CN1277444A - Electrochemical super-capacitor and its making method - Google Patents
Electrochemical super-capacitor and its making method Download PDFInfo
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- CN1277444A CN1277444A CN00119499A CN00119499A CN1277444A CN 1277444 A CN1277444 A CN 1277444A CN 00119499 A CN00119499 A CN 00119499A CN 00119499 A CN00119499 A CN 00119499A CN 1277444 A CN1277444 A CN 1277444A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Electric Double-Layer Capacitors Or The Like (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The electrochemical super-capacitor has positive pole of hydroxide or oxide of nickel, negative pole of large-area porous carbon material, electrolyte of alkali solution and insulating diaphragm between the positive pole and negative pole for ions to pass through. It has high energy density and power performance and thus wide application range.
Description
The present invention relates to the electrochemistry storage device, particularly a kind of oxide and hydroxide with nickel is made anodal electrochemical super-capacitor and manufacture method thereof.
Electrochemical capacitor has obtained people with its outstanding effect and advantage and has approved widely in electronics industry.Compare with traditional capacitor, electrochemical capacitor has high capacitance, limited frequency response, high equivalent series resistance (ESR), the electric capacity relevant with voltage and the relevant self discharge speed with voltage.Electrochemical capacitor is to be used for providing bigger excitation energy for high-energy laser at first.The model electrochemical capacitor can also replace nickel-cadmium cell and the lithium battery uninterrupted power supply (ups) Unity as computer and communication system.Large-scale electrochemical capacitor is used for electric automobile provides heavy-current discharge under situations such as startup, braking, the high power that has effectively solved storage battery discharges and recharges problem, has prolonged the working life of storage battery.Therefore, electrochemical capacitor has a wide range of applications at numerous areas.
Be different from traditional capacitor, the high power capacity of electrochemical capacitor forms by adopting the large tracts of land porous electrode and storing energy between the diffuse double layer.Can separate matter at electrode-electric and form this diffuse double layer at the interface naturally when having voltage between the electrode, its thickness generally has only the diameter of a hydrone, has formed minimum effective " plate separation " thus.In addition, under many circumstances, energy stored increases by so-called " pseudo-capacitance " or " pseudocapacity " basically, and this kind effect also occurs in electrode-electric and separates matter at the interface.Electric double layer capacitance is generally 16-40 microfarad/square centimeter, and passes through the highest 100 microfarads/more than the square centimeter of can reaching of capacitance that " pseudo-capacitance " form.Adsorption desorption or fast electrochemical redox reaction (there is not tangible phase change in active material) take place near electrode place or its, and this capacitance can further increase.The capacitance of this increase is called " pseudo-capacitance ", resulting device by popular being called of people " ultra-capacitor " or ultracapacitor ", it is the pseudocapacity of reflection faraday signal, has the specific capacity higher than pure electric double layer capacitance.
Double layer capacitor is based on high surface area electrode material activity charcoal, and this kind material provides high surface A, and " effectively double-deck " thickness d is reduced to the atomic diameter scale, has therefore formed high capacitance.Beck has delivered the patent of first piece of relevant double electric layer capacitor early than the sixties.But the real rise of electrochemical capacitor research is to be widely used as the computer uninterrupted power supply and after the early 1990s, American National Ministry of Energy proposed electrochemical capacitor is applied to the huge plan of electric automobile at it.
The general stored energy of chemical power source equals to change relevant electric charge with electrochemical redox and multiply by potential difference between the battery electrode.Discharge and recharge the variation that often relates to the active material phase in the course of reaction.Thereby, although energy density is higher relatively, discharges and recharges reaction speed and compare relatively slow with electrochemical capacitor.Compare with battery, electrochemical capacitor have do not need repairing, longer cycle life, safe in utilization, do not have advantages such as memory effect.The more important thing is that electrochemical capacitor has the performance that the big electric current of high power that battery do not have discharges and recharges continuously, has promoted this class high power devices and Products Development.Therefore, electrochemical capacitor is a kind of extremely attractive energy storage device.
The energy storage system that is used for electric motor car requires to possess high energy density so that enough driving scopes to be provided.It must have higher power density to satisfy the acceleration performance demands of electric automobile.It must have sufficiently long discharge and recharge the life-span and also must have the user the price that can afford.The plurality of advantages of electrochemical capacitor energy storage system makes it have the potentiality of application in fields such as electric vehicle power sources.Electrochemical capacitor is necessary in the hybrid electric vehicle composite power source, electrochemical capacitor can be provided for electric automobile and quicken fast, the power increment that the heavy load operation is required can't this maximum commercialization technical barrier of high power discharge thereby solved batteries of electric automobile.Battery and electric capacity form parallel circuits, when automobile overflows row still by the battery normal power supply, under relative abominable service conditions such as automobile starting, acceleration, climbing and braking, then capacitor is started working, the use of capacitor has effectively solved the heavy-current discharge problem of battery, and compares a kind of battery with effect of the same race of design and want much worthwhile on cost.
At present technology is comparatively ripe is to be the electrochemical double layer capacitor (i.e. the positive and negative pole material of this capacitor all be made up of active carbon class material symmetry capacitor) of electrode material with the porous activated carbon, but studies have shown that, generally be difficult in practice reach according to the materials theory capacitance that calculates to the thickness of the mensuration of surface area and electrode couple layer, the surface area of material is big more, gap between the capacity of Theoretical Calculation and actual measurement is big more, because " micropore " that the surface of material with carbon element exists electrolyte to be difficult to flood, we can't utilize the surface area of active carbon fully.Therefore, it is little to improve the leeway of material capacitance by the surface area that improves material.Contact resistance between activated carbon granule has limited Electric double-layer capacitor with higher power output.The striving direction that promotes the development of electrochemical capacitor store energy should be placed on " pseudo-capacitance " that how to make full use of material, on the capacity characteristic that improves material significantly.
It is transition metal oxide class material such as ru oxide RuO that material people with higher faraday " pseudo-capacitance " study more
2XH
2O) etc., RuO
2XH
2Though O possesses gratifying capacity (hundreds of farad/gram active material), but its fancy price has limited its further business-like application, people also study other metal oxide such as nickel oxide, but the symmetry electric capacity operating potential narrow range that this material is formed, and final discharging voltage is when being zero volt, understanding some electric weight can't emit, thereby the energy density of electric capacity is relatively low.Therefore, up to the present, also lack electrochemical super-capacitor a kind of cheapness, superior performance, that can be applied to a plurality of fields on the market.
The object of the present invention is to provide a kind of electrochemical super-capacitor and manufacture method thereof,, this electrochemical capacitor is had than cadmium nickel, the better power characteristic of Ni-H cell to improve the energy density of electrochemical capacitor.
The object of the present invention is achieved like this, and a kind of electrochemical super-capacitor is characterized in that it comprises:
1. the oxide of nickel and hydroxide are done anodal;
2. porous large tracts of land charcoal material as cathode;
3. aqueous slkali is made electrolyte;
4. between positive pole and the negative pole being can be by the insulation diaphragm of ion.
Said anodal manufacturing step is as follows:
1. nickel sulfate solution is added in the sodium hydroxide solution in the spray mode, constantly stir in the course of reaction, generate nickel hydroxide precipitate, through washing, after the drying, with its crushing screening;
2. under 250 ℃ of-500 ℃ of temperature, carry out the sintering dehydration;
3. the conductive agent that adds 10%-30%;
4. the adhesive that adds 5%-10%;
5. make slurry, be coated on the collector;
6. compacting, oven dry, capacitor anode is made in section.
Said anodal manufacturing step can also be as follows:
1. be anode with the metallic nickel, the micropore substrate is a negative electrode, at a certain temperature, carries out electrolysis in neutral or acid nickel nitrate solution;
2. the substrate crossed of electrochemical impregnation through washing, drying after, in sodium hydroxide solution, discharge and recharge a period of time continuously;
3. washing again, dry, discharge and recharge, and this step is repeatedly repeatedly;
4. carrying out making capacitor anode after the sintering dehydration under 250 ℃ of-500 ℃ of temperature.
The said anodal other method of making is:
1. nickel hydroxide colloid is by viscosity centrifugal, that colloid is adjusted in oven dry;
2. the conductive agent that adds 10%-30%;
3. the adhesive that adds 5%-10%;
4. make slurry, be coated on the collector;
5. suppress, dry, cut into slices and make capacitor anode.
Said negative pole is the conductive agent of the large-area raw material of wood-charcoal material adding 10%-30% of employing porous, adds the adhesive of 5%-10%, makes slurry, is coated on the collector, makes through suppressing, dry, cutting into slices.
Said aqueous slkali can be lithium hydroxide or potassium hydroxide or NaOH or its mixed solution.
Said barrier film is all-glass paper or polymer film.
Said conductive agent is graphite or carbon black or nickel powder.
Said adhesive is polytetrafluoroethylene or poly-inclined to one side tetrafluoroethene.
Said collector is nickel foam or punching nickel-clad steel plate or aluminium foil or Copper Foil.
Said raw material of wood-charcoal material is an active carbon, or carbon nano-fiber, or CNT (carbon nano-tube).
Because the present invention has used the distinct methods preparation and the oxide of the nickel handled and hydroxide as the positive pole of electrochemical capacitor, use the negative pole of the porous large tracts of land raw material of wood-charcoal material of distinct methods preparation as electrochemical capacitor, use the electrolyte of aqueous slkali as electrochemical capacitor, be can be between positive pole and the negative pole by the insulating properties barrier film of ion, so electrochemical super-capacitor of the present invention, have the energy density higher than common double layer capacitance, be better than ordinary hydrogen nickel, the power characteristic of ickel-cadmium cell is a kind of electrochemical super-capacitor with superperformance.
Enumerate the manufacture method of three embodiment brief description electrochemical super-capacitors of the present invention below.
Embodiment 1
The preparation method of positive electrode is identical with the preparation method of cadmium nickel, Ni-H cell positive electrode, with the NiSO of certain density (1: 2)
4Solution joins in the NaOH solution in the spray mode and goes, and constantly stirs in the course of reaction, generates Ni (OH)
2Precipitation, after super-dry, washing, with its crushing screening, product can carry out further sintering processed in 250 ℃ of-500 ℃ of temperature ranges, will add various additives in the material (as LiOH, Co
2O
3, Ba (OH)
2Deng) and 10%-30% conductive agent (as graphite, carbon black, nickel powder etc.).Add an amount of adhesive (as polytetrafluoroethylene, poly-inclined to one side tetrafluoroethene, carboxycellulose sodium etc.), make slurry, be coated on the collector (as nickel foam, punching nickel-clad steel plate, aluminium foil, Copper Foil etc.),, make the positive pole of capacitor through operations such as compacting, oven dry, sections.
Choose the large-area material with carbon element (as active carbon, nano-scale carbon fiber, CNT (carbon nano-tube), carbon aerosol etc. or its mixture) of certain porous, the conductive agent (as graphite, carbon black, nickel powder etc.) that adds 10%-30%, the adhesive (as polytetrafluoroethylene, poly-inclined to one side tetrafluoroethene etc.) that adds 5%-10%, be coated on the collector on (as nickel foam, punching nickel-clad steel plate, aluminium foil, Copper Foil etc.), through operations such as compacting, oven dry, sections, make the negative pole of capacitor.
Choose strong alkali solution (as LiOH, KOH, NaOH etc.) and be dissolved in ionic solvent (as water) or nonionic solvent (as ethanol, propene carbonate etc.) as electrolyte.Choose the insulating properties material that possesses the ion guide general character as barrier film (as all-glass paper, polymer film etc.) with positive pole, negative pole, electrolyte, the electrochemical capacitor of barrier film assembling becoming with difformity and purposes.
Embodiment 2
The positive pole of each capacitor of the electrochemical method system of use, with the metallic nickel is anode, the micropore substrate is a negative electrode, under uniform temperature, in neutral or acid nickel nitrate solution, carry out electrolysis, the substrate that electrochemical impregnation is crossed is through after washing, the drying, in NaOH solution, discharge and recharge a period of time continuously, washing again, dry, discharge and recharge, this program several times repeatedly, the electrode that makes can carry out the sintering processed in 250 ℃ of-500 ℃ of temperature after as the positive pole of capacitor.
Choose the large-area material with carbon element (as active carbon, nano-scale carbon fiber, CNT (carbon nano-tube), carbon aerosol etc. or its mixture) of certain porous, the conductive agent (as graphite, carbon black, nickel powder etc.) that adds 10%-30%, the adhesive (as polytetrafluoroethylene, poly-inclined to one side tetrafluoroethene etc.) that adds 5%-10%, be coated on the collector on (as nickel foam, punching nickel-clad steel plate, aluminium foil, Copper Foil etc.), through operations such as compacting, oven dry, sections, make the negative pole of capacitor.
Choose strong alkaline substance (as LiOH, KOH, NaOH etc.) and be dissolved in ionic solvent (as water) or nonionic solvent (as ethanol, propene carbonate etc.) as electrolyte.Choose the insulating properties material that possesses the ion guide general character as barrier film (as all-glass paper, polymer film etc.) with positive pole, negative pole, electrolyte, the electrochemical capacitor of barrier film assembling becoming with difformity and purposes.
Embodiment 3
Use diverse ways to prepare Ni (OH)
2Colloid is as with nickel acetate [Ni (AC)
26H
2O] behind 100 degrees centigrade of drying and dehydrating certain hours, place the reaction that is hydrolyzed of the deionized water of certain volume, produce Ni (OH)
2Colloid, adjust the viscosity of colloid by methods such as centrifugal, oven dry, the conductive agent (as graphite, carbon black, nickel powder etc.) that adds 10%-30%, the adhesive (as polytetrafluoroethylene, poly-inclined to one side tetrafluoroethene etc.) that adds 5%-10%, be coated on the collector on (as nickel foam, punching nickel-clad steel plate, aluminium foil, Copper Foil etc.), through operations such as compacting, oven dry, sections, make the positive pole of capacitor.
Choose the large-area material with carbon element (as active carbon, nano-scale carbon fiber, CNT (carbon nano-tube), carbon aerosol etc. or its mixture) of certain porous, the conductive agent (as graphite, carbon black, nickel powder etc.) that adds 10%-30%, the adhesive (as polytetrafluoroethylene, poly-inclined to one side tetrafluoroethene etc.) that adds 5%-10%, be coated on the collector on (as nickel foam, punching nickel-clad steel plate, aluminium foil, Copper Foil etc.), through operations such as compacting, oven dry, sections, make the negative pole of capacitor.
Choose strong alkaline substance (as LiOH, KOH, NaOH etc.) and be dissolved in ionic solvent (as water) or nonionic solvent (as ethanol, propene carbonate etc.) as electrolyte.Choose the insulating properties material that possesses the ion guide general character as barrier film (as all-glass paper, polymer film etc.) with positive pole, negative pole, electrolyte, the electrochemical capacitor of barrier film assembling becoming with difformity and purposes.
It has the capacity characteristic that obviously is better than common double electric layer capacitor electrochemical capacitance by the foregoing description preparation, after tested the capacitor specific capacity reach 80 farads/more than the gram; Simultaneously, the power characteristic of this ultra-capacitor obviously surpasses Ni-H cell and ickel-cadmium cell; The potential range of capacitor work surpasses the symmetry electric capacity of being made up of nickel compound; Because the electrode that uses common nickel hydroxide or nickel oxide material electrode to replace an absorbent charcoal material in the double electric layer capacitor in the invention, this ultra-capacitor has than the much lower cost of electrochemical capacitor that uses active carbon or ruthenium-oxide material fully.
Claims (17)
1, a kind of electrochemical super-capacitor is characterized in that it comprises:
1. the oxide of nickel and hydroxide are done anodal;
2. porous large tracts of land charcoal material as cathode;
3. aqueous slkali is made electrolyte;
4. between positive pole and the negative pole being can be by the insulation diaphragm of ion.
2, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said anodal manufacturing step is as follows:
1. nickel sulfate solution is added in the sodium hydroxide solution in the spray mode, constantly stir in the course of reaction, generate nickel hydroxide precipitate, through washing, after the drying, with its crushing screening;
2. under 250 ℃ of-500 ℃ of temperature, carry out the sintering dehydration;
3. the conductive agent that adds 10%-30%;
4. the adhesive that adds 5%-10%;
5. make slurry, be coated on the collector;
6. compacting, oven dry, capacitor anode is made in section.
3, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said anodal manufacturing step is as follows:
1. be anode with the metallic nickel, the micropore substrate is a negative electrode, at a certain temperature, carries out electrolysis in neutral or acid nickel nitrate solution;
2. the substrate crossed of electrochemical impregnation through washing, drying after, in sodium hydroxide solution, discharge and recharge a period of time continuously;
3. washing again, dry, discharge and recharge, and this step is repeatedly repeatedly;
4. carrying out making capacitor anode after the sintering dehydration under 250 ℃ of-500 ℃ of temperature.
4, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said anodal manufacturing step is as follows:
1. nickel hydroxide colloid is by viscosity centrifugal, that colloid is adjusted in oven dry;
2. the conductive agent that adds 10%-30%;
3. the adhesive that adds 5%-10%;
4. make slurry, be coated on the collector;
5. suppress, dry, cut into slices and make capacitor anode.
5, the manufacture method of electrochemical super-capacitor according to claim 1, it is characterized in that said negative pole is the conductive agent that adopts the large-area raw material of wood-charcoal material adding 10%-30% of porous, the adhesive that adds 5%-10%, make slurry, be coated on the collector, make through compacting, oven dry, section.
6, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said aqueous slkali can be lithium hydroxide or potassium hydroxide or NaOH or its mixed solution.
7, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said barrier film is all-glass paper or polymer film.
8, the manufacture method of electrochemical super-capacitor according to claim 2 is characterized in that said conductive agent is graphite or carbon black or nickel powder.
9, the manufacture method of electrochemical super-capacitor according to claim 4 is characterized in that said conductive agent is graphite or carbon black or nickel powder.
10, the manufacture method of electrochemical super-capacitor according to claim 5 is characterized in that said conductive agent is graphite or carbon black or nickel powder.
11, the manufacture method of electrochemical super-capacitor according to claim 2 is characterized in that said adhesive is polytetrafluoroethylene or poly-inclined to one side tetrafluoroethene.
12, the manufacture method of electrochemical super-capacitor according to claim 4 is characterized in that said adhesive is polytetrafluoroethylene or poly-inclined to one side tetrafluoroethene.
13, the manufacture method of electrochemical super-capacitor according to claim 5 is characterized in that said adhesive is polytetrafluoroethylene or poly-inclined to one side tetrafluoroethene.
14, the manufacture method of electrochemical super-capacitor according to claim 2 is characterized in that said collector is nickel foam or punching nickel-clad steel plate or aluminium foil or Copper Foil.
15, the manufacture method of electrochemical super-capacitor according to claim 4 is characterized in that said collector is nickel foam or punching nickel-clad steel plate or aluminium foil or Copper Foil.
16, the manufacture method of electrochemical super-capacitor according to claim 5 is characterized in that said collector is nickel foam or punching nickel-clad steel plate or aluminium foil or Copper Foil.
17, the manufacture method of electrochemical super-capacitor according to claim 1 is characterized in that said raw material of wood-charcoal material is an active carbon, or carbon nano-fiber, or CNT (carbon nano-tube).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001194992A CN1265407C (en) | 2000-07-21 | 2000-07-21 | Electrochemical super-capacitor and its making method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001194992A CN1265407C (en) | 2000-07-21 | 2000-07-21 | Electrochemical super-capacitor and its making method |
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| Publication Number | Publication Date |
|---|---|
| CN1277444A true CN1277444A (en) | 2000-12-20 |
| CN1265407C CN1265407C (en) | 2006-07-19 |
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|---|---|---|---|
| CNB001194992A Expired - Fee Related CN1265407C (en) | 2000-07-21 | 2000-07-21 | Electrochemical super-capacitor and its making method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101310410B (en) * | 2006-02-24 | 2011-11-30 | 韩国飞世龙电池有限公司 | Hybrid battery |
| CN102324320A (en) * | 2011-07-29 | 2012-01-18 | 上海奥威科技开发有限公司 | High-performance super capacitor |
| CN102354615A (en) * | 2011-09-30 | 2012-02-15 | 天津国泰之光新材料技术研究院有限公司 | Preparation method of slurry for positive plate of high-energy nickel-carbon supercapacitor |
| CN102522209A (en) * | 2011-09-30 | 2012-06-27 | 天津国泰之光新材料技术研究院有限公司 | Preparation method of cathode negative plate slurry of high-energy nickel-carbon supercapacitor |
| CN102054590B (en) * | 2009-11-10 | 2012-08-22 | 江苏海四达电源股份有限公司 | Technology for preparing nickel positive electrode serving as key component of high-power super capacitor |
| CN102938323A (en) * | 2011-08-15 | 2013-02-20 | 海洋王照明科技股份有限公司 | Asymmetric electrochemical capacitor and method for preparing same |
| WO2013044681A1 (en) * | 2011-09-30 | 2013-04-04 | 天津国泰之光新材料技术研究院有限公司 | Positive plate slurry of high-energy nickel/carbon super capacitor |
| CN106395814A (en) * | 2016-08-30 | 2017-02-15 | 浙江大维高新技术股份有限公司 | Preparation method of special activated-carbon electrode block for capacitive deionizing equipment |
| CN106449137A (en) * | 2016-09-06 | 2017-02-22 | 吉林大学 | Preparation method for asymmetric super capacitor with cobalt hydroxide and active carbon as anode and cathode respectively |
-
2000
- 2000-07-21 CN CNB001194992A patent/CN1265407C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101310410B (en) * | 2006-02-24 | 2011-11-30 | 韩国飞世龙电池有限公司 | Hybrid battery |
| CN102054590B (en) * | 2009-11-10 | 2012-08-22 | 江苏海四达电源股份有限公司 | Technology for preparing nickel positive electrode serving as key component of high-power super capacitor |
| CN102324320B (en) * | 2011-07-29 | 2015-06-10 | 上海奥威科技开发有限公司 | High-performance super capacitor |
| CN102324320A (en) * | 2011-07-29 | 2012-01-18 | 上海奥威科技开发有限公司 | High-performance super capacitor |
| CN102938323B (en) * | 2011-08-15 | 2016-04-13 | 海洋王照明科技股份有限公司 | Asymmetric electrochemical capacitor and preparation method thereof |
| CN102938323A (en) * | 2011-08-15 | 2013-02-20 | 海洋王照明科技股份有限公司 | Asymmetric electrochemical capacitor and method for preparing same |
| CN102522209A (en) * | 2011-09-30 | 2012-06-27 | 天津国泰之光新材料技术研究院有限公司 | Preparation method of cathode negative plate slurry of high-energy nickel-carbon supercapacitor |
| WO2013044683A1 (en) * | 2011-09-30 | 2013-04-04 | 天津国泰之光新材料技术研究院有限公司 | Method for preparing positive plate slurry of high-energy nickel/carbon super capacitor |
| CN102522209B (en) * | 2011-09-30 | 2013-09-25 | 天津国泰之光新材料技术研究院有限公司 | Preparation method of cathode negative plate slurry of high-energy nickel-carbon supercapacitor |
| WO2013044681A1 (en) * | 2011-09-30 | 2013-04-04 | 天津国泰之光新材料技术研究院有限公司 | Positive plate slurry of high-energy nickel/carbon super capacitor |
| CN102354615A (en) * | 2011-09-30 | 2012-02-15 | 天津国泰之光新材料技术研究院有限公司 | Preparation method of slurry for positive plate of high-energy nickel-carbon supercapacitor |
| CN106395814A (en) * | 2016-08-30 | 2017-02-15 | 浙江大维高新技术股份有限公司 | Preparation method of special activated-carbon electrode block for capacitive deionizing equipment |
| CN106395814B (en) * | 2016-08-30 | 2018-04-10 | 浙江大维高新技术股份有限公司 | A kind of preparation method of capacitive deionization device-specific activated carbon electrodes block |
| CN106449137A (en) * | 2016-09-06 | 2017-02-22 | 吉林大学 | Preparation method for asymmetric super capacitor with cobalt hydroxide and active carbon as anode and cathode respectively |
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| Publication number | Publication date |
|---|---|
| CN1265407C (en) | 2006-07-19 |
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