CN1271990C - Liquid cosmetics - Google Patents
Liquid cosmetics Download PDFInfo
- Publication number
- CN1271990C CN1271990C CNB031193587A CN03119358A CN1271990C CN 1271990 C CN1271990 C CN 1271990C CN B031193587 A CNB031193587 A CN B031193587A CN 03119358 A CN03119358 A CN 03119358A CN 1271990 C CN1271990 C CN 1271990C
- Authority
- CN
- China
- Prior art keywords
- composition
- ascorbic acid
- liquid make
- sodium
- ascorbyl phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61G—TRANSPORT, PERSONAL CONVEYANCES, OR ACCOMMODATION SPECIALLY ADAPTED FOR PATIENTS OR DISABLED PERSONS; OPERATING TABLES OR CHAIRS; CHAIRS FOR DENTISTRY; FUNERAL DEVICES
- A61G5/00—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs
- A61G5/02—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs propelled by the patient or disabled person
- A61G5/024—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs propelled by the patient or disabled person having particular operating means
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61G—TRANSPORT, PERSONAL CONVEYANCES, OR ACCOMMODATION SPECIALLY ADAPTED FOR PATIENTS OR DISABLED PERSONS; OPERATING TABLES OR CHAIRS; CHAIRS FOR DENTISTRY; FUNERAL DEVICES
- A61G5/00—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs
- A61G5/08—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs foldable
- A61G5/0875—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs foldable dismountable, e.g. where the wheelchair can be disassembled for transportation or storage
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61G—TRANSPORT, PERSONAL CONVEYANCES, OR ACCOMMODATION SPECIALLY ADAPTED FOR PATIENTS OR DISABLED PERSONS; OPERATING TABLES OR CHAIRS; CHAIRS FOR DENTISTRY; FUNERAL DEVICES
- A61G5/00—Chairs or personal conveyances specially adapted for patients or disabled persons, e.g. wheelchairs
- A61G5/10—Parts, details or accessories
- A61G5/1005—Wheelchairs having brakes
- A61G5/101—Wheelchairs having brakes of the parking brake type, e.g. holding the wheelchair
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Cosmetics (AREA)
Abstract
The present invention provided a liquid cosmetic having excellent sense of use even in the presence of a water-soluble L-ascorbic acid derivative. The liquid cosmetic comprises (a) a specific polyoxypropylene diglyceryl, (b) 0.5-5 wt.% of the water-soluble L-ascorbic acid derivative, (c) one or more kinds of polyhydric alcohols containing three or more hydroxy groups as essential components and (d) ethanol in the content mass ratio of the component (a) to the component (b) of 1:10-10:1.
Description
Technical field
The present invention relates under the situation that the water solublity L-ascorbic acid derivates that uses as whitening composition exists, have high moistening effect and skin care effect and the usability better fluid cosmetics of the sensation that is not clamminess.
Background technology
Water solublity ascorbic acid derivates in the past has good whitening effect because of it, and is widely used in preparing cosmetics.But, if these cosmetics contain a large amount of water miscible L-ascorbic acid derivates, will produce the sensation of unique sensation that is clamminess and formation mucosa, feeling after the use is very bad.In order to obtain good usability, prior art has adopted the method for high molecular weight materials such as sneaking into water soluble polymer, wax, powder respectively and has sneaked into the sensation that the method for wet goods lubricant suppresses to be clamminess.For example, can sneak into dextrin fatty acid ester (spy opens the claim and the technical field part of 2002-020529 communique), voluminous powder and/or water absorption powder (spy opens the claim and the technical field part of 2002-104919 communique), water soluble polyether dimethyl polysiloxane (spy opens the claim and the technical field part of 2000-290128 communique), silicone oil (spy opens the page 2 of 2001-151623 communique, goes to the 16th from upper right the 6th row) etc.
Summary of the invention
But, when these methods are used for mobile liquid make-up, the usability better fluid cosmetics of the very difficult technically sensation that obtains to have the skin care effect and be not clamminess.In view of the foregoing, the invention provides the usability better fluid cosmetics that contain water solublity L-ascorbic acid derivates.
The present inventor is for solving above-mentioned problem, further investigate, it found that, in the liquid make-up that contains water solublity L-ascorbic acid derivates, if contain polyoxypropylene diglycerol and polyhydric alcohol with three above hydroxyls, just can obtain good usability, finish the present invention thus.
That is, the present invention relates to liquid make-up, this liquid make-up contains the following ingredients (a)~(c) as neccessary composition:
(a) polyoxypropylene diglycerol,
(b) the water solublity L-ascorbic acid derivates of 0.5~5 quality %,
(c) has the polyhydric alcohol of three above hydroxyls.
And, the present invention relates to also contain the alcoholic acid liquid make-up of composition (d), and the mass ratio that relates to composition (a) and composition (b) is 1: 10~10: 1 a liquid make-up.
Below composition of the present invention is described.
The composition that uses among the present invention (a) polyoxypropylene diglycerol is used to suppress the sensation that is clamminess that composition (b) water solublity L-ascorbic acid derivates is produced.Composition (a) is for having the material as the structure of following general formula 1 expression.Composition (a) is the chemical compound that the addition polymerization oxypropylene obtains in the diglycerol, there is no particular limitation to the average addition molal quantity of oxypropylene, but consider from the effect of the sensation that suppresses to be clamminess, with respect to per 1 mole of diglycerol, preferred 5~20 moles average addition molal quantity.
[general formula 1]
(preferred m+n+o+p=5~20)
Can select one or more described polyoxypropylene diglycerols to be used in combination as required.The example of the commercial articles of described composition (a) such as Savondol GP-9 (Japanese oils and fats), PristolDGP-09 (ミ ヨ シ oils and fats), SY-DP9, SY-DP14 (above is the preparation of this pharmaceutical industries of slope) etc.
With respect to the gross mass of liquid make-up, the content of the composition that uses among the present invention (a) is preferably 0.001~30 quality % (following usefulness " % " expression, " the quality % " in this description and " weight % " same meaning.), more preferably 0.1~10%.In this scope, can obtain having the good skin care and the liquid make-up of moistening effect.
The composition that uses among the present invention (b) water solublity L-ascorbic acid derivates is used to give the whitening effect of cosmetics, itself so long as water-soluble substances just there is no particular limitation.Its concrete example as, L-sodium ascorbate, L-potassium ascorbate, L-Magnesium ascorbate, L-sodium ascorbyl phosphate, L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate potassium, L-ascorbic acid sodium sulfate, L-ascorbic acid magnesium sulfate, L-ascorbic acid potassium sulfate etc.Wherein, from the self stability of medicament and the simplicity when mixing consider preferred L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate, L-ascorbic acid sodium sulfate.Can select one or more described combinations of substances to use as required.
With respect to the gross mass of liquid make-up, the content of the composition that uses among the present invention (b) is preferably 0.5~5%, and more preferably 1~3%.In this scope, can obtain having good whitening effect and skin care effect and the moisture retention better fluid cosmetics of the sensation that is not clamminess.
The polyhydric alcohol that the composition that uses among the present invention (c) has three above hydroxyls is used to give the moistening effect of cosmetics.Described intramolecularly has the glycerol that contract such as the example of polyhydric alcohol of three above hydroxyls such as glycerol, diglycerol, triglycerin, four glycerol, maltose, maltose alcohol, sucrose, fructose, xylitol, Sorbitol, maltotriose, erithritol and their polythene derivative, glucosan derivative etc. more.Wherein, consider that preferred intramolecularly has the polyhydric alcohol of 3~10 hydroxyls from moistening effect.Can use one or more described polyhydric alcohol as required with three above hydroxyls.
With respect to the gross mass of liquid make-up, the content of described composition (c) is preferably 0.001~30%, and more preferably 0.1~10%.In this scope, can obtain moistening effect especially fully.
Because liquid make-up of the present invention contains mentioned component (a)~(c), and has good usability.Because liquid make-up of the present invention also contains composition (d) ethanol, and the sensation that has better skin care effect and more can suppress to be clamminess.With respect to the gross mass of liquid make-up, the content of described composition (d) is preferably 1~30%, and more preferably 3~20%.
And, if the mass ratio (a) of mentioned component (a) and composition (b):, more preferably in 1: 5~5: 1 scopes, just can suppress the sensation that is clamminess better, and further improve effect of the present invention (b) at 1: 10~10: 1.(" mass ratio " and " weight ratio " same meaning in this description.)
In addition, the liquid condition of liquid make-up of the present invention is meant when using to have mobile state under general state, and its viscosity number at 20 ℃ is 5~40,000mPas.Preferred 10~20,000mPas, more preferably 10~5, in the scope of 000mPas, be expected to obtain having the liquid make-up of good more usability.
There is no particular limitation to the compound method of liquid make-up of the present invention, but can suitably select according to the formula property of cosmetics.Have for instance, surfactant and oil preparation etc. is dissolved in the ethanol, be dispersed in the condensing method of preparing in the water then; With the method for the mechanical force preparation that utilizes high-pressure homogenizer etc. etc.
Liquid make-up of the present invention can also be as medical exterior-applied article and topical drug etc. except can be used as cosmetics.The example of described cosmetics comprises, various liquid preparations such as astringent, beautifying liquid, fragrant composition.And also available known method is made described liquid make-up in preparations such as spray, mousse, and it is immersed on non-woven fabrics etc. make the film like preparation.
In the scope that does not influence effect of the present invention, liquid make-up of the present invention can contain the composition that generally uses in the fields such as cosmetics, medical exterior-applied article and external pharmaceuticals.For example, surfactant, oil preparation, wetting agent, polymer substance, UV absorbent, multivalent intercalating agent, nertralizer, pH regulator agent, antioxidant, antibacterial, antiseptic, pigment, powder body, pigment, spice, drug effect agent etc. can suitably be used as required.
The specific embodiment
[embodiment]
The following examples have further described the present invention, but the present invention is not limited to these embodiment.
Embodiment 1~12 and comparative example 1~5; Astringent
The astringent of preparation composition as table 1 (embodiment) and table 2 (comparative example) shown in to usability, promptly has or not three of the sensation that is clamminess, skin care effect, moistening effects etc. to estimate.
Table 1
Composition | Embodiment (%) | ||||||||||||
1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | ||
1 | Polyoxypropylene (9) diglycerol | 1 | 1 | 1 | 10 | 0.3 | 10 | 1 | 0.5 | - | 1 | 1 | 10 |
2 | Polyoxypropylene (14) diglycerol | - | - | - | - | - | - | - | - | 1 | - | - | - |
3 | Glycerol | 5 | - | - | 5 | 5 | 5 | 5 | 0.5 | 5 | 5 | 5 | 5 |
4 | Maltose alcohol | - | 5 | - | - | - | - | - | - | - | - | - | - |
5 | Triglycerin | - | - | 5 | - | - | - | - | - | - | - | - | - |
6 | The L-magnesium ascorbyl phosphate | 3 | 3 | 3 | 3 | 3 | 1 | 1 | 0.5 | 3 | 3 | - | - |
7 | The L-sodium ascorbyl phosphate | - | - | - | - | - | - | - | - | - | - | 3 | 1 |
8 | Sodium citrate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
9 | Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
10 | Ethanol | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | - | 10 | 10 |
11 | Dipropylene glycol | - | - | - | - | - | - | - | - | - | 10 | - | - |
12 | Polyethylene glycol oxide (60) hardened castor oil | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
Composition (a)/composition (b) | 1/3 | 1/3 | 1/3 | 10/ 3 | 1/1 0 | 10/ 1 | 1/1 | 1/1 | 1/3 | 1/3 | 1/3 | 10/ 1 | |
Judge | Have or not the sensation that is clamminess | ◎ | ◎ | ○ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ |
The skin care effect | ◎ | ◎ | ◎ | ○ | ○ | ○ | ◎ | ◎ | ◎ | ○ | ◎ | ○ | |
Moistening effect | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ |
Table 2
Composition | Comparative example (%) | |||||
1 | 2 | 3 | 4 | 5 | ||
1 | Polyoxypropylene (9) diglycerol | - | - | 1 | 2 | 6 |
2 | Polyoxypropylene (14) diglycerol | - | - | - | - | - |
3 | Glycerol | - | 5 | - | 5 | 5 |
4 | Maltose alcohol | - | - | - | - | - |
5 | Triglycerin | - | - | - | - | - |
6 | The L-magnesium ascorbyl phosphate | 3 | 3 | 3 | 6 | 6 |
7 | The L-sodium ascorbyl phosphate | - | - | - | - | - |
8 | Sodium citrate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
9 | Pure water | Surplus | Surplus | Surplus | Surplus | Surplus |
10 | Ethanol | 10 | 10 | 10 | 10 | 10 |
11 | Dipropylene glycol | - | - | - | - | - |
12 | Polyethylene glycol oxide (60) hardened castor oil | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
Composition (a)/composition (b) | - | - | 1/3 | 1/3 | 1/1 | |
Judge | Have or not the sensation that is clamminess | × | × | ○ | × | △ |
The skin care effect | × | × | × | △ | × | |
Moistening effect | × | ○ | × | ○ | ○ |
Preparation method
A: with composition 1~9 at 40 ℃ of mixed dissolutions.
B: composition 10~12 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The decision method of usability
Usability (having or not the sensation, skin care effect, the moistening effect that are clamminess) after being coated in astringent on the skin by 10 professional judges' evaluations divides 5 ranks with following evaluation criterion, judges according to its average mark.
[evaluation criterion]
5 minutes: very good
4 minutes: good
3 minutes: general
2 minutes: bad
1 minute: very bad
[criterion]
◎: average mark is more than 4.5 minutes
Zero: average mark 3.5 minutes~4.5 minutes
△: average mark 2.5 minutes~3.5 minutes
*: average mark is below 2.5 minutes
The result who obtains by above evaluation methodology is as table 1, shown in the table 2.
Shown in the result of table 1, the astringent of the embodiment of the invention 1~12 even sneaked into water solublity L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate, also can obtain good usability.In contrast, the comparative example 1~5 of table 2 can not be met the astringent of all assessment items.
Embodiment 13: astringent
(composition) (%)
1, polyoxyethylene (60) hardened castor oil 0.3
2, the oil-soluble Radix Glycyrrhizae extract 0.01
3, vitamin E Nicotinate 0.01
4, ethanol 5.0
5, glycerol 10.0
6, polyoxyethylene (10) methyl glucosamine 2.0
7, the L-magnesium ascorbyl phosphate 3.0
8, polyoxypropylene (9) diglycerol 0.5
9, citric acid 0.01
10, sodium citrate 0.03
11, the Chamomile extracting solution 0.01
12, Garden lavender water 0.01
13, the L-arginine 0.1
14, antiseptic is an amount of
15, pure water surplus
Preparation method
A: with composition 1~4 at 40 ℃ of mixed dissolutions.
B: composition 5~15 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The astringent of embodiment 13 is to have the astringent that is clamminess and feels few, have the skin care effect abundant moistening effect, that produced by water solublity L-magnesium ascorbyl phosphate.
Embodiment 14: astringent
(composition) (%)
1, the different stearyl ether 0.1 of polyoxyethylene (40)
2, the different stearyl ether 0.05 of polyoxyethylene (20)
3, polyoxyethylene (6) alkyl (C12-18) ether phosphoric acid 0.1
4, olive oil 0.2
5, natural Vitamin E 0.2
6, the oil-soluble Herba Rosmarini Officinalis extract 0.01
7, vitamin E Nicotinate 0.01
8, ethanol 10.0
9, Sorbitol 3.0
10, polyoxypropylene (14) diglycerol 3.0
11, sodium citrate 0.5
12, sodium ethylene diamine tetracetate (EDT) 0.03
13, the Semen Coicis extracting solution 0.01
14, the Chamomile extracting solution 0.1
15, the L-magnesium ascorbyl phosphate 1.0
16, sodium pyroglutamate 0.2
17, sodium lactate 0.1
18, aqueous solution of sodium hyaluronate (1%) 2.0
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1~8 at 40 ℃ of mixed dissolutions.
B: composition 9~20 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The astringent of embodiment 14 is the astringent that is clamminess and feels few, have abundant skin moistening effect and long-time stability that is produced by water solublity L-magnesium ascorbyl phosphate.
Embodiment 15: beautifying liquid
(composition) (%)
1, the hydrogenation soybean phospholipid 1.0
2, polyoxyethylene (10) cholesterol ethers 0.03
3, ceramide 3 0.1
4, stearic acid 0.01
5, three (2 ethyl hexanoic acid) glyceride 0.05
6, the oil-soluble Radix Glycyrrhizae extract 0.01
7, vitamin A palmitate 0.01
8, dipropylene glycol 5.0
9, pure water 15.0
10, L-ascorbic acid sodium sulfate 1.0
11, sodium citrate 0.05
12, ethanol 3.0
13,, the Fructus cydoniae oblongae seed extract 15.0
14, polyoxypropylene (9) diglycerol 1.0
15, diglycerol 5.0
16, the aqueous solution 30.0 of 1% (folder) oxa-grace rubber
17, acetylglutamate 0.3
18, spherical nylon powder 1.0
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1~8 at 85 ℃ of mixed dissolutions.
B: 85 ℃ of heating, the limit is fully stirred to wherein adding A in the limit with composition 9.
C: cooling B, carry out corpusculed by high-pressure homogenizer.
D: composition 10~20 is dissolved in mixed at room temperature.
E: in D, add C, mix obtaining beautifying liquid.
The beautifying liquid of embodiment 15 is the beautifying liquid that is clamminess and feels few, have abundant moistening effect and good usability that is produced by water solublity L-magnesium ascorbyl phosphate.
As mentioned above, liquid make-up of the present invention not only has the whitening function of water solublity L-ascorbic acid derivates, and also can obtain good usability under the situation that water solublity L-ascorbic acid derivates exists.
Claims (3)
1, a kind of liquid make-up is characterized in that, this liquid make-up contains the following ingredients (a)~(c) as neccessary composition:
(a) polyoxypropylene diglycerol,
(b) the water solublity L-ascorbic acid derivates of 0.5~5 quality %, described water solublity L-ascorbic acid derivates is selected from a kind of in the group of being made up of L-sodium ascorbate, L-potassium ascorbate, L-Magnesium ascorbate, L-sodium ascorbyl phosphate, L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate potassium, L-ascorbic acid sodium sulfate, L-ascorbic acid magnesium sulfate, L-ascorbic acid potassium sulfate or more than 2 kinds
(c) has the polyhydric alcohol of three above hydroxyls.
2, liquid make-up as claimed in claim 1 is characterized in that, this liquid make-up also contains composition (d) ethanol.
3, the liquid make-up described in claim 1 or 2 is characterized in that, the mass ratio of described composition (a) and composition (b) is 1: 10~10: 1.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002089111 | 2002-03-27 | ||
JP089111/2002 | 2002-03-27 | ||
JP327142/2002 | 2002-11-11 | ||
JP2002327142A JP2004002281A (en) | 2002-03-27 | 2002-11-11 | Liquid cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1446533A CN1446533A (en) | 2003-10-08 |
CN1271990C true CN1271990C (en) | 2006-08-30 |
Family
ID=28456300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB031193587A Expired - Lifetime CN1271990C (en) | 2002-03-27 | 2003-03-14 | Liquid cosmetics |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2004002281A (en) |
KR (1) | KR20030077968A (en) |
CN (1) | CN1271990C (en) |
HK (1) | HK1058001A1 (en) |
TW (1) | TWI282740B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2009007048A (en) * | 2006-12-26 | 2009-07-10 | Romano Dev Inc | Skin lightening composition for hyperpigmented skin. |
JP6973919B2 (en) * | 2017-09-06 | 2021-12-01 | 株式会社ノエビア | External skin preparation |
-
2002
- 2002-11-11 JP JP2002327142A patent/JP2004002281A/en active Pending
-
2003
- 2003-03-04 TW TW092104511A patent/TWI282740B/en not_active IP Right Cessation
- 2003-03-13 KR KR10-2003-0015590A patent/KR20030077968A/en not_active Application Discontinuation
- 2003-03-14 CN CNB031193587A patent/CN1271990C/en not_active Expired - Lifetime
-
2004
- 2004-02-09 HK HK04100859A patent/HK1058001A1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW200304382A (en) | 2003-10-01 |
HK1058001A1 (en) | 2004-04-30 |
CN1446533A (en) | 2003-10-08 |
KR20030077968A (en) | 2003-10-04 |
TWI282740B (en) | 2007-06-21 |
JP2004002281A (en) | 2004-01-08 |
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Granted publication date: 20060830 |