CN1265885A - Oil-soluble vitamin powder and making process thereof - Google Patents
Oil-soluble vitamin powder and making process thereof Download PDFInfo
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- CN1265885A CN1265885A CN 00100452 CN00100452A CN1265885A CN 1265885 A CN1265885 A CN 1265885A CN 00100452 CN00100452 CN 00100452 CN 00100452 A CN00100452 A CN 00100452A CN 1265885 A CN1265885 A CN 1265885A
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Abstract
The pressent invention provides an oil-soluble vitamin powder and its production method. It is characterized by that it uses peach gum made in China as main wall matrial raw material for embedding, and matches it with other wall material and auxiliary material to embed oil-soluble vitamin, then it adopts the spray-drying process to make it form good capsule to protect the instable vitamin oil. The tests show that the embedding rate and stability of said invented oil-soluble vitamin powder product can be reached to that of powder product obtained by using arabic gum in traditional method.
Description
The present invention relates to a kind of free flowable oil-soluble vitamin powder goods, relating in particular to homemade Resina persicae is that main wall material is carried out embedding, and spray-dried oil-soluble vitamin powder goods and the manufacture method thereof that obtains.
The powdered fat soluble vitamin has good stability through after the embedding, can be widely used in condensed food, medicine and the feedstuff, to replenish wherein vitamin amount.Before the present invention, the manufacturing of powdered fat soluble vitamin adopts arabic gum to carry out embedding for the wall material more, it is general that what use is the arabic gum that belongs to the xenogenesis plant extract together from pulse family acacia (Acacia Senegal Wild), this arabic gum main product Africa, import is all leaned in domestic use, and cost an arm and a leg, so cause product cost high, range of application is restricted.So seek feasible edible glue class succedaneum in the non-arabic gum place of production, become one of research topic of insider.
The object of the present invention is to provide a kind of oil-soluble vitamin powder, wherein used homemade Resina persicae to replace most of arabic gum, still kept the quality and the result of use of product as main wall material.
It is that main wall material is carried out embedding that another purpose of the present invention is to provide with the Resina persicae, spray drying is made the method for oil-soluble vitamin powder then, under the prerequisite that produces the equal quality product, reach the purpose that reduces product cost, opened up the Resina persicae application simultaneously.
Oil-soluble vitamin powder provided by the invention, be with the embedding of suitable wall material, and the spray dried products with steady flow's property, include the Resina persicae of main amount and an amount of edible animal and plant glue class and cellulose and derivant thereof, carbohydrate in the wall material of this powder.
Fat soluble vitamin mainly is meant vitamin A, D, E, K and derivant thereof, according to pulverulent product provided by the invention, comprise 60～80 parts of Resina persicaes, 10～25 parts of edible animal and plant glue classes and cellulose and derivant thereof, 3～15 parts of carbohydrates in per 100 weight portions of its wall material raw material.
The Resina persicae that the present invention uses is meant the polysaccharide natural gum that extracts from the oozy water-insoluble colloid substance of epidermis injury that fruit tree skins such as peach tree, mountain peach, Fructus Pruni pseudocerasi, Lee, Fructus Pruni cause because of a variety of causes, and doctor, medicine and edibility that tool higher all nontoxic to people and animals.It is reported that the main component of Resina persicae has galactose, arabinose, xylose, glucuronic acid, rhamnose etc., similar with arabic gum.The two main chemical compositions situation can see the following form:
| Composition | Content (%) | |
| Resina persicae | Arabic gum | |
| The D-galactose | ????35 | ????37 |
| L-arabinose | ????42 | ????30 |
| The D-glucuronic acid | ????7 | ????14 |
| The L-rhamnose | ????2 | ????11 |
| The D-xylose | ????14 | |
Can find out from last table, though Resina persicae is considered to similar to arabic gum on composition and content thereof, but also have certain difference,, also should just can finish by specific technical process so desire in the embedding operation of oily material, to realize substituting or the alternative arabic gum of part with Resina persicae.
For this reason, the present invention also provides with the main wall material raw material of Resina persicae as the embedding vitamins oil, replaces or partly replace arabic gum, by the process of spray drying manufacturing oil-soluble vitamin powder.
The used Resina persicae of the present invention is the solubility Resina persicae that meets national standard that obtains through extracting processing on natural Resina persicae basis, and promptly natural Resina persicae is through immersion, hydrolysis, decolouring, desalination, separation, dried product.Resina persicae after the extraction is an off-white powder, and the hydrotrope can reach 99.8%, and wherein state's adopted drug name code is: 402202100101.Extraction processing technique existing open report before the present invention about Resina persicae; can be referring to Liu Xiaogeng, Xu Gangzhu " Resina persicae extracts research " " oil and foodstuffs science and technology " 1998.3, p23～25,27 belong to prior art; be not to belong to the present invention to protect category, so will not describe in detail at this.
According to the manufacture method of oil-soluble vitamin powder provided by the invention, it may further comprise the steps:
(1) preparation is based on the wall material raw material of Resina persicae: comprise 60～80 parts of Resina persicaes, 10～25 parts of edible animal and plant glue classes and cellulose also its derivant, 3～15 parts of carbohydrates in per 100 weight portion wall material raw materials;
(2) above-mentioned wall material raw material adds under 40～80 ℃ in 1～2 times of water of its weight and stirs, and leaves standstill bubble is overflowed fully, makes wall material stabilizing solution;
(3) add fat soluble vitamin oil under the room temperature, the weight ratio of itself and wall material raw material is 0.1～0.8: 1, obtains stable emulsion through homogenizing;
(4) spray drying, 150～250 ℃ of the inlet temperatures of spray tower, 70～110 ℃ of outlet temperatures.
The present invention compared with prior art main feature is to have used in the wall material the homemade Resina persicae of main amount, and cooperate with edible animal and plant glue class and cellulose and derivant, reach traditional handicraft and use the equal effect of arabic gum, wherein said edible animal and plant glue class and cellulose and its derivant are optional from gelatin (or gelatin hydrolysate), arabic gum, alginate jelly, carrageenan, pectin, methylcellulose or ethyl cellulose etc., and use amount is preferably 15～18 parts.
The carbohydrate that uses in the wall material of the present invention can be selected from lactose, maltose, corn syrup, dextrin or modified starch etc., and use amount is preferably 6～11 parts.
Be the embedding quality of assurance spray dried products and the stability of result of use and product; identical with the conventional embedding operation of oil-soluble material; wall material raw material also comprises usually as conventional adjuvants such as emulsifying agent, antioxidant, antibacterial; can select related preparations and conventional addition in the general food additive of granted use for use, the addition of preferred emulsifier of the present invention, antioxidant and antibacterial is respectively 0.5～1 ‰, 0.1 ‰～2% and 0.1～0.2% of wall material raw material and vitamins oil weight sum.
According to technical solution of the present invention, wherein emulsifying agent can be selected from glycerol stearic acid, sucrose ester or fatty acid monoglyceride etc., and preferred addition is 0.6～0.9 ‰ of wall material raw material and a vitamins oil weight sum.Antioxidant can be selected from vitamin C, isoascorbic acid, vitamin E, dibutyl hydroxy toluene (BHT) (BHT) or butylhydroxy methoxy benzene (BHA) etc., and preferred addition is 0.7 ‰～1.2% of wall material raw material and a vitamins oil weight sum.Antibacterial then can be selected conventional sodium benzoate, potassium sorbate or sodium sorbate etc. for use.
The application target of adjuvants such as mentioned emulsifier, antioxidant, antibacterial is performance stable and the maintenance spray product, usually emulsifying agent, antioxidant can mix wall material stabilizing solution the back adding with vitamins oil, emulsifying then, routine operation as this area, the homogenizing of emulsion can adopt the mode of double-stage homogenization, and homogenization pressure is chosen as 150～210kg/cm usually
2, so that the particle diameter of emulsion droplets reaches 0.1～3 μ for well.
Except that above-mentioned raw materials, the inventor finds in test, adding cheese unit hydrochlorate in wall material raw material will help microcapsule granule to form good wall matter, so, also can include the sour sodium of cheese unit, the sour calcium of cheese sour potassium of unit or cheese unit of 1.2～8 weight portions in wall material raw material of the present invention, be the best with 3～6 parts especially.
The present invention is when preparation wall material stabilizing solution, wish to use the alap water of metal ion content, avoid vitamins oil oxidized, preferably use demineralized water, as distilled water, deionized water etc., also can use for example water after ultrafiltration and reverse-osmosis treated, and stir and to make material dissolution, mixing time evenly is advisable with the dissolving fully of raw material, generally can stir 0.5～3 hour, under 40～80 ℃ of temperature, leave standstill then the bubble that produces is overflowed as far as possible fully, need leave standstill usually 12～24 hours.
Fat soluble vitamin described in the present invention is often referred to vitamin A, D, E, K and derivant thereof, form with vitamins oil joins in the wall material liquid, the weight ratio of itself and wall material raw material is 0.1～0.8: 1, the addition of different types of vitamins oil can be different, preferred proportion is 0.2～0.7: 1, as for the homogenizing and the spray-drying process of emulsion, be the routine operation of this area, the present invention is not particularly limited.
In sum, the present invention makes in the method for oil-soluble vitamin powder, has used homemade Resina persicae to be the main wall material raw material; and cooperate other wall material and adjuvant; vitamins oil is carried out embedding, make it to form good tunicle, protection is provided for unsettled vitamins oil by spray drying.Testing result proves, and though oil-soluble vitamin powder goods of the present invention embedding rate and stable aspect, all reached the powder-product result that traditional method uses arabic gum to obtain.Resina persicae is the side-product in orchards such as peach, mountain peach, Lee, Fructus Pruni pseudocerasi and Fructus Pruni, in state-owned profuse resource distribution, be the natural resources that also are not developed and utilize at present, thus enforcement of the present invention, for new way has been opened up in the utilization of Resina persicae resources effective, simultaneously, substitute expensive arabic gum with Resina persicae, help reducing import, reduce product cost, make vitamin powder might have application widely, also promoted the utilization of Resina persicae resource conversely.
Below describe the realization of the object of the invention in detail by specific embodiment, but do not limit practical range of the present invention with this.
Embodiment 1
Resina persicae 78kg, arabic gum 16kg, maltose 6.5kg, fatty acid monoglyceride 0.1kg, sodium benzoate 0.18kg, the sour sodium 2.5kg of cheese unit, antioxidant vitamin E 1.0kg, the 58 ℃ of stirrings of distilled water insulation that add 220kg made it whole dissolvings in 40 minutes, and left standstill 15 hours, the vitamin A palmitate that at room temperature adds 35kg to this emulsion, mix homogeneously and through double-stage homogenization is made stable emulsion, it is sent into spray tower carry out spray drying, 170 ℃ of inlet temperatures, 100 ℃ of outlet temperatures obtain content and are 23% vitamin A powder 128kg.
Embodiment 2
Resina persicae 132.2kg, gelatin hydrolysate 31.6kg, lactose 16kg, the sour sodium 8kg of cheese unit mixes the back and adds the 360kg deionized water, adds potassium sorbate 0.4kg simultaneously, be incubated 65 ℃ and stir 50 minutes to all dissolvings, left standstill 24 hours, and added 40kg vitamin D oil under the room temperature, add glyceryl stearate 0.21kg simultaneously, antioxidant BHA 0.4kg, mix homogeneously is sent into the homogenizer homogenizing, homogenization pressure 180kg/cm
2, spray drying then, 210 ℃ of inlet temperatures, 110 ℃ of outlet temperatures obtain content and are 14% vitamin D powder 213kg.
Embodiment 3
Resina persicae 181.4kg, pectin 43kg, dextrin 28kg, the sour sodium 8.4kg of cheese unit adds the 499kg deionized water, adds sodium sorbate 0.54kg simultaneously, be incubated 42 ℃ and stir 70 minutes, left standstill 18 hours, add the alpha-tocopherol acetate of 180kg under the room temperature to all dissolvings, add sucrose ester 0.4kg again, antioxidant BHT 0.24kg mixes the back homogenizing, obtain stable emulsion and carry out spray drying, 150 ℃ of inlet temperatures, 70 ℃ of outlet temperatures obtain the vitamin E powder 430kg of content 37%.
Claims (17)
1, a kind of oil-soluble vitamin powder, be with the embedding of suitable wall material, and the spray dried products with steady flow's property, it is characterized in that, comprise the Resina persicae of main amount, an amount of edible animal and plant glue class and cellulose and derivant thereof, carbohydrate in the wall material of this powder-product.
2, oil-soluble vitamin powder as claimed in claim 1 comprises 60～80 parts of Resina persicaes, 10～25 parts edible animal and plant glue class and cellulose and derivant thereof, 3～15 parts carbohydrate in per 100 weight portions of its wall material raw material.
3, the manufacture method of the described oil-soluble vitamin powder of claim 1, it may further comprise the steps:
(1) preparation is based on the wall material raw material of Resina persicae: comprise 60～80 parts of Resina persicaes, 10～25 parts of edible animal and plant glue classes and cellulose also its derivant, 3～15 parts of carbohydrates in per 100 weight portion wall material raw materials;
(2) above-mentioned wall material raw material adds under 40～80 ℃ in 1～2 times of water of its weight and stirs, and leaves standstill bubble is overflowed fully, makes wall material stabilizing solution;
(3) add fat soluble vitamin oil, the weight ratio of itself and wall material raw material is 0.1～0.8: 1, obtains stable emulsion through homogenizing;
(4) spray drying.
4, manufacture method as claimed in claim 3, wherein, edible animal and plant glue class and cellulose and derivant thereof are selected from gelatin, arabic gum, alginate jelly, carrageenan, pectin, methylcellulose or ethyl cellulose.
5, as the manufacture method of claim 3 or 4, wherein, the use amount of described edible animal and plant glue class and cellulose and derivant thereof is 15～18 parts.
6, manufacture method as claimed in claim 3, wherein, carbohydrate is selected from lactose, maltose, corn syrup, dextrin or modified starch.
7, as the manufacture method of claim 3 or 6, wherein the use amount of carbohydrate is 6～11 parts.
8, method as claimed in claim 3 wherein, also comprises emulsifying agent, antioxidant and antibacterial in the described wall material raw material.
9, method as claimed in claim 8, wherein the addition of emulsifying agent, antioxidant and antibacterial is respectively 0.5～1 ‰, 0.1 ‰～2% and 0.1～0.2% of wall material raw material and vitamins oil weight sum.
10, method as claimed in claim 9, wherein the addition of emulsifying agent is 0.6～0.9 ‰ of wall material raw material and a vitamins oil weight sum.
11, as the method for claim 8 or 9, wherein emulsifying agent is selected from glycerol stearic acid, sucrose ester or fatty acid monoglyceride.
12, as the method for claim 11, wherein the addition of antioxidant is 0.7 ‰～1.2% of wall material raw material and a vitamins oil weight sum.
13, as the method for claim 8 or 9, wherein antioxidant is selected from vitamin C, isoascorbic acid, vitamin E, dibutyl hydroxy toluene (BHT) or butylhydroxy methoxy benzene.
14, method as claimed in claim 3 wherein, also includes 1.2～8 parts the sour calcium of cheese sour potassium of unit or cheese unit in per 100 weight portion wall material raw materials.
15, as the method for claim 14, wherein the amount of the sour calcium of cheese sour potassium of unit or cheese unit is 3～6 parts.
16, method as claimed in claim 3, wherein, fat soluble vitamin oil is 0.2～0.7: 1 with the weight ratio of wall material raw material.
17, as the method for claim 3 or 16, wherein, use demineralized water dissolving wall material raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00100452 CN1124131C (en) | 2000-01-31 | 2000-01-31 | Oil-soluble vitamin powder and making process thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00100452 CN1124131C (en) | 2000-01-31 | 2000-01-31 | Oil-soluble vitamin powder and making process thereof |
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| Publication Number | Publication Date |
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| CN1265885A true CN1265885A (en) | 2000-09-13 |
| CN1124131C CN1124131C (en) | 2003-10-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 00100452 Expired - Fee Related CN1124131C (en) | 2000-01-31 | 2000-01-31 | Oil-soluble vitamin powder and making process thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103734520A (en) * | 2013-12-20 | 2014-04-23 | 大连赛姆生物工程技术有限公司 | Self-ingestion type plant source composite pharmaceutical effect nutriment for horse and preparation method of self-ingestion type plant source composite pharmaceutical effect nutriment |
| CN106262933A (en) * | 2016-11-08 | 2017-01-04 | 浙江工业大学 | A kind of preparation method of Vitamin E contained micro capsule |
| CN107136352A (en) * | 2017-07-03 | 2017-09-08 | 青岛玛斯特生物技术有限公司 | Spraying vitamin premix and its application in aquatic feeds after a kind of |
| CN108013474A (en) * | 2017-12-25 | 2018-05-11 | 大连医诺生物股份有限公司 | Water soluble vitamin microcapsule granule and preparation method thereof |
| CN112655968A (en) * | 2020-12-15 | 2021-04-16 | 南通励成生物工程有限公司 | High-stability vitamin K2Powder and method for producing same |
| CN113491345A (en) * | 2020-04-07 | 2021-10-12 | 云南恩典科技产业发展有限公司 | Bead blasting wall material with antibacterial function and preparation method of bead blasting wall material |
-
2000
- 2000-01-31 CN CN 00100452 patent/CN1124131C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103734520A (en) * | 2013-12-20 | 2014-04-23 | 大连赛姆生物工程技术有限公司 | Self-ingestion type plant source composite pharmaceutical effect nutriment for horse and preparation method of self-ingestion type plant source composite pharmaceutical effect nutriment |
| CN103734520B (en) * | 2013-12-20 | 2015-07-22 | 大连赛姆生物工程技术有限公司 | Self-ingestion type plant source composite pharmaceutical effect nutriment for horse and preparation method of self-ingestion type plant source composite pharmaceutical effect nutriment |
| CN106262933A (en) * | 2016-11-08 | 2017-01-04 | 浙江工业大学 | A kind of preparation method of Vitamin E contained micro capsule |
| CN107136352A (en) * | 2017-07-03 | 2017-09-08 | 青岛玛斯特生物技术有限公司 | Spraying vitamin premix and its application in aquatic feeds after a kind of |
| CN107136352B (en) * | 2017-07-03 | 2018-06-29 | 青岛玛斯特生物技术有限公司 | Spraying vitamin premix and its application in aquatic feeds after a kind of |
| CN108013474A (en) * | 2017-12-25 | 2018-05-11 | 大连医诺生物股份有限公司 | Water soluble vitamin microcapsule granule and preparation method thereof |
| CN113491345A (en) * | 2020-04-07 | 2021-10-12 | 云南恩典科技产业发展有限公司 | Bead blasting wall material with antibacterial function and preparation method of bead blasting wall material |
| CN113491345B (en) * | 2020-04-07 | 2023-03-28 | 云南恩典科技产业发展有限公司 | Bead blasting wall material with antibacterial function and preparation method of bead blasting wall material |
| CN112655968A (en) * | 2020-12-15 | 2021-04-16 | 南通励成生物工程有限公司 | High-stability vitamin K2Powder and method for producing same |
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| Publication number | Publication date |
|---|---|
| CN1124131C (en) | 2003-10-15 |
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Owner name: BEIJING KELIBOSANG FOOD LIMITED LIABILITY COMPANY Free format text: FORMER OWNER: BEIJING KELI NEW TECHNIQUE DEVELOPMENT HEAD OFFICE Effective date: 20090814 |
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Effective date of registration: 20090814 Address after: North Tower 16, 801 South Avenue, Beijing, Xicheng District, Xizhimen Patentee after: Beijing Keli Bosang Food Co., Ltd. Address before: No. 27, West Third Ring Road North, Beijing, Haidian District Patentee before: Keli New Tech. Development General Co., Beijing |
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