CN1263552A - Softener active derived from acylated triethanolamine - Google Patents

Softener active derived from acylated triethanolamine Download PDF

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CN1263552A
CN1263552A CN 98807149 CN98807149A CN1263552A CN 1263552 A CN1263552 A CN 1263552A CN 98807149 CN98807149 CN 98807149 CN 98807149 A CN98807149 A CN 98807149A CN 1263552 A CN1263552 A CN 1263552A
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dimethyl
methyl
glycol
pentanediol
isophthalic acid
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CN 98807149
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E·H·瓦尔
T·特林
E·R·卡尔
J·麦唐纳德
Z·刘
A·H·张
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Procter and Gamble Co
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Procter and Gamble Co
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Abstract

Fabric softener compounds having the formula: RC(O)!nN+(R1)mX- wherein each R in a compound is a C6-C22 hydrocarbyl group, preferably having an IV from about 70 to about 140 based upon the IV of the equivalent fatty acid, n is a number from 1 to three on the weight average in any mixture of compounds, each R1 in a compound is a C1-3 alkyl or hydroxy alkyl group, the total of n and the number of R1 groups that are hydroxyethyl groups equaling 3, n+m=4 and X is a softener compatible anion, preferably methyl sulfate, the compound, or mixtures of such compounds, having (a) either a Hunter ''L'' transmission of at least about 85, typically from about 85 to about 95, preferably from about 90 to about 95, more preferably above about 95, if possible, (b) only nondetectable levels, at the conditions of use, of odorous compounds selected from the group consisting of: isopropyl acetate, which should be less than about 5, preferably less than about 3, and more preferably less than about 2, g/L.; 2,2'-ethylidenebis(oxy)bispropane, which should be less than about 200, preferably less than about 100, more preferably less than about 10, and even more preferably less than about 5, g/L.; 1,3,5-trioxane, which should be less than about 50, preferably less than about 20, more preferably less than about 10, and even more preferably less than about 7, g/L.; and/or each short chain fatty acid (4-12, especially 6-10, carbon atoms) ester, especially methyl esters, which should be less than about 4, preferably less than about 3, and more preferably less than about 2, g/L. or (c) preferably, both. The fabric softener actives are preferably prepared in the presence of chelating agent and/or antioxidant, as disclosed herein. Such materials are new. Solvents can be present.

Description

By acidylate trolamine deutero-softening agent actives
Invention field
The present invention relates to be suitable for preparing the specific fabric softener active matter of spissated soft fabric composition.Particularly, provide the acylated derivatives of trolamine, do not noted before it can solve, particularly about some problems of transparent or semitransparent liquid composition.
Background of invention
The concentrated transparent composition that contains the fabric sofetening actives that connects ester and/or amido linkage is disclosed in the E.H.Wahl that submitted on July 11st, 1996, T.Trinh, E.P.Gosselink, in the existing autre action pendante patent application serial numbers 08/679694 of J.C.Letton and M.R.Sivik, wherein disclose the compound of soft fabric, this application is quoted for referencial use at this paper.Fabric softener active matter in this application all is the biodegradable material that is connected with ester bond, and it contains long hydrophobic unsaturated chain.Also considered concentrate composition with the dispersion form.
Summary of the invention
The fabric soft compound of necessity of the present invention is those of following formula:
[RC (O) OC 2H 4] nN +(R 1) mX -Wherein each R in the compound is C 6-C 22Alkyl preferably has only a small amount of or does not have C 6-10Alkyl preferably has iodine number (hereinafter also being called IV) based on the IV meter of the lipid acid of equivalence and is about 70-140, is the numerical value of 1-3 by weight average n in any mixture of compound, each R in the compound 1Be C 1-3Alkyl or hydroxyalkyl, n and be the R of hydroxyethyl groups 1The summation of group number equals 3, and n+m equals 4, and X is the negatively charged ion compatible with softening agent, the preferable methyl sulfate radical.(C18: lipid acid 1 component) suitable: the ratio of trans isomer preferably was at least about 1: 1, and preferred about 2: 1, more preferably 3: 1, even more preferably from about 4: 1, or higher.
The mixture of this compound or compound have (a) Hunter " L " transmission value be at least about 85, generally about 85-95, preferably about 90-95 if possible, more preferably is higher than about 95; (b) under working conditions, have only low-down scent of compound of for example failing detection limit, it is selected from isopropyl acetate; 2,2 '-ethylene (oxygen), two propane; 1,3,5-trioxane and/or short chain fatty acid (4-12, a particularly 6-10 carbon atom) ester, particularly methyl esters; Or (c) preferably has the two feature.
Above compound is applicable to the concentrated fabric care composition, particularly transparent concentrate composition.This compound provides the composition that improves, and it contains: the about 2-75% of A., preferably about 8%-70%, 13%-65% more preferably from about, even the mixture of 18%-40% described compound or this compound more preferably from about; With the weight of B., be less than about 40% and have ClogP and be about 0.15-0.64 and main solvent with at least some degrees of asymmetry by said composition.
In addition, said composition can be aqueous stable fabric softener dispersion composite, and it contains, weight by said composition: about 5%-35%, preferred about 8%-30%, 10%-28% more preferably from about, even the described cationic fabric softener compound of 13%-26% more preferably from about.
For clear composition, weight by composition, solvent generally is less than about 40%, preferred about 5%-35%, 10%-25% more preferably from about, even 12%-18% more preferably from about, particularly having ClogP is about 0.15-0.64, preferred about 0.25-0.62, the more preferably from about main solvent of 0.40-0.60.Described solvent generally is a main solvent.When the main solvent that has q.s not for example 2,2,4-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1, the derivative of the ethoxylate of 3-pentanediol, diethoxy thing or triethoxy thing; 2-ethyl-1, the 3-hexylene glycol; And/or 2-ethyl-1, when 3-hexylene glycol ethoxylate (1-3) and/or its mixture, can add other solvent, preferred 1,4 cyclohexane dimethanol can provide transparent product, or even can provide stable product.
Typical main solvent is preferably selected from:
I. monohydroxy-alcohol comprises:
A. n-propyl alcohol; And/or
B. 2-butanols and/or 2-methyl-2-propyl alcohol;
II. hexylene glycol isomer comprises: 2, and 3-dimethyl-2,3-butyleneglycol; 2,3-dimethyl-1,2-butyleneglycol; 3,3-dimethyl-1,2-butyleneglycol; 2-methyl-2, the 3-pentanediol; 3-methyl-2, the 3-pentanediol; 4-methyl-2, the 3-pentanediol; 2, the 3-hexylene glycol; 3, the 4-hexylene glycol; 2-ethyl-1, the 2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; And/or 1, the 2-hexylene glycol;
III. the heptanediol isomer comprises: 2-butyl-1, ammediol; 2,2-diethyl-1, ammediol; 2-(1-methyl-propyl)-1, ammediol; 2-(2-methyl-propyl)-1, ammediol; 2-methyl-2-propyl group-1, ammediol; 2,3,3-trimethylammonium-1,2-butyleneglycol; 2-ethyl-2-methyl isophthalic acid, the 4-butyleneglycol; 2-ethyl-3-methyl isophthalic acid, the 4-butyleneglycol; 2-propyl group-1, the 4-butyleneglycol; 2-sec.-propyl-1, the 4-butyleneglycol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl-1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; 2-ethyl-1, the 5-pentanediol; The 2-methyl isophthalic acid, the 6-hexylene glycol; The 3-methyl isophthalic acid, the 6-hexylene glycol; 2-methyl-2, the 3-hexylene glycol; 3-methyl-2, the 3-hexylene glycol; 4-methyl-2, the 3-hexylene glycol; 5-methyl-2, the 3-hexylene glycol; 2-methyl-3, the 4-hexylene glycol; 3-methyl-3, the 4-hexylene glycol; 1, the 3-heptanediol; 1, the 4-heptanediol; 1, the 5-heptanediol; And/or 1, the 6-heptanediol;
IV. the ethohexadiol isomer comprises: 2-(2-methyl butyl)-1, ammediol; 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(1-methyl butyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-(3-methyl butyl)-1, ammediol; 2-butyl-2-methyl isophthalic acid, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-ethyl-2-propyl group-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2,2-diethyl-1,3 butylene glycol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-ethyl-2,3-dimethyl-1,3 butylene glycol; 2-(1, the 1-dimethyl ethyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-methyl-2-sec.-propyl-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 3-methyl-2-sec.-propyl-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-methyl-2-propyl group-1, the 4-butyleneglycol; 2-(1-methyl-propyl)-1, the 4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 2-(2-dimethyl propyl)-1, the 4-butyleneglycol; 2-methyl-3-propyl group-1, the 4-butyleneglycol; 3-methyl-2-sec.-propyl-1, the 4-butyleneglycol; 2,2,3-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1,3-pentanediol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,4,4-trimethylammonium-1,3-pentanediol; 3,4,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,4-pentanediol; 2,2,4-trimethylammonium-1,4-pentanediol; 2,3,3-trimethylammonium-1,4-pentanediol; 2,3,4-trimethylammonium-1,4-pentanediol; 3,3,4-trimethylammonium-1,4-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2,3,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-2,4-pentanediol; 2,3,4-trimethylammonium-2,4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 5-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 2-sec.-propyl-1, the 5-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 2,2-dimethyl-1,6-hexylene glycol; 2,3-dimethyl-1,6-hexylene glycol; 2,4-dimethyl-1,6-hexylene glycol; 2,5-dimethyl-1,6-hexylene glycol; 3,3-dimethyl-1,6-hexylene glycol; 3,4-dimethyl-1,6-hexylene glycol; 2,3-dimethyl-2,4-hexylene glycol; 2,4-dimethyl-2,4-hexylene glycol; 2,5-dimethyl-2,4-hexylene glycol; 3,3-dimethyl-2,4-hexylene glycol; 3,4-dimethyl-2,4-hexylene glycol; 3,5-dimethyl-2,4-hexylene glycol; 4,5-dimethyl-2,4-hexylene glycol; 5,5-dimethyl-2,4-hexylene glycol; 2,3-dimethyl-2,5-hexylene glycol; 2,4-dimethyl-2,5-hexylene glycol; 2,5-dimethyl-2,5-hexylene glycol; 3,3-dimethyl-2,5-hexylene glycol; 3,4-dimethyl-2,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 3-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol;
V. nonanediol isomer comprises: 2,3,3, and 4-tetramethyl--2,4-pentanediol; The 3-tertiary butyl-2, the 4-pentanediol; 2,5,5-trimethylammonium-2,4-hexylene glycol; 3,3,4-trimethylammonium-2,4-hexylene glycol; 3,3,5-trimethylammonium-2,4-hexylene glycol; 3,5,5-trimethylammonium-2,4-hexylene glycol; 4,5,5-trimethylammonium-2,4-hexylene glycol; 3,3,4-trimethylammonium-2,5-hexylene glycol; And/or 3,3,5-trimethylammonium-2,5-hexylene glycol;
VI. glyceryl ether and/or two (hydroxyalkyl) ether comprises: 3-(n-pentyloxy)-1,2-propylene glycol; 3-(2-pentyloxy)-1, the 2-propylene glycol; 3-(3-pentyloxy)-1, the 2-propylene glycol; 3-(2-methyl-1-butene oxygen base)-1, the 2-propylene glycol; 3-(isopentyloxy)-1, the 2-propylene glycol; 3-(3-methyl-2-butoxy)-1, the 2-propylene glycol; 3-(cyclohexyloxy)-1, the 2-propylene glycol; 3-(1-hexamethylene-1-alkene oxygen base)-1, the 2-propylene glycol; 2-(pentyloxy)-1, ammediol; 2-(2-pentyloxy)-1, ammediol; 2-(3-pentyloxy)-1, ammediol; 2-(2-methyl-1-butene oxygen base)-1, ammediol; 2-(isopentyloxy)-1, ammediol; 2-(3-methyl-2-butoxy)-1, ammediol; 2-(cyclohexyloxy)-1, ammediol; 2-(1-hexamethylene-1-alkene oxygen base)-1, ammediol, triethoxy 3-(butoxy)-1,2-propylene glycol; Tetraethoxy 3-(butoxy)-1, the 2-propylene glycol; Five ethoxylation 3-(butoxy)-1, the 2-propylene glycol; Six ethoxylation 3-(butoxy)-1, the 2-propylene glycol; Seven ethoxylation 3-(butoxy)-1, the 2-propylene glycol; Eight ethoxylation 3-(butoxy)-1, the 2-propylene glycol; Nine ethoxylation 3-(butoxy)-1, the 2-propylene glycol; One propoxylation 3-(butoxy)-1, the 2-propylene glycol; Two butylene oxide base 3-(butoxy)-1, the 2-propylene glycol; Three butylidene oxygen base 3-(butoxy)-1, the 2-propylene glycol; 3-phenoxy group-1, the 2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 3-(1-phenyl-2-propoxy-)-1, the 2-propylene glycol; 2-phenoxy group-1, ammediol; 2-(tolyloxy)-1, ammediol; 2-(to tolyloxy)-1, ammediol; 2-benzyloxy-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; 2-(1-phenyl ethoxy)-1, ammediol; Two (2-hydroxyl butyl) ether; And/or two (2-hydroxycyclopent base) ether;
VII. saturated and undersaturated alicyclic diol and their derivative comprise:
(a) saturated two pure and mild their derivatives comprise:
1-sec.-propyl-1, the 2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 2,4,5-trimethylammonium-1,3-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxyl hexanaphthene ethanol; 1-hydroxyl cyclohexane methanol; 1-ethyl-1, the 3-cyclohexanediol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1, the 3-cyclohexanediol; 2-hydroxyl hexanaphthene ethanol; 2-hydroxyethyl-1-hexalin; 2-methylol hexalin; 3-hydroxyethyl-1-hexalin; 3-hydroxyl hexanaphthene ethanol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; 4-methylol hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1, the 3-cyclohexanediol; 1,2-encircles heptanediol; The 2-methyl isophthalic acid, 3-encircles heptanediol; The 2-methyl isophthalic acid, 4-encircles heptanediol; The 4-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 4-encircles heptanediol; The 6-methyl isophthalic acid, 4-encircles heptanediol; 1,3-encircles ethohexadiol; 1,4-encircles ethohexadiol; 1,5-encircles ethohexadiol; 1,2-cyclohexanediol diethoxy thing; 1,2-cyclohexanediol triethoxy thing; 1,2-cyclohexanediol tetraethoxy thing; 1,2-cyclohexanediol five ethoxylates; 1,2-cyclohexanediol six ethoxylates; 1,2-cyclohexanediol seven ethoxylates; 1,2-cyclohexanediol eight ethoxylates; 1,2-cyclohexanediol nine ethoxylates; 1,2-cyclohexanediol one propoxylated glycerine; 1,2-cyclohexanediol one butoxy thing; 1,2-cyclohexanediol dibutoxy thing and/or 1,2-cyclohexanediol three butoxy things; With
(b) undersaturated alicyclic diol comprises: 1-vinyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4-tetramethyl--3-cyclobutene-1,2-glycol; 3,4-diethyl-3-cyclobutene-1,2-glycol; 3-(1, the 1-dimethyl ethyl)-3-cyclobutene-1, the 2-glycol; 3-butyl-3-cyclobutene-1, the 2-glycol; 1,2-dimethyl-4-methylene radical-1,2-encircles pentanediol; 1-ethyl-3-methylene radical-1,2-encircles pentanediol; 4-(1-propenyl)-1,2-encircles pentanediol; 1-ethyl-3-methyl-3-cyclopentenes-1, the 2-glycol; 1-vinyl-1, the 2-cyclohexanediol; 1-methyl-3-methylene radical-1, the 2-cyclohexanediol; 1-methyl-4-methylene radical-1, the 2-cyclohexanediol; 3-vinyl-1, the 2-cyclohexanediol; 4-vinyl-1, the 2-cyclohexanediol; 2,6-dimethyl-3-tetrahydrobenzene-1,2-glycol; 6,6-dimethyl-3-tetrahydrobenzene-1,2-glycol; 3,6-dimethyl-4-tetrahydrobenzene-1,2-glycol; 4,5-dimethyl-4-tetrahydrobenzene-1,2-glycol; 3-cyclooctene-1, the 2-glycol; 4-cyclooctene-1, the 2-glycol; And/or 5-cyclooctene-1, the 2-glycol;
VIII.C 3-8The alkoxy derivative of glycol [hereinafter, " EO " represents polyethoxylated, that is, and and-(CH 2CH 2O) nH; The end capped polyethoxylated of Me-En represent methylidene-(CH 2CH 2O) nCH 3" 2 (Me-En) " representative needs 2 Me-En groups; The poly-propoxylated glycerine of " PO " representative ,-(CH (CH 3) CH 2O) nH; " BO " represents polytetramethylene oxygen base, (CH (CH 2CH 3) CH 2O) nH; " n-BO " representative poly-(just-Ya butoxy) or poly-(tetramethylene) oxygen base-(CH 2CH 2CH 2CH 2O) nH.Term " (C used herein x) " be meant the carbonatoms in the oxyalkylated base mateiral], comprising:
1. 1,2-propylene glycol 2 (Me-E 3-4); 1,2-propylene glycol PO 4The 2-methyl isophthalic acid, 2-propylene glycol (Me-E 4-10); The 2-methyl isophthalic acid, 2-propylene glycol 2 (Me-E 1); The 2-methyl isophthalic acid, 2-propylene glycol PO 3The 2-methyl isophthalic acid, 2-propylene glycol BO 11, ammediol 2 (Me-E 6-8); 1, ammediol PO 5-62,2-diethyl-1, ammediol E 1-72,2-diethyl-1, ammediol PO 12,2-diethyl-1, ammediol n-BO 1-222 (Me E 1-2); 2 PO 3-42-(1-methyl-propyl)-1, ammediol E 1-72-(1-methyl-propyl)-1, ammediol PO 12-(1-methyl-propyl)-1, ammediol n-BO 1-22-(2-methyl-propyl)-1, ammediol E 1-72-(2-methyl-propyl)-1, ammediol PO 12-(2-methyl-propyl)-1, ammediol n-BO 1-22-ethyl-1, ammediol (Me E 6-10); 2-ethyl-1, ammediol 2 (Me E 1); 2-ethyl-1, ammediol PO 32-ethyl-2-methyl isophthalic acid, ammediol (Me E 1-6); 2-ethyl-2-methyl isophthalic acid, ammediol PO 22-ethyl-2-methyl isophthalic acid, ammediol BO 12-sec.-propyl-1, ammediol (Me E 1-6); 2-sec.-propyl-1, ammediol PO 22-sec.-propyl-1, ammediol BO 1The 2-methyl isophthalic acid, ammediol 2 (Me E 2-5); The 2-methyl isophthalic acid, ammediol PO 4-5The 2-methyl isophthalic acid, ammediol BO 22-methyl-2-sec.-propyl-1, ammediol E 2-92-methyl-2-sec.-propyl-1, ammediol PO 12-methyl-2-sec.-propyl-1, ammediol n-BO 1-32-methyl-2-propyl group-1, ammediol E 1-72-methyl-2-propyl group-1, ammediol PO 12-methyl-2-propyl group-1, ammediol n-BO 1-22-propyl group-1, ammediol (Me E 1-4); 2-propyl group-1, ammediol PO 22-propyl group-1, ammediol BO 1
2. 1,2-butyleneglycol (Me E 2-8); 1,2-butyleneglycol PO 2-31,2-butyleneglycol BO 12,3-dimethyl-1,2-butyleneglycol E 1-62,3-dimethyl-1,2-butyleneglycol n-BO 1-22-ethyl-1,2-butyleneglycol E 1-32-ethyl-1,2-butyleneglycol n-BO 1The 2-methyl isophthalic acid, 2-butyleneglycol (Me E 1-2); The 2-methyl isophthalic acid, 2-butyleneglycol PO 13,3-dimethyl-1,2-butyleneglycol E 1-63,3-dimethyl-1,2-butyleneglycol n-BO 1-2The 3-methyl isophthalic acid, 2-butyleneglycol (Me E 1-2); The 3-methyl isophthalic acid, 2-butyleneglycol PO 11,3 butylene glycol 2 (Me E 3-6); 1,3 butylene glycol PO 5 1,3 butylene glycol BO 22,2,3-trimethylammonium-1,3 butylene glycol (Me E 1-3); 2,2,3-trimethylammonium-1,3 butylene glycol PO 1-22,2-dimethyl-1,3 butylene glycol (Me E 3-8); 2,2-dimethyl-1,3 butylene glycol PO 32,3-dimethyl-1,3 butylene glycol (Me E 3-8); 2,3-dimethyl-1,3 butylene glycol PO 32-ethyl-1,3 butylene glycol (Me E 1-6); 2-ethyl-1,3 butylene glycol PO 2-32-ethyl-1,3 butylene glycol BO 12-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (Me E 1); 2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol PO 12-ethyl-2-methyl isophthalic acid, 3-butyleneglycol n-BO 2-42-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (Me-E 1); 2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol PO 12-ethyl-3-methyl isophthalic acid, 3-butyleneglycol n-BO 2-42-sec.-propyl-1,3 butylene glycol (Me E 1); 2-sec.-propyl-1,3 butylene glycol PO 12-sec.-propyl-1,3 butylene glycol n-BO 2-4The 2-methyl isophthalic acid, 3-butyleneglycol 2 (Me E 1-3); The 2-methyl isophthalic acid, 3-butyleneglycol PO 42-propyl group-1,3 butylene glycol E 2-92-propyl group-1,3 butylene glycol PO 12-propyl group-1,3 butylene glycol n-BO 1-3The 3-methyl isophthalic acid, 3-butyleneglycol 2 (Me E 1-3); The 3-methyl isophthalic acid, 3-butyleneglycol PO 41,4-butyleneglycol 2 (Me E 2-4); 1,4-butyleneglycol PO 4-51,4-butyleneglycol BO 22,2,3-trimethylammonium-1,4-butyleneglycol E 2-92,2,3-trimethylammonium-1,4-butyleneglycol PO 12,2,3-trimethylammonium-1,4-butyleneglycol n-BO 1-32,2-dimethyl-1,4-butyleneglycol (Me E 1-6); 2,2-dimethyl-1,4-butyleneglycol PO 22,2-dimethyl-1,4-butyleneglycol BO 12,3-dimethyl-1,4-butyleneglycol (Me E 1-6); 2,3-dimethyl-1,4-butyleneglycol PO 22,3-dimethyl-1,4-butyleneglycol BO 12-ethyl-1,4-butyleneglycol (Me E 1-4); 2-ethyl-1,4-butyleneglycol PO 22-ethyl-1,4-butyleneglycol BO 12-ethyl-2-methyl isophthalic acid, 4-butyleneglycol E 1-72-ethyl-2-methyl isophthalic acid, 4-butyleneglycol PO 12-ethyl-2-methyl isophthalic acid, 4-butyleneglycol n-BO 1-22-ethyl-3-methyl isophthalic acid, 4-butyleneglycol E 1-72-ethyl-3-methyl isophthalic acid, 4-butyleneglycol PO 12-ethyl-3-methyl isophthalic acid, 4-butyleneglycol n-BO 1-22-sec.-propyl-1,4-butyleneglycol E 1-72-sec.-propyl-1,4-butyleneglycol PO 1Different third methyl isophthalic acid of 2-, 4-butyleneglycol n-BO 1-2The 2-methyl isophthalic acid, 4-butyleneglycol (Me E 6-10); The 2-methyl isophthalic acid, 4-butyleneglycol 2 (MeE 1); The 2-methyl isophthalic acid, 4-butyleneglycol PO 3The 2-methyl isophthalic acid, 4-butyleneglycol BO 12-propyl group-1,4-butyleneglycol E 1-52-propyl group-1,4-butyleneglycol n-BO 1-23-ethyl-1-methyl isophthalic acid, 4-butyleneglycol E 2-93-ethyl-1-methyl isophthalic acid, 4-butyleneglycol PO 13-ethyl-1-methyl isophthalic acid, 4-butyleneglycol n-BO 1-32,3-butyleneglycol (MeE 6-10); 2,3-butyleneglycol 2 (Me E 1); 2,3-butyleneglycol PO 3-42,3-butyleneglycol BO 12,3-dimethyl-2,3-butyleneglycol E 3-92,3-dimethyl-2,3-butyleneglycol PO 12,3-dimethyl-2,3-butyleneglycol BO 1-32-methyl-2,3-butyleneglycol (Me E 1-5); 2-methyl-2,3-butyleneglycol PO 22-methyl-2,3-butyleneglycol BO 1
3. 1,2-pentanediol E 3-101,2-pentanediol PO 11,2-pentanediol n-BO 2-3The 2-methyl isophthalic acid, 2-pentanediol E 1-3The 2-methyl isophthalic acid, 2-pentanediol n-BO 1The 2-methyl isophthalic acid, 2-pentanediol BO 1The 3-methyl isophthalic acid, 2-pentanediol E 1-3The 3-methyl isophthalic acid, 2-pentanediol n-BO 1The 4-methyl isophthalic acid, 2-pentanediol E 1-3The 4-methyl isophthalic acid, 2-pentanediol n-BO 11,3-pentanediol 2 (Me-E 1-2); 1,3-pentanediol PO 3-42,2-dimethyl-1,3-pentanediol (Me-E 1); 2,2-dimethyl-1,3-pentanediol PO 12,2-dimethyl-1,3-pentanediol n-BO 2-42,3-dimethyl-1,3-pentanediol (Me-E 1); 2,3-dimethyl-1,3-pentanediol PO 12,3-dimethyl-1,3-pentanediol n-BO 2-42,4-dimethyl-1,3-pentanediol (Me-E 1); 2,4-dimethyl-1,3-pentanediol PO 12,4-dimethyl-1,3-pentanediol n-BO 2-42-ethyl-1,3-pentanediol E 2-92-ethyl-1,3-pentanediol PO 12-ethyl-1,3-pentanediol n-BO 1-3The 2-methyl isophthalic acid, 3-pentanediol 2 (Me-E 1-6); The 2-methyl isophthalic acid, 3-pentanediol PO 2-3The 2-methyl isophthalic acid, 3-pentanediol BO 13,4-dimethyl-1,3-pentanediol (Me-E 1); 3,4-dimethyl-1,3-pentanediol PO 13,4-dimethyl-1,3-pentanediol n-BO 2-4The 3-methyl isophthalic acid, 3-pentanediol (Me-E 1-6); The 3-methyl isophthalic acid, 3-pentanediol PO 2-3The 3-methyl isophthalic acid, 3-pentanediol BO 14,4-dimethyl-1,3-pentanediol (Me-E 1); 4,4-dimethyl-1,3-pentanediol PO 14,4-dimethyl-1,3-pentanediol n-BO 2-4The 4-methyl isophthalic acid, 3-pentanediol (Me-E 1-6); The 4-methyl isophthalic acid, 3-pentanediol PO 2-3The 4-methyl isophthalic acid, 3-pentanediol BO 11,4-pentanediol 2 (Me-E 1-2); 1,4-pentanediol PO 3-42,2-dimethyl-1,4-pentanediol (Me-E 1); 2,2-dimethyl-1,4-pentanediol PO 12,2-dimethyl-1,4-pentanediol n-BO 2-42,3-dimethyl-1,4-pentanediol (Me-E 1); 2,3-dimethyl-1,4-pentanediol PO 12,3-dimethyl-1,4-pentanediol n-BO 2-42,4-dimethyl-1,4-pentanediol (Me-E 1); 2,4-dimethyl-1,4-pentanediol PO 12,4-dimethyl-1,4-pentanediol n-BO 2-4The 2-methyl isophthalic acid, 4-pentanediol (Me-E 1-6); The 2-methyl isophthalic acid, 4-pentanediol PO 2-3The 2-methyl isophthalic acid, 4-pentanediol BO 13,3-dimethyl-1,4-pentanediol (Me-E 1); 3,3-dimethyl-1,4-pentanediol PO 13,3-dimethyl-1,4-pentanediol n-BO 2-43,4-dimethyl-1,4-pentanediol (Me-E 1); 3,4-dimethyl-1,4-pentanediol PO 13,4-dimethyl-1,4-pentanediol n-BO 2-4The 3-methyl isophthalic acid, 4-pentanediol 2 (Me-E 1-6); The 3-methyl isophthalic acid, 4-pentanediol PO 2-3The 3-methyl isophthalic acid, 4-pentanediol BO 1The 4-methyl isophthalic acid, 4-pentanediol 2 (Me-E 1-6); The 4-methyl isophthalic acid, 4-pentanediol PO 2-3The 4-methyl isophthalic acid, 4-pentanediol BO 11,5-pentanediol (Me-E 4-10); 1,5-pentanediol 2 (Me-E 1); 1,5-pentanediol PO 32,2-dimethyl-1,5-pentanediol E 1-72,2-dimethyl-1,5-pentanediol PO 12,2-dimethyl-1,5-pentanediol n-BO 1-22,3-dimethyl-1,5-pentanediol E 1-72,3-dimethyl-1,5-pentanediol PO 12,3-dimethyl-1,5-pentanediol n-BO 1-22,4-dimethyl-1,5-pentanediol E 1-72,4-dimethyl-1,5-pentanediol PO 12,4-dimethyl-1,5-pentanediol n-BO 1-22-ethyl-1,5-pentanediol E 1-52-ethyl-1,5-pentanediol n-BO 1-2The 2-methyl isophthalic acid, 5-pentanediol (Me-E 1-4); The 2-methyl isophthalic acid, 5-pentanediol PO 23,3-dimethyl-1,5-pentanediol E 1-73,3-dimethyl-1,5-pentanediol PO 13,3-dimethyl-1,5-pentanediol n-BO 1-2The 3-methyl isophthalic acid, 5-pentanediol (Me-E 1-4); The 3-methyl isophthalic acid, 5-pentanediol PO 22,3-pentanediol (Me-E 1-3); 2,3-pentanediol PO 22-methyl-2,3-pentanediol E 1-72-methyl-2,3-pentanediol PO 12-methyl-2,3-pentanediol n-BO 1-23-methyl-2,3-pentanediol E 1-73-methyl-2,3-pentanediol PO 13-methyl-2,3-pentanediol n-BO 1-24-methyl-2,3-pentanediol E 1-74-methyl-2,3-pentanediol PO 14-methyl-2,3-pentanediol n-BO 1-22,4-pentanediol 2 (Me-E 1-4); 2,4-pentanediol PO 42,3-dimethyl-2,4-pentanediol (Me-E 1-4); 2,3-dimethyl-2,4-pentanediol PO 22,4-dimethyl-2,4-pentanediol (Me-E 1-4); 2,4-dimethyl-2,4-pentanediol PO 22-methyl-2,4-pentanediol (Me-E 5-10); 2-methyl-2,4-pentanediol PO 33,3-dimethyl-2,4-pentanediol (Me-E 1-4); 3,3-dimethyl-2,4-pentanediol PO 23-methyl-2,4-pentanediol (Me-E 5-10); 3-methyl-2,4-pentanediol PO 3
4. 1,3-hexylene glycol (Me-E 1-5); 1,3-hexylene glycol PO 21,3-hexylene glycol BO 1The 2-methyl isophthalic acid, 3-hexylene glycol E 2-9The 2-methyl isophthalic acid, 3-hexylene glycol PO 1The 2-methyl isophthalic acid, 3-hexylene glycol n-BO 1-3The 2-methyl isophthalic acid, 3-hexylene glycol BO 1The 3-methyl isophthalic acid, 3-hexylene glycol E 2-9The 3-methyl isophthalic acid, 3-hexylene glycol PO 1The 3-methyl isophthalic acid, 3-hexylene glycol n-BO 1-3The 4-methyl isophthalic acid, 3-hexylene glycol E 2-9The 4-methyl isophthalic acid, 3-hexylene glycol PO 1The 4-methyl isophthalic acid, 3-hexylene glycol n-BO 1-3The 5-methyl isophthalic acid, 3-hexylene glycol E 2-9The 5-methyl isophthalic acid, 3-hexylene glycol PO 1The 5-methyl isophthalic acid, 3-hexylene glycol n-BO 1-31,4-hexylene glycol (Me-E 1-5); 1,4-hexylene glycol PO 21,4-hexylene glycol BO 1The 2-methyl isophthalic acid, 4-hexylene glycol E 2-9The 2-methyl isophthalic acid, 4-hexylene glycol PO 1The 2-methyl isophthalic acid, 4-hexylene glycol n-BO 1-3The 3-methyl isophthalic acid, 4-hexylene glycol E 2-9The 3-methyl isophthalic acid, 4-hexylene glycol PO 1The 3-methyl isophthalic acid, 4-hexylene glycol n-BO 1-3The 4-methyl isophthalic acid, 4-hexylene glycol E 2-9The 4-methyl isophthalic acid, 4-hexylene glycol PO 1The 4-methyl isophthalic acid, 4-hexylene glycol n-BO 1-3The 5-methyl isophthalic acid, 4-hexylene glycol E 2-9The 5-methyl isophthalic acid, 4-hexylene glycol PO 1The 5-methyl isophthalic acid, 4-hexylene glycol n-BO 1-31,5-hexylene glycol (Me-E 1-5); 1,5-hexylene glycol PO 21,5-hexylene glycol BO 1The 2-methyl isophthalic acid, 5-hexylene glycol E 2-9The 2-methyl isophthalic acid, 5-hexylene glycol PO 1The 2-methyl isophthalic acid, 5-hexylene glycol n-BO 1-3The 3-methyl isophthalic acid, 5-hexylene glycol E 2-9The 3-methyl isophthalic acid, 5-hexylene glycol PO 1The 3-methyl isophthalic acid, 5-hexylene glycol n-BO 1-3The 4-methyl isophthalic acid, 5-hexylene glycol E 2-9The 4-methyl isophthalic acid, 5-hexylene glycol PO 1The 4-methyl isophthalic acid, 5-hexylene glycol n-BO 1-3The 5-methyl isophthalic acid, 5-hexylene glycol E 2-9The 5-methyl isophthalic acid, 5-hexylene glycol PO 1The 5-methyl isophthalic acid, 5-hexylene glycol n-BO 1-31,6-hexylene glycol (Me-E 1-2); 1,6-hexylene glycol PO 1-21,6-hexylene glycol n-BO 4The 2-methyl isophthalic acid, 6-hexylene glycol E 1-5The 2-methyl isophthalic acid, 6-hexylene glycol n-BO 1-2The 3-methyl isophthalic acid, 6-hexylene glycol E 1-5The 3-methyl isophthalic acid, 6-hexylene glycol n-BO 1-22,3-hexylene glycol E 1-52,3-hexylene glycol n-BO 12,3-hexylene glycol BO 12,4-hexylene glycol (Me-E 3-8); 2,4-hexylene glycol PO 32-methyl-2,4-hexylene glycol (Me E 1-2); 2-methyl-2,4-hexylene glycol PO 1-23-methyl-2,4-hexylene glycol (Me-E 1-2); 3-methyl-2,4-hexylene glycol PO 1-24-methyl-2,4-hexylene glycol (Me-E 1-2); 4-methyl-2,4-hexylene glycol PO 1-25-methyl-2,4-hexylene glycol (Me-E 1-2); 5-methyl-2,4-hexylene glycol PO 1-22,5-hexylene glycol (Me-E 3-8); 2,5-hexylene glycol PO 32-methyl-2,5-hexylene glycol (Me-E 1-2); 2-methyl-2,5-hexylene glycol PO 1-23-methyl-2,5-hexylene glycol (Me-E 1-2); 3-methyl-2,5-hexylene glycol PO 1-23,4-hexylene glycol E 1-53,4-hexylene glycol n-BO 13,4-hexylene glycol BO 1
5. 1,3-heptanediol E 1-71,3-heptanediol PO 11,3-heptanediol n-BO 1-21,4-heptanediol E 1-71,4-heptanediol PO 11,4-heptanediol n-BO 1-21,5-heptanediol E 1-71,5-heptanediol PO 11,5-heptanediol n-BO 1-21,6-heptanediol E 1-71,6-heptanediol PO 11,6-heptanediol n-BO 1-21,7-heptanediol E 1-21,7-heptanediol n-BO 22,4-heptanediol E 3-102,4-heptanediol (Me-E 1); 2,4-heptanediol PO 12,4-heptanediol n-BO 32,5-heptanediol E 3-102,5-heptanediol (Me-E 1); 2,5-heptanediol PO 12,5-heptanediol n-BO 32,6-heptanediol E 3-102,6-heptanediol (Me-E 1); 2,6-heptanediol PO 12,6-heptanediol n-BO 33,5-heptanediol E 3-103,5-heptanediol (Me-E 1); 3,5-heptanediol PO 13,5-heptanediol n-BO 3
6. 3-methyl-2-sec.-propyl-1,3 butylene glycol PO 12,3,3-trimethylammonium-2,4-pentanediol PO 12,2-diethyl-1,3 butylene glycol E 2-52,3-dimethyl-2,4-hexylene glycol E 2-52,4-dimethyl-2,4-hexylene glycol E 2-52,5-dimethyl-2,4-hexylene glycol E 2-53,3-dimethyl-2,4-hexylene glycol E 2-53,4-dimethyl-2,4-hexylene glycol E 2-53,5-dimethyl-2,4-hexylene glycol E 2-54,5-dimethyl-2,4-hexylene glycol E 2-55,5-dimethyl-2,4-hexylene glycol E 2-52,3-dimethyl-2,5-hexylene glycol E 2-52,4-dimethyl-2,5-hexylene glycol E 2-52,5-dimethyl-2,5-hexylene glycol E 2-53,3-dimethyl-2,5-hexylene glycol E 2-53,4-dimethyl-2,5-hexylene glycol E 2-53-methyl-3,5-heptanediol E 2-52,2-diethyl-1,3 butylene glycol n-BO 1-22,3-dimethyl-2,4-hexylene glycol n-BO 1-22,4-dimethyl-2,4-hexylene glycol n-BO 1-22,5-dimethyl-2,4-hexylene glycol n-BO 1-23,3-dimethyl-2,4-hexylene glycol n-BO 1-23,4-dimethyl-2,4-hexylene glycol n-BO 1-23,5-dimethyl-2,4-hexylene glycol n-BO 1-24,5-dimethyl-2,4-hexylene glycol n-BO 1-25,5-dimethyl-2,4-hexylene glycol n-BO 1-22,3-dimethyl-2,5-hexylene glycol n-BO 1-22,4-dimethyl-2,5-hexylene glycol n-BO 1-22,5-dimethyl-2,5-hexylene glycol n-BO 1-23,3-dimethyl-2,5-hexylene glycol n-BO 1-23,4-dimethyl-2,5-hexylene glycol n-BO 1-23-methyl-3,5-heptanediol n-BO 1-22-(1, the 2-dimethyl propyl)-1, ammediol n-BO 1-22-ethyl-2,3-dimethyl-1,3 butylene glycol n-BO 12-methyl-2-sec.-propyl-1,3 butylene glycol n-BO 13-methyl-2-sec.-propyl-1,4-butyleneglycol n-BO 12,2,3-trimethylammonium-1,3-pentanediol n-BO 12,2,4-trimethylammonium-1,3-pentanediol n-BO 12,4,4-trimethylammonium-1,3-pentanediol n-BO 13,4,4-trimethylammonium-1,3-pentanediol n-BO 12,2,3-trimethylammonium-1,4-pentanediol n-BO 12,2,4-trimethylammonium-1,4-pentanediol n-BO 12,3,3-trimethylammonium-1,4-pentanediol n-BO 12,3,4-trimethylammonium-1,4-pentanediol n-BO 13,3,4-trimethylammonium-1,4-pentanediol n-BO 12,3,4-trimethylammonium-2,4-pentanediol n-BO 14-ethyl-2,4-hexylene glycol n-BO 12-methyl-2,4-heptanediol n-BO 13-methyl-2,4-heptanediol n-BO 14-methyl-2,4-heptanediol n-BO 15-methyl-2,4-heptanediol n-BO 16-methyl-2,4-heptanediol n-BO 12-methyl-2,5-heptanediol n-BO 13-methyl-2,5-heptanediol n-BO 14-methyl-2,5-heptanediol n-BO 15-methyl-2,5-heptanediol n-BO 16-methyl-2,5-heptanediol n-BO 12-methyl-2,6-heptanediol n-BO 13-methyl-2,6-heptanediol n-BO 14-methyl-2,6-heptanediol n-BO 12-methyl-3,5-heptanediol n-BO 12-(1, the 2-dimethyl propyl)-1, ammediol E 1-32-ethyl-2,3-dimethyl-1,3 butylene glycol E 1-32-methyl-2-sec.-propyl-1,3 butylene glycol E 1-33-methyl-2-sec.-propyl-1,4-butyleneglycol E 1-32,2,3-trimethylammonium-1,3-pentanediol E 1-32,2,4-trimethylammonium-1,3-pentanediol E 1-32,4,4-trimethylammonium-1,3-pentanediol E 1-33,4,4-trimethylammonium-1,3-pentanediol E 1-32,2,3-trimethylammonium-1,4-pentanediol E 1-32,2,4-trimethylammonium-1,4-pentanediol E 1-32,3,3-trimethylammonium-1,4-pentanediol E 1-32,3,4-trimethylammonium-1,4-pentanediol E 1-33,3,4-trimethylammonium-1,4-pentanediol E 1-32,3,4-trimethylammonium-2,4-pentanediol E 1-34-ethyl-2,4-hexylene glycol E 1-32-methyl-2,4-heptanediol E 1-33-methyl-2,4-heptanediol E 1-34-methyl-2,4-heptanediol E 1-35-methyl-2,4-heptanediol E 1-36-methyl-2,4-heptanediol E 1-32-methyl-2,5-heptanediol E 1-33-methyl-2,5-heptanediol E 1-34-methyl-2,5-heptanediol E 1-35-methyl-2,5-heptanediol E 1-36-methyl-2,5-heptanediol E 1-32-methyl-2,6-heptanediol E 1-33-methyl-2,6-heptanediol E 1-34-methyl-2,6-heptanediol E 1-3And/or 2-methyl-3,5-heptanediol E 1-3And
7. their mixture.IX. aromatic diol comprises: 1-phenyl-1; 1-phenyl-1, the 2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; 1-phenyl-1,3 butylene glycol; 3-phenyl-1,3 butylene glycol; 1-phenyl-1, the 4-butyleneglycol; 2-phenyl-1, the 4-butyleneglycol; And/or 1-phenyl-2, the 3-butyleneglycol;
X. be the homologue of above structure or the main solvent of analogue, wherein add one or more CH 2Group, and for added each CH 2Group, all the adjacent carbons from molecule is removed two hydrogen atoms to form carbon-to-carbon double bond, the hydrogen atom sum keeps constant in the molecule thereby make, and comprising:
2,2-two-2-propenyl-1, ammediol; 2-(1-pentenyl)-1, ammediol; 2-(2-methyl-2-propenyl)-2-(2-propenyl)-1, ammediol; 2-(3-methyl-1-butene base)-1, ammediol; 2-(4-pentenyl)-1, ammediol; 2-ethyl-2-(2-methyl-2-propenyl)-1, ammediol; 2-ethyl-2-(2-propenyl)-1, ammediol; 2-methyl-2-(3-methyl-3-butenyl)-1, ammediol; 2,2-diallyl-1,3 butylene glycol; 2-(1-ethyl-1-propenyl)-1,3 butylene glycol; 2-(crotyl)-2-methyl isophthalic acid, the 3-butyleneglycol; 2-(3-methyl-2-butene base)-1,3 butylene glycol; 2-ethyl-2-(2-propenyl)-1,3 butylene glycol; 2-methyl-2-(1-methyl-2-propenyl)-1,3 butylene glycol; 2,3-two (1-methyl ethylidene)-1,4-butyleneglycol; 2-(3-methyl-2-butene base)-3-methylene radical-1, the 4-butyleneglycol; 2-(1,1-dimethyl propyl-2-butylene-1,4-glycol; 2-(1-methyl-propyl)-2-butylene-1, the 4-glycol; 2-butyl-2-butylene-1, the 4-glycol; 2-vinyl-3-ethyl-1, the 3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1, the 4-pentanediol; 2-(1-propenyl)-1, the 5-pentanediol; 2-(2-propenyl)-1, the 5-pentanediol; 2-ethylidene-3-methyl isophthalic acid, the 5-pentanediol; 2-propylidene-1, the 5-pentanediol; 3-ethylidene-2,4-dimethyl-2,4-pentanediol; 2-(1, the 1-dimethyl ethyl)-4-amylene-1, the 3-glycol; 2-ethyl-2,3-dimethyl-4-amylene-1,3-glycol; 4-ethyl-2-methylene radical-1, the 4-hexylene glycol; 2,3,5-trimethylammonium-1,5-hexadiene-3,4-glycol; 5-ethyl-3-methyl isophthalic acid, 5-hexadiene-3,4-glycol; 2-(1-methyl ethylene)-1, the 5-hexylene glycol; 2-vinyl-1, the 6-hexylene glycol; 5,5-dimethyl-1-hexene-3,4-glycol; 5,5-dimethyl-1-hexene-3,4-glycol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-glycol; 2-vinyl-2,5-dimethyl-3-hexene-1,6-glycol; 2-ethyl-3-hexene-1, the 6-glycol; 3,4-dimethyl-3-hexene-1,6-glycol; 2,5-dimethyl-4-hexene-2,3-glycol; 3,4-dimethyl-4-hexene-2,3-glycol; 3-(2-propenyl)-5-hexene-1, the 3-glycol; 2,3-dimethyl-5-hexene-2,3-glycol; 3,4-dimethyl-5-hexene-2,3-glycol; 3,5-dimethyl-5-hexene-2,3-glycol; 3-vinyl-2,5-dimethyl-5-hexene-2,4-glycol; 6-methyl-5-methylene radical-1, the 4-heptanediol; 2,3-dimethyl-1,5-heptadiene-3,4-glycol; 2,5-dimethyl-1,5-heptadiene-3,4-glycol; 3,5-dimethyl-1,5-heptadiene-3,4-glycol; 2,6-two (methylene radical)-1,7-heptanediol; 4-methylene radical-1, the 7-heptanediol; 2,4-dimethyl-1-teracrylic acid, 5-glycol; 2,6-dimethyl-1-teracrylic acid, 5-glycol; 3-vinyl-5-methyl isophthalic acid-teracrylic acid, the 5-glycol; 6,6-dimethyl-1-teracrylic acid, 5-glycol; 4,6-dimethyl-2,4-heptadiene-2,6-glycol; 4,4-dimethyl-2,5-heptadiene-1,7-glycol; 2,5,5-trimethylammonium-2,6-heptadiene-1,4-glycol; 5,6-dimethyl-2-heptene-1,4-glycol; 5-ethyl-2-heptene-1, the 5-glycol; 2-methyl-2-heptene-1, the 7-glycol; 4,6-dimethyl-3-heptene-1,5-glycol; 3-methyl-6-methylene radical-3-heptene-1, the 7-glycol; 2,4-dimethyl-3-heptene-2,5-glycol; 2,5-dimethyl-3-heptene-2,5-glycol; 2,6-dimethyl-3-heptene-2,6-glycol; 4,6-dimethyl-3-heptene-2,6-glycol; 2,4-dimethyl-5-heptene-1,3-glycol; 3,6-dimethyl-5-heptene-1,3-glycol; 2,6-dimethyl-5-heptene-1,4-glycol; 3,6-dimethyl-5-heptene-1,4-glycol; 2,3-dimethyl-5-heptene-2,4-glycol; 2,2-dimethyl-6-heptene-1,3-glycol; 4-(2-propenyl)-6-heptene-1, the 4-glycol; 5,6-dimethyl-6-heptene-1,4-glycol; 2,4-dimethyl-6-heptene-1,5-glycol; 2-ethylidene-6-methyl-6-heptene-1, the 5-glycol; 4-(2-propenyl)-6-heptene-2, the 4-glycol; 5,5-dimethyl-6-heptene-2,4-glycol; 4,6-dimethyl-6-heptene-2,5-glycol; 5-vinyl-4-methyl-6-heptene-2, the 5-glycol; 2-methylene radical-1, the 3-ethohexadiol; 2,6-dimethyl-1,6-octadiene-3,5-glycol; 3,7-dimethyl-1,6-octadiene-3,5-glycol; 2,6-dimethyl-1,7-octadiene-3,6-glycol; 2,7-dimethyl-1,7-octadiene-3,6-glycol; 3,6-dimethyl-1,7-octadiene-3,6-glycol; 3-vinyl-1-octene-3, the 6-glycol; 2,7-dimethyl-2,4,6-sarohornene-1,8-glycol; 3,7-dimethyl-2,4-octadiene-1,7-glycol; 2,6-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,6-octadiene-1,4-glycol (Rosiridol); 2-methyl-2,6-octadiene-1,8-glycol; 3,7-dimethyl-2,7-octadiene-1,4-glycol; 2,6-dimethyl-2,7-octadiene-1,5-glycol; 2,6-dimethyl-2,7-octadiene-1,6-glycol (8-hydroxyl phantol); 2,7-dimethyl-2,7-octadiene-1,6-glycol; The 2-octene-1, the 4-glycol; The 2-octene-1, the 7-glycol; 2-methyl-6-methylene radical-2-octene-1, the 7-glycol; 3,7-dimethyl-3,5-octadiene-1,7-glycol; 2,7-dimethyl-3,5-octadiene-2,7-glycol; 4-methylene radical-3, the 5-ethohexadiol; 2,6-dimethyl-3,7-octadiene-1,6-glycol; 2,7-dimethyl-3,7-octadiene-2,5-glycol; 2,6-dimethyl-3,7-octadiene-2,6-glycol; 4-methyl-3-octene-1, the 5-glycol; 5-methyl-3-octene-1, the 5-glycol; 2,2-dimethyl-4,6-octadiene-1,3-glycol; 2,6-dimethyl-4,7-octadiene-2,3-glycol; 2,6-dimethyl-4,7-octadiene-2,6-glycol; 7-methyl-4-octene-1, the 6-glycol; 2,7-two (methylene radical); The 2-methylene radical-; 2,7-dimethyl-5,7-octadiene-1,4-glycol; 7-methyl-5,7-octadiene-1,4-glycol; The 5-octene-1, the 3-glycol; 7-methyl-6-octene-1, the 3-glycol; 7-methyl-6-octene-1, the 4-glycol; The 6-octene-1, the 5-glycol; 7-methyl-6-octene-1, the 5-glycol; 2-methyl-6-octene-3, the 5-glycol; 4-methyl-6-octene-3, the 5-glycol; 2-methyl-7-octene-1, the 3-glycol; 4-methyl-7-octene-1, the 3-glycol; 7-methyl-7-octene-1, the 3-glycol; The 7-octene-1, the 5-glycol; The 7-octene-1, the 6-glycol; 5-methyl-7-octene-1, the 6-glycol; 2-methyl-6-methylene radical-7-octene-2, the 4-glycol; 7-methyl-7-octene-2, the 5-glycol; 2-methyl-7-octene-3, the 5-glycol; 1-nonene-3, the 5-glycol; 1-nonene-3, the 7-glycol; 3-nonene-2, the 5-glycol; 8-methyl-4,6-nonadiene-1,3-glycol; 4-nonene-2, the 8-glycol; 6,8-nonadiene-1,5-glycol; 7-nonene-2, the 4-glycol; 8-nonene-2, the 4-glycol; 8-nonene-2, the 5-glycol; 1,9-decadiene-3,8-glycol; And/or 1,9-decadiene-4,6-glycol; And
XI. their mixture.
This transparent composition can be randomly, but preferably, contain: (1) is enough to improve the low-molecular weight water-soluble solvent of effective quantity of transparency, for example ethanol, Virahol, propylene glycol, 1, ammediol, Texacar PC etc., this water-soluble solvent exists with the content that can not be formed clear composition by himself; (2) randomly, but preferably, 0%-is about 15%, preferably about 0.1%-8%, more preferably from about 0.2%-5% spices; (3) randomly, 0%-is about 2%, preferably about 0.01%-0.2%, more preferably from about 0.035%-0.1% stablizer; (4) randomly, the water-soluble Ca salt of effective quantity of enhancing the transparency and/or magnesium salts, preferred muriate.
The equipoise of said composition generally is a water.
Preferably the present composition is to contain the 3%-95% that has an appointment, preferably about 10%-80%, more preferably from about 30%-70% even the more preferably from about water of 40-about 60% and about 5%-40%, preferably about 7%-35%, more preferably from about 10%-25% even above-mentioned alcohols main solvent B water base, translucent or transparent of 12%-18% more preferably from about, the composition of preferably transparent, these preferred products (composition) are not translucent or transparent under the situation of no main solvent B.Translucent or transparent for composition is become, 50% of the organic solvent total amount that the quantity of employed main solvent B preferably surpass to exist more preferably surpasses approximately 60%, even more preferably surpasses about 75%.
Preferably main solvent content is remained on the minimum level that acceptable stability/transparency can be provided to the present composition.The existence of water is for having material impact for making these compositions reach transparent required main solvent.Water-content is high more, and is high more for realizing the transparent required main solvent content of product (with respect to softening agent content).Otherwise water-content is few more, and the main solvent (with respect to softening agent) that needs is few more.Therefore, under the low water content of about 3-15%, the weight ratio of softening agent actives and main solvent is preferably about 55: 45 to about 85: 15, more preferably from about 60: 40 to about 80: 20.Under the water-content of about 15%-70%, the weight ratio of softening agent actives and main solvent is preferably about 45: 55 to about 70: 30, more preferably from about 55: 45 to about 70: 30.But under the high water content of about 70%-80%, softening agent actives and main solvent weight ratio are preferably about 30: 70 to about 55: 45, more preferably from about 35: 65 to about 45: 55.When water-content is higher, the ratio of softening agent/main solvent should in addition higher.
For a minute lively stock, the content of actives is about 5%-35%, preferably about 8%-30%, 10%-28% more preferably from about, even the mixture of the described compound of 13%-26% or this compound more preferably from about.
The pH of said composition should be about 1-5, preferably about 2-4, more preferably from about 3-4.
Detailed Description Of The Invention I. fabric sofetening actives
The transparent fabric sofetening composition of the present invention contains and accounts for the about 2-75% of said composition weight, preferably about 8-70%, 13-65% even more preferably from about 18-40% is as the fabric softener active matter of the above-mentioned specific necessity of this paper of necessary component more preferably from about, and it has following formula:
[RC (O) OC 2H 4] nN +(R 1) mX -Wherein each R in the compound is C 6-C 22Alkyl, based on the IV meter with preferably suitable/inverse proportional lipid acid hereinafter described of equivalence, preferably having IV is about 70-140, is the numerical value of 1-3 by weight average n in any mixture of compound, each R in the compound 1Be C 1-3Alkyl or hydroxyalkyl, n and be the R of hydroxyethyl groups 1The summation of group number equals 3, and n+m equals 4, and X is the negatively charged ion compatible with softening agent, the preferable methyl sulfate radical.(C18: lipid acid 1 component) suitable: the ratio of trans isomer preferably was at least about 1: 1, and preferred about 2: 1, more preferably 3: 1, even more preferably from about 4: 1, or higher.
The mixture of this compound or compound have (a) Hunter " L " transmission value be at least about 85, generally about 85-95, preferably about 90-95 if possible, more preferably is higher than about 95; (b) under working conditions, have only low amount, the scent of compound of promptly relative non-detection limit, it is selected from isopropyl acetate; 2,2 '-ethylene (oxygen), two propane; 1,3,5-trioxane and/or short chain fatty acid (4-12, a particularly 6-10 carbon atom) ester, particularly methyl esters; Or (c) preferably has the two.
Hunter " L " transmission value is by following mensuration: (1) is about 10% solvent of actives with softening agent actives and content, transparent to guarantee, preferred solvent is ethoxylation (1 mole of EO) 2,2,4-trimethylammonium-1, HunterAssociates Laboratory is used with respect to distilled water in 3-pentanediol and (2), Reston, the Hunter ColorQUEST of Virginia preparation Colorimeter is measured the L colour.
Go up the amount that the content of aerial odoriferous substance defines odoring substance by being determined at softening agent actives sample (about 92% actives).Use produces color atlas at the 200ml sample in about 2 gram sample sky.This sky sample is absorbed on the solid absorbent and by at about-100 ℃ of following low temperature the light direct heat being separated and is drawn onto on the post.The evaluation of material composition is based on chromatographic peak.More certified impurity relate to the solvent (for example ethanol and Virahol) that uses in quaternized method.Oxyethyl group and methoxy-ether generally are sweet tastes.In common commercial sample, find to have C 6-C 8Methyl esters, but in the typical softening agent actives of the present invention, do not have.These esters impel common commercial sample that perceptible relatively poor smell is arranged.The content of each material odorous of finding in general commercial sample is as follows:
The roughly concentration of overhead impurity
Chemical identification phase concentrations (ng/L)
The typical sample isopropyl acetate 6＜11 of the present invention of commercial sample, 3,5-trioxane 61 52,2 '-subunit two (oxygen), two propane, 244＜1C6 methyl ester, 10＜1C8 methyl ester, 9＜1C10 methyl ester 4＜1
The acceptable content of each odoriferous substance is as follows: isopropyl acetate should be lower than about 5, preferably be lower than about 3, more preferably less than about 2 millimicro grams per liters (η g/L); 2, it is about 200 that 2 '-ethylene (oxygen), two propane should be lower than, preferably be lower than about 100, more preferably less than about 10, even more preferably less than about 5 millimicro grams per liters (η g/L); 1,3, it is about 50 that the 5-trioxane should be lower than, preferably be lower than about 20, more preferably less than about 10, even more preferably less than about 7 millimicro grams per liters (η g/L); And/or each short chain fatty acid (4-12, a particularly 6-10 carbon atom) ester, particularly methyl esters should be lower than about 4, preferably be lower than about 3, more preferably less than about 2 millimicro grams per liters (η g/L).
After this compound is made, or preferably finish coloured and elimination odoriferous substance by selective reaction thing and reaction conditions.Preferably, the reactant of selection has good smell and color.For example, can obtain being used for the lipid acid in long fatty acyl group source or their ester, they have good color and smell and have the short chain (C of extremely low amount 4-12, C particularly 6-10) the fatty acyl group group.In addition, reactant can be cleaned before use.For example, fatty acid reactant can be removed the matrix that causes color and smell and remove short chain fatty acid through twice or three distillations.In addition, the color of trolamine reactant need be controlled to low color level (for example, press the APHA standard, color readings is about 20 or lower).Required degree of purification depends on other component of usage quantity and existence.For example, add dyestuff and can hide some colors.But for the product of transparent and/or light color, color must can detect hardly.For the actives of high level, for example by the weight of composition, about 8%-75%, preferably about 13%-60%, 18%-40% softening agent actives more preferably from about, situation is particularly like this.Similarly, smell can hide by the spices of high level, but under the situation of high level softening agent actives, there is high relatively expense in relevant this method, particularly damages with regard to the smell quality with regard to having to.The smell quality can further be improved by using the ethanol as the quaterisation solvent.
Preferred biodegradable fabric softener compound comprises quaternary ammonium salt, this quaternary ammonium salt is the quaternized products of condensation between following reactant: a) derivative of fractional saturation or unsaturated, straight or branched lipid acid or described acid, described lipid acid or derivative have the hydrocarbon chain that carbonatoms is 5-21 separately, and b) trolamine, be characterised in that described condensation product has acid number and is lower than about 6.5 by measuring with relative this condensation product of phenolphthalein indicator titration of KOH standardized solution.
It is about 5 that this acid number preferably is less than or equal to, more preferably less than about 3.In fact, the AV value is low more, and the softness that obtains is good more.
This acid number is measured with relative this condensation product of phenolphthalein indicator titration of KOH standardized solution by according to ISO#53402.AV is represented as mgKOH/g.
In order to obtain best soft effect, preferred reactant is that the mol ratio with fatty acid part and trolamine is about 1: 1-2.5: 1 existence.
Also the softness that discovery is best is also carried the influence of the wash conditions of washing composition, is more particularly used the influence of the anion surfactant that exists in the solution of soft compound.In fact, the anion surfactant that carries out from washing can interact with softener compound usually, reduces its performance thus.Therefore, according to working conditions, the mol ratio of lipid acid/trolamine may be crucial.Therefore, in wash(ing)cycle with contain and do not have between the rinsing cycle of softening compound thing under the situation that rinse takes place, the anion surfactant of a large amount can be carried and enter in the rinsing cycle of containing the softening compound thing.In this case, the mol ratio of having found fatty acid part/trolamine is about 1.4: 1-1.8: the 1st, and preferred.The anion surfactant of a large amount meaning is that the content of the anion surfactant that exists in rinsing cycle makes the mol ratio of anion surfactant/cationic softener compound of the present invention be at least about 1/10.
Therefore, according to a further aspect in the invention, a kind of method of handling fabric is provided, it comprises the step that fabric is contacted with water-bearing media, this water-bearing media contains softener compound of the present invention or its soft compound, wherein the mol ratio of lipid acid/trolamine is about 1.4 in this softener compound: 1-1.8: 1, and preferred about 1.5: 1, the mol ratio that this water-bearing media comprises anion surfactant and softener compound of the present invention was at least about 1: 10.
On the other hand, taking place then to carry out less anion surfactant under the intermediary situation of rinsing cycle between the rinsing cycle in wash(ing)cycle and later stage, promptly the mol ratio of anion surfactant and cation compound of the present invention is less than about 1: 10.Therefore, the mol ratio of having found lipid acid/trolamine is about 1.8: 1-2.2: 1 is preferred.Therefore, in another aspect of this invention, a kind of method of handling fabric is provided, it comprises the step that fabric is contacted with water-bearing media, this water-bearing media contains softener compound of the present invention or its soft compound, wherein the mol ratio of lipid acid/trolamine is about 1.8 in this softener compound: 1-2: 1, and preferred about 2.0: 1, the mol ratio that this water-bearing media comprises anion surfactant and softener compound of the present invention was lower than about 1: 10.
In the preferred embodiment of the invention, fatty acid part and trolamine are to be about 1 with mol ratio: 1-2.5: 1 exists.
Preferred cation, preferred biodegradable quaternary ammonium fabric softening compound thing can contain-C (O) R group, this group is derived from animal tallow, unsaturated and polyunsaturated lipid acid oleic acid for example, and/or partial hydrogenation fat acid, this partially hydrogenated fatty acid derived from vegetables oil and/or partially hydrogenated vegetables oil as low leaf mustard seed oil, Thistle oil, peanut oil, Oleum Helianthi, Semen Maydis oil, soybean oil, Yatall MA, rice bran wet goods.The unrestricted example of lipid acid (FA) has following roughly distribution: fatty acyl group FA 1FA 2FA 3FA 4FA 5C12 trace trace 00 0,C14 3300 0,C16 4455 5,C18 0056 6C14: 13300 0C16: 1 11 700 3C18: 1 74 73 71 68 67C18: 2488 11 11C18: 30112 2C20: (C18: 1) TPU 49 10 13 13 for 10022 2C20 and above 00200 unknown materials, 00667 totals, 99 99 100 100 102IV 86--90 88--95,99 100 95 cis/trans 20-30 20-30 455
TPU is the percentage ratio of many unsaturatess of existence.
Mixture that can use lipid acid and mixture by the FA of different fatty acid derived, and be preferred.The unrestricted example that can mix the FA that forms FA of the present invention is as follows: fatty acyl group FA 6FA 7C14 0 1,C16 11 25,C18 4 20C14: 10 0C16: 11 0C18: 1 27 45C18: 2 50 6C18: 370 unknown materials 03 amount to 100 100IV 125--138,56 cis/trans (C18: 1) do not obtain 7TPU 57 6FA6By soya fatty acid preparation, FA 7By slight hydrogenant tallow fatty acid preparation.
The preferred necessary softening agent actives that contains the molecule of the hydrophobic grouping [RC (CO) O-] that connects 2 ester bonds containing of significant quantity, this actives is called " DEQA " hereinafter, it is to be prepared as those of single DEQA by the mixture of all different lipid acid of representative (the total mixture of lipid acid), rather than by the mixture of the independent finished product DEQA mixture of the different piece preparation of total fatty acids mixture.
Preferably most of at least fatty acyl group is undersaturated, for example about 50%-100%, and preferably about 55%-95%, 60%-90% more preferably from about, the total concn (TPU) that contains the actives of polyunsaturated fat acyl group is preferably about 3%-30%.The cis/trans ratios of unsaturated fatty acyl group is normally important, and suitable/reverse proportionality is about 1: 1 to about 50: 1, and Schwellenwert is about 1: 1, and preferably at least 3: 1, more preferably from about 4: 1 to about 20: 1.(percentage ratio of total R group that " percentage ratio of softening agent actives " that contains given R group used herein and same R group occupy all softening agent activess of preparation is identical).
Undersaturated, comprise that preferred polyunsaturated fatty acyl group and/or the alkylidene group of above and hereinafter discussing provide effective softness to turn usefulness into astoundingly; but also provide good rewetting characteristic, good antistatic property and particularly excellent freezing and thaw after restorability.
Also easier spissated premixture, this concentrated their the low viscosity of premixture maintenance, so easier processing, for example pumping, mixing etc. of being mixed with of height unsaturated materials.These highly undersaturated materials (total amount that contains the actives of polyunsaturated fat acyl group (TPU) is generally about 3%-30%) are having only low measuring under common and this material bonded solvent situation; promptly; account for about 5%-20% of softening agent/solvent mixture gross weight; preferred about 8%-25%; more preferably from about 10%-is about 20%, even be mixed with dense, the stable present composition then also easilier at ambient temperature.This ability of at low temperatures actives being processed is for many unsaturated groups particularly important, because it has reduced degraded.As described later, when containing good antioxidant, sequestrant and/or reductive agent in compound and the softener composition, can provide other anti-degraded provide protection.
Should be clear, R and R 1Substituting group can randomly be replaced by various groups, for example alkoxyl group or hydroxyl, and can be straight or branched, as long as the R group keeps its hydrophobic basically characteristic.
Preferred long-chain DEQA is the DEQA by the feedstock production that contains the many degrees of unsaturation of high-content; be methylsulfuric acid N; N-two (acyl group oxygen ethyl)-N; the N-dimethyl hydroxyethyl ammonium; wherein acyl group is by the fatty acid derived that contains enough degrees of unsaturation, for example the mixture of tallow fatty acid and soya fatty acid.Another kind of preferred long-chain DEQA is two oil bases (nominal) DEQA, i.e. methylsulfuric acid N wherein, and N-two (oleoyl oxygen ethyl)-N, the N-dimethyl hydroxyethyl ammonium is the DEQA of main ingredient.The preferred feedstock that is used for the lipid acid of this DEQA is a vegetables oil, and/or has the partially hydrogenated vegetables oil of high-content degree of unsaturation, for example oleoyl.
As used in this article, when regulation DEQA diester (n=2), it can comprise the monoesters (n=1) and/or three esters (n=3) of existence.Be diester form at least about 30% DEQA preferably, 0 to about 30% can be the DEQA monoesters, for example has 3 R 1Group.For softnessization, do not having/wash conditions that seldom washing composition is taken out of under, the percentage composition of monoesters should be low as far as possible, preferably is no more than about 15%.But under the high condition of anionic detergent tensio-active agent or detergent builder drag-out, some monoesters is desirable.Diester season thing and monoesters season thing overall proportion be from about 2.5: 1 to about 1: 1, preferably from about 2.3: 1 to about 1.3: 1.Taking out of under the high detergent amount condition, diester/monoesters ratio is preferably about 1.3: 1.The content of monoesters can be controlled by the ratio that changes lipid acid or fatty acyl group source and trolamine when making DEQA.Diester season thing and three ester season thing overall proportion be about 10: 1-1.5: 1, preferred about 5: 1-2.8: 1.
As the above compound of the soft material of necessary biodegradable quaternized ester-amine, can prepare in the embodiment of this invention with the reactive chemistry of standard.In a kind of synthetic method of the diester variations of DTDMAC, formula N (CH 2CH 2OH) 3Amine preferably at two hydroxyl places all with chemical formula be the chloride of acid esterification of RC (O) Cl to form a kind of amine, this amine can be made cationic (R is H) by acidifying, this is a class softening agent, or uses alkylogen R subsequently 1X makes it quaternized, forms desired reaction product (wherein R and R 1Definition is the same).But chemical field the professional will appreciate that, this reaction sequence can be prepared the reagent of extensive selection.
In preferred DEQA softening agent actives, each R is an alkyl, or the alkyl that replaces, preferred alkyl, monounsaturated alkenyl and polyunsaturated alkenyl, by the gross weight of the softening agent actives that exists, the softening agent actives that contains polyunsaturated alkenyl is preferably at least about 3%, more preferably at least about 5%, more preferably at least about 10%, even more preferably at least about 15%; This actives preferably contains blended R group, particularly in the discrete molecule.
In preferred quaternary ammonium fabric softening compound thing, particularly in DEQA, RC (O) O is derived from unsaturated fatty acids, oleic acid for example, and/or the lipid acid and/or the partially hydrogenated lipid acid of deriving and forming from animal tallow, vegetables oil and/or partially hydrogenated vegetables oil such as Tower rape oil, Thistle oil, peanut oil, Oleum Helianthi, soybean oil, Semen Maydis oil, Yatall MA, rice bran wet goods.Used herein, the biodegradable fabric softener active matter that similarly contains ester bond is known as " DEQA ", and it comprises diester, three esters and the monoester compound that contains 1-3, preferred 2 long-chain hydrophobic groups.These fabric softener active matters are characterised in that can wherein there be about 15% solvent C as indicated above in they at least by the conventional blending means processing under the room temperature.
The DEQA of this paper can also contain the lipid acid of low levels, and this lipid acid can be from the by product of any part degraded (hydrolysis) of unreacted initiator that is used for preparing DEQA and/or final product composition having softening agent actives.The preferably low amount of free fatty acids preferably is lower than the about 15% of softening agent actives weight, more preferably less than about 10%, even more preferably less than about 5%.The preferred method of preparation softening agent actives
Fabric softener active matter of the present invention is preparation by the following method preferably, wherein with sequestrant, and preferred diethylentriamine pentacetate (DTPA) and/or quadrol-N, N '-disuccinate (EDDS) adds in this technology.In addition, preferably after distillation and/or fractionation, immediately and/or in esterification reaction process and/or before quaterisation or in the process antioxidant is added in the lipid acid, and/or after prepare burden in the finished product softening agent actives.The softening agent actives that obtains has reduced decolouring and relevant with it unpleasant odor.Typical method may further comprise the steps:
A) provide the triglyceride level source, and make this triglyceride level source reaction form the mixture of lipid acid and/or fatty acid ester;
B) use the mixture that obtains from step (a), under enzymatic synthesis condition, react with trolamine;
C), under quaternized condition, make from the mixture and the formula R of the fatty acid ester of step (b) formation if need 1The quaternizing agent of X reacts, thereby makes this mixture quaternized, wherein R 1Such as in step (b) definition, X is the negatively charged ion compatible with softening agent, be preferably selected from chlorine, bromine, methylsulfate, ethyl sulphate, sulfate radical and nitrate radical, form the quaternary ammonium fabric softener actives thus, methylsulfate and ethyl sulphate are highly preferred, wherein step (c) is to be selected from diethylene triaminepentaacetic acid(DTPA), quadrol-N in existence at least, carries out under the sequestrant of N '-disuccinic acid and their mixture.
Make the step of triglyceride level source reaction also can be included in the reaction of sequestrant under existing, step (b) also can comprise and has sequestrant.
The total amount of the sequestrant that adds, by the weight of the softening agent actives that makes, preferably at about 10ppm-5000ppm, 100ppm-2500ppm scope more preferably from about.This triglyceride level source is preferably selected from animal tallow, vegetables oil, partially hydrogenated vegetables oil and its mixture.More preferably vegetables oil or partially hydrogenated vegetables oil are selected from Tower rape oil, partially hydrogenated Tower rape oil, Thistle oil, partially hydrogenated Thistle oil, peanut oil, partially hydrogenated peanut oil, Oleum Helianthi, partially hydrogenated Oleum Helianthi, Semen Maydis oil, partially hydrogenated Semen Maydis oil, soybean oil, partially hydrogenated soybean oil, Yatall MA, partially hydrogenated Yatall MA, Rice pollard oil, partially hydrogenated Rice pollard oil and their mixture.Most preferably the triglyceride level source is Tower rape oil, partially hydrogenated Tower rape oil and their mixture.This method also comprise to the step (a) and (b) or (c) any step or institute in steps in adding by the step of the antioxidant of the about 0.01%-2% of weight of composition.
Above method has produced the fabric softener active matter of color and unpleasant odor reduction.
The present invention also comprises preparation soft fabric premixture method for compositions.This method comprises and prepares soft fabric actives and with this fabric softener active matter as stated above, randomly contains low-molecular-weight solvent, and has the main solvent of ClogP for about 0.15-0.64 and mixes, and forms the fabric softener premixture thus.This premixture can comprise actives and about 10%-30% weight main solvent of about 55%-85% weight soft fabric.This method comprises that also adding is selected from ethanol, Virahol, propylene glycol, 1, the step of the low-molecular weight water-soluble solvent of ammediol, propylene carbonate, hexylene glycol and its mixture in this premixture.In addition, this method also can comprise to the step (a) and (b) or (c) any step or institute in steps in adding by the step of the anti-oxidant compounds of the about 0.01%-2% of weight of composition.The product of above method preparation is new composition.
The method of the fabric sofetening composition of preparation dispersion form comprises the step that forms premixture as stated above and passes through mixes the step that forms water base body with water and mineral acid; And, under agitation form fabric sofetening composition with premixture and the mixing of water base body.This method also comprises one or more following steps: comprise by adding calcium chloride solution and regulate the step of the viscosity of fabric sofetening composition, add sequestrant and in water base body in premixture, or preferably add perfume composition in finished product.The product of above method preparation also is new composition.II. optional, but preferred main solvent system
The present composition contains and accounts for composition weight and be less than about 40%, preferably about 10%-35%, more preferably from about 12%-25% even the main solvent of 14%-20% more preferably from about.The smell minimum that selected main solvent will make solvent that composition is produced, and make final composition have low viscosity.For example, Virahol is not very effective and the intensive smell is arranged.N-propyl alcohol is comparatively effective, but tangible smell is also arranged.Several butanols are scent of also, but because effectively the transparency/stability is especially used to reduce its smell as the part of main solvent system so can use.Selection to alcohols also comprises best low-temperature stability, that is, still to form under about 40 °F (about 4.4 ℃) be the composition of liquid being low to moderate for they, and it has acceptable low viscosity and translucent, preferably transparent, and after being low to moderate about 20 (about 6.7 ℃) following storage, can restore.
For preparation have requirement stability liquid state of the present invention, concentrate, the fabric softener composition of preferably transparent, the suitability of any main solvent all is optionally astoundingly.Suitable solvent can be selected according to its octanol/water partition ratio (P).The ratio of the equilibrium concentration that the octanol/water partition ratio of main solvent is it in octanol and water.The partition ratio of main solvent component of the present invention is represented their denary logarithm log P forms easily.
The existing report of the log P of a lot of components, for example, can be from Daylight Chemical Information System company (Daylight CIS), Irvine, Califonia, Pomona 92 databases that obtain comprise a lot of data and have quoted original.But log P value most convenient ground is to calculate with " CLOG P " program, and this program also can obtain from Daylight CIS.This program has also been listed the log P experimental value that has in Pomona 92 databases." logP of calculating " (Clog P) determines (referring to A.Leo with the fragment method of Hansch and Leo, at " synthetic medicine chemistry " (Comprehensive Medicinal Chemistry) the 4th volume (C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ramsden compile), the 295th page, Pergamon Press, 1990, this paper quotes as a reference).Fragment method is the chemical structure based on each component, and considers number and type, atom connectivity and the chemical bond of atom.This Clog P value is the most reliable and widely used estimated value for these physicochemical property, preferably uses the experimental value of Clog P rather than log P when selecting to can be used for main solvent component of the present invention.Other method that can be used for calculating Clog P is included in the fragment method of the Crippen described in chemical information and the computational science magazine (J.Chem.Inf.Comput.Sci.) 27,21 (1987); Fragment method at the Viswanadhan described in chemical information and the computational science magazine 29,163 (1989); With method at the Broto described in the European medicinal chemistry (Eur.J.Med.Chem.-Chim.Theor.) 19,71 (1984).
The Clog P of the selected main solvent of the present invention is about 0.64 for about 0.15-, and preferably about 0.25-is about 0.62, and more preferably from about 0.40-is about 0.60, and this main solvent is preferably asymmetric, and preferably its fusing point (or solidification point) makes it in room temperature or to be bordering under the room temperature be liquid state.For some reason, lower molecular weight and biodegradable solvent also need.As if more asymmetric solvent very desirable, and the symmetric solvent of the height with symmetry centre is as 1,7-heptanediol or 1, two (methylol) hexanaphthenes of 4-show the composition that can not form substantial transparent when using separately, though its Clog P value is in the preferred value scope.A kind of can selecteed optimal main solvent by contain 27% chlorination two of having an appointment (oleoyl oxygen ethyl) Dimethyl Ammonium, about 16-20% main solvent and about 4%-6% alcoholic acid composition about 40 °F (about 4.4 ℃) down storage whether keep transparent and under about 0 °F (-18 ℃ approximately), whether can restore to determine from freezing state.
Most preferred main solvent can be differentiated by the outward appearance of handling the dilution process composition that fabric uses.These dilute compositions are dispersions of fabric softener, and its fabric softener composition demonstration that has more the multilamellar vesicle outward appearance than routine has more the unilamellar vesicle outward appearance.As if outward appearance is more near the individual layer system, and the performance of composition is good more.These preferred compositions are on depositing to fabric the time, and showing provides more uniform covering.These compositions are compared with the analogous composition for preparing with same fabric softener active matter in the usual way, and good fabric sofetening effect is provided astoundingly.This composition is compared the spices deposition of also having improved some components inherently with the fabric sofetening composition of routine, especially when spices in room temperature or when being added in the composition under the room temperature.
The available main solvent is above open.Open more specifically, be to list with various layout order, for example, have the aliphatic series and/or the alicyclic diol of given carbonatoms; Monohydroxy-alcohol; Glycerol derivative; The alcoxylates of dibasic alcohol; And the mixture of all above-mentioned substances is found in disclosed PCT application on January 30th, 1997 WO97/03169, this application is quoted for referencial use at this paper, optimal disclosure is seen the 24-82 page or leaf and the 94-108 page or leaf (preparation method) of described WO97/03169 specification sheets.The reference numbering that contains chemical abstracts service's accession number (CAS No.) of those compounds that have this chemical abstracts service accession number in this disclosure, other compound have the method description that can be used to prepare this compound.Some inapplicable main solvent also is listed in this disclosure.But inapplicable main solvent can use with mixture with the main solvent that is suitable for.The available main solvent can be used for preparing the dense fabric softener composition that meets the aforementioned stability of this paper/transparency requirement.
The glycols main solvent that much has same chemical formula can exist with multiple steric isomer and/or optically active isomer form.Each isomer is for example specified different CAS No. usually, 4-methyl-2, and the different isomer of 3-hexylene glycol has been specified following CAS No.:146452-51-9 at least; 146452-50-8; 146452-49-5; 146452-48-4; 123807-34-1; 123807-33-0; 123807-32-9; And 123807-31-8.
In described PCT specification sheets, each chemical formula is only listed a CAS No..This explanation only be exemplary and for enforcement of the present invention this is enough.This explanation is nonrestrictive.Therefore, should know that other isomer with other CAS No. and composition thereof is also included within.By the same token, when certain CAS No. represents a branch period of the day from 11 p.m. to 1 a.m that contains some specific isotope, for example deuterium, tritium, carbon-13 etc., be to be understood that then the isotopic material that contains natural distributed is also included within, vice versa.Similarly disclosure is seen the E.H.Wahl that on July 11st, 1996 submitted to, T.Trinh, E.P.Gosselink is in the existing autre action pendante patent application serial numbers 08/679694 of J.C.Letton and M.R.Sivik, wherein disclose the compound of soft fabric, this application is quoted for referencial use at this paper.
There is not to provide the present invention C of transparent concentrated fabric softener compositions 1-2Monohydroxy-alcohol.Has only a kind of C 3Monohydroxy-alcohol, n-propyl alcohol, have acceptable performance (form transparent product and keep transparent until about 4 ℃ or when being warmed to room temperature again, restore), but it has unfavorable lower boiling (BP).At C 4In the monohydroxy-alcohol, have only 2-butanols and 2-methyl-2-propyl alcohol to have extraordinary performance, but 2-methyl-2-propyl alcohol have unfavorable low BP.Except top and the unsaturated monohydroxy-alcohol mentioned later, there is not to form the C of transparent product 5-6Monohydroxy-alcohol.
In chemical formula, there is the main solvent of two hydroxyls to be suitable for preparing liquid state of the present invention, dense, transparent fabric softener composition.The suitability of various main solvents has selectivity astoundingly, and this depends on the number of carbon atom, the molecule isomer configuration that same carbon atoms number is arranged, degree of unsaturation etc.The main solvent that has similar dissolubility property and at least some asymmetry with above main solvent will have same effect.The ClogP value of suitable main solvent is about 0.64 for about 0.15-, and preferably about 0.25-is about 0.62, and more preferably from about 0.40-about 0.60.
For example, for general formula HO-CH 2-CHOH-(CH 2) n1 of-H, 2-alkanediol main solvent series, n is 1-8, have only 1, the ClogP value of 2-hexylene glycol (n=4) is about 0.53, and it is in effective ClogP scope of about 0.15-about 0.64, this solvent is a kind of good main solvent, belong within the claim scope of the present invention, and the ClogP value exceeds other glycol outside the useful range 0.15-0.64, for example 1,2-propylene glycol, 1,2-butyleneglycol, 1,2-pentanediol, 1,2-ethohexadiol, 1, the 2-decanediol then is not.In addition, among the isomer of hexylene glycol, 1, the 2-hexylene glycol is again good main solvent, and the ClogP value exceeds a lot of other isomer outside the useful range 0.15-0.64 as 1,3-hexylene glycol, 1,4-hexylene glycol, 1,5-hexylene glycol, 1,6-hexylene glycol, 2,4-hexylene glycol and 2, the 5-hexylene glycol then is not.
The C of the transparent concentrate composition on the meaning of the present invention can be provided 3-C 5Dibasic alcohol.
Though a lot of C are arranged 6Dibasic alcohol is possible isomer, but has only just being fit to of listing above to prepare transparent product, and wherein has only 2,3-dimethyl-1,2-butyleneglycol; 3,3-dimethyl-1,2-butyleneglycol; 2-methyl-2, the 3-pentanediol; 3-methyl-2, the 3-pentanediol; 4-methyl-2, the 3-pentanediol; 2, the 3-hexylene glycol; 3, the 4-hexylene glycol; 2-ethyl-1, the 2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; With 1, the 2-hexylene glycol is preferred, most preferably: 2-ethyl-1,2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; With 1, the 2-hexylene glycol.
C 7The possible isomer of glycol is more, but only lists those that can form opaque products, preferably: 2-butyl-1,3 butylene glycol; 2-propyl group-1, the 4-butyleneglycol; 2-ethyl-1, the 5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; The 2-methyl isophthalic acid, the 6-hexylene glycol; The 3-methyl isophthalic acid, the 6-hexylene glycol; 1, the 3-heptanediol; 1, the 4-heptanediol; 1, the 5-heptanediol; 1, the 6-heptanediol; Wherein most preferably: 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol and 2,3-dimethyl-3,4-pentanediol.
Similarly, C 8It is many that the glycol isomer is also wanted, but only list those that can form opaque products, preferably: 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2,2-diethyl-1,3 butylene glycol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-ethyl-2,3-dimethyl-1,3 butylene glycol; 2-(1, the 1-dimethyl ethyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 2-methyl-2-sec.-propyl-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 3-methyl-2-sec.-propyl-1, the 4-butyleneglycol; 2,2,3-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1,3-pentanediol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,4,4-trimethylammonium-1,3-pentanediol; 3,4,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,4-pentanediol; 2,2,4-trimethylammonium-1,4-pentanediol; 2,3,3-trimethylammonium-1,4-pentanediol; 2,3,4-trimethylammonium-1,4-pentanediol; 3,3,4-trimethylammonium-1,4-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2,3,4-trimethylammonium-2,4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol; Be most preferred wherein: 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol.
Preferred eight carbon atom 1, the mixture condensation that 3 diol mixtures can pass through butyraldehyde, isobutyric aldehyde and/or methylethylketone (2-butanone) forms, as long as in the reaction mixture at least two kinds of these reactants are arranged, is reflected under the existence of high alkalinity catalyzer and carries out, subsequently by being hydroconverted into eight carbon 1, the mixture of 3-glycol, that is, and main eight carbon 1 that constitute by following compound, 3 diol mixtures: 2,2,4-trimethylammonium-1,3-pentanediol; 2-ethyl-1, the 3-hexylene glycol; 2,2-dimethyl-1,3-hexylene glycol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 3, the 5-ethohexadiol; 2,2-dimethyl-2,4-hexylene glycol; 2-methyl-3, the 5-heptanediol; And/or 3-methyl-3,5-heptanediol, wherein 2,2,4-trimethylammonium-1, the content of 3-pentanediol in any mixture all fewer than half, may also have because other a small amount of isomer that condensation forms on the 2-butanone methylene radical of (when it exists) rather than on methyl.
Some the not preferred C that lists among Table II-IV in described PCT specification sheets 6-8The property prepared of glycol and other character, for example smell, flowability, fusing point reduction etc. can improve by poly-alkoxylation.In addition, some oxyalkylated C 3-5Glycol is preferred.Above-mentioned C 3-8(in the following description, " EO " refers to polyethoxylated to the preferred alkoxylated derivative of glycol, and " En " refers to-(CH 2CH 2O) nH; The end capped polyethoxylated of Me-En nail base-(CH 2CH 2O) nCH 3" 2 (Me-En) " refers to 2 Me-En groups of needs; The poly-propoxylated glycerine of " PO " representative ,-(CH (CH 3) CH 2O) nH; " BO " refers to polytetramethylene oxygen base ,-(CH (CH 2CH 3) CH 2O) nH; Poly-(the positive inferior butoxy)-(CH of " n-BO " representative 2CH 2CH 2CH 2O) nH) comprising:
1. 1,2-propylene glycol (C3) 2 (Me-E 3-4); 1,2-propylene glycol (C3) PO 4The 2-methyl isophthalic acid, 2-propylene glycol (C4) (Me-E 8-10); The 2-methyl isophthalic acid, 2-propylene glycol (C4) 2 (Me-E 1); The 2-methyl isophthalic acid, 2-propylene glycol (C4) PO 31, ammediol (C3) 2 (Me-E 8); 1, ammediol (C3) PO 62,2-diethyl-1, ammediol (C7) E 4-72,2-diethyl-1, ammediol (C7) PO 12,2-diethyl-1, ammediol (C7) n-BO 22 (C5) 2 (Me E 1-2); 2 (C5) PO 42-(1-methyl-propyl)-1, ammediol (C7) E 4-72-(1-methyl-propyl)-1, ammediol (C7) PO 12-(1-methyl-propyl)-1, ammediol (C7) n-BO 22-(2-methyl-propyl)-1, ammediol (C7) E 4-72-(2-methyl-propyl)-1, ammediol (C7) PO 12-(2-methyl-propyl)-1, ammediol (C7) n-BO 22-ethyl-1, ammediol (C5) (Me E 9-10); 2-ethyl-1, ammediol (C5) 2 (Me E 1); 2-ethyl-1, ammediol (C5) PO 32-ethyl-2-methyl isophthalic acid, ammediol (C6) (Me E 3-6); 2-ethyl-2-methyl isophthalic acid, ammediol (C6) PO 22-ethyl-2-methyl isophthalic acid, ammediol (C6) BO 12-sec.-propyl-1, ammediol (C6) (Me E 3-6); 2-sec.-propyl-1, ammediol (C6) PO 22-sec.-propyl-1, ammediol (C6) BO 1The 2-methyl isophthalic acid, ammediol (C4) 2 (Me E 4-5); The 2-methyl isophthalic acid, ammediol (C4) PO 5The 2-methyl isophthalic acid, ammediol (C4) BO 22-methyl-2-sec.-propyl-1, ammediol (C7) E 6-92-methyl-2-sec.-propyl-1, ammediol (C7) PO 12-methyl-2-sec.-propyl-1, ammediol (C7) n-BO 2-32-methyl-2-propyl group-1, ammediol (C7) E 4-72-methyl-2-propyl group-1, ammediol (C7) PO 12-methyl-2-propyl group-1, ammediol (C7) n-BO 22-propyl group-1, ammediol (C6) (Me E 1-4); 2-propyl group-1, ammediol (C6) PO 2
2. 1,2-butyleneglycol (C4) (Me E 6-8); 1,2-butyleneglycol (C4) PO 2-31,2-butyleneglycol (C4) BO 12,3-dimethyl-1,2-butyleneglycol (C6) E 2-52,3-dimethyl-1,2-butyleneglycol (C6) n-BO 12-ethyl-1,2-butyleneglycol (C6) E 1-32-ethyl-1,2-butyleneglycol (C6) n-BO 1The 2-methyl isophthalic acid, 2-butyleneglycol (C5) (Me E 1-2); The 2-methyl isophthalic acid, 2-butyleneglycol (C5) PO 13,3-dimethyl-1,2-butyleneglycol (C6) E 2-53,3-dimethyl-1,2-butyleneglycol (C6) n-BO 1The 3-methyl isophthalic acid, 2-butyleneglycol (C5) (Me E 1-2); The 3-methyl isophthalic acid, 2-butyleneglycol (C5) PO 11,3 butylene glycol (C4) 2 (Me E 5-6); 1,3 butylene glycol (C4) BO 22,2,3-trimethylammonium-1,3 butylene glycol (C7) (Me E 1-3); 2,2,3-trimethylammonium-1,3 butylene glycol (C7) PO 22,2-dimethyl-1,3 butylene glycol (C6) (Me E 6-8); 2,2-dimethyl-1,3 butylene glycol (C6) PO 32,3-dimethyl-1,3 butylene glycol (C6) (Me E 6-8); 2,3-dimethyl-1,3 butylene glycol (C6) PO 32-ethyl-1,3 butylene glycol (C6) (Me E 4-6); 2-ethyl-1,3 butylene glycol (C6) PO 2-32-ethyl-1,3 butylene glycol (C6) BO 12-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) (Me E 1); 2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) PO 12-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) n-BO 32-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) (Me-E 1); 2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) PO 12-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) n-BO 32-sec.-propyl-1,3 butylene glycol (C7) (Me E 1); 2-sec.-propyl-1,3 butylene glycol (C7) PO 12-sec.-propyl-1,3 butylene glycol (C7) n-BO 3The 2-methyl isophthalic acid, 3-butyleneglycol (C5) 2 (Me E 2-3); The 2-methyl isophthalic acid, 3-butyleneglycol (C5) PO 42-propyl group-1,3 butylene glycol (C7) E 6-82-propyl group-1,3 butylene glycol (C7) PO 12-propyl group-1,3 butylene glycol (C7) n-BO 2-3The 3-methyl isophthalic acid, 3-butyleneglycol (C5) 2 (Me E 2-3); The 3-methyl isophthalic acid, 3-butyleneglycol (C5) PO 41,4-butyleneglycol (C4) 2 (Me E 3-4); 1,4-butyleneglycol (C4) PO 4-52,2,3-trimethylammonium-1,4-butyleneglycol (C7) E 6-92,2,3-trimethylammonium-1,4-butyleneglycol (C7) PO 12,2,3-trimethylammonium-1,4-butyleneglycol (C7) n-BO 2-32,2-dimethyl-1,4-butyleneglycol (C6) (Me E 3-6); 2,2-dimethyl-1,4-butyleneglycol (C6) PO 22,2-dimethyl-1,4-butyleneglycol (C6) BO 12,3-dimethyl-1,4-butyleneglycol (C6) (Me E 3-6); 2,3-dimethyl-1,4-butyleneglycol (C6) PO 22,3-dimethyl-1,4-butyleneglycol (C6) BO 12-ethyl-1,4-butyleneglycol (C6) (Me E 1-4); 2-ethyl-1,4-butyleneglycol (C6) PO 22-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) E 4-72-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) PO 12-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO 22-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) E 4-72-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) PO 12-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO 22-sec.-propyl-1,4-butyleneglycol (C7) E 4-72-sec.-propyl-1,4-butyleneglycol (C7) PO 1Different third methyl isophthalic acid of 2-, 4-butyleneglycol (C7) n-BO 2The 2-methyl isophthalic acid, 4-butyleneglycol (C5) (Me E 9-10); The 2-methyl isophthalic acid, 4-butyleneglycol (C5) 2 (Me E 1); The 2-methyl isophthalic acid, 4-butyleneglycol (C5) PO 32-propyl group-1,4-butyleneglycol (C7) E 2-52-propyl group-1,4-butyleneglycol (C7) n-BO 13-ethyl-1-methyl isophthalic acid, 4-butyleneglycol (C7) E 6-83-ethyl-1-methyl isophthalic acid, 4-butyleneglycol (C7) PO 13-ethyl-1-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO 2-32,3-butyleneglycol (C4) (Me E 9-10); 2,3-butyleneglycol (C4) 2 (Me E 1); 2,3-butyleneglycol (C4) PO 3-42,3-dimethyl-2,3-butyleneglycol (C6) E 7-92,3-dimethyl-2,3-butyleneglycol (C6) PO 12,3-dimethyl-2,3-butyleneglycol (C6) BO 2-32-methyl-2,3-butyleneglycol (C5) (Me E 2-5); 2-methyl-2,3-butyleneglycol (C5) PO 22-methyl-2,3-butyleneglycol (C5) BO 1
3. 1,2-pentanediol (C5) E 7-101,2-pentanediol (C5) PO 11,2-pentanediol (C5) n-BO 3The 2-methyl isophthalic acid, 2-pentanediol (C6) E 1-3The 2-methyl isophthalic acid, 2-pentanediol (C6) n-BO 1The 3-methyl isophthalic acid, 2-pentanediol (C6) E 1-3The 3-methyl isophthalic acid, 2-pentanediol (C6) n-B0 1The 4-methyl isophthalic acid, 2-pentanediol (C6) E 1-3The 4-methyl isophthalic acid, 2-pentanediol (C6) n-BO 11,3-pentanediol (C5) 2 (Me-E 1-2); 1,3-pentanediol (C5) PO 3-42,2-dimethyl-1,3-pentanediol (C7) (Me-E 1); 2,2-dimethyl-1,3-pentanediol (C7) PO 12,2-dimethyl-1,3-pentanediol (C7) n-BO 32,3-dimethyl-1,3-pentanediol (C7) (Me-E 1); 2,3-dimethyl-1,3-pentanediol (C7) PO 12,3-dimethyl-1,3-pentanediol (C7) n-BO 32,4-dimethyl-1,3-pentanediol (C7) (Me-E 1); 2,4-dimethyl-1,3-pentanediol (C7) PO 12,4-dimethyl-1,3-pentanediol (C7) n-BO 32-ethyl-1,3-pentanediol (C7) E 6-82-ethyl-1,3-pentanediol (C7) PO 12-ethyl-1,3-pentanediol (C7) n-BO 2-3The 2-methyl isophthalic acid, 3-pentanediol (C6) 2 (Me-E 4-6); The 2-methyl isophthalic acid, 3-pentanediol (C6) PO 2-33,4-dimethyl-1,3-pentanediol (C7) (Me-E 1); 3,4-dimethyl-1,3-pentanediol (C7) PO 13,4-dimethyl-1,3-pentanediol (C7) n-BO 3The 3-methyl isophthalic acid, 3-pentanediol (C6) 2 (Me-E 4-6); The 3-methyl isophthalic acid, 3-pentanediol (C6) PO 2-34,4-dimethyl-1,3-pentanediol (C7) (Me-E 1); 4,4-dimethyl-1,3-pentanediol (C7) PO 14,4-dimethyl-1,3-pentanediol (C7) n-BO 3The 4-methyl isophthalic acid, 3-pentanediol (C6) 2 (Me-E 4-6); The 4-methyl isophthalic acid, 3-pentanediol (C6) PO 2-31,4-pentanediol (C5) 2 (Me-E 1-2); 1,4-pentanediol (C5) PO 3-42,2-dimethyl-1,4-pentanediol (C7) (Me-E 1); 2,2-dimethyl-1,4-pentanediol (C7) PO 12,2-dimethyl-1,4-pentanediol (C7) n-BO 32,3-dimethyl-1,4-pentanediol (C7) (Me-E 1); 2,3-dimethyl-1,4-pentanediol (C7) PO 12,3-dimethyl-1,4-pentanediol (C7) n-BO 32,4-dimethyl-1,4-pentanediol (C7) (Me-E 1); 2,4-dimethyl-1,4-pentanediol (C7) PO 12,4-dimethyl-1,4-pentanediol (C7) n-BO 3The 2-methyl isophthalic acid, 4-pentanediol (C6) (Me-E 4-6); The 2-methyl isophthalic acid, 4-pentanediol (C6) PO 2-33,3-dimethyl-1,4-pentanediol (C7) (Me-E 1); 3,3-dimethyl-1,4-pentanediol (C7) PO 13,3-dimethyl-1,4-pentanediol (C7) n-BO 33,4-dimethyl-1,4-pentanediol (C7) (Me-E 1); 3,4-dimethyl-1,4-pentanediol (C7) PO 13,4-dimethyl-1,4-pentanediol (C7) n-BO 3The 3-methyl isophthalic acid, 4-pentanediol (C6) 2 (Me-E 4-6); The 3-methyl isophthalic acid, 4-pentanediol (C6) PO 2-3The 4-methyl isophthalic acid, 4-pentanediol (C6) 2 (Me-E 4-6); The 4-methyl isophthalic acid, 4-pentanediol (C6) PO 2-31,5-pentanediol (C5) (Me-E 8-10); 1,5-pentanediol (C5) 2 (Me-E 1); 1,5-pentanediol (C5) PO 32,2-dimethyl-1,5-pentanediol (C7) E 4-72,2-dimethyl-1,5-pentanediol (C7) PO 12,2-dimethyl-1,5-pentanediol (C7) n-BO 22,3-dimethyl-1,5-pentanediol (C7) E 4-72,3-dimethyl-1,5-pentanediol (C7) PO 12,3-dimethyl-1,5-pentanediol (C7) n-BO 22,4-dimethyl-1,5-pentanediol (C7) E 4-72,4-dimethyl-1,5-pentanediol (C7) PO 12,4-dimethyl-1,5-pentanediol (C7) n-BO 22-ethyl-1,5-pentanediol (C7) E 2-52-ethyl-1,5-pentanediol (C7) n-BO 1The 2-methyl isophthalic acid, 5-pentanediol (C6) (Me-E 1-4); The 2-methyl isophthalic acid, 5-pentanediol (C6) PO 23,3-dimethyl-1,5-pentanediol (C7) E 4-73,3-dimethyl-1,5-pentanediol (C7) PO 13,3-dimethyl-1,5-pentanediol (C7) n-BO 2The 3-methyl isophthalic acid, 5-pentanediol (C6) (Me-E 1-4); The 3-methyl isophthalic acid, 5-pentanediol (C6) PO 22,3-pentanediol (C5) (Me-E 1-3); 2,3-pentanediol (C5) PO 22-methyl-2,3-pentanediol (C6) E 4-72-methyl-2,3-pentanediol (C6) PO 12-methyl-2,3-pentanediol (C6) n-BO 23-methyl-2,3-pentanediol (C6) E 4-73-methyl-2,3-pentanediol (C6) PO 13-methyl-2,3-pentanediol (C6) n-BO 24-methyl-2,3-pentanediol (C6) E 4-74-methyl-2,3-pentanediol (C6) PO 14-methyl-2,3-pentanediol (C6) n-BO 22,4-pentanediol (C5) 2 (Me-E 2-4); 2,4-pentanediol (C5) PO 42,3-dimethyl-2,4-pentanediol (C7) (Me-E 2-4); 2,3-dimethyl-2,4-pentanediol (C7) PO 22,4-dimethyl-2,4-pentanediol (C7) (Me-E 2-4); 2,4-dimethyl-2,4-pentanediol (C7) PO 22-methyl-2,4-pentanediol (C7) (Me-E 8-10); 2-methyl-2,4-pentanediol (C7) PO 33,3-dimethyl-2,4-pentanediol (C7) (Me-E 2-4); 3,3-dimethyl-2,4-pentanediol (C7) PO 23-methyl-2,4-pentanediol (C6) (Me-E 8-10); 3-methyl-2,4-pentanediol (C6) PO 3
4. 1,3-hexylene glycol (C6) (Me-E 2-5); 1,3-hexylene glycol (C6) PO 21,3-hexylene glycol (C6) BO 1The 2-methyl isophthalic acid, 3-hexylene glycol (C7) E 6-8The 2-methyl isophthalic acid, 3-hexylene glycol (C7) PO 1The 2-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO 2-3The 3-methyl isophthalic acid, 3-hexylene glycol (C7) E 6-8The 3-methyl isophthalic acid, 3-hexylene glycol (C7) PO 1The 3-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO 2-3The 4-methyl isophthalic acid, 3-hexylene glycol (C7) E 6-8The 4-methyl isophthalic acid, 3-hexylene glycol (C7) PO 1The 4-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO 2-3The 5-methyl isophthalic acid, 3-hexylene glycol (C7) E 6-8The 5-methyl isophthalic acid, 3-hexylene glycol (C7) PO 1The 5-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO 2-31,4-hexylene glycol (C6) (Me-E 2-5); 1,4-hexylene glycol (C6) PO 21,4-hexylene glycol (C6) BO 1The 2-methyl isophthalic acid, 4-hexylene glycol (C7) E 6-8The 2-methyl isophthalic acid, 4-hexylene glycol (C7) PO 1The 2-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO 2-3The 3-methyl isophthalic acid, 4-hexylene glycol (C7) E 6-8The 3-methyl isophthalic acid, 4-hexylene glycol (C7) PO 1The 3-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO 2-3The 4-methyl isophthalic acid, 4-hexylene glycol (C7) E 6-8The 4-methyl isophthalic acid, 4-hexylene glycol (C7) PO 1The 4-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO 2-3The 5-methyl isophthalic acid, 4-hexylene glycol (C7) E 6-8The 5-methyl isophthalic acid, 4-hexylene glycol (C7) PO 1The 5-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO 2-31,5-hexylene glycol (C6) (Me-E 2-5); 1,5-hexylene glycol (C6) PO 21,5-hexylene glycol (C6) BO 1The 2-methyl isophthalic acid, 5-hexylene glycol (C7) E 6-8The 2-methyl isophthalic acid, 5-hexylene glycol (C7) PO 1The 2-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO 2-3The 3-methyl isophthalic acid, 5-hexylene glycol (C7) E 6-8The 3-methyl isophthalic acid, 5-hexylene glycol (C7) PO 1The 3-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO 2-3The 4-methyl isophthalic acid, 5-hexylene glycol (C7) E 6-8The 4-methyl isophthalic acid, 5-hexylene glycol (C7) PO 1The 4-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO 2-3The 5-methyl isophthalic acid, 5-hexylene glycol (C7) E 6-8The 5-methyl isophthalic acid, 5-hexylene glycol (C7) PO 1The 5-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO 2-31,6-hexylene glycol (C6) (Me-E 1-2); 1,6-hexylene glycol (C6) PO 1-21,6-hexylene glycol (C6) n-BO 4The 2-methyl isophthalic acid, 6-hexylene glycol (C7) E 2-5The 2-methyl isophthalic acid, 6-hexylene glycol (C7) n-BO 1The 3-methyl isophthalic acid, 6-hexylene glycol (C7) E 2-5The 3-methyl isophthalic acid, 6-hexylene glycol (C7) n-BO 12,3-hexylene glycol (C6) E 2-52,3-hexylene glycol (C6) n-BO 12,4-hexylene glycol (C6) (Me-E 5-8); 2,4-hexylene glycol (C6) PO 32-methyl-2,4-hexylene glycol (C7) (Me E 1-2); 2-methyl-2,4-hexylene glycol (C7) PO 1-23-methyl-2,4-hexylene glycol (C7) (Me-E 1-2); 3-methyl-2,4-hexylene glycol (C7) PO 1-24-methyl-2,4-hexylene glycol (C7) (Me-E 1-2); 4-methyl-2,4-hexylene glycol (C7) PO 1-25-methyl-2,4-hexylene glycol (C7) (Me-E 1-2); 5-methyl-2,4-hexylene glycol (C7) PO 1-22,5-hexylene glycol (C6) (Me-E 5-8); 2,5-hexylene glycol (C6) PO 32-methyl-2,5-hexylene glycol (C7) (Me-E 1-2); 2-methyl-2,5-hexylene glycol (C7) PO 1-23-methyl-2,5-hexylene glycol (C7) (Me-E 1-2); 3-methyl-2,5-hexylene glycol (C7) PO 1-23,4-hexylene glycol (C6) E 2-53,4-hexylene glycol (C6) n-BO 1
5. 1,3-heptanediol (C7) E 3-61,3-heptanediol (C7) PO 11,3-heptanediol (C7) n-BO 21,4-heptanediol (C7) E 3-61,4-heptanediol (C7) PO 11,4-heptanediol (C7) n-BO 21,5-heptanediol (C7) E 3-61,5-heptanediol (C7) PO 11,5-heptanediol (C7) n-BO 21,6-heptanediol (C7) E 3-61,6-heptanediol (C7) PO 11,6-heptanediol (C7) n-BO 21,7-heptanediol (C7) E 1-21,7-heptanediol (C7) n-BO 12,4-heptanediol (C7) E 7-102,4-heptanediol (C7) (Me-E 1); 2,4-heptanediol (C7) PO 12,4-heptanediol (C7) n-BO 32,5-heptanediol (C7) E 7-102,5-heptanediol (C7) (Me-E 1); 2,5-heptanediol (C7) PO 12,5-heptanediol (C7) n-BO 32,6-heptanediol (C7) E 7-102,6-heptanediol (C7) (Me-E 1); 2,6-heptanediol (C7) PO 12,6-heptanediol (C7) n-BO 33,5-heptanediol (C7) E 7-103,5-heptanediol (C7) (Me-E 1); 3,5-heptanediol (C7) PO 13,5-heptanediol (C7) n-BO 3
6. 3-methyl-2-sec.-propyl-1,3 butylene glycol (C8) PO 12,3,3-trimethylammonium-2,4-pentanediol (C8) PO 12,2-diethyl-1,3 butylene glycol (C8) E 2-52,3-dimethyl-2,4-hexylene glycol (C8) E 2-52,4-dimethyl-2,4-hexylene glycol (C8) E 2-52,5-dimethyl-2,4-hexylene glycol (C8) E 2-53,3-dimethyl-2,4-hexylene glycol (C8) E 2-53,4-dimethyl-2,4-hexylene glycol (C8) E 2-53,5-dimethyl-2,4-hexylene glycol (C8) E 2-54,5-dimethyl-2,4-hexylene glycol (C8) E 2-55,5-dimethyl-2,4-hexylene glycol (C8) E 2-52,3-dimethyl-2,5-hexylene glycol (C8) E 2-52,4-dimethyl-2,5-hexylene glycol (C8) E 2-52,5-dimethyl-2,5-hexylene glycol (C8) E 2-53,3-dimethyl-2,5-hexylene glycol (C8) E 2-53,4-dimethyl-2,5-hexylene glycol (C8) E 2-53-methyl-3,5-heptanediol (C8) E 2-52,2-diethyl-1,3 butylene glycol (C8) n-BO 1-22,3-dimethyl-2,4-hexylene glycol (C8) n-BO 1-22,4-dimethyl-2,4-hexylene glycol (C8) n-BO 1-22,5-dimethyl-2,4-hexylene glycol (C8) n-BO 1-23,3-dimethyl-2,4-hexylene glycol (C8) n-BO 1-23,4-dimethyl-2,4-hexylene glycol (C8) n-BO 1-23,5-dimethyl-2,4-hexylene glycol (C8) n-BO 1-24,5-dimethyl-2,4-hexylene glycol (C8) n-BO 1-25,5-dimethyl-2,4-hexylene glycol n-BO 1-22,3-dimethyl-2,5-hexylene glycol (C8) n-BO 1-22,4-dimethyl-2,5-hexylene glycol (C8) n-BO 1-22,5-dimethyl-2,5-hexylene glycol (C8) n-BO 1-23,3-dimethyl-2,5-hexylene glycol (C8) n-BO 1-23,4-dimethyl-2,5-hexylene glycol (C8) n-BO 1-23-methyl-3,5-heptanediol (C8) n-BO 1-22-(1, the 2-dimethyl propyl)-1, ammediol (C8) n-BO 1-22-ethyl-2,3-dimethyl-1,3 butylene glycol (C8) n-BO 12-methyl-2-sec.-propyl-1,3 butylene glycol (C8) n-BO 13-methyl-2-sec.-propyl-1,4-butyleneglycol (C8) n-BO 12,2,3-trimethylammonium-1,3-pentanediol (C8) n-BO 12,2,4-trimethylammonium-1,3-pentanediol (C8) n-BO 12,4,4-trimethylammonium-1,3-pentanediol (C8) n-BO 13,4,4-trimethylammonium-1,3-pentanediol (C8) n-BO 12,2,3-trimethylammonium-1,4-pentanediol (C8) n-BO 12,2,4-trimethylammonium-1,4-pentanediol (C8) n-BO 12,3,3-trimethylammonium-1,4-pentanediol (C8) n-BO 12,3,4-trimethylammonium-1,4-pentanediol (C8) n-BO 13,3,4-trimethylammonium-1,4-pentanediol (C8) n-BO 12,3,4-trimethylammonium-2,4-pentanediol (C8) n-BO 14-ethyl-2,4-hexylene glycol (C8) n-BO 12-methyl-2,4-heptanediol (C8) n-BO 13-methyl-2,4-heptanediol (C8) n-BO 14-methyl-2,4-heptanediol (C8) n-BO 15-methyl-2,4-heptanediol (C8) n-BO 16-methyl-2,4-heptanediol (C8) n-BO 12-methyl-2,5-heptanediol (C8) n-BO 13-methyl-2,5-heptanediol (C8) n-BO 14-methyl-2,5-heptanediol (C8) n-BO 15-methyl-2,5-heptanediol (C8) n-BO 16-methyl-2,5-heptanediol (C8) n-BO 12-methyl-2,6-heptanediol (C8) n-BO 13-methyl-2,6-heptanediol (C8) n-BO 14-methyl-2,6-heptanediol (C8) n-BO 12-methyl-3,5-heptanediol (C8) n-BO 12-(1, the 2-dimethyl propyl)-1, ammediol (C8) E 1-32-ethyl-2,3-dimethyl-1,3 butylene glycol (C8) E 1-32-methyl-2-sec.-propyl-1,3 butylene glycol (C8) E 1-33-methyl-2-sec.-propyl-1,4-butyleneglycol (C8) E 1-32,2,3-trimethylammonium-1,3-pentanediol (C8) E 1-32,2,4-trimethylammonium-1,3-pentanediol (C8) E 1-32,4,4-trimethylammonium-1,3-pentanediol (C8) E 1-33,4,4-trimethylammonium-1,3-pentanediol (C8) E 1-32,2,3-trimethylammonium-1,4-pentanediol (C8) E 1-32,2,4-trimethylammonium-1,4-pentanediol (C8) E 1-32,3,3-trimethylammonium-1,4-pentanediol (C8) E 1-32,3,4-trimethylammonium-1,4-pentanediol (C8) E 1-33,3,4-trimethylammonium-1,4-pentanediol (C8) E 1-32,3,4-trimethylammonium-2,4-pentanediol (C8) E 1-34-ethyl-2,4-hexylene glycol (C8) E 1-32-methyl-2,4-heptanediol (C8) E 1-33-methyl-2,4-heptanediol (C8) E 1-34-methyl-2,4-heptanediol (C8) E 1-35-methyl-2,4-heptanediol (C8) E 1-36-methyl-2,4-heptanediol (C8) E 1-32-methyl-2,5-heptanediol (C8) E 1-33-methyl-2,5-heptanediol (C8) E 1-34-methyl-2,5-heptanediol (C8) E 1-35-methyl-2,5-heptanediol (C8) E 1-36-methyl-2,5-heptanediol (C8) E 1-32-methyl-2,6-heptanediol (C8) E 1-33-methyl-2,6-heptanediol (C8) E 1-34-methyl-2,6-heptanediol (C8) E 1-3And/or 2-methyl-3,5-heptanediol (C8) E 1-3And
7. their mixture.
In the nonane isomer, have only 2,3,3,4-tetramethyl--2, the 4-pentanediol is highly preferred.
Except the aliphatic diol main solvent and their some alkoxy derivative above and hereinafter discussed, also find some special glycol ethers be suitable for preparing liquid state of the present invention, concentrate, the main solvent of transparent fabric softener composition.Similar to the aliphatic diol main solvent, find that the suitability of various main solvents has selectivity, depend on the carbon atom number in for example concrete glycol ethers molecule.For example, as providing in the Table VI, be C for R wherein 2-C 8The chemical formula of alkyl is HOCH 2-CHOH-CH 2The glyceryl ether series of-O-R, having only chemical formula is HOCH 2-CHOH-CH 2-O-C 5H 11(C wherein 5H 11Comprise different amyl group isomer) the ClogP value of single amyl ether (3-pentyloxy-1,2-propylene glycol) be in the preferred ClogP scope of about 0.25-0.62, and be suitable for preparing the fabric softener of spissated liquid clear of the present invention.Find that also cyclohexyl derivatives is suitable for, but cyclopentyl derivates is then denied.Similarly, when selecting Arylglycerine ether, demonstrate selectivity.In a lot of possible aromatic groups, have only the phenol derivatives of minority to be suitable for.
Also find same narrow selectivity for two (hydroxyalkyl) ether.Find that two (2-hydroxybutyl) ether is suitable for, but two (2-hydroxyl amyl ethers) are then denied.For two (ring hydroxyalkyl) analogue, two (2-hydroxycyclopent base) ether is suitable for, but two (2-hydroxy-cyclohexyl) ether is inapplicable.Hereinafter provided limiting examples about the synthetic method for preparing some preferred two (hydroxyalkyl) ether.
Butyl list glyceryl ether (being also referred to as 3-butoxy-1, the 2-propylene glycol) not too is fit to form the fabric softener of spissated liquid clear of the present invention.But, its polyethoxylated derivative, preferably about triethoxyization more preferably from five ethoxylation to eight ethoxylations, is suitable main solvent to about nine ethoxylations.
All preferred alkyl glycerylether and/or two (hydroxyalkyl) ethers have been identified in described PCT specification sheets, most preferably: 3-(n-pentyloxy)-1,2-propylene glycol; 3-(2-pentyloxy)-1,2 propylene glycol; 3-(3-pentyloxy)-1, the 2-propylene glycol; 3-(2-methyl-1-butene oxygen base)-1, the 2-propylene glycol; 3-(isopentyloxy)-1, the 2-propylene glycol; 3-(3-methyl-2-butoxy)-1, the 2-propylene glycol; 3-(cyclohexyloxy)-1, the 2-propylene glycol; 3-(1-hexamethylene-1-alkene oxygen base)-1, the 2-propylene glycol; 2-(pentyloxy)-1, ammediol; 2-(2-pentyloxy)-1, ammediol; 2-(3-pentyloxy)-1, ammediol; 2-(2-methyl-1-butene oxygen base)-1, ammediol; 2-(isopentyloxy)-1, ammediol; 2-(3-methyl-2-butoxy)-1, ammediol; 2-(cyclohexyloxy)-1, ammediol; 2-(1-hexamethylene-1-alkene oxygen base)-1, ammediol; 3-(butoxy)-1,2-propylene glycol five ethoxylates; 3-(butoxy)-1,2-propylene glycol six ethoxylates; 3-(butoxy)-1,2-propylene glycol seven ethoxylates; 3-(butoxy)-1,2-propylene glycol eight ethoxylates; 3-(butoxy)-1,2-propylene glycol nine ethoxylates; 3-(butoxy)-1,2-propylene glycol one propoxylated glycerine; 3-(butoxy)-1,2-propylene glycol dibutoxy thing; And/or 3-(butoxy)-1,2-propylene glycol three butoxy things.Preferred aromatics glyceryl ether comprises: 3-phenoxy group-1,2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 2-(a hydroxy toluene oxygen base)-1,2-propylene glycol and-1, ammediol; 2-(to hydroxy toluene oxygen base)-1, ammediol; 2-benzyloxy-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; And their mixture.Preferred aromatics glyceryl ether comprises: 3-phenoxy group-1,2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 2-(a hydroxy toluene oxygen base)-1,2-propylene glycol and-1, ammediol; 2-(to hydroxy toluene oxygen base)-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; And their mixture.Most preferred two (hydroxyalkyl) ether comprises: two (2-hydroxyl butyl) ether and two (2-hydroxycyclopent base) ether;
The non-restrictive example for preparing the synthetic method of preferred alkyl and aryl list glyceryl ether is disclosed in the described PCT specification sheets.
Preferred alicyclic diol and derivative thereof comprise: glycol that (1) is saturated and derivative thereof comprise: 1-sec.-propyl-1,2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 2,4,5-trimethylammonium-1,3-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxyl hexanaphthene ethanol; 1-hydroxyl cyclohexane methanol; 1-ethyl-1, the 3-cyclohexanediol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1, the 3-cyclohexanediol; 2-hydroxyl hexanaphthene ethanol; 2-hydroxyethyl-1-hexalin; 2-methylol hexalin; 3-hydroxyethyl-1-hexalin; 3-hydroxyl hexanaphthene ethanol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; 4-methylol hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1, the 3-cyclohexanediol; 1,2-encircles heptanediol; The 2-methyl isophthalic acid, 3-encircles heptanediol; The 2-methyl isophthalic acid, 4-encircles heptanediol; The 4-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 4-encircles heptanediol; The 6-methyl isophthalic acid, 4-encircles heptanediol; 1,3-encircles ethohexadiol; 1,4-encircles ethohexadiol; 1,5-encircles ethohexadiol; 1,2-cyclohexanediol, diethoxy thing; 1,2-cyclohexanediol, triethoxy thing; 1,2-cyclohexanediol, tetraethoxy thing; 1,2-cyclohexanediol, five ethoxylates; 1,2-cyclohexanediol, six ethoxylates; 1,2-cyclohexanediol, seven ethoxylates; 1,2-cyclohexanediol, eight ethoxylates; 1,2-cyclohexanediol, nine ethoxylates; 1,2-cyclohexanediol, a propoxylated glycerine; 1,2-cyclohexanediol, a butoxy thing; 1,2-cyclohexanediol, dibutoxy thing; And/or 1,2-cyclohexanediol, three butoxy things.Most preferred radical of saturated aliphatic glycol and derivative thereof are: 1-sec.-propyl-1,2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1-hydroxyl cyclohexane methanol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; 4-methylol hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 1,2-encircles heptanediol; 1,2-cyclohexanediol, five ethoxylates; 1,2-cyclohexanediol, six ethoxylates; 1,2-cyclohexanediol, seven ethoxylates; 1,2-cyclohexanediol, eight ethoxylates; 1,2-cyclohexanediol, nine ethoxylates; 1,2-cyclohexanediol, a propoxylated glycerine; And/or 1,2-cyclohexanediol, dibutoxy thing.
Optional aromatic diol comprises: 1-phenyl-1; 1-phenyl-1, the 2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; 1-phenyl-1,3 butylene glycol; 3-phenyl-1,3 butylene glycol; And/or 1-phenyl-1, the 4-butyleneglycol, wherein most preferably: 1-phenyl-1,2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; And/or 1-phenyl-1, the 4-butyleneglycol.
As previously mentioned, all are relevant with other preferred main solvent according to identical relation,, Duo a CH than corresponding saturated main solvent that is 2Those materials that the unsaturated materials of group and ClogP remain in the useful range are preferred.But concrete preferred unsaturated diol main solvent is: 2, and 2-diallyl-1,3 butylene glycol; 2-(1-ethyl-1-propenyl)-1,3 butylene glycol; 2-(crotyl)-2-methyl isophthalic acid, the 3-butyleneglycol; 2-(3-methyl-2-butene base)-1,3 butylene glycol; 2-ethyl-2-(2-propenyl)-1,3 butylene glycol; 2-methyl-2-(1-methyl-2-propenyl)-1,3 butylene glycol; 2,3-two (1-methyl ethylidene)-1,4-butyleneglycol; 2-vinyl-3-ethyl-1, the 3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1, the 4-pentanediol; 2-(1, the 1-dimethyl ethyl)-4-amylene-1, the 3-glycol; 2-ethyl-2,3-dimethyl-4-amylene-1,3-glycol; 4-ethyl-2-methylene radical-1, the 4-hexylene glycol; 2,3,5-trimethylammonium-1,5-hexadiene-3,4-glycol; 2-(1-methyl ethylene)-1, the 5-hexylene glycol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-glycol; 6-methyl-5-methylene radical-1, the 4-heptanediol; 4,6-dimethyl-2,4-heptadiene-2,6-glycol; 2,5,5-trimethylammonium-2,6-heptadiene-1,4-glycol; 5,6-dimethyl-2-heptene-1,4-glycol; 4,6-dimethyl-3-heptene-1,5-glycol; 2,4-dimethyl-5-heptene-1,3-glycol; 3,6-dimethyl-5-heptene-1,3-glycol; 2,6-dimethyl-5-heptene-1,4-glycol; 3,6-dimethyl-5-heptene-1,4-glycol; 2,2-dimethyl-6-heptene-1,3-glycol; 5,6-dimethyl-6-heptene-1,4-glycol; 2,4-dimethyl-6-heptene-1,5-glycol; 2-ethylidene-6-methyl-6-heptene-1, the 5-glycol; 4-(2-propenyl)-6-heptene-2, the 4--glycol; 3-vinyl-1-octene-3, the 6-glycol; 2,7-dimethyl-2,4,6-sarohornene-1,8-glycol; 2,6-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,6-octadiene-1,4-glycol (Rosiridol); 2-methyl-2,6-octadiene-1,8-glycol; 3,7-dimethyl-2,7-octadiene-1,4-glycol; 2,6-dimethyl-2,7-octadiene-1,5-glycol; 2,6-dimethyl-2,7-octadiene-1,6-glycol (8-hydroxyl phantol); 2,7-dimethyl-2,7-octadiene-1,6-glycol; 2-methyl-6-methylene radical-2-octene-1, the 7-glycol; 2,7-dimethyl-3,5-octadiene-2,7-glycol; 4-methylene radical-3, the 5-ethohexadiol; 2,6-dimethyl-3,7-octadiene-1,6-glycol; 2-methylene radical-4-octene-1, the 8-glycol; 2-methyl-6-octene-3, the 5-glycol; 4-methyl-6-octene-3, the 5-glycol; 2-methyl-6-methylene radical-7-octene-2, the 4-glycol; 7-methyl-7-octene-2, the 5-glycol; 2-methyl-7-octene-3, the 5-glycol; 1-nonene-3, the 5-glycol; 1-nonene-3, the 7-glycol; 3-nonene-2, the 5-glycol; 4-nonene-2, the 8-glycol; 6,8-nonadiene-1,5-glycol; 7-nonene-2, the 4-glycol; 8-nonene-2, the 4-glycol; 8-nonene-2, the 5-glycol; 1,9-decadiene-3,8-glycol; And/or 1,9-decadiene-4,6-glycol.
Described alcohols main solvent also can preferably be selected from: 2, and 5-dimethyl-2,5-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 2-methyl-2-propyl group-1, ammediol; 1, the 2-hexylene glycol; And their mixture.Preferred described alcohols main solvent then is selected from: 2-ethyl-1,3-hexylene glycol, 2-methyl-2-propyl group-1, ammediol, 1,2-hexylene glycol and their mixture.Even more preferably described alcohols main solvent is to be selected from 2-ethyl-1,3-hexylene glycol, 1,2-hexylene glycol and composition thereof.
When several derivatives of the same glycol with different alkylene oxide group are available, 3-5 oxyethylene group group or 2 oxypropylene groups are for example arranged, or the 2-methyl-2 of an oxygen butylene group, the 3-butyleneglycol, the preferred derivative that uses the group minimum number, that is, use derivative in the case with an oxygen butylene group.But when only needing about 1-4 oxyethylene group group that the good property prepared is provided, this analog derivative also is preferred.
Undersaturated glycol
Be surprisingly found out that between the acceptability (property prepared) of the unsaturated homologue of saturated dibasic alcohol and its higher molecular weight or analogue tangible similarity is arranged.Undersaturated main solvent all adds a methylene radical in addition for each two key in its chemical formula (be CH 2) condition under, then undersaturated homologue/analogue has and the identical property prepared of the saturated main solvent of parent.In other words, have one tangible " adding normally ", that is, preparation is transparent for being fit to, each good saturated main solvent of the present invention of concentrated fabric soft compound, all has suitable undersaturated main solvent, wherein adds one or more CH 2Group, and for added each CH 2Group, all the adjacent carbons from molecule is removed two hydrogen atoms forming carbon-to-carbon double bond, thereby makes hydrogen atom sum in the molecule keep constant with respect to the chemical formula of " parent " saturated main solvent.This is because a wonderful fact promptly, adds one-CH in the solvent chemical formula 2-group has makes its ClogP value increase by about 0.53 effect, remove two adjacent hydrogen atoms with form two keys then make the about appropriate number of ClogP value minimizing (that is) effect, about 0.48, thus roughly compensated-CH 2-adding.Therefore, by each CH for increase 2Group inserts two keys to keep the hydrogen atom sum identical with the saturated main solvent of parent, preferred saturated main solvent has become at least saturated analogues/homologues that contain the preferred higher molecular weight of a carbon atom more, as long as the ClogP value of novel solvent remains in the 0.15-0.64 scope of virtual value, preferred about 0.25-0.62, more preferably from about 0.40-0.60.Below be some illustrative example:
2,2-dimethyl-6-heptene-1,3-glycol (CAS No.140192-39-8) is preferred C9-glycols main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol or 2,2-dimethyl-1,3-hexylene glycol.
2,4-dimethyl-5-heptene-1,3-glycol (CAS No.123363-69-9) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol or 2,4-dimethyl-1,3-hexylene glycol.
2-(1-ethyl-1-propenyl)-1,3 butylene glycol (CAS No.116103-35-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 2-(1-ethyl propyl)-1, ammediol or 2-(1-methyl-propyl)-1,3 butylene glycol.
2-vinyl-3-ethyl-1,3-pentanediol (CAS No.104683-37-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 3-ethyl-2-methyl isophthalic acid, 3-pentanediol or 2-ethyl-3-methyl isophthalic acid, 3-pentanediol.
3,6-dimethyl-5-heptene-1,4-glycol (as CAS No.106777-99-5) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 3-methyl isophthalic acid, 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; Or 3,5-dimethyl-1,4-hexylene glycol.
5,6-dimethyl-6-heptene-1,4-glycol (as CAS No.152344-16-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 5-methyl isophthalic acid, 1-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; Or 4,5-dimethyl-1,3-hexylene glycol.
4-methyl-6-octene-3,5-glycol (CAS No.156414-25-4) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent 2Group and one two keys are derived and are formed: 3, and the 5-ethohexadiol; 3-methyl-2,4-heptanediol or 4-methyl-3,5-heptanediol.
Rosiridol (CAS No.101391-01-9) and isorosiridol (CAS No.149252-15-3) are 3,7-dimethyl-2,6-octadiene-1, two kinds of isomer of 4-glycol, and be preferred C10-glycol main solvent, they can be thought by suitably add two CH in any following preferred C8-glycol main solvent 2Group and two two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; 2,5-dimethyl-1,3-hexylene glycol; Or 3,5-dimethyl-1,4-hexylene glycol.
8-hydroxyl phantol (CAS No.103619-06-3,2,6-dimethyl-2,7-octadiene-1,6-glycol) is preferred C10-glycol main solvent, can think by suitably add two CH in any following preferred C8-glycol main solvent 2Group and two two keys are derived and are formed: 2-methyl isophthalic acid, 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; Or 2,4-dimethyl-1,4-hexylene glycol.
2,7-dimethyl-3,7-octadiene-2,5-glycol (CAS No.171436-39-8) is preferred C10-glycol main solvent, can think by suitably adding two CH to any following preferred C8-glycol main solvent 2Group and two two keys are derived and are formed: 2, and the 5-ethohexadiol; The 6-methyl isophthalic acid, the 4-heptanediol; 2-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; With 2,5-dimethyl-2,4-hexylene glycol.
4-butyl-2-butylene-1,4-glycol (CAS No.153943-66-9) is preferred C8-glycol main solvent, can think by suitably adding a CH to any following preferred C7-glycol main solvent 2Group and one two keys are derived and are formed: 2-propyl group-1,4-butyleneglycol or 2-butyl-1, ammediol.
Based on same reason, a lot of situations itself are the solvents that differs from by the derive unsaturated homologue of the higher molecular weight that forms of poor, inapplicable saturated solvent.For example, 3,5-dimethyl-5-hexene-2,4-glycol (for example CAS No.160429-40-3) they are the unsaturated C8 solvents of difference, can think to form by deriving with the saturated C7 solvent of allowance below nominal size: 3-methyl-2,4-hexylene glycol; 5-methyl-2, the 4-hexylene glycol; Or 2,4-dimethyl-1,3-pentanediol; And 2,6-dimethyl-5-heptene-1,2-glycol (for example CAS No.141505-71-7) they are the unsaturated C9 solvents of difference, can think to form by deriving with the saturated C8 solvent of allowance below nominal size: 2-methyl isophthalic acid, 2-heptanediol; The 6-methyl isophthalic acid, the 2-heptanediol; Or 2,5-dimethyl-1,2-hexylene glycol.
More than about saturated main solvent always have identical acceptable degree unsaturated analogue/homologue add normally in an exception is arranged.This exception relates to the saturated glycol main solvent that two hydroxyls are arranged on two adjacent carbon atoms.In some cases, between two adjacent hydroxyls of poor solvent, insert one or more CH 2Group forms the saturated homologue of higher molecular weight, and it is more suitable in transparent concentrated fabric softener preparation, but such was the case with.For example, do not have the preferred unsaturated 6 of adjacent hydroxyl, 6-dimethyl-1-teracrylic acid, 5-glycol (CAS No.109788-01-4) can think by having the inapplicable 2 of adjacent hydroxyl, and 2-dimethyl-3,4-hexylene glycol are derived and formed.In this case, think 6,6-dimethyl-1-teracrylic acid, 5-glycol are by 2-methyl-3, and it is more credible that 5-heptanediol or 5,5-dimethyl-2,4-hexylene glycol are derived and formed, and these two kinds of alcohol all are preferred main solvents, and do not have adjacent hydroxyl.Otherwise, between the adjacent hydroxyl of preferred main solvent, insert CH 2Group can form the unsaturated diol solvent of inapplicable higher molecular weight.For example, do not have the inapplicable unsaturated 2 of adjacent hydroxyl, 4-dimethyl-5-hexene-2,4-glycol (CAS No.87604-24-8) can think by having the preferred 2 of adjacent hydroxyl, and 3-dimethyl-2,3-pentanediol are derived and formed.In this case, more believable is by 2-methyl-2,4-hexylene glycol or 4-methyl-2,4-hexylene glycol derive form inapplicable undersaturated 2,4-dimethyl-5-hexene-2, the 4-glycol, these two kinds of alcohol are inapplicable solvent and do not have adjacent hydroxyl.Also have some situations, do not have the inapplicable unsaturated solvent of adjacent hydroxyl can think to derive and form by inapplicable solvent with adjacent hydroxyl, for example 4,5-dimethyl-6-hexene-1,3-two is pure and mild 3,4-dimethyl-1, this is a pair of for the 2-pentanediol.Therefore, in order to infer the property prepared of the unsaturated solvent that does not have adjacent hydroxyl, should set out by the saturated homologue of the lower molecular weight that does not have adjacent hydroxyl equally.That is, in general, when two hydroxyls distance/when relation was kept, above-mentioned relation was more reliable.That is, reliably the practice is the property prepared that goes out to send the unsaturated homologue of the higher molecular weight that deduction also has adjacent hydroxyl from the saturated solvent with adjacent hydroxyl.
Have been found that, when fabric softener active matter has described IV and suitable/trans ratios, use these special alcohols main solvents can be under astonishing low main solvent content, promptly, about 40% less than composition weight makes transparent, low viscosity, stable fabric softener composition.Find that also use this alcohols main solvent can make highly spissated fabric softener composition, they are stable, and for example can dilute from about 2: 1 to about 10: 1, and still stablize with the composition of formation low levels fabric softener.
Preferably main solvent content is remained on to making the present composition reach the translucent or transparent minimum level that can realize.The existence of water is for for reaching the transparent required main solvent of these compositions material impact being arranged.Water-content is high more, and is high more for realizing the transparent required main solvent content of product (with respect to softening agent content).Otherwise water-content is few more, and the main solvent (with respect to softening agent) that needs is few more.For example, under the low water content of about 5%-15%, the weight ratio of softening agent actives and main solvent is about 55: 45 to about 85: 15, more preferably from about 60: 40 to about 80: 20.Under the water-content of about 15%-70%, the weight ratio of softening agent actives and main solvent is preferably about 45: 55 to about 70: 30, more preferably from about 55: 45 to about 70: 30.But under the high water content of about 70%-80%, the softening agent actives is preferably about 30: 70 to about 55: 45 with the weight of solvent ratio, more preferably from about 35: 65 to about 45: 55.In the water yield even when higher, the ratio of softening agent/main solvent also should in addition higher.
The mixture of above main solvent is particularly preferred, because one of problem relevant with a large amount of solvents is security.Mixture has reduced the quantity of the material of any existence.Smell and combustibility also can reduce by using mixture, and especially when one of main solvent was volatility and/or scent of, this was likely for low molecular weight substance.Can have being not enough to form the suitable solvent that uses under the content of opaque products: 2,2,4-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1, the ethoxylate of 3-pentanediol, diethoxy thing or triethoxy compound derivative; With and/or 2-ethyl-1, the 3-hexylene glycol.Main solvent is above to have confirmed as most preferred one or more solvents in the preferred mixture.It also is desirable using solvent mixture, and especially when in the preferred main solvent one or more at room temperature were solid, in this situation, mixture can be made into fluid, or has lower fusing point, thereby has improved the workability of softener composition.
Can replace a part of main solvent of the present invention or main solvent mixture with second solvent or second solvent mixture that itself are not suitable as main solvent use of the present invention, as long as the main solvent that in the fabric softener composition of spissated liquid clear, still exists the present invention of effective quantity to be suitable for.Under the situation that at least also has about 15% softening agent actives, effective quantity of main solvent of the present invention, about 5% greater than composition at least, be preferably greater than about 7%, more preferably greater than about 10%.Substituting solvent can use with any content, but preferably is substantially equal to or is less than the quantity of the main solvent that is suitable for of the above-mentioned definition that exists in fabric softener composition.
For example, according to the present invention, though 1,2-pentanediol, 1, the following hydroxypivalyl hydroxypivalate (claiming HPHP later on) of 3-ethohexadiol and chemical formula is inapplicable solvent:
HO-CH 2-C (CH 3) 2-CH 2-O-CO-C (CH 3) 2-CH 2-OH (CAS # 1115-20-4) but these solvents and main solvent, for example preferred 1, the mixture of 2-hexylene glycol main solvent, wherein 1, the content of 2-hexylene glycol main solvent also forms spissated transparent liquid fabric softener composition when useful range.
Spendable some second kind of solvent is above and those solvents of hereinafter listing as inapplicable solvent, and some not oxyalkylated parent solvent of listing among the Table VIII A-VIIIE in described PCT specification sheets.
Can use main solvent that composition is translucent or transparent, perhaps become temperature when translucent or transparent in order to reduce composition.Therefore, the present invention also comprises to not being translucent or transparent or the method for aforementioned content main solvent taking place in the too high composition of instable temperature to add, so that it is translucent or transparent that composition is become, perhaps when composition under envrionment temperature for example or reduce under certain specified temp when being transparent, the temperature that unstable takes place reduces, preferably reduce, more preferably reduce at least about 10 ℃ at least about 5 ℃.The major advantage of main solvent is that it provides maximum benefit for the solvent of given weight.Should be appreciated that said " solvent " is meant effect rather than its physical form under assigned temperature of main solvent, because some main solvent is solid at ambient temperature here.Lactic acid alkyl ester
Some lactic acid alkyl ester, for example ethyl lactate and isopropyl lactate, its ClogP value is in the useful range of about 0.15-0.64, can form with fabric softener active matter of the present invention and concentrate transparent liquid fabric softener composition, but need than more effective glycolic solvents as 1, the slightly high content of 2-hexylene glycol uses down.They also can be used for replacing a part other main solvent of the present invention to concentrate transparent liquid fabric softener composition to form.This illustrates in example I-C.III. other optional component
(A) present composition also can contain other fabric softener active matter, but only exist on a small quantity, general 0%-is about 35%, preferably about 1%-20%, 2%-10% more preferably from about, described other fabric softener active matter is selected from: (1) has the softening agent of following formula:
R 4-m-N (+)-R 1 mA -Wherein each m is 2 or 3; Each R 1Be C 6-C 22, preferred C 14-C 20, but be no more than 1 less than about C 12With other be at least about C 16Alkyl, or the hydrocarbyl substituent that replaces, preferred C 10-20Alkyl or alkenyl (unsaturated alkyl comprises many unsaturated alkyls, is also referred to as " alkylidene group " sometimes), most preferably C 12-18Alkyl or alkenyl wherein contain this R 1The iodine number of the lipid acid of group (hereinafter referred to as " IV ") is about 70 to about 140, more preferably from about 80 to about 130; Most preferably from about 90 to about 115 (term used herein " iodine number " meaning is the iodine number of " parent " lipid acid or " corresponding " lipid acid, and it is used to define R 1The degree of unsaturation of group, this degree of unsaturation with contain same R 1The degree of unsaturation of the lipid acid of base is identical); Wherein, the ratio of cis/trans is about 1: 1 to about 50: 1, and minimum is 1: 1, preferred about 2: 1 to about 40: 1, is more preferably about 3: 1 to about 30: 1, even is more preferably about 4: 1 to about 20: 1; Each R 1Preferably also can be side chain C 14-22Alkyl, preferred side chain C 16-18Alkyl; Each R is H or short chain C 1-6, preferred C 1-3Alkyl or hydroxyalkyl, for example, methyl (most preferably), ethyl, propyl group, hydroxyethyl etc., benzyl, or (R 2O) 2-4H, wherein each R 2Be C 1-6Alkylidene group; A -Be the negatively charged ion compatible with softening agent, preferred chlorion, bromide anion, methylsulfate, ethyl sulphate, sulfate radical, and nitrate radical, more preferably chlorion and methylsulfate;
(2) have the softening agent of following formula: R wherein, R 1And A -Has the definition that provides above separately; Each R 2Be C 1-6Alkylidene group, preferred ethylidene; With G be Sauerstoffatom or-the NR-group;
(3) have the softening agent of following formula:
Figure A9880714900572
R wherein 1, R 2With G as top definition;
(4) be the higher fatty acid of undersaturated and/or side chain and two alkylene triamine basically with for example mol ratio be the reaction product of about 2: 1 ratio reaction, described reaction product contains following formula: compound:
R 1-C (O)-NH-R 2-NH-R 3-NH-C (O)-R 1R wherein 1, R 2As top definition and each R 3Be C 1-6Alkylidene group, preferred ethylidene;
(5) have the softening agent of following formula:
[R 1-C (O)-NR-R 2-N (R) 2-R 3-NR-C (O)-R 1] +A -R wherein, R 1, R 2, R 3And A -As top definition;
(6) be the higher fatty acid of undersaturated and/or side chain and hydroxyalkyl Alkylenediamine basically with mol ratio be the reaction product of about 2: 1 ratio reaction, described reaction product contains following formula: compound:
R 1-C (O)-NH-R 2-N (R 3OH)-C (O)-R 1R wherein 1, R 2And R 3As top definition;
(7) have the softening agent of following formula:
Figure A9880714900581
R wherein, R 1, R 2And A -As top definition; With
(8) their mixture;
But can be used in combination with top softening agent actives a kind of other optionally very the ideal cation compound be to contain an acyclic C of long-chain 8-22The compound of alkyl is selected from:
(8) have the acyclic quaternary ammonium salt of following formula:
[R 1-N (R 5) 2-R 6] +A -R wherein 5And R 6Be C 1-4Alkyl or hydroxyalkyl, and R 1And A -Define as mentioned;
(9) have the imidazole salts of the replacement of following formula:
Figure A9880714900582
R wherein 7Be hydrogen or C 1-4Saturated alkyl or hydroxyalkyl, and R 1And A -Define as mentioned;
(10) have the imidazole salts of the replacement of following formula:
Figure A9880714900591
R wherein 5Be C 1-4Alkyl or hydroxyalkyl, and R 1, R 2, and A -Define as mentioned;
(11) have the Fixanol of following formula:
Figure A9880714900592
R wherein 4Be no cyclic aliphatic C 8-22Alkyl and A -It is negatively charged ion; With
(12) have the alkane acyl ammonia alkylidene group pyridinium salt of following formula: R wherein 1, R 2And A -Define as mentioned; With their mixture.
The example of compound (9) is mono-alkenyl leptodactyline such as single oil base trimethyl ammonium chloride, single canola oil base trimethyl ammonium chloride and soya-bean oil base trimethyl ammonium chloride.Preferred single oil base trimethyl ammonium chloride and single canola oil base trimethyl ammonium chloride.Other example of compound (9) is can be from Witco company according to trade(brand)name Adogen The 415 soya-bean oil base trimethyl ammonium chlorides of buying, erucyl trimethyl ammonium chloride, wherein R 1Be the C that derives and obtain by natural source 22Alkyl; Soya-bean oil base dimethyl ethyl QAE quaternary aminoethyl vitriol, wherein R 1Be C 16-18Alkyl, R 5Be methyl, R 6Be ethyl, and A -It is the ethyl sulphate negatively charged ion; With methyl two (2-hydroxyethyl) oil base ammonium chloride, wherein R 1Be C 18Alkyl, R 5Be 2-hydroxyethyl and R 6It is methyl.
(13) diester quaternary ammonium fabric softener actives (DEQA)
DEQA preferably includes (but getting rid of the above fabric softener of disclosed necessity):
[(R) 2-N +-[(CH 2) n-Y-R 1] 2] A -Wherein each R and A -In optional softening agent (1), define as mentioned, but when n be 2 and y be-during O-(O) C-, R is not a hydroxyethyl; Each n is 1-about 4, preferred 2; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-, preferred-O-(O) C-, but be not-OC (O)-O-; Each R 1In the carbon atom summation, when Y be-O-(O) C-or-(R) add 1 during N-(O) C-, be C 6-C 22, preferred C 14-C 20But summation is less than about 12 YR 1Be no more than one, and other YR 1Summation is at least about 16, each R 1Be long-chain C 8-C 22(or C 7-C 21) alkyl, or the hydrocarbyl substituent that replaces, preferred C 10-C 20(or C 9-C 19) alkyl or alkenyl, C most preferably 12-C 18(or C 11-C 17) alkyl or alkenyl, and when described carbon atom summation be C 16-C 18And R 1When being straight chained alkyl or alkenyl, contain this R 1The iodine number of the maternal fatty acid of group (IV hereinafter referred to as) is preferably about 20-140,50-130 more preferably from about, most preferably from about 70-115[the present invention also contains medium chain ammonium cation fabric soft compound, comprise DEQA analogue/homologue with following formula, wherein: each C (O) O by for example-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-, preferred-O-(O) C-replaces; M is 2 or 3, preferred 2; Each n is 1-4, preferred 2; Each R defines as mentioned; Each R 1Or YR 1Hydrophobic group is saturated C 8-C 14, preferred C 12-14Alkyl, or the hydrocarbyl substituent that replaces (IV is preferably about 10 or lower, more preferably less than about 5), [the total number of carbon atoms in this hydrophobic group is with the total number of carbon atoms in the R group, or when Y be-O-(O) C-or-(R) during N-(O) C-, it is with the total number of carbon atoms in the YR group] and counter ion A -With above-mentioned.Preferred A -Do not comprise phosphoric acid salt.Saturated C 8-C 14Fatty acyl group can be that pure derivative maybe can have the mixing chain length.The fatty acid source that is fit to of described fatty acyl group is coconut oil, lauric acid, sad and capric acid.For C 12-C 14(or C 11-C 13) alkyl, this group is preferably saturated, and for example IV preferably is lower than approximately 10, preferably is lower than about 5.
Another kind of variant has general formula:
R 3-N +-CH 2-CH (YR)-CH 2-YR 1A is each Y wherein, R, R 1, and A -Has implication as hereinbefore.This compound comprises those compounds with following formula:
[CH 3] 3N (+)[CH 2CH (CH 2O (O) CR 1) O (O) CR 1] Cl (-)Wherein each R is methyl or ethyl, preferably each R 1Be at C 15-19Scope.In alkyl or alkenyl chain, can there be branching and substitution value.Negatively charged ion X in this molecule (-)Identical with the definition among the DEQA of above necessity.As using in this article, when the explanation diester, it can comprise the monoesters of existence.The monoesters quantity that can exist identical with in DEQA (1).The example of the preferred DEQA of formula (2) is to have formula 1,2-two (acyloxy)-3-trimethylammonium propyl ammonium muriatic " propyl group " ester quaternary ammonium fabric softener actives, wherein acyl group and FA 5In identical.
The reagent of these types and their usual way of preparation license in people's such as Naik the U.S. Pat 4137180 open on January 30th, 1979, this patent is quoted as a reference by this paper].
(14) (1) is to any mixture of (13).
Can be used for other fabric softener of the present invention and be disclosed in the following patent, wherein disclose the U.S3 of basic structure: Edwards and Diehl at least prevailingly, 861,870; The US4 of Cambre, 308,151; The US3 of Bernardino, 886,075; The US4 of Davis, 233,164; The US4 of Verbruggen, 401,578; The US3 of Wierserma and Rieke, 974,076; With the US4 of Rudkin, Clint and Young, 237,016, all described patents are quoted for referencial use at this paper.Those highly undersaturated variants of the preferably traditional softening agent actives of other softening agent actives of this paper, i.e. double long-chain alkyl azepine derivatives, normally cationic materials, for example two oil base alkyl dimethyl ammonium chlorides and imidazolinium compounds as mentioned below.The example of more biodegradable fabric softener is found in the U.S. Pat 3408361 of the Mannheimer that authorizes October 29 nineteen sixty-eight; The U.S. Pat 4709045 of the Kubo that on November 24th, 1987 authorized etc.; The U.S. Pat 4233451 of the Pracht that on November 11st, 1980 authorized etc.; The U.S. Pat 4127489 of the Pracht that on November 28th, 1979 authorized etc.; The U.S. Pat 3689424 of the Berg that on September 5th, 1972 authorized etc.; The U.S. Pat 4128485 of the Baumann that on December 5th, 1978 authorized etc.; The U.S. Pat 4161604 that on July 17th, 1979 authorized; The U.S. Pat 4339391 of the Hoffman that the U.S. Pat 4189593 of the Wechsler that on February 19th, 1980 authorized etc. and July 13 nineteen eighty-two authorize etc., described patent is quoted for referencial use at this paper.
The example of compound (1) is that two alkylidene group dimethyl ammoniums are as two canola oil base (dicanola) alkyl dimethyl ammonium chlorides, two canola oil base Dimethyl Ammonium Methylsulfates, two (partially hydrogenated soya oils, the cis/trans ratio is about 4: 1) alkyl dimethyl ammonium chloride, two oil base alkyl dimethyl ammonium chlorides.Preferred two oil base alkyl dimethyl ammonium chlorides and two canola oil base alkyl dimethyl ammonium chlorides.Can be used for example that can the commercial two alkylidene group dimethyl ammoniums of buying of the present invention is can be from Witco company according to trade(brand)name Adogen The 472 two oil base alkyl dimethyl ammonium chlorides of buying.
The example of compound (2) is 1-methyl isophthalic acid-oil base amido ethyl-2-oil-based imidazoline Methylsulfate, wherein R 1Be no cyclic aliphatic C 15-17Alkyl, R 2Be ethylidene, G is the NH group, R 5Be methyl and A -Be the methylsulfuric acid salt anionic, it can be from Witco company according to trade(brand)name Varisoft 3690 buy.
The example of compound (3) is 1-oil base amido ethyl-2-oil-based imidazoline, wherein R 1Be no cyclic aliphatic C 15-17Alkyl, R 2Be ethylidene, G is the NH group.
The example of compound (4) is oleic acid and diethylenetriamine with mol ratio is the reaction product of about 2: 1 ratio reaction, and described mixture of reaction products contains the N of following formula, N " two oil base diethylenetriamine:
R 1-C (O)-NH-CH 2CH 2-NH-CH 2CH 2-NH-C (O)-R 1R wherein 1-C (O) is the oleic oil base that can be purchased of deriving and obtaining from plant or animal source, as the Emersol that can buy from Henkel company 223LL or Emersol 7021, and R 2And R 3It is the divalence ethylidene.
The example of compound (5) is the softening agent based on two fatty amidoamines with following formula: [R 1-C (O)-NH-CH 2CH 2-N (CH 3) (CH 2CH 2OH)-CH 2CH 2-NH-C (O)-R 1] +CH 3SO 4 -R wherein 1-C (O) is an oil base, can be from Witco company according to trade(brand)name Varisoft 222LT buys.
The example of compound (6) is oleic acid and N-2-hydroxyethyl ethylene diamine with mol ratio is the reaction product of about 2: 1 ratio reaction, and described mixture of reaction products contains following formula: compound:
R 1-C (O)-NH-CH 2CH 2-N (CH 2CH 2OH)-C (O)-R 1R wherein 1-C (O) is the oleic oil base that can be purchased of deriving and obtaining from plant or animal source, as the Emersol that can buy from Henkel company 223LL or Emersol 7021.
The example of compound (7) is two quaternary ammonium compounds with following formula:
Figure A9880714900631
R wherein 1Being derived by oleic acid obtains, and this compound can be bought from Witco company.
The example of compound (11) is 1-ethyl-1-(2-the hydroxyethyl)-different heptadecyl tetrahydroglyoxaline of 2-sulfovinate, wherein R 1Be C 17Alkyl, R 2Be ethylidene, R 5Be ethyl, and A -It is the ethyl sulphate negatively charged ion.
Negatively charged ion A
Contain in the nitrogen salt any negatively charged ion A compatible with softening agent at positively charged ion of the present invention -Electric neutrality is provided.The most common is to be used to provide electroneutral negatively charged ion from strong acid in these salt, halogenide especially, and as muriate, bromide, or iodide.But also can use other negatively charged ion such as Methylsulfate, sulfovinate, acetate, formate, vitriol, carbonate etc.The present invention preferably uses muriate and Methylsulfate as negatively charged ion A.At A -Represent under the situation of half group, this negatively charged ion also can, but not too preferably have double charge.
(B) the low-molecular weight water-soluble solvent also can use, and its consumption is about 12% for about 0-, and preferably about 1%-is about 10%, more preferably from about 2%-8%.This water-soluble solvent with the same low content of aforesaid main solvent under can not form transparent product, but when the product that main solvent is not enough to provide transparent fully, this water-soluble solvent can provide transparent product.Therefore the existence of these water-soluble solvents is the height ideal.This kind solvent comprises: ethanol, Virahol, 1, and 2-propylene glycol, 1, ammediol, Texacar PC etc., but do not comprise any main solvent (B).These water-soluble solvents affinity to water in the presence of lyophobic dust such as softening agent actives is stronger than main solvent.
(C) whitening agent
The wetting ability white dyes that also can randomly contain some type of 0.005%-5% weight of having an appointment in the present composition, they also work to suppress dye transfer.If use, preferably contain this fluorescent bleaches of about 0.001%-1% weight in the present composition.
Can be used for wetting ability white dyes of the present invention is the following compound of structural formula: R wherein 1Be selected from anilino, N-2-dihydroxy ethyl and NH-2-hydroxyethyl; R 2Be selected from N-2-dihydroxy ethyl, N-2-hydroxyethyl-N-methylamino-, morpholino, chlorine and amino; M is a salt-forming cation, as sodium or potassium.
R in above chemical formula 1Be anilino, R 2Be the N-2-dihydroxy ethyl, and M is when being positively charged ion such as sodium, whitening agent be 4,4 '-two ((4-anilino-6-(N-2-dihydroxy ethyl)-S-triazine-2-yl) amino)-2,2 '-stilbene disulfonic acid and disodium salt.This special brightener species by Ciba-Geigy Corporation with Tinopal-UNPA-GX Trade name sell.Tinopal-UNPA-GX is the preferred wetting ability white dyes in the composition that adds when can be used for rinsing of the present invention.
R in above chemical formula 1Be anilino, R 2Be N-2-hydroxyethyl-N-2-methylamino-, and M is when being positively charged ion such as sodium, then whitening agent be 4,4 '-two ((4-anilino-6-(N-2-hydroxyethyl-N-methylamino-)-S-triazine-2-yl) amino)-2,2 '-the stilbene disulfonic acid disodium salt.This special brightener species by Ciba-GeigyCorporation with Tinopal-5BM-GX Trade name sell.
R in following formula 1Be anilino, R 2Be morpholino, and M is when being positively charged ion such as sodium, then whitening agent be 4,4 '-two ((4-anilino-6-morpholino-S-triazine-2-yl) amino)-2,2 '-the stilbene disulfonic acid, sodium salt.This special whitening agent by Ciba-GeigyCorporation with Tinopal-AMS-GX Trade name sell.
(D) Ren Xuan viscosity/dispersity conditioning agent
Containing saturated and the denseer composition unsaturated diol quaternary ammonium compound can be prepared into stabilising system and needn't add the concentration auxiliary agent.But composition of the present invention may need organic and/or inorganic concentration auxiliary agent to reach higher concentration and/or to satisfy higher stability criterion, and this depends on other component.May or preferably need these normally concentration auxiliary agents of viscosity modifier, so that guarantee its stability under the extreme condition when using the softening agent actives of certain content.The surfactant concentration auxiliary agent is selected from usually: those of the fabric softener that for example above disclosed conduct of (1) single-long-chain alkyl cats product is optional; (2) nonionogenic tenside; (3) oxidation amine; (4) lipid acid; (5) their mixture.These auxiliary agents are at P ﹠amp; In the application 08/461,207 of G pending trial (application on June 5 nineteen ninety-five, Wahl etc.) explanation is arranged, particularly walk to the 20th page of 12 row at the 14th page 12, this article is quoted as a reference in this article.
When having described dispersing auxiliary, its total content is about 2%-25% of composition weight, preferably about 3%-17%, 4%-15% more preferably from about, even 5%-13% more preferably from about.These materials or add as the part of REACTIVE SOFTNER raw material (I), for example, single-long-chain alkyl cats product and/or lipid acid as previously mentioned, or as independent component adding, said lipid acid is the reactant that is used for forming biodegradable fabric softener active matter.The total content of dispersing auxiliary comprises any amount that may exist as the part of component (I).
(1) monoalkyl cationic type quaternary ammonium compound
When having the cationic quaternary ammonium compound of single-long-chain alkyl, its content is generally about 2%-25% of composition weight, preferably about 3%-17%, more preferably from about 4%-15%, even 5%-13% more preferably from about, total monoalkyl cationic type quaternary ammonium compound is in effective content range at least.
Can be used for the preferably following quaternary ammonium salt of general formula of this class monoalkyl cationic type quaternary ammonium compound of the present invention:
[R 4N +(R 5) 3] A -Wherein: R 4Be C 8-C 22Alkyl or alkenyl, preferred C 10-C 18Alkyl or alkenyl, more preferably C 10-C 14Or C 16-C 18Alkyl or alkenyl; Each R 5Be C 1-6The alkyl of alkyl or replacement (as hydroxyalkyl), preferred C 1-C 3Alkyl, as methyl (most preferably), ethyl, propyl group etc., benzyl, hydrogen has about 2-20 oxygen ethylene unit, preferably about 2.5-13 oxygen ethylene unit, the more preferably from about polyethoxylated chain of 3-10 oxygen ethylene unit, and their mixture; A -Identical with the front to the definition of formula (I).
Particularly preferred dispersing auxiliary is single lauryl trimethyl ammonium chloride and single tallow trimethyl ammonium chloride, and they can be by Witco with Varisoft 471 trade name has been bought, and can be by Witco with trade name Varisoft 417 single oil base trimethyl ammonium chlorides of having bought.
R 4Base also can be connected with azonia by a group that contains linking groups such as one or more esters, acid amides, ether, amine, and the basic condensability for raising component (I) etc. of this connections is an ideal.These linking groups are preferably in about 1-3 carbon atom of nitrogen-atoms.
Monoalkyl cationic type quaternary ammonium compound also comprises C 8-C 22The alkyl cholinesterase.The preferred dispersing auxiliary of this type has following chemical formula:
R 1C (O)-O-CH 2CH 2N +(R) 3A -R wherein 1, R and A -Definition the same.
Highly preferred dispersing auxiliary comprises C 12-C 14Cocoyl cholinesterase and C 16-C 18The tallow cholinesterase.
At United States Patent (USP) 4,840, narrated the single-long-chain alkyl dispersing auxiliary of the suitable biodegradation type that in long-chain, contains ester bond among 738 (Hardy and the Walley, on June 20th, 1989 issued), this patent is quoted as a reference in this article.
When dispersing auxiliary contains the alkyl cholinesterase, preferably also contain in the composition a spot of, preferably account for the organic acid of the about 2%-5% of composition weight.Narrated organic acid in european patent application 404471 (Machin etc., announce December 27 nineteen ninety, preamble), this patent is here quoted as a reference.Organic acid preferably is selected from oxyacetic acid, acetate, citric acid and composition thereof.
The ethoxylation quaternary ammonium compound that can be used as the dispersing auxiliary use comprises ethyl two (polyethoxyethanols) the alkyl ethylsulfuric acid ammonium that has 17 moles of ethylene oxide, and it can be obtained trade name Variquat by SherexChemical Company 66; Polyoxyethylene glycol (15) oil base ammonium chloride can be obtained trade name Ethoquad by Akzo 0/25; And polyoxyethylene glycol (15) cocoyl ammonium chloride, can obtain trade name Ethoquad by Akzo 0/25.
The single long-chain material that is fit to meets above-mentioned softening agent actives, wherein only has a R in this molecule 1Group.R 1Or YR 1Group can be replaced by the R group usually.
Though the major function of dispersing auxiliary is to improve the dispersiveness of ester class softening agent, dispersing auxiliary of the present invention preferably also has some softening character so that promote the softness function of composition.Therefore, the present composition preferably is substantially free of the ethoxylated non-ionic type dispersing auxiliary of non-nitrogen, and this type of material can reduce the total soft voltinism energy of composition.
In addition, have only the quaternary ammonium compound of a single long alkyl chain can protect cationic softener not interact with anion surfactant and/or the detergent builder from washing soln, brought in the rinsing liquid.People are starved of has enough single long chain quaternary ammonium compound, and perhaps cationic polymers is with fixing anion surfactant.The wrinkling control that improves is provided like this.The ratio of fabric sofetening promoting agent and single long-chain compound generally is about 100: 1 to about 2: 1, preferred about 50: 1 to about 5: 1, and more preferably from about 13: 1 to about 8: 1.Carry under the condition this ratio preferably about 5: 1 to about 7: 1 at high washing composition.Single long-chain compound generally is present in the rinse process to the content of about 25ppm with about 10ppm.
(2) oxidation amine
Suitable amine oxide comprises and has about 8-22 carbon atom, preferably about 10-18 carbon atom, the more preferably from about alkyl or the hydroxyalkyl part of 8-14 carbon atom, and the amine oxide that is selected from two moieties of the alkyl that contains 1-3 the carbon atom of having an appointment and hydroxyalkyl.
Example comprises dimethyloctylamine oxide, diethyl decyl amine oxide, two (2-hydroxyethyl) dodecyl amine oxide, the dimethyl dodecyl amine oxide, dipropyl tetradecyl amine oxide, methylethyl hexadecyl amine oxide, dimethyl-2-hydroxyl octadecyl amine oxide and cocounut oil aliphatic alkyl dimethyl oxidation amine.
(E) stablizer
In the present composition, can there be stablizer.Terminology used here " stablizer " comprises antioxidant and reductive agent.For antioxidant, the content of these reagent is about 2% for about 0-, preferably about 0.01%-0.2%, and 0.035%-0.1% more preferably from about is for the preferably about 0.01%-0.2% of reductive agent.This has guaranteed the good odor stable under the standing storage condition.Antioxidant and reductive agent stablizer are crucial especially for product perfuming or low fragrance (do not have or seldom spices).These stablizers also can, and preferably, join in the distilled lipid acid and/or before with the trolamine esterification, and/or before quaternization or in the process, add, and/or the back batching, when producing and remaining on storing state, have good color and smell to guarantee the softening agent actives.
The example that can be added to the antioxidant in composition and the technology of the present invention comprises EastmanChemical Products, and Inc is with trade name Tenox PG and Tenox The mixture of xitix, ascorbyl palmitate and Tenox PG that S-1 sells; Can be by Eastman Chemical Products, the trade name that Inc. obtains is Tenox The mixture of-6 BHT (butylation hydroxymethyl), BHA (butylated hydroxyanisol), Tenox PG and citric acid; The trade name that can be obtained by UOP Process Division is Sustane The Yoshinox BHT of BHT; Eastman Chemical Products, the trade name of Inc. is Tenox The tertiary butylated hydroquinone of TBHQ; Eastman ChemicalProducts, Inc. is with Tenox The natural tocopherol that the trade name of GT-1/GT-2 is sold; And Eastman Chemical Products, the butylated hydroxyanisol of the trade name BHA of Inc.; Long-chain (the C of gallic acid 8-C 22) ester, for example lauryl gallate; Irganox 1010; Irganox 1035; Irganox B1171; Irganox 1425; Irganox 3114; Irganox 3125; And their mixture; Preferred Irganox 3125; Irganox 1425; Irganox 3114 and composition thereof; More preferably Irganox 3125 itself or with citric acid and/or other sequestrant for example, the citric acid isopropyl ester mixes; The chemical name that can be obtained by Monsanto is a 1-hydroxy ethylene-1, the Dequest of 1-di 2 ethylhexyl phosphonic acid (hydroxyl ethylidene bisphosphate) 2010, the chemical name that can be obtained by Kodak company is 4, the Tiron of Phenylsulfonic acid/sodium salt between the 5-dihydroxyl , and the chemical name that can be obtained by Aldrich is the DTPA of diethylene triaminepentaacetic acid(DTPA) When using with low amount (for example about 50ppm), the reductive agent that is fit to is a sodium borohydride.
(F) dirt release agent
In the present invention, can add optional dirt release agent.Dirt release agent can mix adding with premixture, can mix adding with acid/water base body, can add before or after adding ionogen, or add after final composition prepares.Can contain 0% to about 10% with the soft compound of the inventive method preparation, preferably from 0.2% to about 5% dirt release agent.This class dirt release agent is polymkeric substance preferably.The polymerization dirt release agent that can be used among the present invention comprises copolymerization block thing of terephthalate and polyoxyethylene or polyoxypropylene etc.
Preferred dirt release agent is the multipolymer with terephthalate and polyoxyethylene blocks.More particularly, these polymkeric substance are to about 35: 65 ethylene glycol terephthalate and polyoxyethylene terephthalate repeating unit to constitute at 25: 75 by mol ratio, and described polyoxyethylene terephthalate contains the polyoxyethylene blocks of molecular weight for about 300-about 2000.The molecular weight ranges of this polymerization dirt release agent is about 5000 to 55000.
But another kind of preferred polymerization dirt release agent is a kind of polyester with crystallization of ethylene glycol terephthalate repeating unit, the polyoxyethylene glycol that wherein contains the ethylene glycol terephthalate unit of the 10%-15% weight of having an appointment and the about 10%-50% weight polyoxyethylene terephthalate unit of formation of deriving from the about 300-of molecular weight about 6000, but ethylene glycol terephthalate unit and the unitary mol ratio of polyoxyethylene terephthalate are 2: 1 to 6: 1 in the polymkeric substance of this crystallization.The example of this polymkeric substance comprises commercial goods Zelcon 4780 (from Dupont) and Milease T (from ICI).
Highly preferred dirt release agent is the following polymkeric substance of general formula: Wherein each X can be suitable capping group, and each X is selected from H usually, contains the alkyl or the acyl group of about 1-4 carbon atom.The selection of p will be considered water solubility, generally is to be about 6-113, is preferably about 20-50.U is crucial for preparation in having the liquid composition of relative high ionic strength.Wherein u should be seldom greater than 10 material.In addition, should have 20% at least, preferably have 40% wherein u at least is material from about 3-5.
R 14Part is 1 basically, the 4-phenylen moiety.Terminology used here " R 14Part is 1 basically, the 4-phenylen moiety ", be meant the R in the compound 14Part is fully by 1, and the 4-phenylen moiety constitutes, and is perhaps partly replaced by other arylidene or alkyl arylene part, alkylene moiety, alkenyl part or their mixture.Can partly replace 1, the arylidene and the alkyl arylene of 4-phenylene partly comprise: 1, and 3-phenylene, 1,2-phenylene, 1,8-naphthylidene, 1,4-naphthylidene, 2,2-diphenylene, 4,4-diphenylene and their mixture.Can the substituted alkylidene group of part and alkenylene partly comprise: propylene, tetramethylene, pentamethylene, hexamethylene, 1, the inferior heptyl of 7-, octamethylene, 1,4-cyclohexylidene and their mixture.
For R 14Part, with non-1, the degree that the 4-phenylene group partly replaces should make the dirt character of freeing of compound not be subjected to any otherwise impact largely.In general, admissible part substitution value depends on the backbone length of compound, that is, long main chain can have bigger by 1,4-phenylen moiety substitution value.Usually, R wherein 14Contain the 50%-100%1 that has an appointment, the compound of 4-phenylen moiety (0% to about 50% non-1,4-phenylen moiety) has enough dirt activity of freeing.For example, the polyester made from m-phthalic acid of 40: 60 mol ratios (1, the 3-phenylene) and terephthalic acid (1, the 4-phenylene) according to the present invention has enough dirt activity of freeing.But because the most of polyester that use in the fiber manufacturing contain the ethylene glycol terephthalate unit, so normal hope reduces with 1, the degree that the group outside the 4-phenylene partly replaces is active to obtain optimum solution decontamination dirt.Preferably, R 14Part complete (that is, containing 100%) is by 1, and the 4-phenylen moiety constitutes, that is, and and each R 14Part is 1, the 4-phenylene.
For R 15Part, the suitable ethylidene or the ethylidene of replacement partly comprise ethylidene, propylene, 1,2-butylidene, 1,2-hexylidene, 3-methoxyl group-propylene and their mixture.Preferably, R 15Part is ethylidene, propylene or its mixture basically.The ethylidene part that comprises big percentage composition can be improved the activity that compound is freed dirt.Surprisingly, comprise the water solubility that can improve compound than the propylene part of big percentage composition.
Therefore, using propylene part or similar branching equivalent is desired for mix any most dirt release agent in the fabric softener composition of liquid state.Preferably, propylene partly is about 75-100%.
It is about 6 that each p value is at least, and preferably is at least about 10.Each n value is generally about 12-about 113.Generally, each p value is about 12-about 43.
Describing more completely in following document relevant for dirt release agent: United States Patent (USP) 4,661,267 (Decker, Konig, Straathof and Gosselink, on April 28th, 1987 issued); 4,711,730 (Gosselink and Diehl, on December 8th, 1987 issued); 4,749,596 (Evans, Huntington, Stewart, Wolf and Zimmerer, on June 7th, 1988 issued); 4,818,569 (on April 4th, 1989 issued for Trinh, Gosselink and Rattinger); 4,877,896 (on October 31st, 1989 issued for Maldonado, Trinh and Gosselink); 4,956,447 (Gosselink etc., issue September 11 nineteen ninety) and 4,976,879 (issue December 11 nineteen ninety for Maldonado, Trinh and Gosselink).These patents all are cited as a reference in this article.
These dirt release agents also can play the soap scum dispersion agent.
(G) soap scum dispersion agent
In the present invention, pre-composition can with a kind of optional soap scum dispersant of non-dirt release agent, and be heated to this component fusing point or higher temperature.
The preferred soap scum dispersion agent of the present invention is that the lyophobic dust by the height ethoxylation forms.This lyophobic dust can be Fatty Alcohol(C12-C14 and C12-C18), lipid acid, aliphatic amide, fatty acid amide, amine oxide, quaternary ammonium compound, or is used for forming the hydrophobic parts of soil release polymers.Preferred soap scum dispersion agent is the height ethoxylation, and for example each molecule on average has and surpasses approximately 17, and preferably more than about 25, more preferably more than about 40 ethylene oxide molecules, polyoxyethylene partly accounts for about 76%-97% of total molecular weight, preferably about 81%-94%.
The content of soap scum dispersion agent is enough to make under working conditions soap scum to remain on acceptable, the unnoticed level preferably of human consumer, but is not enough to that softnessization is had disadvantageous effect.For some purpose, wish not exist soap scum.Quantity according to anionic that in the washing stage of typical laundry processes, uses or non-ionic detergent etc., the efficient that adds present composition rinse stage before, and water hardness, the quantity of negatively charged ion of carrying secretly in fabric (laundry) or nonionic detergent tensio-active agent and detergent builder (especially phosphoric acid salt and zeolite) can change.Usually, should use the soap scum dispersion agent of minimum quantity to avoid disadvantageous effect to soft voltinism matter.Generally, the requirement of soap scum dispersion agent is at least the about 2% of softening agent active matter content, preferably is at least about 4% (for farthest avoiding soap scum, at least 6%, preferably at least 10%).But under about 10% (with respect to softening agent material) or higher content, the softness effect of product has the danger of reduction, especially contains under the situation of a high proportion of nonionogenic tenside that is absorbing during the washing operation at fabric.
Preferred soap scum dispersion agent is: Brij 700 , Varonic U-250 , GenapolT-500 , Genapol T-800 , Plurafac A-79 With Neodol 25-50
(H) sterilant
The example of the sterilant that uses in the present composition comprises glutaraldehyde, formaldehyde, 2-bromo-2-nitropropane-1, and (Inolex Chemicals sells the 3-glycol, is positioned at Philadelphia, Binzhou, trade name Bronopol ), and mixture (the Rohm ﹠amp of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone; Haas Company, trade name Kathon), consumption is about 1-1000ppm, in the weight of this reagent.
(I) spices
The present invention can comprise any spices compatible with softening agent.Suitable spices is disclosed in the United States Patent (USP) of issuing on March 19th, 1,996 5,500,138 (people such as Bacon), and this patent is quoted as a reference at this paper.
Here said spices comprises aromatoising substance or aromatoising substance mixture, comprising natural (promptly, extracting flower, grass, leaf, root, bark, wood, flowers or plant obtains), synthetical (promptly, the mixture of different natural oils or oil component) and the fragrant containing substance of synthetic (that is, synthesize make).These materials often are accompanied by auxiliary substance, for example fixative, extender, stablizer and solvent.These auxiliary substances are also included within this paper said " spices " definition.Usually, spices is the complex mixture of many organic compound.
The example that can be used on the perfume composition in the spices of the present composition includes but not limited to: hexyl cinnamic aldehyde, amyl cinnamic aldehyde, orchidae, n-Hexyl salicylate, terpinol, 3,7-dimethyl-suitable-2,6-octadiene-1-alcohol, 2,6-dimethyl-sec-n-octyl alcohol, 2,6-dimethyl-7-octen-2-ol, 3,7-dimethyl-3-octanol, 3,7-dimethyl-anti--2,6-octadiene-1-alcohol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-1-octanol, 2-methyl-3-(to tert-butyl-phenyl) propionic aldehyde, 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde, tricyclo decenyl propionate, verdy acetate, aubepine, 2-methyl-2-(p-isopropyl phenyl) propionic aldehyde, glycidic acid ethyl-3-methyl-3-phenylester, 4-(p-hydroxybenzene) fourth-2-ketone, 1-(2,6,6-trimethylammonium-2-tetrahydrobenzene-1-yl)-2-butylene-1-ketone, to *-methoxy acetophenone, to methoxyl group-α-phenyl propylene, methyl-2-n-hexyl-3-oxo-cyclopentane carboxylicesters, peach aldehyde.
Other example of aromatoising substance includes but not limited to: orange oil, lemon oil, Oil of grapefruit, Oils, bergamot peel, clove(bud)oil, γ-dodecylic acid lactone, methyl-2-(2-amyl group-3-oxocyclopentyl) acetic ester, β-Nai Jiami, methyl-β-naphthalenone, tonka bean camphor, capraldehyde, phenyl aldehyde, acetate 4-tertiary butyl cyclohexyl, acetate α, alpha-alpha-dimethyl phenethyl ester, acetate aminomethyl phenyl methyl esters, the Schiff's base of 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde and methyl oaminobenzoate, the ring-type ethylene glycol diester of undecane dicarboxylic acid, 3,7-dimethyl-2,6-octadiene-1-nitrile, cetone gamma, α-Zi Luolantong, alpha, beta-lonone, petitgrain oil, vertofix coeur, 7-ethanoyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene, methylionone, methyl isophthalic acid, 6,10-trimethylammonium-2,5,9-cyclododecatriene-1-base ketone, 7-ethanoyl-1,1,3,4,4, the 6-vegolysen, 2,3, the 4-tetraline, the 4-ethanoyl-6-tertiary butyl-1,1-dimethyl-1, the 2-indane, benzophenone, 6-ethanoyl-1,1,2,3,3,5-vegolysen, 2-indane, 5-ethanoyl-3-sec.-propyl-1,1,2,6-tetramethyl--1,2-indane, 1-dodecanal, 7-hydroxyl-3,7-dimethyl octanal, 10-undecene-1-aldehyde, dissident's thiazolinyl hexahydrobenzaldehyde, the formyl radical tristane, the cyclopentadecane acid lactide, 16-hydroxyl-palmitoleic acid lactone, 1,3,4,6,7,8-six hydrogen-4,6,6,7,8,8-hexamethyl cyclopenta-γ-2-chromene, ambroxane, ten dihydros-3a, 6,6,9a-tetramethyl-naphtho-(2,1b) furans, cypress camphor, 5-(2,2,3-front three basic ring penta-3-thiazolinyl)-3-methylpent-2-alcohol, 2-ethyl-4-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-2-butylene-1-alcohol, caryophyllenol, cedryl acetate, to the tert-butylcyclohexyl acetic ester, Wrinkled Gianthyssop Herb, frankincense balm, cistus creticus, Vetiveria zizanoides, flaw in a piece of jade crust face cream, Canada turpentine; And the condensation product of following substances: laurine and methyl o-aminobenzoate; Laurine and indoles; Phenylacetic aldehyde and indoles; 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde and methyl o-aminobenzoate.
Other example of perfume composition has Geraniol, meraneine, phantol, phanteine, tetrahydrolinalool, geraniol, citronellyl acetate, dihydromyrcenol, acetate dihydromyrcene ester, Tetrahydromyrcenol, tirpinyl acetate, nopol, nopyl acetate, 2-phenylethyl alcohol, acetate 2-phenyl chlorocarbonate, phenylcarbinol, jasmal, benzyl salicylate, peruscabin, acetate 1-phenyl chlorocarbonate, dimethylbenzylcarbinol, trichloromethyl phenyl methyl alcohol methyl phenyl carbinol acetic ester, vanoris, acetate vetiveryl ester, vetiverol, 2-methyl-3-(to tert-butyl-phenyl) propionic aldehyde, 2-methyl-3-(p-isopropyl phenyl) propionic aldehyde, 3-(to tert-butyl-phenyl) propionic aldehyde, 4-(4-methyl-3-pentenyl)-3-tetrahydrobenzene formaldehyde, 4-acetoxy-3-amyl group tetrahydropyrans, methyl dihydrojasmonate, 2-n-heptyl cyclopentanone, 3-methyl-2-amyl group cyclopentanone, n-capric aldehyde, n-dodecane aldehyde, 9-decenol-1, phenoxyethyl isobutanoate, the phenylacetic aldehyde dimethyl acetal, the phenylacetic aldehyde diethyl acetal, lemonile, citronellyl nitrile, cypress base acetal, the 3-Santalex, cypress base methyl ether, the different ketone that comes into leaves, the aubepine nitrile, aubepine, heliotropine, oxymethoxyallylbenzene, vanillin food grade,1000.000000ine mesh, phenyl ether, laurine, jononeionone, methylionone, isoraldeine, irone, suitable-3-hexenol and ester thereof, the indane musk odorant, tetralin musk spices, isochroman musk spices, macrocyclic ketone, big lactone musk odorant, the undecane dicarboxylic acid glycol ester.
The spices that can be used for the present composition is not halide matter and nitro musk basically.
The suitable solvent of above-mentioned perfume composition, diluent or carrier for example have: ethanol, Virahol, Diethylene Glycol, monoethyl ether, dipropylene glycol, diethyl phthalate, triethyl citrate etc.Mix these solvents in the spices, the minimum quantity that provides uniform spice solution required preferably is provided the quantity of diluent or carrier.
The content of spices can be final product composition having weight 0% to about 15%, be preferably about 0.1-8%, more preferably about 0.2-about 5%.Fabric softener composition of the present invention has improved the deposition of fabric spices.
(J) sequestrant
The compositions and methods of the invention can randomly use one or more copper and/or nickel sequestrant.This water-soluble chelator can be selected from the aromatic chelating agent of aminocarboxylate, amino phosphonates do, multifunctional replacement and their mixture, they all such as hereinafter definition.The whiteness of fabric and/or brightness improve greatly owing to this sequestrant or recover, and each Stability of Substance is improved in the composition.
The aminocarboxylate that can be used as sequestrant of the present invention comprises edetate (EDTA), N-hydroxyethyl-ethylenediamine triacetate, nitrilotriacetic acid(NTA) salt (NTA), ethylenediamine tetrapropionic acid(EDTP) salt, quadrol-N, N '-two glutaminate, 2-hydroxyl propylene diamine-N, N '-disuccinate, triethylenetetraaminehexaacetic acid salt, diethylentriamine pentacetate (DETPA) and ethanol Diglycocol ester comprise their water-soluble salt, an alkali metal salt for example, ammonium salt of ammonium salt and replacement and composition thereof.
When allowing low total phosphorous to exist in the detergent composition at least, phosphoro-amidate also is adapted at using as sequestrant in the present composition, this comprises ethylenediamine tetraacetic (methylene phosphonic acid salt), diethylenetriamine-N, N, N ', N "; N "-five (methane phosphonic acid) salt (DETMP) and 1-hydroxyl ethane-1,1-diphosphonate (HEDP).Preferably, these amino phosphonates do do not contain alkyl or the alkenyl more than about 6 carbon atoms.
In rinse stage of the present invention, the consumption of sequestrant is generally about 2ppm to about 25ppm, soak time from 1 minute until several hours.
The preferred EDDS (being also referred to as quadrol-N, N '-disuccinate) that the present invention uses is the material of describing in the United States Patent (USP) 4,704,233 mentioned above, has following chemical formula (listing free acid form):
HN (L) C 2H 4N (L) H wherein L is CH 2(COOH) CH 2(COOH) group.
As described in this patent, EDDS can prepare with maleic anhydride and quadrol.(S, S) isomer of preferred biodegradable EDDS can pass through L-aspartic acid and glycol dibromide prepared in reaction.EDDS is that than the superior part of other sequestrant it is all effective to two kinds of positively charged ions of chelating copper and mickel, can obtain with biodegradable form, and not phosphorous.The EDDS that uses as sequestrant among the present invention is generally its salt form, that is, and and one or more in four acidic hydrogens, for example replacements such as sodium, potassium, ammonium, triethanol ammonium by water-soluble cationic M.As previously mentioned, the EDDS sequestrant usually also with the consumption use of about 2ppm to about 25ppm, soaked 1 minute to several hours in rinse cycle of the present invention.Under certain pH, EDDS preferably is used in combination with zinc cation.
The present invention can use various sequestrants.In fact, simple multi-carboxylate for example Citrate trianion, oxygen di-succinate etc. also can use, though these sequestrants are effective not as aminocarboxylate and phosphonate by weight.Therefore, consider different chelating effectiveness degree, can regulate the consumption level.Sequestrant preferably is at least approximately 5 among the present invention to the stability constant (complete Ionized sequestrant) of cupric ion, preferably is at least about 7.Generally, sequestrant constitutes about 0.5%-10% of present composition weight, and 0.75%-5% more preferably from about is not included as those of stablizer.Preferred sequestrant comprises DETMP, DETPA, NTA, EDDS and their mixture.
(K) cationic polymers
The present composition can contain has an appointment 0.001% to about 10%, preferred about 0.01% to about 5%, 0.1% to about 2% cationic polymers more preferably from about, this cationic polymers generally has about 500 to about 1000000, preferred about 1000 to about 500000, more preferably from about 1000 to about 250000, with in addition 2000 to about 100000 molecular weight more preferably from about, with at least about 0.01meq/gm, preferred about 0.1 to about 8meq/gm, more preferably from about 0.5 to about 7 and even 2 to about 6 electric density more preferably from about.For cationic polymers is provided, especially contain the effect of the cationic polymers of amine or imine group, described cationic polymers preferably mainly is with the continuous aqueous phase.
Cationic polymers of the present invention can be amine salt or quaternary ammonium salt.Quaternary ammonium salt preferably.They comprise natural polymer such as some polysaccharide, natural gum, the cationic derivative of starch and some cation synthesising copolymer such as cationic ethylene yl pyridines or halid polymkeric substance of vinyl pyridine and multipolymer.Preferred polymers is water miscible, for example 20 ℃ of degree at least to 0.5% (weight).They preferably have about 600 to about 1000000, and more preferably from about 600 to about 500000, even 800 to about 300000 and especially about 1000 to about 10000 molecular weight more preferably from about.As universal law, molecular weight is low more, and the degree (D.S.) that is replaced by cation group is just high more, this cation group is quaternary group and needing normally, perhaps, and correspondingly, the replacement degree is low more, and the molecular weight of required group is high more, but does not have accurate relation.Usually, cationic polymers should have at least about 0.01meq/gm, and preferred about 0.1 to about 8meq/gm, and more preferably from about 0.5 to about 7 and even 2 to about 6 electric density more preferably from about.
Suitable required cationic polymers is disclosed in " the international cosmetic composition dictionary of CTFA ", the 4th edition, editors such as J.M.Nikitakis, by the Cosmetic, Toiletry, and Fragrance Association publishes, 1991, the document is quoted as a reference by this paper.Its tabulation comprises following material:
In the polysaccharide gum, guar gum and Viscogum BE are preferred, and they are galactomannan gums and can commercially buy.Therefore, guar gum is with trade(brand)name CSAA M/200, and CSA200/50 is sold by Meyhall and Stein-Hall, can buy from identical supplier with the hydroxy alkylated guar gum.Other can comprise by the commercial polysaccharide gum of buying: xanthan gum; Gum ghatti; Tamarind gum; Gum arabic; And agar.
Cation guar gum and their method of preparation are disclosed in English Patent GB1136842 and the U.S. Pat 4031307.Preferably they have 0.1 to about 0.5 D.S..
A kind of effective cation guar gum is a Jaguar C-13S (trade(brand)name-Meyhall).Cation guar gum is very preferred one group of cationic polymers in the present composition, even when being used for containing seldom or not containing the bath of remaining anion surfactant, they are not only as the scavenging agent of remaining anion surfactant but also increase the soft effect of cationic fabric softener.Other polysaccharide base natural gum can be similarly by quaternized, and basically in an identical manner and effect in various degree work.Suitable starch and derivative thereof are native starches as from corn, wheat, those that barley etc. obtain and from the starch such as the potato of rhizome, tapioca (flour) etc., and dextrin, especially pyrodextrin such as dextrin and white dextrin.
Some effectively single cationic polymers is as follows: polyvinyl pyridine, its molecular weight are that effective pyridine nitrogen atom of about 40000, wherein about 60% is by quaternized; Vinyl pyridine/cinnamic mol ratio is 70/30 multipolymer, and its molecular weight is that effective pyridine nitrogen atom of about 43000, wherein about 45% is by as described above by quaternized; The mol ratio of vinyl pyridine/acrylamide is 60/40 multipolymer, and effective pyridine nitrogen atom of wherein about 35% is by as described above by quaternized; The mol ratio of vinyl pyridine/methyl methacrylate is 77/23 and 57/43 multipolymer, and its molecular weight is that effective pyridine nitrogen atom of about 43000, wherein about 97% is by as described above by quaternized.
With low-down concentration, for example 0.001%-0.2% (weight), especially 0.02%-0.1% (weight) just effectively in composition for these cationic polymerss.In some cases, when content surpasses certain optimum level, as if as about 0.05% o'clock of polyvinylpyridine and its styrol copolymer, effect can reduce.
Some other effective cationic polymers is: the multipolymer of vinyl pyridine and N-vinyl pyrrolidone (63/37), and effective pyridine nitrogen atom of wherein about 40% is by quaternized; The multipolymer of vinyl pyridine and vinyl cyanide (60/40) is by as described above by quaternized; Methacrylic acid N, the multipolymer of N-dimethylaminoethyl ester and vinylbenzene (55/45), effective amino nitrogen atom of wherein about 75% is by as described above by quaternized.Effective amino nitrogen atom of about 75% is by as described above by quaternized among the Eudragit E (trade(brand)name of RohmGmbH).Eudragit E is considered to methacrylic acid N, the multipolymer of N-dialkyl aminoalkyl ester and neutral acrylate, and it has about 100000 to about 1000000 molecular weight; N-vinyl pyrrolidone and methacrylic acid N, the multipolymer of N-diethylin methyl ester (40/50), effective amino nitrogen atom of wherein about 50% is by quaternized; These cationic polymerss can be with known method by quaternized alkaline polymer preparation.
And other cationic polymers salt is by quaternised polymine.They have at least 10 repeating units, and are some or all of by quaternized.The commercially available example of this base polymer is also sold by Allied Colloids with general trade(brand)name Alcostat.
The representative instance of polymkeric substance is disclosed in the U.S. Pat 4179382, and this patent is quoted as a reference by this paper.
Each polyamine nitrogen-atoms no matter be primary, the second month in a season or tertiary N atom, is further defined as one of three kinds of following universal classes: simply replace quaternized or oxidation.
Polymkeric substance is by using water soluble anion such as chlorine (Cl -), bromine (Br -), iodine (I -) or any other negative electricity group such as sulfate radical (SO 4 2-) and methylsulphonic acid root (CH 3SO 3-) become neutrality.
Special polyamine backbone is disclosed in the people's such as Ulrich that authorize December 5 nineteen thirty-nine U.S. Pat 2182306; The people's such as Mayle that on May 8th, 1962 authorized U.S. Pat 3033746; The people's such as Esselmann that on July 16th, 1940 authorized U.S. Pat 2208095; The people's such as Crowther that authorize September 17 nineteen fifty-seven U.S. Pat 2806839; In the people's such as Wilson that authorize May 21 nineteen fifty-one U.S. Pat 2553696; All described patents are quoted as a reference by this paper.
The example of adorned polyamine cationic polymers of the present invention comprises PEI ' s, and it comprises the PEI skeleton, and wherein all can pass through with polyoxy alkylidene oxygen unit-(CH by substituted nitrogen-atoms 2CH 2O) 7H replaces hydrogen and is modified, and it has the following formula structure:
Figure A9880714900781
The another kind of polyamine cationic polymers that is fit to comprises PEI skeleton as above, and wherein all can pass through with polyoxy alkylidene oxygen unit-(CH by substituted primary amine nitrogen-atoms 2CH 2O) 7H replaces hydrogen and is modified, and then all oxidable primary and secondary nitrogen-atoms is oxidized to the N-oxide compound and modifies.
Another kind of relevant polyamine cationic polymers contains the PEI skeleton, and wherein the hydrogen atom of all skeletons is substituted amine unit with some skeleton by quaternized.Substituting group is polyoxy alkylidene oxygen unit ,-(CH 2CH 2O) 7H, or methyl.Another kind of relevant polyamine cationic polymers contains the PEI skeleton, and wherein the nitrogen-atoms of skeleton is substituted base (i.e. quilt-(CH 2CH 2O) 7H or methyl) modify, quaternized, be oxidized to the combination of N-oxide compound or these modes.
Certainly, can use the mixture of any above-mentioned cationic polymers, can select to use certain polymkeric substance or special mixture with the physical properties of control combination thing such as the viscosity and the stability of its aqueous dispersion.
In order to reach the most effective, cationic polymers of the present invention should be in continuous aqueous mutually in, reach the content that discloses at least herein.In order to ensure polymkeric substance is with the continuous aqueous phase, and they are being added in preparation composition method just at last preferably.Fabric softener active matter exists with the vesicle form usually.After vesicle forms, when temperature is lower than about 85 °F, add polymkeric substance.
(L) other optional components siloxanes
Siloxanes of the present invention can be polydimethylsiloxane (polydimethylsiloxane or PDMS) or their derivative, for example, and aminosiloxane, ethoxylated siloxanes etc.Preferred PDMS has lower molecular weight, and for example, viscosity is about 2 to about 5000cSt, and preferably about 5 to about 500cSt, and more preferably from about 25 to about 200cSt.Siloxanes milk sap can be advantageously used in the preparation of composition of the present invention.But preferred siloxanes begins not emulsified at least.That is, siloxanes should be emulsified in composition self.In the preparation method for compositions, preferably siloxanes is added in " water base body ", this water base body contains water and optionally contains other and is present in the composition that contains aqueous phase usually.
Lower molecular weight PDMS is preferred in the fabric softener composition of the present invention.Lower molecular weight PDMS emulsification in advance just is easier to preparation.
Can use silicone derivative such as amino-functional group's siloxanes, quaternized siloxanes and contain Si-OH, Si-H, and/or the silicone derivative of Si-Cl key.But these silicone derivatives have more affinity usually to fabric, can accumulate on fabric after re-treatment, in fact cause the fabric absorptivity to reduce.
In the time of in adding entry, fabric softener composition is deposited on fabric face so that soft result of the fabric to be provided with biodegradable cationic fabric softener actives.But in the typical clothes washing method that uses automatic washing machine, when about 40ppm of surpassing is arranged in rinse water, when especially surpassing the biodegradable cationic fabric softness promoting agent of about 50ppm, the water-absorbent of cotton fabric reduces significantly.When using siloxanes under the fabric softener in this amount, siloxanes has improved the water-absorbent of fabric, especially to the fabric of new processing, and does not influence the fabric sofetening performance unfriendly.The absorptive mechanism of this improvement is not clear, because siloxanes itself is hydrophobic.Very unexpectedly they have some improvement to water-absorbent, and water-absorbent are not caused other loss.
The quantity of obviously improving the required PDMS of water-absorbent depends on the rewetting performance that just begins, and the described rewetting performance that just begins depends on the type of the washing composition that uses in the washing.Its significant quantity scope is extremely about 50ppm of about 2ppm in rinse water, and preferred about 5 to about 20ppm.The ratio of PDMS and softening agent actives is about 2: 100 to about 50: 100, preferred about 3: 100 to about 35: 100, and more preferably from about 4: 100 to about 25: 100.As described earlier in this article, the present composition generally needs about 0.2% to about 20%, and preferred about 0.5 to about 10%, more preferably from about 1% to about 5% siloxanes.
But PDMS also improves the easy flatiron ability of fabric except that the rewetting characteristic of improving fabric.When Fabrid care composition contained selectively soil release polymers, the quantity that is deposited on the PDMS on the cotton fabric increased and PDMS has improved the effect of freeing dirt of polyester textile.PDMS also improves the rinsing characteristic of Fabrid care composition by reducing the foaming trend of composition in rinse cycle.Unexpectedly, since the existence of a large amount of relatively PDMS, the reduction of the softness characteristics of Fabrid care composition, also very little if any.
The present invention can be included in normally used other optional ingredient in the fabric treatment composition, for example: tinting material; Sanitas; Tensio-active agent; Antishrinking agent; The fabric stiffener; Spotting agent; Sterilant; Mycocide; Antioxidant such as Yoshinox BHT, corrosion inhibitor, enzyme be proteolytic enzyme, cellulase, amylase, lipase etc. and analogue for example.
Particularly preferred component comprises water-soluble calcium and/or magnesium compound, and they provide additional stability.Villaumite is preferred, but can use acetate, nitrate etc.The content of described calcium and/or magnesium salts is 0% to about 2%, and preferred about 0.05% to about 0.5%, more preferably from about 0.1% to about 0.25%.
The present composition also can comprise other compatible components, comprises that those application serial no that are disclosed in the people such as Rusche that now submit January 12 autre action pendante nineteen ninety-five are 08/372068; The people's such as Shaw that submit January 12 nineteen ninety-five series number is 08/372490; With the people's such as Hartman that submitted on July 19th, 1994 series number be component in 08/277558; These documents are quoted as a reference by this paper.
Can use many synthetic methods to prepare main solvent of the present invention.The method that is fit to is disclosed in the aforementioned autre action pendante application, but not will be understood that as restriction.
Unless otherwise indicated, all umbers, percentage ratio, ratio and ratio are by weight herein, and all numerical value are based on about value of normal credible limit.The relevant portion of all documents of quoting is quoted for referencial use at this paper.
Following non-restrictive example has illustrated the transparent or semitransparent product with acceptable viscosity.
In following synthetic embodiment, further specify the synthetic of fabric soft compound of the present invention.Provide these synthetic embodiment purposes only to be explanation.
The synthetic embodiment A of fatty acid cpds
The merchant that about 1300 gram food grade (by refining, bleach, came unstuck) Canola Oils and about 6.5 grams are equivalent to about 0.13% weight Ni sells nickel hydrogenation catalyst (Engelhard, " N-545 " ) and is placed in the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 170 ℃, and hydrogen is fed in the reactor.Be maintained at about the stirring under the 450rpm in during entire reaction.After about 10 minutes, the temperature in the reactor is about 191 ℃, and hydrogen-pressure is about 11 pounds/inch 2This temperature is maintained at about 190 ℃.After about 127 minutes when beginning to feed hydrogen, hydrogen-pressure is about 10 pounds/inch 2Take out the reactant sample, find that iodine number is about 78 and cis: trans ratio is about 1.098.Under about 190 ℃ in addition after about 20 minutes, hydrogen-pressure is about 9.8 pounds/inch 2Stop to feed hydrogen, stir the material in the cooling reactor.The iodine number of final reacting product is about 74.5 and cis: trans ratio is about 1.35.
The product that taking-up forms in reactor also filters.Its cloud point is about 22.2 ℃.The sample that took out in the time of about 127 minutes and the chain length distribution of acyl substituent of the finished product are determined, and be as shown in table 1, and wherein " saturated " meaning is saturated, and " list " and " two " looks like is respectively monounsaturated and two undersaturated.
Table 1
Saturated 0.7 0.75C20-of single 77.0 73.8C18-, 2 4.5 3.1C20-of saturated 8.9 13.25C18-of single 0.4 0.4C18-of saturated 4.7 4.6C16-of 127 minutes saturated 0.1 0.1C16-of products C 14-of about percentage (mole) chain length sample@single 2.1 2.0 other 1.6 2.0
The synthetic Embodiment B of fatty acid cpds
About 1300 gram food grade Canola Oils and about 5.2 gram Engelhard " N-545 "  nickel hydrogenation catalysts are put into the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 175 ℃, and hydrogen is fed in the reactor.Be maintained at about the stirring under the 450rpm in during entire reaction.After about 5 minutes, the temperature in the reactor is about 190 ℃, and hydrogen-pressure is about 7 pounds/inch 2This temperature is maintained at about 190 ℃.After about 125 minutes when beginning to feed hydrogen, hydrogen-pressure is about 7 pounds/inch 2Take out the reactant sample, find that iodine number is about 85.4.Under about 190 ℃ in addition after about 20 minutes, hydrogen-pressure is about 6 pounds/inch 2Stop to feed hydrogen, stir the material in the cooling reactor.The iodine number of final reacting product is about 80.The product that taking-up forms in reactor also filters, and its cloud point is about 18.6 ℃.
The synthetic Embodiment C of fatty acid cpds
About 1300 gram food grade Canola Oils and about 2.9 gram Engelhard " N-545 "  nickel hydrogenation catalysts are put into the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 180 ℃, and hydrogen is fed in the reactor.Be maintained at about the stirring under the 450rpm in during entire reaction.After about 5 minutes, the temperature in the reactor is about 192 ℃, and hydrogen-pressure is about 10 pounds/inch 2This temperature is maintained at about 190 ± 3 ℃.After about 105 minutes when beginning to feed hydrogen, hydrogen-pressure is about 10 pounds/inch 2Take out the reactant sample, find that iodine number is about 85.5.Under about 190 ℃ in addition after about 20 minutes, hydrogen-pressure is about 10 pounds/inch 2Stop to feed hydrogen, stir the material in the cooling reactor.The iodine number of final reacting product is about 82.4.The product that taking-up forms in reactor also filters, and its cloud point is about 17.2 ℃.
The synthetic embodiment D of fatty acid cpds
About 1300 gram food grade Canola Oils and about 1.4 gram Engelhard " N-545 "  nickel hydrogenation catalysts are put into the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 180 ℃, and hydrogen is fed in the reactor.After about 5 minutes, the temperature in the reactor is about 191 ℃, and hydrogen-pressure is about 10 pounds/inch 2This temperature is maintained at about 190 ± 3 ℃.After about 100 minutes when beginning to feed hydrogen, hydrogen-pressure is about 10 pounds/inch 2Take out the reactant sample, find that iodine number is about 95.4.Under about 190 ℃ in addition after about 20 minutes, hydrogen-pressure is about 10 pounds/inch 2Stop to feed hydrogen, stir the material in the cooling reactor.The iodine number of final reacting product is about 2.3.The product that taking-up forms in reactor also filters, and its cloud point is about 34 ℃.
The synthetic embodiment E of fatty acid cpds
About 1300 gram food grade Canola Oils and about 1.3 gram Engelhard " N-545 "  nickel hydrogenation catalysts are put into the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 190 ℃, with hydrogen feed in the reactor to hydrogen-pressure be about 5 pounds/inch 2After about 3 minutes when beginning to feed hydrogen, take out the reactant sample, find that iodine number is about 98.Be interrupted hydrogenation, add the identical catalyzer of about in addition 0.7 gram, recover reaction conditions down at about 190 ℃, other carried out about 1 hour.Stop to feed hydrogen then, stir the material in the cooling reactor.The iodine number of final reacting product is about 89.9.The product that taking-up forms in reactor also filters, and its cloud point is about 16 ℃.
The synthetic embodiment F of fatty acid cpds
About 1300 gram food grade Canola Oils and about 2.0 gram Engelhard " N-545 "  nickel hydrogenation catalysts are put into the hydrogenator that agitator is housed.This reactor is sealed and find time.Content is heated to about 190 ℃, with hydrogen feed in the reactor to hydrogen-pressure be about 5 pounds/inch 2Be maintained at about the stirring under the 420rpm between the reaction period of whole feeding hydrogen.After about 130 minutes when beginning to feed hydrogen, stop to feed hydrogen, stir the material in the cooling reactor.The iodine number of final reacting product is about 96.4.The product that taking-up forms in reactor also filters, and its cloud point is about 11.2 ℃.
The synthetic embodiment G of fatty acid cpds
The mixture of the about 1200 gram winterized stearin that obtained by synthetic embodiment F and about 200 gram winterized stearin of being obtained by synthetic embodiment A is at about 600 pounds/inch 2Down with 250 ℃ of steam by steam: oil ratio is routine to be hydrolyzed three times about 2.5 hours for about 1.2 (by weight).Remove the isolated aqueous solution that contains glycerine.
The mixture of resulting lipid acid is by about altogether 150 minutes of vacuum distilling, and wherein the temperature of still rises to about 238 ℃ gradually from about 200 ℃, and head temperature rises to about 197 ℃ gradually from about 175 ℃.Keep the vacuum tightness under about 0.3-0.6mm.
The iodine number of the resulting fatty acid product of vacuum distilling is about 99.1, and amine value (AV) is about 197.6, and saponification value (SAP) is about 198.6.
Below be synthetic embodiment according to softener compound of the present invention.The synthetic embodiment 1 of softener compound 1 (SC1)) esterification:
The partially hydrogenated tallow fatty acid of about 489 grams that sold by Witco company and that be purchased with trade(brand)name Distal 51, its IV about 45 and acid number are about 206, are added in the reactor this reactor N 2Purge also under agitation adds about 149 gram trolamines.The mol ratio of lipid acid and trolamine is about 1.8: 1.This mixture is heated above about 150 ℃, reduces pressure and removes water of condensation.Prolong reaction, reach about 5 until acid number.2) quaternized:
Under continuously stirring, in the above-mentioned condensation product of about 627 grams, add about 122 gram methyl-sulfates.Reaction mixture is maintained at about more than 50 ℃, checks residual amine value then.Obtain 749 grams softener compound of the present invention.
This quaternised material is use-case 15% alcohol dilution according to appointment randomly, and this has reduced the fusing point of this material, and this material is handled better.The synthetic embodiment 1 of softener compound 2 (SC2)) esterification:
The fatty oleic acid of about 504 grams that sold by Henkel company and that be purchased with trade(brand)name Emersol 233, its IV about 90 and acid number are about 198, are added in the reactor this reactor N 2Purge also under agitation adds about 149 gram trolamines.The mol ratio of lipid acid and trolamine is about 1.8: 1.This mixture is heated above about 150 ℃, reduces pressure and removes water of condensation.Prolong reaction, reach about 2 until acid number.2) quaternized:
Under continuously stirring, in the above-mentioned condensation product of about 629 grams, add about 122 gram methyl-sulfates.Reaction mixture is maintained at about more than 50 ℃, checks residual amine value then.Obtain about 751 grams softener compound of the present invention.
This quaternised material is use-case 8% alcohol dilution according to appointment randomly, and this has reduced the fusing point of this material, makes the easier processing of this material thus.The synthetic embodiment 1 of softener compound 3 (SC3)) esterification:
According to the synthetic embodiment G preparation of fatty acid cpds have IV be about 100 and acid number be that about 571 gram canola lipid acid of about 196 are added in the reactor this reactor N 2Purge also under agitation adds about 149 gram trolamines.The mol ratio of lipid acid and trolamine is about 2.0: 1.This mixture is heated above about 150 ℃, reduces pressure and removes water of condensation.Prolong reaction, reach about 3 until acid number.2) quaternized:
Under continuously stirring, in the above-mentioned condensation product of about 698 grams, add about 122 gram methyl-sulfates.Reaction mixture is maintained at about more than 50 ℃, checks residual amine value then.Obtain about 820 grams softener compound of the present invention.
This quaternised material is use-case about 50: 50 ethanol/hexylene glycol mixture diluted of 15% according to appointment randomly, and this has reduced the fusing point of this material, makes the easier processing of this material thus.The synthetic embodiment 1 of softener compound 4 (SC4)) esterification:
According to the synthetic embodiment G preparation of fatty acid cpds have IV be about 100 and acid number be that about 457 gram canola lipid acid of about 196 are added in the reactor this reactor N 2Purge also under agitation adds about 149 gram trolamines.The mol ratio of lipid acid and trolamine is about 1.6: 1.This mixture is heated above about 150 ℃, reduces pressure and removes water of condensation.Prolong reaction, reach about 1 until acid number.2) quaternized:
Under continuously stirring, in the above-mentioned condensation product of about 582 grams, add about 122 gram methyl-sulfates.Reaction mixture is maintained at about more than 50 ℃, checks residual amine value then.Obtain 704 grams softener compound of the present invention.
This quaternised material is use-case 8% alcohol dilution according to appointment randomly, and this has reduced the fusing point of this material, makes the easier processing of this material thus.
It is about 90 and by the palatable substances of the following content of η g/L that above synthetic softener compound has Hunter L transmission value: isopropyl acetate＜about 1 generally is can not detection limit; 1,3,5-trioxane about 5.3; 2,2 '-ethylene (oxygen), two propane＜about 1 generally are can not detection limit; C6 methyl esters＜about 1 generally is can not detection limit; C8 methyl esters＜about 1 generally is can not detection limit; With C10 methyl esters＜about 1, generally be can not detection limit.
Above synthetic softener compound also exemplifies explanation in following nonrestrictive fabric sofetening composition embodiment.The abbreviation of Shi Yonging in an embodiment
In soft compound, the component symbol of abbreviation has following implication: SC1: according to the softener compound SC2 of the synthetic embodiment preparation of softener compound 1: according to the softener compound SC3 of the synthetic embodiment preparation of softener compound 2: according to the softener compound SC4 of the synthetic embodiment preparation of softener compound 3: according to the softener compound TMPD of the synthetic embodiment preparation of softener compound 4: 2,2,4-trimethylammonium-1,3-pentanediol CHDM: 1,4 cyclohexane dimethanol
The oil base body that at first at room temperature prepares the softening agent actives prepares the composition in following examples.If the softening agent actives at room temperature is not a fluid, this softening agent actives is if the words that need can be heated to fusion.This softening agent actives uses IKA RW25  mixing tank to mix under about 150rpm about 2-5 minute.Individually, by at room temperature being mixed with deionization (DI) water, HCl prepares acid/water base body.If softening agent actives and/or main solvent at room temperature are not fluids and need to heat that this acid/water base body also should be heated to suitable temperature, for example about 100 °F (about 38 ℃) also make water-bath keep described temperature.Main solvent (if their fusing point is on room temperature, then should fusion under suitable temperature) is added in the softening agent premixture, and this premixture mixed about 5 minutes.Add acid/water base body in the softening agent premixture then and mixing about 20-30 minute or transparent and homogeneous until composition.Make the said composition air cooling to room temperature.
1 2 3 4 5
SC1 8.0 - - - -
SC2 - 8.0 20 30 28
Ethanol 1.4 0.7 1.7 2.6 2.4
1, the 2-hexylene glycol - 10 15 - -
2-ethyl-1, the 3-hexylene glycol - - - - 12
TMPD - - - 12 -
CHDM - - - 5 5
HCl 0.02 0.02 0.02 0.02 0.02
Calcium chloride 0.04 - - - -
Spices 0.5 0.5 1.0 2.0 2.0
Dyestuff 5ppm 5ppm 5ppm 5ppm 5ppm
Deionized water Equal amount Equal amount Equal amount Equal amount Equal amount
6 7 8 9
SC3 8.0 25 - 28
SC4 - - 30 -
Ethanol 0.7 2.2 2.6 2.5
Hexylene glycol 0.7 2.2 - 2.5
1, the 2-hexylene glycol 9 12 15 5
TMPD - 5 - 9
HCl 0.02 0.02 0.02 0.02
Spices 0.5 1.5 1.0 2.0
Dyestuff 5ppm 20ppm ?20ppm 5ppm
Deionized water Equal amount Equal amount Equal amount Equal amount
The oil base body that at first at room temperature prepares the softening agent actives prepares the dispersive composition in following examples.If the softening agent actives at room temperature is not a fluid, this softening agent actives is if the words that need can be heated to fusion.This softening agent actives uses IKA RW25  mixing tank to mix under about 150rpm about 2-5 minute.Individually, by at room temperature being mixed with deionization (DI) water, HCl prepares acid/water base body.If the softening agent actives at room temperature is not fluid and needs to heat that this acid/water base body also should be heated to suitable temperature, for example about 100 °F (about 38 ℃) also make water-bath keep described temperature.Add softening agent, under high energy mixes, form stable dispersion.
For commercial purpose, above composition 1-9 is added into by polypropylene (although useable glass, replacements such as oriented polyethylene) container of making, bottle and (although can use translucent bottle) in the clear vial specifically more specifically, this bottle has sky-blue and transfers, that exist with compensation or any yellow of in storage process, producing (although, for short period of time and perfect transparent product, can use the transparent vessel of not being with tone or other tone), and have UV light absorber so that ultraviolet to inner material in bottle, particularly the effect of highly undersaturated actives reduces to minimum (this absorption agent also can be on the bottle surface).Total effect of transparency and container has proved the transparency of composition, makes the human consumer confirm the quality of product thus.The transparency of fabric softener and smell are crucial for acceptability, especially when having the fabric softener of high level.
Embodiment 10 component A B C D
Weight % weight % weight % weight %SC3 18---SC2-20--SC3-20--SC4---16 ethanol 666 6CaCl 20.5 0.5 0.5 0.5HCl (a) (a) (a) (a) spices 0.2 0.2 0.2 0.2Kathon 3ppm 3ppm 3ppm 3ppm deionized water balance amount equal amount equal amount equal amounts (a) pH of composition is transferred to about 3.5-4.0.
The sample that the canola lipid acid that will be prepared by the inventive method relatively from the softening agent sample that oleic acid makes makes is color relatively.Measure the transparency of Hunter " L " value and visual mensuration color:
The softening agent actives Hunter " L " value The acceptability of transparent composition
Varisoft WE-15 (based on oleic acid) 77.0 Unacceptable
Softening agent actives #1 (based on canola) 99.0 Can accept
Softening agent actives #2 (based on canola) 97.9 Can accept

Claims (11)

1. the fabric soft compound that has following formula:
[RC(O)OC 2H 4] nN +(R 1) mX -
Wherein each R in the compound is C 6-C 22Alkyl is the numerical value of 1-3 by weight average n in any mixture of compound, each R in the compound 1Be C 1-3Alkyl or hydroxyalkyl, n and be the R of hydroxyethyl groups 1The summation of group number equals 3, and n+m equals 4, and X is the negatively charged ion compatible with softening agent, and this compound has (a) Hunter L transmission value and is at least about 85; (b) under working conditions, have only low-down scent of compound of for example failing detection limit, it is selected from isopropyl acetate; 2,2 '-ethylene (oxygen), two propane; And/or short-chain aliphatic ester; Or (c) preferably has the two feature.
2. the compound of claim 1, wherein by the IV of lipid acid of equal value, it is 70-140 that described R has iodine number.
3. claim 2 or 3 compound, wherein by lipid acid of equal value, suitable/trans isomer ratio that described R has is (for C18: be 11 component): 1-20: 1.
4. the compound of arbitrary claim 1-3, wherein said X is a methylsulfate.
5. the compound of arbitrary claim 1-4, wherein said Hunter L transmission value is 85-95.
6. the compound of arbitrary claim 1-5, wherein said short-chain aliphatic ester contains 4-12 or 6-10 carbon atom.
7. the compound of arbitrary claim 1-6, wherein the content of each scent of compound is as follows: isopropyl acetate should be lower than about 5 millimicro grams per liters; 2,2 '-ethylene (oxygen), two propane should be lower than about 200 millimicro grams per liters; 1,3, the 5-trioxane should be lower than about 50 millimicro grams per liters; And/or each C 4-12Chain fatty acid ester should be lower than about 4 millimicro grams per liters.
8. the compound of claim 7, wherein the content of each scent of compound is as follows: isopropyl acetate should be lower than about 3 millimicro grams per liters; 2,2 '-ethylene (oxygen), two propane should be lower than about 100 millimicro grams per liters; 1,3, the 5-trioxane should be lower than about 20 millimicro grams per liters; And/or each C 4-12Chain fatty acid ester should be lower than about 3 millimicro grams per liters, or randomly as follows: isopropyl acetate should be lower than about 2 millimicro grams per liters; 2,2 '-ethylene (oxygen), two propane should be lower than about 10 millimicro grams per liters; 1,3, the 5-trioxane should be lower than about 10 millimicro grams per liters; And/or each C 4-12Chain fatty acid ester should be lower than about 2 millimicro grams per liters.
9. the composition of arbitrary claim 1-8, the content of wherein said component A is 8%-70%; The content of described B component is 5%-40%; With the water that has 3%-95%; Or the content of wherein said component A is 13%-65%; The content of described B component is 7%-35%; With the water that has 10%-80%; Or the content of wherein said component A is 18%-40%; The content of described B component is 10%-25%; With the water that has 30%-70%.
10. the composition of arbitrary claim 1-9, it randomly contains:
(1) be enough to improve the low-molecular weight water-soluble solvent of the significant quantity of transparency, the content of described water-soluble solvent for when use separately it the time do not form clear composition;
(2) 0.1%-8% spices;
(3) 0.01%-0.2% stablizer; With
(4) improve the water-soluble calcium and/or the magnesium salts of transparency significant quantity.
11. aqueous, stable fabric softener dispersion composite, it contains 5%-35%; 8%-30%; 10%-28%; Or the fabric softener compound of 13%-26% claim 1.
CN 98807149 1997-05-19 1998-04-15 Softener active derived from acylated triethanolamine Pending CN1263552A (en)

Applications Claiming Priority (2)

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US4471997P 1997-05-19 1997-05-19
US60/044,719 1997-05-19

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CN1263552A true CN1263552A (en) 2000-08-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112384601A (en) * 2018-07-11 2021-02-19 科莱恩国际有限公司 Preparation and use of high quality esterquat derived from rice bran fatty acids

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112384601A (en) * 2018-07-11 2021-02-19 科莱恩国际有限公司 Preparation and use of high quality esterquat derived from rice bran fatty acids
US11773347B2 (en) 2018-07-11 2023-10-03 Clariant International Ltd Preparation and use of high quality esterquats from rice bran fatty acids

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