CN1272073C - Deodorizer, deodorizing apparatus, and deodorizing and bacteria removing apparatus - Google Patents

Deodorizer, deodorizing apparatus, and deodorizing and bacteria removing apparatus Download PDF

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Publication number
CN1272073C
CN1272073C CNB028045122A CN02804512A CN1272073C CN 1272073 C CN1272073 C CN 1272073C CN B028045122 A CNB028045122 A CN B028045122A CN 02804512 A CN02804512 A CN 02804512A CN 1272073 C CN1272073 C CN 1272073C
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China
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aforementioned
air
deodorizer
downstream
pressurd vessel
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CNB028045122A
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CN1491120A (en
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天利义弘
山岸利明
天利悦郎
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Wasun International Trading Co Ltd
YAMAGISHI INDUSTRIAL Co Ltd
AMARI SEIKOU Co Ltd
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Wasun International Trading Co Ltd
YAMAGISHI INDUSTRIAL Co Ltd
AMARI SEIKOU Co Ltd
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Publication of CN1491120A publication Critical patent/CN1491120A/en
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Publication of CN1272073C publication Critical patent/CN1272073C/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention provides a deodorizer, a deodorizing apparatus, and a deodorizing and bacteria removing apparatus using same, especially a deodorizer for removing reliably a bad smell component in discharged air from a machine such as a raw garbage treatment machine, a facility, or an apparatus or in an atmosphere, and a deodorizing apparatus and a deodorizing and bacteria-removing apparatus that use the deodorizer. The deodorizer comprises an air introduction portion for introducing air containing bad smell, a heating portion connected to the air introduction portion, a chamber located on the downstream side of the heating portion, a bad smell purification portion located on the downstream side of the chamber, and an air discharge portion located on the downstream side of the bad smell purification portion.

Description

Deodorizer, deodorization device and deodorize bactericidal device
Technical field
The present invention relates to containing deodorizer, the deodorization device that uses this deodorizer and the deodorize bactericidal device that air that various unpleasant one-tenth grade is handled.The air that contains various unpleasant compositions for example, air that contains odor pollutant of being discharged from house refuse (kitchen throw away contain moisture rubbish) datatron etc. etc.
Background technology
Such as everyone knows, will be from general family, dining room, the house refuse that the kitchen of food service industry, supermarket, grand hotel etc., processing factory, house refuse storehouse etc. are discharged utilizes the domestic garbage treatment machine of microorganism composted beginning to popularize.
, this domestic garbage treatment machine is decomposed by the fermentation of house refuse by microorganism, for example, produce the odor pollutant of ammonia, methanthiol, hydrogen sulfide, dimethyl sulfide, methylate two sulfur, trimethylamine, acetaldehyde etc., and this odor pollutant is removed in expectation.
In addition, for example, from the aerofluxus of food processing industry, compost factory etc., contain above-mentioned odor pollutant too, also this odor pollutant is removed in expectation.
Therefore, proposition will contain the aerofluxus of these odor pollutants heats, and carries out thermal decomposition by the stench purifier that is loaded with catalyst.
, the aerofluxus that will contain these odor pollutants is heated, and only carries out thermal decomposition by the stench purifier that is loaded with catalyst, is confirmed to be and can not removes odor pollutant really.
Especially, methanthiol etc. although carry out handling as above-mentioned deodorize, still are comprised in the aerofluxus, become the low problem of the rate of removing.
In addition, be not limited only to above-mentioned stench, for example: the stink of removing the smoking room in the office, the stink of house pet in pet shop, pets hospital, the family, nursing house, increasing, but the machine of corresponding these expectations, device are still untapped from the expectation of the stink in residence ward room, the stink of hospital etc.
The content of invention
The present invention invents for the problem points that solves in the past, and its purpose is: provide a kind of and can remove really with in the aerofluxus of the various machines headed by the domestic garbage treatment machine, unit etc. or deodorizer, the deodorization device that uses this deodorizer and the deodorize bactericidal device of the odor pollutant in the surrounding.
The deodorizer that the present invention relates to, possessing has: import the air introduction part that contains mephitic air; Be connected in the heating part of this air introduction part; Be positioned at the downstream of this heating part the chamber, be positioned at the stench purification portion in the downstream of this chamber; Reach, be positioned at the air leading-out portion in the downstream of this stench purification portion.
Again, other deodorizer that the present invention relates to, possessing has: import the air introduction part that contains mephitic air; Be connected in first heating part of this air introduction part; Be positioned at first Room in the downstream of this first heating part; Be positioned at the first stench purification portion in the downstream of this first Room; Be positioned at second heating part in the downstream of this first stench purification portion; Be positioned at second Room in the downstream of this second heating part; Be positioned at the second stench purification portion in the downstream of this second Room; Reach, be positioned at the air leading-out portion in the downstream of this second stench purification portion.
Relevant deodorization device of the present invention, possessing has: above-mentioned deodorizer; The air that is used for connecting the air introduction part of discharging the exhaust portion that contains mephitic air and deodorizer imports uses pipe arrangement; Reach, be connected in the air derivation pipe arrangement of the air leading-out portion of deodorizer.
This deodorization device, and then possess and have: reclaiming derives the air heat of emitting with pipe arrangement from air and comes heated air to import the air-cooled heat exchanger that contains malodorous air with pipe arrangement.
Relevant other deodorize bactericidal device involved in the present invention, possessing has: above-mentioned deodorizer; Possess suction unit and exhaust portion, take in the inner pressurd vessel of deodorizer; The suction fan that the suction unit of this inner pressurd vessel is provided with; Possess suction unit and exhaust portion, take in the outer container of inner pressurd vessel; Be equipped in the inner pressurd vessel, the air heat that recovery is emitted from the air leading-out portion of deodorizer comes heated air to import with the mephitic air that contains in the pipe arrangement, and the air-cooled heat exchanger of the exhaust portion of the air importing content device that will be emitted from the air leading-out portion of deodorizer; Be formed between inner pressurd vessel and the outer container, the air that will import from the suction unit of outer container imports the air suction way of air-cooled heat exchanger; Be formed between inner pressurd vessel and the outer container, will import the air flue of the exhaust portion of outer container from the air that air-cooled heat exchanger is discharged; Reach, be located at the air propeller of air flue.
In this deodorize bactericidal device, outer container, constituted by the cylindrical body that possesses suction unit at lower sides and possess the lengthwise of exhaust portion on top, and inner pressurd vessel, constituted by the cylindrical body that possesses suction unit in upper portion side wall and possess the lengthwise of exhaust portion on top, deodorizer is the lower side that the air introduction part is equipped on inner pressurd vessel, and the air leading-out portion is equipped on the upper side of inner pressurd vessel.
The simple declaration of drawing
Fig. 1 is the deodorizer cutaway view of the relevant an embodiment of the present invention of expression.
Fig. 2 is the importing side end face figure of the deodorizer of presentation graphs 1.
Fig. 3 is the derivation side end face figure of the deodorizer of presentation graphs 1.
Fig. 4 is the cutaway view along the A-A line of Fig. 1.
Fig. 5 is the cutaway view along the B-B line of Fig. 1.
Fig. 6 is the cutaway view along the C-C line of Fig. 1.
Fig. 7 is the cutaway view along the D-D line of Fig. 1.
Fig. 8 is the axonometric chart of variation of the liner 12 of displayed map 1.
Fig. 9 is the side view and the axonometric chart of variation of the liner 32 of displayed map 1.
Figure 10 is the side view and the axonometric chart of variation of the liner 44 of displayed map 1.
Figure 11 is the axonometric chart of variation of the liner 72 of displayed map 1.
Figure 12 is the cutaway view that shows the deodorizer of the other example of relevant the present invention.
Figure 13 is the end view drawing of importing side that shows the deodorizer of Figure 12.
Figure 14 is the end view drawing of derivation side that shows the deodorizer of Figure 12.
Figure 15 is the cutaway view along the E-E line of Figure 12.
Figure 16 is the cutaway view along the F-F line of Figure 12.
Figure 17 is the cutaway view along the G-G line of Figure 12.
Figure 18 is the cutaway view along the H-H line of Figure 12.
Figure 19 is the axonometric chart of variation that shows the liner 112 of Figure 12.
Figure 20 is the axonometric chart of variation that shows the liner 32 of Figure 12.
Figure 21 is the axonometric chart of variation that shows the liner 158 of Figure 12.
Figure 22 is the axonometric chart of variation that shows the liner 82 of Figure 12.
Figure 23 is the exploded view that shows the bobbin 124 (154) of Figure 12.
Figure 24 is the key diagram that shows the deodorization device of relevant an embodiment of the present invention.
Figure 25 is the key diagram that shows the deodorize bactericidal device of relevant an embodiment of the present invention.
The figure number explanation
1,100 ... deodorizer 2 ... urceolus
3.4 ... heat-barrier material, 10 ... the air introduction part,
12,32,44,58,62,82,112,158 ... liner,
12a, 12b, 12c, 12d, 12e, 22a, 32a, 32b, 32c, 32d, 32e, 34a, 44a, 44b, 44c, 44d, 44e, 58a, 62a, 64a, 58a, 72b, 72c, 72d, 72e, 112a, 158a ... through hole,
12f, 32f, 44f, 44g, 44h, 44i, 44j, 74f, 74g, 74h, 74i, 158d ... pressure bar,
20,120 ... first heating part, 21,121 ... introduction part,
22,41,52,71,122,152,162 ... body,
23,42,53,123,153 ... flange,
24,54,124,154 ... electric heater,
25,55,125,65,165 ... bobbin,
25a ... flange part, 25a, 25b, 55a, 55b ... flange part,
26,56,126 ... heater coil, 27,57,127 ... terminal,
31 ... Room the 1st, 31,61 ... member, 32 ... liner,
32a ... through hole, 32a ... spacer member, 34,64 ... shield,
35,65 ... temperature sensor, 40 ... the first stench purification portion, 41 ... body,
42 ... flange, 43,44,73,74 ... catalyst carrier, 44 ... catalyst carrier,
33,45,63,75 ... spacer member, 50,150 ... second heating part,
52 ... body, 53 ... flange, 53a ... through hole,
54 ... hot plate, 55 ... bobbin, 57 ... terminal,
58 ... liner, 58a ... through hole, 60 ... second Room,
61 ... member, 62 ... liner, 62a ... through hole,
63 ... spacer member, 64 ... shield, 64a ... through hole,
65 ... temperature-sensitive sticker, 70 ... the second stench purification portion, 71 ... body,
72 ... flange, 73 ... catalyst carrier, 74 ... catalyst carrier,
75 ... spacer member, 76 ... leading-out portion, 80 ... the air leading-out portion,
82 ... liner, 82a ... through hole, 112b, 158b ... support rod,
122c, 158c ... rod member, 155a ... heater coil coiling portion,
200 ... deodorization device, 210 ... air imports uses pipe arrangement,
220 ... air is derived and is used pipe arrangement, 230 ... heat exchanger, 231 ... outer tube,
232 ... interior pipe, 233 ... blow-off outlet, 234 ... air propeller,
240 ... exhaustor, 300 ... domestic garbage treatment machine, 310 ... air vent,
400 ... the deodorize bactericidal device, 401 ... inner pressurd vessel, 402,406 ... suction unit,
403,407 ... exhaust portion, 404 ... suction fan, 405 ... outer container,
413 ... fan, 415 ... first air suction way, 416 ... second air suction way,
417 ... the 3rd air suction way, 418 ... air flue, 419 ... exhaust fan,
420 ... seat, 421,422 ... spaced walls, 423 ... the gap.
The preferred forms of invention
Below, the present invention is illustrated according to the embodiment shown in the drawing.
The 1st figure to the 7 figure are embodiments that show relevant deodorizer of the present invention.
The deodorizer 1 of relevant present embodiment, binding has: import the air introduction part 10 that contains mephitic air; Be connected in first heating part 20 of air introduction part 10; Be positioned at first Room 30 in the downstream of first heating part 20; Be positioned at the first stench purification portion 40 in the downstream of first Room 30; Be positioned at second heating part 50 in the downstream of the first stench purification portion 40; Be positioned at second Room 60 of the downstream survey of second heating part 50; Be positioned at the second stench purification portion 70 in the downstream of second Room 60; Reach, be positioned at the air leading-out portion 80 in the downstream of the second stench purification portion 70.And with urceolus 2 constituting on every side around these.In the inboard of urceolus 2, form: the directly heat-barrier material 3 of the felt shape around each member, and double-layer structural that the outside of the heat-barrier material 3 of felt shape is centered on tabular heat-barrier material 4.
Air introduction part 10 in the present embodiment, is the introduction part 21 of dual-purpose first heating part 20.In introduction part 21, liner 12 is installed.
First heating part 20, it constitutes: be provided with the metal body 22 of flange 23 at both ends and be equipped on electric heater 24 in this body 22.Electric heater 24, the outside coiling heater coil 26 that has the bobbin 25 of criss-cross flange part 25a, 25b at two ends constitutes.The terminal 27 of electric heater 24, break-through body 22 are directed to outside power supply.
The first stench purification portion 40, it constitutes: be provided with the metal body 41 of flange 42, the predetermined spacer member 45 that is equipped on 2 catalyst carriers 43,44 in this body 41 and is equipped on 43,44 of 2 catalyst carriers at both ends.
Here, metal body 41 and metal body 22, internal diameter is about equally.
2 catalyst carriers 43,44 for example, are coated with gamma-alumina on the ceramic carrier that is made of the cordierite (Cordierite) of the porous matter of honeycomb shape etc., and make platinum on the surface, palladium (Pd), rhodium catalyst such as (Rh) disperses and be coated with.In addition, also can catalyst be disperseed and be coated with.
Between first heating part 20 and the first stench purification portion 40, set member 31 to be formed with first Room 30, this sets member 31 and confuses by first heating part, 20 heated air flows.
Confuse the member 31 of air flow, it constitutes: be fixed in liner 32 between first heating part 20 and the first stench purification portion 40, by be equipped on the spacer member that several bar constituted 33 between liner 32 and the catalyst carrier 43, and, be installed on the shield 34 of spacer member 33.
Liner 32 makes the diameter of through hole 32a littler than the through hole 12a of the liner 12 of introduction part 21.
Shield 34 is provided with the through hole 34a bigger slightly than the through hole 22a of liner 32.
In first Room 30, temperature sensor 35 is installed.
Second heating part 50 constitutes equally with first heating part 20.
Second heating part 50, it constitutes: be provided with at two ends flange 53 metal body 52, and, be equipped on the electric heater 54 in this body 52.Electric heater 54, the outside coiling heater coil 56 of bobbin 55 that has flange part 55a, the 55b of ten civilian shapes at two ends constitutes.The terminal 57 of electric heater 54, break-through body 52 also is directed at outside power supply.
Between second heating part 50 and the first stench purification portion 40, be equipped with and the liner 58 of liner 32 with shape.
The second stench purification portion 70 constitutes equally with the first stench purification portion 40.
The second stench purification portion 70, it constitutes: be provided with at both ends flange 72 metal body 71, predetermined be equipped on 2 catalyst carriers 73,74 this body 71 in, reach, be equipped on the spacer member 75 of 73,74 of 2 catalyst carriers.
Here, metal body 71 and metal body 52, internal diameter is about equally.2 catalyst carriers 73,74 for example, are coated with gamma-alumina on the ceramic carrier that is made of the porous matter cordierite (Cordierite) of honeycomb shape etc., and make platinum on the surface, the catalyst of palladium (Pd), rhodium (Rh) etc. disperses and be coated with.In addition, 2 catalyst carriers 73,74 also can make catalyst disperse on the metal carrier of aluminium alloy etc. equally and are coated with.
Between second heating part 50 and the second stench purification portion 70, set the member 61 that confuses by second heating part, 50 heated air flows to form second Room 60.
Confuse the member 61 of air flow, it constitutes: be fixed in liner 62 between second heating part 50 and the second stench purification portion 70, by being equipped on the spacer member that several bar constituted 63 between liner 62 and the catalyst carrier 73 and being installed on the shield 64 of spacer member 63.
Liner 62, the through hole 32a that makes the diameter of through hole 62a and liner 32 about equally.
Shield 64 is provided with the through hole 64a bigger slightly than the through hole 62a of liner 62.
In second Room 60, temperature sensor 65 is installed.
Air leading-out portion 80, in the present embodiment, the leading-out portion 76 of the dual-purpose second stench purification portion 70.At leading-out portion 76, liner 82 is installed.Liner 82, the through hole 62a that makes the diameter of through hole 82a and liner 62 about equally.
Secondly, the effect to the deodorizer 1 of relevant present embodiment is illustrated.
At first, switch in first heating part 20 and second heating part 50, carry out standby till making the ambient temperature of first Room 30 and second Room 60 become about 280 ℃~about 330 ℃ with temperature sensor 35,65, if confirming becomes about 280 ℃~about 330 ℃, controlled by the control device of being located at the outside and kept this temperature.
Then, the air that will contain odor pollutant is pressed into from introduction part 21 (air introduction part 10).
Bulged-in air is heated to about 280 ℃~about 330 ℃ in first heating part 20, and is directed to first Room 30.
At this moment, be heated to about 280 ℃~about 330 ℃ air, the member 31 by confusing air flow is first indoor being disturbed.Promptly, the about 280 ℃~about 330 ℃ air that is heated to from 20 discharges of first heating part, by than the internal diameter of the body 22 through hole 32a of the liner 32 of path more, so in the downstream of liner 32, produce eddy current, confuse and be heated to about 280 ℃~about 330 ℃ air, airborne odor pollutant is effectively disperseed, and then, shield 34 by the downstream can be given air with the effect of confusing equally, therefore, import the airborne odor pollutant of the first stench purification portion 40, cross over the region-wide dispersity that roughly forms homogenization of catalyst carrier 43 of the inflow side of the first stench purification portion 40.
Secondly, catalyst carrier 43 makes catalyst activityization by being heated to about 280 ℃~about 330 ℃ air, promotes the deodorize processing of airborne odor pollutant.
Then, the air of emitting from catalyst carrier 43, by and the catalyst carrier 44 in downstream between the spacer member 45 formed spaces that set be disturbed once again, afterwards, import the catalyst carrier 44 in downstream.Therefore, before the catalyst carrier 44 that flows into the downstream, airborne odor pollutant is scattered in the air once again, crosses over the region-wide dispersity that roughly forms homogenization of the catalyst carrier 44 in downstream.
Secondly, from the air that the catalyst carrier 44 in downstream is emitted, be conducted to second heating part 50.
At this moment, the air of emitting from the catalyst carrier 44 in downstream is by than the catalyst carrier 44 in the downstream through hole 56 of the liner 58 of path more, so be subjected to confusing effect this moment.
Secondly, flow into the air of second heating part 50, be heated once again.
Then, the air of emitting from second heating part 50 is disturbed second indoor 60 by the member 61 that confuses air flow.About 280 ℃~330 ℃ of the ambient temperature of second Room 60.
At this moment, be heated to about 280 ℃~about 330 ℃ air once again, in second Room 60, be disturbed by the member 61 that confuses air flow.Promptly, discharge from second heating part 50 and to be heated to about 280 ℃~about 330 ℃ air, by than the internal diameter of the body 52 through hole 62a of the liner 62 of path more, so in the downstream of liner 62, produce eddy current, confuse the air after being heated, airborne odor pollutant is more effectively disperseed, and then, can give air with confusing effect equally by the shield 64 in downstream.Therefore, import the airborne odor pollutant of the second stench purification portion 70, the whole district of catalyst carrier 73 of crossing over the inflow side of the second stench purification portion 70 roughly forms the dispersity of homogenization.
Secondly, catalyst carrier 73 makes catalyst activityization by heated air, promotes the deodorize processing of airborne odor pollutant.
Then, the air from catalyst carrier 73 is emitted is disturbed once again by the 75 formed spaces of the spacer member between the catalyst carrier 74 that is provided in the downstream, afterwards, imports the catalyst carrier 74 in downstream.Therefore, airborne odor pollutant is scattered in the air once again before the catalyst carrier 74 that flows into the downstream, and the whole district of crossing over the catalyst carrier 74 in downstream roughly forms the dispersity of homogenization.
Secondly, the air from the catalyst carrier 74 in downstream is discharged is discharged from from air leading-out portion 80.
As more than, if according to this example, what then be imported into contains mephitic air, via: be heated to about 280 ℃~about 330 ℃ in first heating part 20, as the operation of easy deodorize condition of stage in the back; In first Room 30, confuse, odor pollutant is scattered in the air equably, the operation that the first stench purification portion 40 by last stages is handled as deodorize easily by the member 31 that confuses air flow; Under this state, import the catalyst carrier 43 of the upstream side of the first stench purification portion 40, accept the operation that effective deodorize is handled by catalyst, accepting the previous stage that effective deodorize is handled by the catalyst on the catalyst carrier 44 in downstream, bear the effect of confusing once again, with the dispersive once again operation of odor pollutant; Bear the operation that effective deodorize is handled by the catalyst on the catalyst carrier 44 in downstream; Be heated to about 280 ℃~about 330 ℃ once again in second heating part 50, make the operation of the residual easy deodorize of odor pollutant; Confuse by the member 61 that confuses air flow in second Room 60, residual odor pollutant is scattered in the air once again equably, the second stench purification portion 70 by after-stage is handled deodorize and is easy to operation; Under this state, import to the catalyst carrier 73 of the upstream side of the second stench purification portion 70, accept the operation that effective deodorize is handled by catalyst, accepting the previous stage that effective deodorize is handled by the catalyst on the catalyst carrier 44 in downstream, bear the effect of confusing once again, make the dispersed once again operation of odor pollutant; And, bear the operation that effective deodorize is handled by the catalyst on the catalyst carrier 44 in downstream; And be discharged from, so contain the air of odor pollutant, after heating through be disturbed for several times with the first stench purification portion 40 and the second stench purification portion 70 in proposed effectively deodorize by the contacting efficiency of the catalyst of activation.
Its result, will contain the air heat of odor pollutant after, in single previous device that only carries out deodorize with the stench purification portion and the remarkable removal of the methanthiol that can't obtain becomes possibility.
By the way, if according to this example, the airborne odor pollutant in the time of then will importing, by 3 comparison expression odor bag methods (outlet method) when testing, the odor concentration 550 of odor concentration 55000 that can be when importing during as derivation.During methanthiol when deriving according to gas chromatography (gaschromatography) (FPD method) instrumentation again: 0.6PPM~0.04PPM is<0.0001PPM (odor strength 1: but the degree of inadequate perception of malodor).That is, but when deriving about about 85% of the deodorize odor pollutant.In addition, previous device: be about 50~60% the rate of removing.
In addition, this example, each liner 12,32,44,62,82, for be provided with 1 through hole 22a, 32a, 44a, 62a, the situation of 82a is described, but also several through hole can be set.
For example, as shown in Figure 8, liner 12 matches with the shape of the bobbin 25 of first heating part 20, for guiding air easily, is provided with 4 through hole 12b, 12c, 12d, 12e, also can be provided with pressure bar (the giving as security the エ rod) 12f that is connected to bobbin 25 in central authorities.
As shown in Figure 9, liner 32, match with the shape of the bobbin 25 of first heating part 20, in order to guide air easily, be provided with 4 through hole 32b, 32c, 32d, 32e, be provided with the pressure bar 32f that is connected to bobbin 25 in central authorities, also can confuse the member 31 of air flow in the opposition side setting of pressure bar 32f.In addition, liner 62 also can be same with Fig. 9 conduct.
As shown in figure 10, liner 44, match with the shape of the bobbin 25 of first heating part 20, in order to guide air easily, be provided with 4 through hole 44b, 44c, 44d, 44c, be provided with pressure bar 44f, 44g, 44h, the 44i of the catalyst carrier 44 that is connected to the downstream in central authorities, also can be at pressure bar 44f, 44g, 44h, 44i, the opposition side setting be connected to the pressure bar 44j of the bobbin 55 of second heating part 50.
As shown in figure 11, liner 72 matches with the shape of the bobbin 25 of first heating part 20, for guiding air easily, be provided with 4 through hole 72b, 72c, 72d, 72e, pressure bar 74f, 74g, 74h, the 74i of the catalyst carrier 74 that is connected to the downstream also can be set in central authorities.
Again, shield 34,64 is described for the situation that is provided with through hole 34a, 64a, but is provided with rising portions (for example in the downstream of through hole 34a, 64a, by plunging processing etc. to be formed), and then also can be used as and give the shape of air flow easily with rotating flow.
Again, the spacer member 45,75 that separates the catalyst carrier 43,44,73,74 in the first stench purification portion 40 and the second stench purification portion 70 can have arbitrarily angled and then as the shape of giving air flow with rotating flow easily too.
Again, the first stench purification portion 40 and the second stench purification portion 70 are described for the situation of using 2 catalyst carrier 43,44,73,74 respectively, but also can constitute with 1 catalyst carrier respectively.
In addition, the deodorizer 1 of relevant above-mentioned example, binding has: import the air introduction part 10 that contains mephitic air; Be connected in first heating part 20 of air introduction part 10; Be positioned at first Room 30 in the downstream of first heating part 20; Be positioned at the first stench purification portion 40 in the downstream of first Room 30; Be positioned at second heating part 50 in the downstream of the first stench purification portion 40; Be positioned at second Room 60 in the downstream of second heating part 50; Be positioned at the second stench purification portion 70 in the downstream of second Room 60; And, be positioned at the air leading-out portion 80 in the downstream of the second stench purification portion 70, and will center on urceolus 2 around these and constitute, but also can omit second heating part 50, second Room 60 and the second stench purification portion 70, in the downstream of the first stench purification portion 40 air leading-out portion 80 is installed.
Figure 12 to Figure 13 is the deodorizer 100 that shows relevant other embodiments of the present invention.
The deodorizer 100 of relevant this example, in first heating part 120 and second heating part 150, curls inward has electric heater 124,154 these points, and is different with deodorizer 1.Therefore, other formations, identical with deodorizer shown in Figure 1, so give same numbering in same formation.
At first, first heating part 120, it constitutes: be provided with the metal body 122 of flange 123 at two ends and be equipped on electric heater 124 in this body 122.Electric heater 124, it constitutes: have the bobbin cylindraceous 125 of the heater coil coiling 125a of portion and be wound in the heater coil 126 of the heater coil coiling 125a of portion at inner face.The terminal 127 of electric heater 124 connects body 122 and is directed at outside power supply.
Be located at the liner 112 of the importing side 121 of first heating part 120, being situated between at the through hole 112a that is located at central authorities is provided with rod member 122c by support rod 112b.
Secondly, second heating part 150, it constitutes: be provided with at both ends flange 153 metal body 162, and, be equipped on the electric heater 154 in this body 152.Electric heater 154, it constitutes: have the bobbin cylindraceous 155 of the heater coil coiling 155a of portion and be wound in the heater coil 156 of the heater coil coiling 155a of portion at inner face.The terminal 157 of electric heater 154 connects body 152 and is directed at outside power supply.
Be located at the liner 158 of the importing side of second heating part 150, same with liner 112, being situated between on the through hole 158a that is located at central authorities is provided with rod member 158c by support rod 158b, is provided with pressure bar 158d with catalyst carrier 44 butts in downstream at the opposition side of rod member 158c.
As described above, present embodiment, first heating part 120 and second heating part 150, because employing constitutes curls inward electric heater 124,154 is arranged, so between the rod member 112,158c and the bobbin 125,165 that are provided with respectively on the liner 112,158, form the wind direction tube, can the air that import is side directed towards downstream energetically.
Its result, air forms with electric heater 124,154 and directly contacts, and can improve the thermal efficiency.
The deodorizer of other action effects and Fig. 1 is same.
Again, in this example: for example, also can be same with the various changes among Fig. 8 to Figure 11.
In addition, the deodorizer 100 of relevant above-mentioned example, binding has: import the air introduction part 10 that contains mephitic air; Be connected in first heating part 120 of air introduction part 10: first Room 30 that is positioned at the downstream of first heating part 120; Be positioned at the first stench purification portion 40 in the downstream of first Room 30; Second heating part 150 that is positioned at the downstream of the first stench purification portion 40 is positioned at second Room 60 in the downstream of second heating part 150; Be positioned at the second stench purification portion 70 in the downstream of second Room 60; And, be positioned at the air leading-out portion 80 in the downstream of the second stench purification portion 70, and will center on urceolus 2 around these and constitute, but also can omit second heating part 150, second Room 60 and the second stench purification portion 70 are installed air leading-out portion 80 in the downstream of the first stench purification portion 40.
Figure 24 is the deodorization device 200 that deodorizer 1 (or deodorizer 100) is used in expression.
The deodorization device 200 of relevant this example, it constitutes: the air that is linked to the air introduction part 10 of deodorizer 1 (or deodorizer 100) imports with pipe arrangement 210; Fortune is tied in the air of the air leading-out portion 80 of deodorizer 1 (or deodorizer 100) and is derived with pipe arrangement 220; Derive with pipe arrangement 220 with pipe arrangement 210 and air in conjunction with the air importing, the air heat that recovery is emitted with pipe arrangement 220 from the air derivation adds warm air and imports with the air-cooled heat exchanger 230 that contains mephitic air in the pipe arrangement 210; Jie is connected in the exhaustor 240 that air is derived the air vent 310 of using pipe arrangement 220 and domestic garbage treatment machine 300 by this heat exchanger 230.
Heat exchanger 230 is to import the outer tube 231 of using pipe arrangement 210 and exhaustor 240 with connecting air, and is connected in the air derivation air type heat exchanger of the interior pipe 232 of pipe arrangement 220 as the structure of the double pipe on concentric circular.The both ends of heat exchanger 230 are blocked, and are provided with the blow-off outlet 233 that possesses air propeller 234 in the downstream.
Therefore, at heat exchanger 230, the air that is imported into from exhaustor 240, being heated to import by air by flow air in the pipe 232 in flowing passes out to deodorizer 1 (or deodorizer 100) with pipe arrangement 210.
Secondly, the effect of the deodorization device 200 of relevant this example is illustrated.
At first, contained the odor pollutant air from what the air vent 310 of domestic garbage treatment machine 300 discharged, the fan that is had by domestic garbage treatment machine 300 is blown into, and then passes through the attraction of the air propeller 234 of heat exchanger 30, is drawn into deodorizer 1 (or deodorizer 100).
Secondly, be drawn into the air of deodorizer 1 (or deodorizer 100), in deodorizer 1 (or deodorizer 100), be subjected to handling, by deodorize as above-mentioned deodorize.
Then, the air after the deodorize carries out heat exchange and is cooled to about about 40 ℃ with the air that is fed to deodorizer 1 (or deodorizer 100) in heat exchanger 230, is discharged in the atmosphere by air propeller 234.
As described above, if according to this example, the air that contains odor pollutant of being discharged then from the air vent 310 of domestic garbage treatment machine 300, the fan that is had by domestic garbage treatment machine 300 and the air propeller 234 of heat exchanger 230, blown into certain flow towards deodorizer 1 (or deodorizer 100) is forcibly stable, in deodorizer 1 (or deodorizer 100) as oneself states, acceptance reduces airborne methanthiol after about deodorization functions of about 85%, carry out heat exchange by heat exchanger 20 and the air of newly sending to deodorizer 1 (or deodorizer 100), dropping to about about 40 ℃ temperature that human body is not almost had an influence can be released in the atmosphere, so, can help in the past because the domestic garbage treatment machine 300 that airborne odor pollutant is kept someone at a respectful distance universal.
And the deodorization device 200 of relevant this example can dispose air arbitrarily and import with pipe arrangement 210, and air is derived with pipe arrangement 220 and air-cooled heat exchanger 230, thus space especially, even narrow place also can be provided with easily.
In addition, this example is described for the situation that is applicable to domestic garbage treatment machine 300, but the present invention is not limited thereto, and also can be connected with the air vent from taking-up air such as food processing industry, compost factories.
Figure 25 shows the deodorize bactericidal device 400 that uses deodorizer 1 (or deodorizer 100).
The deodorize bactericidal device 400 of relevant this example possesses: deodorizer 1 (or deodorizer 100); Possess suction unit 402 and exhaust portion 403, take in the inner pressurd vessel 401 of deodorizer 1 (or deodorizer 100); The suction fan 404 that possesses the suction unit 402 of inner pressurd vessel 401; Possess suction unit 406 and exhaust portion 407, take in the outer container 405 of inner pressurd vessel 401; Be equipped in the inner pressurd vessel 401, reclaim the air heat of being emitted and add the mephitic air that contains in the warm air introduction part 10 from the air leading-out portion 80 of deodorizer 1 (or deodorizer 100), and the air of being emitted is directed at the air-cooled heat exchanger 410 of the exhaust portion 403 of inner pressurd vessel 401 from the air leading-out portion 80 of deodorizer 1 (or deodorizer 100); Be formed between inner pressurd vessel 401 and the outer container 405, the air that is imported be directed at first air suction way 415 of the suction unit 402 of inner pressurd vessel 401 from the suction unit 406 of outer container 405; Be formed between inner pressurd vessel 401 and the outer container 405, be directed at second air suction way 416 in the air-cooled heat exchanger 410; The air of being discharged is directed at the 3rd air suction way 417 of the air introduction part 10 of deodorizer 1 (or deodorizer 100) from air-cooled heat exchanger 410; Be directed at the air flue 418 of the exhaust portion 407 of outer container 405; And be located at the exhaust fan 419 of the exhaust portion 407 of outer container 405.
In this, inner pressurd vessel 401 is made of suction unit 402 that has in upper portion side wall and the cylindrical body that has the lengthwise of exhaust portion 403 on top.
Outer container 405 is made of the cylindrical body that possesses suction unit 406 at lower sides and possess the lengthwise of exhaust portion 407 on top.
Deodorizer 1 (or deodorizer 100) is equipped on the lower side of inner pressurd vessel 401 with air introduction part 10, and air leading-out portion 80 is equipped on the upper side of inner pressurd vessel 401.
In deodorize bactericidal device 400, the bottom that seat 420 is used for blocking inner pressurd vessel 401 and outer container 405 is installed.
Do not flow in the form of air flue 418 with the air that is directed into first air suction way 415, between inner pressurd vessel 401 and outer container 405, be provided with spaced walls 421.
The air that is directed in second air suction way 416 is provided with spaced walls 422 not flow in the 3rd air suction way 417 in inner pressurd vessel 401.
Air flue 318, the air that is imported into can unresistedly be discharged by exhaust fan 419, is provided with gap 423 in a part and is connected with first air suction way 415.
Air-cooled heat exchanger 410, different with air-cooled heat exchanger 230 shown in Figure 24, formation will be discharged in air flue 418 from top by inner aerofluxus.That is, get into air from suction unit 411, exhaust heat is captured at this in the space in the outside by being located at exhaust channel, is led in the 3rd air suction way 417 by fan 413 from exhaust portion 412.
Below, the effect of the relevant deodorize bactericidal device 400 of the present embodiment of such formation is described.
At first, give first heating part 20 (120), second heating part 50 (150), suction fan 404 and discharge fan 419 energisings, starting deodorizer 1 (or deodorizer 100).
Like this, the surrounding air of deodorize bactericidal device 400 is inhaled into from the suction unit 406 of outer container 405, is situated between by first air suction way 415, the drawing fan 404 of the suction unit 402 by being located at inner pressurd vessel 401 is fed in second air suction way 416 from suction unit 402.
Secondly, air in second air suction way 416, imported in the air-cooled heat exchanger 410 by suction unit 411 from air-cooled heat exchanger 410, here and the aerofluxus of internal flow between carry out heat exchange, absorb deflated heat and be imported in the 3rd air suction way 417 from exhaust portion 412 by fan 413.
Secondly, air in the 3rd air suction way 417, be directed in the deodorizer 1 (or deodorizer 100) from the air introduction part 10 of deodorizer 1 (or deodorizer 100), make airborne stench by deodorize, the bacterium that swims is sterilized be discharged in the air-cooled heat exchanger 410 from air leading-out portion 80.
Then, discharge the air in air-cooled heat exchanger 410, in air-cooled heat exchanger 410, capture heat, be directed at air flue 418, be discharged from by the exhaust portion 407 of exhaust fan 419 from outer container 405 by exhaust fan 419.
If deodorize bactericidal device 400 according to relevant this example, then by deodorizer 1 (or deodorizer 100), air is warmed to 280 ℃~330 ℃, for example, with the antibacterial of airborne virus etc., mycete, tick, pollen, dust, dust etc. by the burning sterilization, purify, and can carry out deodorize by oxidation catalyst.
And then, be illustrated, can reach following effect,
For example,, then in smoking room, be contained in the unpleasant composition (ammonia, acetaldehyde, acetic acid etc.) in the cigarette of medicated cigarette, come deodorize, be contained in the carbon monoxide in the cigarette, be broken down into carbon dioxide and water by deodorizer 1 (or deodorizer 100) if smoking room in the office is set.Simultaneously, can bring into play peace and quiet air and effect on moisture extraction.
Relatively, in the past ion, plasma mode device, can not remove the unpleasant composition (ammonia, acetaldehyde, acetic acid etc.) in the cigarette that in smoking room, is contained in medicated cigarette, and be contained in the carbon monoxide in the cigarette.
Again, be arranged in the family of pet shop, pets hospital, pet feeding, but the stink of the distinctive body odor of deodorize animal, fecaluria then.By suppressing the breeding of assorted bacterium, kill the health control that dermatosis antibacterial or indoor infectious bacteria promote animal again.
Again, as be arranged at nursing house, from residence nurse old man's room, then can become odorless with become the body odor composition " nonenal " that body odor changes (aged smelly) reason owing to the age.Again, can be used to catch a cold the extremely infectious bacteria of bacterium etc. or assorted bacterium etc.The foul smell in room can be become odorless again.
Again, be arranged at hospital, then can be used to the stink of deodorize ward, dirt processing, rubbish place to place, can carry out the deodorize in toilet, public lavatory, bathroom etc., sterilization.Particularly also can kill tulase, the bacterium that swims in the air that the yellow staphylococcus of methicillin BRL-1241 durability (the yellow Block De of メ チ シ リ Application durability ウ shape coccus) (MRSA) is waited also can help the prevention superinfection in the hospital greatly.
Again, be arranged at food processing factory etc., then can be used to deodorize at the abnormal smells from the patient of the strong vegetable of tastes such as the foul smell of a large amount of edible meat of preserving the place that food process, fish, Bulbus Allii etc.Again, aspect administration of health, have bactericidal effect, can be used as preventive measure and make very big contribution swim in airborne 0-157 or mycete, assorted bacterium etc.
Again, be arranged at newly-built family or have in the house etc. of furniture, the material that causes house syndrome (sick-house) (bonding agent, coating etc.) on newly-built family or furniture is entangled with in then oxidable decomposition.
Again, be arranged at enzyme bathing pool (ferment plain Wind Lu), total beauty salon (エ ス テ テ ィ ッ Network サ ロ Application), bathroom, dressing cubicle etc., then can reduce because the stench of the antiperspirant of user or metabolic waste oxidasic former thereby the ammonia that causes, hydrogen sulfide etc.By bactericidal action, can realize happiness balneation easily again.
Again, be arranged at factory, operation place etc., but then the cutting oil in the deodorize workshop, grind the corrupt stench of cutting wet goods, the peculiar foul smell that sends in the foul smell gas that comes out based on the drying oven of new material, materials processing etc.
In addition, in this example, deodorizer 1 (or deodorizer 100), as above-mentioned, be not limited to Fig. 1 or device shown in Figure 12, also can omit second heating part 50 (150), second Room 60 and the second stench purification portion 70 are installed air leading-out portion 80 in the downstream of the first stench purification portion 40.
Utilize possibility on the industry
If according to the present invention, can make the sky that contains odor pollutant from discharges such as domestic garbage treatment machines The odor concentration of gas becomes one of percentage. That is, make containing from discharges such as domestic garbage treatment machines The odor pollutant air, become for people's insentience strong close to 550 times of odor concentrations, the foul smell of odorless The air of the concentration<0.0001PPM of degree 1, methyl mercaptan.
According to the present invention, then can be used to sterilization, purify and to be present in airborne virus etc. again, Bacterium, mould, tick, pollen, dust, dust etc., and it is airborne to can be used to deodorization Odor pollutant.

Claims (6)

1, a kind of deodorizer, possessing has:
Importing contains the air introduction part of mephitic air;
Be connected in aforementioned air introduction part, be provided in the inner face of bobbin or electric heater that outside coiling heater coil forms and first heating part that constitutes;
Be positioned at first Room in the downstream of aforementioned first heating part;
Be positioned at the first stench purification portion in the downstream of aforementioned first Room;
Be positioned at second heating part in the downstream of the aforementioned first stench purification portion;
Be positioned at second Room in the downstream of aforementioned second heating part;
Be positioned at the second stench purification portion in the downstream of aforementioned second Room; And,
Be positioned at the air leading-out portion in the downstream of the aforementioned second stench purification portion;
It is characterized by, aforementioned first heating part is equipped with the member that confuses air flow on the position that connects the aforementioned air introduction part and first Room respectively;
Aforementioned first Room and aforementioned second Room are equipped with the member that confuses the air flow after being heated;
Aforementioned first stench purification portion and the aforementioned second stench purification portion are to set the ceramic of the honeycomb shape of carrying catalyst or metal 2 catalyst carriers with predetermined space and constitute.
2, a kind of deodorization device is characterized by, and possessing has:
The deodorizer that claim 1 is put down in writing;
The air that is used for connecting the air introduction part of discharging aforementioned exhaust portion that contains mephitic air and aforementioned deodorizer imports uses pipe arrangement;
Connect the air leading-out portion of aforementioned deodorizer, and set the air derivation pipe arrangement that sucking-off constitutes with fan;
Recovery is derived the air heat of emitting with pipe arrangement from aforementioned air and is heated aforementioned air importing with the air-cooled heat exchanger that contains mephitic air in the pipe arrangement.
3, a kind of deodorize bactericidal device is characterized by, and possessing has:
Deodorizer, it has and imports air introduction part, the heating part that is connected in aforementioned air introduction part, the chamber that is positioned at the downstream of aforementioned heating part, the stench purification portion that is positioned at the downstream of chamber contain mephitic air, the air leading-out portion that is positioned at the downstream of aforementioned stench purification portion; And,
Possess suction unit and exhaust portion, take in the inner pressurd vessel of aforementioned deodorizer;
The suction fan that is provided with in the suction unit of aforementioned inner pressurd vessel;
Possess suction unit and exhaust portion, take in the outer container of aforementioned inner pressurd vessel;
Be equipped in the aforementioned inner pressurd vessel, the air heat that recovery is emitted from the aforementioned air leading-out portion of the aforementioned deodorizer mephitic air that contains in the aforementioned air introduction part of heating, and will be directed at the air-cooled heat exchanger of the exhaust portion of aforementioned inner pressurd vessel from the air that the aforementioned air leading-out portion of aforementioned deodorizer is emitted;
Be formed between aforementioned inner pressurd vessel and the aforementioned outer container, the air that will import from the suction unit of aforementioned outer container is directed at the air suction way of aforementioned air-cooled heat exchanger;
Be formed between aforementioned inner pressurd vessel and the aforementioned outer container, will be directed at the air flue of the exhaust portion of aforementioned outer container from the air that aforementioned air-cooled heat exchanger is discharged; And,
Be located at the air propeller of aforementioned air flue.
4, the deodorize bactericidal device of putting down in writing as claim 3 is characterized by,
Aforementioned outer container, by possessing aforementioned suction unit at lower sides, and the lengthwise cylindrical body that possesses aforementioned exhaust portion on top constitutes,
Aforementioned inner pressurd vessel, by possessing aforementioned suction unit in upper portion side wall, and the lengthwise cylindrical body that possesses aforementioned exhaust portion on top constitutes,
Aforementioned deodorizer is the lower side that aforementioned air introduction part is equipped on aforementioned inner pressurd vessel, and aforementioned air leading-out portion is equipped on the upper side of aforementioned inner pressurd vessel.
5, a kind of deodorize bactericidal device, possessing has,
Importing contains the air introduction part of mephitic air;
Be connected in aforementioned air introduction part, be equipped with the electric heater that inner face or outside coiling heater coil at bobbin form and first heating part that constitutes;
Be positioned at first Room in the downstream of aforementioned first heating part;
Be positioned at the first stench purification portion in the downstream of aforementioned first Room;
Be positioned at second heating part in the downstream of the aforementioned first stench purification portion;
Be positioned at second Room in the downstream of aforementioned second heating part;
Be positioned at the second stench purification portion in the downstream of aforementioned second Room;
Be positioned at the air leading-out portion in the downstream of the aforementioned second stench purification portion; It is characterized by,
Aforementioned first heating part is equipped with the member that confuses air flow on the position that connects the aforementioned air introduction part and first Room respectively;
Aforementioned first Room and aforementioned second Room are equipped with the member that confuses the air flow after being heated; And have:
Aforementioned first stench purification portion and the aforementioned second stench purification portion set ceramic or metal 2 deodorizers that catalyst carrier forms of the honeycomb shape of carrying catalyst with predetermined space;
Possess suction unit and exhaust portion, take in the inner pressurd vessel of aforementioned deodorizer;
The suction fan that is provided with in the suction unit of aforementioned inner pressurd vessel;
Possess suction unit and exhaust portion, take in the outer container of aforementioned inner pressurd vessel;
Be equipped in the aforementioned inner pressurd vessel, the air heat that recovery is emitted from the aforementioned air leading-out portion of the aforementioned deodorizer mephitic air that contains in the aforementioned air introduction part of heating, and will be directed at the air-cooled heat exchanger of the exhaust portion of aforementioned inner pressurd vessel from the air that the aforementioned air leading-out portion of aforementioned deodorizer is emitted;
Be formed between aforementioned inner pressurd vessel and the aforementioned outer container, the air that will import from the suction unit of aforementioned outer container is directed at the air suction way of aforementioned air-cooled heat exchanger;
Be formed between aforementioned inner pressurd vessel and the aforementioned outer container, will be directed at the air flue of the exhaust portion of aforementioned outer container from the air that aforementioned air-cooled heat exchanger is discharged; And,
Be located at the air propeller of aforementioned air flue.
6, the deodorize bactericidal device of putting down in writing as claim 5 is characterized by,
Aforementioned outer container, by possessing aforementioned suction unit at lower sides, and the lengthwise cylindrical body that possesses aforementioned exhaust portion on top constitutes,
Aforementioned inner pressurd vessel, by possessing aforementioned suction unit in upper portion side wall, and the lengthwise cylindrical body that possesses aforementioned exhaust portion on top constitutes,
Aforementioned deodorizer is the lower side that aforementioned air introduction part is equipped on aforementioned inner pressurd vessel, and aforementioned air leading-out portion is equipped on the upper side of aforementioned inner pressurd vessel.
CNB028045122A 2001-12-14 2002-12-12 Deodorizer, deodorizing apparatus, and deodorizing and bacteria removing apparatus Expired - Fee Related CN1272073C (en)

Applications Claiming Priority (2)

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JP382129/2001 2001-12-14

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KR (1) KR100527263B1 (en)
CN (1) CN1272073C (en)
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KR100499725B1 (en) * 2004-12-01 2005-07-05 주식회사 엔유씨전자 Food garbage disposer
KR100775907B1 (en) * 2006-11-23 2007-11-15 원제군 Garbage deodorizer device

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JPH0898875A (en) * 1994-09-30 1996-04-16 Mugen Eng Kk Sterilization/deodorization and device therefor
JPH10232481A (en) * 1997-02-20 1998-09-02 Konica Corp Photosensitive material processor
JPH11223368A (en) * 1998-02-10 1999-08-17 Matsushita Electric Ind Co Ltd Air cleaner
CN1313731A (en) * 1999-06-08 2001-09-19 三洋电机株式会社 Hair dryer
JP2001259006A (en) * 2000-03-22 2001-09-25 Daikin Ind Ltd Deodorizing device
JP2001269394A (en) * 2000-03-28 2001-10-02 Matsushita Electric Ind Co Ltd Deodorization apparatus and refuse processor using it
JP2001299880A (en) * 2000-04-18 2001-10-30 Hideki Kurihara Deodorizing device
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TW200301143A (en) 2003-07-01

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