core |
| CN102503379B (en) * | 2011-10-18 | 2013-07-31 | 陕西斯瑞工业有限责任公司 | Preparation method of ultra-low temperature curing ceramic magnetic core |
| CN106478092A (en) * | 2015-09-01 | 2017-03-08 | 华北理工大学 | A kind of preparation method of high-intensity high-density calcium zirconate ceramics |
| CN106554194A (en) * | 2016-11-21 | 2017-04-05 | 武汉科技大学 | A kind of ceramsite sand rotary kiln liner and preparation method thereof |
| CN108950172A (en) * | 2017-03-15 | 2018-12-07 | 王鲁洋 | A kind of experimental method that machinery welding stress is eliminated |
| CN107266048B (en) * | 2017-06-29 | 2020-09-18 | 绵阳市美汇科技有限公司 | Special wear-resistant ceramic material |
| CN107266048A (en) * | 2017-06-29 | 2017-10-20 | 绵阳市美汇科技有限公司 | A kind of special, wear-resistant ceramic material |
| CN108359874A (en) * | 2018-03-02 | 2018-08-03 | 深圳市明丽达钟表有限公司 | A kind of novel artificial corundum and the wrist-watch using the Alundum |
| CN108793974A (en) * | 2018-06-25 | 2018-11-13 | 河津市锦浩特种陶瓷有限公司 | High intensity, high abrasion coffee color aluminium oxide ceramics and preparation method thereof |
| CN108863319A (en) * | 2018-06-25 | 2018-11-23 | 河津市锦浩特种陶瓷有限公司 | High-strength, high-toughness alumina is ceramic and preparation method thereof |
| CN108892489A (en) * | 2018-06-25 | 2018-11-27 | 河津市锦浩特种陶瓷有限公司 | Easy fired high alumina ceramic and preparation method thereof |
| CN109761590A (en) * | 2019-03-18 | 2019-05-17 | 中北大学 | A kind of high-temperature resistant aluminium oxide composite ceramic material and preparation method thereof |
| CN109761590B (en) * | 2019-03-18 | 2021-07-09 | 中北大学 | High-temperature-resistant alumina composite ceramic material and preparation method thereof |
| CN116063063A (en) * | 2023-02-20 | 2023-05-05 | 大城县宏大高温材料有限公司 | Erosion-resistant shaping refractory material and preparation method thereof |
| CN116063063B (en) * | 2023-02-20 | 2023-09-05 | 大城县宏大高温材料有限公司 | Erosion-resistant shaping refractory material and preparation method thereof |
| CN117417183A (en) * | 2023-12-19 | 2024-01-19 | 淄博市淄川金龙磨料磨具有限公司 | Composite corundum material and preparation method and application thereof |
| CN117417183B (en) * | 2023-12-19 | 2024-03-08 | 淄博市淄川金龙磨料磨具有限公司 | Composite corundum material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1281832A (en) | Abrasion-resistant corundum ceramics | |
| CN102363286A (en) | Steel blank grinding abrasion wheel adopting microcrystal ceramic bonding agents | |
| CN103848618B (en) | A kind of synthesizing ferrum-aluminium spinelle and production method thereof | |
| CN103819211A (en) | Light wear-proof and fire-proof plastic mass for circulating fluidized bed boiler and preparation method of light wear-proof and fire-proof plastic mass | |
| CN102219530A (en) | Silicon mullite brick and preparation method thereof | |
| CN101786612A (en) | TiN powder material and preparation method thereof | |
| CN1247174A (en) | High-strength antiwear ceramic sheet and its making method | |
| CN101712553A (en) | Production method of high refractorinees-under-load softening anti-strip high-alumina brick | |
| CN103951451B (en) | The manufacture method of high-strength wearable lining brick | |
| CN106904948A (en) | A kind of quasi- nano wearproof alpha-aluminium oxide ball preparation method | |
| CN102391835A (en) | Middle-sized aluminum mill ball and preparation method | |
| CN110803916A (en) | High-strength wear-resistant silicon mullite brick and preparation method thereof | |
| CN102249571A (en) | Energy-saving composite white cement | |
| CN106608727A (en) | Synthetic forsterite checker brick for glass kiln regenerative chamber and preparation method of synthetic forsterite checker brick | |
| CN105130469A (en) | Refractory material | |
| CN107973586A (en) | Handle the method and Ceramic Tiles of ferrochrome slag | |
| CN1275892C (en) | Manufacturing method of inside burning type construction gypsum | |
| CN1702054A (en) | Zirconia reinforced alumina ceramic liner | |
| CN1557713A (en) | Method for preparing aluminum oxide utilizing industrial sludge of aluminium section bar plant | |
| CN102329141A (en) | Silicon-carbide composite corundum mullite brick | |
| CN1654549A (en) | Process for preparing butyl rubber bottle stopper reinforced filling by using coals kaolin | |
| CN101691296B (en) | Zircon corundum ceramics | |
| CN101318809A (en) | Low-temperature 90% AL2O3 porcelain powder | |
| CN112745111A (en) | High-density chromium-zirconium-corundum brick for hazardous waste disposal rotary kiln | |
| CN101768004B (en) | Low-pore in situ oriental topaz brick and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |