CN1275868C - Phenolic waste water treatment method by nitrated macroporous absorption resin - Google Patents
Phenolic waste water treatment method by nitrated macroporous absorption resin Download PDFInfo
- Publication number
- CN1275868C CN1275868C CN 200510037861 CN200510037861A CN1275868C CN 1275868 C CN1275868 C CN 1275868C CN 200510037861 CN200510037861 CN 200510037861 CN 200510037861 A CN200510037861 A CN 200510037861A CN 1275868 C CN1275868 C CN 1275868C
- Authority
- CN
- China
- Prior art keywords
- resin
- nitration
- wastewater
- macroporous resin
- eluent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011347 resin Substances 0.000 title claims abstract description 53
- 229920005989 resin Polymers 0.000 title claims abstract description 53
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000010521 absorption reaction Methods 0.000 title description 9
- 238000004065 wastewater treatment Methods 0.000 title description 4
- 239000002351 wastewater Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 25
- 150000002989 phenols Chemical class 0.000 claims abstract description 17
- 238000001179 sorption measurement Methods 0.000 claims abstract description 17
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 4
- 238000006396 nitration reaction Methods 0.000 claims description 23
- 239000003480 eluent Substances 0.000 claims description 19
- 238000005406 washing Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 239000002594 sorbent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 238000011084 recovery Methods 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 125000005245 nitryl group Chemical group [N+](=O)([O-])* 0.000 abstract 3
- 238000000746 purification Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229940090668 parachlorophenol Drugs 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- -1 nitro para-chlorophenol Chemical group 0.000 description 3
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- BFCFYVKQTRLZHA-UHFFFAOYSA-N 1-chloro-2-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1Cl BFCFYVKQTRLZHA-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- LKPRIFLRJXZUBK-UHFFFAOYSA-N 6-diazo-5-nitrocyclohexa-2,4-dien-1-ol Chemical compound [N+](=O)([O-])C=1C(C(C=CC1)O)=[N+]=[N-] LKPRIFLRJXZUBK-UHFFFAOYSA-N 0.000 description 1
- 241001566735 Archon Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- JSAIENUMNDAGTD-UHFFFAOYSA-N benzene ethene styrene Chemical compound C1=CC=CC=C1.C=C.C=C.C=CC1=CC=CC=C1 JSAIENUMNDAGTD-UHFFFAOYSA-N 0.000 description 1
- 238000002306 biochemical method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Phenolic compound | Content (ppm) before handling | The Ph value | Handle back content (ppm) | The rate of recovery (%) | |
Example 1 | P-cresol | 560 | 9.5 | 0.20 | 43 |
Example 2 | P methoxy phenol | 455 | 9.5 | 0.20 | 61 |
Example 3 | Para-chlorophenol | 950 | 10 | 0.15 | 68 |
Example 4 | Adjacent nitro para-chlorophenol | 1265 | 11 | 0.15 | 76 |
Example 5 | Adjacent nitro para-chlorophenol | 1265 | 11 | 0.20 | 77 |
Example 6 | Naphthols | 325 | 9 | 0.45 | 22 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200510037861 CN1275868C (en) | 2005-02-25 | 2005-02-25 | Phenolic waste water treatment method by nitrated macroporous absorption resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200510037861 CN1275868C (en) | 2005-02-25 | 2005-02-25 | Phenolic waste water treatment method by nitrated macroporous absorption resin |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1669940A CN1669940A (en) | 2005-09-21 |
CN1275868C true CN1275868C (en) | 2006-09-20 |
Family
ID=35041414
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200510037861 Expired - Fee Related CN1275868C (en) | 2005-02-25 | 2005-02-25 | Phenolic waste water treatment method by nitrated macroporous absorption resin |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1275868C (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101898937B (en) * | 2010-03-02 | 2013-05-08 | 江苏工业学院 | Method for adsorbing and recycling phenol in wastewater by polyamine macroporous resin |
CN105236509A (en) * | 2015-11-13 | 2016-01-13 | 如皋市金陵化工有限公司 | Bisphenol S high-concentration waste water pre-treatment technology |
CN111003904A (en) * | 2019-12-31 | 2020-04-14 | 天津大学 | Resourceful treatment method of high-concentration phenol-containing wastewater |
CN111115744A (en) * | 2020-01-10 | 2020-05-08 | 浙江长征化工有限公司 | Treatment method of disperse red 60 condensed wastewater |
-
2005
- 2005-02-25 CN CN 200510037861 patent/CN1275868C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1669940A (en) | 2005-09-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jiangsu Shengtong Environment Engineering Co., Ltd. Assignor: Jiangsu Polytechnic University Contract fulfillment period: 2009.4.23 to 2014.4.23 contract change Contract record no.: 2009320000782 Denomination of invention: Phenolic waste water treatment method by nitrated macroporous absorption resin Granted publication date: 20060920 License type: Exclusive license Record date: 2009.5.6 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.4.23 TO 2014.4.23; CHANGE OF CONTRACT Name of requester: JIANGSU SHENGTONG ENVIRONMENT ENGINEERING CO., LTD Effective date: 20090506 |
|
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060920 Termination date: 20110225 |