CN1279063A - Detergent composition - Google Patents
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- CN1279063A CN1279063A CN00120152A CN00120152A CN1279063A CN 1279063 A CN1279063 A CN 1279063A CN 00120152 A CN00120152 A CN 00120152A CN 00120152 A CN00120152 A CN 00120152A CN 1279063 A CN1279063 A CN 1279063A
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- grease
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- scavenger
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
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- Veterinary Medicine (AREA)
- Public Health (AREA)
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- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
A two part cleansing and oily soil removing composition comprising:a) a first part containing an aqueous domain containing one or more surface active agent(s) selected from anionic, nonionic, amphoteric, zwitterionic and cationic surface active agents, soap and mixtures thereof, wherein the surfactnt containing composition contains an effective amount of a short chain polyol oily soil remover; and b) a second part containing an aqueous or non-aqueous domain containing one or more agent(s) for removing oily soil, the non-aqueous domain being in a non-emulsified state; wherein the domains are greater than 1000 microns in size and are separate but combinedly dispensable from a single packaging means as discrete domains.
Description
The present invention relates to be fit to the composition of detergent of topical application, be used to clean and remove the grease on the human body, especially for the cosmetics of removing on the skin.Exactly, the present invention relates to mainly the compositions of effectively removing cosmetics from face, it brings clean, the salubrious dermal sensation relevant with the expansion type cleaning agent usually.
Know in order to the compositions of removing the cosmetics on the skin.They generally contain the solvent of high concentration, and greasepaint for example, this solvent effectively penetrate and disperse to constitute the wax of cosmetics dirt and the oil reservoir of pigment particles.These class cosmetics are removed compositions and be can be designed as wipe-off type, for example use cotton sheet, perhaps can be designed as washing and remove type, can also contain surfactant under latter instance, so that the emulsifying altogether of cosmetic base and solvent naphtha.
But, it is found that usually that the aftersensation that the cosmetics scavenger that is mixed with oil or Water-In-Oil or emulsion oil-in-water is left skin for is oily.In flushing process, that they also are tending towards non-foaming or produce few foam.Consumer is clean, salubrious dermal sensation after having a preference for cleaning substantially.In order to reach this requirement, often need carry out dual clean, especially changed the situation that heavy make-up is arranged.
Conventional expansion type cleaning agent, for example known soap slab, facial cleanser, bath mix the i.e. abundant foam of generation with foam, shampoo and bath gel with water, remove the light dirt (for example sebum) on the skin surface, leave the clean and salubrious sensation of skin for.But, this series products is tending towards quite invalid on weight dirts such as removing cosmetics, also may produce significant drying effect to skin.
Novel " 2 the close 1 " cleaning agent of one class has appearred in recent years, is known as to combine effective cosmetics removing effect and easy washability, foaming characteristic and the common advantages such as dermal sensation relevant with the expansion type cleaning agent.The reason that these products do not win the staple market share is the result of the compromise of having to take in their preparation.Usually can not remove cosmetics fully from the face of routine with known " 2 close 1 " cleaning agent that foam obtains, simultaneously, remove those " 2 close 1 " cleaning agent that preparation obtains from the cosmetics of routine and then can not bring thoroughly clean, salubrious dermal sensation.
It also is known preparing another kind of " 2 close 1 " product, and this product both provided cleaning effect mutually by different products, and moisturizing effect is provided again.For example, WO 96/02230 discloses the compositions that comprises a kind of surfactant and a kind of effective agent (benefit agent), wherein this surfactant and effective agent are isolating, are assigned as discontinuous zone but can unite from single packing device with predetermined ratio.Effectively agent separates the deposition that allegedly can improve effective agent with surfactant.But, WO 96/02230 relates generally to be with a kind of electrodeposition substance on skin, and the present invention will reach the opposite effect of removing the material on the skin.
The problem that this class dual purpose compositions can run into usually is the removing concentration of component deficiency that they contain, or the effective dose deficiency when using, so that dirty scavenging action is not gratifying to weight such as for example cosmetic compositions.
Another problem relevant with moistening dual function compositions or dirt removal compositions with this class cleaning is unstability.WO 94/03152 relates to the bath gel that comprises on-soap detergent, silicone oil and cationic polymer, and according to the document, if keep product stability, the maximum average droplet size of operable silicone oil is 2 microns.But, the notion of stability is prolonged and the various aspects of preparation, comprises dyestuff and antimicrobial stability, and importantly product does not show any rotten sign through storage after a while.
Another problem that may be relevant with the prior art Cleasing compositions is their low foaminq power.High-caliber foaming and good quality, froth are the important attribute of profound influence user to the sensation of product quality and effect.
We have found that a kind of method of preparing this based composition, make them can bring effective grease to remove effect, particularly good cosmetics are removed effect, still produce the sensation relevant with the expansion type cleaning agent simultaneously.
We further find, cleaning can be improved by a kind of compositions is provided with the stability of dirt removal dual function product and the release and the effect of scavenger, cleaning is isolating with removing component in the said composition, is assigned as discontinuous zone but can unite from single packing device.
Therefore according to a first aspect of the invention, provide the cleaning of two parts and grease to remove fluid composition, comprised:
A) contain the first of a water zone, one or more surfactants are contained in this zone, be selected from anion, nonionic, both sexes, amphion and cationic surface active agent, soap class and their mixture, the compositions that wherein contains surfactant contains the short chain polyhydric alcohol grease scavenger of effective dose; With
B) contain the second portion of a moisture or non-aqua region, one or more reagent that is used to remove grease is contained in this zone, and described moisture or non-aqua region is non-emulsified state;
Wherein these two parts provide size greater than 1000 microns zone, and these two parts are isolating, are assigned as discontinuous zone but can unite from single packing device.
Said composition is applicable to thorough cleaning skin.Be included in grease scavenger in the compositions in order to remove the grease on the skin, for example cosmetics.
The present invention also provides and has utilized above-mentioned cleaning and grease to remove the method that compositions improves the scavenging action of skin grease, and this method comprises:
ⅰ) allocation table surface-active agent and the reagent that is used to remove grease from packing device;
ⅱ) reagent of surfactant and being used to being removed grease spreads upon human body; With
ⅲ) mixture of gained grease and cleaning agent is removed in the water flushing.
The present invention is further also providing the band of suitable partial smearing and use to pack Cleasing compositions in the embodiment.The packing that is applicable to this embodiment of the present invention is preferably a kind of multicell packing, for example two Room packing.
Advantage of the present invention is the effect of the aqueous liquid composition by containing surfactant in use, very well removes grease.Particularly have been found that, containing the short chain polyhydric alcohol grease scavenger that comprises relatively small amount in the surfactant part a kind of like this compositions can be provided in two part compositionss, it has excellent cosmetics and removes effect, but some shortcoming, the particularly shortcoming of relevant composition stable of existing two partial foaming type Cleasing compositions have been avoided.
And have been found that, it is compatible containing the preferred surfactant that uses preferred short chain polyhydric alcohol grease scavenger in the surfactant part and be used in the compositions in first of compositions, and the latter comprises alkyl polyglucoside, MAP and their mixture.
Do not accept opinion and limit, it is believed that to be distributed in the relatively large drop in the wiping process of grease scavenger when compositions is used in the compositions second portion that these drops are easy to remove the grease on the skin, for example cosmetics.By to short chain polyhydric alcohol grease scavenger with join the amount that first of compositions contains the short chain polyhydric alcohol in the surfactant part and suitably select, contain at the former under the situation of water unmixability component, needn't utilize emulsifying technology to prepare initial compositions.In addition, it is believed that from the relatively large grease scavenger drop of compositions second portion more more effective than less relatively emulsion droplet when removing grease, the former generates in the wiping process of compositions on the spot, and the grease removing is separated into single phase mutually or the zone can help its generation.
Cosmetics film to high local concentrations discharges potent agent, can strengthen the removing effect of cosmetics.Relatively large drop then in use size reduce, however owing to smear used wiping action in the process, so help it to be dissolved as decentralized photo in mutually at the aqueous surfactant of compositions.
Use the particular type grease scavenger of relatively small amount to have been found that the elimination efficiency that can further improve cosmetics at surfactant in mutually, avoid simultaneously being considered in the past comprising that when existing shortcoming when containing surfactant and add the grease scavenger in mutually first of compositions contains the stability of surfactant part.The existence of grease scavenger also finds to help first of compositions to contain other attributes of surfactant part in the compositions, comprises physics and antimicrobial stability.
The suitable strip form of taking first and second part compositions in each zone according to compositions of the present invention, suitable from the packing of two Room side by side co-extruded come out (promptly, do not mix), first and second part of compositions is housed in the isolating chamber standby in the mode that is isolated from each other.
The present invention also provides additional advantage, and these advantages are not inevitable relevant with effect itself, but with avoid the instable problem of preparation and bring other benefits of consumer relation is more arranged, comprising:
(a) incompatibility of preparation composition may cause in the storage unstability with separate, can avoid this incompatibility by making the distribution in different zones of each composition;
(b) system of two kinds of different structures can be used to provide best product viscosity, consumer's sensation and each regional outward appearance, and this structural system is more suitable for each regional requirement;
(c) two kinds of different corrosion protection systems can be used for each regional optimum stabilization, and this corrosion protection system is more suitable for each regional requirement;
(d) similarly, two kinds of dyes/pigments systems in each zone can bring benefit to consumer, for example strengthen product and are effective and real 2 and close the such conception of species of 1 product;
(e) the preparation composition can be kept in the separate areas, when using, mix, reaction produces the perceptible sensation of consumer, for example when containing surfactant part and containing heating, viscosity or the cosmetic variation of grease when partially mixed, particularly mixed compositions is thinning, improve the distribution of compositions on skin, improved the removing effect of grease;
(f) anyly can be kept at one to the light activated material of UV and have the indoor of UV filter capacity, save UV and filtered and packaged quantitative cost; With
(g) use of multicell packing rather than single chamber packing can reduce the path that light passes product, thereby has improved external transparency.
The each other volume ratio of first and second parts of compositions in topical compositions can be 20: 80 to 80: 20 usually, is preferably 60: 40 to 40: 60.For convenient and package arrangement for simplicity, topical compositions comprised, and first to contain the volume ratio that surfactant part and second grease remove partly each other be 50: 50.
The surfactant that is included in the composition comprises water zone can be selected from the known surfactant that is applicable to the partial smearing human body arbitrarily.Particularly preferably be gentle surfactant, just do not damage skin outer layer, cuticular surfactant.
The anionic detergent that is suitable for comprises the fatty acyl group isethionate of following formula:
RCO
2CH
2CH
2SO
3M
Wherein R is the alkyl or alkenyl of 7 to 21 carbon atoms, and M is a soluble cation, for example the ammonium of sodium, potassium, ammonium or replacement.Preferably, 3/4 RCO group has 12 to 18 carbon atoms, can derive from Cortex cocois radicis, Petiolus Trachycarpi or Cortex cocois radicis/Petiolus Trachycarpi admixture.
Other preferred anionic surfactants detergents are alkyl ether sulfates of following formula:
RO(CH
2CH
2O)
nSO
3M
Wherein R is the alkyl of 8 to 22 carbon atoms, and n is 0.5 to 10, especially 1.5 to 8, and M is as the defined soluble cation of preamble.
Other possible anionic detergents comprise alkyl glycerol ether sulfate, sulfosuccinate, taurate, sarcosinate, sulfosalicylic acetate, phosphate, phosphate ester and ethoxylation phosphate; Acyl-lactate, glycinate, alanine salt and glutamate, Glu; With their mixture.
Sulfosuccinate can be the monoalkyl sulfosuccinate of following formula: R
5O
2CCH
2CH (SO
3M) CO
2M; The acylamino-of following formula-MEA sulfosuccinate: R
5CONHCH
2CH
2O
2CCH
2(SO
3M) CO
2M; R wherein
5Be C
8-C
20Alkyl is preferably C
12-C
15Alkyl, M are soluble cations.
Sarcosinate generally is shown below: R
5CON (CH
3) CH
2CO
2M, wherein R
5Be C
8-C
20Alkyl is preferably C
12-C
15Alkyl, M are soluble cations.
Taurate generally is shown below: R
5CONR
6CH
2CH
2SO
3M, wherein R
5Be C
8-C
20Alkyl is preferably C
12-C
15Alkyl, R
6Be C
1-C
4Alkyl, M are soluble cations.
Amino acid surfactant comprises acyl group alanine salt, acylglycine salt and acyl glutamate, is shown below:
Alanine salt:
Wherein R is the alkyl or alkenyl of 7 to 21 carbon atoms, and M is a soluble cation, for example the ammonium of sodium, potassium, ammonium or replacement.Acyl group alanine salt can obtain from the L-alanine:
Or from
Alanine obtains:
Glycinate:
Wherein R is the alkyl or alkenyl of 7 to 21 carbon atoms, and M is a soluble cation, for example the ammonium of sodium, potassium, ammonium or replacement.
Glutamate, Glu:
Wherein R is the alkyl or alkenyl of 7 to 21 carbon atoms, and M is a soluble cation, for example the ammonium of sodium, potassium, ammonium or replacement.
Generally avoid using thick surfactant, for example uncle's alkyl sulfonate or alkylbenzenesulfonate.
If surfactant comprises soap, this soap is preferably from having C
8To C
22The material of saturated basically carbochain obtains, and is preferably to have C
12To C
18The potassium of carbochain or triethanolamine soap.
Preferably joining the anionic species that first of compositions contains in the surfactant part is alkyl poly glucoside surfactant, monoalkyl and/or dialkyl group phosphate surfactant active and their mixture.
The nonionic surfactant that is suitable for comprises ethoxylate, the especially C of alkyl polysaccharide, lactose amide, glycol ester, glycerol monoethers, polyhydroxy amides (glucamide), primary alconol and secondary alcohol
8-20Aliphatic alcohol ethoxylate, every mol of alcohol on average have 1 to 20 moles of ethylene oxide.
The amphoteric surfactant that is suitable for comprises the alkyl hydroxyethyl imidazoline derivant, and for example alkyl both sexes acetate, alkyl both sexes propionate, alkyl both sexes diacetin and alkyl both sexes dipropionate are shown below:
With
Wherein R is the alkyl or alkenyl of 8 to 20 carbon atoms, and n is 1 or 2, and M is a soluble cation, for example the ammonium of sodium, potassium, ammonium or replacement.
Also can use any above-mentioned surfactant mixtures.
Surfactant concentrations is preferably 10 to 80wt% in the compositions, and more preferably 20 to 50wt%, contains surfactant partly in first of compositions.
Also preferably compositions comprises that 1 to 20wt% has the cosurfactant of foaming facilitation or the gentle effect of skin, contains surfactant partly in first of compositions.The material that is suitable for is the amphoteric ion type detergent, and the alkyl or alkenyl that they have 7 to 18 carbon atoms satisfies the general construction formula:
R wherein
1Be the alkyl or alkenyl of 7 to 18 carbon atoms, R
2And R
3Be alkyl, hydroxy alkyl or the carboxyalkyl of 1 to 3 carbon atom independently of one another;
M is 2 to 4;
N is 0 or 1;
X is the alkylidene of 1 to 3 carbon atom, is optionally replaced by hydroxyl;
Y is-CO
2 -Or-SO
3 -
The amphoteric ion type detergent that satisfies above-mentioned general formula comprises the simple betanin of following formula:
Amido betaines with following formula:
Wherein m is 2 or 3.
In two formulas, R
1, R
2And R
3Be defined as preamble.
R particularly
1Can be the C that derives from Cortex cocois radicis
12With C
14The mixture of alkyl makes at least half, is preferably 3/4 radicals R
1Have 10 to 14 carbon atoms.R
2And R
3Be preferably methyl.
Further probability is the sulfobetaines of following formula:
Or
Wherein m is 2 or 3, or their variant, wherein-(CH
2)
3SO
3Quilt
Replace the R in these formulas
1, R
2And R
3Be defined as preamble.
The short chain polyhydric alcohol grease scavenger that the surfactant part also comprises relative low concentration that contains according to of the present invention pair of part compositions.The short chain polyhydric alcohol grease scavenger that is suitable for preferably contains at least two polyhydric alcohol groups, and carbon chain lengths is C
4Or below, molecular weight is less than about 100.
Particularly preferred polyhydric alcohol grease scavenger comprises propylene glycol and glycerol, especially propylene glycol.
The effective dose of this class short chain grease reagent is about 0.5 to about 15wt% in the first surface activating agent of the topical compositions part, is preferably 3 to 15wt%, contains surfactant partly in first of compositions.The concentration of preferred in some cases short chain polyhydric alcohol grease scavenger is 10 to 15wt%, although in some cases, when the concentration of short chain polyhydric alcohol grease scavenger is higher than approximately 12% the time, unwanted reduction may take place the viscosity of compositions.Under these concentration, find that the cosmetics elimination efficiency of two part compositionss has improved, but can not cause the side effect relevant with the stability of compositions surface active agent composition.The compositions that contains the short chain polyhydric alcohol grease scavenger of these concentration also can help the physical stability of compositions, has both comprised the stability under high temperature and the low temperature, also comprises the stability at any dyestuff that may exist.
Particularly when this short chain grease scavenger is propylene glycol, have been found that, if in the compositions concentration of propylene glycol greater than about 6wt%, be preferably 10% or more than, contain surfactant partly in first of compositions, then help to contain the antimicrobial stability of surface activator composition.When propylene glycol be used as first contain in the Surfactant part the grease scavenger time, also find to help the stability of this part compositions, particularly under the situation of using the preferred anionic surfactants surfactant, i.e. alkyl polyglucoside, list and/or dialkyl group phosphate or their mixture.
It is most preferred that the phase that contains surfactant does not contain any Polyethylene Glycol, perhaps contain at least and be less than about 10wt%, be preferably the Polyethylene Glycol that is less than 5wt%, contain the part of surfactant in compositions.Have been found that, disadvantageous reaction can take place with other components that contain in the surface activator composition in them, particularly under the situation of utilizing list and/or dialkyl group phosphate surfactant active, alkyl poly glucoside surfactant or their mixture, the stability to compositions has a negative impact thus.Find that also Polyethylene Glycol and a lot of dyestuffs also may be inconsistent, and these dyestuffs are need be included in the part that contains surfactant.
Preferably liquid or solution of used scavenger can comprise straight or branched hydrocarbon (for example mineral oil, 2-Methylpentadecane), ester (for example isopropyl palmitate), silicone (for example Cyclomethicone), natural or synthetic triglyceride (for example Oleum Ricini, sunflower oil, macadimia nut core oil, glycerol three (2-ethylhexanoate)) and plant extract (for example Hamamelis virginiana, Centaurea cyanus extract) in the second portion according to of the present invention pair of part compositions.
But, scavenger is suitable comprises:
A) polymerized polyalcohol, for example Polyethylene Glycol (for example PEG 200-600);
B) polyhydric alcohol, for example propylene glycol, glycerol and sorbitol;
C) solvent, for example ethanol;
D) nonionic surfactant of HLB value＜10; With
F) their mixture.
Particularly preferred scavenger comprises propylene glycol and glycerol in the second portion.Preferred scavenger is the mixture of propylene glycol and glycerol in the compositions second portion, ratio each other is preferably 1: 3 to 3: 1, under this ratio, can obtain best cosmetics and remove effect, find also that simultaneously such compositions has good stable, especially the stability under the low temperature.
0 to 70% water also can be contained in the zone that comprises scavenger.Can also contain one and dash or multiple hydrophilic surfactant active, its objective is that promotion forms emulsion oil-in-water in last rinsing step process, but a kind of like this emulsion is not present in the zone of being prepared.
The content of scavenger is preferably 1 to 70wt%, most preferably is 5 to 60wt% in the total composition, and then 30-55wt% more preferably, in the scavenger of compositions partly.
One preferred aspect, it is surfactant to the electrolyte sensitivity that compositions contains used surfactant in the surfactant part, and the grease scavenger of compositions partly contains a kind of electrolyte, the surfactant part of thinning compositions when mixing is provided thus, and assist to remove grease in the above described manner.
Another preferred aspect of the present invention is that the part that compositions contains surfactant contains silicon dioxide, and its mean diameter should be greater than 10 microns.Preferred silica concentration is 3 to 15%, more preferably 5 to 12%, the best is about 10%, contains the weight of surfactant part in compositions.Have been found that compositions contains that big silica concentration under this level helps the cosmetics of compositions to remove ability in the surfactant part, but higher concentration can weaken the processing characteristics of compositions.
Also can in the second grease scavenger part of compositions, add nearly silicon dioxide with concentration.
Other fine powders, for example particle diameter also can be included in the topical compositions valuably greater than 10 microns micronization polyethylene.
Preferably contain the short chain monocarbon alcohol of relative low concentration according to compositions of the present invention, ethanol for example makes that the viscosity of compositions is unlikely to fall lowly excessively.Preferably, compositions contains gross weight and is less than 5% short chain monocarbon alcohol, although in some cases, the existing of a small amount of short chain monocarbon alcohol (for example 2% or more than) can help the antimicrobial properties of compositions.
Other optionally composition comprise structure agent or thickening agent, they can join mutually or in biphase of compositions, keep the stability in the storage, and distribute and use in suitable viscosity is provided.
The material of the moisture foaming surfactant phase of structure that is suitable for comprises the electrolyte that can bring out surfactant micelle size or geometric change; Can tolerate the water-soluble polymer of surfactant; And inorganic matter, for example clay or amorphous silica.
Be used in second the selection of preferred thickener in mutually that comprises scavenger depend on this be mutually aqueous also be (for example, it is to be substrate with oil or to be substrate with the polyhydric alcohol) of non-water.The thickening agent that is applicable to hydrated matrix phase or polyhydric alcohol matrix phase comprises hydrophilic polymer, inorganic matter and their mixture.The thickening agent that is applicable to the oil matrix phase comprises oil-soluble polymers, wax and inorganic matter, and particularly those are through hydrophobically modified person.
" international cosmetic composition handbook (International cosmetic IngredientDictionary) the 5th edition other examples that provided structure agent and thickening agent in 1993, this book is by CTFA (cosmetics, toilet articles and fragrance association (The Cosmetic, Toiletry ﹠amp; FragranceAssociation)) publish, quote as a reference at this.
Other typical components of this based composition can preferably include opacifier, are preferably 0.05 to 0.5wt%; Antiseptic is preferably 0.05 to 1.0wt%; And essence, be preferably 0.1 to 0.5wt%.
About the physics performance according to compositions of the present invention, an essential feature of the present invention is that grease is removed solution and moisture foaming surfactant solution is isolating, distributes but can unite from packing device.Usually, the latter can be single packing device.A kind of like this packing device comprises the system that comprises two or more chambers.
Known in the art have a large amount of these class packing devices, comprises push and pull pump formula allotter and two sleeve pipes, they can be assembled into side by side the chamber or one be enclosed within another the inside.Instantiation comprises United States Patent (USP) 5020694 described multi-chamber distribution containers and United States Patent (USP) 4964539 described multi-chamber tubes.
It is most preferred that aqueous surfactant and scavenger can be distributed from single packing device, for example according to the difference of the application target of compositions, the two becomes predetermined ratio.The advantage of associating allocation table surface-active agent and scavenger is to have avoided two kinds of components to carry out the blended inconvenience in back.When need be with the separation component of compositions in order to reach required effect during with accurate mixed, this point be particularly advantageous.
Though in the preferred case, single packing device can comprise two chambers, wherein contains aqueous surfactant and grease scavenger respectively, but the number of chamber is more also to be possible, and one-chamber system even also it is contemplated that.
For example, in one-chamber system, can become the present composition discontinuity zone be the isolating striped of surfactant and scavenger, perhaps a kind of reagent is suspended in the drop in the another kind of reagent, the department choosing ground form to seal.
Another kind guarantees that surfactant and the isolating method of scavenger relate to by coextrusion or injection the separated region of compositions is packed in the single chamber packing that to form hanging drop or striped product, wherein each striped or drop contain surfactant or scavenger.
The suitable skin cleaning product that is mixed with of the present composition, for example face is used or the hands cleaning compositions, but they also can be mixed with bathing or bathe and use gel or hair washing product.
The present composition generally can be dumpable liquid or semiliquid, for example colloid or paste.
Embodiment
With reference to following non-limiting examples will the present invention is further elaborated.
Following compositions represents a part according to topical compositions of the present invention.The topical compositions first that compositions 1-5 representative is fit to contains the part of surfactant, and the compositions second that compositions 6-10 representative is fit to contains the part of grease scavenger.The each several part of topical compositions is suitable for mixing, is packaged in the bitubular packing and therefrom distributes, and this packing is above-mentioned United States Patent (USP) 5020694 or 4964539 described general types.
Compositions can be utilized prepared well known in the art.For example, concerning surface activator composition, will mix, add silicon dioxide and polyethylene powders then, under vacuum, mix except that the composition component silicon dioxide, polyethylene powders, essence and the antiseptic.At last, add essence and antiseptic and mixing.Concerning second portion, acrylate copolymer can be dispersed in the water with high shear, under agitation add grease scavenger and antiseptic, form uniform disperse system.Can under vacuum, stirring, add all the other components then.
Each component can be divided in the cell of dual compartment package then, distribute this two parts compositions with equal-volume.
| Embodiment | 1 | 2 | 3 | 4 | 5 |
| Alkyl androstanediol (1) | 20 | 20 | 20 | - | - |
| Lauryl phosplate (2) | 40 | 38 | 30 | - | - |
| Cocoyl amido propyl dimethylglycine solution (3) | 2．0 | 1．0 | 2．0 | - | - |
| SLES | - | - | - | 30 | 40 |
| CAPB | - | - | - | 10 | 10 |
| Propylene glycol | 12 | 10 | 8 | 8 | 10 |
| Glycerol | - | - | 2 | - | 5 |
| Silicon dioxide | 10 | 10 | 5 | 8 | 10 |
| Polyethylene powders | 2．0 | 2．0 | 2．0 | 5．0 | 1．0 |
| Polyoxyethylene (160 EO) anhydro sorbitol three isostearates (4) | 0．5 | 0．5 | 0．5 | 0．5 | 0．5 |
| Ethylenediaminetetraacetic acid (edentate) four sodium | 0．05 | 0．05 | 0．05 | 0．05 | 0．05 |
| Methyl parahydroxybenzoate | 0．5 | 0．5 | 0．5 | 0．5 | 0．5 |
| Water | Add to 100 | ||||
(1) Mydol 12, available from Kao company
(2) Priory B-300D is available from Kao company
(3) Nissan Anon BDF-H is available from NOF company
(4) Rheodol TWIS399C is available from Kao company
| Embodiment | 6 | 7 | 8 | 9 | 10 |
| Alkyl acrylate cross-linked polymer | 0．6 | 0．4 | 0．5 | 0．4 | 0．6 |
| Propylene glycol | 10 | 20 | 24 | 16 | 30 |
| Glycerol | 40 | 30 | 24 | 32 | 20 |
| Methyl parahydroxybenzoate | 0．3 | 0．2 | 0．1 | 0．3 | 0．2 |
| No. 201 green (dyestuff) | ????0．0005 | ||||
| Disodiumedetate | ????0．05 | ||||
| KOH | ????0．1 | ||||
| Polyoxyethylene | ????0．3 | ||||
| Polyoxypropylene 2 decyls, four decyl ethers (5) | ????0．3 | ||||
| Essence | ????1．0 | ||||
| Water | Add to 100 | ||||
(5) PEN-4630 is available from Nikko Chemicals company
Claims (29)
1, the cleaning of two parts and grease are removed compositions, comprise:
A) contain the first of a water zone, one or more surfactants are contained in this zone, be selected from anion, nonionic, both sexes, amphion and cationic surface active agent, soap class and their mixture, the compositions that wherein contains surfactant contains the short chain polyhydric alcohol grease scavenger of effective dose; With
B) contain the second portion of a moisture or non-aqua region, one or more reagent that is used to remove grease is contained in this zone, and described non-aqua region is non-emulsified state;
Wherein the size of above-mentioned zone is assigned as discontinuous zone but can unite greater than 1000 microns and be isolating from single packing device.
2, according to the compositions of claim 1, wherein this single packing device comprises two isolating chambers.
3, according to the compositions of claim 1 or 2, one of wherein said zone is the form of microencapsulation.
4, the compositions any according to aforementioned claim, distribution can be united with predetermined ratio in wherein said zone.
5, the compositions any according to aforementioned claim, the reagent that wherein is used to remove grease is selected from polymerized polyalcohol; Polyhydric alcohol; Size is greater than 10 microns solid particulate matter; Solvent; The nonionic surfactant of HLB value＜10; With their mixture.
6, the compositions any according to aforementioned claim, wherein first of said composition contains surfactant and partly contains a kind of surfactant to the electrolyte sensitivity, and the second grease scavenger of compositions partly contains a kind of electrolyte.
7, according to the compositions of claim 6, wherein contain surfactant part and second grease and remove when partially mixed in first of compositions, compositions is thinning.
8, the compositions any according to aforementioned claim, wherein the concentration of the short chain polyhydric alcohol grease scavenger that contains in the surfactant of the said composition part is 0.5 to 15%, contains the weight of surfactant part in compositions.
9, the compositions any according to aforementioned claim, wherein this short chain polyhydric alcohol grease scavenger has at least two polyhydric alcohol groups.
10, the compositions any according to aforementioned claim, wherein the molecular weight of this short chain polyhydric alcohol grease scavenger is less than 100.
11, the compositions any according to aforementioned claim, wherein the carbon chain lengths of this short chain polyhydric alcohol grease scavenger is C
4Or below.
12, the compositions any according to aforementioned claim, wherein this short chain polyhydric alcohol grease scavenger is propylene glycol or glycerol.
13, the compositions any according to aforementioned claim, wherein this anion surfactant is a kind of single alkyl phosphonic acid salt surfactant.
14, the compositions any according to aforementioned claim, wherein the said composition part that contains surfactant contains the Polyethylene Glycol that is less than 10wt%.
15, according to the compositions of claim 14, wherein said composition does not contain Polyethylene Glycol.
16, the compositions any according to aforementioned claim, wherein the said composition second portion of removing grease comprises propylene glycol and glycerol.
17, according to the compositions of claim 16, wherein the ratio of propylene glycol and glycerol is 1: 3 to 3: 1.
18, the compositions any according to aforementioned claim comprises 3 to 15% silicon dioxide in addition, contains the weight of surfactant part in first of compositions.
19, the compositions any according to aforementioned claim contains and is less than 5% short chain monocarbon alcohol, with general composition weight meter.
20, the compositions any according to aforementioned claim, wherein this reagent that is used to remove grease is with a kind of thickening agent thickening.
21, the compositions any according to aforementioned claim, wherein the second grease scavenger of said composition partly comprises 1 to the 70wt% reagent that is used to remove grease, in second portion weight.
22, the compositions any according to aforementioned claim, wherein this grease is cosmetics.
23, the compositions any according to aforementioned claim, wherein this water zone that contains surfactant is with a kind of thickening agent thickening.
24, utilize any described cleaning of aforementioned claim and grease to remove the method that fluid composition improves the scavenging action of skin grease, this method comprises:
ⅰ) allocation table surface-active agent and the reagent that is used to remove grease from packing device;
ⅱ) reagent of surfactant and being used to being removed grease spreads upon human body; With
ⅲ) mixture of gained grease and cleaning agent is removed in the water flushing.
25, according to the method for claim 24, wherein said composition is distributed from single packing device.
26, according to the method for claim 24 or 25, wherein this surfactant and being used for reagent of removing grease distributes from packing device with predetermined ratio.
27, band partial package compositions comprises according to any described Cleasing compositions of claim 1 to 23 in the distribution package that is fit to.
28, according to the band packaging compositions of claim 27, wherein this packing has two or more chambers.
29, according to the band packaging compositions of claim 27 or 28, wherein first and second part volume ratio each other of said composition is 50: 50.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9910387A GB2349646B (en) | 1999-05-05 | 1999-05-05 | Two-part cleansing composition |
| GB9910387.1 | 1999-05-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1279063A true CN1279063A (en) | 2001-01-10 |
| CN1240365C CN1240365C (en) | 2006-02-08 |
Family
ID=10852851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001201522A Expired - Fee Related CN1240365C (en) | 1999-05-05 | 2000-05-05 | Detergent composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP4704540B2 (en) |
| KR (1) | KR100706149B1 (en) |
| CN (1) | CN1240365C (en) |
| GB (1) | GB2349646B (en) |
| ID (1) | ID25811A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2827515B1 (en) * | 2001-07-20 | 2005-06-03 | Oreal | FOAMING COMPOSITION BASED ON SILICA AND CATIONIC POLYMER |
| US6673755B2 (en) * | 2002-01-16 | 2004-01-06 | The Procter & Gamble Company | Personal cleansing compositions containing cleansing and skin active phases separated by one or more packaging barriers |
| US7053029B2 (en) * | 2002-03-27 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Use indicating soap |
| FR2915373A1 (en) * | 2007-04-27 | 2008-10-31 | Oreal | COMPOSITION OF CARE AND / OR MAKE-UP OF KERATINIC MATERIAL (S) |
| JP2009191098A (en) * | 2008-02-12 | 2009-08-27 | Diversey Ip Internatl Bv | Liquid detergent composition for clothing |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5165917B1 (en) * | 1988-11-09 | 2000-03-14 | Oreal | Eye makeup remover with two separate phases |
| DE4100490C1 (en) * | 1991-01-10 | 1992-03-05 | Goldwell Ag, 6100 Darmstadt, De | |
| EP0766681A1 (en) * | 1994-06-24 | 1997-04-09 | Takeda Chemical Industries, Ltd. | Processes for production of quinoline or quinazoline derivatives and intermediates therefor |
| GB9414573D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Detergent composition |
| JPH09151113A (en) * | 1995-11-30 | 1997-06-10 | Noevir Co Ltd | Skin cleaning agent |
| EP0916334A1 (en) * | 1997-11-07 | 1999-05-19 | Unilever Plc | Detergent composition |
-
1999
- 1999-05-05 GB GB9910387A patent/GB2349646B/en not_active Expired - Fee Related
-
2000
- 2000-04-25 JP JP2000124235A patent/JP4704540B2/en not_active Expired - Fee Related
- 2000-05-04 KR KR1020000023877A patent/KR100706149B1/en not_active IP Right Cessation
- 2000-05-04 ID IDP20000373A patent/ID25811A/en unknown
- 2000-05-05 CN CNB001201522A patent/CN1240365C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB2349646B (en) | 2004-01-07 |
| KR100706149B1 (en) | 2007-04-11 |
| GB9910387D0 (en) | 1999-07-07 |
| GB2349646A (en) | 2000-11-08 |
| JP4704540B2 (en) | 2011-06-15 |
| KR20010029684A (en) | 2001-04-06 |
| JP2001019620A (en) | 2001-01-23 |
| CN1240365C (en) | 2006-02-08 |
| ID25811A (en) | 2000-11-09 |
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| C14 | Grant of patent or utility model | ||
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| C56 | Change in the name or address of the patentee |
Owner name: UNILEVER N.V. Free format text: FORMER NAME: UNILEVER NV |
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Address after: Rotterdam Patentee after: Unilever N. V. Address before: Rotterdam Patentee before: Unilever NV |
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Granted publication date: 20060208 Termination date: 20140505 |