CN1280099A - Technology for producing alumina via high alumina to silica ratio sintering process - Google Patents
Technology for producing alumina via high alumina to silica ratio sintering process Download PDFInfo
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- CN1280099A CN1280099A CN 99112306 CN99112306A CN1280099A CN 1280099 A CN1280099 A CN 1280099A CN 99112306 CN99112306 CN 99112306 CN 99112306 A CN99112306 A CN 99112306A CN 1280099 A CN1280099 A CN 1280099A
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- Prior art keywords
- stripping
- alumina
- technology
- grog
- slip
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Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000005245 sintering Methods 0.000 title claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 13
- 238000005516 engineering process Methods 0.000 title claims description 9
- 239000000377 silicon dioxide Substances 0.000 title claims description 6
- 239000011575 calcium Substances 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 7
- 238000000354 decomposition reaction Methods 0.000 claims description 6
- 229910001570 bauxite Inorganic materials 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000004571 lime Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 150000004645 aluminates Chemical class 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000029087 digestion Effects 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000005406 washing Methods 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 238000010304 firing Methods 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 238000004131 Bayer process Methods 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001648 diaspore Inorganic materials 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
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- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The present invention relates to the production of light metal, and aims at providing alkali-lime sintering process of producing alumina with high grade bauxite with Al/Si ratio 6-12. If features the pulp Al/Si ratio of 6-12, alkali content of 0.9-1.0 %, calcium content 0.8-2.5 T and Al2O3 concentration in solium aluminate solution after digestion of 130-250 g/l. The technological process has small amount of circulating material, low quantity of sludge, high efficiency and low production cost.
Description
The present invention relates to the light metal technical field of smelting.
As you know, aluminum oxide is not still produced the raw material of metallic aluminium, but also is widely used in numerous areas such as refractory materials, chemical industry, light industry.Adopt processed natural bauxite production Al more in the world now
2O
3, as the A/S of bauxite (Al in the ore
2O
3And SiO
2Weight ratio) 10 when above, generally adopts Bayer process, namely press and boil lixiviation process, and to lean ore, namely the ore of A/S＜8～10 generally adopts Bayer-sintering combination method.A/S is the bauxite of 3-5, and China through years of researches and practice, has set up the technological process of production of processing with alkali-lime sinter process.This above-mentioned flow process comprises operations such as the desiliconization of slip preparation, grog sintering, grog stripping, dissolution fluid is made with extra care, the decomposition of refining back solution, Aluminium hydroxide roasting.In the Pulp preparation operation, slip alkali is than (mol ratio) [Na
2O]/([Al
2O
3]+[Fe
2O
3]) be controlled at O.94～O.98, and calcium is than (mol ratio) [CaO]/[SiO
2] be 2.22～2.26, the alumina silica ratio Al of ore pulp
2O
3/ SiO
2(weight ratio) is generally about 4.O.Above-mentioned slip is fired in rotary kiln, 1250 ℃～1300 ℃ of firing temperatures; In grog stripping operation, there is side reaction, i.e. β-2CaO.SiO in the grog
2In process in leaching, decompose the Ca of generation (OH)
2With the Al in the solution
2O
3And SiO
2Water generation reaction fossil garnet causes a part of Al in the solution
2O
3Reenter insoluble solid phase, thereby cause Al
2O
3Loss.In order to control and to reduce above-mentioned side reaction loss, Al in the sodium aluminate solution after the stripping
2O
3Content must be controlled at below 130 grams per liters, so whole technical process has to operate in the low concentration situation, solid circulating rate strengthens.Moreover handled ore grade is low, SiO
2Content is higher, and flow process discharge waste residue amount is big.More than comprehensive, whole flow process energy consumption height, efficient is low, the production cost height.
The objective of the invention is: provide the alkali-lime sinter process technical process of a kind of processing than the bauxite of higher-grade (about A/S 6-12), the solid circulating rate of whole flow process is reduced, the waste residue amount reduces, thereby improves process efficiency, reduces production costs.
The present invention is technology for producing alumina via high alumina to silica ratio sintering process, comprise the operations such as refined liquid decomposition after solution desilicification after slip preparation, clinkersintering, grog stripping, the stripping, the desiliconization, Aluminium hydroxide roasting, main feature is: at the slip preparation process, slip A/S is controlled at 6～12, alkali is than 0.8～1.0, calcium is than 0.8～2.5, and in grog stripping operation, the sodium aluminate solution composition is after the stripping: (grams per liter) Al
2O
3130～250, Na
2O is complete 150～170, Na
2O carbon 5～20, SiO2 5～20, causticization factor alpha k 1.2～1.5.
At above-mentioned slip preparation process, the alkali ratio is preferably 0.9-1.0, and the calcium ratio is preferably 1.2-2.3.
The sodium aluminate solution alumina concentration is preferably the 160-200 grams per liter after the stripping of grog stripping operation, and α k is preferably 1.2-1.3.
Production technology of the present invention is compared with original production process, and the ore unit consumption is by 1.95 tons/ton-Al of former technology
2O
3, be down to 1.50 tons/ton-Al
2O
3Waste residue (red mud) discharge capacity is by 1.7 tons/ton-Al of former technology
2O
3, be down to 0.8 ton/ton-Al
2O
3, reduce the pollution to environment, and greatly reduced the energy consumption of alumina by sintering, improved Business Economic Benefit.
Accompanying drawing is a process flow diagram of the present invention
Comment the invention process example as follows below in conjunction with accompanying drawing:
The chemical analysis of used bauxite is (weight %): SiO
26.52, Fe
2O
33.83, Al
2O
369.1 CaO 9.10, Na
2O 0.8, K
2O 0.64, TiO
22.99, other 7.02, ore igloss 13.84%;
The main thing phase composite of used bauxite (weight %): diaspore 79.2, anatase octahedrite 3.0, kaolinite 3.4, quartz 1.2, rhombohedral iron ore 4.0, other are 9.2 years old
Used lime stone (or contain equivalent CaO lime) composition (weight %): SiO
20.84, Fe
2O
30.18, Al
2O
31.1 CaO 54.37, other are 43.51 years old
Burn till with coal chemistry composition (weight %): SiO
242.6, Fe
2O
35.9, Al
2O
331.7 CaO 6.12, other are 13.68 years old
Stripping is with adjusting liquid composition (grams per liter): Na
2O is complete 55.7, Al
2O
342.2, Na
2O carbon 10.32, Na
2The severe 45.34. of O
The slip preparation is to connect bauxite: Wingdale: industrial ground caustic (weight ratio) is 1: 0.26: 0.23 a ratio, adds bauxite, Wingdale, industrial ground caustic in the raw material mill, and allocates evaporation carbon mother liquid 1.56m into by bauxite per ton
3, slip is milled to+120 mesh sieves on residual about 10%.
Above-mentioned slip is delivered to rotary kiln and fired grog, is firing process, firing temperature: 1260--1320 ℃, material was the 0.5-1 hour chamotte kiln residence time.Gained grog composition is (weight %): SiO
25.34, Fe
2O
32.61, Al
2O
345.0 CaO 9.96, Na
2O is effective 27.8, Na
2O sulphur 2.0, SO
33.87, TiO
21.82 other are 1.6 years old.
The grog that burns till carries out stripping with adjusting liquid in the stripping wet-milling, instantly go out operation, about 80-90 ℃ of stripping temperature, dissolution fluid composition (grams per liter): Na
2O is complete 160.9, Al
2O
3206, Na
2O carbon 10.3, SiO
210, Na
2O severe 150.6.
After the grog stripping, red mud separates with filtering equipment, and solution advances desiliconization process and carries out desiliconization, 165-175 ℃ of desiliconization temperature, and 1.0 hours residence time, separate effluxing or fully utilizing processing after the solid (red mud) that obtains washs, liquid is put in order in the washing lotion auxiliary tone.
White residue separates employing filter and leaf filter, the sodium aluminate solution (Al that obtains after the separation
2O
3/ SiO
2About=330) advance the carbon operation break-down, make byproduct, the whole liquid of white residue washing lotion auxiliary tone after the white residue washing.
Sodium aluminate solution divides two sections to carry out carbonating and decompose, and first section rate of decomposition is controlled at 75-85%, and aluminium hydroxide advances the calcining process roasting and obtains the product aluminum oxide behind the separating, washing, and liquid is put in order in the washing lotion auxiliary tone.Carbon mother liquid after one section decomposition and separation continues logical carbonic acid gas and carries out degree of depth carbonating and decompose, rate of decomposition is controlled at about 95%, secondary decomposes the siliceous higher aluminium hydroxide (being called for short thick aluminium hydroxide) that obtains, separate the back and produce aluminium hydroxide with bayer process, roasting obtains the product aluminum oxide then.Secondary decomposes the carbon mother liquid that obtains and prepares burden through evaporating laggard defibrination operation.Product aluminum oxide major impurity content (weight %): SiO
20.031, Fe
2O
30.008, Na
2O 0.39.
Claims (3)
1. technology for producing alumina via high alumina to silica ratio sintering process, comprise operations such as solution decomposition after solution desilicification after slip preparation, grog sintering, grog stripping, the stripping, the desiliconization, Aluminium hydroxide roasting, it is characterized in that, described slip preparation process, slip A/S is 6～12, and alkali is than 0.9～1.0, and calcium is than 0.8～2.5, in above-mentioned grog stripping operation, the composition of sodium aluminate solution is (grams per liter): Al after the stripping
2O
3130～250, Na
2O is complete 150～170, Na
2O carbon 5～20, SiO
25～20, causticization factor alpha k 1.2～1.5.
2. according to the described technology of claim 1, it is characterized in that the alkali ratio of described slip is 0.9～1.0, calcium is than 0.8～2.4.
3. according to claim 1 or 2 described technologies, it is characterized in that after the described stripping Al in the sodium aluminate solution
2O
3Concentration is 180～220 grams per liters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991123069A CN1136150C (en) | 1999-07-09 | 1999-07-09 | Technology for producing alumina via high alumina to silica ratio sintering process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991123069A CN1136150C (en) | 1999-07-09 | 1999-07-09 | Technology for producing alumina via high alumina to silica ratio sintering process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1280099A true CN1280099A (en) | 2001-01-17 |
| CN1136150C CN1136150C (en) | 2004-01-28 |
Family
ID=5275626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991123069A Expired - Lifetime CN1136150C (en) | 1999-07-09 | 1999-07-09 | Technology for producing alumina via high alumina to silica ratio sintering process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1136150C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314591C (en) * | 2004-05-14 | 2007-05-09 | 山东铝业股份有限公司 | Process for preparing alumina by two-component sintering method |
| CN1326774C (en) * | 2004-12-03 | 2007-07-18 | 贵阳铝镁设计研究院 | Discharging method and device for non-condensable gas of pressure boiler |
| CN1333226C (en) * | 2004-11-24 | 2007-08-22 | 贵阳铝镁设计研究院 | Exhausting method and apparatus for high-pressure dissolving condenser |
| CN102092910A (en) * | 2010-12-15 | 2011-06-15 | 中国铝业股份有限公司 | Treatment method of red mud by Bayer process |
| CN102107895A (en) * | 2010-12-22 | 2011-06-29 | 昊青薪材（北京）技术有限公司 | Improved soda lime sintering method for processing aluminum-containing raw material |
| CN102432035A (en) * | 2011-08-31 | 2012-05-02 | 昊青薪材（北京）技术有限公司 | Sodium calcium aluminosilcate slag alkali recovery process |
| CN104591241A (en) * | 2015-02-04 | 2015-05-06 | 河北科技大学 | Lime sintering treatment method and clinker prepared by same |
| CN104649305A (en) * | 2013-11-21 | 2015-05-27 | 神华集团有限责任公司 | Magnesium oxide roasting method for extracting aluminium |
| CN104649304A (en) * | 2013-11-21 | 2015-05-27 | 神华集团有限责任公司 | Alkaline aluminum extraction and dealkalized red mud obtaining method and dealkalized red mud obtained and application of dealkalized red mud |
-
1999
- 1999-07-09 CN CNB991123069A patent/CN1136150C/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314591C (en) * | 2004-05-14 | 2007-05-09 | 山东铝业股份有限公司 | Process for preparing alumina by two-component sintering method |
| CN1333226C (en) * | 2004-11-24 | 2007-08-22 | 贵阳铝镁设计研究院 | Exhausting method and apparatus for high-pressure dissolving condenser |
| CN1326774C (en) * | 2004-12-03 | 2007-07-18 | 贵阳铝镁设计研究院 | Discharging method and device for non-condensable gas of pressure boiler |
| CN102092910A (en) * | 2010-12-15 | 2011-06-15 | 中国铝业股份有限公司 | Treatment method of red mud by Bayer process |
| CN102107895A (en) * | 2010-12-22 | 2011-06-29 | 昊青薪材（北京）技术有限公司 | Improved soda lime sintering method for processing aluminum-containing raw material |
| CN102107895B (en) * | 2010-12-22 | 2013-05-22 | 昊青薪材（北京）技术有限公司 | Improved soda lime sintering method for processing aluminum-containing raw material |
| CN102432035A (en) * | 2011-08-31 | 2012-05-02 | 昊青薪材（北京）技术有限公司 | Sodium calcium aluminosilcate slag alkali recovery process |
| CN104649305A (en) * | 2013-11-21 | 2015-05-27 | 神华集团有限责任公司 | Magnesium oxide roasting method for extracting aluminium |
| CN104649304A (en) * | 2013-11-21 | 2015-05-27 | 神华集团有限责任公司 | Alkaline aluminum extraction and dealkalized red mud obtaining method and dealkalized red mud obtained and application of dealkalized red mud |
| CN104649304B (en) * | 2013-11-21 | 2016-06-15 | 神华集团有限责任公司 | A kind of alkali method is carried aluminium and is obtained dealkalize red mud and the application thereof of the method for dealkalize red mud and acquisition |
| CN104649305B (en) * | 2013-11-21 | 2016-09-21 | 神华集团有限责任公司 | A kind of method that magnesium oxide roasting carries aluminum |
| CN104591241A (en) * | 2015-02-04 | 2015-05-06 | 河北科技大学 | Lime sintering treatment method and clinker prepared by same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1136150C (en) | 2004-01-28 |
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Owner name: CHINESE ALUMINIUM CO., LTD. Free format text: FORMER OWNER: SHANDONG ALUMINIUM INDUSTRIAL CORP. Effective date: 20040820 |
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Effective date of registration: 20040820 Address after: 100814 No. 12, Fuxing Road, Beijing, Haidian District Patentee after: Aluminum Corporation of China Limited Address before: 255051 No. 1, five km road, Zhangdian District, Shandong, Zibo Patentee before: Shandong Aluminium Industry Co. |
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Granted publication date: 20040128 |